Articles | Volume 25, issue 1
https://doi.org/10.5194/hess-25-401-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/hess-25-401-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
27 Jan 2021
Research article |
| 27 Jan 2021
| 27 Jan 2021
A comparison of catchment travel times and storage deduced from deuterium and tritium tracers using StorAge Selection functions
Nicolas Björn Rodriguez
CORRESPONDING AUTHOR
Catchment and Eco-hydrology Research Group, Environmental Research and Innovation Department, Luxembourg Institute of Science and Technology, Belvaux, Luxembourg
Institute of Water Resources and River Basin Management, Karlsruhe Institute of Technology, Karlsruhe, Germany
Laurent Pfister
Catchment and Eco-hydrology Research Group, Environmental Research and Innovation Department, Luxembourg Institute of Science and Technology, Belvaux, Luxembourg
Erwin Zehe
Institute of Water Resources and River Basin Management, Karlsruhe Institute of Technology, Karlsruhe, Germany
Julian Klaus
Catchment and Eco-hydrology Research Group, Environmental Research and Innovation Department, Luxembourg Institute of Science and Technology, Belvaux, Luxembourg
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EGUsphere, https://doi.org/10.5194/egusphere-2025-3365, https://doi.org/10.5194/egusphere-2025-3365, 2025
This preprint is open for discussion and under review for Hydrology and Earth System Sciences (HESS).
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Measurements of water isotopes are often used to estimate water transit time distributions and aquifer storage thickness in catchments. However, laboratory-scale measurements show that water isotopes exhibit transport behavior identical to that of inert chemical tracers rather than of pure water. The measured mean tracer and apparent mean water velocities are not necessarily equal; recognition of this inequality is critical when estimating catchment properties such as aquifer storage thickness.
Mortimer L. Bacher, Julian Klaus, Adam S. Ward, Jasmine Krause, Catalina Segura, and Clarissa Glaser
EGUsphere, https://doi.org/10.5194/egusphere-2025-1625, https://doi.org/10.5194/egusphere-2025-1625, 2025
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Slug tracer experiments are biased toward faster flow paths, underscoring the need for tracers that reveal temporally longer timescales. We explore integrating solute tracers with naturally occurring radon to quantify flow paths of different timescales at the reach scale. Joint calibration of a transient storage model with both tracers better constrains model parameters, highlighting that this approach is critical for improving solute transport estimates in future studies.
Karl Nicolaus van Zweel, Laurent Gourdol, Jean François Iffly, Loïc Léonard, François Barnich, Laurent Pfister, Erwin Zehe, and Christophe Hissler
Earth Syst. Sci. Data, 17, 2217–2229, https://doi.org/10.5194/essd-17-2217-2025, https://doi.org/10.5194/essd-17-2217-2025, 2025
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Our study monitored groundwater in a Luxembourg forest over a year to understand water and chemical changes. We found seasonal variations in water chemistry, influenced by rainfall and soil interactions. These data help predict environmental responses and manage water resources better. By measuring key parameters like pH and dissolved oxygen, our research provides valuable insights into groundwater behaviour and serves as a resource for future environmental studies.
Judith Nijzink, Ralf Loritz, Laurent Gourdol, Davide Zoccatelli, Jean François Iffly, and Laurent Pfister
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-482, https://doi.org/10.5194/essd-2024-482, 2025
Preprint under review for ESSD
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Guilhem Türk, Christoph J. Gey, Bernd R. Schöne, Marius G. Floriancic, James W. Kirchner, Loic Leonard, Laurent Gourdol, Richard Keim, and Laurent Pfister
EGUsphere, https://doi.org/10.5194/egusphere-2025-1530, https://doi.org/10.5194/egusphere-2025-1530, 2025
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How landscape features affect water storage and release in catchments remains poorly understood. Here we used water stable isotopes in 12 streams to assess the fraction of precipitation reaching streamflow in less than 2 weeks. More recent precipitation was found when streamflow was high and the fraction was linked to the geology (i.e. high when impermeable, low when permeable). Such information is key for better anticipating streamflow responses to a changing climate.
Svenja Hoffmeister, Sibylle Kathrin Hassler, Friederike Lang, Rebekka Maier, Betserai Isaac Nyoka, and Erwin Zehe
EGUsphere, https://doi.org/10.5194/egusphere-2025-1719, https://doi.org/10.5194/egusphere-2025-1719, 2025
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Combining trees and crops in agroforestry systems can potentially be a sustainable option for agriculture facing climate change impacts. We used methods from soil science and hydrology to assess the effect of adding gliricidia trees to maize fields, on carbon content, soil properties and water availability. Our results show a clear increase in carbon contents and effects on physical soil characteristics and water uptake and retention as a consequence of the agroforestry treatment.
Evgeny Shavelzon, Erwin Zehe, and Yaniv Edery
EGUsphere, https://doi.org/10.22541/essoar.173687429.91307309/v1, https://doi.org/10.22541/essoar.173687429.91307309/v1, 2025
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We analyze how chemical reactions and fluid movement interact in porous materials, focusing on how water paths form in underground environments. Using a thermodynamic approach, we track energy dissipation and entropy changes to understand this process. Over time, water channels become more defined, reducing chemical mixing and energy loss. Eventually, the system stabilizes, with flow concentrated in efficient pathways, minimizing further reactions and energy use.
Tim Busker, Daniela Rodriguez Castro, Sergiy Vorogushyn, Jaap Kwadijk, Davide Zoccatelli, Rafaella Loureiro, Heather J. Murdock, Laurent Pfister, Benjamin Dewals, Kymo Slager, Annegret H. Thieken, Jan Verkade, Patrick Willems, and Jeroen C. J. H. Aerts
EGUsphere, https://doi.org/10.5194/egusphere-2025-828, https://doi.org/10.5194/egusphere-2025-828, 2025
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In July 2021, the Netherlands, Luxembourg, Germany, and Belgium were hit by an extreme flood event with over 200 fatalities. Our study provides, for the first time, critical insights into the operational flood early-warning systems in this entire region. Based on 13 expert interviews, we conclude that the systems strongly improved in all countries. Interviewees stressed the need for operational impact-based forecasts, but emphasized that its operational implementation is challenging.
Guilhem Türk, Christoph Johannes Gey, Bernd Reinhard Schöne, and Laurent Pfister
EGUsphere, https://doi.org/10.5194/egusphere-2024-4169, https://doi.org/10.5194/egusphere-2024-4169, 2025
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Past stream flow dynamics can be assessed using the stable isotopes of oxygen (O16/O18) in streams and precipitation from various proxy sources. Here, we show how they are retrieved in precipitation for ~150 years using temperature records and an atmospheric circulation classification scheme. Our robust and assumption-lean approach compares to model performances in the literature, demonstrating atmospheric controls of the temperature influence on precipitation O16/O18 compositions.
Huibin Gao, Laurent Pfister, and James W. Kirchner
EGUsphere, https://doi.org/10.5194/egusphere-2025-613, https://doi.org/10.5194/egusphere-2025-613, 2025
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Some streams respond to rainfall with flow that peaks twice: a sharp first peak followed by a broad second peak. We analyzed data from a catchment in Luxembourg to better understand the processes behind this phenomenon. Our results show that the first peak is mostly driven directly by rainfall, and the second peak is mostly driven by rain that infiltrates to groundwater. We also show that the relative importance of these two processes depends on how wet the landscape is before the rain falls.
Samuele Ceolin, Stanislaus J. Schymanski, Dagmar van Dusschoten, Robert Koller, and Julian Klaus
Biogeosciences, 22, 691–703, https://doi.org/10.5194/bg-22-691-2025, https://doi.org/10.5194/bg-22-691-2025, 2025
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We investigated if and how roots of maize plants respond to multiple abrupt changes in soil moisture. We measured root lengths using a magnetic resonance imaging technique and calculated changes in growth rates after applying water pulses. The root growth rates increased in wetted soil layers within 48 hours and decreased in non-wetted layers, indicating fast adaptation of the root systems to moisture changes. Our findings could improve irrigation management and vegetation models.
Paolo Nasta, Günter Blöschl, Heye R. Bogena, Steffen Zacharias, Roland Baatz, Gabriëlle De Lannoy, Karsten H. Jensen, Salvatore Manfreda, Laurent Pfister, Ana M. Tarquis, Ilja van Meerveld, Marc Voltz, Yijian Zeng, William Kustas, Xin Li, Harry Vereecken, and Nunzio Romano
Hydrol. Earth Syst. Sci., 29, 465–483, https://doi.org/10.5194/hess-29-465-2025, https://doi.org/10.5194/hess-29-465-2025, 2025
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The Unsolved Problems in Hydrology (UPH) initiative has emphasized the need to establish networks of multi-decadal hydrological observatories to tackle catchment-scale challenges on a global scale. This opinion paper provocatively discusses two endmembers of possible future hydrological observatory (HO) networks for a given hypothesized community budget: a comprehensive set of moderately instrumented observatories or, alternatively, a small number of highly instrumented supersites.
Ashish Manoj J, Ralf Loritz, Hoshin Gupta, and Erwin Zehe
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2024-375, https://doi.org/10.5194/hess-2024-375, 2024
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Svenja Hoffmeister, Rafael Bohn Reckziegel, Ben du Toit, Sibylle K. Hassler, Florian Kestel, Rebekka Maier, Jonathan P. Sheppard, and Erwin Zehe
Hydrol. Earth Syst. Sci., 28, 3963–3982, https://doi.org/10.5194/hess-28-3963-2024, https://doi.org/10.5194/hess-28-3963-2024, 2024
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We studied a tree–crop ecosystem consisting of a blackberry field and an alder windbreak. In the water-scarce region, irrigation provides sufficient water for plant growth. The windbreak lowers the irrigation amount by reducing wind speed and therefore water transport into the atmosphere. These ecosystems could provide sustainable use of water-scarce landscapes, and we studied the complex interactions by observing several aspects (e.g. soil, nutrients, carbon assimilation, water).
Laurent Gourdol, Michael K. Stewart, Uwe Morgenstern, and Laurent Pfister
Hydrol. Earth Syst. Sci., 28, 3519–3547, https://doi.org/10.5194/hess-28-3519-2024, https://doi.org/10.5194/hess-28-3519-2024, 2024
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Determining water transit times in aquifers is key to a better understanding of groundwater resources and their sustainable management. For our research, we used high-accuracy tritium data from 35 springs draining the Luxembourg Sandstone aquifer. We assessed the mean transit times of groundwater and found that water moves on average more than 10 times more slowly vertically in the vadose zone of the aquifer (~12 m yr-1) than horizontally in its saturated zone (~170 m yr-1).
Ginevra Fabiani, Julian Klaus, and Daniele Penna
Hydrol. Earth Syst. Sci., 28, 2683–2703, https://doi.org/10.5194/hess-28-2683-2024, https://doi.org/10.5194/hess-28-2683-2024, 2024
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There is a limited understanding of the role that topography and climate play in tree water use. Through a cross-site comparison in Luxembourg and Italy, we investigated beech water use along slopes in different climates. Our findings indicate that in landscapes characterized by stronger hydraulic and climatic gradients there is greater spatial variation in tree physiological responses. This highlights how differing growing conditions across landscapes can lead to contrasting tree performances.
Samuel Schroers, Ulrike Scherer, and Erwin Zehe
Hydrol. Earth Syst. Sci., 27, 2535–2557, https://doi.org/10.5194/hess-27-2535-2023, https://doi.org/10.5194/hess-27-2535-2023, 2023
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The hydrological cycle shapes our landscape. With an accelerating change of the world's climate and hydrological dynamics, concepts of evolution of natural systems become more important. In this study, we elaborated a thermodynamic framework for runoff and sediment transport and show from model results as well as from measurements during extreme events that the developed concept is useful for understanding the evolution of the system's mass, energy, and entropy fluxes.
Judith Meyer, Malte Neuper, Luca Mathias, Erwin Zehe, and Laurent Pfister
Hydrol. Earth Syst. Sci., 26, 6163–6183, https://doi.org/10.5194/hess-26-6163-2022, https://doi.org/10.5194/hess-26-6163-2022, 2022
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We identified and analysed the major atmospheric components of rain-intense thunderstorms that can eventually lead to flash floods: high atmospheric moisture, sufficient latent instability, and weak thunderstorm cell motion. Between 1981 and 2020, atmospheric conditions became likelier to support strong thunderstorms. However, the occurrence of extreme rainfall events as well as their rainfall intensity remained mostly unchanged.
Enrico Bonanno, Günter Blöschl, and Julian Klaus
Hydrol. Earth Syst. Sci., 26, 6003–6028, https://doi.org/10.5194/hess-26-6003-2022, https://doi.org/10.5194/hess-26-6003-2022, 2022
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There is an unclear understanding of which processes regulate the transport of water, solutes, and pollutants in streams. This is crucial since these processes control water quality in river networks. Compared to other approaches, we obtained clearer insights into the processes controlling solute transport in the investigated reach. This work highlights the risks of using uncertain results for interpreting the processes controlling water movement in streams.
Audrey Douinot, Jean François Iffly, Cyrille Tailliez, Claude Meisch, and Laurent Pfister
Hydrol. Earth Syst. Sci., 26, 5185–5206, https://doi.org/10.5194/hess-26-5185-2022, https://doi.org/10.5194/hess-26-5185-2022, 2022
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The objective of the paper is to highlight the seasonal and singular shift of the transfer time distributions of two catchments (≅10 km2).
Based on 2 years of rainfall and discharge observations, we compare variations in the properties of TTDs with the physiographic characteristics of catchment areas and the eco-hydrological cycle. The paper eventually aims to deduce several factors conducive to particularly rapid and concentrated water transfers, which leads to flash floods.
Ralf Loritz, Maoya Bassiouni, Anke Hildebrandt, Sibylle K. Hassler, and Erwin Zehe
Hydrol. Earth Syst. Sci., 26, 4757–4771, https://doi.org/10.5194/hess-26-4757-2022, https://doi.org/10.5194/hess-26-4757-2022, 2022
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In this study, we combine a deep-learning approach that predicts sap flow with a hydrological model to improve soil moisture and transpiration estimates at the catchment scale. Our results highlight that hybrid-model approaches, combining machine learning with physically based models, are a promising way to improve our ability to make hydrological predictions.
Alessandro Montemagno, Christophe Hissler, Victor Bense, Adriaan J. Teuling, Johanna Ziebel, and Laurent Pfister
Biogeosciences, 19, 3111–3129, https://doi.org/10.5194/bg-19-3111-2022, https://doi.org/10.5194/bg-19-3111-2022, 2022
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We investigated the biogeochemical processes that dominate the release and retention of elements (nutrients and potentially toxic elements) during litter degradation. Our results show that toxic elements are retained in the litter, while nutrients are released in solution during the first stages of degradation. This seems linked to the capability of trees to distribute the elements between degradation-resistant and non-degradation-resistant compounds of leaves according to their chemical nature.
Samuel Schroers, Olivier Eiff, Axel Kleidon, Ulrike Scherer, Jan Wienhöfer, and Erwin Zehe
Hydrol. Earth Syst. Sci., 26, 3125–3150, https://doi.org/10.5194/hess-26-3125-2022, https://doi.org/10.5194/hess-26-3125-2022, 2022
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In hydrology the formation of landform patterns is of special interest as changing forcings of the natural systems, such as climate or land use, will change these structures. In our study we developed a thermodynamic framework for surface runoff on hillslopes and highlight the differences of energy conversion patterns on two related spatial and temporal scales. The results indicate that surface runoff on hillslopes approaches a maximum power state.
Alexander Sternagel, Ralf Loritz, Brian Berkowitz, and Erwin Zehe
Hydrol. Earth Syst. Sci., 26, 1615–1629, https://doi.org/10.5194/hess-26-1615-2022, https://doi.org/10.5194/hess-26-1615-2022, 2022
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We present a (physically based) Lagrangian approach to simulate diffusive mixing processes on the pore scale beyond perfectly mixed conditions. Results show the feasibility of the approach for reproducing measured mixing times and concentrations of isotopes over pore sizes and that typical shapes of breakthrough curves (normally associated with non-uniform transport in heterogeneous soils) may also occur as a result of imperfect subscale mixing in a macroscopically homogeneous soil matrix.
Erwin Zehe, Ralf Loritz, Yaniv Edery, and Brian Berkowitz
Hydrol. Earth Syst. Sci., 25, 5337–5353, https://doi.org/10.5194/hess-25-5337-2021, https://doi.org/10.5194/hess-25-5337-2021, 2021
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This study uses the concepts of entropy and work to quantify and explain the emergence of preferential flow and transport in heterogeneous saturated porous media. We found that the downstream concentration of solutes in preferential pathways implies a downstream declining entropy in the transverse distribution of solute transport pathways. Preferential flow patterns with lower entropies emerged within media of higher heterogeneity – a stronger self-organization despite a higher randomness.
Laurent Gourdol, Rémi Clément, Jérôme Juilleret, Laurent Pfister, and Christophe Hissler
Hydrol. Earth Syst. Sci., 25, 1785–1812, https://doi.org/10.5194/hess-25-1785-2021, https://doi.org/10.5194/hess-25-1785-2021, 2021
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Electrical resistivity tomography (ERT) is a remarkable tool for characterizing the regolith, but its use over large areas remains cumbersome due to the requirement of small electrode spacing (ES). In this study we document the issues of using oversized ESs and propose a new approach to overcome this limitation. We demonstrate that our protocol significantly improves the accuracy of ERT profiles using large ES and offers a cost-effective means for carrying out large-scale surveys.
Jan Bondy, Jan Wienhöfer, Laurent Pfister, and Erwin Zehe
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2021-174, https://doi.org/10.5194/hess-2021-174, 2021
Manuscript not accepted for further review
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The Budyko curve is a widely-used and simple framework to predict the mean water balance of river catchments. While many catchments are in close accordance with the Budyko curve, others show more or less significant deviations. Our study aims at better understanding the role of soil storage characteristics in the mean water balance and offsets from the Budyko curve. Soil storage proved to be a very sensitive property and potentially explains significant deviations from the curve.
Alexander Sternagel, Ralf Loritz, Julian Klaus, Brian Berkowitz, and Erwin Zehe
Hydrol. Earth Syst. Sci., 25, 1483–1508, https://doi.org/10.5194/hess-25-1483-2021, https://doi.org/10.5194/hess-25-1483-2021, 2021
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The key innovation of the study is a method to simulate reactive solute transport in the vadose zone within a Lagrangian framework. We extend the LAST-Model with a method to account for non-linear sorption and first-order degradation processes during unsaturated transport of reactive substances in the matrix and macropores. Model evaluations using bromide and pesticide data from irrigation experiments under different flow conditions on various timescales show the feasibility of the method.
Samuel Schroers, Olivier Eiff, Axel Kleidon, Jan Wienhöfer, and Erwin Zehe
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2021-79, https://doi.org/10.5194/hess-2021-79, 2021
Manuscript not accepted for further review
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In this study we ask the basic question why surface runoff forms drainage networks and confluences at all and how structural macro form and micro topography is a result of thermodynamic laws. We find that on a macro level hillslopes should tend from negative exponential towards exponential forms and that on a micro level the formation of rills goes hand in hand with drainage network formation of river basins. We hypothesize that we can learn more about erosion processes if we extend this theory.
Ralf Loritz, Markus Hrachowitz, Malte Neuper, and Erwin Zehe
Hydrol. Earth Syst. Sci., 25, 147–167, https://doi.org/10.5194/hess-25-147-2021, https://doi.org/10.5194/hess-25-147-2021, 2021
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This study investigates the role and value of distributed rainfall in the runoff generation of a mesoscale catchment. We compare the performance of different hydrological models at different periods and show that a distributed model driven by distributed rainfall yields improved performances only during certain periods. We then step beyond this finding and develop a spatially adaptive model that is capable of dynamically adjusting its spatial model structure in time.
Conrad Jackisch, Samuel Knoblauch, Theresa Blume, Erwin Zehe, and Sibylle K. Hassler
Biogeosciences, 17, 5787–5808, https://doi.org/10.5194/bg-17-5787-2020, https://doi.org/10.5194/bg-17-5787-2020, 2020
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We developed software to calculate the root water uptake (RWU) of beech tree roots from soil moisture dynamics. We present our approach and compare RWU to measured sap flow in the tree stem. The study relates to two sites that are similar in topography and weather but with contrasting soils. While sap flow is very similar between the two sites, the RWU is different. This suggests that soil characteristics have substantial influence. Our easy-to-implement RWU estimate may help further studies.
Jasper Foets, Carlos E. Wetzel, Núria Martínez-Carreras, Adriaan J. Teuling, Jean-François Iffly, and Laurent Pfister
Hydrol. Earth Syst. Sci., 24, 4709–4725, https://doi.org/10.5194/hess-24-4709-2020, https://doi.org/10.5194/hess-24-4709-2020, 2020
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Diatoms (microscopic algae) are regarded as useful tracers in catchment hydrology. However, diatom analysis is labour-intensive; therefore, only a limited number of samples can be analysed. To reduce this number, we explored the potential for a time-integrated mass-flux sampler to provide a representative sample of the diatom assemblage for a whole storm run-off event. Our results indicate that the Phillips sampler did indeed sample representative communities during two of the three events.
Uwe Ehret, Rik van Pruijssen, Marina Bortoli, Ralf Loritz, Elnaz Azmi, and Erwin Zehe
Hydrol. Earth Syst. Sci., 24, 4389–4411, https://doi.org/10.5194/hess-24-4389-2020, https://doi.org/10.5194/hess-24-4389-2020, 2020
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In this paper we propose adaptive clustering as a new method for reducing the computational efforts of distributed modelling. It consists of identifying similar-acting model elements during the runtime, clustering them, running the model for just a few representatives per cluster, and mapping their results to the remaining model elements in the cluster. With the example of a hydrological model, we show that this saves considerable computation time, while largely maintaining the output quality.
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Short summary
Different parts of water have often been used as tracers to determine the age of water in streams. The stable tracers, such as deuterium, are thought to be unable to reveal old water compared to the radioactive tracer called tritium. We used both tracers, measured in precipitation and in a stream in Luxembourg, to show that this is not necessarily true. It is, in fact, advantageous to use the two tracers together, and we recommend systematically using tritium in future studies.
Different parts of water have often been used as tracers to determine the age of water in...
