Articles | Volume 25, issue 9
https://doi.org/10.5194/hess-25-5219-2021
https://doi.org/10.5194/hess-25-5219-2021
Technical note
 | 
27 Sep 2021
Technical note |  | 27 Sep 2021

Technical note: Unresolved aspects of the direct vapor equilibration method for stable isotope analysis (δ18O, δ2H) of matrix-bound water: unifying protocols through empirical and mathematical scrutiny

Benjamin Gralher, Barbara Herbstritt, and Markus Weiler

Related authors

Technical note: Discrete in situ vapor sampling for subsequent lab-based water stable isotope analysis
Barbara Herbstritt, Benjamin Gralher, Stefan Seeger, Michael Rinderer, and Markus Weiler
Hydrol. Earth Syst. Sci., 27, 3701–3718, https://doi.org/10.5194/hess-27-3701-2023,https://doi.org/10.5194/hess-27-3701-2023, 2023
Short summary
Technical note: Conservative storage of water vapour – practical in situ sampling of stable isotopes in tree stems
Ruth-Kristina Magh, Benjamin Gralher, Barbara Herbstritt, Angelika Kübert, Hyungwoo Lim, Tomas Lundmark, and John Marshall
Hydrol. Earth Syst. Sci., 26, 3573–3587, https://doi.org/10.5194/hess-26-3573-2022,https://doi.org/10.5194/hess-26-3573-2022, 2022
Short summary
Continuous, near-real-time observations of water stable isotope ratios during rainfall and throughfall events
Barbara Herbstritt, Benjamin Gralher, and Markus Weiler
Hydrol. Earth Syst. Sci., 23, 3007–3019, https://doi.org/10.5194/hess-23-3007-2019,https://doi.org/10.5194/hess-23-3007-2019, 2019
Short summary
Inter-laboratory comparison of cryogenic water extraction systems for stable isotope analysis of soil water
Natalie Orlowski, Lutz Breuer, Nicolas Angeli, Pascal Boeckx, Christophe Brumbt, Craig S. Cook, Maren Dubbert, Jens Dyckmans, Barbora Gallagher, Benjamin Gralher, Barbara Herbstritt, Pedro Hervé-Fernández, Christophe Hissler, Paul Koeniger, Arnaud Legout, Chandelle Joan Macdonald, Carlos Oyarzún, Regine Redelstein, Christof Seidler, Rolf Siegwolf, Christine Stumpp, Simon Thomsen, Markus Weiler, Christiane Werner, and Jeffrey J. McDonnell
Hydrol. Earth Syst. Sci., 22, 3619–3637, https://doi.org/10.5194/hess-22-3619-2018,https://doi.org/10.5194/hess-22-3619-2018, 2018
Short summary

Related subject area

Subject: Vadose Zone Hydrology | Techniques and Approaches: Instruments and observation techniques
High-resolution operational soil moisture monitoring for forests in central Germany
Ivan Vorobevskii, Thi Thanh Luong, Rico Kronenberg, and Rainer Petzold
Hydrol. Earth Syst. Sci., 28, 3567–3595, https://doi.org/10.5194/hess-28-3567-2024,https://doi.org/10.5194/hess-28-3567-2024, 2024
Short summary
Technical Note: Revisiting the general calibration of cosmic-ray neutron sensors to estimate soil water content
Maik Heistermann, Till Francke, Martin Schrön, and Sascha E. Oswald
Hydrol. Earth Syst. Sci., 28, 989–1000, https://doi.org/10.5194/hess-28-989-2024,https://doi.org/10.5194/hess-28-989-2024, 2024
Short summary
Technical note: A fast and objective autosampler for direct vapor equilibration isotope measurements
Jonas Pyschik, Stefan Seeger, Barbara Herbstritt, and Markus Weiler
EGUsphere, https://doi.org/10.5194/egusphere-2024-528,https://doi.org/10.5194/egusphere-2024-528, 2024
Short summary
Effects of changes in climatic conditions on soil water storage patterns
Annelie Ehrhardt, Jannis S. Groh, and Horst H. Gerke
EGUsphere, https://doi.org/10.5194/egusphere-2024-118,https://doi.org/10.5194/egusphere-2024-118, 2024
Short summary
Coupled hydrogeophysical inversion of an artificial infiltration experiment monitored with ground-penetrating radar: synthetic demonstration
Rohianuu Moua, Nolwenn Lesparre, Jean-François Girard, Benjamin Belfort, François Lehmann, and Anis Younes
Hydrol. Earth Syst. Sci., 27, 4317–4334, https://doi.org/10.5194/hess-27-4317-2023,https://doi.org/10.5194/hess-27-4317-2023, 2023
Short summary

Cited articles

Araguás-Araguás, L., Rozanski, K., Gonfiantini, R., and Louvat, D.: Isotope effects accompanying vacuum extraction of soil water for stable isotope analyses, J. Hydrol., 168, 159–171, https://doi.org/10.1016/0022-1694(94)02636-P, 1995. 
Bachmat, Y. and Bear, J.: On the Concept and Size of a Representative Elementary Volume (Rev), in: Advances in Transport Phenomena in Porous Media, edited by: Bear, J. and Corapcioglu, M. Y., NATO ASI Series (Series E: Applied Sciences), 128, Springer, Dordrecht, https://doi.org/10.1007/978-94-009-3625-6_1, 1987. 
Bertrand, G., Masini, J., Goldscheider, N., Meeks, J., Lavastre, V., Celle-Jeanton, H., Gobat, J.-M., and Hunkeler, D.: Determination of spatiotemporal variability of tree water uptake using stable isotopes (δ18O, δ2H) in an alluvial system supplied by a high-altitude watershed, Pfyn forest, Switzerland, Ecohydrology, 7, 319–333, https://doi.org/10.1002/eco.1347, 2014. 
Boumaiza, L., Chesnaux, R., Walter, J., and Stumpp, C.: Assessing groundwater recharge and transpiration in a humid northern region dominated by snowmelt using vadose-zone depth profiles, Hydrogeol. J., 28, 2315–2329, https://doi.org/10.1007/s10040-020-02204-z, 2020. 
Brand, W. A., Geilmann, H., Crosson, E. R., and Rella, C. W.: Cavity ring-down spectroscopy versus high-temperature conversion isotope ratio mass spectrometry; a case study on δ2H and δ18O of pure water samples and alcohol/water mixtures, Rapid Commun. Mass Sp., 23, 1879–1884, https://doi.org/10.1002/rcm.4083, 2009. 
Download
Short summary
We scrutinized the quickest currently available method for stable isotope analysis of matrix-bound water. Simulating common procedures, we demonstrated the limits of certain materials currently used and identified a reliable and cost-efficient alternative. Further, we calculated the optimum proportions of important protocol aspects critical for precise and accurate analyses. Our unifying protocol suggestions increase data quality and comparability as well as the method's general applicability.