Articles | Volume 26, issue 8
https://doi.org/10.5194/hess-26-2161-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/hess-26-2161-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
HESS Opinions: Chemical transport modeling in subsurface hydrological systems – space, time, and the “holy grail” of “upscaling”
Brian Berkowitz
CORRESPONDING AUTHOR
Department of Earth and Planetary Sciences, Weizmann Institute of
Science, Rehovot 7610001, Israel
Related authors
Dan Elhanati, Erwin Zehe, Ishai Dror, and Brian Berkowitz
EGUsphere, https://doi.org/10.5194/egusphere-2025-3365, https://doi.org/10.5194/egusphere-2025-3365, 2025
Short summary
Short summary
Measurements of water isotopes are often used to estimate water transit time distributions and aquifer storage thickness in catchments. However, laboratory-scale measurements show that water isotopes exhibit transport behavior identical to that of inert chemical tracers rather than of pure water. The measured mean tracer and apparent mean water velocities are not necessarily equal; recognition of this inequality is critical when estimating catchment properties such as aquifer storage thickness.
Dan Elhanati, Nadine Goeppert, and Brian Berkowitz
Hydrol. Earth Syst. Sci., 28, 4239–4249, https://doi.org/10.5194/hess-28-4239-2024, https://doi.org/10.5194/hess-28-4239-2024, 2024
Short summary
Short summary
A continuous time random walk framework was developed to allow modeling of a karst aquifer discharge response to measured rainfall. The application of the numerical model yielded robust fits between modeled and measured discharge values, especially for the distinctive long tails found during recession times. The findings shed light on the interplay of slow and fast flow in the karst system and establish the application of the model for simulating flow and transport in such systems.
Alexander Sternagel, Ralf Loritz, Brian Berkowitz, and Erwin Zehe
Hydrol. Earth Syst. Sci., 26, 1615–1629, https://doi.org/10.5194/hess-26-1615-2022, https://doi.org/10.5194/hess-26-1615-2022, 2022
Short summary
Short summary
We present a (physically based) Lagrangian approach to simulate diffusive mixing processes on the pore scale beyond perfectly mixed conditions. Results show the feasibility of the approach for reproducing measured mixing times and concentrations of isotopes over pore sizes and that typical shapes of breakthrough curves (normally associated with non-uniform transport in heterogeneous soils) may also occur as a result of imperfect subscale mixing in a macroscopically homogeneous soil matrix.
Erwin Zehe, Ralf Loritz, Yaniv Edery, and Brian Berkowitz
Hydrol. Earth Syst. Sci., 25, 5337–5353, https://doi.org/10.5194/hess-25-5337-2021, https://doi.org/10.5194/hess-25-5337-2021, 2021
Short summary
Short summary
This study uses the concepts of entropy and work to quantify and explain the emergence of preferential flow and transport in heterogeneous saturated porous media. We found that the downstream concentration of solutes in preferential pathways implies a downstream declining entropy in the transverse distribution of solute transport pathways. Preferential flow patterns with lower entropies emerged within media of higher heterogeneity – a stronger self-organization despite a higher randomness.
Alexander Sternagel, Ralf Loritz, Julian Klaus, Brian Berkowitz, and Erwin Zehe
Hydrol. Earth Syst. Sci., 25, 1483–1508, https://doi.org/10.5194/hess-25-1483-2021, https://doi.org/10.5194/hess-25-1483-2021, 2021
Short summary
Short summary
The key innovation of the study is a method to simulate reactive solute transport in the vadose zone within a Lagrangian framework. We extend the LAST-Model with a method to account for non-linear sorption and first-order degradation processes during unsaturated transport of reactive substances in the matrix and macropores. Model evaluations using bromide and pesticide data from irrigation experiments under different flow conditions on various timescales show the feasibility of the method.
Dan Elhanati, Erwin Zehe, Ishai Dror, and Brian Berkowitz
EGUsphere, https://doi.org/10.5194/egusphere-2025-3365, https://doi.org/10.5194/egusphere-2025-3365, 2025
Short summary
Short summary
Measurements of water isotopes are often used to estimate water transit time distributions and aquifer storage thickness in catchments. However, laboratory-scale measurements show that water isotopes exhibit transport behavior identical to that of inert chemical tracers rather than of pure water. The measured mean tracer and apparent mean water velocities are not necessarily equal; recognition of this inequality is critical when estimating catchment properties such as aquifer storage thickness.
Dan Elhanati, Nadine Goeppert, and Brian Berkowitz
Hydrol. Earth Syst. Sci., 28, 4239–4249, https://doi.org/10.5194/hess-28-4239-2024, https://doi.org/10.5194/hess-28-4239-2024, 2024
Short summary
Short summary
A continuous time random walk framework was developed to allow modeling of a karst aquifer discharge response to measured rainfall. The application of the numerical model yielded robust fits between modeled and measured discharge values, especially for the distinctive long tails found during recession times. The findings shed light on the interplay of slow and fast flow in the karst system and establish the application of the model for simulating flow and transport in such systems.
Alexander Sternagel, Ralf Loritz, Brian Berkowitz, and Erwin Zehe
Hydrol. Earth Syst. Sci., 26, 1615–1629, https://doi.org/10.5194/hess-26-1615-2022, https://doi.org/10.5194/hess-26-1615-2022, 2022
Short summary
Short summary
We present a (physically based) Lagrangian approach to simulate diffusive mixing processes on the pore scale beyond perfectly mixed conditions. Results show the feasibility of the approach for reproducing measured mixing times and concentrations of isotopes over pore sizes and that typical shapes of breakthrough curves (normally associated with non-uniform transport in heterogeneous soils) may also occur as a result of imperfect subscale mixing in a macroscopically homogeneous soil matrix.
Erwin Zehe, Ralf Loritz, Yaniv Edery, and Brian Berkowitz
Hydrol. Earth Syst. Sci., 25, 5337–5353, https://doi.org/10.5194/hess-25-5337-2021, https://doi.org/10.5194/hess-25-5337-2021, 2021
Short summary
Short summary
This study uses the concepts of entropy and work to quantify and explain the emergence of preferential flow and transport in heterogeneous saturated porous media. We found that the downstream concentration of solutes in preferential pathways implies a downstream declining entropy in the transverse distribution of solute transport pathways. Preferential flow patterns with lower entropies emerged within media of higher heterogeneity – a stronger self-organization despite a higher randomness.
Alexander Sternagel, Ralf Loritz, Julian Klaus, Brian Berkowitz, and Erwin Zehe
Hydrol. Earth Syst. Sci., 25, 1483–1508, https://doi.org/10.5194/hess-25-1483-2021, https://doi.org/10.5194/hess-25-1483-2021, 2021
Short summary
Short summary
The key innovation of the study is a method to simulate reactive solute transport in the vadose zone within a Lagrangian framework. We extend the LAST-Model with a method to account for non-linear sorption and first-order degradation processes during unsaturated transport of reactive substances in the matrix and macropores. Model evaluations using bromide and pesticide data from irrigation experiments under different flow conditions on various timescales show the feasibility of the method.
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Short summary
Extensive efforts have focused on quantifying conservative chemical transport in geological formations. We assert that an explicit accounting of temporal information, under uncertainty, in addition to spatial information, is fundamental to an effective modeling formulation. We further assert that efforts to apply chemical transport equations at large length scales, based on measurements and model parameter values relevant to significantly smaller length scales, are an unattainable
holy grail.
Extensive efforts have focused on quantifying conservative chemical transport in geological...
Special issue