Articles | Volume 29, issue 11
https://doi.org/10.5194/hess-29-2485-2025
https://doi.org/10.5194/hess-29-2485-2025
Research article
 | 
16 Jun 2025
Research article |  | 16 Jun 2025

Numerical analysis of the effect of heterogeneity on CO2 dissolution enhanced by gravity-driven convection

Yufei Wang, Daniel Fernàndez-Garcia, and Maarten W. Saaltink

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Cited articles

Agartan, E., Trevisan, L., Cihan, A., Birkholzer, J., Zhou, Q., and Illangasekare, T. H.: Experimental study on effects of geologic heterogeneity in enhancing dissolution trapping of supercritical CO2, Water Resour. Res., 51, 1635–1648, https://doi.org/10.1002/2014WR015778, 2015. a
Amooie, M. A., Soltanian, M. R., and Moortgat, J.: Solutal convection in porous media: comparison between boundary conditions of constant concentration and constant flux, Phys. Rev. E, 98, 033118, https://doi.org/10.1103/PhysRevE.98.033118, 2018. a
Anbar, S. and Akin, S.: Development of a linear predictive model for carbon dioxide sequestration in deep saline carbonate aquifers, Comput. Geosci., 37, 1802–1815, 2011. a
Bachu, S., Bonijoly, D., Bradshaw, J., Burruss, R., Holloway, S., Christensen, N. P., and Mathiassen, O. M.: CO2 storage capacity estimation: methodology and gaps, Int. J. Greenh. Gas Con., 1, 430–443, https://doi.org/10.1016/S1750-5836(07)00086-2, 2007. a
Backhaus, S., Turitsyn, K., and Ecke, R. E.: Convective instability and mass transport of diffusion layers in a Hele-Shaw geometry, Phys. Rev. Lett., 106, 104501, https://doi.org/10.1103/PhysRevLett.106.104501, 2011. a
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Short summary
During geological carbon sequestration, the injected supercritical CO2, being less dense, floats above the brine. The dissolution of CO2 into brine helps mitigate the risk of CO2 leakage. As CO2 dissolves into the brine, it increases the density of brine in the upper layer, initiating gravity-driven convection (GDC), which significantly enhances the rate of CO2 dissolution. We derived two empirical formulas to predict the asymptotic dissolution rate driven by GDC in heterogeneous fields.
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