Articles | Volume 28, issue 15
https://doi.org/10.5194/hess-28-3519-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/hess-28-3519-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Short high-accuracy tritium data time series for assessing groundwater mean transit times in the vadose and saturated zones of the Luxembourg Sandstone aquifer
Luxembourg Institute of Science and Technology (LIST), Belvaux, Luxembourg
Michael K. Stewart
GNS Science, Tritium & Water Dating Laboratory, Te Awa Kairangi ki Tai / Lower Hutt, New Zealand
Uwe Morgenstern
GNS Science, Tritium & Water Dating Laboratory, Te Awa Kairangi ki Tai / Lower Hutt, New Zealand
Laurent Pfister
Luxembourg Institute of Science and Technology (LIST), Belvaux, Luxembourg
Faculty of Science, Technology and Medicine, University of Luxembourg, Belval, Luxembourg
Related authors
Karl Nicolaus van Zweel, Laurent Gourdol, Jean François Iffly, Loïc Léonard, François Barnich, Laurent Pfister, Erwin Zehe, and Christophe Hissler
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-259, https://doi.org/10.5194/essd-2024-259, 2024
Preprint under review for ESSD
Short summary
Short summary
Our study monitored groundwater in a Luxembourg forest over a year to understand water and chemical changes. We found seasonal variations in water chemistry, influenced by rainfall and soil interactions. This data helps predict environmental responses and manage water resources better. By measuring key parameters like pH and dissolved oxygen, our research provides valuable insights into groundwater behavior and serves as a resource for future environmental studies.
Laurent Gourdol, Rémi Clément, Jérôme Juilleret, Laurent Pfister, and Christophe Hissler
Hydrol. Earth Syst. Sci., 25, 1785–1812, https://doi.org/10.5194/hess-25-1785-2021, https://doi.org/10.5194/hess-25-1785-2021, 2021
Short summary
Short summary
Electrical resistivity tomography (ERT) is a remarkable tool for characterizing the regolith, but its use over large areas remains cumbersome due to the requirement of small electrode spacing (ES). In this study we document the issues of using oversized ESs and propose a new approach to overcome this limitation. We demonstrate that our protocol significantly improves the accuracy of ERT profiles using large ES and offers a cost-effective means for carrying out large-scale surveys.
Laurent Gourdol, Rémi Clément, Jérôme Juilleret, Laurent Pfister, and Christophe Hissler
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2018-519, https://doi.org/10.5194/hess-2018-519, 2018
Revised manuscript not accepted
Short summary
Short summary
Electrical Resistivity Tomography (ERT) is a remarkable tool for characterizing the geometry and properties of the regolith. However, its use for large horizontal surveys remains cumbersome to characterize shallow subsurface structures due to the requirement of small electrode spacing increments. Here we propose a new approach to overcome this limitation. We demonstrate that our protocol significantly improves the accuracy of ERT profiles when using large electrode spacing increments.
Karl Nicolaus van Zweel, Laurent Gourdol, Jean François Iffly, Loïc Léonard, François Barnich, Laurent Pfister, Erwin Zehe, and Christophe Hissler
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-259, https://doi.org/10.5194/essd-2024-259, 2024
Preprint under review for ESSD
Short summary
Short summary
Our study monitored groundwater in a Luxembourg forest over a year to understand water and chemical changes. We found seasonal variations in water chemistry, influenced by rainfall and soil interactions. This data helps predict environmental responses and manage water resources better. By measuring key parameters like pH and dissolved oxygen, our research provides valuable insights into groundwater behavior and serves as a resource for future environmental studies.
Paolo Nasta, Günter Blöschl, Heye R. Bogena, Steffen Zacharias, Roland Baatz, Gabriëlle De Lannoy, Karsten H. Jensen, Salvatore Manfreda, Laurent Pfister, Ana M. Tarquis, Ilja van Meerveld, Marc Voltz, Yijian Zeng, William Kustas, Xin Li, Harry Vereecken, and Nunzio Romano
EGUsphere, https://doi.org/10.5194/egusphere-2024-1678, https://doi.org/10.5194/egusphere-2024-1678, 2024
Short summary
Short summary
The Unsolved Problems in Hydrology (UPH) initiative has emphasized the need to establish networks of multi-decadal hydrological observatories to tackle catchment-scale challenges on a global scale. This opinion paper provocatively discusses two end members of possible future hydrological observatory (HO) networks for a given hypothesized community budget: a comprehensive set of moderately instrumented observatories or, alternatively, a small number of highly instrumented super-sites.
Conny Tschritter, Christopher J. Daughney, Sapthala Karalliyadda, Brioch Hemmings, Uwe Morgenstern, and Catherine Moore
Hydrol. Earth Syst. Sci., 27, 4295–4316, https://doi.org/10.5194/hess-27-4295-2023, https://doi.org/10.5194/hess-27-4295-2023, 2023
Short summary
Short summary
Understanding groundwater travel time (groundwater age) is crucial for tracking flow and contaminants. While groundwater age is usually inferred from age tracers, this study utilised two machine learning techniques with common groundwater chemistry data. The results of both methods correspond to traditional approaches. They are useful where hydrochemistry data exist but age tracer data are limited. These methods could help enhance our knowledge, aiding in sustainable freshwater management.
Judith Meyer, Malte Neuper, Luca Mathias, Erwin Zehe, and Laurent Pfister
Hydrol. Earth Syst. Sci., 26, 6163–6183, https://doi.org/10.5194/hess-26-6163-2022, https://doi.org/10.5194/hess-26-6163-2022, 2022
Short summary
Short summary
We identified and analysed the major atmospheric components of rain-intense thunderstorms that can eventually lead to flash floods: high atmospheric moisture, sufficient latent instability, and weak thunderstorm cell motion. Between 1981 and 2020, atmospheric conditions became likelier to support strong thunderstorms. However, the occurrence of extreme rainfall events as well as their rainfall intensity remained mostly unchanged.
Audrey Douinot, Jean François Iffly, Cyrille Tailliez, Claude Meisch, and Laurent Pfister
Hydrol. Earth Syst. Sci., 26, 5185–5206, https://doi.org/10.5194/hess-26-5185-2022, https://doi.org/10.5194/hess-26-5185-2022, 2022
Short summary
Short summary
The objective of the paper is to highlight the seasonal and singular shift of the transfer time distributions of two catchments (≅10 km2).
Based on 2 years of rainfall and discharge observations, we compare variations in the properties of TTDs with the physiographic characteristics of catchment areas and the eco-hydrological cycle. The paper eventually aims to deduce several factors conducive to particularly rapid and concentrated water transfers, which leads to flash floods.
Zibo Zhou, Ian Cartwright, and Uwe Morgenstern
Hydrol. Earth Syst. Sci., 26, 4497–4513, https://doi.org/10.5194/hess-26-4497-2022, https://doi.org/10.5194/hess-26-4497-2022, 2022
Short summary
Short summary
Streams may receive water from different sources in their catchment. There is limited understanding of which water stores intermittent streams are connected to. Using geochemistry we show that the intermittent streams in southeast Australia are connected to younger smaller near-river water stores rather than regional groundwater. This makes these streams more vulnerable to the impacts of climate change and requires management of the riparian zone for their protection.
Alessandro Montemagno, Christophe Hissler, Victor Bense, Adriaan J. Teuling, Johanna Ziebel, and Laurent Pfister
Biogeosciences, 19, 3111–3129, https://doi.org/10.5194/bg-19-3111-2022, https://doi.org/10.5194/bg-19-3111-2022, 2022
Short summary
Short summary
We investigated the biogeochemical processes that dominate the release and retention of elements (nutrients and potentially toxic elements) during litter degradation. Our results show that toxic elements are retained in the litter, while nutrients are released in solution during the first stages of degradation. This seems linked to the capability of trees to distribute the elements between degradation-resistant and non-degradation-resistant compounds of leaves according to their chemical nature.
Michael Kilgour Stewart, Uwe Morgenstern, and Ian Cartwright
Hydrol. Earth Syst. Sci., 25, 6333–6338, https://doi.org/10.5194/hess-25-6333-2021, https://doi.org/10.5194/hess-25-6333-2021, 2021
Short summary
Short summary
The combined use of deuterium and tritium to determine travel time distributions in streams is an important development in catchment hydrology (Rodriguez et al., 2021). This comment, however, argues that their results do not generally invalidate the truncation hypothesis of Stewart et al. (2010) (i.e. that stable isotopes underestimate travel times through catchments), as they imply, but asserts instead that the hypothesis still applies to many other catchments.
Laurent Gourdol, Rémi Clément, Jérôme Juilleret, Laurent Pfister, and Christophe Hissler
Hydrol. Earth Syst. Sci., 25, 1785–1812, https://doi.org/10.5194/hess-25-1785-2021, https://doi.org/10.5194/hess-25-1785-2021, 2021
Short summary
Short summary
Electrical resistivity tomography (ERT) is a remarkable tool for characterizing the regolith, but its use over large areas remains cumbersome due to the requirement of small electrode spacing (ES). In this study we document the issues of using oversized ESs and propose a new approach to overcome this limitation. We demonstrate that our protocol significantly improves the accuracy of ERT profiles using large ES and offers a cost-effective means for carrying out large-scale surveys.
Jan Bondy, Jan Wienhöfer, Laurent Pfister, and Erwin Zehe
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2021-174, https://doi.org/10.5194/hess-2021-174, 2021
Manuscript not accepted for further review
Short summary
Short summary
The Budyko curve is a widely-used and simple framework to predict the mean water balance of river catchments. While many catchments are in close accordance with the Budyko curve, others show more or less significant deviations. Our study aims at better understanding the role of soil storage characteristics in the mean water balance and offsets from the Budyko curve. Soil storage proved to be a very sensitive property and potentially explains significant deviations from the curve.
Nicolas Björn Rodriguez, Laurent Pfister, Erwin Zehe, and Julian Klaus
Hydrol. Earth Syst. Sci., 25, 401–428, https://doi.org/10.5194/hess-25-401-2021, https://doi.org/10.5194/hess-25-401-2021, 2021
Short summary
Short summary
Different parts of water have often been used as tracers to determine the age of water in streams. The stable tracers, such as deuterium, are thought to be unable to reveal old water compared to the radioactive tracer called tritium. We used both tracers, measured in precipitation and in a stream in Luxembourg, to show that this is not necessarily true. It is, in fact, advantageous to use the two tracers together, and we recommend systematically using tritium in future studies.
Jasper Foets, Carlos E. Wetzel, Núria Martínez-Carreras, Adriaan J. Teuling, Jean-François Iffly, and Laurent Pfister
Hydrol. Earth Syst. Sci., 24, 4709–4725, https://doi.org/10.5194/hess-24-4709-2020, https://doi.org/10.5194/hess-24-4709-2020, 2020
Short summary
Short summary
Diatoms (microscopic algae) are regarded as useful tracers in catchment hydrology. However, diatom analysis is labour-intensive; therefore, only a limited number of samples can be analysed. To reduce this number, we explored the potential for a time-integrated mass-flux sampler to provide a representative sample of the diatom assemblage for a whole storm run-off event. Our results indicate that the Phillips sampler did indeed sample representative communities during two of the three events.
Michael Kilgour Stewart and Philippa Lauren Aitchison-Earl
Hydrol. Earth Syst. Sci., 24, 3583–3601, https://doi.org/10.5194/hess-24-3583-2020, https://doi.org/10.5194/hess-24-3583-2020, 2020
Short summary
Short summary
This paper is important for water resource management, being concerned with irrigation return flow causing
hotspotsin nitrate concentrations in groundwater and
denitrification imprintswhere nitrate concentrations are reduced by denitrification although the dissolved oxygen concentration is not low. The work is highly significant for modelling of nitrate transport through soil–groundwater systems, for understanding denitrification processes, and for managing fertilizer application to land.
Bernd R. Schöne, Aliona E. Meret, Sven M. Baier, Jens Fiebig, Jan Esper, Jeffrey McDonnell, and Laurent Pfister
Hydrol. Earth Syst. Sci., 24, 673–696, https://doi.org/10.5194/hess-24-673-2020, https://doi.org/10.5194/hess-24-673-2020, 2020
Short summary
Short summary
We present the first annually resolved stable isotope record (1819–1998) from shells of Swedish river mussels. Data reflect hydrological processes in the catchment and changes in the isotope value of local precipitation. The latter is related to the origin of moisture from which precipitation formed (North Atlantic or the Arctic) and governed by large-scale atmospheric circulation patterns. Results help to better understand climate dynamics and constrain ecological changes in river ecosystems.
Laurent Gourdol, Rémi Clément, Jérôme Juilleret, Laurent Pfister, and Christophe Hissler
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2018-519, https://doi.org/10.5194/hess-2018-519, 2018
Revised manuscript not accepted
Short summary
Short summary
Electrical Resistivity Tomography (ERT) is a remarkable tool for characterizing the geometry and properties of the regolith. However, its use for large horizontal surveys remains cumbersome to characterize shallow subsurface structures due to the requirement of small electrode spacing increments. Here we propose a new approach to overcome this limitation. We demonstrate that our protocol significantly improves the accuracy of ERT profiles when using large electrode spacing increments.
Barbara Glaser, Marta Antonelli, Marco Chini, Laurent Pfister, and Julian Klaus
Hydrol. Earth Syst. Sci., 22, 5987–6003, https://doi.org/10.5194/hess-22-5987-2018, https://doi.org/10.5194/hess-22-5987-2018, 2018
Short summary
Short summary
We demonstrate how thermal infrared images can be used for mapping the appearance and disappearance of water at the surface. The use of thermal infrared images allows for mapping this appearance and disappearance for various temporal and spatial resolutions, and the images can be understood intuitively. We explain the necessary steps in detail, from image acquisition to final processing, by relying on image examples and experience from an 18-month mapping campaign.
Michael P. Schwab, Julian Klaus, Laurent Pfister, and Markus Weiler
Biogeosciences, 15, 2177–2188, https://doi.org/10.5194/bg-15-2177-2018, https://doi.org/10.5194/bg-15-2177-2018, 2018
Short summary
Short summary
We studied the diel fluctuations of dissolved organic carbon (DOC) concentrations in a small stream in Luxembourg. We identified an increased proportion of DOC from terrestrial sources as responsible for the peaks in DOC in the afternoon. Warmer water temperatures in the riparian zone in the afternoon increased the amount of water flowing towards the stream. Consequently, an increased amount of DOC-rich water from the riparian zone was entering the stream.
William Howcroft, Ian Cartwright, and Uwe Morgenstern
Hydrol. Earth Syst. Sci., 22, 635–653, https://doi.org/10.5194/hess-22-635-2018, https://doi.org/10.5194/hess-22-635-2018, 2018
Short summary
Short summary
Documenting mean transit times is critical for understanding and managing catchments. Mean transit times in six headwater catchments of the Otway Ranges, Australia, determined using tritium, range from 7 to 230 years. Tritium activities correlate well with streamflow but are difficult to predict from catchment attributes or major ion geochemistry. The long mean transit times suggest that the catchments are buffered from short-term rainfall variations.
Michael K. Stewart, Uwe Morgenstern, Maksym A. Gusyev, and Piotr Małoszewski
Hydrol. Earth Syst. Sci., 21, 4615–4627, https://doi.org/10.5194/hess-21-4615-2017, https://doi.org/10.5194/hess-21-4615-2017, 2017
Short summary
Short summary
This paper presents for the first time the effects of aggregation errors on mean transit times and young fractions estimated using tritium concentrations. Such errors, due to heterogeneity in catchments, had previously been demonstrated for seasonal tracer cycles by Kirchner (2016a). We found that mean transit times derived from tritium are just as susceptible to aggregation bias as those from seasonal tracer cycles. Young fractions were found to be almost immune to aggregation bias.
Monique Beyer, Uwe Morgenstern, Rob van der Raaij, and Heather Martindale
Hydrol. Earth Syst. Sci., 21, 4213–4231, https://doi.org/10.5194/hess-21-4213-2017, https://doi.org/10.5194/hess-21-4213-2017, 2017
Short summary
Short summary
The determination of groundwater age can aid characterization of aquifers, providing information on groundwater mixing, flow, volume, and recharge rates. Here we assess a recently discovered groundwater age tracer, Halon-1301. Its performance as an age tracer is assessed against six other well-established, widely used age tracers in 302 groundwater samples. We show Halon-1301 reliably inferred age, thus potentially becoming a useful groundwater age tracer where other tracers are compromised.
Michael P. Schwab, Julian Klaus, Laurent Pfister, and Markus Weiler
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2017-416, https://doi.org/10.5194/hess-2017-416, 2017
Revised manuscript not accepted
Simon Paul Seibert, Conrad Jackisch, Uwe Ehret, Laurent Pfister, and Erwin Zehe
Hydrol. Earth Syst. Sci., 21, 2817–2841, https://doi.org/10.5194/hess-21-2817-2017, https://doi.org/10.5194/hess-21-2817-2017, 2017
Short summary
Short summary
Runoff production mechanisms and their corresponding physiographic controls continue to pose major research challenges in catchment hydrology. We propose innovative data-driven diagnostic signatures for overcoming the prevailing status quo in inter-comparison studies. Specifically, we present dimensionless double mass curves which allow us to infer information on runoff generation at the seasonal and annual timescales. The method is based on commonly available data.
Ian Cartwright and Uwe Morgenstern
Hydrol. Earth Syst. Sci., 20, 4757–4773, https://doi.org/10.5194/hess-20-4757-2016, https://doi.org/10.5194/hess-20-4757-2016, 2016
Short summary
Short summary
This research used tritium to determine the timescales that water is stored in peatlands and eucalyptus forest catchments in upland river systems in southeast Australia. The mean transit times in the peatland catchments of less than a few years contrast with much longer transit times (years to decades) in adjacent eucalyptus catchments. The peat is susceptible to drying which renders it vulnerable to degradation and bushfire and does not represent a long-term water store to upland streams.
Maksym A. Gusyev, Uwe Morgenstern, Michael K. Stewart, Yusuke Yamazaki, Kazuhisa Kashiwaya, Terumasa Nishihara, Daisuke Kuribayashi, Hisaya Sawano, and Yoichi Iwami
Hydrol. Earth Syst. Sci., 20, 3043–3058, https://doi.org/10.5194/hess-20-3043-2016, https://doi.org/10.5194/hess-20-3043-2016, 2016
Short summary
Short summary
Tritium-estimated groundwater mean transit times (MTTs) and storage volumes provide useful information for water resources management especially during droughts. In Hokkaido, we find that (1) one tritium measurement at baseflow is already sufficient to estimate MTT for some catchments, (2) the hydrogeological settings control tritium transit times of subsurface groundwater storage at baseflow, and (3) in future, one tritium measurement will be sufficient to estimate MTT in most Japanese catchments.
C. Duvert, M. K. Stewart, D. I. Cendón, and M. Raiber
Hydrol. Earth Syst. Sci., 20, 257–277, https://doi.org/10.5194/hess-20-257-2016, https://doi.org/10.5194/hess-20-257-2016, 2016
Short summary
Short summary
The transit time of water is a key indicator of hydrological processes at the catchment scale. Our results suggest that the use of tritium time series in streamwater can be highly valuable for assessing the temporal variations in the transit time of older groundwater contributions to streamflow. We also show that, shortly after high flow events, the transit time of the old water fraction increases and tends to approach the groundwater residence time.
I. Cartwright and U. Morgenstern
Hydrol. Earth Syst. Sci., 19, 3771–3785, https://doi.org/10.5194/hess-19-3771-2015, https://doi.org/10.5194/hess-19-3771-2015, 2015
Short summary
Short summary
This study documents the age of water that contributes to rivers in upper catchments using the radioactive tracer tritium. River water in the upper Ovens Valley (Australia) is several years to decades old and water from different parts of the catchment (e.g., soil, regolith, and groundwater) is mobilised at different flow conditions. The results indicate that these rivers are buffered against short term climate variability but are susceptible to longer-term climate and land use changes
N. Martínez-Carreras, C. E. Wetzel, J. Frentress, L. Ector, J. J. McDonnell, L. Hoffmann, and L. Pfister
Hydrol. Earth Syst. Sci., 19, 3133–3151, https://doi.org/10.5194/hess-19-3133-2015, https://doi.org/10.5194/hess-19-3133-2015, 2015
Short summary
Short summary
We tested the hypothesis that different diatom species assemblages inhabit specific moisture domains of the catchment and, consequently, the presence of certain species assemblages in the stream during runoff events offers the potential for recording whether there was hydrological connectivity between these domains or not. In the Weierbach catchment, the transport of aerial diatoms during events suggested a rapid connectivity between the soil surface and the stream.
M. Beyer, R. van der Raaij, U. Morgenstern, and B. Jackson
Hydrol. Earth Syst. Sci., 19, 2775–2789, https://doi.org/10.5194/hess-19-2775-2015, https://doi.org/10.5194/hess-19-2775-2015, 2015
Short summary
Short summary
We assess the potential of Halon-1301 as a new groundwater age tracer, which had not been assessed in detail. We determine Halon-1301 and infer age in 17 New Zealand groundwater samples and various modern waters. Halon-1301 reliably inferred age in 71% of the sites within 1 SD of the ages inferred from tritium and SF6. The remaining (anoxic) waters show reduced concentrations of Halon-1301 along with even further reduced concentrations of CFCs. The reason(s) for this need to be further assessed.
S. Kang, F. Wang, U. Morgenstern, Y. Zhang, B. Grigholm, S. Kaspari, M. Schwikowski, J. Ren, T. Yao, D. Qin, and P. A. Mayewski
The Cryosphere, 9, 1213–1222, https://doi.org/10.5194/tc-9-1213-2015, https://doi.org/10.5194/tc-9-1213-2015, 2015
Short summary
M. K. Stewart
Hydrol. Earth Syst. Sci., 19, 2587–2603, https://doi.org/10.5194/hess-19-2587-2015, https://doi.org/10.5194/hess-19-2587-2015, 2015
Short summary
Short summary
This paper presents new baseflow separation and recession analysis methods for streamflow. The baseflow separation method ("bump and rise method" or BRM) aims to accurately simulate the shape of tracer-determined baseflow or pre-event water. The recession analysis approach advocates analyzing quickflow and baseflow as well as streamflow because analyzing the latter alone gives misleading information on catchment storage reservoirs. The methods are demonstrated for the Glendhu streamflow record.
U. Morgenstern, C. J. Daughney, G. Leonard, D. Gordon, F. M. Donath, and R. Reeves
Hydrol. Earth Syst. Sci., 19, 803–822, https://doi.org/10.5194/hess-19-803-2015, https://doi.org/10.5194/hess-19-803-2015, 2015
E. Zehe, U. Ehret, L. Pfister, T. Blume, B. Schröder, M. Westhoff, C. Jackisch, S. J. Schymanski, M. Weiler, K. Schulz, N. Allroggen, J. Tronicke, L. van Schaik, P. Dietrich, U. Scherer, J. Eccard, V. Wulfmeyer, and A. Kleidon
Hydrol. Earth Syst. Sci., 18, 4635–4655, https://doi.org/10.5194/hess-18-4635-2014, https://doi.org/10.5194/hess-18-4635-2014, 2014
M. A. Gusyev, D. Abrams, M. W. Toews, U. Morgenstern, and M. K. Stewart
Hydrol. Earth Syst. Sci., 18, 3109–3119, https://doi.org/10.5194/hess-18-3109-2014, https://doi.org/10.5194/hess-18-3109-2014, 2014
A. M. J. Coenders-Gerrits, L. Hopp, H. H. G. Savenije, and L. Pfister
Hydrol. Earth Syst. Sci., 17, 1749–1763, https://doi.org/10.5194/hess-17-1749-2013, https://doi.org/10.5194/hess-17-1749-2013, 2013
M. A. Gusyev, M. Toews, U. Morgenstern, M. Stewart, P. White, C. Daughney, and J. Hadfield
Hydrol. Earth Syst. Sci., 17, 1217–1227, https://doi.org/10.5194/hess-17-1217-2013, https://doi.org/10.5194/hess-17-1217-2013, 2013
Related subject area
Subject: Groundwater hydrology | Techniques and Approaches: Modelling approaches
Assessing groundwater level modelling using a 1-D convolutional neural network (CNN): linking model performances to geospatial and time series features
High-resolution long-term average groundwater recharge in Africa estimated using random forest regression and residual interpolation
Towards understanding the influence of seasons on low-groundwater periods based on explainable machine learning
Data-driven modeling of hydraulic head time series: results and lessons learned from the 2022 groundwater modeling challenge
Shannon entropy of transport self-organization due to dissolution–precipitation reaction at varying Peclet numbers in initially homogeneous porous media
A high-resolution map of diffuse groundwater recharge rates for Australia
Influence of bank slope on sinuosity-driven hyporheic exchange flow and residence time distribution during a dynamic flood event
Technical note: A model of chemical transport in a wellbore–aquifer system
Disentangling coastal groundwater level dynamics in a global dataset
The impact of future climate projections and anthropogenic activities on basin-scale groundwater availability
Current and future roles of meltwater–groundwater dynamics in a proglacial Alpine outwash plain
On the challenges of global entity-aware deep learning models for groundwater level prediction
Incorporating interpretation uncertainties from deterministic 3D hydrostratigraphic models in groundwater models
Adjoint subordination to calculate backward travel time probability of pollutants in water with various velocity resolutions
On the optimal level of complexity for the representation of groundwater-dependent wetland systems in land surface models
Estimation of groundwater age distributions from hydrochemistry: comparison of two metamodelling algorithms in the Heretaunga Plains aquifer system, New Zealand
Technical note: Novel analytical solution for groundwater response to atmospheric tides
Calibration of groundwater seepage against the spatial distribution of the stream network to assess catchment-scale hydraulic properties
Climate-warming-driven changes in the cryosphere and their impact on groundwater–surface-water interactions in the Heihe River basin
Comparison of artificial neural networks and reservoir models for simulating karst spring discharge on five test sites in the Alpine and Mediterranean regions
A general model of radial dispersion with wellbore mixing and skin effects
Estimation of hydraulic conductivity functions in karst regions by particle swarm optimization with application to Lake Vrana, Croatia
The origin of hydrological responses following earthquakes in a confined aquifer: insight from water level, flow rate, and temperature observations
Advance prediction of coastal groundwater levels with temporal convolutional and long short-term memory networks
Three-dimensional hydrogeological parametrization using sparse piezometric data
Machine-learning-based downscaling of modelled climate change impacts on groundwater table depth
Frequency domain water table fluctuations reveal impacts of intense rainfall and vadose zone thickness on groundwater recharge
Characterizing groundwater heat transport in a complex lowland aquifer using paleo-temperature reconstruction, satellite data, temperature–depth profiles, and numerical models
Karst spring recession and classification: efficient, automated methods for both fast- and slow-flow components
Exploring river–aquifer interactions and hydrological system response using baseflow separation, impulse response modeling, and time series analysis in three temperate lowland catchments
Experimental study of non-Darcy flow characteristics in permeable stones
Karst spring discharge modeling based on deep learning using spatially distributed input data
HESS Opinions: Chemical transport modeling in subsurface hydrological systems – space, time, and the “holy grail” of “upscaling”
Spatiotemporal variations in water sources and mixing spots in a riparian zone
Delineation of discrete conduit networks in karst aquifers via combined analysis of tracer tests and geophysical data
Reactive transport modeling for supporting climate resilience at groundwater contamination sites
Improved understanding of regional groundwater drought development through time series modelling: the 2018–2019 drought in the Netherlands
Simulation of long-term spatiotemporal variations in regional-scale groundwater recharge: contributions of a water budget approach in cold and humid climates
Feedback mechanisms between precipitation and dissolution reactions across randomly heterogeneous conductivity fields
Taking theory to the field: streamflow generation mechanisms in an intermittent Mediterranean catchment
Coupling saturated and unsaturated flow: comparing the iterative and the non-iterative approach
Time lags of nitrate, chloride, and tritium in streams assessed by dynamic groundwater flow tracking in a lowland landscape
Using Long Short-Term Memory networks to connect water table depth anomalies to precipitation anomalies over Europe
Estimation of groundwater recharge from groundwater levels using nonlinear transfer function noise models and comparison to lysimeter data
Early hypogenic carbonic acid speleogenesis in unconfined limestone aquifers by upwelling deep-seated waters with high CO2 concentration: a modelling approach
Impacts of climate change on groundwater flooding and ecohydrology in lowland karst
How daily groundwater table drawdown affects the diel rhythm of hyporheic exchange
Groundwater level forecasting with artificial neural networks: a comparison of long short-term memory (LSTM), convolutional neural networks (CNNs), and non-linear autoregressive networks with exogenous input (NARX)
Groundwater and baseflow drought responses to synthetic recharge stress tests
Determination of vadose zone and saturated zone nitrate lag times using long-term groundwater monitoring data and statistical machine learning
Mariana Gomez, Maximilian Nölscher, Andreas Hartmann, and Stefan Broda
Hydrol. Earth Syst. Sci., 28, 4407–4425, https://doi.org/10.5194/hess-28-4407-2024, https://doi.org/10.5194/hess-28-4407-2024, 2024
Short summary
Short summary
To understand the impact of external factors on groundwater level modelling using a 1-D convolutional neural network (CNN) model, we train, validate, and tune individual CNN models for 505 wells distributed across Lower Saxony, Germany. We then evaluate the performance of these models against available geospatial and time series features. This study provides new insights into the relationship between these factors and the accuracy of groundwater modelling.
Anna Pazola, Mohammad Shamsudduha, Jon French, Alan M. MacDonald, Tamiru Abiye, Ibrahim Baba Goni, and Richard G. Taylor
Hydrol. Earth Syst. Sci., 28, 2949–2967, https://doi.org/10.5194/hess-28-2949-2024, https://doi.org/10.5194/hess-28-2949-2024, 2024
Short summary
Short summary
This study advances groundwater research using a high-resolution random forest model, revealing new recharge areas and spatial variability, mainly in humid regions. Limited data in rainy zones is a constraint for the model. Our findings underscore the promise of machine learning for large-scale groundwater modelling while further emphasizing the importance of data collection for robust results.
Andreas Wunsch, Tanja Liesch, and Nico Goldscheider
Hydrol. Earth Syst. Sci., 28, 2167–2178, https://doi.org/10.5194/hess-28-2167-2024, https://doi.org/10.5194/hess-28-2167-2024, 2024
Short summary
Short summary
Seasons have a strong influence on groundwater levels, but relationships are complex and partly unknown. Using data from wells in Germany and an explainable machine learning approach, we showed that summer precipitation is the key factor that controls the severeness of a low-water period in fall; high summer temperatures do not per se cause stronger decreases. Preceding winters have only a minor influence on such low-water periods in general.
Raoul Alexander Collenteur, Ezra Haaf, Mark Bakker, Tanja Liesch, Andreas Wunsch, Jenny Soonthornrangsan, Jeremy White, Nick Martin, Rui Hugman, Michael Fienen, Ed de Sousa, Didier Vanden Berghe, Xinyang Fan, Tim Peterson, Janis Bikše, Antoine Di Ciacca, Xinyue Wang, Yang Zheng, Maximilian Nölscher, Julian Koch, Raphael Schneider, Nikolas Benavides Höglund, Sivarama Krishna Reddy Chidepudi, Abel Henriot, Nicolas Massei, Abderrahim Jardani, Max Gustav Rudolph, Amir Rouhani, Jaime Gómez-Hernández, Seifeddine Jomaa, Anna Pölz, Tim Franken, Morteza Behbooei, Jimmy Lin, Bryan Tolson, and Rojin Meysami
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2024-111, https://doi.org/10.5194/hess-2024-111, 2024
Revised manuscript accepted for HESS
Short summary
Short summary
We present the results of the 2022 groundwater modeling challenge, where 15 teams applied data-driven models to simulate hydraulic heads. 3 groups of models were identified: lumped models, machine learning models, and deep learning models. For all wells, reasonable performance was obtained by at least 1 team from group. There was not 1 team that performed best for all wells. In conclusion, the challenge was a successful initiative to compare different models and learn from each other.
Evgeny Shavelzon and Yaniv Edery
Hydrol. Earth Syst. Sci., 28, 1803–1826, https://doi.org/10.5194/hess-28-1803-2024, https://doi.org/10.5194/hess-28-1803-2024, 2024
Short summary
Short summary
We investigate the interaction of transport with dissolution–precipitation reactions in porous media using the concepts of entropy and work to quantify the emergence of preferential flow paths. We show that the preferential-flow-path phenomenon and the hydraulic power required to maintain the driving pressure drop intensify over time along with the heterogeneity due to the interaction between the transport and the reactive processes. This is more pronounced in diffusion-dominated flows.
Stephen Lee, Dylan J. Irvine, Clément Duvert, Gabriel C. Rau, and Ian Cartwright
Hydrol. Earth Syst. Sci., 28, 1771–1790, https://doi.org/10.5194/hess-28-1771-2024, https://doi.org/10.5194/hess-28-1771-2024, 2024
Short summary
Short summary
Global groundwater recharge studies collate recharge values estimated using different methods that apply to different timescales. We develop a recharge prediction model, based solely on chloride, to produce a recharge map for Australia. We reveal that climate and vegetation have the most significant influence on recharge variability in Australia. Our recharge rates were lower than other models due to the long timescale of chloride in groundwater. Our method can similarly be applied globally.
Yiming Li, Uwe Schneidewind, Zhang Wen, Stefan Krause, and Hui Liu
Hydrol. Earth Syst. Sci., 28, 1751–1769, https://doi.org/10.5194/hess-28-1751-2024, https://doi.org/10.5194/hess-28-1751-2024, 2024
Short summary
Short summary
Meandering rivers are an integral part of many landscapes around the world. Here we used a new modeling approach to look at how the slope of riverbanks influences water flow and solute transport from a meandering river channel through its bank and into/out of the connected groundwater compartment (aquifer). We found that the bank slope can be a significant factor to be considered, especially when bank slope angles are small, and riverbank and aquifer conditions only allow for slow water flow.
Yiqun Gan and Quanrong Wang
Hydrol. Earth Syst. Sci., 28, 1317–1323, https://doi.org/10.5194/hess-28-1317-2024, https://doi.org/10.5194/hess-28-1317-2024, 2024
Short summary
Short summary
1. A revised 3D model of solute transport is developed in the well–aquifer system. 2. The accuracy of the new model is tested against benchmark analytical solutions. 3. Previous models overestimate the concentration of solute in both aquifers and wellbores in the injection well test case. 4. Previous models underestimate the concentration in the extraction well test case.
Annika Nolte, Ezra Haaf, Benedikt Heudorfer, Steffen Bender, and Jens Hartmann
Hydrol. Earth Syst. Sci., 28, 1215–1249, https://doi.org/10.5194/hess-28-1215-2024, https://doi.org/10.5194/hess-28-1215-2024, 2024
Short summary
Short summary
This study examines about 8000 groundwater level (GWL) time series from five continents to explore similarities in groundwater systems at different scales. Statistical metrics and machine learning techniques are applied to identify common GWL dynamics patterns and analyze their controlling factors. The study also highlights the potential and limitations of this data-driven approach to improve our understanding of groundwater recharge and discharge processes.
Steven Reinaldo Rusli, Victor F. Bense, Syed M. T. Mustafa, and Albrecht H. Weerts
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2024-26, https://doi.org/10.5194/hess-2024-26, 2024
Revised manuscript accepted for HESS
Short summary
Short summary
In this paper, we investigate the impact of climatic and anthropogenic factors on future groundwater availability. The changes are simulated using hydrological and groundwater flow models. We found out that the future groundwater status is influenced more so by anthropogenic factors compared to climatic factors. The results are beneficial to inform the responsible parties in operational water management to achieve future (ground)water governance.
Tom Müller, Matteo Roncoroni, Davide Mancini, Stuart N. Lane, and Bettina Schaefli
Hydrol. Earth Syst. Sci., 28, 735–759, https://doi.org/10.5194/hess-28-735-2024, https://doi.org/10.5194/hess-28-735-2024, 2024
Short summary
Short summary
We investigate the role of a newly formed floodplain in an alpine glaciated catchment to store and release water. Based on field measurements, we built a numerical model to simulate the water fluxes and show that recharge occurs mainly due to the ice-melt-fed river. We identify three future floodplains, which could emerge from glacier retreat, and show that their combined storage leads to some additional groundwater storage but contributes little additional baseflow for the downstream river.
Benedikt Heudorfer, Tanja Liesch, and Stefan Broda
Hydrol. Earth Syst. Sci., 28, 525–543, https://doi.org/10.5194/hess-28-525-2024, https://doi.org/10.5194/hess-28-525-2024, 2024
Short summary
Short summary
We build a neural network to predict groundwater levels from monitoring wells. We predict all wells at the same time, by learning the differences between wells with static features, making it an entity-aware global model. This works, but we also test different static features and find that the model does not use them to learn exactly how the wells are different, but only to uniquely identify them. As this model class is not actually entity aware, we suggest further steps to make it so.
Trine Enemark, Rasmus Bødker Madsen, Torben O. Sonnenborg, Lærke Therese Andersen, Peter B. E. Sandersen, Jacob Kidmose, Ingelise Møller, Thomas Mejer Hansen, Karsten Høgh Jensen, and Anne-Sophie Høyer
Hydrol. Earth Syst. Sci., 28, 505–523, https://doi.org/10.5194/hess-28-505-2024, https://doi.org/10.5194/hess-28-505-2024, 2024
Short summary
Short summary
In this study, we demonstrate an approach to evaluate the interpretation uncertainty within a manually interpreted geological model in a groundwater model. Using qualitative estimates of uncertainties, several geological realizations are developed and implemented in groundwater models. We confirm existing evidence that if the conceptual model is well defined, interpretation uncertainties within the conceptual model have limited impact on groundwater model predictions.
Yong Zhang, Graham E. Fogg, HongGuang Sun, Donald M. Reeves, Roseanna M. Neupauer, and Wei Wei
Hydrol. Earth Syst. Sci., 28, 179–203, https://doi.org/10.5194/hess-28-179-2024, https://doi.org/10.5194/hess-28-179-2024, 2024
Short summary
Short summary
Pollutant release history and source identification are helpful for managing water resources, but it remains a challenge to reliably identify such information for real-world, complex transport processes in rivers and aquifers. In this study, we filled this knowledge gap by deriving a general backward governing equation and developing the efficient solver. Field applications showed that this model and solver are applicable for a broad range of flow systems, dimensions, and spatiotemporal scales.
Mennatullah T. Elrashidy, Andrew M. Ireson, and Saman Razavi
Hydrol. Earth Syst. Sci., 27, 4595–4608, https://doi.org/10.5194/hess-27-4595-2023, https://doi.org/10.5194/hess-27-4595-2023, 2023
Short summary
Short summary
Wetlands are important ecosystems that store carbon and play a vital role in the water cycle. However, hydrological computer models do not always represent wetlands and their interaction with groundwater accurately. We tested different possible ways to include groundwater–wetland interactions in these models. We found that the optimal method to include wetlands and groundwater in the models is reliant on the intended use of the models and the characteristics of the land and soil being studied.
Conny Tschritter, Christopher J. Daughney, Sapthala Karalliyadda, Brioch Hemmings, Uwe Morgenstern, and Catherine Moore
Hydrol. Earth Syst. Sci., 27, 4295–4316, https://doi.org/10.5194/hess-27-4295-2023, https://doi.org/10.5194/hess-27-4295-2023, 2023
Short summary
Short summary
Understanding groundwater travel time (groundwater age) is crucial for tracking flow and contaminants. While groundwater age is usually inferred from age tracers, this study utilised two machine learning techniques with common groundwater chemistry data. The results of both methods correspond to traditional approaches. They are useful where hydrochemistry data exist but age tracer data are limited. These methods could help enhance our knowledge, aiding in sustainable freshwater management.
Jose M. Bastias Espejo, Chris Turnadge, Russell S. Crosbie, Philipp Blum, and Gabriel C. Rau
Hydrol. Earth Syst. Sci., 27, 3447–3462, https://doi.org/10.5194/hess-27-3447-2023, https://doi.org/10.5194/hess-27-3447-2023, 2023
Short summary
Short summary
Analytical models estimate subsurface properties from subsurface–tidal load interactions. However, they have limited accuracy in representing subsurface physics and parameter estimation. We derived a new analytical solution which models flow to wells due to atmospheric tides. We applied it to field data and compared our findings with subsurface knowledge. Our results enhance understanding of subsurface systems, providing valuable information on their behavior.
Ronan Abhervé, Clément Roques, Alexandre Gauvain, Laurent Longuevergne, Stéphane Louaisil, Luc Aquilina, and Jean-Raynald de Dreuzy
Hydrol. Earth Syst. Sci., 27, 3221–3239, https://doi.org/10.5194/hess-27-3221-2023, https://doi.org/10.5194/hess-27-3221-2023, 2023
Short summary
Short summary
We propose a model calibration method constraining groundwater seepage in the hydrographic network. The method assesses the hydraulic properties of aquifers in regions where perennial streams are directly fed by groundwater. The estimated hydraulic conductivity appear to be highly sensitive to the spatial extent and density of streams. Such an approach improving subsurface characterization from surface information is particularly interesting for ungauged basins.
Amanda Triplett and Laura E. Condon
Hydrol. Earth Syst. Sci., 27, 2763–2785, https://doi.org/10.5194/hess-27-2763-2023, https://doi.org/10.5194/hess-27-2763-2023, 2023
Short summary
Short summary
Accelerated melting in mountains is a global phenomenon. The Heihe River basin depends on upstream mountains for its water supply. We built a hydrologic model to examine how shifts in streamflow and warming will impact ground and surface water interactions. The results indicate that degrading permafrost has a larger effect than melting glaciers. Additionally, warming temperatures tend to have more impact than changes to streamflow. These results can inform other mountain–valley system studies.
Guillaume Cinkus, Andreas Wunsch, Naomi Mazzilli, Tanja Liesch, Zhao Chen, Nataša Ravbar, Joanna Doummar, Jaime Fernández-Ortega, Juan Antonio Barberá, Bartolomé Andreo, Nico Goldscheider, and Hervé Jourde
Hydrol. Earth Syst. Sci., 27, 1961–1985, https://doi.org/10.5194/hess-27-1961-2023, https://doi.org/10.5194/hess-27-1961-2023, 2023
Short summary
Short summary
Numerous modelling approaches can be used for studying karst water resources, which can make it difficult for a stakeholder or researcher to choose the appropriate method. We conduct a comparison of two widely used karst modelling approaches: artificial neural networks (ANNs) and reservoir models. Results show that ANN models are very flexible and seem great for reproducing high flows. Reservoir models can work with relatively short time series and seem to accurately reproduce low flows.
Wenguang Shi, Quanrong Wang, Hongbin Zhan, Renjie Zhou, and Haitao Yan
Hydrol. Earth Syst. Sci., 27, 1891–1908, https://doi.org/10.5194/hess-27-1891-2023, https://doi.org/10.5194/hess-27-1891-2023, 2023
Short summary
Short summary
The mechanism of radial dispersion is important for understanding reactive transport in the subsurface and for estimating aquifer parameters required in the optimization design of remediation strategies. A general model and associated analytical solutions are developed in this study. The new model represents the most recent advancement on radial dispersion studies and incorporates a host of important processes that are not taken into consideration in previous investigations.
Vanja Travaš, Luka Zaharija, Davor Stipanić, and Siniša Družeta
Hydrol. Earth Syst. Sci., 27, 1343–1359, https://doi.org/10.5194/hess-27-1343-2023, https://doi.org/10.5194/hess-27-1343-2023, 2023
Short summary
Short summary
In order to model groundwater flow in karst aquifers, it is necessary to approximate the influence of the unknown and irregular structure of the karst conduits. For this purpose, a procedure based on inverse modeling is adopted. Moreover, in order to reconstruct the functional dependencies related to groundwater flow, the particle swarm method was used, through which the optimal solution of unknown functions is found by imitating the movement of ants in search of food.
Shouchuan Zhang, Zheming Shi, Guangcai Wang, Zuochen Zhang, and Huaming Guo
Hydrol. Earth Syst. Sci., 27, 401–415, https://doi.org/10.5194/hess-27-401-2023, https://doi.org/10.5194/hess-27-401-2023, 2023
Short summary
Short summary
We documented the step-like increases of water level, flow rate, and water temperatures in a confined aquifer following multiple earthquakes. By employing tidal analysis and a coupled temperature and flow rate model, we find that post-seismic vertical permeability changes and recharge model could explain the co-seismic response. And co-seismic temperature changes are caused by mixing of different volumes of water, with the mixing ratio varying according to each earthquake.
Xiaoying Zhang, Fan Dong, Guangquan Chen, and Zhenxue Dai
Hydrol. Earth Syst. Sci., 27, 83–96, https://doi.org/10.5194/hess-27-83-2023, https://doi.org/10.5194/hess-27-83-2023, 2023
Short summary
Short summary
In a data-driven framework, groundwater levels can generally only be calculated 1 time step ahead. We discuss the advance prediction with longer forecast periods rather than single time steps by constructing a model based on a temporal convolutional network. Model accuracy and efficiency were further compared with an LSTM-based model. The two models derived in this study can help people cope with the uncertainty of what might occur in hydrological scenarios under the threat of climate change.
Dimitri Rambourg, Raphaël Di Chiara, and Philippe Ackerer
Hydrol. Earth Syst. Sci., 26, 6147–6162, https://doi.org/10.5194/hess-26-6147-2022, https://doi.org/10.5194/hess-26-6147-2022, 2022
Short summary
Short summary
The reproduction of flows and contaminations underground requires a good estimation of the parameters of the geological environment (mainly permeability and porosity), in three dimensions. While most researchers rely on geophysical methods, which are costly and difficult to implement in the field, this study proposes an alternative using data that are already widely available: piezometric records (monitoring of the water table) and the lithological description of the piezometric wells.
Raphael Schneider, Julian Koch, Lars Troldborg, Hans Jørgen Henriksen, and Simon Stisen
Hydrol. Earth Syst. Sci., 26, 5859–5877, https://doi.org/10.5194/hess-26-5859-2022, https://doi.org/10.5194/hess-26-5859-2022, 2022
Short summary
Short summary
Hydrological models at high spatial resolution are computationally expensive. However, outputs from such models, such as the depth of the groundwater table, are often desired in high resolution. We developed a downscaling algorithm based on machine learning that allows us to increase spatial resolution of hydrological model outputs, alleviating computational burden. We successfully applied the downscaling algorithm to the climate-change-induced impacts on the groundwater table across Denmark.
Luca Guillaumot, Laurent Longuevergne, Jean Marçais, Nicolas Lavenant, and Olivier Bour
Hydrol. Earth Syst. Sci., 26, 5697–5720, https://doi.org/10.5194/hess-26-5697-2022, https://doi.org/10.5194/hess-26-5697-2022, 2022
Short summary
Short summary
Recharge, defining the renewal rate of groundwater resources, is difficult to estimate at basin scale. Here, recharge variations are inferred from water table variations recorded in boreholes. First, results show that aquifer-scale properties controlling these variations can be inferred from boreholes. Second, groundwater is recharged by both intense and seasonal rainfall. Third, the short-term contribution appears overestimated in recharge models and depends on the unsaturated zone thickness.
Alberto Casillas-Trasvina, Bart Rogiers, Koen Beerten, Laurent Wouters, and Kristine Walraevens
Hydrol. Earth Syst. Sci., 26, 5577–5604, https://doi.org/10.5194/hess-26-5577-2022, https://doi.org/10.5194/hess-26-5577-2022, 2022
Short summary
Short summary
Heat in the subsurface can be used to characterize aquifer flow behaviour. The temperature data obtained can be useful for understanding the groundwater flow, which is of particular importance in waste disposal studies. Satellite images of surface temperature and a temperature–time curve were implemented in a heat transport model. Results indicate that conduction plays a major role in the aquifer and support the usefulness of temperature measurements.
Tunde Olarinoye, Tom Gleeson, and Andreas Hartmann
Hydrol. Earth Syst. Sci., 26, 5431–5447, https://doi.org/10.5194/hess-26-5431-2022, https://doi.org/10.5194/hess-26-5431-2022, 2022
Short summary
Short summary
Analysis of karst spring recession is essential for management of groundwater. In karst, recession is dominated by slow and fast components; separating these components is by manual and subjective approaches. In our study, we tested the applicability of automated streamflow recession extraction procedures for a karst spring. Results showed that, by simple modification, streamflow extraction methods can identify slow and fast components: derived recession parameters are within reasonable ranges.
Min Lu, Bart Rogiers, Koen Beerten, Matej Gedeon, and Marijke Huysmans
Hydrol. Earth Syst. Sci., 26, 3629–3649, https://doi.org/10.5194/hess-26-3629-2022, https://doi.org/10.5194/hess-26-3629-2022, 2022
Short summary
Short summary
Lowland rivers and shallow aquifers are closely coupled. We study their interactions here using a combination of impulse response modeling and hydrological data analysis. The results show that the lowland catchments are groundwater dominated and that the hydrological system from precipitation impulse to groundwater inflow response is a very fast response regime. This study also provides an alternative method to estimate groundwater inflow to rivers from the perspective of groundwater level.
Zhongxia Li, Junwei Wan, Tao Xiong, Hongbin Zhan, Linqing He, and Kun Huang
Hydrol. Earth Syst. Sci., 26, 3359–3375, https://doi.org/10.5194/hess-26-3359-2022, https://doi.org/10.5194/hess-26-3359-2022, 2022
Short summary
Short summary
Four permeable rocks with different pore sizes were considered to provide experimental evidence of Forchheimer flow and the transition between different flow regimes. The mercury injection technique was used to measure the pore size distribution, which is an essential factor for determining the flow regime, for four permeable stones. Finally, the influences of porosity and particle size on the Forchheimer coefficients were discussed.
Andreas Wunsch, Tanja Liesch, Guillaume Cinkus, Nataša Ravbar, Zhao Chen, Naomi Mazzilli, Hervé Jourde, and Nico Goldscheider
Hydrol. Earth Syst. Sci., 26, 2405–2430, https://doi.org/10.5194/hess-26-2405-2022, https://doi.org/10.5194/hess-26-2405-2022, 2022
Short summary
Short summary
Modeling complex karst water resources is difficult enough, but often there are no or too few climate stations available within or close to the catchment to deliver input data for modeling purposes. We apply image recognition algorithms to time-distributed, spatially gridded meteorological data to simulate karst spring discharge. Our models can also learn the approximate catchment location of a spring independently.
Brian Berkowitz
Hydrol. Earth Syst. Sci., 26, 2161–2180, https://doi.org/10.5194/hess-26-2161-2022, https://doi.org/10.5194/hess-26-2161-2022, 2022
Short summary
Short summary
Extensive efforts have focused on quantifying conservative chemical transport in geological formations. We assert that an explicit accounting of temporal information, under uncertainty, in addition to spatial information, is fundamental to an effective modeling formulation. We further assert that efforts to apply chemical transport equations at large length scales, based on measurements and model parameter values relevant to significantly smaller length scales, are an unattainable
holy grail.
Guilherme E. H. Nogueira, Christian Schmidt, Daniel Partington, Philip Brunner, and Jan H. Fleckenstein
Hydrol. Earth Syst. Sci., 26, 1883–1905, https://doi.org/10.5194/hess-26-1883-2022, https://doi.org/10.5194/hess-26-1883-2022, 2022
Short summary
Short summary
In near-stream aquifers, mixing between stream water and ambient groundwater can lead to dilution and the removal of substances that can be harmful to the water ecosystem at high concentrations. We used a numerical model to track the spatiotemporal evolution of different water sources and their mixing around a stream, which are rather difficult in the field. Results show that mixing mainly develops as narrow spots, varying In time and space, and is affected by magnitudes of discharge events.
Jacques Bodin, Gilles Porel, Benoît Nauleau, and Denis Paquet
Hydrol. Earth Syst. Sci., 26, 1713–1726, https://doi.org/10.5194/hess-26-1713-2022, https://doi.org/10.5194/hess-26-1713-2022, 2022
Short summary
Short summary
Assessment of the karst network geometry is an important challenge in the accurate modeling of karst aquifers. In this study, we propose an approach for the identification of effective three-dimensional discrete karst conduit networks conditioned on tracer tests and geophysical data. The applicability of the proposed approach is illustrated through a case study at the Hydrogeological Experimental Site in Poitiers, France.
Zexuan Xu, Rebecca Serata, Haruko Wainwright, Miles Denham, Sergi Molins, Hansell Gonzalez-Raymat, Konstantin Lipnikov, J. David Moulton, and Carol Eddy-Dilek
Hydrol. Earth Syst. Sci., 26, 755–773, https://doi.org/10.5194/hess-26-755-2022, https://doi.org/10.5194/hess-26-755-2022, 2022
Short summary
Short summary
Climate change could change the groundwater system and threaten water supply. To quantitatively evaluate its impact on water quality, numerical simulations with chemical and reaction processes are required. With the climate projection dataset, we used the newly developed hydrological and chemical model to investigate the movement of contaminants and assist the management of contamination sites.
Esther Brakkee, Marjolein H. J. van Huijgevoort, and Ruud P. Bartholomeus
Hydrol. Earth Syst. Sci., 26, 551–569, https://doi.org/10.5194/hess-26-551-2022, https://doi.org/10.5194/hess-26-551-2022, 2022
Short summary
Short summary
Periods of drought often lead to groundwater shortages in large regions, which cause damage to nature and the economy. To take measures, we need a good understanding of where and when groundwater shortage occurs. In this study, we have tested a method that can combine large amounts of groundwater measurements in an automated way and provide detailed maps of how groundwater shortages develop during a drought period. This information can help water managers to limit future groundwater shortages.
Emmanuel Dubois, Marie Larocque, Sylvain Gagné, and Guillaume Meyzonnat
Hydrol. Earth Syst. Sci., 25, 6567–6589, https://doi.org/10.5194/hess-25-6567-2021, https://doi.org/10.5194/hess-25-6567-2021, 2021
Short summary
Short summary
This work demonstrates the relevance of using a water budget model to understand long-term transient and regional-scale groundwater recharge (GWR) in cold and humid climates where groundwater observations are scarce. Monthly GWR is simulated for 57 years on 500 m x 500 m cells in Canada (36 000 km2 area) with limited uncertainty due to a robust automatic calibration method. The increases in precipitation and temperature since the 1960s have not yet produced significant changes in annual GWR.
Yaniv Edery, Martin Stolar, Giovanni Porta, and Alberto Guadagnini
Hydrol. Earth Syst. Sci., 25, 5905–5915, https://doi.org/10.5194/hess-25-5905-2021, https://doi.org/10.5194/hess-25-5905-2021, 2021
Short summary
Short summary
The interplay between dissolution, precipitation and transport is widely encountered in porous media, from CO2 storage to cave formation in carbonate rocks. We show that dissolution occurs along preferential flow paths with high hydraulic conductivity, while precipitation occurs at locations close to yet separated from these flow paths, thus further funneling the flow and changing the probability density function of the transport, as measured on the altered conductivity field at various times.
Karina Y. Gutierrez-Jurado, Daniel Partington, and Margaret Shanafield
Hydrol. Earth Syst. Sci., 25, 4299–4317, https://doi.org/10.5194/hess-25-4299-2021, https://doi.org/10.5194/hess-25-4299-2021, 2021
Short summary
Short summary
Understanding the hydrologic cycle in semi-arid landscapes includes knowing the physical processes that govern where and why rivers flow and dry within a given catchment. To gain this understanding, we put together a conceptual model of what processes we think are important and then tested that model with numerical analysis. The results broadly confirmed our hypothesis that there are three distinct regions in our study catchment that contribute to streamflow generation in quite different ways.
Natascha Brandhorst, Daniel Erdal, and Insa Neuweiler
Hydrol. Earth Syst. Sci., 25, 4041–4059, https://doi.org/10.5194/hess-25-4041-2021, https://doi.org/10.5194/hess-25-4041-2021, 2021
Short summary
Short summary
We compare two approaches for coupling a 2D groundwater model with multiple 1D models for the unsaturated zone. One is non-iterative and very fast. The other one is iterative and involves a new way of treating the specific yield, which is crucial for obtaining a consistent solution in both model compartments. Tested on different scenarios, this new method turns out to be slower than the non-iterative approach but more accurate and still very efficient compared to fully integrated 3D model runs.
Vince P. Kaandorp, Hans Peter Broers, Ype van der Velde, Joachim Rozemeijer, and Perry G. B. de Louw
Hydrol. Earth Syst. Sci., 25, 3691–3711, https://doi.org/10.5194/hess-25-3691-2021, https://doi.org/10.5194/hess-25-3691-2021, 2021
Short summary
Short summary
We reconstructed historical and present-day tritium, chloride, and nitrate concentrations in stream water of a catchment using
land-use-based input curves and calculated travel times of groundwater. Parameters such as the unsaturated zone thickness, mean travel time, and input patterns determine time lags between inputs and in-stream concentrations. The timescale of the breakthrough of pollutants in streams is dependent on the location of pollution in a catchment.
Yueling Ma, Carsten Montzka, Bagher Bayat, and Stefan Kollet
Hydrol. Earth Syst. Sci., 25, 3555–3575, https://doi.org/10.5194/hess-25-3555-2021, https://doi.org/10.5194/hess-25-3555-2021, 2021
Short summary
Short summary
This study utilized spatiotemporally continuous precipitation anomaly (pra) and water table depth anomaly (wtda) data from integrated hydrologic simulation results over Europe in combination with Long Short-Term Memory (LSTM) networks to capture the time-varying and time-lagged relationship between pra and wtda in order to obtain reliable models to estimate wtda at the individual pixel level.
Raoul A. Collenteur, Mark Bakker, Gernot Klammler, and Steffen Birk
Hydrol. Earth Syst. Sci., 25, 2931–2949, https://doi.org/10.5194/hess-25-2931-2021, https://doi.org/10.5194/hess-25-2931-2021, 2021
Short summary
Short summary
This study explores the use of nonlinear transfer function noise (TFN) models to simulate groundwater levels and estimate groundwater recharge from observed groundwater levels. A nonlinear recharge model is implemented in a TFN model to compute the recharge. The estimated recharge rates are shown to be in good agreement with the recharge observed with a lysimeter present at the case study site in Austria. The method can be used to obtain groundwater recharge rates at
sub-yearly timescales.
Franci Gabrovšek and Wolfgang Dreybrodt
Hydrol. Earth Syst. Sci., 25, 2895–2913, https://doi.org/10.5194/hess-25-2895-2021, https://doi.org/10.5194/hess-25-2895-2021, 2021
Short summary
Short summary
The evolution of karst aquifers is often governed by solutions gaining their aggressiveness in depth. Although the principles of
hypogene speleogenesisare known, modelling studies based on reactive flow in fracture networks are missing. We present a model where dissolution at depth is triggered by the mixing of waters of different origin and chemistry. We show how the initial position of the mixing zone and flow instabilities therein determine the position and shape of the final conduits.
Patrick Morrissey, Paul Nolan, Ted McCormack, Paul Johnston, Owen Naughton, Saheba Bhatnagar, and Laurence Gill
Hydrol. Earth Syst. Sci., 25, 1923–1941, https://doi.org/10.5194/hess-25-1923-2021, https://doi.org/10.5194/hess-25-1923-2021, 2021
Short summary
Short summary
Lowland karst aquifers provide important wetland habitat resulting from seasonal flooding on the land surface. This flooding is controlled by surcharging of the karst system, which is very sensitive to changes in rainfall. This study investigates the predicted impacts of climate change on a lowland karst catchment in Ireland and highlights the relative vulnerability to future changing climate conditions of karst systems and any associated wetland habitats.
Liwen Wu, Jesus D. Gomez-Velez, Stefan Krause, Anders Wörman, Tanu Singh, Gunnar Nützmann, and Jörg Lewandowski
Hydrol. Earth Syst. Sci., 25, 1905–1921, https://doi.org/10.5194/hess-25-1905-2021, https://doi.org/10.5194/hess-25-1905-2021, 2021
Short summary
Short summary
With a physically based model that couples flow and heat transport in hyporheic zones, the present study provides the first insights into the dynamics of hyporheic responses to the impacts of daily groundwater withdrawal and river temperature fluctuations, allowing for a better understanding of transient hyporheic exchange processes and hence an improved pumping operational scheme.
Andreas Wunsch, Tanja Liesch, and Stefan Broda
Hydrol. Earth Syst. Sci., 25, 1671–1687, https://doi.org/10.5194/hess-25-1671-2021, https://doi.org/10.5194/hess-25-1671-2021, 2021
Jost Hellwig, Michael Stoelzle, and Kerstin Stahl
Hydrol. Earth Syst. Sci., 25, 1053–1068, https://doi.org/10.5194/hess-25-1053-2021, https://doi.org/10.5194/hess-25-1053-2021, 2021
Short summary
Short summary
Potential future groundwater and baseflow drought hazards depend on systems' sensitivity to altered recharge conditions. With three generic scenarios, we found different sensitivities across Germany driven by hydrogeology. While changes in drought hazard due to seasonal recharge shifts will be rather low, a lengthening of dry spells could cause stronger responses in regions with slow groundwater response to precipitation, urging local water management to prepare for more severe droughts.
Martin J. Wells, Troy E. Gilmore, Natalie Nelson, Aaron Mittelstet, and John K. Böhlke
Hydrol. Earth Syst. Sci., 25, 811–829, https://doi.org/10.5194/hess-25-811-2021, https://doi.org/10.5194/hess-25-811-2021, 2021
Short summary
Short summary
Groundwater in many agricultural areas contains high levels of nitrate, which is a concern for drinking water supplies. The rate at which nitrate moves through the subsurface is a critical piece of information for predicting how quickly groundwater nitrate levels may improve after agricultural producers change their approach to managing crop water and fertilizers. In this study, we explored a new statistical modeling approach to determine rates at which nitrate moves into and through an aquifer.
Cited articles
AGE: Guidelines for the designation of groundwater protection zones (Leitfaden für die Ausweisung von Grundwasserschutzzonen), AGE – Administration de la Gestion de l'Eau, https://eau.gouvernement.lu/dam-assets/eaux-souterraines/documents/ZPS-DOC-1-Leitfaden-Schutzzonen.pdf (last access: 28 April 2023), 2010.
AGE: Management plan for the international river basin districts Rhine and Meuse on Luxembourger territory 2015–2021 (Plan de gestion pour les parties des districts hydrographiques internationaux Rhin et Meuse situées sur territoire luxembourgeois 2015–2021), AGE – Administration de la Gestion de l'Eau, http://geoportail.eau.etat.lu/pdf/plan de gestion/FR/2e plan de gestion pour le Luxembourg (2015-2021)_22.12.2015.pdf (last access: 28 April 2023), 2015.
Al-Jaf, P., Smith, M., and Gunzel, F.: Unsaturated Zone Flow Processes and Aquifer Response Time in the Chalk Aquifer, Brighton, South East England, Groundwater, 59, 381–395, https://doi.org/10.1111/gwat.13055, 2021.
Allen, R. G., Pereira, L. S., Raes, D., and Smith, M.: Crop evapotranspiration – Guidelines for computing crop water requirements. FAO Irrigation and Drainage Paper 56, Food and Agriculture Organization of the United Nations, Rome, Italy, https://www.fao.org/4/x0490e/x0490e00.htm (last access: 6 June 2024), 1998.
Angelini, P.: Correlation and spectral analysis of two hydrogeological systems in central Italy, Hydrolog. Sci. J., 4, 425–438, https://doi.org/10.1080/02626669709492038, 1997.
Balvín, A., Hokr, M., Šteklová, K., and Rálek, P.: Inverse modeling of natural tracer transport in a granite massif with lumped-parameter and physically based models: case study of a tunnel in Czechia, Hydrogeol. J., 29, 2633–2654, https://doi.org/10.1007/s10040-021-02389-x, 2021.
Berg, D.: Fractures in the Paleozoic and Mesozoic deposits of Luxembourg and the western Eifel: its relations with the general tectonics and their influence on the river network (Die Klüfte im Paläozoikum und Mesozoikum von Luxemburg und der westlichen Eifel: ihre Beziehungen zur allgemeinen Tektonik und ihr Einfluß auf das Gewässernetz), Publ. Serv. Geol., Luxembourg, p. 89, https://geologie.lu/index.php/telechargements/send/6-publications-sgl-volumes/503-v16 (last access: 10 June 2024), 1965.
Berners, H. P.: A lower Liassic offshore bar environment, contribution to the sedimentology of the Luxemburg Sandstone, Annales de la société Géologique de Belgique, 10, 87–102, https://popups.uliege.be/0037-9395/index.php?id=3104&file=1&pid=3102 (last access: 4 March 2024), 1983.
Bethke, C. M. and Johnson, T. M.: Groundwater Age and Groundwater Age Dating, Annu. Rev. Earth Planet. Sci., 36, 121–152, https://doi.org/10.1146/annurev.earth.36.031207.124210, 2008.
Beven, K. and Binley, A.: The future of distributed models: Model calibration and uncertainty prediction, Hydrol. Process., 6, 279–298, https://doi.org/10.1002/hyp.3360060305, 1992.
Beven, K. and Binley, A.: GLUE: 20 years on, Hydrol. Process., 28, 5897–5918, https://doi.org/10.1002/hyp.10082, 2014.
Beyer, M., Morgenstern, U., and Jackson, B.: Review of techniques for dating young groundwater (<100 years) in New Zealand, J. Hydrol. (NZ), 53, 93–111, 2014.
Bintz, J. and Muller, A.: On the representation of the Luxembourg Sandstone on the new general geological map of the Grand-Duchy (Sur la représentation du Grès de Luxembourg sur la nouvelle carte géologique générale du Grand-Duché), Arch. Inst. Grand-ducal Luxemb. Sect. Sci. Nat. Phys. Math., 31, 241–258, 1965.
Blavoux, B., Lachassagne, P., Henriot, A., Ladouche, B., Marc, V., Beley, J. J., Nicoud, G., and Olive, P.: A fifty-year chronicle of tritium data for characterising the functioning of the Evian and Thonon (France) glacial aquifers, J. Hydrol., 494, 116–133, https://doi.org/10.1016/j.jhydrol.2013.04.029, 2013.
Bloomfield, J. P. and Marchant, B. P.: Analysis of groundwater drought building on the standardised precipitation index approach, Hydrol. Earth Syst. Sci., 17, 4769–4787, https://doi.org/10.5194/hess-17-4769-2013, 2013.
Bloomfield, J. P., Marchant, B. P., Bricker, S. H., and Morgan, R. B.: Regional analysis of groundwater droughts using hydrograph classification, Hydrol. Earth Syst. Sci., 19, 4327–4344, https://doi.org/10.5194/hess-19-4327-2015, 2015.
Bohn, T., Cocco, E., Gourdol, L., Guignard, C., and Hoffmann, L.: Determination of atrazine and degradation products in Luxembourgish drinking water: origin and fate of potential endocrine-disrupting pesticides, Food Addit. Contam. Pt. A, 28, 1041–1054, https://doi.org/10.1080/19440049.2011.580012, 2011.
Boulvain, F., Belanger, I., Delsate, D., Dosquet, D., Ghysel, P., Godefroit, P., Laloux, M., Roche, M., Teerlinck, H., and Thorez, J.: New lithostratigraphical, sedimentological, mineralogical and paleontological data on the Mesozoic of the Belgian Lorraine, Geologica Belgic, 3, 3–33, https://doi.org/10.20341/gb.2014.021, 2000.
Boulvain, F., Belanger, I., Delsate, D., Ghysel, P., Godefroit, P., Laloux, M., Monteyne, R., and Roche, M.: Triassic and Jurassic lithostratigraphic units (Belgian Lorraine), Geologica Belgica, 4, 113–119, https://doi.org/10.20341/gb.2014.048, 2001.
Box, G. E. P., Jenkins, G. M., Reinsel, G. C., and Ljung G. M.: Time Series Analysis: Forecasting and Control, in: 5th Edn., Wiley, Hoboken, NJ, USA, ISBN 978-1-118-67502-1, 2015.
Busenberg, E., Plummer, L. N., Cook, P. G., Solomon, D. K., Han, L .F., Gröning, M., and Oster, H.: Sampling and analytical methods, in: Use of Chlorofluorocarbons in Hydrology: A Guidebook, IAEA, Vienna, 199–220, http://www-pub.iaea.org/MTCD/publications/pdf/Pub1238_web.pdf (last access: 28 April 2023), 2006.
Cai, Z. and Ofterdinger, U.: Analysis of groundwater-level response to rainfall and estimation of annual recharge in fractured hard rock aquifers, NW Ireland, J. Hydrol., 535, 71–84, https://doi.org/10.1016/j.jhydrol.2016.01.066, 2016.
Cammeraat, L. H., Sevink, J., Hissler, C., Juilleret, J., Jansen, B., Kooijman, A. M., Pfister, L., and Verstraten, J. M.: Soils of the Luxembourg Lias cuesta landscape, in: The Luxembourg Gutland Landscape, edited by: Kooijman, A. M., Cammeraat, L. H., and Seijmonsbergen, A. C., Springer, 107–130, https://doi.org/10.1007/978-3-319-65543-7_6, 2017.
Cartwright, I., Cendón, D., Currell, M., and Meredith, K.: A review of radioactive isotopes and other residence time tracers in understanding groundwater recharge: Possibilities, challenges, and limitations, J. Hydrol., 555, 797–811, https://doi.org/10.1016/j.jhydrol.2017.10.053, 2017.
Cartwright, I., Morgenstern, U., Howcroft, W., Hofmann, H., Armit, R., Stewart, M., and Irvine, D.: The variation and controls of mean transit times in Australian headwater catchments, Hydrol. Process., 34, 4034–4048, https://doi.org/10.1002/hyp.13862, 2020.
Cauquoin, A., Jean-Baptiste, P., Risi, C., Fourré, E., Stenni, B., and Landais, A.: The global distribution of natural tritium in precipitation simulated with an Atmospheric General Circulation Model and comparison with observations, Earth Planet. Sc. Lett., 427, 160–170, https://doi.org/10.1016/j.epsl.2015.06.043, 2015.
Claes, S., Nader, F. H., and Youssef, S.: Coupled experimental/numerical workflow for assessing quantitative diagenesis and dynamic porosity/permeability evolution in calcite-cemented sandstone reservoir rocks, Oil Gas Sci. Technol., 73, 36, https://doi.org/10.2516/ogst/2018027, 2018.
Clavaud, J. B., Maineult, A., Zamora, M., Rasolofosaon, P., and Schlitter, C.: Permeability anisotropy and its relations with porous medium structure, J. Geophys. Res., 113, B01202, https://doi.org/10.1029/2007JB005004, 2008.
Colbach, R.: Overview of the geology of the Luxembourg Sandstone(s), in: Proceedings of the 2nd International Conference on Sandstone Landscapes, Ferrantia, 44, edited by: Ries, C. and Krippel, Y., 155–160, https://ps.mnhn.lu/ferrantia/publications/Ferrantia44.pdf (last access: 28 April 2023), 2005.
Cook, P. G. and Solomon, D. K.: Recent advances in dating young groundwater: chlorofluorocarbons, 3H3He and 85Kr, J. Hydrol., 191, 245–265, https://doi.org/10.1016/S0022-1694(96)03051-X, 1997.
Delbart, C., Valdes, D., Barbecot, F., Tognelli, A., Richon, P., and Couchoux, L.: Temporal variability of karst aquifer response time established by the sliding-windows cross-correlation method, J. Hydrol., 511, 580–588, https://doi.org/10.1016/j.jhydrol.2014.02.008, 2014.
Dotto, C. B. S., Mannina, G., Kleidorfer, M., Vezzaro, L., Henrichs, M., McCarthy, D. T., Freni, G., Rauch, W., and Deletic, A.: Comparison of different uncertainty techniques in urban stormwater quantity and quality modelling, Water Res., 46, 2545–2558, https://doi.org/10.1016/j.watres.2012.02.009, 2012.
Duvert, C., Stewart, M. K., Cendón, D. I., and Raiber, M.: Time series of tritium, stable isotopes and chloride reveal short-term variations in groundwater contribution to a stream, Hydrol. Earth Syst. Sci., 20, 257–277, https://doi.org/10.5194/hess-20-257-2016, 2016.
Eastoe, C. J., Watts, C. J., Ploughe, M., and Wright, W. E.: Future use of tritium in mapping pre-bomb groundwater volumes, Groundwater, 50, 87–93, https://doi.org/10.1111/j.1745-6584.2011.00806.x, 2012.
Eberts, S. M., Böhlke, J. K., Kauffman, L. J., and Jurgens, B. C.: Comparison of particle-tracking and lumped-parameter age-distribution models for evaluating vulnerability of production wells to contamination, Hydrogeol. J., 20, 263–282, https://doi.org/10.1007/s10040-011-0810-6, 2012.
Edmunds, W. M. and Shand, P. (Eds.): Natural groundwater quality – Summary and significance for water resources management, in: Natural Groundwater Quality, Blackwell, London, 441–462, https://doi.org/10.1002/9781444300345.ch21, 2009.
Edmunds, W. M. and Smedley, P. L.: Residence time indicators in groundwater: the East Midlands Triassic sandstone aquifer, Appl. Geochem., 15, 737–752, https://doi.org/10.1016/S0883-2927(99)00079-7, 2000.
Einsiedl, F.: Flow system dynamics and water storage of a fissured-porous karst aquifer characterized by artificial and environmental tracers, J. Hydrol., 312, 312–321, https://doi.org/10.1016/j.jhydrol.2005.03.031, 2005.
Faber, A. and Weis, R.: The Luxembourg Sandstone. Scientific and patrimonial importance of its fossiliderous sites, in: Proceedings of the 2nd International Conference on Sandstone Landscapes, Ferrantia, 44, edited by: Ries, C. and Krippel, Y., 161–164, https://ps.mnhn.lu/ferrantia/publications/Ferrantia44.pdf (last access: 28 April 2023), 2005.
Farlin, J., Gallé, T., Bayerle, M., Pittois, D., Braun, C., El Khabbaz, H., Elsner, M., and Maloszewski, P.: Predicting Pesticide Attenuation in a Fractured Aquifer Using Lumped-Parameter Models, Groundwater, 51, 276–285, https://doi.org/10.1111/j.1745-6584.2012.00964.x, 2013a.
Farlin, J., Drouet, L., Gallé, T., Pittois, D., Bayerle, M., Braun, C., Maloszewski, P., Vandenborght, J., Elsner, M., and Kies, A.: Delineating spring recharge areas in a fractured sandstone aquifer (Luxembourg) based on pesticide mass balance, Hydrogeol. J., 21, 799–812, https://doi.org/10.1007/s10040-013-0964-5, 2013b.
Farlin, J., Bayerle, M., Pittois, D., and Gallé, T.: Estimating Pesticide Attenuation From Water Dating and the Ratio of Metabolite to Parent Compound, Groundwater, 55, 550–557, https://doi.org/10.1111/gwat.12499, 2017.
Farlin, J., Gallé, T., Bayerle, M., Pittois, D., Köppchen, S., Krause, M., and Hofmann, D.: Breakthrough dynamics of S-Metolachlor metabolites in drinkingwater wells: transport pathways and time to trend reversal, J. Contam. Hydrol., 213, 62–72, https://doi.org/10.1016/j.jconhyd.2018.05.002, 2018.
Farlin, J., Gallé, T., Pittois, D., Bayerle, M., and Schaul, T.: Groundwater quality monitoring network design and optimisation based on measured contaminant concentration and taking solute transit time into account, J. Hydrol., 573, 516–523, https://doi.org/10.1016/j.jhydrol.2019.01.067, 2019.
Fiorillo, F. and Doglioni, A.: The relation between karst spring discharge and rainfall by cross-correlation analysis (Campania, Southern Italy), Hydrogeol. J., 18, 1881–1895, https://doi.org/10.1007/s10040-010-0666-1, 2010.
Fox, R., Hauwell, J., and Hick, S.: Tunnel Grouft in Luxembourg: progression by the traditional method and support by application of fiber-reinforced shotcrete (Le tunnel Grouft au Luxembourg: avancement par la méthode traditionnelle et soutènement par application de béton projeté fibré), Tunnels et Ouvrages Souterrains, 208, 271–276, https://www.aftes.fr/fr/product/tunnels-et-ouvrages-souterrains-n-208-juillet-aout-2008/ (last access: 10 June 2024), 2008.
Gallart, F., Roig-Planasdemunt, M., Stewart, M. K., Llorens,P., Morgenstern, U., Stichler, W., Pfister, P., and Latron, J.: A GLUE-based uncertainty assessment framework for tritium-inferred transit time estimations under baseflow conditions, Hydrol. Process., 30, 4741–4760, https://doi.org/10.1002/hyp.10991, 2016.
Gerber, C., Purtschert, R., Hunkeler, D., Hug, R., and Sültenfuss, J.: Using environmental tracers to determine the relative importance of travel times in the unsaturated and saturated zones for the delay of nitrate reduction measures, J. Hydrol., 561, 250–266, https://doi.org/10.1016/j.jhydrol.2018.03.043, 2018.
Gleeson, T., Befus, K., Jasechko, S., Luijendijk, E., and Bayani Cardenas, M.: The global volume and distribution of modern groundwater, Nat. Geosci., 9, 161–167, https://doi.org/10.1038/s41561-018-0164-y, 2016.
Goupil, M., Heap, M. J., and Baud, P.: Permeability anisotropy in sandstones from the Soultz-sous-Forêts geothermal reservoir (France): implications for large-scale fluid flow modelling, Geoth. Energy, 10, 32, https://doi.org/10.1186/s40517-022-00243-1, 2022.
Gourdol, L., Hissler, C., Hoffmann, L., and Pfister, L.: On the potential for the Partial Triadic Analysis to grasp the spatio-temporal variability of groundwater hydrochemistry, Appl. Geochem., 39, 93–107, https://doi.org/10.1016/j.apgeochem.2013.10.002, 2013.
Gourdol, L., Stewart, M. K., Morgenstern, U., and Pfister, L.: Code and data for: Short high-accuracy tritium data time series for assessing groundwater mean transit times in the vadose and saturated zones of the Luxembourg Sandstone aquifer, Zenodo [code and data set], https://doi.org/10.5281/zenodo.11506262, 2024.
Gusyev, M. A., Morgenstern, U., Stewart, M. K., Yamazaki, Y., Kashiwaya, K., Nishihara, T., Kuribayashi, D., Sawano, H., and Iwami, Y.: Application of tritium in precipitation and baseflow in Japan: a case study of groundwater transit times and storage in Hokkaido watersheds, Hydrol. Earth Syst. Sci., 20, 3043–3058, https://doi.org/10.5194/hess-20-3043-2016, 2016.
Han, L. F., Gröning, M., Plummer, L. N., and Solomon, D. K.: Comparison of the CFC technique with other techniques (3H, 3H/3He, 85Kr), in: Use of Chlorofluorocarbons in Hydrology: A Guidebook, IAEA, Vienna, 191–198, http://www-pub.iaea.org/MTCD/publications/pdf/Pub1238_web.pdf (last access: 28 April 2023), 2006.
Hissler, C. and Gourdol, L.: Assessment of soil maximum water-holding capacity in Luxembourg at national scale: a first estimate based on recent datasets (Évaluation de la réserve utile maximale en eau des sols au Luxembourg à l'échelle nationale : une première estimation basée sur des jeux de données récents), Report drafted on behalf of the Administration de la gestion de l'eau, 2015.
Hissler, C., Gourdol, L., Juilleret, J., Marx, S., Leydet, L., and Flammang, F.: Pedotransfer functions for predicting soil hydrological characteristics in Luxembourg: literature review and reliability tests for predicting the soil maximum water-holding capacity (Fonctions de pédotransfert pour la prédiction des caractéristiques hydriques des sols au Luxembourg : analyse bibliographique et premiers tests de fiabilité pour la prédiction de la réserve utilisable maximale des sols), Report drafted on behalf of the Administration des services techniques de l'agriculture, 2015.
Hitchmough, A. M., Riley, M. S., Herbert, A. W., and Tellam, J. H.: Estimating the hydraulic properties of the fracture network in a sandstone aquifer, J. Contam. Hydrol., 93, 38–57, https://doi.org/10.1016/j.jconhyd.2007.01.012, 2007.
IAEA and WMO: Global Network of Isotopes in Precipitation, The GNIP Database, https://nucleus.iaea.org/wiser (last access: 15 July 2021), 2019.
Jasechko, S.: Partitioning young and old groundwater with geochemical tracers, Chem. Geol., 427, 35–42, https://doi.org/10.1016/j.chemgeo.2016.02.012, 2016.
Jasechko, S.: Global isotope hydrogeology – review, Rev. Geophys., 57, 835–965, https://doi.org/10.1029/2018RG000627, 2019.
Jemcov, I. and Petric, M.: Measured precipitation vs effective infiltration and their influence on the assessment of karst systems based on results of the time series analysis, J. Hydrol., 379, 304–314, https://doi.org/10.1016/j.jhydrol.2009.10.016, 2009.
Jeong, J., Park, E., Han, W. S., Kim, K. Y., Oh, J., Ha, K., Yoon, H., and Yun, S. T.: A method of estimating sequential average unsaturated zone travel times from precipitation and water table level time series data, J. Hydrol., 554, 570–581, https://doi.org/10.1016/j.jhydrol.2017.09.042, 2017.
Jerbi, H., Hamdi, M., Snoussi, M., Benabdelmalek, M., Jnoub, H., and Tarhouni, J.: Usefulness of historical measurements of tritium content in groundwater for recharge assessment in semi-arid regions: application to several aquifers in central Tunisia, Hydrogeol. J., 27, 1645–1660, https://doi.org/10.1007/s10040-019-01937-w, 2019.
Jurgens, B. C., Bohlke, J. K., and Eberts, S. M.: TracerLPM (Version 1): An Excel® workbook for interpreting groundwater age distributions from environmental tracer data, US Geological Survey Techniques and Methods Report 4-F3, US Geological Survey, Reston, USA, 60 pp., https://pubs.usgs.gov/tm/4-f3/pdf/tm4-F3.pdf (last access: 10 June 2024), 2019.
Katz, B. G., Chelette, A. R., and Pratt, T. R.: Use of chemical and isotopic tracers to assess nitrate contamination and ground-water age, Woodville Karst Plain, USA, J. Hydrol., 289, 36–61, https://doi.org/10.1016/j.jhydrol.2003.11.001, 2004.
Kausch, B. and Maquil, R.: Geological and geomorphological evolution of Luxembourg and its cuesta landscape, in: The Luxembourg Gutland Landscape, edited by: Kooijman, A. M., Cammeraat, L. H., and Seijmonsbergen, A. C., Springer, 1–19, https://doi.org/10.1007/978-3-319-65543-7_1, 2017.
Lal, D. and Peters, B.: Cosmic ray produced radioactivity on the earth, in: Encyclopedia of Physics, vol. 46, edited by: Flugge, S., Springer, New York, 407–434, https://doi.org/10.1007/978-3-642-46079-1_7, 1967.
Lanini, S., Caballero, Y., Seguin, J. J., and Maréchal, J.C.: ESPERE – A Multiple-Method Microsoft Excel Application for Estimating Aquifer Recharge, Groundwater, 54, 155–156, https://doi.org/10.1111/gwat.12390, 2016.
Larocque, M., Mangin, A., Razack, M., and Banton O.: Contribution of correlation and spectral analyses to the regional study of a large karst aquifer (Charente, France), J. Hydrol., 205, 217–231, https://doi.org/10.1016/S0022-1694(97)00155-8, 1998.
Lauber, U. and Goldscheider, N.: Use of artificial and natural tracers to assess groundwater transit-time distribution and flow systems in a high-alpine karst system (Wetterstein Mountains, Germany), Hydrogeol. J., 22, 1807–1824, https://doi.org/10.1007/s10040-014-1173-6, 2014.
Le Duy, N., Nguyen, T. V. K., Nguyen, D. V., Tran, A. T., Nguyen, H. T., Heidbüchel, I., Merz, B., and Apel, H.: Groundwater dynamics in the Vietnamese Mekong Delta: Trends, memory effects, and response times, J. Hydrol.: Reg. Stud., 33, 100746, https://doi.org/10.1016/j.ejrh.2020.100746, 2021.
Lee, J. Y. and Lee, K. K.: Use of hydrologic time series data for identification of recharge mechanism in a fractured bedrock aquifer system, J. Hydrol., 229, 190–201, https://doi.org/10.1016/S0022-1694(00)00158-X, 2000.
Lee, L. J. E., Lawrence, D. S. L., and Price, M.: Analysis of water-level response to rainfall and implications for recharge pathways in the Chalk aquifer, SE England, J. Hydrol., 330, 604–620, https://doi.org/10.1016/j.jhydrol.2006.04.025, 2006.
Leibundgut, C. and Seibert, J.: Tracer hydrology, in: Treatise on Water Science, edited by: Wilderer, P., Elsevier, Oxford, 215–236, https://doi.org/10.1016/B978-0-444-53199-5.00036-1, 2011.
Leibundgut, C., Maloszewski, P., and Kulls, C.: Tracers in Hydrology, John Wiley & Sons, New York, NY, USA, https://doi.org/10.1002/9780470747148, 2009.
Leray, S., Engdahl, N. B., Massoudieh, A., Bresciani, E., and McCallum, J.: Residence time distributions for hydrologic systems: Mechanistic foundations and steady state analytical solutions, J. Hydrol., 543, 67–87, https://doi.org/10.1016/j.jhydrol.2016.01.068, 2016.
Li, L., Xia, J., Xu, C. Y., and Singh, V. P.: Evaluation of the subjective factors of the GLUE method and comparison with the formal Bayesian method in uncertainty assessment of hydrological models, J. Hydrol., 390, 210–221, https://doi.org/10.1016/j.jhydrol.2010.06.044, 2010.
Libby, W. F.: The Potential Usefulness of Natural Tritium, P. Natl. Acad. Sci. USA, 39, 245–247, https://doi.org/10.1073/pnas.39.4.245, 1953.
Lucas, L. L. and Unterweger, M. P.: Comprehensive Review and Critical Evaluation of the Half-Life of Tritium, J. Res. Natl. Inst. Stand. Technol., 105, 541–549, https://doi.org/10.6028/jres.105.043, 2000.
Luxconsult: Determination of groundwater protection zones for drinking water sources in the municipality of Luxembourg Part 6a – Birelergrund 1–10 (Festlegung der Grundwasserschutzzonen für die Trinkwasserquellen der Gemeinde Luxembourg Teil 6a - Birelergrund 1–10), Study conducted for the General Commissariat for Soil and Water Protection of the Ministry of the Environment, 1992.
MacDonald, A. M., Darling, W. G., Ball, D. F., and Oster, H.: Identifying trends in groundwater quality using residence time indicators: an example from the Permian aquifer of Dumfries, Scotland, Hydrogeol. J., 11, 504–517, https://doi.org/10.1007/s10040-003-0275-3, 2003.
Maier, R., Leven, C., Sánchez-León, E., Strasser, D., Stoll, M., and Cirpka, O.A.: Revealing vertical aquifer heterogeneity and hydraulic anisotropy by pumping partially penetrating wells, Hydrogeol. J., 30, 463–477, https://doi.org/10.1007/s10040-022-02458-9, 2022.
Maloszewski, P. and Zuber, A.: Determining the turnover time of groundwater systems with the aid of environmental tracers: 1. Models and their applicability, J. Hydrol., 57, 207–231, https://doi.org/10.1016/0022-1694(82)90147-0, 1982.
Mammoliti, E., Fronzi, D., Mancini, A., Valigi, D., and Tazioli, A.: WaterbalANce, a WebApp for Thornthwaite – Mather Water Balance Computation: Comparison of Applications in Two European Watersheds, Hydrology, 8, 34, https://doi.org/10.3390/hydrology8010034, 2021.
Mangin, A.: Use of correlation and spectral analysis in the approach of hydrological systems (Utilisation des analyses corrélatoire et spectrale dans l'approche des systèmes hydrologiques), Comptes rendus de l'Académie des Sciences, Paris, Série II, 293, 401–404, 1981a.
Mangin, A.: Contributions of cross-correlation and spectral analysis to the knowledge of hydrological systems (Apports des analyses corrélatoire et spectrale croisées dans la connaissance des systèmes hydrologiques), Comptes rendus de l'Académie des Sciences, Paris, Série II, 293, 1011–1014, 1981b.
Mangin, A.: The use of autocorrelation and spectral analyses to obtain a better understanding of hydrological systems (Pour une meilleure connaissance des systèmes hydrologiques à partir des analyses corrélatoire et spectrale), J. Hydrol., 67, 25-43, https://doi.org/10.1016/0022-1694(84)90230-0, 1984.
Marçais, J., de Dreuzy, J. R., Ginn, T. R., Rousseau-Gueutin, P., and Leray, S.: Inferring transit time distributions from atmospheric tracer data: Assessment of the predictive capacities of Lumped Parameter Models on a 3D crystalline aquifer model, J. Hydrol., 525, 619–631, https://doi.org/10.1016/j.jhydrol.2015.03.055, 2015.
McDonnell, J. J. and Beven, K.: Debates – The future of hydrological sciences: A (common) path forward? A call to action aimed at understanding velocities, celerities, and residence time distributions of the headwater hydrograph, Water Resour. Res., 50, 5342–5350, https://doi.org/10.1002/2013WR015141, 2014.
McGuire, K. J. and McDonnell, J. J.: A review and evaluation of catchment transit time modelling, J. Hydrol., 330, 543–563, https://doi.org/10.1016/j.jhydrol.2006.04.020, 2006.
Meus, P. and Willems, L.: Tracer tests to infer the drainage of the multiple porosity aquifer of Luxembourg Sandstone (Grand-Duchy of Luxembourg): implications for drinking water protection, Hydrogeol. J., 29, 461–480, https://doi.org/10.1007/s10040-020-02274-z, 2021.
Moges, E., Demissie, Y., Larsen, L., and Yassin, F.: Review: Sources of hydrological model uncertainties and advances in their analysis, Water, 13, 28, https://doi.org/10.3390/w13010028, 2021.
Molenaar, N.: Origin of Low-Permeability Calcite-Cemented Lenses in Shallow Marine Sandstones and CaCO3 Cementation Mechanisms: An Example from the Lower Jurassic Luxemburg Sandstone, Luxemburg, Special Publication of the International Association of Sedimentologists, 26, 193–211, https://doi.org/10.1002/9781444304893.ch9, 1998.
Morgenstern, U. and Daughney, C. J.: Groundwater age for identification of baseline groundwater quality and impacts of land use intensification – The National Groundwater Monitoring Programme of New Zealand, J. Hydrol., 456–457, 79–93, https://doi.org/10.1016/j.jhydrol.2012.06.010, 2012.
Morgenstern, U. and Taylor, C. B.: Ultra Low-level tritium measurement using electrolytic enrichment and LSC, Isotop. Environ. Health Stud., 45, 96–117, https://doi.org/10.1080/10256010902931194, 2009.
Morgenstern, U., Stewart, M. K., and Stenger, R.: Dating of streamwater using tritium in a post nuclear bomb pulse world: continuous variation of mean transit time with streamflow, Hydrol. Earth Syst. Sci., 14, 2289–2301, https://doi.org/10.5194/hess-14-2289-2010, 2010.
Morgenstern, U., Daughney, C. J., Leonard, G., Gordon, D., Donath, F. M., and Reeves, R.: Using groundwater age and hydrochemistry to understand sources and dynamics of nutrient contamination through the catchment into Lake Rotorua, New Zealand, Hydrol. Earth Syst. Sci., 19, 803–822, https://doi.org/10.5194/hess-19-803-2015, 2015.
Morishima, H., Kawai, H., Koga, T., and Niwa, T.: The Trends of Global Tritium Precipitations, J. Radiat. Res. 26, 283–312, https://doi.org/10.1269/jrr.26.283, 1985.
Nash, J. and Sutcliffe, J.: River flow forecasting through conceptual models part I – a discussion of principles, J. Hydrol., 10, 282–290, https://doi.org/10.1016/0022-1694(70)90255-6, 1970.
Newman, B. D., Osenbrück, K., Aeschbach-Hertig, W., Solomon, D. K., Cook, P., Różański, K., and Kipfer, R.: Dating of `young' groundwaters using environmental tracers: advantages, applications, and research needs, Isotop. Environ. Health Stud., 46, 259–278, https://doi.org/10.1080/10256016.2010.514339, 2010.
Ozyurt, N. N., Lutz, H. O., Hunjak, T., Mance, D., and Roller-Lutz, Z.: Characterization of the Gacka River basin karst aquifer (Croatia): hydrogeochemistry stable isotopes and tritium-based mean residence times, Sci. Total Environ., 487, 245–254, https://doi.org/10.1016/j.scitotenv.2014.04.018, 2014.
Padilla, A. and Pulido-Bosch, A.: Study of hydrographs of karst aquifers by means of correlation and cross-spectral analysis, J. Hydrol., 168, 73–89, https://doi.org/10.1016/0022-1694(94)02648-U, 1995.
Panagopoulos, G. and Lambrakis, N.: The contribution of time series analysis to the study of the hydrodynamic characteristics of the karst systems: application on two typical karst aquifers of Greece (Trifilia, Almyros Crete), J. Hydrol., 329, 368–376, https://doi.org/10.1016/j.jhydrol.2006.02.023, 2006.
Paradis, D., Ballard, J. M., Lefebvre, R., and Savard, M. M.: Multi-scale nitrate transport in a sandstone aquifer system under intensive agriculture, Hydrogeol. J., 26, 511–531, https://doi.org/10.1007/s10040-017-1668-z, 2018.
Pfister, L., Martínez-Carreras, N., Hissler, C., Klaus, J., Carrer, G. E., Stewart, M. K., and McDonnell, J. J.: Bedrock geology controls on catchment storage, mixing, and release: A comparative analysis of 16 nested catchments, Hydrol. Process., 31, 1828–1845, https://doi.org/10.1002/hyp.11134, 2017.
Purtschert, R.: Timescales and Tracers, in: Natural Groundwater Quality, edited by: Edmunds, W. M. and Shand, P., Wiley, https://doi.org/10.1002/9781444300345.ch5a, 2008.
Purtschert, R., Corcho Alvarado, J., and Loosli, H. H.: Dating Examples in European Reference Aquifers, in: Natural Groundwater Quality, edited Edmunds, W. M. and Shand, P., Wiley, https://doi.org/10.1002/9781444300345.ch5b, 2008.
Rädle, V., Kersting, A., Schmidt, M., Ringena, L., Robertz, J., Aeschbach, W., Oberthaler, M., and Müller, T.: Multi-tracer groundwater dating in Southern Oman using Bayesian modelling, Water Resour. Res., 58, e2021WR031776, https://doi.org/10.1029/2021WR031776, 2022.
Rajaram, H.: Matrix diffusion as a mechanism contributing to fractal stream chemistry and long-tailed transit time distributions, Geophys. Res. Lett., 48, e2021GL094292, https://doi.org/10.1029/2021GL094292, 2021.
R Core Team: R: A language and environment for statistical computing, R Foundation for Statistical Computing, Vienna, Austria, https://www.R-project.org (last access: 10 June 2024), 2022.
RGD: Grand-Ducal regulation of 2 October 2018 creating protection zones around the groundwater catchments of the Glasbouren, Brennerei and Dommeldange sites located on the territories of the communes of Luxembourg, Niederanven, Steinsel and Walferdange (Règlement grand-ducal du 2 octobre 2018 portant création des zones de protection autour des captages d'eau souterraine des sites Glasbouren, Brennerei et Dommeldange situées sur les territoires des communes de Luxembourg, Niederanven, Steinsel et Walferdange), https://data.legilux.public.lu/filestore/eli/etat/leg/rgd/2018/10/02/a934/jo/fr/pdfa/eli-etat-leg-rgd-2018-10-02-a934-jo-fr-pdfa.pdf (last access: 28 April 2023), 2018.
RGD: Grand-Ducal regulation of 16 May 2019 creating protection zones around the Siwebueren and Katzebuer-Millebaach groundwater catchments located on the territories of the communes of Kopstal, Luxembourg, Strassen and Walferdange (Règlement grand-ducal du 16 mai 2019 portant création des zones de protection autour des captages d'eau souterraine Siwebueren et Katzebuer-Millebaach situées sur les territoires des communes de Kopstal, Luxembourg, Strassen et Walferdange), https://data.legilux.public.lu/filestore/eli/etat/leg/rgd/2019/05/16/a342/jo/fr/pdfa/eli-etat-leg-rgd-2019-05-16-a342-jo-fr-pdfa.pdf (last access: 28 April 2023), 2019.
RGD: Grand-Ducal regulation of 25 August 2021 creating protection zones around the Pulvermühle groundwater catchment situated on the territories of the communes of Luxembourg, Niederanven and Sandweiler (Règlement grand-ducal du 25 août 2021 portant création des zones de protection autour du captage d'eau souterraine Pulvermühle situées sur les territoires des communes de Luxembourg, Niederanven et Sandweiler), https://data.legilux.public.lu/filestore/eli/etat/leg/rgd/2021/08/25/a677/jo/fr/pdfa/eli-etat-leg-rgd-2021-08-25-a677-jo-fr-pdfa.pdf (last access: 28 April 2023), 2021a.
RGD: Grand-Ducal regulation of 25 August 2021 creating protection zones around the Birelergronn groundwater catchment site located on the territories of the communes of Niederanven, Sandweiler and Schuttrange (Règlement grand-ducal du 25 août 2021 portant création de zones de protection autour du site de captage d'eau souterraine Birelergronn situées sur les territoires des communes de Niederanven, Sandweiler et Schuttrange), https://data.legilux.public.lu/filestore/eli/etat/leg/rgd/2021/08/25/a678/jo/fr/pdfa/eli-etat-leg-rgd-2021-08-25-a678-jo-fr-pdfa.pdf (last access: 28 April 2023), 2021b.
RGD: Draft Grand-Ducal regulation creating protection zones around the groundwater catchments of the Kopstal catchment site (west side) and located on the territories of the municipalities of Kehlen and Kopstal (Projet de règlement grand-ducal portant création des zones de protection autour des captages d'eau souterraine du site de captage Kopstal (côté Ouest) et situées sur les territoires des communes de Kehlen et Kopstal), http://geoportail.eau.etat.lu/pdf/eaux souterraines/ZPS/RGD/PRGD ZPS Kopstal_coteOuest.pd (last access: 28 April 2023), 2022a.
RGD: Draft Grand-Ducal regulation creating protection zones around the groundwater catchments of the Kopstal catchment site (East side) and located on the territories of the municipalities of Kopstal, Lorentzweiler and Steinsel (Projet de règlement grand-ducal portant création des zones de protection autour des captages d'eau souterraine du site de captage Kopstal (côté Est) et situées sur les territoires des communes de Kopstal, Lorentzweiler et Steinsel), http://geoportail.eau.etat.lu/pdf/eaux souterraines/ZPS/RGD/PRGD ZPS Kopstal_coteEst.pdf (last access: 28 April 2023), 2022b.
Ries, C. and Krippel, Y.: Sandstone Landscapes in Europe – Past, Present and Future, in: Proceedings of the 2nd International Conference on Sandstone Landscapes, 25–28 May 2005, Vianden, Luxembourg, MNHN, Ferrantia, 44, edited by: Ries, C., and Krippel, Y., 256 pp., https://ps.mnhn.lu/ferrantia/publications/Ferrantia44.pdf (last access: 28 April 2023), 2005.
Samir, M.: Fracture roughness analysis in Luxembourg Sandstone, MS Thesis in Geology, ULB – Université Libre de Bruxelles, Faculty of Sciences, DGES – Department of Geosciences, Environment and Society, https://ulb.academia.edu/samirmohammad (last access: 28 April 2023), 2019.
Scaini, A., Audebert, M., Hissler, C., Fenicia, F., Gourdol, L., Pfister, L., and Beven, K. J.: Velocity and celerity dynamics at plot scale inferred from artificial tracing experiments and time-lapse ERT, J. Hydrol., 546, 28–43, https://doi.org/10.1016/j.jhydrol.2016.12.035, 2017.
Schäfer, A. and Colbach, R.: The Early Liassic Luxembourg Sandstone – Depositional environments and the interpretation of stratigraphic sequences in the Trier-Luxembourg Basin, Zeitschrift der Deutschen Gesellschaft für Geowissenschaften, 172, 99–125, https://doi.org/10.1127/zdgg/2021/0268, 2021.
Schmidt, A., Frank, G., Stichler, W., Duester, L., Steinkopff, T., and Stumpp, C.: Overview of tritium records from precipitation and surface waters in Germany, Hydrol. Process., 34, 1489–1493, https://doi.org/10.1002/hyp.13691, 2020.
Shao, W., Su, Y., Yang, Z., Ma, X., and Langhammer, J.: Quantify the Pore Water Velocity Distribution by a Celerity Function, Geofluids, 2018, 1054730, https://doi.org/10.1155/2018/1054730, 2018.
Stewart, M. K. and Morgenstern, U.: Importance of tritium-based transit times in hydrological systems, Wiley Interdisciplin. Rev. Water, 3, 145–154, https://doi.org/10.1002/wat2.1134, 2016.
Stewart, M. K., Mehlhorn, J., and Elliott, S.: Hydrometric and natural tracer (oxygen-18, silica, tritium and sulphur hexafluoride) evidence for a dominant groundwater contribution to Pukemanga Stream, New Zealand, Hydrol. Process., 21, 3340–3356, https://doi.org/10.1002/hyp.6557, 2007.
Stewart, M. K., Morgenstern, U., and McDonnell, J. J.: Truncation of stream residence time: how the use of stable isotopes has skewed our concept of streamwater age and origin, Hydrol. Process., 24, 1646–1659, https://doi.org/10.1002/hyp.7576, 2010.
Stewart, M. K., Morgenstern, U., McDonnell, J. J., and Pfister, L.: The “hidden streamflow” challenge in catchment hydrology: A call to action for streamwater transit time analysis, Hydrol. Process., 26, 2061–2066, https://doi.org/10.1002/hyp.9262, 2012.
Stewart, M. K., Morgenstern, U., Gusyev, M. A., and Maloszewski, P.: Aggregation effects on tritium-based mean transit times and young water fractions in spatially heterogeneous catchments and groundwater systems, Hydrol. Earth Syst. Sci., 21, 4615–4627, https://doi.org/10.5194/hess-21-4615-2017, 2017.
Stewart, M .K., Morgenstern, U., and Cartwright, I.: Comment on “A comparison of catchment travel times and storage deduced from deuterium and tritium tracers using StorAge Selection functions” by Rodriguez et al. (2021), Hydrol. Earth Syst. Sci., 25, 6333—6338, https://doi.org/10.5194/hess-25-6333-2021, 2021.
Stolp, B. J., Solomon, D. K., Suckow, A., Vitvar, T., Rank, D., Aggarwal, P. K., and Han, L. F.: Age dating base flow at springs and gaining streams using helium-3 and tritium: Fischa-Dagnitz system, southern Vienna Basin, Austria, Water Resour. Res., 46, W07503, https://doi.org/10.1029/2009WR008006, 2010.
Stumpp, C., Klaus, J., and Stichler, W.: Analysis of long-term stable isotopic composition in German precipitation, J. Hydrol., 517, 351–361, https://doi.org/10.1016/j.jhydrol.2014.05.034, 2014.
Tadros, C. V., Hughes, C. E., Crawford, J., Hollins, S. E., and Chisari, R.: Tritium in Australian precipitation: A 50 year record, J. Hydrol., 513, 262–273, https://doi.org/10.1016/j.jhydrol.2014.03.031, 2014.
Terzer-Wassmuth, S., Araguás-Araguás, L. J., Copia, L., and Wassenaar, L. A.: High spatial resolution prediction of tritium (3H) in contemporary global precipitation, Sci. Rep., 12, 10271, https://doi.org/10.1038/s41598-022-14227-5, 2022.
Thiros, N. E., Siirila-Woodburn, E. R., Dennedy-Frank, P. J., Williams, K. H., and Gardner, W. P.: Constraining bedrock groundwater residence times in a mountain system with environmental tracer observations and Bayesian uncertainty quantification, Water Resour. Res., 59, e2022WR033282, https://doi.org/10.1029/2022WR033282, 2023.
Thornthwaite, C. W.: An approach toward a rational classification of climate, Geogr. Rev., 38, 55-94, 1948.
Tukey, J.: An introduction to the calculations of numerical spectrum analysis, in: Spectral Analysis of Time Series, edited by: Harris, B., Wiley, New York, USA, 25–46, 1968.
Turnadge, C. and Smerdon, B. D.: A review of methods for modelling environmental tracers in groundwater: Advantages of tracer concentration simulation, J. Hydrol., 519, 3674–3689, https://doi.org/10.1016/j.jhydrol.2014.10.056, 2014.
Van den Bril, K. and Swennen, R.: Sedimentological control on carbonate cementation in the Luxembourg Sandstone Formation, Geologica Belgica, 12, 3–23, https://popups.uliege.be/1374-8505/index.php?id=2634&file=1&pid=2629 (last access: 4 March 2024), 2009.
Van Loon, A. F., Kumar, R., and Mishra, V.: Testing the use of standardised indices and GRACE satellite data to estimate the European 2015 groundwater drought in near real time, Hydrol. Earth Syst. Sci., 21, 1947–1971, https://doi.org/10.5194/hess-21-1947-2017, 2017.
Van Verseveld, W. J., Barnard, H. R., Graham, C. B., McDonnell, J. J., Brooks, J. R., and Weiler, M.: A sprinkling experiment to quantify celerity–velocity differences at the hillslope scale, Hydrol. Earth Syst. Sci., 21, 5891–5910, https://doi.org/10.5194/hess-21-5891-2017, 2017.
Von Hoyer, M.: Hydrogeological and hydrochemical investigations in the Luxembourg Sandstone (Hydrogeologische und hydrochemische Untersuchungen im Luxemburger Sandstein), Publ. Serv. Geol. Luxemb., Luxembourg, p. 61, https://geologie.lu/index.php/telechargements/send/6-publications-sgl-volumes/508-v21 (last access: 10 June 2024), 1971.
Worthington, S. R. H.: Diagnostic tests for conceptualizing transport in bedrock aquifers, J. Hydrol., 529, 365–372, https://doi.org/10.1016/j.jhydrol.2015.08.002, 2015.
Worthington, S. R. H. and Foley, A. E.: Deriving celerity from monitoring data in carbonate aquifers, J. Hydrol., 598, 126451, https://doi.org/10.1016/j.jhydrol.2021.126451, 2021.
Yager, R. M., Plummer, L. N., Kauffman, L. J., Doctor, D. H., Nelms, D. L., and Schlosser, P.: Comparison of age distributions estimated from environmental tracers by using binary-dilution and numerical models of fractured and folded karst: Shenandoah Valley of Virginia and West Virginia, USA, Hydrogeol. J., 21, 1193–1217, https://doi.org/10.1007/s10040-013-0997-9, 2013.
Zhou, Z., Cartwright, I., and Morgenstern, U.: Sources and mean transit times of stream water in an intermittent river system: the upper Wimmera River, southeast Australia, Hydrol. Earth Syst. Sci., 26, 4497–4513, https://doi.org/10.5194/hess-26-4497-2022, 2022.
Zuber, A., Witczak, S., Różański, K., Śliwka, I., Opoka, M., Mochalski, P., Kuc, T., Karlikowska, J., Kania, J., Jackowicz-Korczyński, M., and Duliński, M.: Groundwater dating with 3H and SF6 in relation to mixing patterns, transport modelling and hydrochemistry, Hydrol. Process., 19, 2247–2275, https://doi.org/10.1002/hyp.5669, 2005.
Short summary
Determining water transit times in aquifers is key to a better understanding of groundwater resources and their sustainable management. For our research, we used high-accuracy tritium data from 35 springs draining the Luxembourg Sandstone aquifer. We assessed the mean transit times of groundwater and found that water moves on average more than 10 times more slowly vertically in the vadose zone of the aquifer (~12 m yr-1) than horizontally in its saturated zone (~170 m yr-1).
Determining water transit times in aquifers is key to a better understanding of groundwater...