Research article 27 Sep 2017
Research article | 27 Sep 2017
Hydrological controls on DOC : nitrate resource stoichiometry in a lowland, agricultural catchment, southern UK
Catherine M. Heppell et al.
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Mohammad Farzamian, Dario Autovino, Angelo Basile, Roberto De Mascellis, Giovanna Dragonetti, Fernando Monteiro Santos, Andrew Binley, and Antonio Coppola
Hydrol. Earth Syst. Sci., 25, 1509–1527, https://doi.org/10.5194/hess-25-1509-2021, https://doi.org/10.5194/hess-25-1509-2021, 2021
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Soil salinity is a serious threat in numerous arid and semi-arid areas of the world. Given this threat, efficient field assessment methods are needed to monitor the dynamics of soil salinity in salt-affected lands efficiently. We demonstrate that rapid and non-invasive geophysical measurements modelled by advanced numerical analysis of the signals and coupled with hydrological modelling can provide valuable information to assess the spatio-temporal variability in soil salinity over large areas.
Sheena A. Spencer, Axel E. Anderson, Uldis Silins, and Adrian L. Collins
Hydrol. Earth Syst. Sci., 25, 237–255, https://doi.org/10.5194/hess-25-237-2021, https://doi.org/10.5194/hess-25-237-2021, 2021
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We used unique chemical signatures of precipitation, hillslope soil water, and groundwater sources of streamflow to explore seasonal variation in runoff generation in a snow-dominated mountain watershed underlain by glacial till and permeable bedrock. Reacted hillslope water reached the stream first at the onset of snowmelt, followed by a dilution effect by snowmelt from May to June. Groundwater and riparian water were important sources later in the summer. Till created complex subsurface flow.
Rosanna A. Lane, Gemma Coxon, Jim E. Freer, Thorsten Wagener, Penny J. Johnes, John P. Bloomfield, Sheila Greene, Christopher J. A. Macleod, and Sim M. Reaney
Hydrol. Earth Syst. Sci., 23, 4011–4032, https://doi.org/10.5194/hess-23-4011-2019, https://doi.org/10.5194/hess-23-4011-2019, 2019
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We evaluated four hydrological model structures and their parameters on over 1100 catchments across Great Britain, considering modelling uncertainties. Models performed well for most catchments but failed in parts of Scotland and south-eastern England. Failures were often linked to inconsistencies in the water balance. This research shows what conceptual lumped models can achieve, gives insights into where and why these models may fail, and provides a benchmark of national modelling capability.
Sergey Chalov, Valentin Golosov, Adrian Collins, and Mike Stone
Proc. IAHS, 381, 1–1, https://doi.org/10.5194/piahs-381-1-2019, https://doi.org/10.5194/piahs-381-1-2019, 2019
Steven J. Granger, Juan A. Qunicke, Paul Harris, Adrian L. Collins, and Martin S. Blackwell
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2017-684, https://doi.org/10.5194/hess-2017-684, 2018
Manuscript not accepted for further review
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This manuscript looks at the measurement of water quality parameters through the collection of physical samples which are then analysed in an analytical laboratory compared to data generated by equipment placed in the environment. The advantage with this is that large volumes of data are collected at relatively low cost, however the instruments are not subject to the same scientific rigour as in the laboratory. A comparison of the two allows an assessment to be made of the two approaches.
Mary C. Ockenden, Wlodek Tych, Keith J. Beven, Adrian L. Collins, Robert Evans, Peter D. Falloon, Kirsty J. Forber, Kevin M. Hiscock, Michael J. Hollaway, Ron Kahana, Christopher J. A. Macleod, Martha L. Villamizar, Catherine Wearing, Paul J. A. Withers, Jian G. Zhou, Clare McW. H. Benskin, Sean Burke, Richard J. Cooper, Jim E. Freer, and Philip M. Haygarth
Hydrol. Earth Syst. Sci., 21, 6425–6444, https://doi.org/10.5194/hess-21-6425-2017, https://doi.org/10.5194/hess-21-6425-2017, 2017
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This paper describes simple models of phosphorus load which are identified for three catchments in the UK. The models use new hourly observations of phosphorus load, which capture the dynamics of phosphorus transfer in small catchments that are often missed by models with a longer time step. Unlike more complex, process-based models, very few parameters are required, leading to low parameter uncertainty. Interpretation of the dominant phosphorus transfer modes is made based solely on the data.
Ian D. L. Foster, John Boardman, Adrian L. Collins, Ruth Copeland-Phillips, Nikolaus J. Kuhn, Tim M. Mighall, Simon Pulley, and Kate M. Rowntree
Proc. IAHS, 375, 29–34, https://doi.org/10.5194/piahs-375-29-2017, https://doi.org/10.5194/piahs-375-29-2017, 2017
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The paper explores existing data bases relating to erosion and sediment transport in South Africa. It identifies a number of problems with using these and stresses the need to supplement existing data with a novel approach based on the use of sediments accumulating in small farm dams. These could provide directly comparable data by identifying a common time line in all dams using a radioactive fallout isotope called Caesium-137 that was first liberated into the global atmosphere in the 1950s.
C. E. M. Lloyd, J. E. Freer, P. J. Johnes, and A. L. Collins
Hydrol. Earth Syst. Sci., 20, 625–632, https://doi.org/10.5194/hess-20-625-2016, https://doi.org/10.5194/hess-20-625-2016, 2016
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This paper examines the current methodologies for quantifying storm behaviour through hysteresis analysis, and explores a new method. Each method is systematically tested and the impact on the results is examined. Recommendations are made regarding the most effective method of calculating a hysteresis index. This new method allows storm hysteresis behaviour to be directly compared between storms, parameters, and catchments, meaning it has wide application potential in water quality research.
C. E. M. Lloyd, K. Michaelides, D. R. Chadwick, J. A. J. Dungait, and R. P. Evershed
Biogeosciences, 13, 551–566, https://doi.org/10.5194/bg-13-551-2016, https://doi.org/10.5194/bg-13-551-2016, 2016
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Our interdisciplinary research brings together methodologies from hydrology, soil science and biogeochemistry to address key questions about the transport of cattle slurry in the environment. The paper provides a novel approach to trace dissolved and particulate components of cattle slurry through an experimental hillslope system. This work provides one of the first examples of using biomarkers to assess the effects of slope gradient and rainfall intensity on the movement of slurry derived-OM.
F. N. Outram, C. E. M. Lloyd, J. Jonczyk, C. McW. H. Benskin, F. Grant, M. T. Perks, C. Deasy, S. P. Burke, A. L. Collins, J. Freer, P. M. Haygarth, K. M. Hiscock, P. J. Johnes, and A. L. Lovett
Hydrol. Earth Syst. Sci., 18, 3429–3448, https://doi.org/10.5194/hess-18-3429-2014, https://doi.org/10.5194/hess-18-3429-2014, 2014
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Subject: Catchment hydrology | Techniques and Approaches: Theory development
Barriers to mainstream adoption of catchment-wide natural flood management: a transdisciplinary problem-framing study of delivery practice
Low hydrological connectivity after summer drought inhibits DOC export in a forested headwater catchment
Rainbow color map distorts and misleads research in hydrology – guidance for better visualizations and science communication
Attribution of growing season evapotranspiration variability considering snowmelt and vegetation changes in the arid alpine basins
Event and seasonal hydrologic connectivity patterns in an agricultural headwater catchment
Exploring the role of hydrological pathways in modulating multi-annual climate teleconnection periodicities from UK rainfall to streamflow
Technical note: “Bit by bit”: a practical and general approach for evaluating model computational complexity vs. model performance
Hillslope and groundwater contributions to streamflow in a Rocky Mountain watershed underlain by glacial till and fractured sedimentary bedrock
A framework for seasonal variations of hydrological model parameters: impact on model results and response to dynamic catchment characteristics
Hydrology and beyond: the scientific work of August Colding revisited
The influence of a prolonged meteorological drought on catchment water storage capacity: a hydrological-model perspective
Hydrological and runoff formation processes based on isotope tracing during ablation period in the source regions of Yangtze River
Importance of snowmelt contribution to seasonal runoff and summer low flows in Czechia
Concentration–discharge relationships vary among hydrological events, reflecting differences in event characteristics
Recession analysis revisited: impacts of climate on parameter estimation
Understanding the effects of climate warming on streamflow and active groundwater storage in an alpine catchment: the upper Lhasa River
Technical note: An improved discharge sensitivity metric for young water fractions
Hydrological signatures describing the translation of climate seasonality into streamflow seasonality
Spatial and temporal variation in river corridor exchange across a 5th-order mountain stream network
Historic hydrological droughts 1891–2015: systematic characterisation for a diverse set of catchments across the UK
A topographic index explaining hydrological similarity by accounting for the joint controls of runoff formation
Trajectories of nitrate input and output in three nested catchments along a land use gradient
Contrasting rainfall-runoff characteristics of floods in desert and Mediterranean basins
Anthropogenic and catchment characteristic signatures in the water quality of Swiss rivers: a quantitative assessment
Using paired catchments to quantify the human influence on hydrological droughts
HESS Opinions: Socio-economic and ecological trade-offs of flood management – benefits of a transdisciplinary approach
A parsimonious transport model of emerging contaminants at the river network scale
Emergent stationarity in Yellow River sediment transport and the underlying shift of dominance: from streamflow to vegetation
A new probability density function for spatial distribution of soil water storage capacity leads to the SCS curve number method
How does initial soil moisture influence the hydrological response? A case study from southern France
Studying catchment storm response using event- and pre-event-water volumes as fractions of precipitation rather than discharge
Anatomy of simultaneous flood peaks at a lowland confluence
Including effects of watershed heterogeneity in the curve number method using variable initial abstraction
Seasonal shifts in export of DOC and nutrients from burned and unburned peatland-rich catchments, Northwest Territories, Canada
Sensitivity of young water fractions to hydro-climatic forcing and landscape properties across 22 Swiss catchments
Effects of climatic seasonality on the isotopic composition of evaporating soil waters
From engineering hydrology to Earth system science: milestones in the transformation of hydrologic science
Human influences on streamflow drought characteristics in England and Wales
A dimensionless approach for the runoff peak assessment: effects of the rainfall event structure
Groundwater impacts on surface water quality and nutrient loads in lowland polder catchments: monitoring the greater Amsterdam area
Experimental determination of the flood wave transformation and the sediment resuspension in a small regulated stream in an agricultural catchment
The CAMELS data set: catchment attributes and meteorology for large-sample studies
Spatio-temporal patterns of the effects of precipitation variability and land use/cover changes on long-term changes in sediment yield in the Loess Plateau, China
Origin of water in the Badain Jaran Desert, China: new insight from isotopes
Evaluation of extensive floods in western/central Europe
Ensemble reconstruction of spatio-temporal extreme low-flow events in France since 1871
Unravelling abiotic and biotic controls on the seasonal water balance using data-driven dimensionless diagnostics
Flood risk reduction and flow buffering as ecosystem services – Part 1: Theory on flow persistence, flashiness and base flow
Flood risk reduction and flow buffering as ecosystem services – Part 2: Land use and rainfall intensity effects in Southeast Asia
Historical and future trends in wetting and drying in 291 catchments across China
Thea Wingfield, Neil Macdonald, Kimberley Peters, and Jack Spees
Hydrol. Earth Syst. Sci., 25, 6239–6259, https://doi.org/10.5194/hess-25-6239-2021, https://doi.org/10.5194/hess-25-6239-2021, 2021
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Human activities are causing greater and more frequent floods. Natural flood management (NFM) uses processes of the water cycle to slow the flow of rainwater, bringing together land and water management. Despite NFM's environmental and social benefits, it is yet to be widely adopted. Two environmental practitioner groups collaborated to produce a picture of the barriers to delivery, showing that there is a perceived lack of support from government and the public for NFM.
Katharina Blaurock, Burkhard Beudert, Benjamin S. Gilfedder, Jan H. Fleckenstein, Stefan Peiffer, and Luisa Hopp
Hydrol. Earth Syst. Sci., 25, 5133–5151, https://doi.org/10.5194/hess-25-5133-2021, https://doi.org/10.5194/hess-25-5133-2021, 2021
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Dissolved organic carbon (DOC) is an important part of the global carbon cycle with regards to carbon storage, greenhouse gas emissions and drinking water treatment. In this study, we compared DOC export of a small, forested catchment during precipitation events after dry and wet preconditions. We found that the DOC export from areas that are usually important for DOC export was inhibited after long drought periods.
Michael Stoelzle and Lina Stein
Hydrol. Earth Syst. Sci., 25, 4549–4565, https://doi.org/10.5194/hess-25-4549-2021, https://doi.org/10.5194/hess-25-4549-2021, 2021
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We found with a scientific paper survey (~ 1000 papers) that 45 % of the papers used rainbow color maps or red–green visualizations. Those rainbow visualizations, although attracting the media's attention, will not be accessible for up to 10 % of people due to color vision deficiency. The rainbow color map distorts and misleads scientific communication. The study gives guidance on how to avoid, improve and trust color and how the flaws of the rainbow color map should be communicated in science.
Tingting Ning, Zhi Li, Qi Feng, Zongxing Li, and Yanyan Qin
Hydrol. Earth Syst. Sci., 25, 3455–3469, https://doi.org/10.5194/hess-25-3455-2021, https://doi.org/10.5194/hess-25-3455-2021, 2021
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Previous studies decomposed ET variance in precipitation, potential ET, and total water storage changes based on Budyko equations. However, the effects of snowmelt and vegetation changes have not been incorporated in snow-dependent basins. We thus extended this method in arid alpine basins of northwest China and found that ET variance is primarily controlled by rainfall, followed by coupled rainfall and vegetation. The out-of-phase seasonality between rainfall and snowmelt weaken ET variance.
Lovrenc Pavlin, Borbála Széles, Peter Strauss, Alfred Paul Blaschke, and Günter Blöschl
Hydrol. Earth Syst. Sci., 25, 2327–2352, https://doi.org/10.5194/hess-25-2327-2021, https://doi.org/10.5194/hess-25-2327-2021, 2021
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We compared the dynamics of streamflow, groundwater and soil moisture to investigate how different parts of an agricultural catchment in Lower Austria are connected. Groundwater is best connected around the stream and worse uphill, where groundwater is deeper. Soil moisture connectivity increases with increasing catchment wetness but is not influenced by spatial position in the catchment. Groundwater is more connected to the stream on the seasonal scale compared to the event scale.
William Rust, Mark Cuthbert, John Bloomfield, Ron Corstanje, Nicholas Howden, and Ian Holman
Hydrol. Earth Syst. Sci., 25, 2223–2237, https://doi.org/10.5194/hess-25-2223-2021, https://doi.org/10.5194/hess-25-2223-2021, 2021
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In this paper, we find evidence for the cyclical behaviour (on a 7-year basis) in UK streamflow records that match the main cycle of the North Atlantic Oscillation. Furthermore, we find that the strength of these 7-year cycles in streamflow is dependent on proportional contributions from groundwater and the response times of the underlying groundwater systems. This may allow for improvements to water management practices through better understanding of long-term streamflow behaviour.
Elnaz Azmi, Uwe Ehret, Steven V. Weijs, Benjamin L. Ruddell, and Rui A. P. Perdigão
Hydrol. Earth Syst. Sci., 25, 1103–1115, https://doi.org/10.5194/hess-25-1103-2021, https://doi.org/10.5194/hess-25-1103-2021, 2021
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Computer models should be as simple as possible but not simpler. Simplicity refers to the length of the model and the effort it takes the model to generate its output. Here we present a practical technique for measuring the latter by the number of memory visits during model execution by
Strace, a troubleshooting and monitoring program. The advantage of this approach is that it can be applied to any computer-based model, which facilitates model intercomparison.
Sheena A. Spencer, Axel E. Anderson, Uldis Silins, and Adrian L. Collins
Hydrol. Earth Syst. Sci., 25, 237–255, https://doi.org/10.5194/hess-25-237-2021, https://doi.org/10.5194/hess-25-237-2021, 2021
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We used unique chemical signatures of precipitation, hillslope soil water, and groundwater sources of streamflow to explore seasonal variation in runoff generation in a snow-dominated mountain watershed underlain by glacial till and permeable bedrock. Reacted hillslope water reached the stream first at the onset of snowmelt, followed by a dilution effect by snowmelt from May to June. Groundwater and riparian water were important sources later in the summer. Till created complex subsurface flow.
Tian Lan, Kairong Lin, Chong-Yu Xu, Zhiyong Liu, and Huayang Cai
Hydrol. Earth Syst. Sci., 24, 5859–5874, https://doi.org/10.5194/hess-24-5859-2020, https://doi.org/10.5194/hess-24-5859-2020, 2020
Dan Rosbjerg
Hydrol. Earth Syst. Sci., 24, 4575–4585, https://doi.org/10.5194/hess-24-4575-2020, https://doi.org/10.5194/hess-24-4575-2020, 2020
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August Colding contributed the first law of thermodynamics, evaporation from water and grass, steady free surfaces in conduits, the cross-sectional velocity distribution in conduits, a complete theory for the Gulf Stream, air speed in cyclones, the piezometric surface in confined aquifers, the unconfined elliptic water table in soil between drain pipes, and the wind-induced set-up in the sea during storms.
Zhengke Pan, Pan Liu, Chong-Yu Xu, Lei Cheng, Jing Tian, Shujie Cheng, and Kang Xie
Hydrol. Earth Syst. Sci., 24, 4369–4387, https://doi.org/10.5194/hess-24-4369-2020, https://doi.org/10.5194/hess-24-4369-2020, 2020
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This study aims to identify the response of catchment water storage capacity (CWSC) to meteorological drought by examining the changes of hydrological-model parameters after drought events. This study improves our understanding of possible changes in the CWSC induced by a prolonged meteorological drought, which will help improve our ability to simulate the hydrological system under climate change.
Zong-Jie Li, Zong-Xing Li, Ling-Ling Song, Juan Gui, Jian Xue, Bai Juan Zhang, and Wen De Gao
Hydrol. Earth Syst. Sci., 24, 4169–4187, https://doi.org/10.5194/hess-24-4169-2020, https://doi.org/10.5194/hess-24-4169-2020, 2020
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This study mainly explores the hydraulic relations, recharge–drainage relations and their transformation paths, and the processes of each water body. It determines the composition of runoff, quantifies the contribution of each runoff component to different types of tributaries, and analyzes the hydrological effects of the temporal and spatial variation in runoff components. More importantly, we discuss the hydrological significance of permafrost and hydrological processes.
Michal Jenicek and Ondrej Ledvinka
Hydrol. Earth Syst. Sci., 24, 3475–3491, https://doi.org/10.5194/hess-24-3475-2020, https://doi.org/10.5194/hess-24-3475-2020, 2020
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Changes in snow affect the runoff seasonality, including summer low flows. Here we analyse this effect in 59 mountain catchments in Czechia. We show that snow is more effective in generating runoff compared to rain. Snow-poor years generated lower groundwater recharge than snow-rich years, which resulted in higher deficit volumes in summer. The lower recharge and runoff in the case of a snowfall-to-rain transition due to air temperature increase might be critical for water supply in the future.
Julia L. A. Knapp, Jana von Freyberg, Bjørn Studer, Leonie Kiewiet, and James W. Kirchner
Hydrol. Earth Syst. Sci., 24, 2561–2576, https://doi.org/10.5194/hess-24-2561-2020, https://doi.org/10.5194/hess-24-2561-2020, 2020
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Changes of stream water chemistry in response to discharge changes provide important insights into the storage and release of water from the catchment. Here we investigate the variability in concentration–discharge relationships among different solutes and hydrologic events and relate it to catchment conditions and dominant water sources.
Elizabeth R. Jachens, David E. Rupp, Clément Roques, and John S. Selker
Hydrol. Earth Syst. Sci., 24, 1159–1170, https://doi.org/10.5194/hess-24-1159-2020, https://doi.org/10.5194/hess-24-1159-2020, 2020
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Recession analysis uses the receding streamflow following precipitation events to estimate watershed-average properties. Two methods for recession analysis use recession events individually or all events collectively. Using synthetic case studies, this paper shows that analyzing recessions collectively produces flawed interpretations. Moving forward, recession analysis using individual recessions should be used to describe the average and variability of watershed behavior.
Lu Lin, Man Gao, Jintao Liu, Jiarong Wang, Shuhong Wang, Xi Chen, and Hu Liu
Hydrol. Earth Syst. Sci., 24, 1145–1157, https://doi.org/10.5194/hess-24-1145-2020, https://doi.org/10.5194/hess-24-1145-2020, 2020
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In this paper, recession flow analysis – assuming nonlinearized outflow from aquifers into streams – was used to quantify active groundwater storage in a headwater catchment with high glacierization and large-scale frozen ground on the Tibetan Plateau. Hence, this work provides a perspective to clarify the impact of glacial retreat and frozen ground degradation due to climate change on hydrological processes.
Francesc Gallart, Jana von Freyberg, María Valiente, James W. Kirchner, Pilar Llorens, and Jérôme Latron
Hydrol. Earth Syst. Sci., 24, 1101–1107, https://doi.org/10.5194/hess-24-1101-2020, https://doi.org/10.5194/hess-24-1101-2020, 2020
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How catchments store and release rain or melting water is still not well known. Now, it is broadly accepted that most of the water in streams is older than several months, and a relevant part may be many years old. But the age of water depends on the stream regime, being usually younger during high flows. This paper tries to provide tools for better analysing how the age of waters varies with flow in a catchment and for comparing the behaviour of catchments diverging in climate, size and regime.
Sebastian J. Gnann, Nicholas J. K. Howden, and Ross A. Woods
Hydrol. Earth Syst. Sci., 24, 561–580, https://doi.org/10.5194/hess-24-561-2020, https://doi.org/10.5194/hess-24-561-2020, 2020
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In many places, seasonal variability in precipitation and evapotranspiration (climate) leads to seasonal variability in river flow (streamflow). In this work, we explore how climate seasonality is transformed into streamflow seasonality and what controls this transformation (e.g. climate aridity and geology). The results might be used in grouping catchments, predicting the seasonal streamflow regime in ungauged catchments, and building hydrological simulation models.
Adam S. Ward, Steven M. Wondzell, Noah M. Schmadel, Skuyler Herzog, Jay P. Zarnetske, Viktor Baranov, Phillip J. Blaen, Nicolai Brekenfeld, Rosalie Chu, Romain Derelle, Jennifer Drummond, Jan H. Fleckenstein, Vanessa Garayburu-Caruso, Emily Graham, David Hannah, Ciaran J. Harman, Jase Hixson, Julia L. A. Knapp, Stefan Krause, Marie J. Kurz, Jörg Lewandowski, Angang Li, Eugènia Martí, Melinda Miller, Alexander M. Milner, Kerry Neil, Luisa Orsini, Aaron I. Packman, Stephen Plont, Lupita Renteria, Kevin Roche, Todd Royer, Catalina Segura, James Stegen, Jason Toyoda, Jacqueline Wells, and Nathan I. Wisnoski
Hydrol. Earth Syst. Sci., 23, 5199–5225, https://doi.org/10.5194/hess-23-5199-2019, https://doi.org/10.5194/hess-23-5199-2019, 2019
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The movement of water and solutes between streams and their shallow, connected subsurface is important to many ecosystem functions. These exchanges are widely expected to vary with stream flow across space and time, but these assumptions are seldom tested across basin scales. We completed more than 60 experiments across a 5th-order river basin to document these changes, finding patterns in space but not time. We conclude space-for-time and time-for-space substitutions are not good assumptions.
Lucy J. Barker, Jamie Hannaford, Simon Parry, Katie A. Smith, Maliko Tanguy, and Christel Prudhomme
Hydrol. Earth Syst. Sci., 23, 4583–4602, https://doi.org/10.5194/hess-23-4583-2019, https://doi.org/10.5194/hess-23-4583-2019, 2019
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It is important to understand historic droughts in order to plan and prepare for possible future events. In this study we use the standardised streamflow index for 1891–2015 to systematically identify, characterise and rank hydrological drought events for 108 near-natural UK catchments. Results show when and where the most severe events occurred and describe events of the early 20th century, providing catchment-scale detail important for both science and planning applications of the future.
Ralf Loritz, Axel Kleidon, Conrad Jackisch, Martijn Westhoff, Uwe Ehret, Hoshin Gupta, and Erwin Zehe
Hydrol. Earth Syst. Sci., 23, 3807–3821, https://doi.org/10.5194/hess-23-3807-2019, https://doi.org/10.5194/hess-23-3807-2019, 2019
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In this study, we develop a topographic index explaining hydrological similarity within a energy-centered framework, with the observation that the majority of potential energy is dissipated when rainfall becomes runoff.
Sophie Ehrhardt, Rohini Kumar, Jan H. Fleckenstein, Sabine Attinger, and Andreas Musolff
Hydrol. Earth Syst. Sci., 23, 3503–3524, https://doi.org/10.5194/hess-23-3503-2019, https://doi.org/10.5194/hess-23-3503-2019, 2019
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This study shows quantitative and temporal offsets between nitrogen input and riverine output, using time series of three nested catchments in central Germany. The riverine concentrations show lagged reactions to the input, but at the same time exhibit strong inter-annual changes in the relationship between riverine discharge and concentration. The study found a strong retention of nitrogen that is dominantly assigned to a hydrological N legacy, which will affect future stream concentrations.
Davide Zoccatelli, Francesco Marra, Moshe Armon, Yair Rinat, James A. Smith, and Efrat Morin
Hydrol. Earth Syst. Sci., 23, 2665–2678, https://doi.org/10.5194/hess-23-2665-2019, https://doi.org/10.5194/hess-23-2665-2019, 2019
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This study presents a comparison of flood properties over multiple Mediterranean and desert catchments. While in Mediterranean areas floods are related to rainfall amount, in deserts we observed a strong connection with the characteristics of the more intense part of storms. Because of the different mechanisms involved, despite having significantly shorter and more localized storms, deserts are able to produce floods with a magnitude comparable to Mediterranean areas.
Martina Botter, Paolo Burlando, and Simone Fatichi
Hydrol. Earth Syst. Sci., 23, 1885–1904, https://doi.org/10.5194/hess-23-1885-2019, https://doi.org/10.5194/hess-23-1885-2019, 2019
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The study focuses on the solute export from rivers with the purpose of discerning the impacts of anthropic activities and catchment characteristics on water quality. The results revealed a more detectable impact of the anthropic activities than of the catchment characteristics. The solute export follows different dynamics depending on catchment characteristics and mainly on solute-specific properties. The export modality is consistent across different catchments only for a minority of solutes.
Anne F. Van Loon, Sally Rangecroft, Gemma Coxon, José Agustín Breña Naranjo, Floris Van Ogtrop, and Henny A. J. Van Lanen
Hydrol. Earth Syst. Sci., 23, 1725–1739, https://doi.org/10.5194/hess-23-1725-2019, https://doi.org/10.5194/hess-23-1725-2019, 2019
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We explore the use of the classic
paired-catchmentapproach to quantify human influence on hydrological droughts. In this approach two similar catchments are compared and differences are attributed to the human activity present in one. In two case studies in UK and Australia, we found that groundwater abstraction aggravated streamflow drought by > 200 % and water transfer alleviated droughts with 25–80 %. Understanding the human influence on droughts can support water management decisions.
Karl Auerswald, Peter Moyle, Simon Paul Seibert, and Juergen Geist
Hydrol. Earth Syst. Sci., 23, 1035–1044, https://doi.org/10.5194/hess-23-1035-2019, https://doi.org/10.5194/hess-23-1035-2019, 2019
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The demand for flood protection often results in the construction of more and bigger levees along rivers. We highlight that such technical solutions often result in undesired socio-economic and ecological consequences such as increased downstream flooding risk, changes of groundwater levels, and a loss of aquatic and terrestrial biodiversity. We propose a transdisciplinary approach of integrated flood management and green infrastructure instead of reliance on technical protection measures.
Elena Diamantini, Stefano Mallucci, and Alberto Bellin
Hydrol. Earth Syst. Sci., 23, 573–593, https://doi.org/10.5194/hess-23-573-2019, https://doi.org/10.5194/hess-23-573-2019, 2019
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The description of pharmaceutical fate and transport introduced into a watershed is a challenging topic, especially because of the possible adverse effects on human health. In addition, an accurate estimation of solute sources and routes is still missing. This study uses a new promising modeling approach to predict pharmaceutical concentrations in rivers. Results show an interesting relationship between solute concentrations in waters and touristic fluxes.
Sheng Ye, Qihua Ran, Xudong Fu, Chunhong Hu, Guangqian Wang, Gary Parker, Xiuxiu Chen, and Siwei Zhang
Hydrol. Earth Syst. Sci., 23, 549–556, https://doi.org/10.5194/hess-23-549-2019, https://doi.org/10.5194/hess-23-549-2019, 2019
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Our study shows that there is declining coupling between sediment concentration and discharge from daily to annual scales for gauges across the Yellow River basin (YRB). Not only the coupling, but also the magnitude of sediment response to discharge variation decreases with long-term mean discharge. This emergent stationarity can be related to sediment retardation by vegetation, suggesting the shift of dominance from water to vegetation as mean annual discharge increases.
Dingbao Wang
Hydrol. Earth Syst. Sci., 22, 6567–6578, https://doi.org/10.5194/hess-22-6567-2018, https://doi.org/10.5194/hess-22-6567-2018, 2018
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A novel distribution function is proposed for describing the spatial distribution of soil water storage capacity, and then the classical and empirical hydrologic model (the SCS curve number method) is derived as when the initial soil water storage is zero. This distribution function unifies the SCS curve number method and probability-distributed models such as the VIC and Xinanjiang models. The unified model provides a better way for modeling surface runoff.
Magdalena Uber, Jean-Pierre Vandervaere, Isabella Zin, Isabelle Braud, Maik Heistermann, Cédric Legoût, Gilles Molinié, and Guillaume Nord
Hydrol. Earth Syst. Sci., 22, 6127–6146, https://doi.org/10.5194/hess-22-6127-2018, https://doi.org/10.5194/hess-22-6127-2018, 2018
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We investigate how rivers in a flash-flood-prone region in southern France respond to rainfall depending on initial soil moisture. Therefore, high-resolution data of rainfall, river discharge and soil moisture were used. We find that during dry initial conditions, the rivers hardly respond even for heavy rain events, but for wet initial conditions, the response remains unpredictable: for some rain events almost all rainfall is transformed to discharge, whereas this is not the case for others.
Jana von Freyberg, Bjørn Studer, Michael Rinderer, and James W. Kirchner
Hydrol. Earth Syst. Sci., 22, 5847–5865, https://doi.org/10.5194/hess-22-5847-2018, https://doi.org/10.5194/hess-22-5847-2018, 2018
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We show event- and pre-event-water volumes as fractions of precipitation, rather than discharge, to provide an alternative and more insightful approach to study catchment hydrological processes. For this, we analyze 24 storm events using high-frequency measurements of stable water isotopes in stream water and precipitation at a pre-Alpine catchment. Antecedent wetness and storm characteristics are dominant controls on event-water discharge and pre-event-water mobilization from storage.
Tjitske J. Geertsema, Adriaan J. Teuling, Remko Uijlenhoet, Paul J. J. F. Torfs, and Antonius J. F. Hoitink
Hydrol. Earth Syst. Sci., 22, 5599–5613, https://doi.org/10.5194/hess-22-5599-2018, https://doi.org/10.5194/hess-22-5599-2018, 2018
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This study investigate the processes and effects of simultaneous flood peaks at a lowland confluence. The flood peaks are analyzed with the relatively new dynamic time warping method, which offers a robust means of tracing flood waves in discharge time series at confluences. The time lag between discharge peaks in the main river and its lowland tributaries is small compared to the wave duration; therefore the exact timing of discharge peaks may be little relevant to flood risk.
Vijay P. Santikari and Lawrence C. Murdoch
Hydrol. Earth Syst. Sci., 22, 4725–4743, https://doi.org/10.5194/hess-22-4725-2018, https://doi.org/10.5194/hess-22-4725-2018, 2018
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The curve number (CN) method is the most widely used approach for estimating runoff from rainfall. Despite its popularity, there is a conceptual flaw where CN varies with rainfall although it is assumed to be constant. In this paper, we describe theoretical analyses that show how this behavior is due to watershed heterogeneity, and we then provide simple modifications to the method to improve its runoff predictions. The findings will benefit hydrologists and watershed models that use CN method.
Katheryn Burd, Suzanne E. Tank, Nicole Dion, William L. Quinton, Christopher Spence, Andrew J. Tanentzap, and David Olefeldt
Hydrol. Earth Syst. Sci., 22, 4455–4472, https://doi.org/10.5194/hess-22-4455-2018, https://doi.org/10.5194/hess-22-4455-2018, 2018
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In this study we investigated whether climate change and wildfires are likely to alter water quality of streams in western boreal Canada, a region that contains large permafrost-affected peatlands. We monitored stream discharge and water quality from early snowmelt to fall in two streams, one of which drained a recently burned landscape. Wildfire increased the stream delivery of phosphorous and possibly increased the release of old natural organic matter previously stored in permafrost soils.
Jana von Freyberg, Scott T. Allen, Stefan Seeger, Markus Weiler, and James W. Kirchner
Hydrol. Earth Syst. Sci., 22, 3841–3861, https://doi.org/10.5194/hess-22-3841-2018, https://doi.org/10.5194/hess-22-3841-2018, 2018
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We explored how the fraction of streamflow younger than ca. 3 months (Fyw) varies with landscape characteristics and climatic forcing, using an extensive isotope data set from 22 Swiss catchments. Overall, Fyw tends to be larger when catchments are wet and discharge is correspondingly higher, indicating an increase in the proportional contribution of faster flow paths at higher flows. We quantify this
discharge sensitivityof Fyw and relate it to the dominant streamflow-generating mechanisms.
Paolo Benettin, Till H. M. Volkmann, Jana von Freyberg, Jay Frentress, Daniele Penna, Todd E. Dawson, and James W. Kirchner
Hydrol. Earth Syst. Sci., 22, 2881–2890, https://doi.org/10.5194/hess-22-2881-2018, https://doi.org/10.5194/hess-22-2881-2018, 2018
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Evaporation causes the isotopic composition of soil water to become different from that of the original precipitation source. If multiple samples originating from the same source are available, they can be used to reconstruct the original source composition. However, soil water is influenced by seasonal variability in both precipitation sources and evaporation patterns. We show that this variability, if not accounted for, can lead to biased estimates of the precipitation source water.
Murugesu Sivapalan
Hydrol. Earth Syst. Sci., 22, 1665–1693, https://doi.org/10.5194/hess-22-1665-2018, https://doi.org/10.5194/hess-22-1665-2018, 2018
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The paper presents major milestones in the transformation of hydrologic science over the last 50 years from engineering hydrology to Earth system science. This transformation has involved a transition from a focus on time (empirical) to space (Newtonian mechanics), and to time (Darwinian co-evolution). Hydrology is now well positioned to again return to a focus on space or space–time and a move towards regional process hydrology.
Erik Tijdeman, Jamie Hannaford, and Kerstin Stahl
Hydrol. Earth Syst. Sci., 22, 1051–1064, https://doi.org/10.5194/hess-22-1051-2018, https://doi.org/10.5194/hess-22-1051-2018, 2018
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In this study, a screening approach was applied on a set of streamflow records for which various human influences are indicated to identify streamflow records that have drought characteristics that deviate from those expected under pristine conditions. Prolonged streamflow drought duration, a weaker correlation between streamflow and precipitation, and changes in streamflow drought occurrence over time were related to human influences such as groundwater abstractions or reservoir operations.
Ilaria Gnecco, Anna Palla, and Paolo La Barbera
Hydrol. Earth Syst. Sci., 22, 943–956, https://doi.org/10.5194/hess-22-943-2018, https://doi.org/10.5194/hess-22-943-2018, 2018
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The paper proposes a dimensionless framework to investigate the impact of the rainfall event structure on the runoff peak. A set of analytical expressions are derived from a constant hyetograph to assess the maximum runoff peak for a given event structure irrespective of the specific catchment. A catchment application is discussed to point out the dimensionless procedure implications and to provide some numerical examples of the rainfall structures with respect to observed rainfall events.
Liang Yu, Joachim Rozemeijer, Boris M. van Breukelen, Maarten Ouboter, Corné van der Vlugt, and Hans Peter Broers
Hydrol. Earth Syst. Sci., 22, 487–508, https://doi.org/10.5194/hess-22-487-2018, https://doi.org/10.5194/hess-22-487-2018, 2018
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The study shows the importance of the connection between groundwater and surface water nutrient chemistry in a lowland delta area – the greater Amsterdam area. We expect that taking account of groundwater–surface water interaction is also important in other subsiding and urbanising deltas around the world, where water is managed intensively in order to enable agricultural productivity and achieve water-sustainable cities.
David Zumr, Tomáš Dostál, Jan Devátý, Petr Valenta, Pavel Rosendorf, Alexander Eder, and Peter Strauss
Hydrol. Earth Syst. Sci., 21, 5681–5691, https://doi.org/10.5194/hess-21-5681-2017, https://doi.org/10.5194/hess-21-5681-2017, 2017
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Intensively cultivated landscape is the main non-point source of eroded sediment. The soil particles, carrying bounded nutrients and pollutants, cause both environmental and economic problems downstream. We did several flooding experiments in a typical rural drainage channel to show how the eroded sediment behaves in the headwater streams during spring and summer. We conclude that the channel behaves as a sediment trap during summer. In spring the sediment moves quickly.
Nans Addor, Andrew J. Newman, Naoki Mizukami, and Martyn P. Clark
Hydrol. Earth Syst. Sci., 21, 5293–5313, https://doi.org/10.5194/hess-21-5293-2017, https://doi.org/10.5194/hess-21-5293-2017, 2017
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We introduce a data set describing the landscape of 671 catchments in the contiguous USA: we synthesized various data sources to characterize the topography, climate, streamflow, land cover, soil, and geology of each catchment. This extends the daily time series of meteorological forcing and discharge provided by an earlier study. The diversity of these catchments will help to improve our understanding and modeling of how the interplay between catchment attributes shapes hydrological processes.
Guangyao Gao, Jianjun Zhang, Yu Liu, Zheng Ning, Bojie Fu, and Murugesu Sivapalan
Hydrol. Earth Syst. Sci., 21, 4363–4378, https://doi.org/10.5194/hess-21-4363-2017, https://doi.org/10.5194/hess-21-4363-2017, 2017
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This study extracted spatio-temporal patterns in the effects of LUCC and precipitation variability on sediment yield across the Loess Plateau during 1961–2011. The impacts of precipitation on sediment yield declined with time and the precipitation-sediment relationship showed a coherent spatial pattern. The sediment coefficient, representing the effect of LUCC, decreases linearly with fraction of area treated with erosion control measures and the slopes were highly variable among the catchments.
Xiujie Wu, Xu-Sheng Wang, Yang Wang, and Bill X. Hu
Hydrol. Earth Syst. Sci., 21, 4419–4431, https://doi.org/10.5194/hess-21-4419-2017, https://doi.org/10.5194/hess-21-4419-2017, 2017
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It is critical to identify the origins of water in arid and semiarid regions for management and protection of the water resources. The D, 18O, 3H and 14C in water samples from the Badain Jaran Desert, China, were analyzed. The results show that groundwater supplies the lakes and originates from local precipitation and adjacent mountains. Negative d-excess values of water in the area were the result of evaporation. The 14C ages do not represent the residence time of local groundwater.
Blanka Gvoždíková and Miloslav Müller
Hydrol. Earth Syst. Sci., 21, 3715–3725, https://doi.org/10.5194/hess-21-3715-2017, https://doi.org/10.5194/hess-21-3715-2017, 2017
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This paper addresses the evaluation of extreme floods in western/central Europe in terms of different index variants. The comparison of extreme floods' rankings is presented, as well as the main characteristics of temporal and spatial distributions of flood extremes. The results will be used for the assessment of related meteorological conditions. A comparison of major floods with precipitation and circulation extremes will be useful for a better understanding of the causes of extensive floods.
Laurie Caillouet, Jean-Philippe Vidal, Eric Sauquet, Alexandre Devers, and Benjamin Graff
Hydrol. Earth Syst. Sci., 21, 2923–2951, https://doi.org/10.5194/hess-21-2923-2017, https://doi.org/10.5194/hess-21-2923-2017, 2017
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The historical depth of streamflow observations in France is extended through daily hydrometeorogical reconstructions from 1871 onwards over a large set of near-natural catchments. Innovative approaches are proposed to identify and intercompare extreme low-flow events from these reconstructions, both in time and across France in a homogeneous way over more than 140 years. Analyses bring forward recent well-known events like 1976 and 1989–1990 but also much older ones like 1878 and 1893.
Simon Paul Seibert, Conrad Jackisch, Uwe Ehret, Laurent Pfister, and Erwin Zehe
Hydrol. Earth Syst. Sci., 21, 2817–2841, https://doi.org/10.5194/hess-21-2817-2017, https://doi.org/10.5194/hess-21-2817-2017, 2017
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Runoff production mechanisms and their corresponding physiographic controls continue to pose major research challenges in catchment hydrology. We propose innovative data-driven diagnostic signatures for overcoming the prevailing status quo in inter-comparison studies. Specifically, we present dimensionless double mass curves which allow us to infer information on runoff generation at the seasonal and annual timescales. The method is based on commonly available data.
Meine van Noordwijk, Lisa Tanika, and Betha Lusiana
Hydrol. Earth Syst. Sci., 21, 2321–2340, https://doi.org/10.5194/hess-21-2321-2017, https://doi.org/10.5194/hess-21-2321-2017, 2017
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Deforestation is commonly understood to increase and reforestation to reduce flood risk, but scientific evidence at the relevant landscape scale is scarce and contested. A measure of day-to-day flow persistence is defined here. It is proposed as simple performance indicator for watershed health that can respond to changes in climate and land cover quality, quantity and spatial pattern. Data for four watersheds show decrease or increase in flow persistence in degradation and restoration phases.
Meine van Noordwijk, Lisa Tanika, and Betha Lusiana
Hydrol. Earth Syst. Sci., 21, 2341–2360, https://doi.org/10.5194/hess-21-2341-2017, https://doi.org/10.5194/hess-21-2341-2017, 2017
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Deforestation is commonly understood to increase and reforestation to reduce flood risk, but scientific evidence at the relevant landscape scale is scarce and contested. A measure of day-to-day flow persistence is defined here. It is proposed as simple performance indicator for watershed health that can respond to changes in climate and land cover quality, quantity and spatial pattern. Data for four watersheds show decrease or increase in flow persistence in degradation and restoration phases.
Zhongwang Chen, Huimin Lei, Hanbo Yang, Dawen Yang, and Yongqiang Cao
Hydrol. Earth Syst. Sci., 21, 2233–2248, https://doi.org/10.5194/hess-21-2233-2017, https://doi.org/10.5194/hess-21-2233-2017, 2017
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The significant climate changes remind us to characterize the hydrological response to it. Based on the long-term observed hydrological and meteorological data in 291 catchments across China, we find a pattern of the response stating that
drier regions are more likely to become drier, whereas wetter regions are more likely to become wetter. We also reveal that the precipitation changes play the most significant role in this process.
Cited articles
Ågren, A., Buffam, I., Jansson, M., and Laudon, H.: Importance of seasonality and small streams for the landscape regulation of dissolved organic carbon export, J. Geophys. Res.-Biogeo., 112, G03003, https://doi.org/10.1029/2006jg000381, 2007.
Aitkenhead, J. A. and McDowell, W. H.: Soil C : N ratio as a predictor of annual riverine DOC flux at local and global scales, Global Biogeochem. Cy., 14, 127–138, https://doi.org/10.1029/1999gb900083, 2000.
Allen, D. J., Darling, W. G., Davies, J., Newell, A. J., Gooddy, D. C., and Collins, A. L.: Groundwater conceptual models: implications for evaluating diffuse pollution mitigation measures, Q. J. Eng. Geol. Hydroge., 47, 65–80, https://doi.org/10.1144/qjegh2013-043, 2014.
Aubert, A. H., Gascuel-Odoux, C., Gruau, G., Akkal, N., Faucheux, M., Fauvel, Y., Grimaldi, C., Hamon, Y., Jaffrézic, A., Lecoz-Boutnik, M., Molénat, J., Petitjean, P., Ruiz, L., and Merot, P.: Solute transport dynamics in small, shallow groundwater-dominated agricultural catchments: insights from a high-frequency, multisolute 10 yr-long monitoring study, Hydrol. Earth Syst. Sci., 17, 1379–1391, https://doi.org/10.5194/hess-17-1379-2013, 2013.
Basu, N. B., Destouni, G., Jawitz, J. W., Thompson, S. E., Loukinova, N. V., Darracq, A., Zanardo, S., Yaeger, M., Sivapalan, M., Rinaldo, A., and Rao, P. S. C.: Nutrient loads exported from managed catchments reveal emergent biogeochemical stationarity, Geophys. Res. Lett., 37, L23404, https://doi.org/10.1029/2010gl045168, 2010.
Basu, N. B., Thompson, S. E., and Rao, P. S. C.: Hydrologic and biogeochemical functioning of intensively managed catchments: A synthesis of top-down analyses, Water Resour. Res., 47, W00J15, https://doi.org/10.1029/2011wr010800, 2011.
Bates D., Maechler, M., Bolker, B., and Walker, S.: Fitting linear mixed-effects models using lme4, J. Stat. Softw., 67, 1–48, https://doi.org/10.18637/jss.v067.i01, 2015.
Battin, T. J., Luyssaert, S., Kaplan, L. A., Aufdenkampe, A. K., Richter, A., and Tranvik, L. J.: The boundless carbon cycle, Nat. Geosci., 2, 598–600, https://doi.org/10.1038/ngeo618, 2009.
Bernhardt, E. S. and Likens, G. E.: Dissolved Organic Carbon Enrichment Alters Nitrogen Dynamics in a Forest Stream, Ecology (Durham), 83, 1689–1700, 2002.
Beusen, A. H. W., Dekkers, A. L. M., Bouwman, A. F., Ludwig, W., and Harrison, J.: Estimation of Global River Transport of Sediments and Associated Particulate C, N and P, Global Biogeochem. Cy., 19, GB4S05, https://doi.org/10.1029/2005GB002453, 2005.
Billen, G., Silvestre, M., Grizzetti, B., Leip, A., Bouraoui, F., Behrendt, H., Garnier, J., Humborg, C., Smedberg, E., Johnes, P. J., Kaste, O., Curtis, C., Lepisto, A., Kortelainen, P., Ganeshram, R., Beusen, A., and Voss, M.: Nitrogen flux to coastal waters from regional European watersheds, Chapter 13 in: European Nitrogen Assessment, edited by: Sutton, M. A., Howard, C. M., Erisman, J. W., Billen, G., Bleeker, A., Grennfelt, P., van Grinsven, H., and Grizzetti, B., Cambridge University Press, 271–297, ISBN: 9781107006126, 2011.
Blackwell, E., Mendes de Leon, C. F., and Miller, G. E.: Applying mixed regression models to the analysis of repeated-measures data in psychosomatic medicine, Psychosom. Med., 68, 870–878, 2006.
Boorman, D. B., Hollis, J. M., and Lilly, A.: Hydrology of Soil Types: A Hydrologically Based Classification of the Soils of the United Kingdom, Institute of Hydrology Report No. 126, 1995.
Brater, E. F. and King, H. W.: Handbook of hydraulics for the solution of hydraulic engineering problems, McGraw-Hill, New York, London, 1976.
Bristow, C. R., Barton, C. M., Westhead, R. K., Freshney, C. R., Cox, B. M., and Woods, M. A.: The Wincaton District: a concise account of the geology, Memoir for 1 : 50 000 Geological Sheet 297, British Geological Survey, Keyworth, Nottingham, 1999.
Burt, T. P., Howden, N. J., Worrall, F., Whelan, M. J., and Bieroza, M.: Nitrate in United Kingdom rivers: policy and its outcomes since 1970, Environ. Sci. Technol., 45, 175–181, 2011.
Carpenter, S. R., Caraco, N. F., Correll, D. L., Howarth, R. W., Sharpley, A. N., and Smith, V. H.: Nonpoint pollution of surface waters with phosphorus and nitrogen, Ecol. Appl., 8, 559–568, 1998.
Chittleborough, D. J., Smettem, K. R. J., Cotsaris, E., and Leaney, F. W.: Seasonal changes in path-ways of dissolved organic carbon through a hillslope soil (xeralf) with contrasting texture, Aust. J. Soil Res., 30, 465–476, 1992.
Dagg, M., Benner, R., Lhrenz, S., and Lawrence, D.: Transformation of Dissolved and Particulate Materials on Continental Shelves Influenced by Large Rivers: Plume Processes, Cont. Shelf Res., 24, 833–858, 2004.
Davies, H. and Neal, C.: Estimating nutrient concentrations from catchment characteristics across the UK, Hydrol. Earth Syst. Sci., 11, 550–558, https://doi.org/10.5194/hess-11-550-2007, 2007.
Department for Environment Food & Rural Affairs: a Diffuse Pollution Review, Defra, London, 2002.
Dodds, W. K., Marti, E., Tank, J. L., Pontius, J., and Hamilton, S. K.: Carbon and nitrogen stoichiometry and nitrogen cycling rates in streams, Oecologia, 140, 458–467, 2004.
Durand, P., Breur, L., Johnes, P. J., van Grinsven, H., Butturini, A., Billen, G., Garnier, J., Maberley, S., Carvalho, L., Reay, D., and Curtis, C.: Nitrogen turnover processes and effects in aquatic ecosystems, Chapter 7, in: European Nitrogen Assessment, edited by: Sutton, M. A., Howard, C. M., Erisman, J. W., Billen, G., Bleeker, A., Grennfelt, P., van Grinsven, H., and Grizzetti, B., Cambridge University Press, 126–146, ISBN: 9781107006126, 2011.
Field, A.: Discovering statistics using SPSS for Windows, Sage Publications Ltd., London, 2000.
Frost, P. C., Larson, J. H., Johnston, C. A., Young, K. C., Maurice, P. A., Lamberti, G. A., and Bridgham, S. D.: Landscape predictors of stream dissolved organic matter concentration and physicochemistry in a Lake Superior river watershed, Aquat. Sci., 68, 40–51, https://doi.org/10.1007/s00027-005-0802-5, 2006.
Galloway, J. N. and Cowling, E. B.: Reactive nitrogen and the world: 200 years of change, Ambio, 31, 64–71, 2002.
Godsey, S. E., Kirchner, J. W., and Clow, D. W.: Concentration-discharge relationships reflect chemostatic characteristics of US catchments, Hydrol. Process., 23, 1844–1864, 2009.
Goodale, C. L., Aber, J. D., Vitousek, P. M., and McDowell, W. H.: Long-term decreases in stream nitrate: Successional causes unlikely; Possible links to DOC?, Ecosystems, 8, 334–337, https://doi.org/10.1007/s10021-003-0162-8, 2005.
Grebliunas, B. D. and Perry, W. L.: The role of C : N : P stoichiometry in affecting denitrification in sediments from agricultural surface and tile-water wetlands, SpringerPlus, 5, 359, https://doi.org/10.1186/s40064-016-1820-6, 2016.
Gustard, A., Bullock, A., and Dixon, J. M.: Low flow estimation in the United Kingdom, Institute of Hydrology, Report No. 108, Institute of Hydrology, 292 pp., 1992.
Heathwaite, A. L.: Multiple stressors on water availability at global to catchment scales: understanding human impact on nutrient cycles to protect water quality and water availability in the long term, Freshwater Biol., 55, 241–257, https://doi.org/10.1111/j.1365-2427.2009.02368.x, 2010.
Heppell, C. M. and Binley, A.: Hampshire Avon: Daily discharge, stage and water chemistry data from four tributaries (Sem, Nadder, West Avon, Ebble), NERC Environmental Information Data Centre, https://doi.org/10.5285/0dd10858-7b96-41f1-8db5-e7b4c4168af5, 2016a.
Heppell, C. M. and Binley, A.: Hampshire Avon: Vertical head gradient, saturated hydraulic conductivity and pore water chemistry data from six river reaches, NERC Environmental Information Data Centre, https://doi.org/10.5285/d82a04ce-f04d-40b4-9750-1a2bf7dc29a3, 2016b.
Howden, N. J. K., Burt, T. P., Worrall, F., Mathias, S., and Whelan, M. J.: Nitrate pollution in intensively farmed regions: what are the prospects for sustaining high-quality groundwater?, Water Resour. Res., 47, W00L02, https://doi.org/10.1029/2011WR010843, 2011.
Howarth, R. W., Swaney, D., Billen, G., Garnier, J., Hong, B., Humborg, C., Johnes, P. J., Morth, M., and Marino, R.: Nitrogen Fluxes from the Landscape are Controlled by Net Anthropogenic Nitrogen Inputs and by Climate, Front. Ecol. Environ., 10, 37–43, https://doi.org/10.1890/100178, 2012.
Jardine, P. M., Wilson, G. V., McCarthy, J. F., Luxmoore, R. J., Taylor, D. L., and Zelany, L. W.: Hydrogeochemical processes controlling the transport of dissolved organic carbon through a forested hill-slope, J. Environ. Contam. Hydrol., 6, 3–19, 1990.
Jin, L., Whitehead, P. G., Heppell, C. M., Lansdown, K., Purdie, D. A., and Trimmer, M.: Modelling flow and inorganic nitrogen dynamics on the Hampshire Avon: Linking upstream processes to downstream water quality, Sci. Total Environ., 572, 1496–1506, 2016.
Jiang, R., Woli, K. P., Kuramochi, K., Hayakawa, A., Shimizu, M., and Hatano, R.: Hydrological process controls on nitrogen export during storm events in an agricultural watershed, Soil Sci. Plant. Nutr., 56, 72–85, 2010.
International Organization for Standardization: ISO 1088, Hydrometry – Velocity-area Methods Using Current-Meters – Collection and Processing of Data for Determination of Uncertainties in Flow Measurement, ISO Standards, 2007.
International Organization for Standardization: ISO 1100-2, Hydrometry – Measurement of Liquid Flow in Open Channels – Part 2: Determination of the Stage-discharge Relationship, ISO Standards, 2010.
Lloyd, C. E. M., Freer, J. E., Johnes, P. J., Coxon, G., and Collins, A. L.: Discharge and nutrient uncertainty: implications for nutrient flux estimation in small streams, Hydrol. Proc., 30, 135–152, 2016a.
Lloyd, C. E. M., Freer, J. E., Johnes, P. J., and Collins, A. L.: Using hysteresis analysis of high-resolution water quality monitoring data, including uncertainty, to infer controls on nutrient and sediment transfer in catchments, Sci. Total Environ., 543, 388–404, 2016b.
McGonigle, D. F., Burke, S. P., Collins, A. L., Gartner, R., Haft, M. R., Harris, R. C., Haygarth, P. M., Hedges, M. C., Hiscock, K. M., and Lovett, A. A.: Developing Demonstration Test Catchments as a platform for transdisciplinary land management research in England Wales, Environ. Sci.-Proc. Imp., 16, 1618–1628, 2014.
Morel, B., Durand, P., Jaffrezic, A., Gruau, G., and Molenat, J.: Sources of dissolved organic carbon during stormflow in a headwater agricultural catchment, Hydrol. Proc., 23, 2888–2901, https://doi.org/10.1002/hyp.7379, 2009.
Mulholland, P. J., Dahm, C. N., Dodds, W. K., Gregory, S. V., Grimm, N. B., Hall Jr., R. O., Hamilton, S. K., Johnson, S. L., Peterson, B. J., McDowell, W. H., Meyer, J. L.,Tank, J. L., Valett, H. M., and Webster, J. R.: Lotic intersite nitrogen eXperiment II (LINX II): A cross-site study of the effects of anthropogenic land use change on nitrate uptake and retention in 72 streams across 8 different biomes (2003–2006), Lotic Intersite Nitrogen Experiment available at: http://andrewsforest.oregonstate.edu/data/abstract.cfm?dbcode=AN006, 2015.
Neff, J. C. and Asner, G. P.: Dissolved Organic Carbon in Terrestrial Ecosystems: Synthesis and a Model, Ecosystems, 4, 29–48, https://doi.org/10.1007/s100210000058, 2001.
Oeurng, C., Sauvage, S., Coynel, A., Maneux, E., Etcheber, H., and Sánchez-Pérez, J.-M.: Fluvial transport of suspended sediment and organic carbon during flood events in a large agricultural catchment in southwest France, Hydrol. Proc., 25, 2365–2378, https://doi.org/10.1002/hyp.7999, 2011.
Orr, R. J., Murray, P. J., Eyles, C. J., Blackwell, M. S. A., Cardenas, L. M., Collins, A. L., Dungait, J. A. J., Goulding, K. W. T., Griffith, B. A., Gurr, S. J., Harris, P., Hawkins, J. M. B., Misselbrook, T. H., Rawlings, C., Shepherd, A., Sint, H., Takahashi, T., Tozer, K. N., Whitmore, A. P., Wu, L., and Lee, M. R. F.: The North Wyke Farm Platform: effect of temperate grassland farming systems on soil moisture contents, runoff and associated water quality dynamics, Eur. J. Soil Sci., 67, 374–385, 2016.
Outram, F. N., Lloyd, C. E. M., Jonczyk, J., Benskin, C. McW. H., Grant, F., Perks, M. T., Deasy, C., Burke, S. P., Collins, A. L., Freer, J., Haygarth, P. M., Hiscock, K. M., Johnes, P. J., and Lovett, A. L.: High-frequency monitoring of nitrogen and phosphorus response in three rural catchments to the end of the 2011–2012 drought in England, Hydrol. Earth Syst. Sci., 18, 3429–3448, https://doi.org/10.5194/hess-18-3429-2014, 2014.
Parliamentary Office of Science and Technology (POST): Diffuse pollution of water by agriculture, Postnote, 478, October 2014.
Pinheiro, J., Bates, D., DebRoy, S., Sarkar, D., and R Core Team: nlme: Linear and Nonlinear Mixed Effects Models, R package version 3.1-128, available at: http://CRAN.R-project.org/package=nlme, 2016.
Prior, H. and Johnes, P. J.: Regulation of surface water quality in a Chalk catchment, UK: an assessment of the relative importance of instream and wetland processes, Sci. Total Environ., 282/283, 159–174, 2002.
Rabalais, N. N.: Nitrogen in aquatic ecosystems, Ambio, 31, 102–112, 2002.
R Core Team: a languae and environment for statistical computing, R Foundation for Statistical Computing, Vienna, Austria, https://www.R-project.org/, 2016.
Rodríguez-Cardona, B., Wymore, A. S., and McDowell, W. H.: DOC : NO3 ratios and NO3 uptake in forested headwater streams, J. Geophys. Res.-Biogeo., 121, 205–217, 2016.
Sandford, R. C., Hawkins, J. M. B., Bol, R., and Worsfold, P. J.: Export of dissolved organic carbon and nitrate from grassland in winter using high temporal resolution, in situ UV sensing, Sci. Total Environ., 456–457, 384–391, 2013.
Seibert, J., Grabs, T., Köhler, S., Laudon, H., Winterdahl, M., and Bishop, K.: Linking soil- and stream-water chemistry based on a Riparian Flow-Concentration Integration Model, Hydrol. Earth Syst. Sci., 13, 2287–2297, https://doi.org/10.5194/hess-13-2287-2009, 2009.
Stanley, E. H., Powers, S. M., Lottig, N. R., Buffam, I., and Crawford, J. T.: Contemporary changes in dissolved organic carbon (DOC) in human-dominated rivers: is there a role for DOC management?, Freshwater Biol., 57, 26–42, https://doi.org/10.1111/j.1365-2427.2011.02613.x, 2012.
Taylor, P. G. and Townsend, A. R.: Stoichiometric control of organic carbon-nitrate relationships from soils to the sea, Nature, 464, 1178–1181, https://doi.org/10.1038/nature08985, 2010.
Tesoriero, A. J., Duff, J. H., Saad, D. A., Spahr, N. E., and Wolock, D. M.: Vulnerability of streams to legacy nitrate sources, Environ. Sci. Technol., 47, 3623–3629, https://doi.org/10.1021/es305026x, 2013.
Thomas, Z., Abbott, B. W., Troccaz, O., Baudry, J., and Pinay, G.: Proximate and ultimate controls on carbon and nutrient dynamics of small agricultural catchments, Biogeosciences, 13, 1863–1875, https://doi.org/10.5194/bg-13-1863-2016, 2016.
Tiemeyer, B. and Kahle, P.: Nitrogen and dissolved organic carbon (DOC) losses from an artificially drained grassland on organic soils, Biogeosciences, 11, 4123–4137, https://doi.org/10.5194/bg-11-4123-2014, 2014.
Vitousek, P. M., Aber, J. D., Howarth, R. W., Likens, G. E., Matson, P. A., Schindler, D. W., Schlesinger, W. H., and Tilman, D.: Human alteration of the global nitrogen cycle: Sources and consequences, Ecol. Appl., 7, 737–750, https://doi.org/10.2307/2269431, 1997.
Vitousek, P. M., Naylor, R., Crews, T., David, M. B., Drinkwater, L. E., Johnes, P. J., Katzenberger, J., Martinelli, L. A., Matson, P. A., Nziguheba, G., Ojima, D., Palm, C., Robertson, G. P., Sanchez, P. A., Townsend, A. R., and Zhang, F.: Nutrient imbalances in agricultural development, Science, 326, 1319–1320, 2009.
Wang, L., Stuart, M. E., Bloomfield, J. P., Butcher, A. S., and Gooddy, D. C.: Prediction of the arrival of peak nitrate concentrations at the water table at the regional scale in Great Britain, Hydrol. Proc., 26, 226–239, 2012.
Wang, L., Butcher, A. S., Stuart, M. E., Gooddy, D. C., and Bloomfield, J. P.: The nitrate time bomb: a numerical way to investigate nitrate storage and lag time in the USZ, Environ. Geochem. Hlth., 35, 667–681, 2013.
Wang, L., Stuart, M. E., Lewis, M. A., Ward, R. S., Skirvin, D., Naden, P. S., A. L. Collins, and Ascott, M. J.: The changing trend in nitrate concentrations in major aquifers due to historical nitrate loading from agricultural land across England and Wales from 1925 to 2150, Sci. Total Environ., 542, 694–705, 2016.
Watts, G., Battarbee, R. W., Bloomfield, J. P., Crossman, J., and Daccache, A.: Climate change and water in the UK – past changes and future prospects, Prog. Phys. Geog., 39, 6–28, 2015.
Whitehead, P. G., Wilby, R. L., Butterfield, D., and Wade, A. J.: Impacts of climate change on in-stream nitrogen in a lowland chalk stream: an appraisal of adaptation strategies, Sci. Total Environ., 365, 260–273, 2006.
Whitehead, P. G., Wilby, R. L., Battarbee, R. W., Kernan, M., and Wade, A. J.: A review of the potential impacts of climate change on surface water quality, Hydrol. Sci. J., 54, 101–123, 2009.
Withers, P. J. A., Neal, C., Jarvie, H. P., and Doody, D. G.: Agriculture and Eutrophication: Where Do We Go from Here?, Sustainability, 6, 5853–5875, https://doi.org/10.3390/su6095853, 2014.
Yang, X.-L., Li, T.-K., Hua, K.-K., and Zhang, Y.-L.: Investigation of first flushes in a small rural-agricultural catchment, Pol. J. Environ. Stud., 24, 381–389, 2015.
Yates, C. A. and Johnes, P. J.: Nitrogen speciation and phosphorus fractionation dynamics in a lowland chalk catchment: the Upper Wylye, Sci. Total Environ., 444, 466–479, https://doi.org/10.1016/j.scitotenv.2012.12.002, 2013.
Yates, C. A., Johnes, P. J., and Spencer, R. G. M.: Assessing the drivers of dissolved organic matter export from two contrasting lowland catchments, UK, Sci. Total Environ., 569–570, 1330–1340, https://doi.org/10.1016/j.scitotenv.2016.06.211, 2016.
Short summary
The role that hydrology plays in controlling the interplay between dissolved organic carbon (DOC) and nitrogen in rivers of lowland, agricultural landscapes is poorly understood, yet important to assess given the potential changes to production and delivery of DOC and nitrate arising from climate change. We measured DOC and nitrate concentrations in river water of the lowland river Hampshire Avon (Wiltshire, southern UK), revealing significant seasonal variations in DOC : nitrate transport.
The role that hydrology plays in controlling the interplay between dissolved organic carbon...