Articles | Volume 25, issue 9
https://doi.org/10.5194/hess-25-5219-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/hess-25-5219-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Technical note
| 
27 Sep 2021
Technical note |
| 27 Sep 2021
| 27 Sep 2021
Technical note: Unresolved aspects of the direct vapor equilibration method for stable isotope analysis (δ18O, δ2H) of matrix-bound water: unifying protocols through empirical and mathematical scrutiny
Benjamin Gralher
CORRESPONDING AUTHOR
Chair of Hydrology, University of Freiburg, Freiburg 79098, Germany
Barbara Herbstritt
Chair of Hydrology, University of Freiburg, Freiburg 79098, Germany
Markus Weiler
Chair of Hydrology, University of Freiburg, Freiburg 79098, Germany
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Hydrol. Earth Syst. Sci., 27, 3701–3718, https://doi.org/10.5194/hess-27-3701-2023, https://doi.org/10.5194/hess-27-3701-2023, 2023
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We present a method to collect water vapor samples into bags in the field without an in-field analyser, followed by isotope analysis in the lab. This new method resolves even fine-scaled natural isotope variations. It combines low-cost and lightweight components for maximum spatial and temporal flexibility regarding environmental setups. Hence, it allows for sampling even in terrains that are rather difficult to access, enabling future extended isotope datasets in soil sciences and ecohydrology.
Ruth-Kristina Magh, Benjamin Gralher, Barbara Herbstritt, Angelika Kübert, Hyungwoo Lim, Tomas Lundmark, and John Marshall
Hydrol. Earth Syst. Sci., 26, 3573–3587, https://doi.org/10.5194/hess-26-3573-2022, https://doi.org/10.5194/hess-26-3573-2022, 2022
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We developed a method of sampling and storing water vapour for isotope analysis, allowing us to infer plant water uptake depth. Measurements can be made at high temporal and spatial resolution even in remote areas. We ensured that all necessary components are easily available, making this method cost efficient and simple to implement. We found our method to perform well in the lab and in the field, enabling it to become a tool for everyone aiming to resolve questions regarding the water cycle.
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We describe a novel technique for the precise, quasi real-time observation of water-stable isotopes in gross precipitation and throughfall from tree canopies in parallel. Various processes (e.g. rainfall intensity, evapotranspiration, exchange with ambient vapour) thereby control throughfall intensity and isotopic composition. The achieved temporal resolution now competes with common meteorological measurements, thus enabling new ways to employ water-stable isotopes in forested catchments.
Natalie Orlowski, Lutz Breuer, Nicolas Angeli, Pascal Boeckx, Christophe Brumbt, Craig S. Cook, Maren Dubbert, Jens Dyckmans, Barbora Gallagher, Benjamin Gralher, Barbara Herbstritt, Pedro Hervé-Fernández, Christophe Hissler, Paul Koeniger, Arnaud Legout, Chandelle Joan Macdonald, Carlos Oyarzún, Regine Redelstein, Christof Seidler, Rolf Siegwolf, Christine Stumpp, Simon Thomsen, Markus Weiler, Christiane Werner, and Jeffrey J. McDonnell
Hydrol. Earth Syst. Sci., 22, 3619–3637, https://doi.org/10.5194/hess-22-3619-2018, https://doi.org/10.5194/hess-22-3619-2018, 2018
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To extract water from soils for isotopic analysis, cryogenic water extraction is the most widely used removal technique. This work presents results from a worldwide laboratory intercomparison test of cryogenic extraction systems. Our results showed large differences in retrieved isotopic signatures among participating laboratories linked to interactions between soil type and properties, system setup, extraction efficiency, extraction system leaks, and each lab’s internal accuracy.
Robin Schwemmle, Hannes Leistert, Andreas Steinbrich, and Markus Weiler
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The new process-based hydrological toolbox model, RoGeR (https://roger.readthedocs.io/), can be used to estimate the components of the hydrological cycle and the related travel times of pollutants through parts of the hydrological cycle. These estimations may contribute to effective water resources management. This paper presents the toolbox concept and provides a simple example of providing estimations to water resources management.
Jonas Pyschik, Stefan Seeger, Barbara Herbstritt, and Markus Weiler
EGUsphere, https://doi.org/10.5194/egusphere-2024-528, https://doi.org/10.5194/egusphere-2024-528, 2024
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We developed a device which automates the analysis process of stable water isotopes. Stable water isotopes are a natural tracer which many researchers use to investigate water (re-)distribution processes in environmental systems. The device helps to analyse such environmental samples by automating a formerly tidious manual labor process, alowwing for a higher sample throughput. This enables larger sampling campaigns, since more samples can be processed before reaching their limited storage time.
Barbara Herbstritt, Benjamin Gralher, Stefan Seeger, Michael Rinderer, and Markus Weiler
Hydrol. Earth Syst. Sci., 27, 3701–3718, https://doi.org/10.5194/hess-27-3701-2023, https://doi.org/10.5194/hess-27-3701-2023, 2023
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We present a method to collect water vapor samples into bags in the field without an in-field analyser, followed by isotope analysis in the lab. This new method resolves even fine-scaled natural isotope variations. It combines low-cost and lightweight components for maximum spatial and temporal flexibility regarding environmental setups. Hence, it allows for sampling even in terrains that are rather difficult to access, enabling future extended isotope datasets in soil sciences and ecohydrology.
Stefan Seeger and Markus Weiler
Hydrol. Earth Syst. Sci., 27, 3393–3404, https://doi.org/10.5194/hess-27-3393-2023, https://doi.org/10.5194/hess-27-3393-2023, 2023
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This study proposes a low-budget method to quantify the radial distribution of water transport velocities within trees at a high spatial resolution. We observed a wide spread of water transport velocities within a tree stem section, which were on average 3 times faster than the flux velocity. The distribution of transport velocities has implications for studies that use water isotopic signatures to study root water uptake and usually assume uniform or even implicitly infinite velocities.
Andreas Hänsler and Markus Weiler
Hydrol. Earth Syst. Sci., 26, 5069–5084, https://doi.org/10.5194/hess-26-5069-2022, https://doi.org/10.5194/hess-26-5069-2022, 2022
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Spatially explicit quantification of design storms is essential for flood risk assessment and planning. However, available datasets are mainly based on spatially interpolated station-based design storms. Since the spatial interpolation of the data inherits a large potential for uncertainty, we develop an approach to be able to derive spatially explicit design storms on the basis of weather radar data. We find that our approach leads to an improved spatial representation of design storms.
Anne Hartmann, Markus Weiler, Konrad Greinwald, and Theresa Blume
Hydrol. Earth Syst. Sci., 26, 4953–4974, https://doi.org/10.5194/hess-26-4953-2022, https://doi.org/10.5194/hess-26-4953-2022, 2022
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Analyzing the impact of soil age and rainfall intensity on vertical subsurface flow paths in calcareous soils, with a special focus on preferential flow occurrence, shows how water flow paths are linked to the organization of evolving landscapes. The observed increase in preferential flow occurrence with increasing moraine age provides important but rare data for a proper representation of hydrological processes within the feedback cycle of the hydro-pedo-geomorphological system.
Ruth-Kristina Magh, Benjamin Gralher, Barbara Herbstritt, Angelika Kübert, Hyungwoo Lim, Tomas Lundmark, and John Marshall
Hydrol. Earth Syst. Sci., 26, 3573–3587, https://doi.org/10.5194/hess-26-3573-2022, https://doi.org/10.5194/hess-26-3573-2022, 2022
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We developed a method of sampling and storing water vapour for isotope analysis, allowing us to infer plant water uptake depth. Measurements can be made at high temporal and spatial resolution even in remote areas. We ensured that all necessary components are easily available, making this method cost efficient and simple to implement. We found our method to perform well in the lab and in the field, enabling it to become a tool for everyone aiming to resolve questions regarding the water cycle.
Nils Hinrich Kaplan, Theresa Blume, and Markus Weiler
Hydrol. Earth Syst. Sci., 26, 2671–2696, https://doi.org/10.5194/hess-26-2671-2022, https://doi.org/10.5194/hess-26-2671-2022, 2022
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This study is analyses how characteristics of precipitation events and soil moisture and temperature dynamics during these events can be used to model the associated streamflow responses in intermittent streams. The models are used to identify differences between the dominant controls of streamflow intermittency in three distinct geologies of the Attert catchment, Luxembourg. Overall, soil moisture was found to be the most important control of intermittent streamflow in all geologies.
Jan Greiwe, Markus Weiler, and Jens Lange
Biogeosciences, 18, 4705–4715, https://doi.org/10.5194/bg-18-4705-2021, https://doi.org/10.5194/bg-18-4705-2021, 2021
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We analyzed variability in diel nitrate patterns at three locations in a lowland stream. Comparison of time lags between monitoring sites with water travel time indicated that diel patterns were created by in-stream processes rather than transported downstream from an upstream point of origin. Most of the patterns (70 %) could be explained by assimilatory nitrate uptake. The remaining patterns suggest seasonally varying dominance and synchronicity of different biochemical processes.
Stefan Seeger and Markus Weiler
Biogeosciences, 18, 4603–4627, https://doi.org/10.5194/bg-18-4603-2021, https://doi.org/10.5194/bg-18-4603-2021, 2021
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We developed a setup for fully automated in situ measurements of stable water isotopes in soil and the stems of fully grown trees. We used this setup in a 12-week field campaign to monitor the propagation of a labelling pulse from the soil up to a stem height of 8 m.
We could observe trees shifting their main water uptake depths multiple times, depending on water availability.
The gained knowledge about the temporal dynamics can help to improve water uptake models and future study designs.
Andreas Hänsler and Markus Weiler
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2021-366, https://doi.org/10.5194/hess-2021-366, 2021
Manuscript not accepted for further review
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Spatially explicit quantification on design storms are essential for flood risk assessment. However this information can be only achieved from substantially long records of rainfall measurements, usually only available for a few stations. Hence, design storms estimates from these few stations are then spatially interpolated leading to a major source of uncertainty. Therefore we defined a methodology to extend spatially explicit weather radar data to be used for the estimation of design storms.
Anne Hartmann, Markus Weiler, Konrad Greinwald, and Theresa Blume
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2021-242, https://doi.org/10.5194/hess-2021-242, 2021
Manuscript not accepted for further review
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Our field observation-based examination of flow path evolution, soil formation and vegetation succession across ten millennia on calcareous parent material shows how water flow paths and subsurface water storage are linked to the organization of evolving landscapes. We provide important but rare data and observations for a proper handling of hydrologic processes and their role within the feedback cycle of the hydro-pedo-geomorphological system.
Axel Schaffitel, Tobias Schuetz, and Markus Weiler
Geosci. Model Dev., 14, 2127–2142, https://doi.org/10.5194/gmd-14-2127-2021, https://doi.org/10.5194/gmd-14-2127-2021, 2021
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This paper presents FluSM, an algorithm to derive the water balance from soil moisture and metrological measurements. This data-driven water balance framework uses soil moisture as an input and therefore is applicable for cases with unclear processes and lacking parameters. In a case study, we apply FluSM to derive the water balance of 15 different permeable pavements under field conditions. These findings are of special interest for urban hydrology.
Robin Schwemmle, Dominic Demand, and Markus Weiler
Hydrol. Earth Syst. Sci., 25, 2187–2198, https://doi.org/10.5194/hess-25-2187-2021, https://doi.org/10.5194/hess-25-2187-2021, 2021
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A better understanding of the reasons why model performance is unsatisfying represents a crucial part for meaningful model evaluation. We propose the novel diagnostic efficiency (DE) measure and diagnostic polar plots. The proposed evaluation approach provides a diagnostic tool for model developers and model users and facilitates interpretation of model performance.
Michael Rinderer, Jaane Krüger, Friederike Lang, Heike Puhlmann, and Markus Weiler
Biogeosciences, 18, 1009–1027, https://doi.org/10.5194/bg-18-1009-2021, https://doi.org/10.5194/bg-18-1009-2021, 2021
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We quantified the lateral and vertical subsurface flow (SSF) and P concentrations of three beech forest plots with contrasting soil properties during sprinkling experiments. Vertical SSF was 2 orders of magnitude larger than lateral SSF, and both consisted mainly of pre-event water. P concentrations in SSF were high during the first 1 to 2 h (nutrient flushing) but nearly constant thereafter. This suggests that P in the soil solution was replenished fast by mineral or organic sources.
Merle Koelbing, Tobias Schuetz, and Markus Weiler
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2021-24, https://doi.org/10.5194/hess-2021-24, 2021
Revised manuscript not accepted
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Based on a unique and comprehensive data set of urban micro-meteorological variables, which were observed with a mobile climate station, we developed a new method to transfer mesoscale reference potential evapotranspiration to the urban microscale in street canyons. Our findings can be transferred easily to existing urban hydrologic models to improve modelling results with a more precise estimate of potential evapotranspiration on street level.
Anne Hartmann, Markus Weiler, and Theresa Blume
Earth Syst. Sci. Data, 12, 3189–3204, https://doi.org/10.5194/essd-12-3189-2020, https://doi.org/10.5194/essd-12-3189-2020, 2020
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Our analysis of soil physical and hydraulic properties across two soil chronosequences of 10 millennia in the Swiss Alps provides important observation of the evolution of soil hydraulic behavior. A strong co-evolution of soil physical and hydraulic properties was revealed by the observed change of fast-draining coarse-textured soils to slow-draining soils with a high water-holding capacity in correlation with a distinct change in structural properties and organic matter content.
Daniel Beiter, Markus Weiler, and Theresa Blume
Hydrol. Earth Syst. Sci., 24, 5713–5744, https://doi.org/10.5194/hess-24-5713-2020, https://doi.org/10.5194/hess-24-5713-2020, 2020
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We investigated the interactions between streams and their adjacent hillslopes in terms of water flow. It could be revealed that soil structure has a strong influence on how hillslopes connect to the streams, while the groundwater table tells us a lot about when the two connect. This observation could be used to improve models that try to predict whether or not hillslopes are in a state where a rain event will be likely to produce a flood in the stream.
Maria Staudinger, Stefan Seeger, Barbara Herbstritt, Michael Stoelzle, Jan Seibert, Kerstin Stahl, and Markus Weiler
Earth Syst. Sci. Data, 12, 3057–3066, https://doi.org/10.5194/essd-12-3057-2020, https://doi.org/10.5194/essd-12-3057-2020, 2020
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The data set CH-IRP provides isotope composition in precipitation and streamflow from 23 Swiss catchments, being unique regarding its long-term multi-catchment coverage along an alpine–pre-alpine gradient. CH-IRP contains fortnightly time series of stable water isotopes from streamflow grab samples complemented by time series in precipitation. Sampling conditions, catchment and climate information, lab standards and errors are provided together with areal precipitation and catchment boundaries.
Nils Hinrich Kaplan, Theresa Blume, and Markus Weiler
Hydrol. Earth Syst. Sci., 24, 5453–5472, https://doi.org/10.5194/hess-24-5453-2020, https://doi.org/10.5194/hess-24-5453-2020, 2020
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In recent decades the demand for detailed information of spatial and temporal dynamics of the stream network has grown in the fields of eco-hydrology and extreme flow prediction. We use temporal streamflow intermittency data obtained at various sites using innovative sensing technology as well as spatial predictors to predict and map probabilities of streamflow intermittency. This approach has the potential to provide intermittency maps for hydrological modelling and management practices.
Michael Stoelzle, Maria Staudinger, Kerstin Stahl, and Markus Weiler
Proc. IAHS, 383, 43–50, https://doi.org/10.5194/piahs-383-43-2020, https://doi.org/10.5194/piahs-383-43-2020, 2020
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The role of recharge and catchment storage is crucial to understand streamflow drought sensitivity. Here we introduce a model experiment with recharge stress tests as complement to climate scenarios to quantify the streamflow drought sensitivities of catchments in Switzerland. We identified a pre-drought period of 12 months as maximum storage-memory for the study catchments. From stress testing, we found up to 200 days longer summer streamflow droughts and minimum flow reductions of 50 %–80 %.
Anne Hartmann, Ekaterina Semenova, Markus Weiler, and Theresa Blume
Hydrol. Earth Syst. Sci., 24, 3271–3288, https://doi.org/10.5194/hess-24-3271-2020, https://doi.org/10.5194/hess-24-3271-2020, 2020
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Our field observation-based examination of flow path evolution, soil formation, and vegetation succession across 10 millennia shows how water flow paths and subsurface water storage are linked to the organization of evolving landscapes.
The increase found in water storage and preferential flow paths with increasing soil age shows the effect of the complex interaction of vegetation and soil development on flow paths, water balance, and runoff formation during landscape evolution.
Mirko Mälicke, Sibylle K. Hassler, Theresa Blume, Markus Weiler, and Erwin Zehe
Hydrol. Earth Syst. Sci., 24, 2633–2653, https://doi.org/10.5194/hess-24-2633-2020, https://doi.org/10.5194/hess-24-2633-2020, 2020
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We could show that distributed soil moisture time series bear a considerable amount of information about dynamic changes in soil moisture. We developed a new method to describe spatial patterns and analyze their persistency. By combining uncertainty propagation with information theory, we were able to calculate the information content of spatial similarity with respect to measurement uncertainty. This does help to understand when and why the soil is drying in an organized manner.
Axel Schaffitel, Tobias Schuetz, and Markus Weiler
Earth Syst. Sci. Data, 12, 501–517, https://doi.org/10.5194/essd-12-501-2020, https://doi.org/10.5194/essd-12-501-2020, 2020
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This paper contains detailed information about the instrumentation of permeable pavements with soil moisture sensors and the performance of infiltration experiments on these surfaces. The collected data are beneficial for studying urban water and energy cycles. They contain valuable information about the hydrological behavior of permeable pavements and urban subsurface heat anomalies. Due to the lack of similar data, we are convinced that the dataset is of great scientific value.
Michael Stoelzle, Tobias Schuetz, Markus Weiler, Kerstin Stahl, and Lena M. Tallaksen
Hydrol. Earth Syst. Sci., 24, 849–867, https://doi.org/10.5194/hess-24-849-2020, https://doi.org/10.5194/hess-24-849-2020, 2020
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During dry weather, different delayed sources of runoff (e.g. from groundwater, wetlands or snowmelt) modulate the magnitude and variability of streamflow. Hydrograph separation methods often do not distinguish these delayed contributions and mostly pool them into only two components (i.e. quickflow and baseflow). We propose a method that uncovers multiple components and demonstrates how they better reflect streamflow generation processes of different flow regimes.
Fabian Ries, Lara Kirn, and Markus Weiler
Earth Syst. Sci. Data, 12, 245–255, https://doi.org/10.5194/essd-12-245-2020, https://doi.org/10.5194/essd-12-245-2020, 2020
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Pluvial or flash floods generated by heavy precipitation events cause large economic damage and loss of life worldwide. As discharge observations from such extreme occurrences are rare, data from artificial sprinkling experiments offer valuable information on runoff generation processes, overland and subsurface flow rates, and response times. A extensive data set from 132 large-scale sprinkling experiments in Germany is described and presented in this paper.
Dominic Demand, Theresa Blume, and Markus Weiler
Hydrol. Earth Syst. Sci., 23, 4869–4889, https://doi.org/10.5194/hess-23-4869-2019, https://doi.org/10.5194/hess-23-4869-2019, 2019
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This study presents an analysis of 135 soil moisture profiles for identification of the spatial and temporal preferential flow occurrence in a complex landscape. Especially dry conditions and high rainfall intensities were found to increase preferential flow occurrence in soils. This results in a seasonal pattern of preferential flow with a higher occurrence in summer. During this time grasslands showed increased flow velocities, whereas forest sites exhibited a higher amount of bypass flow.
Nils Hinrich Kaplan, Ernestine Sohrt, Theresa Blume, and Markus Weiler
Earth Syst. Sci. Data, 11, 1363–1374, https://doi.org/10.5194/essd-11-1363-2019, https://doi.org/10.5194/essd-11-1363-2019, 2019
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Different sensing techniques including time-lapse imagery, electric conductivity and stage measurements were used to generate a combined dataset of the presence and absence of streamflow within a large number of nested sub-catchments in the Attert catchment, Luxembourg. The first sites of observation were established in 2013 and successively extended to a total number of 182 in 2016. The dataset can be used to improve understanding of the temporal and spatial dynamics of the stream network.
Barbara Herbstritt, Benjamin Gralher, and Markus Weiler
Hydrol. Earth Syst. Sci., 23, 3007–3019, https://doi.org/10.5194/hess-23-3007-2019, https://doi.org/10.5194/hess-23-3007-2019, 2019
Short summary
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We describe a novel technique for the precise, quasi real-time observation of water-stable isotopes in gross precipitation and throughfall from tree canopies in parallel. Various processes (e.g. rainfall intensity, evapotranspiration, exchange with ambient vapour) thereby control throughfall intensity and isotopic composition. The achieved temporal resolution now competes with common meteorological measurements, thus enabling new ways to employ water-stable isotopes in forested catchments.
Jobin Joseph, Christoph Külls, Matthias Arend, Marcus Schaub, Frank Hagedorn, Arthur Gessler, and Markus Weiler
SOIL, 5, 49–62, https://doi.org/10.5194/soil-5-49-2019, https://doi.org/10.5194/soil-5-49-2019, 2019
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By coupling an OA-ICOS with hydrophobic but gas-permeable membranes placed at different depths in acidic and calcareous soils, we investigated the contribution of abiotic and biotic components to total soil CO2 release. In calcareous Gleysol, CO2 originating from carbonate dissolution contributed to total soil CO2 concentration at detectable degrees, probably due to CO2 evasion from groundwater. Inward diffusion of atmospheric CO2 was found to be pronounced in the topsoil layers at both sites.
Mirko Mälicke, Sibylle K. Hassler, Markus Weiler, Theresa Blume, and Erwin Zehe
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2018-396, https://doi.org/10.5194/hess-2018-396, 2018
Manuscript not accepted for further review
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In this study we use time dependent variograms to identify periods of organized soil moisture during drying. We could identify emerging spatial patterns which imply periods of terrestrial control on soil moisture organization. The coupling of time dependent variograms with density based clustering is a new approach to detect similarity in spatial patterns. The presented method is useful to describe states of organization and improve kriging workflows by extending their prerequisites.
Jana von Freyberg, Scott T. Allen, Stefan Seeger, Markus Weiler, and James W. Kirchner
Hydrol. Earth Syst. Sci., 22, 3841–3861, https://doi.org/10.5194/hess-22-3841-2018, https://doi.org/10.5194/hess-22-3841-2018, 2018
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We explored how the fraction of streamflow younger than ca. 3 months (Fyw) varies with landscape characteristics and climatic forcing, using an extensive isotope data set from 22 Swiss catchments. Overall, Fyw tends to be larger when catchments are wet and discharge is correspondingly higher, indicating an increase in the proportional contribution of faster flow paths at higher flows. We quantify this
discharge sensitivityof Fyw and relate it to the dominant streamflow-generating mechanisms.
Natalie Orlowski, Lutz Breuer, Nicolas Angeli, Pascal Boeckx, Christophe Brumbt, Craig S. Cook, Maren Dubbert, Jens Dyckmans, Barbora Gallagher, Benjamin Gralher, Barbara Herbstritt, Pedro Hervé-Fernández, Christophe Hissler, Paul Koeniger, Arnaud Legout, Chandelle Joan Macdonald, Carlos Oyarzún, Regine Redelstein, Christof Seidler, Rolf Siegwolf, Christine Stumpp, Simon Thomsen, Markus Weiler, Christiane Werner, and Jeffrey J. McDonnell
Hydrol. Earth Syst. Sci., 22, 3619–3637, https://doi.org/10.5194/hess-22-3619-2018, https://doi.org/10.5194/hess-22-3619-2018, 2018
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To extract water from soils for isotopic analysis, cryogenic water extraction is the most widely used removal technique. This work presents results from a worldwide laboratory intercomparison test of cryogenic extraction systems. Our results showed large differences in retrieved isotopic signatures among participating laboratories linked to interactions between soil type and properties, system setup, extraction efficiency, extraction system leaks, and each lab’s internal accuracy.
Jakob Sohrt, Heike Puhlmann, and Markus Weiler
SOIL Discuss., https://doi.org/10.5194/soil-2018-13, https://doi.org/10.5194/soil-2018-13, 2018
Revised manuscript not accepted
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We sampled concentrations of phosphorus (P) in laterally flowing water in the organic layer of three beech forest sites. Sampling frequency was in the range to minutes to ours with the intent of capturing short term variability of this parameter and the underlying mechanisms, which were analyzed with a modeling approach. While site affiliation was found to be a strong influence on P concentrations in lateral flow, some universal effects – like antecedent soil moisture – could also be determined.
Daphné Freudiger, David Mennekes, Jan Seibert, and Markus Weiler
Earth Syst. Sci. Data, 10, 805–814, https://doi.org/10.5194/essd-10-805-2018, https://doi.org/10.5194/essd-10-805-2018, 2018
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To understand glacier changes in the Swiss Alps at the large scale, long-term datasets are needed. To fill the gap between the existing glacier inventories of the Swiss Alps between 1850 and 1973, we digitized glacier outlines from topographic historical maps of Switzerland for the time periods ca. 1900 and ca. 1935. We found that > 88 % of the digitized glacier area was plausible compared to four inventories. The presented dataset is therefore valuable information for long-term glacier studies.
Michael P. Schwab, Julian Klaus, Laurent Pfister, and Markus Weiler
Biogeosciences, 15, 2177–2188, https://doi.org/10.5194/bg-15-2177-2018, https://doi.org/10.5194/bg-15-2177-2018, 2018
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We studied the diel fluctuations of dissolved organic carbon (DOC) concentrations in a small stream in Luxembourg. We identified an increased proportion of DOC from terrestrial sources as responsible for the peaks in DOC in the afternoon. Warmer water temperatures in the riparian zone in the afternoon increased the amount of water flowing towards the stream. Consequently, an increased amount of DOC-rich water from the riparian zone was entering the stream.
Jan Seibert, Marc J. P. Vis, Irene Kohn, Markus Weiler, and Kerstin Stahl
Hydrol. Earth Syst. Sci., 22, 2211–2224, https://doi.org/10.5194/hess-22-2211-2018, https://doi.org/10.5194/hess-22-2211-2018, 2018
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In many glacio-hydrological models glacier areas are assumed to be constant over time, which is a crucial limitation. Here we describe a novel approach to translate mass balances as simulated by the (glacio)hydrological model into glacier area changes. We combined the Δh approach of Huss et al. (2010) with the bucket-type model HBV and introduced a lookup table approach, which also allows periods with advancing glaciers to be represented, which is not possible with the original Huss method.
Sibylle Kathrin Hassler, Markus Weiler, and Theresa Blume
Hydrol. Earth Syst. Sci., 22, 13–30, https://doi.org/10.5194/hess-22-13-2018, https://doi.org/10.5194/hess-22-13-2018, 2018
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We use sap velocity measurements from 61 trees on 132 days to gain knowledge about the controls of landscape-scale transpiration, distinguishing tree-, stand- and site-specific controls on sap velocity and sap flow patterns and examining their dynamics during the vegetation period. Our results show that these patterns are not exclusively determined by tree characteristics. Thus, including site characteristics such as geology and aspect could be beneficial for modelling or management purposes.
Willem J. van Verseveld, Holly R. Barnard, Chris B. Graham, Jeffrey J. McDonnell, J. Renée Brooks, and Markus Weiler
Hydrol. Earth Syst. Sci., 21, 5891–5910, https://doi.org/10.5194/hess-21-5891-2017, https://doi.org/10.5194/hess-21-5891-2017, 2017
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How stream water responds immediately to a rainfall or snow event, while the average time it takes water to travel through the hillslope can be years or decades and is poorly understood. We assessed this difference by combining a 24-day sprinkler experiment (a tracer was applied at the start) with a process-based hydrologic model. Immobile soil water, deep groundwater contribution and soil depth variability explained this difference at our hillslope site.
Michael P. Schwab, Julian Klaus, Laurent Pfister, and Markus Weiler
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2017-416, https://doi.org/10.5194/hess-2017-416, 2017
Revised manuscript not accepted
Lisa Angermann, Conrad Jackisch, Niklas Allroggen, Matthias Sprenger, Erwin Zehe, Jens Tronicke, Markus Weiler, and Theresa Blume
Hydrol. Earth Syst. Sci., 21, 3727–3748, https://doi.org/10.5194/hess-21-3727-2017, https://doi.org/10.5194/hess-21-3727-2017, 2017
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This study investigates the temporal dynamics and response velocities of lateral preferential flow at the hillslope. The results are compared to catchment response behavior to infer the large-scale implications of the observed processes. A large portion of mobile water flows through preferential flow paths in the structured soils, causing an immediate discharge response. The study presents a methodological approach to cover the spatial and temporal domain of these highly heterogeneous processes.
Conrad Jackisch, Lisa Angermann, Niklas Allroggen, Matthias Sprenger, Theresa Blume, Jens Tronicke, and Erwin Zehe
Hydrol. Earth Syst. Sci., 21, 3749–3775, https://doi.org/10.5194/hess-21-3749-2017, https://doi.org/10.5194/hess-21-3749-2017, 2017
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Rapid subsurface flow in structured soils facilitates fast vertical and lateral redistribution of event water. We present its in situ exploration through local measurements and irrigation experiments. Special emphasis is given to a coherent combination of hydrological and geophysical methods. The study highlights that form and function operate as conjugated pairs. Dynamic imaging through time-lapse GPR was key to observing both and to identifying hydrologically relevant structures.
Maik Renner, Sibylle K. Hassler, Theresa Blume, Markus Weiler, Anke Hildebrandt, Marcus Guderle, Stanislaus J. Schymanski, and Axel Kleidon
Hydrol. Earth Syst. Sci., 20, 2063–2083, https://doi.org/10.5194/hess-20-2063-2016, https://doi.org/10.5194/hess-20-2063-2016, 2016
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We estimated forest transpiration (European beech) along a steep valley cross section. Atmospheric demand, obtained by the thermodynamic limit of maximum power, is the dominant control of transpiration at all sites.
To our surprise we find that transpiration is rather similar across sites with different aspect (north vs. south) and different stand structure due to systematically varying sap velocities. Such a compensation effect is highly relevant for modeling and upscaling of transpiration.
Katharina F. Gimbel, Heike Puhlmann, and Markus Weiler
Hydrol. Earth Syst. Sci., 20, 1301–1317, https://doi.org/10.5194/hess-20-1301-2016, https://doi.org/10.5194/hess-20-1301-2016, 2016
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It is usually assumed that soil properties are not affected by drought events. We used dye tracer experiments to test this assumption on six forest soils, which were forced into drought conditions. The results of this study show clear evidence for changes in infiltration pathways. In addition, most soils developed soil water repellency. Overall, the results suggest that the past climatic conditions are more important than the actual soil moisture status regarding hydrophobicity and infiltration.
Tobias Schuetz, Chantal Gascuel-Odoux, Patrick Durand, and Markus Weiler
Hydrol. Earth Syst. Sci., 20, 843–857, https://doi.org/10.5194/hess-20-843-2016, https://doi.org/10.5194/hess-20-843-2016, 2016
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We quantify the spatio-temporal impact of distinct nitrate sinks and sources on stream network nitrate dynamics in an agricultural headwater. By applying a data-driven modelling approach, we are able to fully distinguish between mixing and dilution processes, and biogeochemical in-stream removal processes along the stream network. In-stream nitrate removal is estimated by applying a novel transfer coefficient based on energy availability.
A. Hartmann, J. Kobler, M. Kralik, T. Dirnböck, F. Humer, and M. Weiler
Biogeosciences, 13, 159–174, https://doi.org/10.5194/bg-13-159-2016, https://doi.org/10.5194/bg-13-159-2016, 2016
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We consider the time period before and after a wind disturbance in an Austrian karst system. Using a process-based flow and solute transport simulation model we estimate impacts on DIN and DOC. We show that DIN increases for several years, while DOC remains within its pre-disturbance variability. Simulated transit times indicate that impact passes through the hydrological system within some months but with a small fraction exceeding transit times of even a year.
M. Sprenger, T. H. M. Volkmann, T. Blume, and M. Weiler
Hydrol. Earth Syst. Sci., 19, 2617–2635, https://doi.org/10.5194/hess-19-2617-2015, https://doi.org/10.5194/hess-19-2617-2015, 2015
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We present a novel approach that includes information about the pore water stable isotopic composition in inverse model approaches to estimate soil hydraulic parameters. Different approaches are presented and their adequacy regarding the model efficiency, realism and parameter identifiability are discussed. The advantages of the new approach are shown by an application of the inverse estimated parameters to infer the water balance and the transit time for three different study sites.
M. Staudinger, M. Weiler, and J. Seibert
Hydrol. Earth Syst. Sci., 19, 1371–1384, https://doi.org/10.5194/hess-19-1371-2015, https://doi.org/10.5194/hess-19-1371-2015, 2015
K. F. Gimbel, K. Felsmann, M. Baudis, H. Puhlmann, A. Gessler, H. Bruelheide, Z. Kayler, R. H. Ellerbrock, A. Ulrich, E. Welk, and M. Weiler
Biogeosciences, 12, 961–975, https://doi.org/10.5194/bg-12-961-2015, https://doi.org/10.5194/bg-12-961-2015, 2015
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This paper introduces a novel rainfall reduction experiment to investigate drought effects on soil-forest-understory-ecosystems. An annual drought with a return period of 40 years was imposed, while other ecosystem variables (humidity, air & soil temperature) remained unaffected. The first year of drought showed considerable changes in soil moisture dynamics, which affected leaf stomatal conductance of understory species as well as evapotranspiration rates of the forest understory ecosystem.
S. Seeger and M. Weiler
Hydrol. Earth Syst. Sci., 18, 4751–4771, https://doi.org/10.5194/hess-18-4751-2014, https://doi.org/10.5194/hess-18-4751-2014, 2014
E. Zehe, U. Ehret, L. Pfister, T. Blume, B. Schröder, M. Westhoff, C. Jackisch, S. J. Schymanski, M. Weiler, K. Schulz, N. Allroggen, J. Tronicke, L. van Schaik, P. Dietrich, U. Scherer, J. Eccard, V. Wulfmeyer, and A. Kleidon
Hydrol. Earth Syst. Sci., 18, 4635–4655, https://doi.org/10.5194/hess-18-4635-2014, https://doi.org/10.5194/hess-18-4635-2014, 2014
J. Schwerdtfeger, M. S. Johnson, E. G. Couto, R. S. S. Amorim, L. Sanches, J. H. Campelo Jr., and M. Weiler
Hydrol. Earth Syst. Sci., 18, 4407–4422, https://doi.org/10.5194/hess-18-4407-2014, https://doi.org/10.5194/hess-18-4407-2014, 2014
B. Merz, J. Aerts, K. Arnbjerg-Nielsen, M. Baldi, A. Becker, A. Bichet, G. Blöschl, L. M. Bouwer, A. Brauer, F. Cioffi, J. M. Delgado, M. Gocht, F. Guzzetti, S. Harrigan, K. Hirschboeck, C. Kilsby, W. Kron, H.-H. Kwon, U. Lall, R. Merz, K. Nissen, P. Salvatti, T. Swierczynski, U. Ulbrich, A. Viglione, P. J. Ward, M. Weiler, B. Wilhelm, and M. Nied
Nat. Hazards Earth Syst. Sci., 14, 1921–1942, https://doi.org/10.5194/nhess-14-1921-2014, https://doi.org/10.5194/nhess-14-1921-2014, 2014
D. Freudiger, I. Kohn, K. Stahl, and M. Weiler
Hydrol. Earth Syst. Sci., 18, 2695–2709, https://doi.org/10.5194/hess-18-2695-2014, https://doi.org/10.5194/hess-18-2695-2014, 2014
R. S. Smith, R. D. Moore, M. Weiler, and G. Jost
Hydrol. Earth Syst. Sci., 18, 1835–1856, https://doi.org/10.5194/hess-18-1835-2014, https://doi.org/10.5194/hess-18-1835-2014, 2014
T. H. M. Volkmann and M. Weiler
Hydrol. Earth Syst. Sci., 18, 1819–1833, https://doi.org/10.5194/hess-18-1819-2014, https://doi.org/10.5194/hess-18-1819-2014, 2014
M. Gassmann, C. Stamm, O. Olsson, J. Lange, K. Kümmerer, and M. Weiler
Hydrol. Earth Syst. Sci., 17, 5213–5228, https://doi.org/10.5194/hess-17-5213-2013, https://doi.org/10.5194/hess-17-5213-2013, 2013
A. Hartmann, M. Weiler, T. Wagener, J. Lange, M. Kralik, F. Humer, N. Mizyed, A. Rimmer, J. A. Barberá, B. Andreo, C. Butscher, and P. Huggenberger
Hydrol. Earth Syst. Sci., 17, 3305–3321, https://doi.org/10.5194/hess-17-3305-2013, https://doi.org/10.5194/hess-17-3305-2013, 2013
N. Dietermann and M. Weiler
Hydrol. Earth Syst. Sci., 17, 2657–2668, https://doi.org/10.5194/hess-17-2657-2013, https://doi.org/10.5194/hess-17-2657-2013, 2013
J. Garvelmann, S. Pohl, and M. Weiler
Hydrol. Earth Syst. Sci., 17, 1415–1429, https://doi.org/10.5194/hess-17-1415-2013, https://doi.org/10.5194/hess-17-1415-2013, 2013
M. Stoelzle, K. Stahl, and M. Weiler
Hydrol. Earth Syst. Sci., 17, 817–828, https://doi.org/10.5194/hess-17-817-2013, https://doi.org/10.5194/hess-17-817-2013, 2013
Related subject area
Subject: Vadose Zone Hydrology | Techniques and Approaches: Instruments and observation techniques
High-resolution operational soil moisture monitoring for forests in central Germany
Technical Note: Revisiting the general calibration of cosmic-ray neutron sensors to estimate soil water content
Coupled hydrogeophysical inversion of an artificial infiltration experiment monitored with ground-penetrating radar: synthetic demonstration
Technical note: Discrete in situ vapor sampling for subsequent lab-based water stable isotope analysis
A change in perspective: downhole cosmic-ray neutron sensing for the estimation of soil moisture
Impacts of soil management and climate on saturated and near-saturated hydraulic conductivity: analyses of the Open Tension-disk Infiltrometer Meta-database (OTIM)
Physics-informed machine learning for understanding rock moisture dynamics in a sandstone cave
Relationship of seasonal variations in drip water δ13CDIC, δ18O, and trace elements with surface and physical cave conditions of La Vallina cave, NW Spain
In situ estimation of soil hydraulic and hydrodispersive properties by inversion of electromagnetic induction measurements and soil hydrological modeling
Towards disentangling heterogeneous soil moisture patterns in cosmic-ray neutron sensor footprints
The International Soil Moisture Network: serving Earth system science for over a decade
Technical note: Evaporating water is different from bulk soil water in δ2H and δ18O and has implications for evaporation calculation
Spatio-temporal soil moisture retrieval at the catchment scale using a dense network of cosmic-ray neutron sensors
Deep desiccation of soils observed by long-term high-resolution measurements on a large inclined lysimeter
A novel analytical approach for the simultaneous measurement of nitrate and dissolved organic carbon in soil water
Exploring the regolith with electrical resistivity tomography in large-scale surveys: electrode spacing-related issues and possibility
Soil dielectric characterization during freeze–thaw transitions using L-band coaxial and soil moisture probes
Hydrological signals in tilt and gravity residuals at Conrad Observatory (Austria)
New measures of deep soil water recharge during the vegetation restoration process in semi-arid regions of northern China
Estimation of subsurface soil moisture from surface soil moisture in cold mountainous areas
Investigating unproductive water losses from irrigated agricultural crops in the humid tropics through analyses of stable isotopes of water
Pacific climate reflected in Waipuna Cave drip water hydrochemistry
Field observations of soil hydrological flow path evolution over 10 millennia
A proposed method for estimating interception from near-surface soil moisture response
Controls of fluorescent tracer retention by soils and sediments
Reflection tomography of time-lapse GPR data for studying dynamic unsaturated flow phenomena
Effects of preferential flow on snowmelt partitioning and groundwater recharge in frozen soils
Spatio-temporal relevance and controls of preferential flow at the landscape scale
Real-time monitoring of nitrate in soils as a key for optimization of agricultural productivity and prevention of groundwater pollution
A soil non-aqueous phase liquid (NAPL) flushing laboratory experiment based on measuring the dielectric properties of soil–organic mixtures via time domain reflectometry (TDR)
The value of satellite remote sensing soil moisture data and the DISPATCH algorithm in irrigation fields
Estimating epikarst water storage by time-lapse surface-to-depth gravity measurements
Inter-laboratory comparison of cryogenic water extraction systems for stable isotope analysis of soil water
Preferential flow systems amended with biogeochemical components: imaging of a two-dimensional study
Imaging groundwater infiltration dynamics in the karst vadose zone with long-term ERT monitoring
Calibrating electromagnetic induction conductivities with time-domain reflectometry measurements
Multiscale soil moisture estimates using static and roving cosmic-ray soil moisture sensors
Field-scale water balance closure in seasonally frozen conditions
Improving calibration and validation of cosmic-ray neutron sensors in the light of spatial sensitivity
Is annual recharge coefficient a valid concept in arid and semi-arid regions?
Transport and degradation of perchlorate in deep vadose zone: implications from direct observations during bioremediation treatment
Monitoring soil moisture from middle to high elevation in Switzerland: set-up and first results from the SOMOMOUNT network
Experimental study on retardation of a heavy NAPL vapor in partially saturated porous media
Repeated electromagnetic induction measurements for mapping soil moisture at the field scale: validation with data from a wireless soil moisture monitoring network
ENSO–cave drip water hydrochemical relationship: a 7-year dataset from south-eastern Australia
Incorporation of globally available datasets into the roving cosmic-ray neutron probe method for estimating field-scale soil water content
Real-time monitoring of nitrate transport in the deep vadose zone under a crop field – implications for groundwater protection
Technical note: Improving the AWAT filter with interpolation schemes for advanced processing of high resolution data
Estimating field-scale root zone soil moisture using the cosmic-ray neutron probe
Does drought alter hydrological functions in forest soils?
Ivan Vorobevskii, Thi Thanh Luong, Rico Kronenberg, and Rainer Petzold
Hydrol. Earth Syst. Sci., 28, 3567–3595, https://doi.org/10.5194/hess-28-3567-2024, https://doi.org/10.5194/hess-28-3567-2024, 2024
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An introduced high-resolution soil moisture monitoring framework combines a 1D water balance model, real-time meteorological data, and a national soil database to present point-based operational data with a user-friendly web platform. Its significance lies in the improvement of forest management by making informed, local-scale decisions crucial for mitigating climate change impacts. In the paper, we present a technical description and validation of the framework and showcase its features.
Maik Heistermann, Till Francke, Martin Schrön, and Sascha E. Oswald
Hydrol. Earth Syst. Sci., 28, 989–1000, https://doi.org/10.5194/hess-28-989-2024, https://doi.org/10.5194/hess-28-989-2024, 2024
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Cosmic-ray neutron sensing (CRNS) is a non-invasive technique used to obtain estimates of soil water content (SWC) at a horizontal footprint of around 150 m and a vertical penetration depth of up to 30 cm. However, typical CRNS applications require the local calibration of a function which converts neutron counts to SWC. As an alternative, we propose a generalized function as a way to avoid the use of local reference measurements of SWC and hence a major source of uncertainty.
Rohianuu Moua, Nolwenn Lesparre, Jean-François Girard, Benjamin Belfort, François Lehmann, and Anis Younes
Hydrol. Earth Syst. Sci., 27, 4317–4334, https://doi.org/10.5194/hess-27-4317-2023, https://doi.org/10.5194/hess-27-4317-2023, 2023
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Hydraulic properties of soil include the ability of water to move through the soil and the amount of water that is held in the soil in dry or wet conditions. In this work, we further investigate a protocol used to evaluate such hydraulic properties. We propose a modified version of the protocol, with which we show (i) how the data obtained with this protocol are influenced by the soil hydraulic properties and (ii) how one can use it to estimate these properties.
Barbara Herbstritt, Benjamin Gralher, Stefan Seeger, Michael Rinderer, and Markus Weiler
Hydrol. Earth Syst. Sci., 27, 3701–3718, https://doi.org/10.5194/hess-27-3701-2023, https://doi.org/10.5194/hess-27-3701-2023, 2023
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We present a method to collect water vapor samples into bags in the field without an in-field analyser, followed by isotope analysis in the lab. This new method resolves even fine-scaled natural isotope variations. It combines low-cost and lightweight components for maximum spatial and temporal flexibility regarding environmental setups. Hence, it allows for sampling even in terrains that are rather difficult to access, enabling future extended isotope datasets in soil sciences and ecohydrology.
Daniel Rasche, Jannis Weimar, Martin Schrön, Markus Köhli, Markus Morgner, Andreas Güntner, and Theresa Blume
Hydrol. Earth Syst. Sci., 27, 3059–3082, https://doi.org/10.5194/hess-27-3059-2023, https://doi.org/10.5194/hess-27-3059-2023, 2023
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We introduce passive downhole cosmic-ray neutron sensing (d-CRNS) as an approach for the non-invasive estimation of soil moisture in deeper layers of the unsaturated zone which exceed the observational window of above-ground CRNS applications. Neutron transport simulations are used to derive mathematical descriptions and transfer functions, while experimental measurements in an existing groundwater observation well illustrate the feasibility and applicability of the approach.
Guillaume Blanchy, Lukas Albrecht, Gilberto Bragato, Sarah Garré, Nicholas Jarvis, and John Koestel
Hydrol. Earth Syst. Sci., 27, 2703–2724, https://doi.org/10.5194/hess-27-2703-2023, https://doi.org/10.5194/hess-27-2703-2023, 2023
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We collated the Open Tension-disk Infiltrometer Meta-database (OTIM). We analysed topsoil hydraulic conductivities at supply tensions between 0 and 100 mm of 466 data entries. We found indications of different flow mechanisms at saturation and at tensions >20 mm. Climate factors were better correlated with near-saturated hydraulic conductivities than soil properties. Land use, tillage system, soil compaction and experimenter bias significantly influenced K to a similar degree to soil properties.
Kai-Gao Ouyang, Xiao-Wei Jiang, Gang Mei, Hong-Bin Yan, Ran Niu, Li Wan, and Yijian Zeng
Hydrol. Earth Syst. Sci., 27, 2579–2590, https://doi.org/10.5194/hess-27-2579-2023, https://doi.org/10.5194/hess-27-2579-2023, 2023
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Our knowledge on sources and dynamics of rock moisture is limited. By using frequency domain reflectometry (FDR), we monitored rock moisture in a cave. The results of an explainable deep learning model reveal that the direct source of rock moisture responsible for weathering in the studied cave is vapour, not infiltrating precipitation. A physics-informed deep learning model, which uses variables controlling vapor condensation as model inputs, leads to accurate rock water content predictions.
Oliver Kost, Saúl González-Lemos, Laura Rodríguez-Rodríguez, Jakub Sliwinski, Laura Endres, Negar Haghipour, and Heather Stoll
Hydrol. Earth Syst. Sci., 27, 2227–2255, https://doi.org/10.5194/hess-27-2227-2023, https://doi.org/10.5194/hess-27-2227-2023, 2023
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Cave monitoring studies including cave drip water are unique opportunities to sample water which has percolated through the soil and rock. The change in drip water chemistry is resolved over the course of 16 months, inferring seasonal and hydrological variations in soil and karst processes at the water–air and water–rock interface. Such data sets improve the understanding of hydrological and hydrochemical processes and ultimately advance the interpretation of geochemical stalagmite records.
Giovanna Dragonetti, Mohammad Farzamian, Angelo Basile, Fernando Monteiro Santos, and Antonio Coppola
Hydrol. Earth Syst. Sci., 26, 5119–5136, https://doi.org/10.5194/hess-26-5119-2022, https://doi.org/10.5194/hess-26-5119-2022, 2022
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Soil hydraulic and hydrodispersive properties are necessary for modeling water and solute fluxes in agricultural and environmental systems. Despite the major efforts in developing methods (e.g., lab-based, pedotransfer functions), their characterization at applicative scales remains an imperative requirement. Thus, this paper proposes a noninvasive in situ method integrating electromagnetic induction and hydrological modeling to estimate soil hydraulic and transport properties at the plot scale.
Daniel Rasche, Markus Köhli, Martin Schrön, Theresa Blume, and Andreas Güntner
Hydrol. Earth Syst. Sci., 25, 6547–6566, https://doi.org/10.5194/hess-25-6547-2021, https://doi.org/10.5194/hess-25-6547-2021, 2021
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Cosmic-ray neutron sensing provides areal average soil moisture measurements. We investigated how distinct differences in spatial soil moisture patterns influence the soil moisture estimates and present two approaches to improve the estimate of soil moisture close to the instrument by reducing the influence of soil moisture further afield. Additionally, we show that the heterogeneity of soil moisture can be assessed based on the relationship of different neutron energies.
Wouter Dorigo, Irene Himmelbauer, Daniel Aberer, Lukas Schremmer, Ivana Petrakovic, Luca Zappa, Wolfgang Preimesberger, Angelika Xaver, Frank Annor, Jonas Ardö, Dennis Baldocchi, Marco Bitelli, Günter Blöschl, Heye Bogena, Luca Brocca, Jean-Christophe Calvet, J. Julio Camarero, Giorgio Capello, Minha Choi, Michael C. Cosh, Nick van de Giesen, Istvan Hajdu, Jaakko Ikonen, Karsten H. Jensen, Kasturi Devi Kanniah, Ileen de Kat, Gottfried Kirchengast, Pankaj Kumar Rai, Jenni Kyrouac, Kristine Larson, Suxia Liu, Alexander Loew, Mahta Moghaddam, José Martínez Fernández, Cristian Mattar Bader, Renato Morbidelli, Jan P. Musial, Elise Osenga, Michael A. Palecki, Thierry Pellarin, George P. Petropoulos, Isabella Pfeil, Jarrett Powers, Alan Robock, Christoph Rüdiger, Udo Rummel, Michael Strobel, Zhongbo Su, Ryan Sullivan, Torbern Tagesson, Andrej Varlagin, Mariette Vreugdenhil, Jeffrey Walker, Jun Wen, Fred Wenger, Jean Pierre Wigneron, Mel Woods, Kun Yang, Yijian Zeng, Xiang Zhang, Marek Zreda, Stephan Dietrich, Alexander Gruber, Peter van Oevelen, Wolfgang Wagner, Klaus Scipal, Matthias Drusch, and Roberto Sabia
Hydrol. Earth Syst. Sci., 25, 5749–5804, https://doi.org/10.5194/hess-25-5749-2021, https://doi.org/10.5194/hess-25-5749-2021, 2021
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The International Soil Moisture Network (ISMN) is a community-based open-access data portal for soil water measurements taken at the ground and is accessible at https://ismn.earth. Over 1000 scientific publications and thousands of users have made use of the ISMN. The scope of this paper is to inform readers about the data and functionality of the ISMN and to provide a review of the scientific progress facilitated through the ISMN with the scope to shape future research and operations.
Hongxiu Wang, Jingjing Jin, Buli Cui, Bingcheng Si, Xiaojun Ma, and Mingyi Wen
Hydrol. Earth Syst. Sci., 25, 5399–5413, https://doi.org/10.5194/hess-25-5399-2021, https://doi.org/10.5194/hess-25-5399-2021, 2021
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Evaporation led to progressively more heavy-isotope-enriched bulk soil water (BW) following the precipitation/irrigation of heavy-isotope-depleted new water but causes progressively more heavy-isotope-depleted BW following irrigation of heavy-isotope-enriched new water. The results indicated that δ2H and δ18O in evaporating water (EW) were similar to new water and differed from BW. However, the evaporative water loss calculated from BW did not differ significantly from that of EW.
Maik Heistermann, Till Francke, Martin Schrön, and Sascha E. Oswald
Hydrol. Earth Syst. Sci., 25, 4807–4824, https://doi.org/10.5194/hess-25-4807-2021, https://doi.org/10.5194/hess-25-4807-2021, 2021
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Cosmic-ray neutron sensing (CRNS) is a powerful technique for retrieving representative estimates of soil moisture in footprints extending over hectometres in the horizontal and decimetres in the vertical. This study, however, demonstrates the potential of CRNS to obtain spatio-temporal patterns of soil moisture beyond isolated footprints. To that end, we analyse data from a unique observational campaign that featured a dense network of more than 20 neutron detectors in an area of just 1 km2.
Markus Merk, Nadine Goeppert, and Nico Goldscheider
Hydrol. Earth Syst. Sci., 25, 3519–3538, https://doi.org/10.5194/hess-25-3519-2021, https://doi.org/10.5194/hess-25-3519-2021, 2021
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Soil moisture levels have decreased significantly over the past 2 decades. This decrease is not uniformly distributed over the observation period. The largest changes occur at tipping points during years of extreme drought, after which soil moisture levels reach significantly different alternate stable states. Not only the overall trend in soil moisture is affected, but also the seasonal dynamics.
Elad Yeshno, Ofer Dahan, Shoshana Bernstain, and Shlomi Arnon
Hydrol. Earth Syst. Sci., 25, 2159–2168, https://doi.org/10.5194/hess-25-2159-2021, https://doi.org/10.5194/hess-25-2159-2021, 2021
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In this research, we present a novel approach, enabling the measurement of nitrate concentrations in natural soil porewater containing natural soil dissolved organic carbon. This method can be used as the basis onto which an affordable and miniaturized nitrate monitoring sensor for soils can be developed. This sensor can play a significant role in reducing nitrate pollution in water resources, optimizing fertilizers application during agricultural activity and decreasing food production costs.
Laurent Gourdol, Rémi Clément, Jérôme Juilleret, Laurent Pfister, and Christophe Hissler
Hydrol. Earth Syst. Sci., 25, 1785–1812, https://doi.org/10.5194/hess-25-1785-2021, https://doi.org/10.5194/hess-25-1785-2021, 2021
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Electrical resistivity tomography (ERT) is a remarkable tool for characterizing the regolith, but its use over large areas remains cumbersome due to the requirement of small electrode spacing (ES). In this study we document the issues of using oversized ESs and propose a new approach to overcome this limitation. We demonstrate that our protocol significantly improves the accuracy of ERT profiles using large ES and offers a cost-effective means for carrying out large-scale surveys.
Alex Mavrovic, Renato Pardo Lara, Aaron Berg, François Demontoux, Alain Royer, and Alexandre Roy
Hydrol. Earth Syst. Sci., 25, 1117–1131, https://doi.org/10.5194/hess-25-1117-2021, https://doi.org/10.5194/hess-25-1117-2021, 2021
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This paper presents a new probe that measures soil microwave permittivity in the frequency range of satellite L-band sensors. The probe capacities will allow for validation and calibration of the models used to estimate landscape physical properties from raw microwave satellite datasets. Our results show important discrepancies between model estimates and instrument measurements that will need to be addressed.
Bruno Meurers, Gábor Papp, Hannu Ruotsalainen, Judit Benedek, and Roman Leonhardt
Hydrol. Earth Syst. Sci., 25, 217–236, https://doi.org/10.5194/hess-25-217-2021, https://doi.org/10.5194/hess-25-217-2021, 2021
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Gravity and tilt time series acquired at Conrad Observatory (Austria) reflect gravity and deformation associated with short- and long-term environmental processes, revealing a complex water transport process after heavy rain and rapid snowmelt. Gravity residuals are sensitive to the Newtonian effect of water mass transport. Tilt residual anomalies capture strain–tilt coupling effects due to surface or subsurface deformation from precipitation or pressure changes in the adjacent fracture system.
Yiben Cheng, Xinle Li, Yunqi Wang, Hongbin Zhan, Wenbin Yang, and Qunou Jiang
Hydrol. Earth Syst. Sci., 24, 5875–5890, https://doi.org/10.5194/hess-24-5875-2020, https://doi.org/10.5194/hess-24-5875-2020, 2020
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The Three North Forest Program has produced a vast area of lined forest in semi-arid regions, which consumes a large amount of water resources. This study uses a newly designed lysimeter to measure water distribution without destroying the in situ vegetation soil structure. It addresses the shortcomings of a traditional lysimeter, in terms of changing the in situ soil structure and destroying the vegetation root system, and the shortcomings of high costs and inconvenient installation.
Jie Tian, Zhibo Han, Heye Reemt Bogena, Johan Alexander Huisman, Carsten Montzka, Baoqing Zhang, and Chansheng He
Hydrol. Earth Syst. Sci., 24, 4659–4674, https://doi.org/10.5194/hess-24-4659-2020, https://doi.org/10.5194/hess-24-4659-2020, 2020
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Large-scale profile soil moisture (SM) is important for water resource management, but its estimation is a challenge. Thus, based on in situ SM observations in a cold mountain, a strong relationship between the surface SM and subsurface SM is found. Both the subsurface SM of 10–30 cm and the profile SM of 0–70 cm can be estimated from the surface SM of 0–10 cm accurately. By combing with the satellite product, we improve the large-scale profile SM estimation in the cold mountains finally.
Amani Mahindawansha, Christoph Külls, Philipp Kraft, and Lutz Breuer
Hydrol. Earth Syst. Sci., 24, 3627–3642, https://doi.org/10.5194/hess-24-3627-2020, https://doi.org/10.5194/hess-24-3627-2020, 2020
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Stable isotopes of soil water are an effective tool to reveal soil hydrological processes in irrigated agricultural fields. Flow mechanisms and isotopic patterns of soil water in the soil matrix differ, depending on the crop and irrigation practices. Isotope data supported the fact that unproductive water losses via evaporation can be reduced by introducing dry seasonal crops to the crop rotation system.
Cinthya Nava-Fernandez, Adam Hartland, Fernando Gázquez, Ola Kwiecien, Norbert Marwan, Bethany Fox, John Hellstrom, Andrew Pearson, Brittany Ward, Amanda French, David A. Hodell, Adrian Immenhauser, and Sebastian F. M. Breitenbach
Hydrol. Earth Syst. Sci., 24, 3361–3380, https://doi.org/10.5194/hess-24-3361-2020, https://doi.org/10.5194/hess-24-3361-2020, 2020
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Speleothems are powerful archives of past climate for understanding modern local hydrology and its relation to regional circulation patterns. We use a 3-year monitoring dataset to test the sensitivity of Waipuna Cave to seasonal changes and El Niño–Southern Oscillation (ENSO) dynamics. Drip water data suggest a fast response to rainfall events; its elemental composition reflects a seasonal cycle and ENSO variability. Waipuna Cave speleothems have a high potential for past ENSO reconstructions.
Anne Hartmann, Ekaterina Semenova, Markus Weiler, and Theresa Blume
Hydrol. Earth Syst. Sci., 24, 3271–3288, https://doi.org/10.5194/hess-24-3271-2020, https://doi.org/10.5194/hess-24-3271-2020, 2020
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Our field observation-based examination of flow path evolution, soil formation, and vegetation succession across 10 millennia shows how water flow paths and subsurface water storage are linked to the organization of evolving landscapes.
The increase found in water storage and preferential flow paths with increasing soil age shows the effect of the complex interaction of vegetation and soil development on flow paths, water balance, and runoff formation during landscape evolution.
Subodh Acharya, Daniel McLaughlin, David Kaplan, and Matthew J. Cohen
Hydrol. Earth Syst. Sci., 24, 1859–1870, https://doi.org/10.5194/hess-24-1859-2020, https://doi.org/10.5194/hess-24-1859-2020, 2020
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Interception is the storage and subsequent evaporation of rain by vegetation and surface litter. Quantifying interception is critical for understanding the water balance, but it can be difficult and costly to measure. We developed an approach to estimate interception using automated soil moisture measurements during rainfall events. Results suggest that interception can be estimated using soil moisture data, leading to potential cost savings and logistical advantages over conventional methods.
Marcus Bork, Jens Lange, Markus Graf-Rosenfellner, and Friederike Lang
Hydrol. Earth Syst. Sci., 24, 977–989, https://doi.org/10.5194/hess-24-977-2020, https://doi.org/10.5194/hess-24-977-2020, 2020
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Fluorescent tracers such as uranine and sulforhodamine B are useful tools to gain knowledge about water and solute fluxes in aquatic and terrestrial ecosystems. In this study we systematically investigated the influence of important soil properties (pH, organic carbon content and texture) on tracer adsorption in soils and sediments. These properties also determine whether the tracers in the respective soil behave conservatively or non-conservatively.
Adam R. Mangel, Stephen M. J. Moysey, and John Bradford
Hydrol. Earth Syst. Sci., 24, 159–167, https://doi.org/10.5194/hess-24-159-2020, https://doi.org/10.5194/hess-24-159-2020, 2020
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Water flows through soils in an incredibly complex network of pathways. Understanding these pathways is critical to sustainable use of water resources. Ground-penetrating radar (GPR) can image water in near-surface soils the same way an X-ray is used to image the human body. Utilizing innovative ways of collecting and processing the GPR data, we can image complex water flow in space and through time, which allows for the continued development of our ideas and models of subsurface water flow.
Aaron A. Mohammed, Igor Pavlovskii, Edwin E. Cey, and Masaki Hayashi
Hydrol. Earth Syst. Sci., 23, 5017–5031, https://doi.org/10.5194/hess-23-5017-2019, https://doi.org/10.5194/hess-23-5017-2019, 2019
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In cold regions, the permeability of the frozen ground is an important factor influencing a watershed's response to snowmelt. This study highlights the effects of preferential flow in frozen soils on snowmelt redistribution and groundwater recharge in seasonally frozen landscapes.
Dominic Demand, Theresa Blume, and Markus Weiler
Hydrol. Earth Syst. Sci., 23, 4869–4889, https://doi.org/10.5194/hess-23-4869-2019, https://doi.org/10.5194/hess-23-4869-2019, 2019
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This study presents an analysis of 135 soil moisture profiles for identification of the spatial and temporal preferential flow occurrence in a complex landscape. Especially dry conditions and high rainfall intensities were found to increase preferential flow occurrence in soils. This results in a seasonal pattern of preferential flow with a higher occurrence in summer. During this time grasslands showed increased flow velocities, whereas forest sites exhibited a higher amount of bypass flow.
Elad Yeshno, Shlomi Arnon, and Ofer Dahan
Hydrol. Earth Syst. Sci., 23, 3997–4010, https://doi.org/10.5194/hess-23-3997-2019, https://doi.org/10.5194/hess-23-3997-2019, 2019
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Lack of adequate instrumentation for monitoring nutrient availability in agricultural soils leads in most cases to over-application of fertilizers, often resulting in groundwater pollution. This research presents a novel approach for real-time, in situ monitoring of nitrate in soils using absorption spectroscopy techniques while preventing interference from dissolved organic carbon. Column experiments with this system resulted in accurate nitrate measurements in three different soil types.
Alessandro Comegna, Antonio Coppola, Giovanna Dragonetti, and Angelo Sommella
Hydrol. Earth Syst. Sci., 23, 3593–3602, https://doi.org/10.5194/hess-23-3593-2019, https://doi.org/10.5194/hess-23-3593-2019, 2019
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We carried out a series of laboratory-controlled experiments in order to simulate different scenarios of practical interest aiming to analyze, from a dielectric point of view, the influence of different washing solutions on non-aqueous phase liquid (NAPL) removal. Furthermore, on the basis of the results obtained, we validated a dielectric mixing model for predicting the volumetric amounts of NAPL (θNAPL) within the contaminated soil as the decontamination process progressed.
Mireia Fontanet, Daniel Fernàndez-Garcia, and Francesc Ferrer
Hydrol. Earth Syst. Sci., 22, 5889–5900, https://doi.org/10.5194/hess-22-5889-2018, https://doi.org/10.5194/hess-22-5889-2018, 2018
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One of the main objectives of remote sensing methodology is to downscale soil moisture to improve irrigation management. The DISPATCH algorithm is able to measure soil moisture at 1 km resolution using SMOS and MODIS data. In this work DISPATCH has been evaluated with soil moisture sensors, under heterogeneous conditions where local irrigation is applied. Results show that DISPATCH is not sensitive when local irrigation is applied even at low resolution.
Cédric Champollion, Sabrina Deville, Jean Chéry, Erik Doerflinger, Nicolas Le Moigne, Roger Bayer, Philippe Vernant, and Naomi Mazzilli
Hydrol. Earth Syst. Sci., 22, 3825–3839, https://doi.org/10.5194/hess-22-3825-2018, https://doi.org/10.5194/hess-22-3825-2018, 2018
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Gravity monitoring at the surface and in situ (in caves) has been conducted in a karst hydro-system in the south of France (Larzac plateau). Subsurface water storage is evidenced with a spatial variability probably associated with lithology differences and confirmed by MRS measurements. Gravity allows transient water storage to be estimated on the seasonal scale.
Natalie Orlowski, Lutz Breuer, Nicolas Angeli, Pascal Boeckx, Christophe Brumbt, Craig S. Cook, Maren Dubbert, Jens Dyckmans, Barbora Gallagher, Benjamin Gralher, Barbara Herbstritt, Pedro Hervé-Fernández, Christophe Hissler, Paul Koeniger, Arnaud Legout, Chandelle Joan Macdonald, Carlos Oyarzún, Regine Redelstein, Christof Seidler, Rolf Siegwolf, Christine Stumpp, Simon Thomsen, Markus Weiler, Christiane Werner, and Jeffrey J. McDonnell
Hydrol. Earth Syst. Sci., 22, 3619–3637, https://doi.org/10.5194/hess-22-3619-2018, https://doi.org/10.5194/hess-22-3619-2018, 2018
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To extract water from soils for isotopic analysis, cryogenic water extraction is the most widely used removal technique. This work presents results from a worldwide laboratory intercomparison test of cryogenic extraction systems. Our results showed large differences in retrieved isotopic signatures among participating laboratories linked to interactions between soil type and properties, system setup, extraction efficiency, extraction system leaks, and each lab’s internal accuracy.
Ashley R. Pales, Biting Li, Heather M. Clifford, Shyla Kupis, Nimisha Edayilam, Dawn Montgomery, Wei-zhen Liang, Mine Dogan, Nishanth Tharayil, Nicole Martinez, Stephen Moysey, Brian Powell, and Christophe J. G. Darnault
Hydrol. Earth Syst. Sci., 22, 2487–2509, https://doi.org/10.5194/hess-22-2487-2018, https://doi.org/10.5194/hess-22-2487-2018, 2018
Arnaud Watlet, Olivier Kaufmann, Antoine Triantafyllou, Amaël Poulain, Jonathan E. Chambers, Philip I. Meldrum, Paul B. Wilkinson, Vincent Hallet, Yves Quinif, Michel Van Ruymbeke, and Michel Van Camp
Hydrol. Earth Syst. Sci., 22, 1563–1592, https://doi.org/10.5194/hess-22-1563-2018, https://doi.org/10.5194/hess-22-1563-2018, 2018
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Understanding water infiltration in karst regions is crucial as the aquifers they host provide drinkable water for a quarter of the world's population. We present a non-invasive tool to image hydrological processes in karst systems. At our field site, the injection of electrical current in the ground, repeated daily over a 3-year period, allowed imaging changes in the groundwater content. We show that specific geological layers control seasonal to rainfall-triggered water infiltration dynamics.
Giovanna Dragonetti, Alessandro Comegna, Ali Ajeel, Gian Piero Deidda, Nicola Lamaddalena, Giuseppe Rodriguez, Giulio Vignoli, and Antonio Coppola
Hydrol. Earth Syst. Sci., 22, 1509–1523, https://doi.org/10.5194/hess-22-1509-2018, https://doi.org/10.5194/hess-22-1509-2018, 2018
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The paper aims to infer the bulk electrical conductivity distribution in the root zone from EMI readings. TDR measurements were used as ground-truth data to evaluate the goodness of the estimations by EMI inversion. The approach is based on the mean and standard deviation of the EMI and TDR series. It looks for the physical reasons for the differences between EMI- and TDR-based electrical conductivity and provides a correction of the bias based on the statistical sources of the discrepancies.
David McJannet, Aaron Hawdon, Brett Baker, Luigi Renzullo, and Ross Searle
Hydrol. Earth Syst. Sci., 21, 6049–6067, https://doi.org/10.5194/hess-21-6049-2017, https://doi.org/10.5194/hess-21-6049-2017, 2017
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Satellite and broad-scale model estimates of soil moisture have improved in resolution. However, validation and calibration of these products has been limited because of a lack of observations on corresponding scales. We use a mobile soil moisture monitoring platform, known as the
rover, to derive soil moisture at 9 km and 1 km resolution. We describe methods to calculate soil moisture and present results from multiple surveys. The products produced are well suited to validation studies.
Xicai Pan, Warren Helgason, Andrew Ireson, and Howard Wheater
Hydrol. Earth Syst. Sci., 21, 5401–5413, https://doi.org/10.5194/hess-21-5401-2017, https://doi.org/10.5194/hess-21-5401-2017, 2017
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In this paper we present a case study from a heterogeneous pasture site in the Canadian prairies, where we have quantified the various components of the water balance on the field scale, and critically examine some of the simplifying assumptions which are often invoked when applying water budget approaches in applied hydrology. We highlight challenges caused by lateral fluxes of blowing snow and ambiguous partitioning of snow melt water into runoff and infiltration.
Martin Schrön, Markus Köhli, Lena Scheiffele, Joost Iwema, Heye R. Bogena, Ling Lv, Edoardo Martini, Gabriele Baroni, Rafael Rosolem, Jannis Weimar, Juliane Mai, Matthias Cuntz, Corinna Rebmann, Sascha E. Oswald, Peter Dietrich, Ulrich Schmidt, and Steffen Zacharias
Hydrol. Earth Syst. Sci., 21, 5009–5030, https://doi.org/10.5194/hess-21-5009-2017, https://doi.org/10.5194/hess-21-5009-2017, 2017
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A field-scale average of near-surface water content can be sensed by cosmic-ray neutron detectors. To interpret, calibrate, and validate the integral signal, it is important to account for its sensitivity to heterogeneous patterns like dry or wet spots. We show how point samples contribute to the neutron signal based on their depth and distance from the detector. This approach robustly improves the sensor performance and data consistency, and even reveals otherwise hidden hydrological features.
Yiben Cheng, Hongbin Zhan, Wenbin Yang, Hongzhong Dang, and Wei Li
Hydrol. Earth Syst. Sci., 21, 5031–5042, https://doi.org/10.5194/hess-21-5031-2017, https://doi.org/10.5194/hess-21-5031-2017, 2017
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This study uses a newly designed lysimeter to study three consecutive years (2013–2015) of deep soil recharge (DSR) underneath bare sand land on the eastern margin of Mu Us Sandy Land in the Ordos Basin of China. The objective is to identify the characteristics of the DSR distribution and the factors affecting the DSR distribution. Specifically, we would like to examine if the commonly used recharge coefficient concept can be applied for arid and semi-arid regions.
Ofer Dahan, Idan Katz, Lior Avishai, and Zeev Ronen
Hydrol. Earth Syst. Sci., 21, 4011–4020, https://doi.org/10.5194/hess-21-4011-2017, https://doi.org/10.5194/hess-21-4011-2017, 2017
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In situ bioremediation of a perchlorate-contaminated vadose zone was conducted through infiltration of electron-donor-enriched water. A vadose zone monitoring system (VMS) provided real-time tracking of the hydraulic and chemical conditions across the unsaturated zone. Variations in concentration profiles of perchlorate, chloride, DOC and bromide in the vadose zone pore water showed limited migration capacity of biologically consumable carbon and significant mobilization of perchlorate.
Cécile Pellet and Christian Hauck
Hydrol. Earth Syst. Sci., 21, 3199–3220, https://doi.org/10.5194/hess-21-3199-2017, https://doi.org/10.5194/hess-21-3199-2017, 2017
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This paper presents a detailed description of the new Swiss soil moisture monitoring network SOMOMOUNT, which comprises six stations distributed along an elevation gradient ranging from 1205 to 3410 m. The liquid soil moisture (LSM) data collected during the first 3 years are discussed with regard to their soil type and climate dependency as well as their altitudinal distribution. The elevation dependency of the LSM was found to be non-linear with distinct dynamics at high and low elevation.
Simon Matthias Kleinknecht, Holger Class, and Jürgen Braun
Hydrol. Earth Syst. Sci., 21, 1381–1396, https://doi.org/10.5194/hess-21-1381-2017, https://doi.org/10.5194/hess-21-1381-2017, 2017
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Retardation of migrating contaminant vapors in the subsurface may mitigate groundwater contamination or vapor intrusion into buildings. An experimental investigation was conducted to quantify the retardation of carbon disulfide (CS2) vapor in moist porous media based on the analysis of concentration breakthrough curves. Findings linked retardation to types of porous media and water saturation. Moreover, the first evidence of biodegradation of the CS2 vapor was found in the column experiments.
Edoardo Martini, Ulrike Werban, Steffen Zacharias, Marco Pohle, Peter Dietrich, and Ute Wollschläger
Hydrol. Earth Syst. Sci., 21, 495–513, https://doi.org/10.5194/hess-21-495-2017, https://doi.org/10.5194/hess-21-495-2017, 2017
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With a process-based interpretation of electromagnetic induction measurements, we discussed the potential and limitations of such a method for soil moisture mapping. Results will help clarify the complex and time-varying effect of stable soil properties and dynamic state variables on the physical parameters measured, with implications for future studies. We highlighted the importance of time-series data and the need for a multidisciplinary approach for proper interpretation.
Carol V. Tadros, Pauline C. Treble, Andy Baker, Ian Fairchild, Stuart Hankin, Regina Roach, Monika Markowska, and Janece McDonald
Hydrol. Earth Syst. Sci., 20, 4625–4640, https://doi.org/10.5194/hess-20-4625-2016, https://doi.org/10.5194/hess-20-4625-2016, 2016
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We investigated the potential use of trace element and stable oxygen-isotope variations in cave drip water as palaeorainfall proxies in an Australian alpine karst site. Using 7 years of cave monitoring data, we constrained the hydrological processes impacting the drip-water composition and identified a robust ENSO–drip water hydrochemical relationship. These findings are fundamental for reconstructing past ENSO variability from speleothems (cave deposits) regionally and globally.
William Alexander Avery, Catherine Finkenbiner, Trenton E. Franz, Tiejun Wang, Anthony L. Nguy-Robertson, Andrew Suyker, Timothy Arkebauer, and Francisco Muñoz-Arriola
Hydrol. Earth Syst. Sci., 20, 3859–3872, https://doi.org/10.5194/hess-20-3859-2016, https://doi.org/10.5194/hess-20-3859-2016, 2016
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Here we present a strategy to use globally available datasets in the calibration function used to convert observed moderated neutron counts into volumetric soil water content. While local sampling protocols are well documented for fixed probes, the use of roving probes presents new calibration challenges. With over 200 fixed probes and 10 roving probes in use globally, we anticipate this paper will serve as a keystone for the growing cosmic-ray neutron probe and hydrologic community.
Tuvia Turkeltaub, Daniel Kurtzman, and Ofer Dahan
Hydrol. Earth Syst. Sci., 20, 3099–3108, https://doi.org/10.5194/hess-20-3099-2016, https://doi.org/10.5194/hess-20-3099-2016, 2016
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Efficient groundwater protection from pollution originating in agriculture requires effective monitoring means capable of tacking pollution processes in the vadose zone, long before groundwater pollution turns into an unavoidable fact. In this study, a vadose zone monitoring system that was installed under a crop field fertilized by dairy slurry enabled real-time tracking of nitrate plum migration down the vadose zone from the land surface to the water table at 18m depth.
Andre Peters, Thomas Nehls, and Gerd Wessolek
Hydrol. Earth Syst. Sci., 20, 2309–2315, https://doi.org/10.5194/hess-20-2309-2016, https://doi.org/10.5194/hess-20-2309-2016, 2016
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The AWAT (Adaptive Window and Adaptive Threshold) filter routine for high-resolution lysimeter data is improved. The threshold scheme with original step interpolation yields unrealistic fluxes for high temporal resolution. Improvement applies linear and spline interpolation schemes so that fluxes in high temporal resolution are automatically calculated. The spline scheme allows continuous differentiability of filtered data so that any output resolution for the fluxes is sound.
Amber M. Peterson, Warren D. Helgason, and Andrew M. Ireson
Hydrol. Earth Syst. Sci., 20, 1373–1385, https://doi.org/10.5194/hess-20-1373-2016, https://doi.org/10.5194/hess-20-1373-2016, 2016
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Remote sensing techniques can provide useful large-scale estimates of soil moisture. However, these methods often only sense near-surface soil moisture, whereas many applications require estimates of the entire root zone. In this study we propose and test methods to "depth-scale" the shallow soil moisture measurements obtained using the cosmic-ray neutron probe to represent the entire root zone, thereby improving the applicability of this measurement approach.
Katharina F. Gimbel, Heike Puhlmann, and Markus Weiler
Hydrol. Earth Syst. Sci., 20, 1301–1317, https://doi.org/10.5194/hess-20-1301-2016, https://doi.org/10.5194/hess-20-1301-2016, 2016
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It is usually assumed that soil properties are not affected by drought events. We used dye tracer experiments to test this assumption on six forest soils, which were forced into drought conditions. The results of this study show clear evidence for changes in infiltration pathways. In addition, most soils developed soil water repellency. Overall, the results suggest that the past climatic conditions are more important than the actual soil moisture status regarding hydrophobicity and infiltration.
Cited articles
Araguás-Araguás, L., Rozanski, K., Gonfiantini, R., and Louvat, D.: Isotope effects accompanying vacuum extraction of soil water for stable isotope analyses, J. Hydrol., 168, 159–171, https://doi.org/10.1016/0022-1694(94)02636-P, 1995.
Bachmat, Y. and Bear, J.: On the Concept and Size of a Representative Elementary Volume (Rev), in: Advances in Transport Phenomena in Porous Media, edited by: Bear, J. and Corapcioglu, M. Y., NATO ASI Series (Series E: Applied Sciences), 128, Springer, Dordrecht, https://doi.org/10.1007/978-94-009-3625-6_1, 1987.
Bertrand, G., Masini, J., Goldscheider, N., Meeks, J., Lavastre, V., Celle-Jeanton, H., Gobat, J.-M., and Hunkeler, D.: Determination of spatiotemporal variability of tree water uptake using stable isotopes (δ18O, δ2H) in an alluvial system supplied by a high-altitude watershed, Pfyn forest, Switzerland, Ecohydrology, 7, 319–333, https://doi.org/10.1002/eco.1347, 2014.
Boumaiza, L., Chesnaux, R., Walter, J., and Stumpp, C.: Assessing groundwater recharge and transpiration in a humid northern region dominated by snowmelt using vadose-zone depth profiles, Hydrogeol. J., 28, 2315–2329, https://doi.org/10.1007/s10040-020-02204-z, 2020.
Brand, W. A., Geilmann, H., Crosson, E. R., and Rella, C. W.: Cavity ring-down spectroscopy versus high-temperature conversion isotope ratio mass spectrometry; a case study on δ2H and δ18O of pure water samples and alcohol/water mixtures, Rapid Commun. Mass Sp., 23, 1879–1884, https://doi.org/10.1002/rcm.4083, 2009.
Chesnaux, R. and Stumpp, C.: Advantages and challenges of using soil water isotopes to assess groundwater recharge dominated by snowmelt at a field study located in Canada, Hydrol. Sci. J., 63, 679–695, https://doi.org/10.1080/02626667.2018.1442577, 2018.
Clark, I. D. and Fritz, P.: Environmental Isotopes in Hydrogeology, Lewis, Boca Raton, 348 pp., https://doi.org/10.1201/9781482242911, 1997.
Craig, H.: Standard for reporting concentrations of deuterium and oxygen-18 in natural waters, Science, 133, 1833–1834, https://doi.org/10.1126/science.133.3467.1833, 1961.
Dalton, J.: Experimental Essays on the Constitution of Mixed Gases: On the Force of Steam or Vapour from Water or Other Liquids in Different Temperatures, Both in a Torricelli Vacuum and in Air; on Evaporation; and on Expansion of Gases by Heat, Memoirs of the Literary and Philosophical Society of Manchester, 5, 536–602, 1802.
David, K., Timms, W., Hughes, C. E., Crawford, J., and McGeeney, D.: Application of the pore water stable isotope method and hydrogeological approaches to characterise a wetland system, Hydrol. Earth Syst. Sci., 22, 6023–6041, https://doi.org/10.5194/hess-22-6023-2018, 2018.
Filippini, M., Stumpp, C., Nijenhuis, I., Richnow, H. H., and Gargini, A.: Evaluation of aquifer recharge and vulnerability in an alluvial lowland using environmental tracers, J. Hydrol., 529, 1657–1668, https://doi.org/10.1016/j.jhydrol.2015.07.055, 2015.
Foken, T.: Angewandte Meteorologie, Springer-Verlag, Berlin, 325 pp., https://doi.org/10.1007/978-3-642-25525-0_8, 2008.
Gaj, M., Lamparter, A., Woche, S. K., Bachmann, J., McDonnell, J. J., and Stange, C. F.: The role of matric potential, solid interfacial chemistry, and wettability on isotopic equilibrium fractionation, Vadose Zone J., 18, 180083, https://doi.org/10.2136/vzj2018.04.0083, 2019.
Garvelmann, J., Külls, C., and Weiler, M.: A porewater-based stable isotope approach for the investigation of subsurface hydrological processes, Hydrol. Earth Syst. Sci., 16, 631–640, https://doi.org/10.5194/hess-16-631-2012, 2012.
Gat, J. R.: Oxygen and hydrogen isotopes in the hydrologic cycle, Annu. Rev. Earth Pl. Sc., 24, 225–262, https://doi.org/10.1146/annurev.earth.24.1.225, 1996.
Gralher, B., Herbstritt, B., Weiler, M., Wassenaar, L. I., and Stumpp, C.: Correcting laser-based water stable isotope readings biased by carrier gas changes, Environ. Sci. Technol., 50, 7074–7081, https://doi.org/10.1021/acs.est.6b01124, 2016.
Gralher, B., Herbstritt, B., Weiler, M., Wassenaar, L. I., and Stumpp, C.: Correcting for biogenic gas matrix effects on laser-based pore water-vapor stable isotope measurements, Vadose Zone J., 17, 170157, https://doi.org/10.2136/vzj2017.08.0157, 2018.
Gonfiantini, R.: Environmental isotopes in lake studies,. in: Handbook of environmental isotope geochemistry, edited by: Fritz, P. and Fontes, J. C., 2, 113–168, https://doi.org/10.1016/B978-0-444-42225-5.50008-5, 1986.
Harrington, G. A., Gardner, W. P., Smerdon, B. D., and Hendry, M. J.: Palaeohydrogeological insights from natural tracer profiles in aquitard porewater, Great Artesian Basin, Australia, Water Resour. Res., 49, 4054–4070, https://doi.org/10.1002/wrcr.20327, 2013.
Hendry, M. J. and Wassenaar, L. I.: Inferring Heterogeneity in Aquitards Using High-Resolution δD and δ18O Profiles, Groundwater, 47, 639–645, https://doi.org/10.1111/j.1745-6584.2009.00564.x, 2009.
Hendry, M. J., Barbour, S. L., Zettl, J., Chostner, V., and Wassenaar, L. I.: Controls on the long-term downward transport of δ2H of water in a regionally extensive, two-layered aquitard system, Water Resour. Res., 47, W06505, https://doi.org/10.1029/2010WR010044, 2011a.
Hendry, M. J., Richman, B., and Wassenaar, L. I.: Correcting for methane interferences on δ2H and δ18O measurements in pore water using H2O(liquid)−H2O(vapor) equilibration laser spectroscopy., Anal. Chem., 83, 5789–5796, https://doi.org/10.1021/ac201341p, 2011b.
Hendry, M. J. and Wassenaar, L. I.: Millennial-scale diffusive migration of solutes in thick clay-rich aquitards: evidence from multiple environmental tracers, Hydrogeol. J., 19, 259–270, https://doi.org/10.1007/s10040-010-0647-4, 2011.
Hendry, M. J., Barbour, S. L., Novakowski, K., and Wassenaar, L. I.: Paleohydrogeology of the Cretaceous sediments of the Williston Basin using stable isotopes of water, Water Resour. Res., 49, 4580–4592, https://doi.org/10.1002/wrcr.20321, 2013.
Hendry, M. J., Schmeling, E., Wassenaar, L. I., Barbour, S. L., and Pratt, D.: Determining the stable isotope composition of pore water from saturated and unsaturated zone core: improvements to the direct vapour equilibration laser spectrometry method, Hydrol. Earth Syst. Sci., 19, 4427–4440, https://doi.org/10.5194/hess-19-4427-2015, 2015.
Herbstritt, B., Gralher, B., and Weiler, M.: Continuous in situ measurements of stable isotopes in liquid water, Water Resour. Res., 48, W03601, https://doi.org/10.1029/2011WR011369, 2012.
Horita, J.: Saline waters, in: Isotopes in the Water Cycle – Past, Present and Future of a Developing Science, edited by: Aggarwal, P. K., Gat, J. R., and Froehlich, K. F. O., Springer, Doordrecht, the Netherlands, 381 pp., https://doi.org/10.1007/1-4020-3023-1_17, 2005.
Ingraham, N. L. and Criss, R. E.: Effects of surface area and volume on the rate of isotopic exchange between water and water vapor, J. Geophys. Res.-Atmos., 98, 20547–20553, https://doi.org/10.1029/93jd01735, 1993.
Ingraham, N. L. and Criss, R. E.: The effect of vapor pressure on the rate of isotopic exchange between water and water vapor, Chem. Geol., 150, 287–292, https://doi.org/10.1016/s0009-2541(98)00109-0, 1998.
Kleine, L., Tetzlaff, D., Smith, A., Wang, H., and Soulsby, C.: Using water stable isotopes to understand evaporation, moisture stress, and re-wetting in catchment forest and grassland soils of the summer drought of 2018, Hydrol. Earth Syst. Sci., 24, 3737–3752, https://doi.org/10.5194/hess-24-3737-2020, 2020.
Koehler, G. and Wassenaar, L. I.: Realtime Stable Isotope Monitoring of Natural Waters by Parallel-Flow Laser Spectroscopy, Anal. Chem., 83, 913–919, https://doi.org/10.1021/ac102584q, 2011.
Koehler, G., Wassenaar, L. I., and Hendry, J.: Measurement of stable isotope activities in saline aqueous solutions using optical spectroscopy methods, Isotopes in environmental and health studies, 49, 378–386, https://doi.org/10.1080/10256016.2013.815183, 2013.
Rayleigh, Lord O. M. F. R. S.: LIX. On the distillation of binary mixtures, The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, 4, 521–537, https://doi.org/10.1080/14786440209462876, 1902.
Majoube M. F.: Fractionnement en oxygène-18 et en deuterium entre l'eau et sa vapeur, J. Chem. Phys., 58, 1423–1436, 1971.
Malowany, K., Stix, J., Van Pelt, A., and Lucic, G.: H2S interference on CO2 isotopic measurements using a Picarro G1101-i cavity ring-down spectrometer, Atmos. Meas. Tech., 8, 4075–4082, https://doi.org/10.5194/amt-8-4075-2015, 2015.
Martín-Gómez, P., Barbeta, A., Voltas, J., Peñuelas, J., Dennis, K., Palacio, S., Dawson, T. E., and Ferrio, J. P.: Isotope-ratio infrared spectroscopy: a reliable tool for the investigation of plant-water sources?, New Phytol, 207, 914–927, https://doi.org/10.1111/nph.13376, 2015.
Mattei, A., Barbecot, F., Guillon, S., Goblet, P., Hélie, J. F., and Meyzonnat, G.: Improved accuracy and precision of water stable isotope measurements using the direct vapour equilibration method, Rapid Commun. Mass Sp., 33, 1613–1622, https://doi.org/10.1002/rcm.8494, 2019.
Mattei, A., Barbecot, F., Goblet, P., and Guillon, S.: Pore water isotope fingerprints to understand the spatiotemporal groundwater recharge variability in ungauged watersheds, Vadose Zone J., 19, e20066, https://doi.org/10.1002/vzj2.20066, 2020.
Millar, C., Pratt, D., Schneider, D. J., and McDonnell, J. J.: A comparison of extraction systems for plant water stable isotope analysis, Rapid Commun. Mass Sp., 32, 1031–1044, https://doi.org/10.1002/rcm.8136, 2018.
Millar, C., Pratt, D., Schneider, D. J., Koehler, G., and McDonnell, J. J.: Further experiments comparing direct vapor equilibration and cryogenic vacuum distillation for plant water stable isotope analysis, Rapid Commun. Mass Sp., 1, 19-05-P, https://doi.org/10.1002/rcm.8530, 2019.
Mueller, M. H., Alaoui, A., Kuells, C., Leistert, H., Meusburger, K., Stumpp, C., Weiler, M., and Alewell, C.: Tracking water pathways in steep hillslopes by δ18O depth profiles of soil water, J. Hydrol., 519, 340–352, https://doi.org/10.1016/j.jhydrol.2014.07.031, 2014.
Munksgaard, N. C., Wurster, C. M., and Bird, M. I.: Continuous analysis of δ18O and δD values of water by diffusion sampling cavity ring-down spectrometry: a novel sampling device for unattended field monitoring of precipitation, ground and surface waters, Rapid Commun. Mass Sp., 25, 3706–3712, https://doi.org/10.1002/rcm.5282, 2011.
Nakata, K., Hasegawa, T., Oyama, T., and Miyakawa, K.: Evaluation of δ2H and δ18O of water in pores extracted by compression method – effects of closed pores and comparison to direct vapor equilibration and laser spectrometry method, J. Hydrol., 561, 547–556, https://doi.org/10.1016/j.jhydrol.2018.03.058, 2018.
Oerter, E. J., Perelet, A., Pardyjak, E., and Bowen, G.: Membrane inlet laser spectroscopy to measure H and O stable isotope compositions of soil and sediment pore water with high sample throughput, Rapid Commun. Mass Sp., 31, 75–84, https://doi.org/10.1002/rcm.7768, 2016.
Pratt, D. L., Lu, M., Barbour, S. L., and Hendry, M. J.: An evaluation of materials and methods for vapour measurement of the isotopic composition of pore water in deep, unsaturated zones, Isot. Environ. Healt. S., 52, 529–543, https://doi.org/10.1080/10256016.2016.1151423, 2016.
Rothfuss, Y., Vereecken, H., and Brüggemann, N.: Monitoring water stable isotopic composition in soils using gas-permeable tubing and infrared laser absorption spectroscopy, Water Resour. Res., 49, 3747–3755, https://doi.org/10.1002/wrcr.20311, 2013.
Smith, A., Tetzlaff, D., Kleine, L., Maneta, M. P., and Soulsby, C.: Isotope-aided modelling of ecohydrologic fluxes and water ages under mixed land use in Central Europe: The 2018 drought and its recovery, Hydrol. Process., 34, 3406–3425, https://doi.org/10.1002/hyp.13838, 2020.
Sprenger, M., Herbstritt, B., and Weiler, M.: Established methods and new opportunities for pore water stable isotope analysis, Hydrol. Process., 29, 5174–5192, https://doi.org/10.1002/hyp.10643, 2015a.
Sprenger, M., Volkmann, T. H. M., Blume, T., and Weiler, M.: Estimating flow and transport parameters in the unsaturated zone with pore water stable isotopes, Hydrol. Earth Syst. Sci., 19, 2617–2635, https://doi.org/10.5194/hess-19-2617-2015, 2015b.
Stumpp, C. and Hendry, M. J.: Spatial and temporal dynamics of water flow and solute transport in a heterogeneous glacial till: The application of high-resolution profiles of δ18O and δ2H in pore waters, J. Hydrol., 438–439, 203–214, https://doi.org/10.1016/j.jhydrol.2012.03.024, 2012.
URL1: Polymer Service GmbH, Merseburg, Germany: https://wiki.polymerservice-merseburg.de/index.php/Barriere-Kunststoffe, last access: 21 September 2021.
Volkmann, T. H. M. and Weiler, M.: Continual in situ monitoring of pore water stable isotopes in the subsurface, Hydrol. Earth Syst. Sci., 18, 1819–1833, https://doi.org/10.5194/hess-18-1819-2014, 2014.
Volkmann, T. H. M., Kühnhammer, K., Herbstritt, B., Gessler, A., and Weiler, M.: A method for in situ monitoring of the isotope composition of tree xylem water using laser spectroscopy, Plant Cell Environ., 39, 2055–2063, https://doi.org/10.1111/pce.12725, 2016.
Wang, H., Si, B., Pratt, D., Li, H., and Ma, X.: Calibration method affects the measured δ2H and δ18O in soil water by direct H2Oliquid–H2Ovapour equilibration with laser spectroscopy, Hydrol. Process., 9, 1–11, https://doi.org/10.1002/hyp.13606, 2019.
Wassenaar, L. I., Hendry, M. J., Chostner, V. L., and Lis, G. P.: High resolution pore water δ2H and δ18O measurements by H2O(liquid)–H2O(vapor) equilibration laser spectroscopy, Environ. Sci. Technol., 42, 9262–9267, https://doi.org/10.1021/es802065s, 2008.
Werner, R. A. and Brand, W. A.: Referencing strategies and techniques in stable isotope ratio analysis, Rapid Commun. Mass Sp., 15, 501–519, https://doi.org/10.1002/rcm.258, 2001.
West, A. G., Goldsmith, G. R., Matimati, I., and Dawson, T. E.: Spectral analysis software improves confidence in plant and soil water stable isotope analyses performed by isotope ratio infrared spectroscopy (IRIS), Rapid Commun. Mass Sp., 25, 2268–2274, https://doi.org/10.1002/rcm.5126, 2011.
Short summary
We scrutinized the quickest currently available method for stable isotope analysis of matrix-bound water. Simulating common procedures, we demonstrated the limits of certain materials currently used and identified a reliable and cost-efficient alternative. Further, we calculated the optimum proportions of important protocol aspects critical for precise and accurate analyses. Our unifying protocol suggestions increase data quality and comparability as well as the method's general applicability.
We scrutinized the quickest currently available method for stable isotope analysis of...
