Articles | Volume 24, issue 5
https://doi.org/10.5194/hess-24-2561-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/hess-24-2561-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
15 May 2020
Research article |
| 15 May 2020
Concentration–discharge relationships vary among hydrological events, reflecting differences in event characteristics
Julia L. A. Knapp
CORRESPONDING AUTHOR
Department of Environmental Systems Science, ETH Zurich, 8092 Zurich, Switzerland
Jana von Freyberg
Department of Environmental Systems Science, ETH Zurich, 8092 Zurich, Switzerland
Swiss Federal Institute for Forest, Snow and Landscape Research WSL, 8903 Birmensdorf, Switzerland
Bjørn Studer
Department of Environmental Systems Science, ETH Zurich, 8092 Zurich, Switzerland
Leonie Kiewiet
Department of Geography, University of Zurich, 8057 Zurich,
Switzerland
James W. Kirchner
Department of Environmental Systems Science, ETH Zurich, 8092 Zurich, Switzerland
Swiss Federal Institute for Forest, Snow and Landscape Research WSL, 8903 Birmensdorf, Switzerland
Department of Earth and Planetary Science, University of California, Berkeley, CA 94720, USA
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Nitrate contamination of rivers from agricultural sources is a challenge for water quality management. During runoff events, different transport paths within the catchment might be activated, generating a variety of responses in nitrate concentration in stream water. Using nitrate samples from 184 German catchments and a runoff event classification, we show that hydrologic connectivity during runoff events is a key control of nitrate transport from catchments to streams in our study domain.
Tobias Nicollier, Gilles Antoniazza, Lorenz Ammann, Dieter Rickenmann, and James W. Kirchner
Earth Surf. Dynam., 10, 929–951, https://doi.org/10.5194/esurf-10-929-2022, https://doi.org/10.5194/esurf-10-929-2022, 2022
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Monitoring sediment transport is relevant for flood safety and river restoration. However, the spatial and temporal variability of sediment transport processes makes their prediction challenging. We investigate the feasibility of a general calibration relationship between sediment transport rates and the impact signals recorded by metal plates installed in the channel bed. We present a new calibration method based on flume experiments and apply it to an extensive dataset of field measurements.
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Hydrol. Earth Syst. Sci., 26, 3393–3417, https://doi.org/10.5194/hess-26-3393-2022, https://doi.org/10.5194/hess-26-3393-2022, 2022
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We present a new way to detect snowmelt using daily cycles in streamflow driven by solar radiation. Results show that warmer sites have earlier and more intermittent snowmelt than colder sites, and the timing of early snowmelt events is strongly correlated with the timing of streamflow volume. A space-for-time substitution shows greater sensitivity of streamflow timing to climate change in colder rather than in warmer places, which is then contrasted with land surface simulations.
Leonie Kiewiet, Ernesto Trujillo, Andrew Hedrick, Scott Havens, Katherine Hale, Mark Seyfried, Stephanie Kampf, and Sarah E. Godsey
Hydrol. Earth Syst. Sci., 26, 2779–2796, https://doi.org/10.5194/hess-26-2779-2022, https://doi.org/10.5194/hess-26-2779-2022, 2022
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Climate change affects precipitation phase, which can propagate into changes in streamflow timing and magnitude. This study examines how variations in rainfall and snowmelt affect discharge. We found that annual discharge and stream cessation depended on the magnitude and timing of rainfall and snowmelt and on the snowpack melt-out date. This highlights the importance of precipitation timing and emphasizes the need for spatiotemporally distributed simulations of snowpack and rainfall dynamics.
Nikos Theodoratos and James W. Kirchner
Earth Surf. Dynam., 9, 1545–1561, https://doi.org/10.5194/esurf-9-1545-2021, https://doi.org/10.5194/esurf-9-1545-2021, 2021
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We examine stream-power incision and linear diffusion landscape evolution models with and without incision thresholds. We present a steady-state relationship between curvature and the steepness index, which plots as a straight line. We view this line as a counterpart to the slope–area relationship for the case of landscapes with hillslope diffusion. We show that simple shifts and rotations of this line graphically express the topographic response of landscapes to changes in model parameters.
Scott T. Allen and James W. Kirchner
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Extracting water from plant stems can introduce analytical errors in isotope analyses. We demonstrate that sensitivities to suspected errors can be evaluated and that conclusions drawn from extracted plant water isotope ratios are neither generally valid nor generally invalid. Ultimately, imperfect measurements of plant and soil water isotope ratios can continue to support useful inferences if study designs are appropriately matched to their likely biases and uncertainties.
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Marius G. Floriancic, Wouter R. Berghuijs, Tobias Jonas, James W. Kirchner, and Peter Molnar
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James W. Kirchner, Sarah E. Godsey, Madeline Solomon, Randall Osterhuber, Joseph R. McConnell, and Daniele Penna
Hydrol. Earth Syst. Sci., 24, 5095–5123, https://doi.org/10.5194/hess-24-5095-2020, https://doi.org/10.5194/hess-24-5095-2020, 2020
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Elham Rouholahnejad Freund, Massimiliano Zappa, and James W. Kirchner
Hydrol. Earth Syst. Sci., 24, 5015–5025, https://doi.org/10.5194/hess-24-5015-2020, https://doi.org/10.5194/hess-24-5015-2020, 2020
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Leonie Kiewiet, Ilja van Meerveld, Manfred Stähli, and Jan Seibert
Hydrol. Earth Syst. Sci., 24, 3381–3398, https://doi.org/10.5194/hess-24-3381-2020, https://doi.org/10.5194/hess-24-3381-2020, 2020
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Nikos Theodoratos and James W. Kirchner
Earth Surf. Dynam., 8, 505–526, https://doi.org/10.5194/esurf-8-505-2020, https://doi.org/10.5194/esurf-8-505-2020, 2020
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Elham Rouholahnejad Freund, Ying Fan, and James W. Kirchner
Hydrol. Earth Syst. Sci., 24, 1927–1938, https://doi.org/10.5194/hess-24-1927-2020, https://doi.org/10.5194/hess-24-1927-2020, 2020
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Evapotranspiration (ET) rates and properties that regulate them are spatially heterogeneous. Averaging over spatial heterogeneity in precipitation (P) and potential evapotranspiration (PET) as the main drivers of ET may lead to biased estimates of energy and water fluxes from the land to the atmosphere. We show that this bias is largest in mountainous terrains, in regions with temperate climates and dry summers, and in landscapes where spatial variations in P and PET are inversely correlated.
Francesc Gallart, Jana von Freyberg, María Valiente, James W. Kirchner, Pilar Llorens, and Jérôme Latron
Hydrol. Earth Syst. Sci., 24, 1101–1107, https://doi.org/10.5194/hess-24-1101-2020, https://doi.org/10.5194/hess-24-1101-2020, 2020
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How catchments store and release rain or melting water is still not well known. Now, it is broadly accepted that most of the water in streams is older than several months, and a relevant part may be many years old. But the age of water depends on the stream regime, being usually younger during high flows. This paper tries to provide tools for better analysing how the age of waters varies with flow in a catchment and for comparing the behaviour of catchments diverging in climate, size and regime.
James W. Kirchner and Scott T. Allen
Hydrol. Earth Syst. Sci., 24, 17–39, https://doi.org/10.5194/hess-24-17-2020, https://doi.org/10.5194/hess-24-17-2020, 2020
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Perhaps the oldest question in hydrology is
Where does water go when it rains?. Here we present a new way to measure how the terrestrial water cycle partitions precipitation into its two ultimate fates:
green waterthat is evaporated or transpired back to the atmosphere and
blue waterthat is discharged to stream channels. Our analysis may help in gauging the vulnerability of both water resources and terrestrial ecosystems to changes in rainfall patterns.
Adam S. Ward, Steven M. Wondzell, Noah M. Schmadel, Skuyler Herzog, Jay P. Zarnetske, Viktor Baranov, Phillip J. Blaen, Nicolai Brekenfeld, Rosalie Chu, Romain Derelle, Jennifer Drummond, Jan H. Fleckenstein, Vanessa Garayburu-Caruso, Emily Graham, David Hannah, Ciaran J. Harman, Jase Hixson, Julia L. A. Knapp, Stefan Krause, Marie J. Kurz, Jörg Lewandowski, Angang Li, Eugènia Martí, Melinda Miller, Alexander M. Milner, Kerry Neil, Luisa Orsini, Aaron I. Packman, Stephen Plont, Lupita Renteria, Kevin Roche, Todd Royer, Catalina Segura, James Stegen, Jason Toyoda, Jacqueline Wells, and Nathan I. Wisnoski
Hydrol. Earth Syst. Sci., 23, 5199–5225, https://doi.org/10.5194/hess-23-5199-2019, https://doi.org/10.5194/hess-23-5199-2019, 2019
Short summary
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The movement of water and solutes between streams and their shallow, connected subsurface is important to many ecosystem functions. These exchanges are widely expected to vary with stream flow across space and time, but these assumptions are seldom tested across basin scales. We completed more than 60 experiments across a 5th-order river basin to document these changes, finding patterns in space but not time. We conclude space-for-time and time-for-space substitutions are not good assumptions.
H. J. Ilja van Meerveld, James W. Kirchner, Marc J. P. Vis, Rick S. Assendelft, and Jan Seibert
Hydrol. Earth Syst. Sci., 23, 4825–4834, https://doi.org/10.5194/hess-23-4825-2019, https://doi.org/10.5194/hess-23-4825-2019, 2019
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Flowing stream networks extend and retract seasonally and in response to precipitation. This affects the distances and thus the time that it takes a water molecule to reach the flowing stream and the stream outlet. When the network is fully extended, the travel times are short, but when the network retracts, the travel times become longer and more uniform. These dynamics should be included when modeling solute or pollutant transport.
Julia L. A. Knapp, Colin Neal, Alessandro Schlumpf, Margaret Neal, and James W. Kirchner
Hydrol. Earth Syst. Sci., 23, 4367–4388, https://doi.org/10.5194/hess-23-4367-2019, https://doi.org/10.5194/hess-23-4367-2019, 2019
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We describe, present, and make publicly available two extensive data sets of stable water isotopes in streamwater and precipitation at Plynlimon, Wales, consisting of measurements at 7-hourly intervals for 17 months and at weekly intervals for 4.25 years. We use these data to calculate new water fractions and transit time distributions for different discharge rates and seasons, thus quantifying the contribution of recent precipitation to streamflow under different conditions.
Adam S. Ward, Jay P. Zarnetske, Viktor Baranov, Phillip J. Blaen, Nicolai Brekenfeld, Rosalie Chu, Romain Derelle, Jennifer Drummond, Jan H. Fleckenstein, Vanessa Garayburu-Caruso, Emily Graham, David Hannah, Ciaran J. Harman, Skuyler Herzog, Jase Hixson, Julia L. A. Knapp, Stefan Krause, Marie J. Kurz, Jörg Lewandowski, Angang Li, Eugènia Martí, Melinda Miller, Alexander M. Milner, Kerry Neil, Luisa Orsini, Aaron I. Packman, Stephen Plont, Lupita Renteria, Kevin Roche, Todd Royer, Noah M. Schmadel, Catalina Segura, James Stegen, Jason Toyoda, Jacqueline Wells, Nathan I. Wisnoski, and Steven M. Wondzell
Earth Syst. Sci. Data, 11, 1567–1581, https://doi.org/10.5194/essd-11-1567-2019, https://doi.org/10.5194/essd-11-1567-2019, 2019
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Studies of river corridor exchange commonly focus on characterization of the physical, chemical, or biological system. As a result, complimentary systems and context are often lacking, which may limit interpretation. Here, we present a characterization of all three systems at 62 sites in a 5th-order river basin, including samples of surface water, hyporheic water, and sediment. These data will allow assessment of interacting processes in the river corridor.
Scott T. Allen, Scott Jasechko, Wouter R. Berghuijs, Jeffrey M. Welker, Gregory R. Goldsmith, and James W. Kirchner
Hydrol. Earth Syst. Sci., 23, 3423–3436, https://doi.org/10.5194/hess-23-3423-2019, https://doi.org/10.5194/hess-23-3423-2019, 2019
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We developed global maps that concisely quantify the seasonality of stable isotope ratios in precipitation, using data from 653 meteorological stations across all seven continents. We make these gridded global maps publicly available to support diverse stable isotope applications.
Andrea Rücker, Stefan Boss, James W. Kirchner, and Jana von Freyberg
Hydrol. Earth Syst. Sci., 23, 2983–3005, https://doi.org/10.5194/hess-23-2983-2019, https://doi.org/10.5194/hess-23-2983-2019, 2019
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To better understand how rain-on-snow (ROS) events affect snowpack outflow volumes and streamflow generation, we measured snowpack outflow volumes and isotopic composition during 10 ROS events with automated snowmelt lysimeters at three locations in a pre-Alpine catchment. We quantified the spatio-temporal variability of snowpack outflow and its relative contribution to streamflow, and identified rainfall characteristics and initial snow depth as major controls on snow hydrological processes.
Scott T. Allen, James W. Kirchner, Sabine Braun, Rolf T. W. Siegwolf, and Gregory R. Goldsmith
Hydrol. Earth Syst. Sci., 23, 1199–1210, https://doi.org/10.5194/hess-23-1199-2019, https://doi.org/10.5194/hess-23-1199-2019, 2019
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We used stable isotopes of xylem water to study differences in the seasonal origin of water in more than 900 individual trees from three dominant species in 182 Swiss forested sites. We discovered that midsummer transpiration was mostly supplied by winter precipitation across diverse humid climates. Our findings provide new insights into tree vulnerability to droughts, transport of water (and thus solutes) in soils, and the climatic information conveyed by plant-tissue isotopes.
James W. Kirchner
Hydrol. Earth Syst. Sci., 23, 303–349, https://doi.org/10.5194/hess-23-303-2019, https://doi.org/10.5194/hess-23-303-2019, 2019
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How long does it take for raindrops to become streamflow? Here I propose a new approach to this old problem. I show how we can use time series of isotope data to measure the average fraction of same-day rainfall appearing in streamflow, even if this fraction varies greatly from rainstorm to rainstorm. I show that we can quantify how this fraction changes from small rainstorms to big ones, and from high flows to low flows, and how it changes with the lag time between rainfall and streamflow.
Jana von Freyberg, Bjørn Studer, Michael Rinderer, and James W. Kirchner
Hydrol. Earth Syst. Sci., 22, 5847–5865, https://doi.org/10.5194/hess-22-5847-2018, https://doi.org/10.5194/hess-22-5847-2018, 2018
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We show event- and pre-event-water volumes as fractions of precipitation, rather than discharge, to provide an alternative and more insightful approach to study catchment hydrological processes. For this, we analyze 24 storm events using high-frequency measurements of stable water isotopes in stream water and precipitation at a pre-Alpine catchment. Antecedent wetness and storm characteristics are dominant controls on event-water discharge and pre-event-water mobilization from storage.
Daniele Penna, Luisa Hopp, Francesca Scandellari, Scott T. Allen, Paolo Benettin, Matthias Beyer, Josie Geris, Julian Klaus, John D. Marshall, Luitgard Schwendenmann, Till H. M. Volkmann, Jana von Freyberg, Anam Amin, Natalie Ceperley, Michael Engel, Jay Frentress, Yamuna Giambastiani, Jeff J. McDonnell, Giulia Zuecco, Pilar Llorens, Rolf T. W. Siegwolf, Todd E. Dawson, and James W. Kirchner
Biogeosciences, 15, 6399–6415, https://doi.org/10.5194/bg-15-6399-2018, https://doi.org/10.5194/bg-15-6399-2018, 2018
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Understanding how water flows through ecosystems is needed to provide society and policymakers with the scientific background to manage water resources sustainably. Stable isotopes of hydrogen and oxygen in water are a powerful tool for tracking water fluxes, although the heterogeneity of natural systems and practical methodological issues still limit their full application. Here, we examine the challenges in this research field and highlight new perspectives based on interdisciplinary research.
Nikos Theodoratos, Hansjörg Seybold, and James W. Kirchner
Earth Surf. Dynam., 6, 779–808, https://doi.org/10.5194/esurf-6-779-2018, https://doi.org/10.5194/esurf-6-779-2018, 2018
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We perform dimensional analysis on a frequently used landscape evolution model (LEM). Defining characteristic scales in a novel way, we significantly simplify the LEM and develop an efficient numerical modeling approach. Our characteristic scales are physically meaningful; they quantify competitions between landscape-forming processes and are related to salient properties of landscape topography. Dimensional analyses of other LEMs may benefit from our approach in defining characteristic scales.
Jana von Freyberg, Scott T. Allen, Stefan Seeger, Markus Weiler, and James W. Kirchner
Hydrol. Earth Syst. Sci., 22, 3841–3861, https://doi.org/10.5194/hess-22-3841-2018, https://doi.org/10.5194/hess-22-3841-2018, 2018
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We explored how the fraction of streamflow younger than ca. 3 months (Fyw) varies with landscape characteristics and climatic forcing, using an extensive isotope data set from 22 Swiss catchments. Overall, Fyw tends to be larger when catchments are wet and discharge is correspondingly higher, indicating an increase in the proportional contribution of faster flow paths at higher flows. We quantify this
discharge sensitivityof Fyw and relate it to the dominant streamflow-generating mechanisms.
Paolo Benettin, Till H. M. Volkmann, Jana von Freyberg, Jay Frentress, Daniele Penna, Todd E. Dawson, and James W. Kirchner
Hydrol. Earth Syst. Sci., 22, 2881–2890, https://doi.org/10.5194/hess-22-2881-2018, https://doi.org/10.5194/hess-22-2881-2018, 2018
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Evaporation causes the isotopic composition of soil water to become different from that of the original precipitation source. If multiple samples originating from the same source are available, they can be used to reconstruct the original source composition. However, soil water is influenced by seasonal variability in both precipitation sources and evaporation patterns. We show that this variability, if not accounted for, can lead to biased estimates of the precipitation source water.
Albrecht von Boetticher, Jens M. Turowski, Brian W. McArdell, Dieter Rickenmann, Marcel Hürlimann, Christian Scheidl, and James W. Kirchner
Geosci. Model Dev., 10, 3963–3978, https://doi.org/10.5194/gmd-10-3963-2017, https://doi.org/10.5194/gmd-10-3963-2017, 2017
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The open-source fluid dynamic solver presented in v. Boetticher et al. (2016) combines a Coulomb viscosplastic rheological model with a Herschel–Bulkley model based on material properties for 3-D debris flow simulations. Here, we validate the solver and illustrate the model sensitivity to water content, channel curvature, content of fine material and channel bed roughness. We simulate both laboratory-scale and large-scale debris-flow experiments, using only one of the two calibration parameters.
Jana von Freyberg, Bjørn Studer, and James W. Kirchner
Hydrol. Earth Syst. Sci., 21, 1721–1739, https://doi.org/10.5194/hess-21-1721-2017, https://doi.org/10.5194/hess-21-1721-2017, 2017
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We present a newly developed instrument package that enables the online analysis of stable water isotopes and major ion chemistry at 30 min intervals in the field. The resulting data streams provide an unprecedented view of hydrochemical dynamics on the catchment scale. Based on a detailed analysis of the variable behavior of isotopic and chemical tracers in stream water and precipitation over a 4-week period, we developed a conceptual hypothesis for runoff generation in the studied catchment.
Elham Rouholahnejad Freund and James W. Kirchner
Hydrol. Earth Syst. Sci., 21, 217–233, https://doi.org/10.5194/hess-21-217-2017, https://doi.org/10.5194/hess-21-217-2017, 2017
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Our analysis shows that averaging over sub-grid heterogeneity in precipitation and potential evapotranspiration (ET), as typical earth system models do, overestimates the average of the spatially variable ET. We also show when aridity index increases with altitude, lateral redistribution would transfer water from more humid uplands to more arid lowlands, resulting in a net increase in ET. Therefore, the Earth system models that neglect lateral transfer underestimate ET in those regions.
Alexander R. Beer, James W. Kirchner, and Jens M. Turowski
Earth Surf. Dynam., 4, 885–894, https://doi.org/10.5194/esurf-4-885-2016, https://doi.org/10.5194/esurf-4-885-2016, 2016
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Spatial bedrock erosion data from stream channels are important for engineering issues and landscape evolution model assessment. However, acquiring such data is challenging and only few data sets exist. Detecting changes in repeated photographs of painted bedrock surfaces easily allows for semi-quantitative conclusions on the spatial distribution of sediment transport and its effects: abrasion on surfaces facing the streamflow and shielding of surfaces by abundant sediment.
Albrecht von Boetticher, Jens M. Turowski, Brian W. McArdell, Dieter Rickenmann, and James W. Kirchner
Geosci. Model Dev., 9, 2909–2923, https://doi.org/10.5194/gmd-9-2909-2016, https://doi.org/10.5194/gmd-9-2909-2016, 2016
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Debris flows are characterized by unsteady flows of water with different content of clay, silt, sand, gravel, and large particles, resulting in a dense moving mixture mass. Here we present a three-dimensional fluid dynamic solver that simulates the flow as a mixture of a pressure-dependent rheology model of the gravel mixed with a Herschel–Bulkley rheology of the fine material suspension. We link rheological parameters to the material composition. The user must specify two free model parameters.
J. W. Kirchner
Hydrol. Earth Syst. Sci., 20, 279–297, https://doi.org/10.5194/hess-20-279-2016, https://doi.org/10.5194/hess-20-279-2016, 2016
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Catchment mean transit times have been widely inferred from seasonal cycles of environmental tracers in precipitation and streamflow. Here I show that these cycles yield strongly biased estimates of mean transit times in spatially heterogeneous catchments (and, by implication, in real-world catchments). However, I also show that these cycles can be used to reliably estimate the fraction of "young" water in streamflow, meaning water that fell as precipitation less than roughly 2–3 months ago.
J. W. Kirchner
Hydrol. Earth Syst. Sci., 20, 299–328, https://doi.org/10.5194/hess-20-299-2016, https://doi.org/10.5194/hess-20-299-2016, 2016
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Here I show that seasonal tracer cycles yield strongly biased estimates of mean transit times in nonstationary catchments (and, by implication, in real-world catchments). However, they can be used to reliably estimate the fraction of "young" water in streamflow, meaning water that fell as precipitation less than roughly 2–3 months ago. This young water fraction varies systematically between high and low flows and may help in characterizing controls on stream chemistry.
F. Kobierska, T. Jonas, J. W. Kirchner, and S. M. Bernasconi
Hydrol. Earth Syst. Sci., 19, 3681–3693, https://doi.org/10.5194/hess-19-3681-2015, https://doi.org/10.5194/hess-19-3681-2015, 2015
A. von Boetticher, J. M. Turowski, B. W. McArdell, D. Rickenmann, M. Hürlimann, C. Scheidl, and J. W. Kirchner
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmdd-8-6379-2015, https://doi.org/10.5194/gmdd-8-6379-2015, 2015
Preprint withdrawn
F. U. M. Heimann, D. Rickenmann, J. M. Turowski, and J. W. Kirchner
Earth Surf. Dynam., 3, 15–34, https://doi.org/10.5194/esurf-3-15-2015, https://doi.org/10.5194/esurf-3-15-2015, 2015
F. U. M. Heimann, D. Rickenmann, M. Böckli, A. Badoux, J. M. Turowski, and J. W. Kirchner
Earth Surf. Dynam., 3, 35–54, https://doi.org/10.5194/esurf-3-35-2015, https://doi.org/10.5194/esurf-3-35-2015, 2015
Related subject area
Subject: Catchment hydrology | Techniques and Approaches: Theory development
A hydrological framework for persistent pools along non-perennial rivers
Evidence-based requirements for perceptualising intercatchment groundwater flow in hydrological models
Droughts can reduce the nitrogen retention capacity of catchments
Explaining changes in rainfall–runoff relationships during and after Australia's Millennium Drought: a community perspective
Three hypotheses on changing river flood hazards
Hydrologic implications of projected changes in rain-on-snow melt for Great Lakes Basin watersheds
A multivariate-driven approach for disentangling the reduction in near-natural Iberian water resources post-1980
Hydrology and riparian forests drive carbon and nitrogen supply and DOC : NO3− stoichiometry along a headwater Mediterranean stream
Event controls on intermittent streamflow in a temperate climate
Inclusion of flood diversion canal operation in the H08 hydrological model with a case study from the Chao Phraya River basin: model development and validation
Flood generation: process patterns from the raindrop to the ocean
Use of streamflow indices to identify the catchment drivers of hydrographs
Theoretical and empirical evidence against the Budyko catchment trajectory conjecture
Spatial distribution of groundwater recharge, based on regionalised soil moisture models in Wadi Natuf karst aquifers, Palestine
Barriers to mainstream adoption of catchment-wide natural flood management: a transdisciplinary problem-framing study of delivery practice
Low hydrological connectivity after summer drought inhibits DOC export in a forested headwater catchment
Rainbow color map distorts and misleads research in hydrology – guidance for better visualizations and science communication
Attribution of growing season evapotranspiration variability considering snowmelt and vegetation changes in the arid alpine basins
Event and seasonal hydrologic connectivity patterns in an agricultural headwater catchment
Exploring the role of hydrological pathways in modulating multi-annual climate teleconnection periodicities from UK rainfall to streamflow
Technical note: “Bit by bit”: a practical and general approach for evaluating model computational complexity vs. model performance
Hillslope and groundwater contributions to streamflow in a Rocky Mountain watershed underlain by glacial till and fractured sedimentary bedrock
A framework for seasonal variations of hydrological model parameters: impact on model results and response to dynamic catchment characteristics
Hydrology and beyond: the scientific work of August Colding revisited
The influence of a prolonged meteorological drought on catchment water storage capacity: a hydrological-model perspective
Hydrological and runoff formation processes based on isotope tracing during ablation period in the source regions of Yangtze River
Importance of snowmelt contribution to seasonal runoff and summer low flows in Czechia
Recession analysis revisited: impacts of climate on parameter estimation
Understanding the effects of climate warming on streamflow and active groundwater storage in an alpine catchment: the upper Lhasa River
Technical note: An improved discharge sensitivity metric for young water fractions
Hydrological signatures describing the translation of climate seasonality into streamflow seasonality
Spatial and temporal variation in river corridor exchange across a 5th-order mountain stream network
Historic hydrological droughts 1891–2015: systematic characterisation for a diverse set of catchments across the UK
A topographic index explaining hydrological similarity by accounting for the joint controls of runoff formation
Trajectories of nitrate input and output in three nested catchments along a land use gradient
Contrasting rainfall-runoff characteristics of floods in desert and Mediterranean basins
Anthropogenic and catchment characteristic signatures in the water quality of Swiss rivers: a quantitative assessment
Using paired catchments to quantify the human influence on hydrological droughts
HESS Opinions: Socio-economic and ecological trade-offs of flood management – benefits of a transdisciplinary approach
A parsimonious transport model of emerging contaminants at the river network scale
Emergent stationarity in Yellow River sediment transport and the underlying shift of dominance: from streamflow to vegetation
A new probability density function for spatial distribution of soil water storage capacity leads to the SCS curve number method
How does initial soil moisture influence the hydrological response? A case study from southern France
Studying catchment storm response using event- and pre-event-water volumes as fractions of precipitation rather than discharge
Anatomy of simultaneous flood peaks at a lowland confluence
Including effects of watershed heterogeneity in the curve number method using variable initial abstraction
Seasonal shifts in export of DOC and nutrients from burned and unburned peatland-rich catchments, Northwest Territories, Canada
Sensitivity of young water fractions to hydro-climatic forcing and landscape properties across 22 Swiss catchments
Effects of climatic seasonality on the isotopic composition of evaporating soil waters
From engineering hydrology to Earth system science: milestones in the transformation of hydrologic science
Sarah A. Bourke, Margaret Shanafield, Paul Hedley, Sarah Chapman, and Shawan Dogramaci
Hydrol. Earth Syst. Sci., 27, 809–836, https://doi.org/10.5194/hess-27-809-2023, https://doi.org/10.5194/hess-27-809-2023, 2023
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Here we present a hydrological framework for understanding the mechanisms supporting the persistence of water in pools along non-perennial rivers. Pools may collect water after rainfall events, be supported by water stored within the river channel sediments, or receive inflows from regional groundwater. These hydraulic mechanisms can be identified using a range of diagnostic tools (critiqued herein). We then apply this framework in north-west Australia to demonstrate its value.
Louisa D. Oldham, Jim Freer, Gemma Coxon, Nicholas Howden, John P. Bloomfield, and Christopher Jackson
Hydrol. Earth Syst. Sci., 27, 761–781, https://doi.org/10.5194/hess-27-761-2023, https://doi.org/10.5194/hess-27-761-2023, 2023
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Water can move between river catchments via the subsurface, termed intercatchment groundwater flow (IGF). We show how a perceptual model of IGF can be developed with relatively simple geological interpretation and data requirements. We find that IGF dynamics vary in space, correlated to the dominant underlying geology. We recommend that IGF
loss functionsmay be used in conceptual rainfall–runoff models but should be supported by perceptualisation of IGF processes and connectivities.
Carolin Winter, Tam V. Nguyen, Andreas Musolff, Stefanie R. Lutz, Michael Rode, Rohini Kumar, and Jan H. Fleckenstein
Hydrol. Earth Syst. Sci., 27, 303–318, https://doi.org/10.5194/hess-27-303-2023, https://doi.org/10.5194/hess-27-303-2023, 2023
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The increasing frequency of severe and prolonged droughts threatens our freshwater resources. While we understand drought impacts on water quantity, its effects on water quality remain largely unknown. Here, we studied the impact of the unprecedented 2018–2019 drought in Central Europe on nitrate export in a heterogeneous mesoscale catchment in Germany. We show that severe drought can reduce a catchment's capacity to retain nitrogen, intensifying the internal pollution and export of nitrate.
Keirnan Fowler, Murray Peel, Margarita Saft, Tim J. Peterson, Andrew Western, Lawrence Band, Cuan Petheram, Sandra Dharmadi, Kim Seong Tan, Lu Zhang, Patrick Lane, Anthony Kiem, Lucy Marshall, Anne Griebel, Belinda E. Medlyn, Dongryeol Ryu, Giancarlo Bonotto, Conrad Wasko, Anna Ukkola, Clare Stephens, Andrew Frost, Hansini Gardiya Weligamage, Patricia Saco, Hongxing Zheng, Francis Chiew, Edoardo Daly, Glen Walker, R. Willem Vervoort, Justin Hughes, Luca Trotter, Brad Neal, Ian Cartwright, and Rory Nathan
Hydrol. Earth Syst. Sci., 26, 6073–6120, https://doi.org/10.5194/hess-26-6073-2022, https://doi.org/10.5194/hess-26-6073-2022, 2022
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Recently, we have seen multi-year droughts tending to cause shifts in the relationship between rainfall and streamflow. In shifted catchments that have not recovered, an average rainfall year produces less streamflow today than it did pre-drought. We take a multi-disciplinary approach to understand why these shifts occur, focusing on Australia's over-10-year Millennium Drought. We evaluate multiple hypotheses against evidence, with particular focus on the key role of groundwater processes.
Günter Blöschl
Hydrol. Earth Syst. Sci., 26, 5015–5033, https://doi.org/10.5194/hess-26-5015-2022, https://doi.org/10.5194/hess-26-5015-2022, 2022
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There is serious concern that river floods are increasing. Starting from explanations discussed in public, the article addresses three hypotheses: land-use change, hydraulic structures, and climate change increase floods. This review finds that all three changes have the potential to not only increase floods, but also to reduce them. It is crucial to consider all three factors of change in flood risk management and communicate them to the general public in a nuanced way.
Daniel T. Myers, Darren L. Ficklin, and Scott M. Robeson
EGUsphere, https://doi.org/10.5194/egusphere-2022-657, https://doi.org/10.5194/egusphere-2022-657, 2022
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We projected climate change impacts to rain-on-snow melt events in the Great Lakes Basin. Decreases in snowpack limit future rain-on-snow melt. Areas with mean winter/spring air temperatures near freezing are most sensitive to rain-on-snow changes. The projected proportion of total monthly snowmelt from rain-on-snow decreases. Timing for rain-on-snow melt projected to be 2 weeks earlier by mid-21st century and affects spring streamflow. This could affect management of freshwater resources.
Amar Halifa-Marín, Miguel A. Torres-Vázquez, Enrique Pravia-Sarabia, Marc Lemus-Canovas, Pedro Jiménez-Guerrero, and Juan Pedro Montávez
Hydrol. Earth Syst. Sci., 26, 4251–4263, https://doi.org/10.5194/hess-26-4251-2022, https://doi.org/10.5194/hess-26-4251-2022, 2022
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Near-natural Iberian water resources have suddenly decreased since the 1980s. These declines have been promoted by the weakening (enhancement) of wintertime precipitation (the NAOi) in the most humid areas, whereas afforestation and drought intensification have played a crucial role in semi-arid areas. Future water management would benefit from greater knowledge of North Atlantic climate variability and reforestation/afforestation processes in semi-arid catchments.
José L. J. Ledesma, Anna Lupon, Eugènia Martí, and Susana Bernal
Hydrol. Earth Syst. Sci., 26, 4209–4232, https://doi.org/10.5194/hess-26-4209-2022, https://doi.org/10.5194/hess-26-4209-2022, 2022
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We studied a small stream located in a Mediterranean forest. Our goal was to understand how stream flow and the presence of riparian forests, which grow in flat banks near the stream, influence the availability of food for aquatic microorganisms. High flows were associated with higher amounts of food because rainfall episodes transfer it from the surrounding sources, particularly riparian forests, to the stream. Understanding how ecosystems work is essential to better manage natural resources.
Nils Hinrich Kaplan, Theresa Blume, and Markus Weiler
Hydrol. Earth Syst. Sci., 26, 2671–2696, https://doi.org/10.5194/hess-26-2671-2022, https://doi.org/10.5194/hess-26-2671-2022, 2022
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This study is analyses how characteristics of precipitation events and soil moisture and temperature dynamics during these events can be used to model the associated streamflow responses in intermittent streams. The models are used to identify differences between the dominant controls of streamflow intermittency in three distinct geologies of the Attert catchment, Luxembourg. Overall, soil moisture was found to be the most important control of intermittent streamflow in all geologies.
Saritha Padiyedath Gopalan, Adisorn Champathong, Thada Sukhapunnaphan, Shinichiro Nakamura, and Naota Hanasaki
Hydrol. Earth Syst. Sci., 26, 2541–2560, https://doi.org/10.5194/hess-26-2541-2022, https://doi.org/10.5194/hess-26-2541-2022, 2022
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The modelling of diversion canals using hydrological models is important because they play crucial roles in water management. Therefore, we developed a simplified canal diversion scheme and implemented it into the H08 global hydrological model. The developed diversion scheme was validated in the Chao Phraya River basin, Thailand. Region-specific validation results revealed that the H08 model with the diversion scheme could effectively simulate the observed flood diversion pattern in the basin.
Günter Blöschl
Hydrol. Earth Syst. Sci., 26, 2469–2480, https://doi.org/10.5194/hess-26-2469-2022, https://doi.org/10.5194/hess-26-2469-2022, 2022
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Sound understanding of how floods come about allows for the development of more reliable flood management tools that assist in mitigating their negative impacts. This article reviews river flood generation processes and flow paths across space scales, starting from water movement in the soil pores and moving up to hillslopes, catchments, regions and entire continents. To assist model development, there is a need to learn from observed patterns of flood generation processes at all spatial scales.
Jeenu Mathai and Pradeep P. Mujumdar
Hydrol. Earth Syst. Sci., 26, 2019–2033, https://doi.org/10.5194/hess-26-2019-2022, https://doi.org/10.5194/hess-26-2019-2022, 2022
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With availability of large samples of data in catchments, it is necessary to develop indices that describe the streamflow processes. This paper describes new indices applicable for the rising and falling limbs of streamflow hydrographs. The indices provide insights into the drivers of the hydrographs. The novelty of the work is on differentiating hydrographs by their time irreversibility property and offering an alternative way to recognize primary drivers of streamflow hydrographs.
Nathan G. F. Reaver, David A. Kaplan, Harald Klammler, and James W. Jawitz
Hydrol. Earth Syst. Sci., 26, 1507–1525, https://doi.org/10.5194/hess-26-1507-2022, https://doi.org/10.5194/hess-26-1507-2022, 2022
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The Budyko curve emerges globally from the behavior of multiple catchments. Single-parameter Budyko equations extrapolate the curve concept to individual catchments, interpreting curves and parameters as representing climatic and biophysical impacts on water availability, respectively. We tested these two key components theoretically and empirically, finding that catchments are not required to follow Budyko curves and usually do not, implying the parametric framework lacks predictive ability.
Clemens Messerschmid and Amjad Aliewi
Hydrol. Earth Syst. Sci., 26, 1043–1061, https://doi.org/10.5194/hess-26-1043-2022, https://doi.org/10.5194/hess-26-1043-2022, 2022
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Temporal distribution of groundwater recharge has been widely studied; yet, much less attention has been paid to its spatial distribution. Based on a previous study of field-measured and modelled formation-specific recharge in the Mediterranean, this paper differentiates annual recharge coefficients in a novel approach and basin classification framework for physical features such as lithology, soil and LU/LC characteristics, applicable also in other previously ungauged basins around the world.
Thea Wingfield, Neil Macdonald, Kimberley Peters, and Jack Spees
Hydrol. Earth Syst. Sci., 25, 6239–6259, https://doi.org/10.5194/hess-25-6239-2021, https://doi.org/10.5194/hess-25-6239-2021, 2021
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Human activities are causing greater and more frequent floods. Natural flood management (NFM) uses processes of the water cycle to slow the flow of rainwater, bringing together land and water management. Despite NFM's environmental and social benefits, it is yet to be widely adopted. Two environmental practitioner groups collaborated to produce a picture of the barriers to delivery, showing that there is a perceived lack of support from government and the public for NFM.
Katharina Blaurock, Burkhard Beudert, Benjamin S. Gilfedder, Jan H. Fleckenstein, Stefan Peiffer, and Luisa Hopp
Hydrol. Earth Syst. Sci., 25, 5133–5151, https://doi.org/10.5194/hess-25-5133-2021, https://doi.org/10.5194/hess-25-5133-2021, 2021
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Dissolved organic carbon (DOC) is an important part of the global carbon cycle with regards to carbon storage, greenhouse gas emissions and drinking water treatment. In this study, we compared DOC export of a small, forested catchment during precipitation events after dry and wet preconditions. We found that the DOC export from areas that are usually important for DOC export was inhibited after long drought periods.
Michael Stoelzle and Lina Stein
Hydrol. Earth Syst. Sci., 25, 4549–4565, https://doi.org/10.5194/hess-25-4549-2021, https://doi.org/10.5194/hess-25-4549-2021, 2021
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We found with a scientific paper survey (~ 1000 papers) that 45 % of the papers used rainbow color maps or red–green visualizations. Those rainbow visualizations, although attracting the media's attention, will not be accessible for up to 10 % of people due to color vision deficiency. The rainbow color map distorts and misleads scientific communication. The study gives guidance on how to avoid, improve and trust color and how the flaws of the rainbow color map should be communicated in science.
Tingting Ning, Zhi Li, Qi Feng, Zongxing Li, and Yanyan Qin
Hydrol. Earth Syst. Sci., 25, 3455–3469, https://doi.org/10.5194/hess-25-3455-2021, https://doi.org/10.5194/hess-25-3455-2021, 2021
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Previous studies decomposed ET variance in precipitation, potential ET, and total water storage changes based on Budyko equations. However, the effects of snowmelt and vegetation changes have not been incorporated in snow-dependent basins. We thus extended this method in arid alpine basins of northwest China and found that ET variance is primarily controlled by rainfall, followed by coupled rainfall and vegetation. The out-of-phase seasonality between rainfall and snowmelt weaken ET variance.
Lovrenc Pavlin, Borbála Széles, Peter Strauss, Alfred Paul Blaschke, and Günter Blöschl
Hydrol. Earth Syst. Sci., 25, 2327–2352, https://doi.org/10.5194/hess-25-2327-2021, https://doi.org/10.5194/hess-25-2327-2021, 2021
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We compared the dynamics of streamflow, groundwater and soil moisture to investigate how different parts of an agricultural catchment in Lower Austria are connected. Groundwater is best connected around the stream and worse uphill, where groundwater is deeper. Soil moisture connectivity increases with increasing catchment wetness but is not influenced by spatial position in the catchment. Groundwater is more connected to the stream on the seasonal scale compared to the event scale.
William Rust, Mark Cuthbert, John Bloomfield, Ron Corstanje, Nicholas Howden, and Ian Holman
Hydrol. Earth Syst. Sci., 25, 2223–2237, https://doi.org/10.5194/hess-25-2223-2021, https://doi.org/10.5194/hess-25-2223-2021, 2021
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In this paper, we find evidence for the cyclical behaviour (on a 7-year basis) in UK streamflow records that match the main cycle of the North Atlantic Oscillation. Furthermore, we find that the strength of these 7-year cycles in streamflow is dependent on proportional contributions from groundwater and the response times of the underlying groundwater systems. This may allow for improvements to water management practices through better understanding of long-term streamflow behaviour.
Elnaz Azmi, Uwe Ehret, Steven V. Weijs, Benjamin L. Ruddell, and Rui A. P. Perdigão
Hydrol. Earth Syst. Sci., 25, 1103–1115, https://doi.org/10.5194/hess-25-1103-2021, https://doi.org/10.5194/hess-25-1103-2021, 2021
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Computer models should be as simple as possible but not simpler. Simplicity refers to the length of the model and the effort it takes the model to generate its output. Here we present a practical technique for measuring the latter by the number of memory visits during model execution by
Strace, a troubleshooting and monitoring program. The advantage of this approach is that it can be applied to any computer-based model, which facilitates model intercomparison.
Sheena A. Spencer, Axel E. Anderson, Uldis Silins, and Adrian L. Collins
Hydrol. Earth Syst. Sci., 25, 237–255, https://doi.org/10.5194/hess-25-237-2021, https://doi.org/10.5194/hess-25-237-2021, 2021
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We used unique chemical signatures of precipitation, hillslope soil water, and groundwater sources of streamflow to explore seasonal variation in runoff generation in a snow-dominated mountain watershed underlain by glacial till and permeable bedrock. Reacted hillslope water reached the stream first at the onset of snowmelt, followed by a dilution effect by snowmelt from May to June. Groundwater and riparian water were important sources later in the summer. Till created complex subsurface flow.
Tian Lan, Kairong Lin, Chong-Yu Xu, Zhiyong Liu, and Huayang Cai
Hydrol. Earth Syst. Sci., 24, 5859–5874, https://doi.org/10.5194/hess-24-5859-2020, https://doi.org/10.5194/hess-24-5859-2020, 2020
Dan Rosbjerg
Hydrol. Earth Syst. Sci., 24, 4575–4585, https://doi.org/10.5194/hess-24-4575-2020, https://doi.org/10.5194/hess-24-4575-2020, 2020
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August Colding contributed the first law of thermodynamics, evaporation from water and grass, steady free surfaces in conduits, the cross-sectional velocity distribution in conduits, a complete theory for the Gulf Stream, air speed in cyclones, the piezometric surface in confined aquifers, the unconfined elliptic water table in soil between drain pipes, and the wind-induced set-up in the sea during storms.
Zhengke Pan, Pan Liu, Chong-Yu Xu, Lei Cheng, Jing Tian, Shujie Cheng, and Kang Xie
Hydrol. Earth Syst. Sci., 24, 4369–4387, https://doi.org/10.5194/hess-24-4369-2020, https://doi.org/10.5194/hess-24-4369-2020, 2020
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This study aims to identify the response of catchment water storage capacity (CWSC) to meteorological drought by examining the changes of hydrological-model parameters after drought events. This study improves our understanding of possible changes in the CWSC induced by a prolonged meteorological drought, which will help improve our ability to simulate the hydrological system under climate change.
Zong-Jie Li, Zong-Xing Li, Ling-Ling Song, Juan Gui, Jian Xue, Bai Juan Zhang, and Wen De Gao
Hydrol. Earth Syst. Sci., 24, 4169–4187, https://doi.org/10.5194/hess-24-4169-2020, https://doi.org/10.5194/hess-24-4169-2020, 2020
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This study mainly explores the hydraulic relations, recharge–drainage relations and their transformation paths, and the processes of each water body. It determines the composition of runoff, quantifies the contribution of each runoff component to different types of tributaries, and analyzes the hydrological effects of the temporal and spatial variation in runoff components. More importantly, we discuss the hydrological significance of permafrost and hydrological processes.
Michal Jenicek and Ondrej Ledvinka
Hydrol. Earth Syst. Sci., 24, 3475–3491, https://doi.org/10.5194/hess-24-3475-2020, https://doi.org/10.5194/hess-24-3475-2020, 2020
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Changes in snow affect the runoff seasonality, including summer low flows. Here we analyse this effect in 59 mountain catchments in Czechia. We show that snow is more effective in generating runoff compared to rain. Snow-poor years generated lower groundwater recharge than snow-rich years, which resulted in higher deficit volumes in summer. The lower recharge and runoff in the case of a snowfall-to-rain transition due to air temperature increase might be critical for water supply in the future.
Elizabeth R. Jachens, David E. Rupp, Clément Roques, and John S. Selker
Hydrol. Earth Syst. Sci., 24, 1159–1170, https://doi.org/10.5194/hess-24-1159-2020, https://doi.org/10.5194/hess-24-1159-2020, 2020
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Recession analysis uses the receding streamflow following precipitation events to estimate watershed-average properties. Two methods for recession analysis use recession events individually or all events collectively. Using synthetic case studies, this paper shows that analyzing recessions collectively produces flawed interpretations. Moving forward, recession analysis using individual recessions should be used to describe the average and variability of watershed behavior.
Lu Lin, Man Gao, Jintao Liu, Jiarong Wang, Shuhong Wang, Xi Chen, and Hu Liu
Hydrol. Earth Syst. Sci., 24, 1145–1157, https://doi.org/10.5194/hess-24-1145-2020, https://doi.org/10.5194/hess-24-1145-2020, 2020
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In this paper, recession flow analysis – assuming nonlinearized outflow from aquifers into streams – was used to quantify active groundwater storage in a headwater catchment with high glacierization and large-scale frozen ground on the Tibetan Plateau. Hence, this work provides a perspective to clarify the impact of glacial retreat and frozen ground degradation due to climate change on hydrological processes.
Francesc Gallart, Jana von Freyberg, María Valiente, James W. Kirchner, Pilar Llorens, and Jérôme Latron
Hydrol. Earth Syst. Sci., 24, 1101–1107, https://doi.org/10.5194/hess-24-1101-2020, https://doi.org/10.5194/hess-24-1101-2020, 2020
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How catchments store and release rain or melting water is still not well known. Now, it is broadly accepted that most of the water in streams is older than several months, and a relevant part may be many years old. But the age of water depends on the stream regime, being usually younger during high flows. This paper tries to provide tools for better analysing how the age of waters varies with flow in a catchment and for comparing the behaviour of catchments diverging in climate, size and regime.
Sebastian J. Gnann, Nicholas J. K. Howden, and Ross A. Woods
Hydrol. Earth Syst. Sci., 24, 561–580, https://doi.org/10.5194/hess-24-561-2020, https://doi.org/10.5194/hess-24-561-2020, 2020
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In many places, seasonal variability in precipitation and evapotranspiration (climate) leads to seasonal variability in river flow (streamflow). In this work, we explore how climate seasonality is transformed into streamflow seasonality and what controls this transformation (e.g. climate aridity and geology). The results might be used in grouping catchments, predicting the seasonal streamflow regime in ungauged catchments, and building hydrological simulation models.
Adam S. Ward, Steven M. Wondzell, Noah M. Schmadel, Skuyler Herzog, Jay P. Zarnetske, Viktor Baranov, Phillip J. Blaen, Nicolai Brekenfeld, Rosalie Chu, Romain Derelle, Jennifer Drummond, Jan H. Fleckenstein, Vanessa Garayburu-Caruso, Emily Graham, David Hannah, Ciaran J. Harman, Jase Hixson, Julia L. A. Knapp, Stefan Krause, Marie J. Kurz, Jörg Lewandowski, Angang Li, Eugènia Martí, Melinda Miller, Alexander M. Milner, Kerry Neil, Luisa Orsini, Aaron I. Packman, Stephen Plont, Lupita Renteria, Kevin Roche, Todd Royer, Catalina Segura, James Stegen, Jason Toyoda, Jacqueline Wells, and Nathan I. Wisnoski
Hydrol. Earth Syst. Sci., 23, 5199–5225, https://doi.org/10.5194/hess-23-5199-2019, https://doi.org/10.5194/hess-23-5199-2019, 2019
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The movement of water and solutes between streams and their shallow, connected subsurface is important to many ecosystem functions. These exchanges are widely expected to vary with stream flow across space and time, but these assumptions are seldom tested across basin scales. We completed more than 60 experiments across a 5th-order river basin to document these changes, finding patterns in space but not time. We conclude space-for-time and time-for-space substitutions are not good assumptions.
Lucy J. Barker, Jamie Hannaford, Simon Parry, Katie A. Smith, Maliko Tanguy, and Christel Prudhomme
Hydrol. Earth Syst. Sci., 23, 4583–4602, https://doi.org/10.5194/hess-23-4583-2019, https://doi.org/10.5194/hess-23-4583-2019, 2019
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It is important to understand historic droughts in order to plan and prepare for possible future events. In this study we use the standardised streamflow index for 1891–2015 to systematically identify, characterise and rank hydrological drought events for 108 near-natural UK catchments. Results show when and where the most severe events occurred and describe events of the early 20th century, providing catchment-scale detail important for both science and planning applications of the future.
Ralf Loritz, Axel Kleidon, Conrad Jackisch, Martijn Westhoff, Uwe Ehret, Hoshin Gupta, and Erwin Zehe
Hydrol. Earth Syst. Sci., 23, 3807–3821, https://doi.org/10.5194/hess-23-3807-2019, https://doi.org/10.5194/hess-23-3807-2019, 2019
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In this study, we develop a topographic index explaining hydrological similarity within a energy-centered framework, with the observation that the majority of potential energy is dissipated when rainfall becomes runoff.
Sophie Ehrhardt, Rohini Kumar, Jan H. Fleckenstein, Sabine Attinger, and Andreas Musolff
Hydrol. Earth Syst. Sci., 23, 3503–3524, https://doi.org/10.5194/hess-23-3503-2019, https://doi.org/10.5194/hess-23-3503-2019, 2019
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This study shows quantitative and temporal offsets between nitrogen input and riverine output, using time series of three nested catchments in central Germany. The riverine concentrations show lagged reactions to the input, but at the same time exhibit strong inter-annual changes in the relationship between riverine discharge and concentration. The study found a strong retention of nitrogen that is dominantly assigned to a hydrological N legacy, which will affect future stream concentrations.
Davide Zoccatelli, Francesco Marra, Moshe Armon, Yair Rinat, James A. Smith, and Efrat Morin
Hydrol. Earth Syst. Sci., 23, 2665–2678, https://doi.org/10.5194/hess-23-2665-2019, https://doi.org/10.5194/hess-23-2665-2019, 2019
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This study presents a comparison of flood properties over multiple Mediterranean and desert catchments. While in Mediterranean areas floods are related to rainfall amount, in deserts we observed a strong connection with the characteristics of the more intense part of storms. Because of the different mechanisms involved, despite having significantly shorter and more localized storms, deserts are able to produce floods with a magnitude comparable to Mediterranean areas.
Martina Botter, Paolo Burlando, and Simone Fatichi
Hydrol. Earth Syst. Sci., 23, 1885–1904, https://doi.org/10.5194/hess-23-1885-2019, https://doi.org/10.5194/hess-23-1885-2019, 2019
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The study focuses on the solute export from rivers with the purpose of discerning the impacts of anthropic activities and catchment characteristics on water quality. The results revealed a more detectable impact of the anthropic activities than of the catchment characteristics. The solute export follows different dynamics depending on catchment characteristics and mainly on solute-specific properties. The export modality is consistent across different catchments only for a minority of solutes.
Anne F. Van Loon, Sally Rangecroft, Gemma Coxon, José Agustín Breña Naranjo, Floris Van Ogtrop, and Henny A. J. Van Lanen
Hydrol. Earth Syst. Sci., 23, 1725–1739, https://doi.org/10.5194/hess-23-1725-2019, https://doi.org/10.5194/hess-23-1725-2019, 2019
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We explore the use of the classic
paired-catchmentapproach to quantify human influence on hydrological droughts. In this approach two similar catchments are compared and differences are attributed to the human activity present in one. In two case studies in UK and Australia, we found that groundwater abstraction aggravated streamflow drought by > 200 % and water transfer alleviated droughts with 25–80 %. Understanding the human influence on droughts can support water management decisions.
Karl Auerswald, Peter Moyle, Simon Paul Seibert, and Juergen Geist
Hydrol. Earth Syst. Sci., 23, 1035–1044, https://doi.org/10.5194/hess-23-1035-2019, https://doi.org/10.5194/hess-23-1035-2019, 2019
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The demand for flood protection often results in the construction of more and bigger levees along rivers. We highlight that such technical solutions often result in undesired socio-economic and ecological consequences such as increased downstream flooding risk, changes of groundwater levels, and a loss of aquatic and terrestrial biodiversity. We propose a transdisciplinary approach of integrated flood management and green infrastructure instead of reliance on technical protection measures.
Elena Diamantini, Stefano Mallucci, and Alberto Bellin
Hydrol. Earth Syst. Sci., 23, 573–593, https://doi.org/10.5194/hess-23-573-2019, https://doi.org/10.5194/hess-23-573-2019, 2019
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The description of pharmaceutical fate and transport introduced into a watershed is a challenging topic, especially because of the possible adverse effects on human health. In addition, an accurate estimation of solute sources and routes is still missing. This study uses a new promising modeling approach to predict pharmaceutical concentrations in rivers. Results show an interesting relationship between solute concentrations in waters and touristic fluxes.
Sheng Ye, Qihua Ran, Xudong Fu, Chunhong Hu, Guangqian Wang, Gary Parker, Xiuxiu Chen, and Siwei Zhang
Hydrol. Earth Syst. Sci., 23, 549–556, https://doi.org/10.5194/hess-23-549-2019, https://doi.org/10.5194/hess-23-549-2019, 2019
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Our study shows that there is declining coupling between sediment concentration and discharge from daily to annual scales for gauges across the Yellow River basin (YRB). Not only the coupling, but also the magnitude of sediment response to discharge variation decreases with long-term mean discharge. This emergent stationarity can be related to sediment retardation by vegetation, suggesting the shift of dominance from water to vegetation as mean annual discharge increases.
Dingbao Wang
Hydrol. Earth Syst. Sci., 22, 6567–6578, https://doi.org/10.5194/hess-22-6567-2018, https://doi.org/10.5194/hess-22-6567-2018, 2018
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A novel distribution function is proposed for describing the spatial distribution of soil water storage capacity, and then the classical and empirical hydrologic model (the SCS curve number method) is derived as when the initial soil water storage is zero. This distribution function unifies the SCS curve number method and probability-distributed models such as the VIC and Xinanjiang models. The unified model provides a better way for modeling surface runoff.
Magdalena Uber, Jean-Pierre Vandervaere, Isabella Zin, Isabelle Braud, Maik Heistermann, Cédric Legoût, Gilles Molinié, and Guillaume Nord
Hydrol. Earth Syst. Sci., 22, 6127–6146, https://doi.org/10.5194/hess-22-6127-2018, https://doi.org/10.5194/hess-22-6127-2018, 2018
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We investigate how rivers in a flash-flood-prone region in southern France respond to rainfall depending on initial soil moisture. Therefore, high-resolution data of rainfall, river discharge and soil moisture were used. We find that during dry initial conditions, the rivers hardly respond even for heavy rain events, but for wet initial conditions, the response remains unpredictable: for some rain events almost all rainfall is transformed to discharge, whereas this is not the case for others.
Jana von Freyberg, Bjørn Studer, Michael Rinderer, and James W. Kirchner
Hydrol. Earth Syst. Sci., 22, 5847–5865, https://doi.org/10.5194/hess-22-5847-2018, https://doi.org/10.5194/hess-22-5847-2018, 2018
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We show event- and pre-event-water volumes as fractions of precipitation, rather than discharge, to provide an alternative and more insightful approach to study catchment hydrological processes. For this, we analyze 24 storm events using high-frequency measurements of stable water isotopes in stream water and precipitation at a pre-Alpine catchment. Antecedent wetness and storm characteristics are dominant controls on event-water discharge and pre-event-water mobilization from storage.
Tjitske J. Geertsema, Adriaan J. Teuling, Remko Uijlenhoet, Paul J. J. F. Torfs, and Antonius J. F. Hoitink
Hydrol. Earth Syst. Sci., 22, 5599–5613, https://doi.org/10.5194/hess-22-5599-2018, https://doi.org/10.5194/hess-22-5599-2018, 2018
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This study investigate the processes and effects of simultaneous flood peaks at a lowland confluence. The flood peaks are analyzed with the relatively new dynamic time warping method, which offers a robust means of tracing flood waves in discharge time series at confluences. The time lag between discharge peaks in the main river and its lowland tributaries is small compared to the wave duration; therefore the exact timing of discharge peaks may be little relevant to flood risk.
Vijay P. Santikari and Lawrence C. Murdoch
Hydrol. Earth Syst. Sci., 22, 4725–4743, https://doi.org/10.5194/hess-22-4725-2018, https://doi.org/10.5194/hess-22-4725-2018, 2018
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The curve number (CN) method is the most widely used approach for estimating runoff from rainfall. Despite its popularity, there is a conceptual flaw where CN varies with rainfall although it is assumed to be constant. In this paper, we describe theoretical analyses that show how this behavior is due to watershed heterogeneity, and we then provide simple modifications to the method to improve its runoff predictions. The findings will benefit hydrologists and watershed models that use CN method.
Katheryn Burd, Suzanne E. Tank, Nicole Dion, William L. Quinton, Christopher Spence, Andrew J. Tanentzap, and David Olefeldt
Hydrol. Earth Syst. Sci., 22, 4455–4472, https://doi.org/10.5194/hess-22-4455-2018, https://doi.org/10.5194/hess-22-4455-2018, 2018
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In this study we investigated whether climate change and wildfires are likely to alter water quality of streams in western boreal Canada, a region that contains large permafrost-affected peatlands. We monitored stream discharge and water quality from early snowmelt to fall in two streams, one of which drained a recently burned landscape. Wildfire increased the stream delivery of phosphorous and possibly increased the release of old natural organic matter previously stored in permafrost soils.
Jana von Freyberg, Scott T. Allen, Stefan Seeger, Markus Weiler, and James W. Kirchner
Hydrol. Earth Syst. Sci., 22, 3841–3861, https://doi.org/10.5194/hess-22-3841-2018, https://doi.org/10.5194/hess-22-3841-2018, 2018
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We explored how the fraction of streamflow younger than ca. 3 months (Fyw) varies with landscape characteristics and climatic forcing, using an extensive isotope data set from 22 Swiss catchments. Overall, Fyw tends to be larger when catchments are wet and discharge is correspondingly higher, indicating an increase in the proportional contribution of faster flow paths at higher flows. We quantify this
discharge sensitivityof Fyw and relate it to the dominant streamflow-generating mechanisms.
Paolo Benettin, Till H. M. Volkmann, Jana von Freyberg, Jay Frentress, Daniele Penna, Todd E. Dawson, and James W. Kirchner
Hydrol. Earth Syst. Sci., 22, 2881–2890, https://doi.org/10.5194/hess-22-2881-2018, https://doi.org/10.5194/hess-22-2881-2018, 2018
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Evaporation causes the isotopic composition of soil water to become different from that of the original precipitation source. If multiple samples originating from the same source are available, they can be used to reconstruct the original source composition. However, soil water is influenced by seasonal variability in both precipitation sources and evaporation patterns. We show that this variability, if not accounted for, can lead to biased estimates of the precipitation source water.
Murugesu Sivapalan
Hydrol. Earth Syst. Sci., 22, 1665–1693, https://doi.org/10.5194/hess-22-1665-2018, https://doi.org/10.5194/hess-22-1665-2018, 2018
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The paper presents major milestones in the transformation of hydrologic science over the last 50 years from engineering hydrology to Earth system science. This transformation has involved a transition from a focus on time (empirical) to space (Newtonian mechanics), and to time (Darwinian co-evolution). Hydrology is now well positioned to again return to a focus on space or space–time and a move towards regional process hydrology.
Cited articles
Basu, N. B., Destouni, G., Jawitz, J. W., Thompson, S. E., Loukinova, N.
V., Darracq, A., Zanardo, S., Yaeger, M., Sivapalan, M., and Rinaldo, A.:
Nutrient loads exported from managed catchments reveal emergent
biogeochemical stationarity, Geophys. Res. Lett., 37, L23404,
https://doi.org/10.1029/2010GL045168, 2010.
Basu, N. B., Thompson, S. E., and Rao, P. S. C.: Hydrologic and
biogeochemical functioning of intensively managed catchments: A synthesis of
top-down analyses, Water Resour. Res., 47, W00J15, https://doi.org/10.1029/2011WR010800, 2011.
Benettin, P. and Van Breukelen, B. M.: Decomposing the bulk electrical
conductivity of streamflow to recover individual solute concentrations at
high frequency, Environ. Sci. Tech. Lett., 4, 518–522,
https://doi.org/10.1021/acs.estlett.7b00472, 2017.
Bieroza, M. Z. and Heathwaite, A. L.: Seasonal variation in phosphorus
concentration–discharge hysteresis inferred from high-frequency in situ
monitoring, J. Hydrol., 524, 333–347, https://doi.org/10.1016/j.jhydrol.2015.02.036, 2015.
Bieroza, M. Z., Heathwaite, A. L., Bechmann, M., Kyllmar, K., and Jordan,
P.: The concentration-discharge slope as a tool for water quality
management, Sci. Total Environ., 630, 738–749, https://doi.org/10.1016/j.scitotenv.2018.02.256, 2018.
Biron, P. M., Roy, A. G., Courschesne, F., Hendershot, W. H., Côté,
B., and Fyles, J.: The effects of antecedent moisture conditions on the
relationship of hydrology to hydrochemistry in a small forested watershed,
Hydrol. Process., 13, 1541–1555, https://doi.org/10.1002/(SICI)1099-1085(19990815)13:11<1541::AID-HYP832>3.0.CO;2-J, 1999.
Bloomfield, C.: A study of podzolization: Part I. The mobilization of iron
and aluminium by Scots pine needles, J. Soil Sci., 4, 5–16,
https://doi.org/10.1111/j.1365-2389.1953.tb00576.x, 1953.
Carey, R. O., Wollheim, W. M., Mulukutla, G. K., and Mineau, M. M.:
Characterizing storm-event nitrate fluxes in a fifth order suburbanizing
watershed using in situ sensors, Environ. Sci. Technol., 48, 7756–7765,
https://doi.org/10.1021/es500252j, 2014.
Cartwright, I., Morgenstern, U., and Hofmann, H.: Concentration versus
streamflow trends of major ions and tritium in headwater streams as
indicators of changing water stores, Hydrol. Process., 34, 485–505,
https://doi.org/10.1002/hyp.13600, 2020.
Clow, D. and Drever, J.: Weathering rates as a function of flow through an
alpine soil, Chem. Geol., 132, 131–141, https://doi.org/10.1016/S0009-2541(96)00048-4, 1996.
Clow, D. W. and Mast, M. A.: Mechanisms for chemostatic behavior in
catchments: implications for CO2 consumption by mineral weathering, Chem.
Geol., 269, 40–51, https://doi.org/10.1016/j.chemgeo.2009.09.014, 2010.
Drever, J. I.: The geochemistry of natural waters, Prentice Hall, Englewood
Cliffs, NJ, USA, 1988.
Dupas, R., Jomaa, S., Musolff, A., Borchardt, D., and Rode, M.: Disentangling the influence of hydroclimatic patterns and agricultural management on river nitrate dynamics from sub-hourly to decadal time scales, Sci. Total Environ., 571, 791–800, https://doi.org/10.1016/j.scitotenv.2016.07.053, 2016.
Evans, C. and Davies, T. D.: Causes of concentration/discharge hysteresis
and its potential as a tool for analysis of episode hydrochemistry, Water
Resour. Res., 34, 129–137, https://doi.org/10.1029/97WR01881, 1998.
Fischer, B. M., Rinderer, M., Schneider, P., Ewen, T., and Seibert, J.:
Contributing sources to baseflow in pre-alpine headwaters using spatial
snapshot sampling, Hydrol. Process., 29, 5321–5336,
https://doi.org/10.1002/hyp.10529, 2015.
Godsey, S. E. and Kirchner, J. W.: Dynamic, discontinuous stream networks:
hydrologically driven variations in active drainage density, flowing
channels and stream order, Hydrol. Process., 28, 5791–5803,
https://doi.org/10.1002/hyp.10310, 2014.
Godsey, S. E., Kirchner, J. W., and Clow, D. W.: Concentration–discharge
relationships reflect chemostatic characteristics of US catchments,
Hydrol. Process., 23, 1844–1864, https://doi.org/10.1002/hyp.7315, 2009.
Godsey, S. E., Hartmann, J., and Kirchner, J. W.: Catchment chemostasis
revisited: Water quality responds differently to variations in weather and
climate, Hydrol. Process., 33, 3056–3069,
https://doi.org/10.1002/hyp.13554, 2019.
Gotoh, S. and Patrick, W.: Transformation of Manganese in a Waterlogged
Soil as Affected by Redox Potential and pH 1, Soil Sci. Soc. Am. J., 36, 738–742, 1972.
Gotoh, S. and Patrick, W.: Transformation of iron in a waterlogged soil as
influenced by redox potential and pH, Soil Sci. Soc. Am. J., 38, 66–71, 1974.
Gottselig, N., Amelung, W., Kirchner, J. W., Bol, R., Eugster, W., Granger,
S. J., Hernández-Crespo, C., Herrmann, F., Keizer, J. J., and
Korkiakoski, M.: Elemental composition of natural nanoparticles and fine
colloids in European forest stream waters and their role as phosphorus
carriers, Global Biogeochem. Cy., 31, 1592–1607,
https://doi.org/10.1002/2017GB005657, 2017.
Grimaldi, C., Grimaldi, M., Millet, A., Bariac, T., and Boulègue, J.:
Behaviour of chemical solutes during a storm in a rainforested headwater
catchment, Hydrol. Process., 18, 93–106, https://doi.org/10.1002/hyp.1314, 2004.
Grybos, M., Davranche, M., Gruau, G., and Petitjean, P.: Is trace metal
release in wetland soils controlled by organic matter mobility or
Fe-oxyhydroxides reduction?, J. Colloid Interf. Sci., 314, 490–501, https://doi.org/10.1016/j.jcis.2007.04.062, 2007.
Gwenzi, W., Chinyama, S. R., and Togarepi, S.: Concentration-discharge
patterns in a small urban headwater stream in a seasonally dry water-limited
tropical environment, J. Hydrol., 550, 12–25, https://doi.org/10.1016/j.jhydrol.2017.04.029, 2017.
Hagedorn, F., Schleppi, P., Waldner, P., and Flühler, H.: Export of
dissolved organic carbon and nitrogen from Gleysol dominated catchments–the
significance of water flow paths, Biogeochemistry, 50, 137–161, https://doi.org/10.1023/A:1006398105953, 2000.
Hall, F. R.: Dissolved Solids-Discharge Relationships: 1. Mixing Models,
Water Resour. Res., 6, 845–850, https://doi.org/10.1029/WR006i003p00845, 1970.
Harter, R. D. and Naidu, R.: Role of metal-organic complexation in metal
sorption by soils, in: Advances in agronomy, Elsevier, 219–263, 1995.
Hegg, C., McArdell, B. W., and Badoux, A.: One hundred years of mountain
hydrology in Switzerland by the WSL, Hydrol. Process., 20, 371–376, https://doi.org/10.1002/hyp.6055, 2006.
Helling, C. S., Chesters, G., and Corey, R.: Contribution of organic matter
and clay to soil cation-exchange capacity as affected by the pH of the
saturating solution 1, Soil Sci. Soc. Am. J., 28, 517–520,
https://doi.org/10.2136/sssaj1964.03615995002800040020x, 1964.
Herndon, E. M., Dere, A. L., Sullivan, P. L., Norris, D., Reynolds, B., and Brantley, S. L.: Landscape heterogeneity drives contrasting concentration–discharge relationships in shale headwater catchments, Hydrol. Earth Syst. Sci., 19, 3333–3347, https://doi.org/10.5194/hess-19-3333-2015, 2015.
Hornung, M., Stevens, P., and Reynolds, B.: The impact of pasture
improvement on the soil solution chemistry of some stagnopodzols in
mid-Wales, Soil Use Manage., 2, 18–26, https://doi.org/10.1111/j.1475-2743.1986.tb00673.x, 1986.
Inamdar, S., O'leary, N., Mitchell, M., and Riley, J.: The impact of storm
events on solute exports from a glaciated forested watershed in western New
York, USA, Hydrol. Process., 20, 3423–3439, https://doi.org/10.1002/hyp.6141, 2006.
Kiewiet, L., von Freyberg, J., and van Meerveld, H.: Spatiotemporal
variability in hydrochemistry of shallow groundwater in a small pre-alpine
catchment: The importance of landscape elements, Hydrol. Process., 33,
2502–2522, https://doi.org/10.1002/hyp.13517, 2019.
Koenig, L., Shattuck, M., Snyder, L., Potter, J., and McDowell, W.:
Deconstructing the effects of flow on DOC, nitrate, and major ion interactions using a high-frequency aquatic sensor network, Water Resour.
Res., 53, 10655–10673, https://doi.org/10.1002/2017WR020739,
2017.
Koger, J. M., Newman, B. D., and Goering, T. J.: Chemostatic behaviour of
major ions and contaminants in a semiarid spring and stream system near Los
Alamos, NM, USA, Hydrol. Process., 32, 1709–1716, https://doi.org/10.1002/hyp.11624, 2018.
Likens, G. E., Driscoll, C. T., Buso, D. C., Siccama, T. G., Johnson, C. E.,
Lovett, G. M., Ryan, D. F., Fahey, T., and Reiners, W. A.: The biogeochemistry of potassium at Hubbard Brook, Biogeochemistry, 25, 61–125,
https://doi.org/10.1007/BF00000881, 1994.
Lloyd, C., Freer, J., Johnes, P., Coxon, G., and Collins, A.: Discharge and
nutrient uncertainty: implications for nutrient flux estimation in small
streams, Hydrol. Process., 30, 135–152, https://doi.org/10.1002/hyp.10574, 2016.
Musolff, A., Schmidt, C., Selle, B., and Fleckenstein, J. H.: Catchment
controls on solute export, Adv. Water Resour., 86, 133–146,
https://doi.org/10.1016/j.advwatres.2015.09.026, 2015.
Nierop, K. G., Jansen, B., and Verstraten, J. M.: Dissolved organic matter,
aluminium and iron interactions: precipitation induced by metal/carbon
ratio, pH and competition, Sci. Total Environ., 300, 201–211, https://doi.org/10.1016/S0048-9697(02)00254-1, 2002.
Rhoades, J.: Cation Exchange Capacity, Methods of soil analysis. Part 2.
Chemical and microbiological properties, American Society of Agronomy, Inc. and Soil Science Society of America, Inc., Madison Wisconsin, USA, 149–157, 1982.
Rinderer, M., Van Meerveld, H., and Seibert, J.: Topographic controls on
shallow groundwater levels in a steep, prealpine catchment: When are the TWI
assumptions valid?, Water Resour. Res., 50, 6067–6080, https://doi.org/10.1002/2013WR015009, 2014.
Rode, M., Wade, A. J., Cohen, M. J., Hensley, R. T., Bowes, M. J., Kirchner,
J. W., Arhonditsis, G. B., Jordan, P., Kronvang, B., Halliday, S. J., Skeffington, R. A., Rozemeijer, J. C., Aubert, A. H., Rinke, K., and Jomaa, S.: Sensors in the stream: the high-frequency wave
25 of the present, Environ. Sci. Technol., 50, 10297–10307, https://doi.org/10.1021/acs.est.6b02155, 2016.
Rose, L. A., Karwan, D. L., and Godsey, S. E.: Concentration–discharge
relationships describe solute and sediment mobilization, reaction, and
transport at event and longer timescales, Hydrol. Process., 32, 2829–2844,
https://doi.org/10.1002/hyp.13235, 2018.
Rusjan, S., Brilly, M., and Mikoš, M.: Flushing of nitrate from a
forested watershed: an insight into hydrological nitrate mobilization
mechanisms through seasonal high-frequency stream nitrate dynamics, J.
Hydrol., 354, 187–202, https://doi.org/10.1016/j.jhydrol.2008.03.009, 2008.
Schleppi, P., Muller, N., Feyen, H., Papritz, A., Bucher, J. B., and
Flühler, H.: Nitrogen budgets of two small experimental forested
catchments at Alptal, Switzerland, Forest Ecol. Manag., 101, 177–185,
https://doi.org/10.1016/S0378-1127(97)00134-5, 1998.
Schwientek, M., Osenbrück, K., and Fleischer, M.: Investigating
hydrological drivers of nitrate export dynamics in two agricultural
catchments in Germany using high-frequency data series, Environ. Earth
Sci., 69, 381–393, https://doi.org/10.1007/s12665-013-2322-2, 2013.
Stähli, M. and Gustafsson, D.: Long-term investigations of the snow
cover in a subalpine semi-forested catchment, Hydrol. Process., 20, 411–428, https://doi.org/10.1002/hyp.6058, 2006.
van Meerveld, H., Fischer, B., Rinderer, M., Stähli, M., and Seibert,
J.: Runoff generation in a pre-alpine catchment: a discussion between a
tracer and a shallow groundwater hydrologist, Cuadernos de Investigación
Geográfica, 44, 429–452, https://doi.org/10.18172/cig.3349, 2018.
von Freyberg, J., Studer, B., and Kirchner, J. W.: A lab in the field: high-frequency analysis of water quality and stable isotopes in stream water and precipitation, Hydrol. Earth Syst. Sci., 21, 1721–1739, https://doi.org/10.5194/hess-21-1721-2017, 2017.
von Freyberg, J., Studer, B., Rinderer, M., and Kirchner, J. W.: Studying catchment storm response using event- and pre-event-water volumes as fractions of precipitation rather than discharge, Hydrol. Earth Syst. Sci., 22, 5847–5865, https://doi.org/10.5194/hess-22-5847-2018, 2018.
Wellington, B. I. and Driscoll, C. T.: The episodic acidification of a
stream with elevated concentrations of dissolved organic carbon, Hydrol.
Process., 18, 2663–2680, https://doi.org/10.1002/hyp.5574,
2004.
Xu, G.-L., Schleppi, P., Li, M.-H., and Fu, S.-L.: Negative responses of
Collembola in a forest soil (Alptal, Switzerland) under experimentally
increased N deposition, Environ. Pollut., 157, 2030–2036, https://doi.org/10.1016/j.envpol.2009.02.026, 2009.
Zobrist, J.: Water chemistry of Swiss Alpine rivers, in: Alpine Waters,
Springer, 95–118, 2010.
Short summary
Changes of stream water chemistry in response to discharge changes provide important insights into the storage and release of water from the catchment. Here we investigate the variability in concentration–discharge relationships among different solutes and hydrologic events and relate it to catchment conditions and dominant water sources.
Changes of stream water chemistry in response to discharge changes provide important insights...
