Articles | Volume 25, issue 12
https://doi.org/10.5194/hess-25-6067-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/hess-25-6067-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Small-scale topography explains patterns and dynamics of dissolved organic carbon exports from the riparian zone of a temperate, forested catchment
Benedikt J. Werner
CORRESPONDING AUTHOR
Department of Hydrogeology, Helmholtz Centre for Environmental Research – UFZ, 04318 Leipzig, Germany
Oliver J. Lechtenfeld
Research group BioGeoOmics, Department of Analytical Chemistry, Helmholtz Centre for Environmental Research – UFZ, 04318 Leipzig, Germany
Andreas Musolff
Department of Hydrogeology, Helmholtz Centre for Environmental Research – UFZ, 04318 Leipzig, Germany
Gerrit H. de Rooij
Department of Soil System Sciences, Helmholtz Centre for Environmental Research – UFZ, 06120 Halle, Germany
Department of Hydrogeology, Helmholtz Centre for Environmental Research – UFZ, 04318 Leipzig, Germany
Ralf Gründling
Department of Soil System Sciences, Helmholtz Centre for Environmental Research – UFZ, 06120 Halle, Germany
Ulrike Werban
Department of Monitoring and Exploration Technologies, Helmholtz Centre for Environmental Research – UFZ, 04318 Leipzig, Germany
Jan H. Fleckenstein
Department of Hydrogeology, Helmholtz Centre for Environmental Research – UFZ, 04318 Leipzig, Germany
Hydrologic Modelling Unit, Bayreuth Center of Ecology and Environmental Research (BayCEER), University of Bayreuth, Bayreuth, Germany
Related authors
Benedikt J. Werner, Andreas Musolff, Oliver J. Lechtenfeld, Gerrit H. de Rooij, Marieke R. Oosterwoud, and Jan H. Fleckenstein
Biogeosciences, 16, 4497–4516, https://doi.org/10.5194/bg-16-4497-2019, https://doi.org/10.5194/bg-16-4497-2019, 2019
Short summary
Short summary
Increased dissolved organic carbon (DOC) concentration in streams can pose a threat to downstream water resources. Analyzing data from an in-stream probe we found that hydroclimatic and hydrological drivers can describe up to 72 % of the observed DOC concentration and composition variability. Variability was found to be highest during discharge events with warm and dry preconditions. The findings suggest an impact of climate change on DOC exports and thus also on downstream water quality.
Pia Ebeling, Andreas Musolff, Rohini Kumar, Andreas Hartmann, and Jan H. Fleckenstein
EGUsphere, https://doi.org/10.5194/egusphere-2024-2761, https://doi.org/10.5194/egusphere-2024-2761, 2024
Short summary
Short summary
Groundwater is a crucial resource at risk by droughts. To understand drought effects on groundwater in Germany, we grouped 6626 wells into six regional and two nationwide head patterns. Weather explained half of the head variations with varied response times. Shallow groundwater responds fast and is more vulnerable to short droughts (few months). Dampened deep heads buffer short droughts but suffer from long droughts and recoveries. Two nationwide trend patterns were linked to human water use.
Peter Jung, Götz Hornbruch, Andreas Dahmke, Peter Dietrich, and Ulrike Werban
EGUsphere, https://doi.org/10.5194/egusphere-2024-257, https://doi.org/10.5194/egusphere-2024-257, 2024
Short summary
Short summary
We demonstrate the feasibility of imaging vertical freezing boundaries using borehole-GPR in an experimental geological latent heat storage, where a part of a shallow quaternary aquifer is frozen. To get insight on the current thermal state in the subsurface the dimension of the frozen volume is assessed. We show, that a combination of crosshole and reflection measurements enables to image the ice body with high accuracy in the, for GPR, challenging environment of saturated sediments.
Arianna Borriero, Rohini Kumar, Tam V. Nguyen, Jan H. Fleckenstein, and Stefanie R. Lutz
Hydrol. Earth Syst. Sci., 27, 2989–3004, https://doi.org/10.5194/hess-27-2989-2023, https://doi.org/10.5194/hess-27-2989-2023, 2023
Short summary
Short summary
We analyzed the uncertainty of the water transit time distribution (TTD) arising from model input (interpolated tracer data) and structure (StorAge Selection, SAS, functions). We found that uncertainty was mainly associated with temporal interpolation, choice of SAS function, nonspatial interpolation, and low-flow conditions. It is important to characterize the specific uncertainty sources and their combined effects on TTD, as this has relevant implications for both water quantity and quality.
Michael Rode, Jörg Tittel, Frido Reinstorf, Michael Schubert, Kay Knöller, Benjamin Gilfedder, Florian Merensky-Pöhlein, and Andreas Musolff
Hydrol. Earth Syst. Sci., 27, 1261–1277, https://doi.org/10.5194/hess-27-1261-2023, https://doi.org/10.5194/hess-27-1261-2023, 2023
Short summary
Short summary
Agricultural catchments show elevated phosphorus (P) concentrations during summer low flow. In an agricultural stream, we found that phosphorus in groundwater was a major source of stream water phosphorus during low flow, and stream sediments derived from farmland are unlikely to have increased stream phosphorus concentrations during low water. We found no evidence that riparian wetlands contributed to soluble reactive (SR) P loads. Agricultural phosphorus was largely buffered in the soil zone.
Georg Kaufmann, Douchko Romanov, Ulrike Werban, and Thomas Vienken
Solid Earth, 14, 333–351, https://doi.org/10.5194/se-14-333-2023, https://doi.org/10.5194/se-14-333-2023, 2023
Short summary
Short summary
We discuss collapse sinkholes occuring since 2004 on the sports field of Münsterdorf, a village north of Hamburg. The sinkholes, 2–5 m in size and about 3–5 m deep, develop in peri-glacial sand, with a likely origin in the Cretaceous chalk, present at about 20 m depth. The area has been analyzed with geophysical and direct-push-based methods, from which material properties of the subsurface have been derived. The properties have been used for mechanical models, predicting the subsidence.
Carolin Winter, Tam V. Nguyen, Andreas Musolff, Stefanie R. Lutz, Michael Rode, Rohini Kumar, and Jan H. Fleckenstein
Hydrol. Earth Syst. Sci., 27, 303–318, https://doi.org/10.5194/hess-27-303-2023, https://doi.org/10.5194/hess-27-303-2023, 2023
Short summary
Short summary
The increasing frequency of severe and prolonged droughts threatens our freshwater resources. While we understand drought impacts on water quantity, its effects on water quality remain largely unknown. Here, we studied the impact of the unprecedented 2018–2019 drought in Central Europe on nitrate export in a heterogeneous mesoscale catchment in Germany. We show that severe drought can reduce a catchment's capacity to retain nitrogen, intensifying the internal pollution and export of nitrate.
Thomas Hermans, Pascal Goderniaux, Damien Jougnot, Jan H. Fleckenstein, Philip Brunner, Frédéric Nguyen, Niklas Linde, Johan Alexander Huisman, Olivier Bour, Jorge Lopez Alvis, Richard Hoffmann, Andrea Palacios, Anne-Karin Cooke, Álvaro Pardo-Álvarez, Lara Blazevic, Behzad Pouladi, Peleg Haruzi, Alejandro Fernandez Visentini, Guilherme E. H. Nogueira, Joel Tirado-Conde, Majken C. Looms, Meruyert Kenshilikova, Philippe Davy, and Tanguy Le Borgne
Hydrol. Earth Syst. Sci., 27, 255–287, https://doi.org/10.5194/hess-27-255-2023, https://doi.org/10.5194/hess-27-255-2023, 2023
Short summary
Short summary
Although invisible, groundwater plays an essential role for society as a source of drinking water or for ecosystems but is also facing important challenges in terms of contamination. Characterizing groundwater reservoirs with their spatial heterogeneity and their temporal evolution is therefore crucial for their sustainable management. In this paper, we review some important challenges and recent innovations in imaging and modeling the 4D nature of the hydrogeological systems.
Felipe A. Saavedra, Andreas Musolff, Jana von Freyberg, Ralf Merz, Stefano Basso, and Larisa Tarasova
Hydrol. Earth Syst. Sci., 26, 6227–6245, https://doi.org/10.5194/hess-26-6227-2022, https://doi.org/10.5194/hess-26-6227-2022, 2022
Short summary
Short summary
Nitrate contamination of rivers from agricultural sources is a challenge for water quality management. During runoff events, different transport paths within the catchment might be activated, generating a variety of responses in nitrate concentration in stream water. Using nitrate samples from 184 German catchments and a runoff event classification, we show that hydrologic connectivity during runoff events is a key control of nitrate transport from catchments to streams in our study domain.
Gerrit Huibert de Rooij
Hydrol. Earth Syst. Sci., 26, 5849–5858, https://doi.org/10.5194/hess-26-5849-2022, https://doi.org/10.5194/hess-26-5849-2022, 2022
Short summary
Short summary
The way soils capture infiltrating water affects crops and natural vegetation as well as groundwater recharge. This retention of soil water is captured by a mathematical function that covers all water contents from very dry to water-saturated. Unfortunately, data in the dry range are often absent or unreliable. I modified an earlier function to be more robust in the absence of dry-range data, and present a computer program to estimate the parameters of the new function.
Jie Yang, Qiaoyu Wang, Ingo Heidbüchel, Chunhui Lu, Yueqing Xie, Andreas Musolff, and Jan H. Fleckenstein
Hydrol. Earth Syst. Sci., 26, 5051–5068, https://doi.org/10.5194/hess-26-5051-2022, https://doi.org/10.5194/hess-26-5051-2022, 2022
Short summary
Short summary
We assessed the effect of catchment topographic slopes on the nitrate export dynamics in terms of the nitrogen mass fluxes and concentration level using a coupled surface–subsurface model. We found that flatter landscapes tend to retain more nitrogen mass in the soil and export less nitrogen mass to the stream, explained by the reduced leaching and increased potential of degradation in flat landscapes. We emphasized that stream water quality is potentially less vulnerable in flatter landscapes.
Pia Ebeling, Rohini Kumar, Stefanie R. Lutz, Tam Nguyen, Fanny Sarrazin, Michael Weber, Olaf Büttner, Sabine Attinger, and Andreas Musolff
Earth Syst. Sci. Data, 14, 3715–3741, https://doi.org/10.5194/essd-14-3715-2022, https://doi.org/10.5194/essd-14-3715-2022, 2022
Short summary
Short summary
Environmental data are critical for understanding and managing ecosystems, including the mitigation of water quality degradation. To increase data availability, we present the first large-sample water quality data set (QUADICA) of riverine macronutrient concentrations combined with water quantity, meteorological, and nutrient forcing data as well as catchment attributes. QUADICA covers 1386 German catchments to facilitate large-sample data-driven and modeling water quality assessments.
Guilherme E. H. Nogueira, Christian Schmidt, Daniel Partington, Philip Brunner, and Jan H. Fleckenstein
Hydrol. Earth Syst. Sci., 26, 1883–1905, https://doi.org/10.5194/hess-26-1883-2022, https://doi.org/10.5194/hess-26-1883-2022, 2022
Short summary
Short summary
In near-stream aquifers, mixing between stream water and ambient groundwater can lead to dilution and the removal of substances that can be harmful to the water ecosystem at high concentrations. We used a numerical model to track the spatiotemporal evolution of different water sources and their mixing around a stream, which are rather difficult in the field. Results show that mixing mainly develops as narrow spots, varying In time and space, and is affected by magnitudes of discharge events.
Joni Dehaspe, Fanny Sarrazin, Rohini Kumar, Jan H. Fleckenstein, and Andreas Musolff
Hydrol. Earth Syst. Sci., 25, 6437–6463, https://doi.org/10.5194/hess-25-6437-2021, https://doi.org/10.5194/hess-25-6437-2021, 2021
Short summary
Short summary
Increased nitrate concentrations in surface waters can compromise river ecosystem health. As riverine nitrate uptake is hard to measure, we explore how low-frequency nitrate concentration and discharge observations (that are widely available) can help to identify (in)efficient uptake in river networks. We find that channel geometry and water velocity rather than the biological uptake capacity dominate the nitrate-discharge pattern at the outlet. The former can be used to predict uptake.
Katharina Blaurock, Burkhard Beudert, Benjamin S. Gilfedder, Jan H. Fleckenstein, Stefan Peiffer, and Luisa Hopp
Hydrol. Earth Syst. Sci., 25, 5133–5151, https://doi.org/10.5194/hess-25-5133-2021, https://doi.org/10.5194/hess-25-5133-2021, 2021
Short summary
Short summary
Dissolved organic carbon (DOC) is an important part of the global carbon cycle with regards to carbon storage, greenhouse gas emissions and drinking water treatment. In this study, we compared DOC export of a small, forested catchment during precipitation events after dry and wet preconditions. We found that the DOC export from areas that are usually important for DOC export was inhibited after long drought periods.
Edoardo Martini, Matteo Bauckholt, Simon Kögler, Manuel Kreck, Kurt Roth, Ulrike Werban, Ute Wollschläger, and Steffen Zacharias
Earth Syst. Sci. Data, 13, 2529–2539, https://doi.org/10.5194/essd-13-2529-2021, https://doi.org/10.5194/essd-13-2529-2021, 2021
Short summary
Short summary
We present the in situ data available from the soil monitoring network
STH-net, recently implemented at the Schäfertal Hillslope site (Germany). The STH-net provides data (soil water content, soil temperature, water level, and meteorological variables – measured at a 10 min interval since 1 January 2019) for developing and testing modelling approaches in the context of vadose zone hydrology at spatial scales ranging from the pedon to the hillslope.
Gerrit Huibert de Rooij, Juliane Mai, and Raneem Madi
Hydrol. Earth Syst. Sci., 25, 983–1007, https://doi.org/10.5194/hess-25-983-2021, https://doi.org/10.5194/hess-25-983-2021, 2021
Short summary
Short summary
The way soils capture infiltrating water affects crops and natural vegetation and groundwater recharge. This retention of soil water is described by a mathematical function that covers all water contents from very dry to water saturated. We combined two existing lines of research to improve the behaviour of a popular function for very dry and very wet conditions. Our new function could handle a wider range of conditions than earlier curves. We provide fits to a wide range of soils.
Ingo Heidbüchel, Jie Yang, Andreas Musolff, Peter Troch, Ty Ferré, and Jan H. Fleckenstein
Hydrol. Earth Syst. Sci., 24, 2895–2920, https://doi.org/10.5194/hess-24-2895-2020, https://doi.org/10.5194/hess-24-2895-2020, 2020
Short summary
Short summary
With the help of a 3-D computer model we examined how long the water of different rain events stays inside small catchments before it is discharged and how the nature of this discharge is controlled by different catchment and climate properties. We found that one can only predict the discharge dynamics when taking into account a combination of catchment and climate properties (i.e., there was not one single most important predictor). Our results can help to manage water pollution events.
Conrad Jackisch, Kai Germer, Thomas Graeff, Ines Andrä, Katrin Schulz, Marcus Schiedung, Jaqueline Haller-Jans, Jonas Schneider, Julia Jaquemotte, Philipp Helmer, Leander Lotz, Andreas Bauer, Irene Hahn, Martin Šanda, Monika Kumpan, Johann Dorner, Gerrit de Rooij, Stefan Wessel-Bothe, Lorenz Kottmann, Siegfried Schittenhelm, and Wolfgang Durner
Earth Syst. Sci. Data, 12, 683–697, https://doi.org/10.5194/essd-12-683-2020, https://doi.org/10.5194/essd-12-683-2020, 2020
Short summary
Short summary
Soil water content and matric potential are central hydrological state variables. A large variety of automated probes and sensor systems for field monitoring exist. In a field experiment under idealised conditions we compared 15 systems for soil moisture and 14 systems for matric potential. The individual records of one system agree well with the others. Most records are also plausible. However, the absolute values of the different measuring systems span a very large range of possible truths.
Adam S. Ward, Steven M. Wondzell, Noah M. Schmadel, Skuyler Herzog, Jay P. Zarnetske, Viktor Baranov, Phillip J. Blaen, Nicolai Brekenfeld, Rosalie Chu, Romain Derelle, Jennifer Drummond, Jan H. Fleckenstein, Vanessa Garayburu-Caruso, Emily Graham, David Hannah, Ciaran J. Harman, Jase Hixson, Julia L. A. Knapp, Stefan Krause, Marie J. Kurz, Jörg Lewandowski, Angang Li, Eugènia Martí, Melinda Miller, Alexander M. Milner, Kerry Neil, Luisa Orsini, Aaron I. Packman, Stephen Plont, Lupita Renteria, Kevin Roche, Todd Royer, Catalina Segura, James Stegen, Jason Toyoda, Jacqueline Hager, and Nathan I. Wisnoski
Hydrol. Earth Syst. Sci., 23, 5199–5225, https://doi.org/10.5194/hess-23-5199-2019, https://doi.org/10.5194/hess-23-5199-2019, 2019
Short summary
Short summary
The movement of water and solutes between streams and their shallow, connected subsurface is important to many ecosystem functions. These exchanges are widely expected to vary with stream flow across space and time, but these assumptions are seldom tested across basin scales. We completed more than 60 experiments across a 5th-order river basin to document these changes, finding patterns in space but not time. We conclude space-for-time and time-for-space substitutions are not good assumptions.
Benedikt J. Werner, Andreas Musolff, Oliver J. Lechtenfeld, Gerrit H. de Rooij, Marieke R. Oosterwoud, and Jan H. Fleckenstein
Biogeosciences, 16, 4497–4516, https://doi.org/10.5194/bg-16-4497-2019, https://doi.org/10.5194/bg-16-4497-2019, 2019
Short summary
Short summary
Increased dissolved organic carbon (DOC) concentration in streams can pose a threat to downstream water resources. Analyzing data from an in-stream probe we found that hydroclimatic and hydrological drivers can describe up to 72 % of the observed DOC concentration and composition variability. Variability was found to be highest during discharge events with warm and dry preconditions. The findings suggest an impact of climate change on DOC exports and thus also on downstream water quality.
Adam S. Ward, Jay P. Zarnetske, Viktor Baranov, Phillip J. Blaen, Nicolai Brekenfeld, Rosalie Chu, Romain Derelle, Jennifer Drummond, Jan H. Fleckenstein, Vanessa Garayburu-Caruso, Emily Graham, David Hannah, Ciaran J. Harman, Skuyler Herzog, Jase Hixson, Julia L. A. Knapp, Stefan Krause, Marie J. Kurz, Jörg Lewandowski, Angang Li, Eugènia Martí, Melinda Miller, Alexander M. Milner, Kerry Neil, Luisa Orsini, Aaron I. Packman, Stephen Plont, Lupita Renteria, Kevin Roche, Todd Royer, Noah M. Schmadel, Catalina Segura, James Stegen, Jason Toyoda, Jacqueline Hager, Nathan I. Wisnoski, and Steven M. Wondzell
Earth Syst. Sci. Data, 11, 1567–1581, https://doi.org/10.5194/essd-11-1567-2019, https://doi.org/10.5194/essd-11-1567-2019, 2019
Short summary
Short summary
Studies of river corridor exchange commonly focus on characterization of the physical, chemical, or biological system. As a result, complimentary systems and context are often lacking, which may limit interpretation. Here, we present a characterization of all three systems at 62 sites in a 5th-order river basin, including samples of surface water, hyporheic water, and sediment. These data will allow assessment of interacting processes in the river corridor.
Monja Ellinger, Ines Merbach, Ulrike Werban, and Mareike Ließ
SOIL, 5, 275–288, https://doi.org/10.5194/soil-5-275-2019, https://doi.org/10.5194/soil-5-275-2019, 2019
Short summary
Short summary
Vis–NIR spectrometry is often applied to capture soil organic carbon (SOC). This study addresses the impact of the involved data and modelling aspects on SOC precision with a focus on the propagation of input data uncertainties. It emphasizes the necessity of transparent documentation of the measurement protocol and the model building and validation procedure. Particularly, when Vis–NIR spectrometry is used for soil monitoring, the aspect of uncertainty propagation becomes essential.
Sophie Ehrhardt, Rohini Kumar, Jan H. Fleckenstein, Sabine Attinger, and Andreas Musolff
Hydrol. Earth Syst. Sci., 23, 3503–3524, https://doi.org/10.5194/hess-23-3503-2019, https://doi.org/10.5194/hess-23-3503-2019, 2019
Short summary
Short summary
This study shows quantitative and temporal offsets between nitrogen input and riverine output, using time series of three nested catchments in central Germany. The riverine concentrations show lagged reactions to the input, but at the same time exhibit strong inter-annual changes in the relationship between riverine discharge and concentration. The study found a strong retention of nitrogen that is dominantly assigned to a hydrological N legacy, which will affect future stream concentrations.
Gerrit Huibert de Rooij
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2018-97, https://doi.org/10.5194/gmd-2018-97, 2018
Publication in GMD not foreseen
Short summary
Short summary
Areas that have few or no weather stations or are subject to climate change still need weather data in order to model the demand for water, the risk of floods and droughts, etc. TEmpotRain generates rainfall, daily temperature extremes, and daily potential evaporation (from the soil) / transpiration (by plants). The physical meaning of the model parameters is clear. This allows realistic values for them to be estimated, even for hypothetical (future) climates for which data are not available.
Raneem Madi, Gerrit Huibert de Rooij, Henrike Mielenz, and Juliane Mai
Hydrol. Earth Syst. Sci., 22, 1193–1219, https://doi.org/10.5194/hess-22-1193-2018, https://doi.org/10.5194/hess-22-1193-2018, 2018
Short summary
Short summary
Water flows through soils with more difficulty when the soil is dried out. Scant rainfall in deserts may therefore result in a seemingly wet soil, but the water will often not penetrate deeply enough to replenish the groundwater. We compared the mathematical functions that describe how well different soils hold their water and found that only a few of them are realistic. The function one chooses to model the soil can have a large impact on the estimate of groundwater recharge.
Rémi Dupas, Andreas Musolff, James W. Jawitz, P. Suresh C. Rao, Christoph G. Jäger, Jan H. Fleckenstein, Michael Rode, and Dietrich Borchardt
Biogeosciences, 14, 4391–4407, https://doi.org/10.5194/bg-14-4391-2017, https://doi.org/10.5194/bg-14-4391-2017, 2017
Short summary
Short summary
Carbon and nutrient export regimes were analyzed from archetypal headwater catchments to
downstream reaches. In headwater catchments, land use and lithology determine
land-to-stream C, N and P transfer processes. The crucial role of riparian
zones in C, N and P coupling was investigated. In downstream reaches,
point-source contributions and in-stream processes alter C, N and P export
regimes.
Edoardo Martini, Ulrike Werban, Steffen Zacharias, Marco Pohle, Peter Dietrich, and Ute Wollschläger
Hydrol. Earth Syst. Sci., 21, 495–513, https://doi.org/10.5194/hess-21-495-2017, https://doi.org/10.5194/hess-21-495-2017, 2017
Short summary
Short summary
With a process-based interpretation of electromagnetic induction measurements, we discussed the potential and limitations of such a method for soil moisture mapping. Results will help clarify the complex and time-varying effect of stable soil properties and dynamic state variables on the physical parameters measured, with implications for future studies. We highlighted the importance of time-series data and the need for a multidisciplinary approach for proper interpretation.
W. He, C. Beyer, J. H. Fleckenstein, E. Jang, O. Kolditz, D. Naumov, and T. Kalbacher
Geosci. Model Dev., 8, 3333–3348, https://doi.org/10.5194/gmd-8-3333-2015, https://doi.org/10.5194/gmd-8-3333-2015, 2015
Short summary
Short summary
This technical paper presents a new tool to simulate reactive transport processes in subsurface systems and which couples the open-source software packages OpenGeoSys and IPhreeqc. A flexible parallelization scheme was developed and implemented to enable an optimized allocation of computer resources. The performance tests of the coupling interface and parallelization scheme illustrate the promising efficiency of this generally valid approach to simulate reactive transport problems.
L. Jørgensen, O. J. Lechtenfeld, R. Benner, M. Middelboe, and C. A. Stedmon
Biogeosciences, 11, 5349–5363, https://doi.org/10.5194/bg-11-5349-2014, https://doi.org/10.5194/bg-11-5349-2014, 2014
E. Bloem, M. de Gee, and G. H. de Rooij
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hessd-11-6993-2014, https://doi.org/10.5194/hessd-11-6993-2014, 2014
Manuscript not accepted for further review
G. H. de Rooij
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hessd-11-83-2014, https://doi.org/10.5194/hessd-11-83-2014, 2014
Revised manuscript has not been submitted
B. J. Kopp, J. H. Fleckenstein, N. T. Roulet, E. Humphreys, J. Talbot, and C. Blodau
Hydrol. Earth Syst. Sci., 17, 3485–3498, https://doi.org/10.5194/hess-17-3485-2013, https://doi.org/10.5194/hess-17-3485-2013, 2013
B. te Brake, M. J. van der Ploeg, and G. H. de Rooij
Hydrol. Earth Syst. Sci., 17, 1933–1949, https://doi.org/10.5194/hess-17-1933-2013, https://doi.org/10.5194/hess-17-1933-2013, 2013
S. Strohmeier, K.-H. Knorr, M. Reichert, S. Frei, J. H. Fleckenstein, S. Peiffer, and E. Matzner
Biogeosciences, 10, 905–916, https://doi.org/10.5194/bg-10-905-2013, https://doi.org/10.5194/bg-10-905-2013, 2013
Related subject area
Subject: Catchment hydrology | Techniques and Approaches: Modelling approaches
On the use of streamflow transformations for hydrological model calibration
Simulation-based inference for parameter estimation of complex watershed simulators
Multi-scale soil moisture data and process-based modeling reveal the importance of lateral groundwater flow in a subarctic catchment
Catchment response to climatic variability: implications for root zone storage and streamflow predictions
Hybrid hydrological modeling for large alpine basins: a semi-distributed approach
Karst aquifer discharge response to rainfall interpreted as anomalous transport
HESS Opinions: Never train a Long Short-Term Memory (LSTM) network on a single basin
Large-sample hydrology – a few camels or a whole caravan?
Comment on “Are soils overrated in hydrology?” by Gao et al. (2023)
Multi-decadal fluctuations in root zone storage capacity through vegetation adaptation to hydro-climatic variability have minor effects on the hydrological response in the Neckar River basin, Germany
Projected future changes in the cryosphere and hydrology of a mountainous catchment in the upper Heihe River, China
On the importance of plant phenology in the evaporative process of a semi-arid woodland: could it be why satellite-based evaporation estimates in the miombo differ?
Regionalization of GR4J model parameters for river flow prediction in Paraná, Brazil
Evolution of river regimes in the Mekong River basin over 8 decades and the role of dams in recent hydrological extremes
Skill of seasonal flow forecasts at catchment scale: an assessment across South Korea
To what extent do flood-inducing storm events change future flood hazards?
When ancient numerical demons meet physics-informed machine learning: adjoint-based gradients for implicit differentiable modeling
Assessing the impact of climate change on high return levels of peak flows in Bavaria applying the CRCM5 large ensemble
Impacts of climate and land surface change on catchment evapotranspiration and runoff from 1951 to 2020 in Saxony, Germany
Quantifying and reducing flood forecast uncertainty by the CHUP-BMA method
Developing a tile drainage module for the Cold Regions Hydrological Model: lessons from a farm in southern Ontario, Canada
To bucket or not to bucket? Analyzing the performance and interpretability of hybrid hydrological models with dynamic parameterization
Widespread flooding dynamics under climate change: characterising floods using grid-based hydrological modelling and regional climate projections
HESS Opinions: The sword of Damocles of the impossible flood
Metamorphic testing of machine learning and conceptual hydrologic models
The influence of human activities on streamflow reductions during the megadrought in central Chile
Elevational control of isotopic composition and application in understanding hydrologic processes in the mid Merced River catchment, Sierra Nevada, California, USA
Lack of robustness of hydrological models: A large-sample diagnosis and an attempt to identify the hydrological and climatic drivers
The Significance of the Leaf-Area-Index on the Evapotranspiration Estimation in SWAT-T for Characteristic Land Cover Types of Western Africa
Enhancing long short-term memory (LSTM)-based streamflow prediction with a spatially distributed approach
Broadleaf afforestation impacts on terrestrial hydrology insignificant compared to climate change in Great Britain
Impacts of spatiotemporal resolutions of precipitation on flood event simulation based on multimodel structures – a case study over the Xiang River basin in China
A network approach for multiscale catchment classification using traits
Multi-model approach in a variable spatial framework for streamflow simulation
Advancing understanding of lake–watershed hydrology: a fully coupled numerical model illustrated by Qinghai Lake
Technical note: Testing the connection between hillslope-scale runoff fluctuations and streamflow hydrographs at the outlet of large river basins
Empirical stream thermal sensitivity cluster on the landscape according to geology and climate
Deep learning for monthly rainfall–runoff modelling: a large-sample comparison with conceptual models across Australia
A large-sample modelling approach towards integrating streamflow and evaporation data for the Spanish catchments
On optimization of calibrations of a distributed hydrological model with spatially distributed information on snow
Toward interpretable LSTM-based modeling of hydrological systems
Flow intermittence prediction using a hybrid hydrological modelling approach: influence of observed intermittence data on the training of a random forest model
What controls the tail behaviour of flood series: rainfall or runoff generation?
Learning Landscape Features from Streamflow with Autoencoders
Seasonal prediction of end-of-dry-season watershed behavior in a highly interconnected alluvial watershed in northern California
Glaciers determine the sensitivity of hydrological processes to perturbed climate in a large mountainous basin on the Tibetan Plateau
Leveraging gauge networks and strategic discharge measurements to aid the development of continuous streamflow records
On the need for physical constraints in deep learning rainfall–runoff projections under climate change: a sensitivity analysis to warming and shifts in potential evapotranspiration
Evaluation of hydrological models on small mountainous catchments: impact of the meteorological forcings
Projecting sediment export from two highly glacierized alpine catchments under climate change: exploring non-parametric regression as an analysis tool
Guillaume Thirel, Léonard Santos, Olivier Delaigue, and Charles Perrin
Hydrol. Earth Syst. Sci., 28, 4837–4860, https://doi.org/10.5194/hess-28-4837-2024, https://doi.org/10.5194/hess-28-4837-2024, 2024
Short summary
Short summary
We discuss how mathematical transformations impact calibrated hydrological model simulations. We assess how 11 transformations behave over the complete range of streamflows. Extreme transformations lead to models that are specialized for extreme streamflows but show poor performance outside the range of targeted streamflows and are less robust. We show that no a priori assumption about transformations can be taken as warranted.
Robert Hull, Elena Leonarduzzi, Luis De La Fuente, Hoang Viet Tran, Andrew Bennett, Peter Melchior, Reed M. Maxwell, and Laura E. Condon
Hydrol. Earth Syst. Sci., 28, 4685–4713, https://doi.org/10.5194/hess-28-4685-2024, https://doi.org/10.5194/hess-28-4685-2024, 2024
Short summary
Short summary
Large-scale hydrologic simulators are a needed tool to explore complex watershed processes and how they may evolve with a changing climate. However, calibrating them can be difficult because they are costly to run and have many unknown parameters. We implement a state-of-the-art approach to model calibration using neural networks with a set of experiments based on streamflow in the upper Colorado River basin.
Jari-Pekka Nousu, Kersti Leppä, Hannu Marttila, Pertti Ala-aho, Giulia Mazzotti, Terhikki Manninen, Mika Korkiakoski, Mika Aurela, Annalea Lohila, and Samuli Launiainen
Hydrol. Earth Syst. Sci., 28, 4643–4666, https://doi.org/10.5194/hess-28-4643-2024, https://doi.org/10.5194/hess-28-4643-2024, 2024
Short summary
Short summary
We used hydrological models, field measurements, and satellite-based data to study the soil moisture dynamics in a subarctic catchment. The role of groundwater was studied with different ways to model the groundwater dynamics and via comparisons to the observational data. The choice of groundwater model was shown to have a strong impact, and representation of lateral flow was important to capture wet soil conditions. Our results provide insights for ecohydrological studies in boreal regions.
Nienke Tempel, Laurène Bouaziz, Riccardo Taormina, Ellis van Noppen, Jasper Stam, Eric Sprokkereef, and Markus Hrachowitz
Hydrol. Earth Syst. Sci., 28, 4577–4597, https://doi.org/10.5194/hess-28-4577-2024, https://doi.org/10.5194/hess-28-4577-2024, 2024
Short summary
Short summary
This study explores the impact of climatic variability on root zone water storage capacities and, thus, on hydrological predictions. Analysing data from 286 areas in Europe and the US, we found that, despite some variations in root zone storage capacity due to changing climatic conditions over multiple decades, these changes are generally minor and have a limited effect on water storage and river flow predictions.
Bu Li, Ting Sun, Fuqiang Tian, Mahmut Tudaji, Li Qin, and Guangheng Ni
Hydrol. Earth Syst. Sci., 28, 4521–4538, https://doi.org/10.5194/hess-28-4521-2024, https://doi.org/10.5194/hess-28-4521-2024, 2024
Short summary
Short summary
This paper developed hybrid semi-distributed hydrological models by employing a process-based model as the backbone and utilizing deep learning to parameterize and replace internal modules. The main contribution is to provide a high-performance tool enriched with explicit hydrological knowledge for hydrological prediction and to improve understanding about the hydrological sensitivities to climate change in large alpine basins.
Dan Elhanati, Nadine Goeppert, and Brian Berkowitz
Hydrol. Earth Syst. Sci., 28, 4239–4249, https://doi.org/10.5194/hess-28-4239-2024, https://doi.org/10.5194/hess-28-4239-2024, 2024
Short summary
Short summary
A continuous time random walk framework was developed to allow modeling of a karst aquifer discharge response to measured rainfall. The application of the numerical model yielded robust fits between modeled and measured discharge values, especially for the distinctive long tails found during recession times. The findings shed light on the interplay of slow and fast flow in the karst system and establish the application of the model for simulating flow and transport in such systems.
Frederik Kratzert, Martin Gauch, Daniel Klotz, and Grey Nearing
Hydrol. Earth Syst. Sci., 28, 4187–4201, https://doi.org/10.5194/hess-28-4187-2024, https://doi.org/10.5194/hess-28-4187-2024, 2024
Short summary
Short summary
Recently, a special type of neural-network architecture became increasingly popular in hydrology literature. However, in most applications, this model was applied as a one-to-one replacement for hydrology models without adapting or rethinking the experimental setup. In this opinion paper, we show how this is almost always a bad decision and how using these kinds of models requires the use of large-sample hydrology data sets.
Franziska Clerc-Schwarzenbach, Giovanni Selleri, Mattia Neri, Elena Toth, Ilja van Meerveld, and Jan Seibert
Hydrol. Earth Syst. Sci., 28, 4219–4237, https://doi.org/10.5194/hess-28-4219-2024, https://doi.org/10.5194/hess-28-4219-2024, 2024
Short summary
Short summary
We show that the differences between the forcing data included in three CAMELS datasets (US, BR, GB) and the forcing data included for the same catchments in the Caravan dataset affect model calibration considerably. The model performance dropped when the data from the Caravan dataset were used instead of the original data. Most of the model performance drop could be attributed to the differences in precipitation data. However, differences were largest for the potential evapotranspiration data.
Ying Zhao, Mehdi Rahmati, Harry Vereecken, and Dani Or
Hydrol. Earth Syst. Sci., 28, 4059–4063, https://doi.org/10.5194/hess-28-4059-2024, https://doi.org/10.5194/hess-28-4059-2024, 2024
Short summary
Short summary
Gao et al. (2023) question the importance of soil in hydrology, sparking debate. We acknowledge some valid points but critique their broad, unsubstantiated views on soil's role. Our response highlights three key areas: (1) the false divide between ecosystem-centric and soil-centric approaches, (2) the vital yet varied impact of soil properties, and (3) the call for a scale-aware framework. We aim to unify these perspectives, enhancing hydrology's comprehensive understanding.
Siyuan Wang, Markus Hrachowitz, and Gerrit Schoups
Hydrol. Earth Syst. Sci., 28, 4011–4033, https://doi.org/10.5194/hess-28-4011-2024, https://doi.org/10.5194/hess-28-4011-2024, 2024
Short summary
Short summary
Root zone storage capacity (Sumax) changes significantly over multiple decades, reflecting vegetation adaptation to climatic variability. However, this temporal evolution of Sumax cannot explain long-term fluctuations in the partitioning of water fluxes as expressed by deviations ΔIE from the parametric Budyko curve over time with different climatic conditions, and it does not have any significant effects on shorter-term hydrological response characteristics of the upper Neckar catchment.
Zehua Chang, Hongkai Gao, Leilei Yong, Kang Wang, Rensheng Chen, Chuntan Han, Otgonbayar Demberel, Batsuren Dorjsuren, Shugui Hou, and Zheng Duan
Hydrol. Earth Syst. Sci., 28, 3897–3917, https://doi.org/10.5194/hess-28-3897-2024, https://doi.org/10.5194/hess-28-3897-2024, 2024
Short summary
Short summary
An integrated cryospheric–hydrologic model, FLEX-Cryo, was developed that considers glaciers, snow cover, and frozen soil and their dynamic impacts on hydrology. We utilized it to simulate future changes in cryosphere and hydrology in the Hulu catchment. Our projections showed the two glaciers will melt completely around 2050, snow cover will reduce, and permafrost will degrade. For hydrology, runoff will decrease after the glacier has melted, and permafrost degradation will increase baseflow.
Henry M. Zimba, Miriam Coenders-Gerrits, Kawawa E. Banda, Petra Hulsman, Nick van de Giesen, Imasiku A. Nyambe, and Hubert H. G. Savenije
Hydrol. Earth Syst. Sci., 28, 3633–3663, https://doi.org/10.5194/hess-28-3633-2024, https://doi.org/10.5194/hess-28-3633-2024, 2024
Short summary
Short summary
The fall and flushing of new leaves in the miombo woodlands co-occur in the dry season before the commencement of seasonal rainfall. The miombo species are also said to have access to soil moisture in deep soils, including groundwater in the dry season. Satellite-based evaporation estimates, temporal trends, and magnitudes differ the most in the dry season, most likely due to inadequate understanding and representation of the highlighted miombo species attributes in simulations.
Louise Akemi Kuana, Arlan Scortegagna Almeida, Emílio Graciliano Ferreira Mercuri, and Steffen Manfred Noe
Hydrol. Earth Syst. Sci., 28, 3367–3390, https://doi.org/10.5194/hess-28-3367-2024, https://doi.org/10.5194/hess-28-3367-2024, 2024
Short summary
Short summary
The authors compared regionalization methods for river flow prediction in 126 catchments from the south of Brazil, a region with humid subtropical and hot temperate climate. The regionalization method based on physiographic–climatic similarity had the best performance for predicting daily and Q95 reference flow. We showed that basins without flow monitoring can have a good approximation of streamflow using machine learning and physiographic–climatic information as inputs.
Huy Dang and Yadu Pokhrel
Hydrol. Earth Syst. Sci., 28, 3347–3365, https://doi.org/10.5194/hess-28-3347-2024, https://doi.org/10.5194/hess-28-3347-2024, 2024
Short summary
Short summary
By examining basin-wide simulations of a river regime over 83 years with and without dams, we present evidence that climate variation was a key driver of hydrologic variabilities in the Mekong River basin (MRB) over the long term; however, dams have largely altered the seasonality of the Mekong’s flow regime and annual flooding patterns in major downstream areas in recent years. These findings could help us rethink the planning of future dams and water resource management in the MRB.
Yongshin Lee, Francesca Pianosi, Andres Peñuela, and Miguel Angel Rico-Ramirez
Hydrol. Earth Syst. Sci., 28, 3261–3279, https://doi.org/10.5194/hess-28-3261-2024, https://doi.org/10.5194/hess-28-3261-2024, 2024
Short summary
Short summary
Following recent advancements in weather prediction technology, we explored how seasonal weather forecasts (1 or more months ahead) could benefit practical water management in South Korea. Our findings highlight that using seasonal weather forecasts for predicting flow patterns 1 to 3 months ahead is effective, especially during dry years. This suggest that seasonal weather forecasts can be helpful in improving the management of water resources.
Mariam Khanam, Giulia Sofia, and Emmanouil N. Anagnostou
Hydrol. Earth Syst. Sci., 28, 3161–3190, https://doi.org/10.5194/hess-28-3161-2024, https://doi.org/10.5194/hess-28-3161-2024, 2024
Short summary
Short summary
Flooding worsens due to climate change, with river dynamics being a key in local flood control. Predicting post-storm geomorphic changes is challenging. Using self-organizing maps and machine learning, this study forecasts post-storm alterations in stage–discharge relationships across 3101 US stream gages. The provided framework can aid in updating hazard assessments by identifying rivers prone to change, integrating channel adjustments into flood hazard assessment.
Yalan Song, Wouter J. M. Knoben, Martyn P. Clark, Dapeng Feng, Kathryn Lawson, Kamlesh Sawadekar, and Chaopeng Shen
Hydrol. Earth Syst. Sci., 28, 3051–3077, https://doi.org/10.5194/hess-28-3051-2024, https://doi.org/10.5194/hess-28-3051-2024, 2024
Short summary
Short summary
Differentiable models (DMs) integrate neural networks and physical equations for accuracy, interpretability, and knowledge discovery. We developed an adjoint-based DM for ordinary differential equations (ODEs) for hydrological modeling, reducing distorted fluxes and physical parameters from errors in models that use explicit and operation-splitting schemes. With a better numerical scheme and improved structure, the adjoint-based DM matches or surpasses long short-term memory (LSTM) performance.
Florian Willkofer, Raul R. Wood, and Ralf Ludwig
Hydrol. Earth Syst. Sci., 28, 2969–2989, https://doi.org/10.5194/hess-28-2969-2024, https://doi.org/10.5194/hess-28-2969-2024, 2024
Short summary
Short summary
Severe flood events pose a threat to riverine areas, yet robust estimates of the dynamics of these events in the future due to climate change are rarely available. Hence, this study uses data from a regional climate model, SMILE, to drive a high-resolution hydrological model for 98 catchments of hydrological Bavaria and exploits the large database to derive robust values for the 100-year flood events. Results indicate an increase in frequency and intensity for most catchments in the future.
Maik Renner and Corina Hauffe
Hydrol. Earth Syst. Sci., 28, 2849–2869, https://doi.org/10.5194/hess-28-2849-2024, https://doi.org/10.5194/hess-28-2849-2024, 2024
Short summary
Short summary
Climate and land surface changes influence the partitioning of water balance components decisively. Their impact is quantified for 71 catchments in Saxony. Germany. Distinct signatures in the joint water and energy budgets are found: (i) past forest dieback caused a decrease in and subsequent recovery of evapotranspiration in the affected regions, and (ii) the recent shift towards higher aridity imposed a large decline in runoff that has not been seen in the observation records before.
Zhen Cui, Shenglian Guo, Hua Chen, Dedi Liu, Yanlai Zhou, and Chong-Yu Xu
Hydrol. Earth Syst. Sci., 28, 2809–2829, https://doi.org/10.5194/hess-28-2809-2024, https://doi.org/10.5194/hess-28-2809-2024, 2024
Short summary
Short summary
Ensemble forecasting facilitates reliable flood forecasting and warning. This study couples the copula-based hydrologic uncertainty processor (CHUP) with Bayesian model averaging (BMA) and proposes the novel CHUP-BMA method of reducing inflow forecasting uncertainty of the Three Gorges Reservoir. The CHUP-BMA avoids the normal distribution assumption in the HUP-BMA and considers the constraint of initial conditions, which can improve the deterministic and probabilistic forecast performance.
Mazda Kompanizare, Diogo Costa, Merrin L. Macrae, John W. Pomeroy, and Richard M. Petrone
Hydrol. Earth Syst. Sci., 28, 2785–2807, https://doi.org/10.5194/hess-28-2785-2024, https://doi.org/10.5194/hess-28-2785-2024, 2024
Short summary
Short summary
A new agricultural tile drainage module was developed in the Cold Region Hydrological Model platform. Tile flow and water levels are simulated by considering the effect of capillary fringe thickness, drainable water and seasonal regional groundwater dynamics. The model was applied to a small well-instrumented farm in southern Ontario, Canada, where there are concerns about the impacts of agricultural drainage into Lake Erie.
Eduardo Acuña Espinoza, Ralf Loritz, Manuel Álvarez Chaves, Nicole Bäuerle, and Uwe Ehret
Hydrol. Earth Syst. Sci., 28, 2705–2719, https://doi.org/10.5194/hess-28-2705-2024, https://doi.org/10.5194/hess-28-2705-2024, 2024
Short summary
Short summary
Hydrological hybrid models promise to merge the performance of deep learning methods with the interpretability of process-based models. One hybrid approach is the dynamic parameterization of conceptual models using long short-term memory (LSTM) networks. We explored this method to evaluate the effect of the flexibility given by LSTMs on the process-based part.
Adam Griffin, Alison L. Kay, Paul Sayers, Victoria Bell, Elizabeth Stewart, and Sam Carr
Hydrol. Earth Syst. Sci., 28, 2635–2650, https://doi.org/10.5194/hess-28-2635-2024, https://doi.org/10.5194/hess-28-2635-2024, 2024
Short summary
Short summary
Widespread flooding is a major problem in the UK and is greatly affected by climate change and land-use change. To look at how widespread flooding changes in the future, climate model data (UKCP18) were used with a hydrological model (Grid-to-Grid) across the UK, and 14 400 events were identified between two time slices: 1980–2010 and 2050–2080. There was a strong increase in the number of winter events in the future time slice and in the peak return periods.
Alberto Montanari, Bruno Merz, and Günter Blöschl
Hydrol. Earth Syst. Sci., 28, 2603–2615, https://doi.org/10.5194/hess-28-2603-2024, https://doi.org/10.5194/hess-28-2603-2024, 2024
Short summary
Short summary
Floods often take communities by surprise, as they are often considered virtually
impossibleyet are an ever-present threat similar to the sword suspended over the head of Damocles in the classical Greek anecdote. We discuss four reasons why extremely large floods carry a risk that is often larger than expected. We provide suggestions for managing the risk of megafloods by calling for a creative exploration of hazard scenarios and communicating the unknown corners of the reality of floods.
Peter Reichert, Kai Ma, Marvin Höge, Fabrizio Fenicia, Marco Baity-Jesi, Dapeng Feng, and Chaopeng Shen
Hydrol. Earth Syst. Sci., 28, 2505–2529, https://doi.org/10.5194/hess-28-2505-2024, https://doi.org/10.5194/hess-28-2505-2024, 2024
Short summary
Short summary
We compared the predicted change in catchment outlet discharge to precipitation and temperature change for conceptual and machine learning hydrological models. We found that machine learning models, despite providing excellent fit and prediction capabilities, can be unreliable regarding the prediction of the effect of temperature change for low-elevation catchments. This indicates the need for caution when applying them for the prediction of the effect of climate change.
Nicolás Álamos, Camila Alvarez-Garreton, Ariel Muñoz, and Álvaro González-Reyes
Hydrol. Earth Syst. Sci., 28, 2483–2503, https://doi.org/10.5194/hess-28-2483-2024, https://doi.org/10.5194/hess-28-2483-2024, 2024
Short summary
Short summary
In this study, we assess the effects of climate and water use on streamflow reductions and drought intensification during the last 3 decades in central Chile. We address this by contrasting streamflow observations with near-natural streamflow simulations. We conclude that while the lack of precipitation dominates streamflow reductions in the megadrought, water uses have not diminished during this time, causing a worsening of the hydrological drought conditions and maladaptation conditions.
Fengjing Liu, Martha H. Conklin, and Glenn D. Shaw
Hydrol. Earth Syst. Sci., 28, 2239–2258, https://doi.org/10.5194/hess-28-2239-2024, https://doi.org/10.5194/hess-28-2239-2024, 2024
Short summary
Short summary
Mountain snowpack has been declining and more precipitation falls as rain than snow. Using stable isotopes, we found flows and flow duration in Yosemite Creek are most sensitive to climate warming due to strong evaporation of waterfalls, potentially lengthening the dry-up period of waterfalls in summer and negatively affecting tourism. Groundwater recharge in Yosemite Valley is primarily from the upper snow–rain transition (2000–2500 m) and very vulnerable to a reduction in the snow–rain ratio.
Léonard Santos, Vazken Andréassian, Torben O. Sonnenborg, Göran Lindström, Alban de Lavenne, Charles Perrin, Lila Collet, and Guillaume Thirel
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2024-80, https://doi.org/10.5194/hess-2024-80, 2024
Revised manuscript accepted for HESS
Short summary
Short summary
This work aims at investigating how hydrological models can be transferred to a period in which climatic conditions are different to the ones of the period in which it was set up. The RAT method, built to detect dependencies between model error and climatic drivers, was applied to 3 different hydrological models on 352 catchments in Denmark, France and Sweden. Potential issues are detected for a significant number of catchments for the 3 models even though these catchments differ for each model.
Fabian Merk, Timo Schaffhauser, Faizan Anwar, Ye Tuo, Jean-Martial Cohard, and Markus Disse
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2024-131, https://doi.org/10.5194/hess-2024-131, 2024
Revised manuscript accepted for HESS
Short summary
Short summary
ET is computed from vegetation (plant transpiration) and soil (soil evaporation). In Western Africa, plant transpiration correlates with vegetation growth. Vegetation is often represented with the leaf-area-index (LAI). In this study, we evaluate the importance of LAI for the ET calculation. We take a close look at the LAI-ET interaction and show the relevance to consider both, LAI and ET. Our work contributes to the understanding of the processes of the terrestrial water cycle.
Qiutong Yu, Bryan A. Tolson, Hongren Shen, Ming Han, Juliane Mai, and Jimmy Lin
Hydrol. Earth Syst. Sci., 28, 2107–2122, https://doi.org/10.5194/hess-28-2107-2024, https://doi.org/10.5194/hess-28-2107-2024, 2024
Short summary
Short summary
It is challenging to incorporate input variables' spatial distribution information when implementing long short-term memory (LSTM) models for streamflow prediction. This work presents a novel hybrid modelling approach to predict streamflow while accounting for spatial variability. We evaluated the performance against lumped LSTM predictions in 224 basins across the Great Lakes region in North America. This approach shows promise for predicting streamflow in large, ungauged basin.
Marcus Buechel, Louise Slater, and Simon Dadson
Hydrol. Earth Syst. Sci., 28, 2081–2105, https://doi.org/10.5194/hess-28-2081-2024, https://doi.org/10.5194/hess-28-2081-2024, 2024
Short summary
Short summary
Afforestation has been proposed internationally, but the hydrological implications of such large increases in the spatial extent of woodland are not fully understood. In this study, we use a land surface model to simulate hydrology across Great Britain with realistic afforestation scenarios and potential climate changes. Countrywide afforestation minimally influences hydrology, when compared to climate change, and reduces low streamflow whilst not lowering the highest flows.
Qian Zhu, Xiaodong Qin, Dongyang Zhou, Tiantian Yang, and Xinyi Song
Hydrol. Earth Syst. Sci., 28, 1665–1686, https://doi.org/10.5194/hess-28-1665-2024, https://doi.org/10.5194/hess-28-1665-2024, 2024
Short summary
Short summary
Input data, model and calibration strategy can affect the accuracy of flood event simulation and prediction. Satellite-based precipitation with different spatiotemporal resolutions is an important input source. Data-driven models are sometimes proven to be more accurate than hydrological models. Event-based calibration and conventional strategy are two options adopted for flood simulation. This study targets the three concerns for accurate flood event simulation and prediction.
Fabio Ciulla and Charuleka Varadharajan
Hydrol. Earth Syst. Sci., 28, 1617–1651, https://doi.org/10.5194/hess-28-1617-2024, https://doi.org/10.5194/hess-28-1617-2024, 2024
Short summary
Short summary
We present a new method based on network science for unsupervised classification of large datasets and apply it to classify 9067 US catchments and 274 biophysical traits at multiple scales. We find that our trait-based approach produces catchment classes with distinct streamflow behavior and that spatial patterns emerge amongst pristine and human-impacted catchments. This method can be widely used beyond hydrology to identify patterns, reduce trait redundancy, and select representative sites.
Cyril Thébault, Charles Perrin, Vazken Andréassian, Guillaume Thirel, Sébastien Legrand, and Olivier Delaigue
Hydrol. Earth Syst. Sci., 28, 1539–1566, https://doi.org/10.5194/hess-28-1539-2024, https://doi.org/10.5194/hess-28-1539-2024, 2024
Short summary
Short summary
Streamflow forecasting is useful for many applications, ranging from population safety (e.g. floods) to water resource management (e.g. agriculture or hydropower). To this end, hydrological models must be optimized. However, a model is inherently wrong. This study aims to analyse the contribution of a multi-model approach within a variable spatial framework to improve streamflow simulations. The underlying idea is to take advantage of the strength of each modelling framework tested.
Lele Shu, Xiaodong Li, Yan Chang, Xianhong Meng, Hao Chen, Yuan Qi, Hongwei Wang, Zhaoguo Li, and Shihua Lyu
Hydrol. Earth Syst. Sci., 28, 1477–1491, https://doi.org/10.5194/hess-28-1477-2024, https://doi.org/10.5194/hess-28-1477-2024, 2024
Short summary
Short summary
We developed a new model to better understand how water moves in a lake basin. Our model improves upon previous methods by accurately capturing the complexity of water movement, both on the surface and subsurface. Our model, tested using data from China's Qinghai Lake, accurately replicates complex water movements and identifies contributing factors of the lake's water balance. The findings provide a robust tool for predicting hydrological processes, aiding water resource planning.
Ricardo Mantilla, Morgan Fonley, and Nicolás Velásquez
Hydrol. Earth Syst. Sci., 28, 1373–1382, https://doi.org/10.5194/hess-28-1373-2024, https://doi.org/10.5194/hess-28-1373-2024, 2024
Short summary
Short summary
Hydrologists strive to “Be right for the right reasons” when modeling the hydrologic cycle; however, the datasets available to validate hydrological models are sparse, and in many cases, they comprise streamflow observations at the outlets of large catchments. In this work, we show that matching streamflow observations at the outlet of a large basin is not a reliable indicator of a correct description of the small-scale runoff processes.
Lillian M. McGill, E. Ashley Steel, and Aimee H. Fullerton
Hydrol. Earth Syst. Sci., 28, 1351–1371, https://doi.org/10.5194/hess-28-1351-2024, https://doi.org/10.5194/hess-28-1351-2024, 2024
Short summary
Short summary
This study examines the relationship between air and river temperatures in Washington's Snoqualmie and Wenatchee basins. We used classification and regression approaches to show that the sensitivity of river temperature to air temperature is variable across basins and controlled largely by geology and snowmelt. Findings can be used to inform strategies for river basin restoration and conservation, such as identifying climate-insensitive areas of the basin that should be preserved and protected.
Stephanie R. Clark, Julien Lerat, Jean-Michel Perraud, and Peter Fitch
Hydrol. Earth Syst. Sci., 28, 1191–1213, https://doi.org/10.5194/hess-28-1191-2024, https://doi.org/10.5194/hess-28-1191-2024, 2024
Short summary
Short summary
To determine if deep learning models are in general a viable alternative to traditional hydrologic modelling techniques in Australian catchments, a comparison of river–runoff predictions is made between traditional conceptual models and deep learning models in almost 500 catchments spread over the continent. It is found that the deep learning models match or outperform the traditional models in over two-thirds of the river catchments, indicating feasibility in a wide variety of conditions.
Patricio Yeste, Matilde García-Valdecasas Ojeda, Sonia R. Gámiz-Fortis, Yolanda Castro-Díez, Axel Bronstert, and María Jesús Esteban-Parra
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2024-57, https://doi.org/10.5194/hess-2024-57, 2024
Revised manuscript accepted for HESS
Short summary
Short summary
Integrating streamflow and evaporation data can help improve the physical realism of hydrologic models. In this work we investigate the capabilities of the Variable Infiltration Capacity (VIC) to reproduce both hydrologic variables for 189 headwater located in Spain. Results from sensitivity analysis indicate that adding two vegetation is enough to improve the representation of evaporation, and the performance of VIC exceeded that of the largest modelling effort currently available in Spain.
Dipti Tiwari, Mélanie Trudel, and Robert Leconte
Hydrol. Earth Syst. Sci., 28, 1127–1146, https://doi.org/10.5194/hess-28-1127-2024, https://doi.org/10.5194/hess-28-1127-2024, 2024
Short summary
Short summary
Calibrating hydrological models with multi-objective functions enhances model robustness. By using spatially distributed snow information in the calibration, the model performance can be enhanced without compromising the outputs. In this study the HYDROTEL model was calibrated in seven different experiments, incorporating the SPAEF (spatial efficiency) metric alongside Nash–Sutcliffe efficiency (NSE) and root-mean-square error (RMSE), with the aim of identifying the optimal calibration strategy.
Luis Andres De la Fuente, Mohammad Reza Ehsani, Hoshin Vijai Gupta, and Laura Elizabeth Condon
Hydrol. Earth Syst. Sci., 28, 945–971, https://doi.org/10.5194/hess-28-945-2024, https://doi.org/10.5194/hess-28-945-2024, 2024
Short summary
Short summary
Long short-term memory (LSTM) is a widely used machine-learning model in hydrology, but it is difficult to extract knowledge from it. We propose HydroLSTM, which represents processes like a hydrological reservoir. Models based on HydroLSTM perform similarly to LSTM while requiring fewer cell states. The learned parameters are informative about the dominant hydrology of a catchment. Our results show how parsimony and hydrological knowledge extraction can be achieved by using the new structure.
Louise Mimeau, Annika Künne, Flora Branger, Sven Kralisch, Alexandre Devers, and Jean-Philippe Vidal
Hydrol. Earth Syst. Sci., 28, 851–871, https://doi.org/10.5194/hess-28-851-2024, https://doi.org/10.5194/hess-28-851-2024, 2024
Short summary
Short summary
Modelling flow intermittence is essential for predicting the future evolution of drying in river networks and better understanding the ecological and socio-economic impacts. However, modelling flow intermittence is challenging, and observed data on temporary rivers are scarce. This study presents a new modelling approach for predicting flow intermittence in river networks and shows that combining different sources of observed data reduces the model uncertainty.
Elena Macdonald, Bruno Merz, Björn Guse, Viet Dung Nguyen, Xiaoxiang Guan, and Sergiy Vorogushyn
Hydrol. Earth Syst. Sci., 28, 833–850, https://doi.org/10.5194/hess-28-833-2024, https://doi.org/10.5194/hess-28-833-2024, 2024
Short summary
Short summary
In some rivers, the occurrence of extreme flood events is more likely than in other rivers – they have heavy-tailed distributions. We find that threshold processes in the runoff generation lead to such a relatively high occurrence probability of extremes. Further, we find that beyond a certain return period, i.e. for rare events, rainfall is often the dominant control compared to runoff generation. Our results can help to improve the estimation of the occurrence probability of extreme floods.
Alberto Bassi, Marvin Höge, Antonietta Mira, Fabrizio Fenicia, and Carlo Albert
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2024-47, https://doi.org/10.5194/hess-2024-47, 2024
Revised manuscript accepted for HESS
Short summary
Short summary
The goal is to remove the impact of meteorological drivers in order to uncover the unique landscape fingerprints of a catchment from streamflow data. Our results reveal an optimal two-feature summary for most catchments, with a third feature needed for challenging cases, associated with aridity and intermittent flow. Baseflow index, aridity, and soil/vegetation attributes strongly correlate with learned features, indicating their importance for streamflow prediction.
Claire Kouba and Thomas Harter
Hydrol. Earth Syst. Sci., 28, 691–718, https://doi.org/10.5194/hess-28-691-2024, https://doi.org/10.5194/hess-28-691-2024, 2024
Short summary
Short summary
In some watersheds, the severity of the dry season has a large impact on aquatic ecosystems. In this study, we design a way to predict, 5–6 months in advance, how severe the dry season will be in a rural watershed in northern California. This early warning can support seasonal adaptive management. To predict these two values, we assess data about snow, rain, groundwater, and river flows. We find that maximum snowpack and total wet season rainfall best predict dry season severity.
Yi Nan and Fuqiang Tian
Hydrol. Earth Syst. Sci., 28, 669–689, https://doi.org/10.5194/hess-28-669-2024, https://doi.org/10.5194/hess-28-669-2024, 2024
Short summary
Short summary
This paper utilized a tracer-aided model validated by multiple datasets in a large mountainous basin on the Tibetan Plateau to analyze hydrological sensitivity to climate change. The spatial pattern of the local hydrological sensitivities and the influence factors were analyzed in particular. The main finding of this paper is that the local hydrological sensitivity in mountainous basins is determined by the relationship between the glacier area ratio and the mean annual precipitation.
Michael J. Vlah, Matthew R. V. Ross, Spencer Rhea, and Emily S. Bernhardt
Hydrol. Earth Syst. Sci., 28, 545–573, https://doi.org/10.5194/hess-28-545-2024, https://doi.org/10.5194/hess-28-545-2024, 2024
Short summary
Short summary
Virtual stream gauging enables continuous streamflow estimation where a gauge might be difficult or impractical to install. We reconstructed flow at 27 gauges of the National Ecological Observatory Network (NEON), informing ~199 site-months of missing data in the official record and improving that accuracy of official estimates at 11 sites. This study shows that machine learning, but also routine regression methods, can be used to supplement existing gauge networks and reduce monitoring costs.
Sungwook Wi and Scott Steinschneider
Hydrol. Earth Syst. Sci., 28, 479–503, https://doi.org/10.5194/hess-28-479-2024, https://doi.org/10.5194/hess-28-479-2024, 2024
Short summary
Short summary
We investigate whether deep learning (DL) models can produce physically plausible streamflow projections under climate change. We address this question by focusing on modeled responses to increases in temperature and potential evapotranspiration and by employing three DL and three process-based hydrological models. The results suggest that physical constraints regarding model architecture and input are necessary to promote the physical realism of DL hydrological projections under climate change.
Guillaume Evin, Matthieu Le Lay, Catherine Fouchier, David Penot, Francois Colleoni, Alexandre Mas, Pierre-André Garambois, and Olivier Laurantin
Hydrol. Earth Syst. Sci., 28, 261–281, https://doi.org/10.5194/hess-28-261-2024, https://doi.org/10.5194/hess-28-261-2024, 2024
Short summary
Short summary
Hydrological modelling of mountainous catchments is challenging for many reasons, the main one being the temporal and spatial representation of precipitation forcings. This study presents an evaluation of the hydrological modelling of 55 small mountainous catchments of the northern French Alps, focusing on the influence of the type of precipitation reanalyses used as inputs. These evaluations emphasize the added value of radar measurements, in particular for the reproduction of flood events.
Lena Katharina Schmidt, Till Francke, Peter Martin Grosse, and Axel Bronstert
Hydrol. Earth Syst. Sci., 28, 139–161, https://doi.org/10.5194/hess-28-139-2024, https://doi.org/10.5194/hess-28-139-2024, 2024
Short summary
Short summary
How suspended sediment export from glacierized high-alpine areas responds to future climate change is hardly assessable as many interacting processes are involved, and appropriate physical models are lacking. We present the first study, to our knowledge, exploring machine learning to project sediment export until 2100 in two high-alpine catchments. We find that uncertainties due to methodological limitations are small until 2070. Negative trends imply that peak sediment may have already passed.
Cited articles
Abbott, B. W., Baranov, V., Mendoza-Lera, C., Nikolakopoulou, M., Harjung, A., Kolbe, T., Balasubramanian, M. N., Vaessen, T. N., Ciocca, F., Campeau, A., Wallin, M. B., Romeijn, P., Antonelli, M., Goncalves, J., Datry, T., Laverman, A. M., de Dreuzy, J. R., Hannah, D. M., Krause, S., Oldham, C., and Pinay, G.: Using multi-tracer inference to move beyond single-catchment ecohydrology, Earth-Sci. Rev., 160, 19–42, https://doi.org/10.1016/j.earscirev.2016.06.014, 2016.
Allen, R. G., Pereira, L. S., Raes, D., and Smith, M.:
Crop evapotranspiration. Guidelines for computing crop water
requirements, in: Irrigation and Drainage, edited by: FAO, FAO, Rome, 1998.
Andersson, J.-O. and Nyberg, L.: Using official map data on topography, wetlands and vegetation cover for prediction of stream water chemistry in boreal headwater catchments, Hydrol. Earth Syst. Sci., 13, 537–549, https://doi.org/10.5194/hess-13-537-2009, 2009.
Battin, T. J., Kaplan, L. A., Newbold, J. D., and Hendricks, S. P.: A mixing model analysis of stream solute dynamics and the contribution of a hyporheic zone to ecosystem function, Freshwater Biol., 48, 995–1014, https://doi.org/10.1046/j.1365-2427.2003.01062.x, 2003.
Battin, T. J., Kaplan, L. A., Findlay, S., Hopkinson, C. S., Marti, E., Packman, A. I., Newbold, J. D., and Sabater, F.: Biophysical controls on organic carbon fluxes in fluvial networks, Nat. Geosci., 1, 95–100, https://doi.org/10.1038/ngeo101, 2008.
Bernhardt, E. S., Blaszczak, J. R., Ficken, C. D., Fork, M. L., Kaiser, K. E., and Seybold, E. C.: Control Points in Ecosystems: Moving Beyond the Hot Spot Hot Moment Concept, Ecosystems, 20, 665–682, https://doi.org/10.1007/s10021-016-0103-y, 2017.
Beven, K. J. and Kirkby, M. J.: A physically based, variable contributing area model of basin hydrology, Hydrolog. Sci. J., 24, 43–69, https://doi.org/10.1080/02626667909491834, 1979.
Birkel, C., Broder, T., and Biester, H.: Nonlinear and threshold-dominated runoff generation controls DOC export in a small peat catchment, J. Geophys. Res.-Biogeo., 122, 498–513, https://doi.org/10.1002/2016jg003621, 2017.
Birkel, C., Duvert, C., Correa, A., Munksgaard, N. C., Maher, D. T., and Hutley, L. B.: Tracer-Aided Modeling in the Low-Relief, Wet-Dry Tropics Suggests Water Ages and DOC Export Are Driven by Seasonal Wetlands and Deep Groundwater, Water Resour. Res., 56, e2019WR026175, https://doi.org/10.1029/2019WR026175, 2020.
Bishop, K., Seibert, J., Koher, S., and Laudon, H.: Resolving the Double Paradox of rapidly mobilized old water with highly variable responses in runoff chemistry, Hydrol. Process., 18, 185–189, https://doi.org/10.1002/hyp.5209, 2004.
Bracken, L. J., Wainwright, J., Ali, G. A., Tetzlaff, D., Smith, M. W., Reaney, S. M., and Roy, A. G.: Concepts of hydrological connectivity: Research approaches, pathways and future agendas, Earth-Sci. Rev., 119, 17–34, https://doi.org/10.1016/j.earscirev.2013.02.001, 2013.
Butman, D. E., Striegl, R. G., Stackpoole, S. M., Del Giorgio, P., Prairie, Y., Pilcher, D., Raymond, P., Pellat, F. P., and Alcocer, J.: Inland waters, 568–595, https://doi.org/10.7930/SOCCR2.2018.Ch14, 2018.
Catalán, N., Pastor, A., Borrego, C. M., Casas-Ruiz,
J. P., Hawkes, J. A., Gutiérrez, C., von Schiller, D., and
Marcé, R.: The relevance of environment vs. composition on
dissolved organic matter degradation in
freshwaters, Limnol. Oceanogr., 66, 306–320,
https://doi.org/10.1002/lno.11606, 2021.
Chantigny, M. H.: Dissolved and water-extractable organic matter in soils: a review on the influence of land use and management practices, Geoderma, 113, 357–380, https://doi.org/10.1016/S0016-7061(02)00370-1, 2003.
Cole, J. J., Prairie, Y. T., Caraco, N. F., McDowell, W. H., Tranvik, L. J., Striegl, R. G., Duarte, C. M., Kortelainen, P., Downing, J. A., Middelburg, J. J., and Melack, J.: Plumbing the global carbon cycle: Integrating inland waters into the terrestrial carbon budget, Ecosystems, 10, 171–184, https://doi.org/10.1007/s10021-006-9013-8, 2007.
Dadi, T., Harir, M., Hertkorn, N., Koschorreck, M., Schmitt-Kopplin, P., and Herzsprung, P.: Redox Conditions Affect Dissolved Organic Carbon Quality in Stratified Freshwaters, Environ. Sci. Technol., 51, 13705–13713, https://doi.org/10.1021/acs.est.7b04194, 2017.
Dawson, J. J. C., Bakewell, C., and Billett, M. F.: Is in-stream processing an important control on spatial changes in carbon fluxes in headwater catchments?, Sci. Total Environ., 265, 153–167, https://doi.org/10.1016/s0048-9697(00)00656-2, 2001.
Diamond, J. S., McLaughlin, D. L., Slesak, R. A., and Stovall, A.: Microtopography is a fundamental organizing structure of vegetation and soil chemistry in black ash wetlands, Biogeosciences, 17, 901–915, https://doi.org/10.5194/bg-17-901-2020, 2020.
Dick, J. J., Tetzlaff, D., Birkel, C., and Soulsby, C.: Modelling landscape controls on dissolved organic carbon sources and fluxes to streams, Biogeochemistry, 122, 361–374, https://doi.org/10.1007/s10533-014-0046-3, 2015.
Dittmar, T., Koch, B., Hertkorn, N., and Kattner, G.: A simple and efficient method for the solid-phase extraction of dissolved organic matter (SPE-DOM) from seawater, Limnol. Oceanogr.-Meth., 6, 230–235, https://doi.org/10.4319/lom.2008.6.230, 2008.
Doherty, J. E. and Hunt, R. J.: Approaches to highly parameterized inversion: a guide to using PEST for groundwater-model calibration, US Department of the Interior, US Geological Survey, Virginia, 2010.
Drake, T. W., Raymond, P. A., and Spencer, R. G. M.: Terrestrial carbon inputs to inland waters: A current synthesis of estimates and uncertainty, Limnol. Oceanogr. Lett., 3, 132–142, https://doi.org/10.1002/lol2.10055, 2018.
Fellman, J. B., Buma, B., Hood, E., Edwards, R. T., and D'Amore, D. V.: Linking LiDAR with streamwater biogeochemistry in coastal temperate rainforest watersheds, Can. J. Fish. Aquat. Sci., 74, 801–811, https://doi.org/10.1139/cjfas-2016-0130, 2017.
Frei, S., Lischeid, G., and Fleckenstein, J. H.: Effects of micro-topography on surface-subsurface exchange and runoff generation in a virtual riparian wetland – A modeling study, Adv. Water Resour., 33, 1388–1401, https://doi.org/10.1016/j.advwatres.2010.07.006, 2010.
Frei, S., Knorr, K. H., Peiffer, S., and Fleckenstein,
J. H.: Surface micro-topography causes hot spots of biogeochemical
activity in wetland systems: A virtual modeling experiment,
J. Geophys. Res.-Biogeo., 117, G00N12, https://doi.org/10.1029/2012jg002012,
2012.
Futter, M. N. and de Wit, H. A.: Testing seasonal and long-term controls of streamwater DOC using empirical and process-based models, Sci. Total Environ., 407, 698–707, https://doi.org/10.1016/j.scitotenv.2008.10.002, 2008.
Gao, H., Birkel, C., Hrachowitz, M., Tetzlaff, D., Soulsby, C., and Savenije, H. H. G.: A simple topography-driven and calibration-free runoff generation module, Hydrol. Earth Syst. Sci., 23, 787–809, https://doi.org/10.5194/hess-23-787-2019, 2019.
Grabs, T., Bishop, K., Laudon, H., Lyon, S. W., and Seibert, J.: Riparian zone hydrology and soil water total organic carbon (TOC): implications for spatial variability and upscaling of lateral riparian TOC exports, Biogeosciences, 9, 3901–3916, https://doi.org/10.5194/bg-9-3901-2012, 2012.
Guarch-Ribot, A. and Butturini, A.: Hydrological conditions regulate dissolved organic matter quality in an intermittent headwater stream. From drought to storm analysis, Sci. Total Environ., 571, 1358–1369, https://doi.org/10.1016/j.scitotenv.2016.07.060, 2016.
Herndon, E. M., Dere, A. L., Sullivan, P. L., Norris, D., Reynolds, B., and Brantley, S. L.: Landscape heterogeneity drives contrasting concentration–discharge relationships in shale headwater catchments, Hydrol. Earth Syst. Sci., 19, 3333–3347, https://doi.org/10.5194/hess-19-3333-2015, 2015.
Herzsprung, P., Hertkorn, N., von Tümpling, W., Harir, M., Friese, K., and Schmitt-Kopplin, P.: Understanding molecular formula assignment of Fourier transform ion cyclotron resonance mass spectrometry data of natural organic matter from a chemical point of view, Anal. Bioanal. Chem., 406, 7977–7987, https://doi.org/10.1007/s00216-014-8249-y, 2014.
Herzsprung, P., Wentzky, V., Kamjunke, N., von
Tümpling, W., Wilske, C., Friese, K., Boehrer, B., Reemtsma, T.,
Rinke, K., and Lechtenfeld, O. J.: Improved Understanding of
Dissolved Organic Matter Processing in Freshwater Using
Complementary Experimental and Machine Learning Approaches,
Environ. Sci. Technol., 54, 13556–13565, https://doi.org/10.1021/acs.est.0c02383, 2020.
James, A. L. and Roulet, N. T.: Antecedent moisture conditions and catchment morphology as controls on spatial patterns of runoff generation in small forest catchments, J. Hydrol., 377, 351–366, https://doi.org/10.1016/j.jhydrol.2009.08.039, 2009.
Jencso, K. G., McGlynn, B. L., Gooseff, M. N., Wondzell, S. M., Bencala, K. E., and Marshall, L. A.: Hydrologic connectivity between landscapes and streams: Transferring reach-and plot-scale understanding to the catchment scale, Water Resour. Res., 45, W04428, https://doi.org/10.1029/2008wr007225, 2009.
Kaiser, K. and Kalbitz, K.: Cycling downwards –
dissolved organic matter in soils, Soil Biol. Biochem., 52, 29–32, https://doi.org/10.1016/j.soilbio.2012.04.002, 2012.
Kind, T. and Fiehn, O.: Seven Golden Rules for heuristic
filtering of molecular formulas obtained by accurate mass
spectrometry, BMC Bioinformatics, 8, 105, https://doi.org/10.1186/1471-2105-8-105, 2007.
Klaus, J. and McDonnell, J. J.: Hydrograph separation using stable isotopes: Review and evaluation, J. Hydrol., 505, 47–64, https://doi.org/10.1016/j.jhydrol.2013.09.006, 2013.
Koch, B. P., Kattner, G., Witt, M., and Passow, U.: Molecular insights into the microbial formation of marine dissolved organic matter: recalcitrant or labile?, Biogeosciences, 11, 4173–4190, https://doi.org/10.5194/bg-11-4173-2014, 2014.
Köhler, S. J., Buffam, I., Seibert, J., Bishop, K. H., and Laudon, H.: Dynamics of stream water TOC concentrations in a boreal headwater catchment: Controlling factors and implications for climate scenarios, J. Hydrol., 373, 44–56, https://doi.org/10.1016/j.jhydrol.2009.04.012, 2009.
Kottek, M., Grieser, J., Beck, C., Rudolf, B., and Rubel, F.: World Map of the Köppen-Geiger climate classification updated, Meteorol. Z., 15, 259–263, https://doi.org/10.1127/0941-2948/2006/0130, 2006.
Krause, S., Freer, J., Hannah, D. M., Howden, N. J. K., Wagener, T., and Worrall, F.: Catchment similarity concepts for understanding dynamic biogeochemical behaviour of river basins, Hydrol. Process., 28, 1554–1560, https://doi.org/10.1002/hyp.10093, 2014.
LaCroix, R. E., Tfaily, M. M., McCreight, M., Jones, M. E., Spokas, L., and Keiluweit, M.: Shifting mineral and redox controls on carbon cycling in seasonally flooded mineral soils, Biogeosciences, 16, 2573–2589, https://doi.org/10.5194/bg-16-2573-2019, 2019.
Larsen, S., Andersen, T., and Hessen, D. O.: Climate change predicted to cause severe increase of organic carbon in lakes, Glob. Change Biol., 17, 1186–1192, https://doi.org/10.1111/j.1365-2486.2010.02257.x, 2011.
Laudon, H., Kuglerova, L., Sponseller, R. A., Futter, M., Nordin, A., Bishop, K., Lundmark, T., Egnell, G., and Agren, A. M.: The role of biogeochemical hotspots, landscape heterogeneity, and hydrological connectivity for minimizing forestry effects on water quality, Ambio, 45, 152–162, https://doi.org/10.1007/s13280-015-0751-8, 2016.
Lê, S., Josse, J., and Husson, F.: FactoMineR: An R Package for Multivariate Analysis, J. Stat. Softw., 25, 1–18, https://doi.org/10.18637/jss.v025.i01, 2008.
Ledesma, J. L., Grabs, T., Bishop, K. H., Schiff, S. L., and Kohler, S. J.: Potential for long-term transfer of dissolved organic carbon from riparian zones to streams in boreal catchments, Glob. Change Biol., 21, 2963–2979, https://doi.org/10.1111/gcb.12872, 2015.
Ledesma, J. L., Futter, M. N., Laudon, H., Evans, C. D., and Kohler, S. J.: Boreal forest riparian zones regulate stream sulfate and dissolved organic carbon, Sci. Total Environ., 560–561, 110–122, https://doi.org/10.1016/j.scitotenv.2016.03.230, 2016.
Ledesma, J. L. J., Futter, M. N., Blackburn, M., Lidman, F., Grabs, T., Sponseller, R. A., Laudon, H., Bishop, K. H., and Kohler, S. J.: Towards an Improved Conceptualization of Riparian Zones in Boreal Forest Headwaters, Ecosystems, 21, 297–315, https://doi.org/10.1007/s10021-017-0149-5, 2018a.
Ledesma, J. L. J., Kothawala, D. N., Bastviken, P., Maehder, S., Grabs, T., and Futter, M. N.: Stream Dissolved Organic Matter Composition Reflects the Riparian Zone, Not Upslope Soils in Boreal Forest Headwaters, Water Resour. Res., 54, 3896–3912, https://doi.org/10.1029/2017wr021793, 2018b.
Lessels, J. S., Tetzlaff, D., Carey, S. K., Smith, P., and Soulsby, C.: A coupled hydrology–biogeochemistry model to simulate dissolved organic carbon exports from a permafrost-influenced catchment, Hydrol. Process., 29, 5383–5396, https://doi.org/10.1002/hyp.10566, 2015.
Luke, S. H., Luckai, N. J., Burke, J. M., and Prepas, E. E.: Riparian areas in the Canadian boreal forest and linkages with water quality in streams, Environ. Rev., 15, 79–97, https://doi.org/10.1139/A07-001, 2007.
Manning, R., Griffith, J. P., Pigot, T., and Vernon-Harcourt, L. F.: On the flow of water in open channels and pipes, Transactions, Institution of Civ. Eng., Dublin, Ireland, 1891.
Matilainen, A., Gjessing, E. T., Lahtinen, T., Hed, L., Bhatnagar, A., and Sillanpaa, M.: An overview of the methods used in the characterisation of natural organic matter (NOM) in relation to drinking water treatment, Chemosphere, 83, 1431–1442, https://doi.org/10.1016/j.chemosphere.2011.01.018, 2011.
Moeck, C., Hunkeler, D., and Brunner, P.: Tutorials as a flexible alternative to GUIs: An example for advanced model calibration using Pilot Points, Environ. Modell. Softw., 66, 78–86, https://doi.org/10.1016/j.envsoft.2014.12.018, 2015.
Mostovaya, A., Koehler, B., Guillemette, F., Brunberg, A.-K., and Tranvik, L. J.: Effects of compositional changes on reactivity continuum and decomposition kinetics of lake dissolved organic matter, J. Geophys. Res.-Biogeo., 121, 1733–1746, https://doi.org/10.1002/2016JG003359, 2016.
Mostovaya, A., Hawkes, J. A., Dittmar, T., and Tranvik, L. J.: Molecular Determinants of Dissolved Organic Matter Reactivity in Lake Water, Front. Earth Sci., 5, 106, https://doi.org/10.3389/feart.2017.00106, 2017.
Musolff, A., Fleckenstein, J. H., Opitz, M., Buttner, O., Kumar, R., and Tittel, J.: Spatio-temporal controls of dissolved organic carbon stream water concentrations, J. Hydrol., 566, 205–215, https://doi.org/10.1016/j.jhydrol.2018.09.011, 2018.
Pinay, G., Peiffer, S., De Dreuzy, J. R., Krause, S., Hannah, D. M., Fleckenstein, J. H., Sebilo, M., Bishop, K., and Hubert-Moy, L.: Upscaling Nitrogen Removal Capacity from Local Hotspots to Low Stream Orders' Drainage Basins, Ecosystems, 18, 1101–1120, https://doi.org/10.1007/s10021-015-9878-5, 2015.
Pisani, O., Bosch, D. D., Coffin, A. W., Endale, D. M., Liebert, D., and Strickland, T. C.: Riparian land cover and hydrology influence stream dissolved organic matter composition in an agricultural watershed, Sci. Total Environ., 717, 137165, https://doi.org/10.1016/j.scitotenv.2020.137165, 2020.
Ploum, S. W., Laudon, H., Peralta-Tapia, A., and Kuglerová, L.: Are dissolved organic carbon concentrations in riparian groundwater linked to hydrological pathways in the boreal forest?, Hydrol. Earth Syst. Sci., 24, 1709–1720, https://doi.org/10.5194/hess-24-1709-2020, 2020.
Prairie, Y. T.: Carbocentric limnology: looking back, looking forward, Can. J. Fish. Aquat. Sci., 65, 543–548, https://doi.org/10.1139/f08-011, 2008.
R Core Team: R: A language and environment for statistical
computing. R Foundation for Statistical Computing, Vienna, Austria, available at:
http://www.R-project.org/ (last access: 11 November 2020), 2014.
Raeke, J., Lechtenfeld, O. J., Tittel, J., Oosterwoud, M. R., Bornmann, K., and Reemtsma, T.: Linking the mobilization of dissolved organic matter in catchments and its removal in drinking water treatment to its molecular characteristics, Water Res., 113, 149–159, https://doi.org/10.1016/j.watres.2017.01.066, 2017.
Raymond, P. A., Hartmann, J., Lauerwald, R., Sobek, S., McDonald, C., Hoover, M., Butman, D., Striegl, R., Mayorga, E., Humborg, C., Kortelainen, P., Dürr, H., Meybeck, M., Ciais, P., and Guth, P.: Global carbon dioxide emissions from inland waters, Nature, 503, 355–359, https://doi.org/10.1038/nature12760, 2013.
Rousseeuw, P. J.: Silhouettes – a Graphical Aid to the Interpretation and Validation of Cluster-Analysis, J. Comput. Appl. Math., 20, 53–65, https://doi.org/10.1016/0377-0427(87)90125-7, 1987.
Scheliga, B., Tetzlaff, D., Nuetzmann, G., and Soulsby, C.: Assessing runoff generation in riparian wetlands: monitoring groundwater–surface water dynamics at the micro-catchment scale, Environ. Monit. Assess., 191, 116, https://doi.org/10.1007/s10661-019-7237-2, 2019.
Seibert, J., Grabs, T., Köhler, S., Laudon, H., Winterdahl, M., and Bishop, K.: Linking soil- and stream-water chemistry based on a Riparian Flow-Concentration Integration Model, Hydrol. Earth Syst. Sci., 13, 2287–2297, https://doi.org/10.5194/hess-13-2287-2009, 2009.
Shen, Y., Chapelle, F. H., Strom, E. W., and Benner, R.: Origins and bioavailability of dissolved organic matter in groundwater, Biogeochemistry, 122, 61–78, https://doi.org/10.1007/s10533-014-0029-4, 2015.
Sherene, T.: Mobility and transport of heavy metals in polluted soil environment, Biological Forum – An International Journal, 2, 112–121, 2010
Stanley, E. H., Powers, S. M., Lottig, N. R., Buffam, I., and Crawford, J. T.: Contemporary changes in dissolved organic carbon (DOC) in human-dominated rivers: is there a role for DOC management?, Freshwater Biol., 57, 26–42, https://doi.org/10.1111/j.1365-2427.2011.02613.x, 2012.
Strohmeier, S., Knorr, K.-H., Reichert, M., Frei, S., Fleckenstein, J. H., Peiffer, S., and Matzner, E.: Concentrations and fluxes of dissolved organic carbon in runoff from a forested catchment: insights from high frequency measurements, Biogeosciences, 10, 905–916, https://doi.org/10.5194/bg-10-905-2013, 2013.
Suecker, J. K., Ryan, J. N., Kendall, C., and Jarrett, R. D.: Determination of hydrologic pathways during snowmelt for alpine/subalpine basins, Rocky Mountain National Park, Colorado, Water Resour. Res., 36, 63–75, 2000.
Tang, Q., Kurtz, W., Schilling, O. S., Brunner, P., Vereecken, H., and Franssen, H. J. H.: The influence of riverbed heterogeneity patterns on river-aquifer exchange fluxes under different connection regimes, J. Hydrol., 554, 383–396, https://doi.org/10.1016/j.jhydrol.2017.09.031, 2017.
Tarboton, D. G.: A new method for the determination of flow directions and upslope areas in grid digital elevation models, Water Resour. Res., 33, 309–319, https://doi.org/10.1029/96wr03137, 1997.
Tfaily, M. M., Wilson, R. M., Cooper, W. T., Kostka, J. E., Hanson, P., and Chanton, J. P.: Vertical Stratification of Peat Pore Water Dissolved Organic Matter Composition in a Peat Bog in Northern Minnesota, J. Geophys. Res.-Biogeo., 123, 479–494, https://doi.org/10.1002/2017jg004007, 2018.
Therrien, R., McLaren, R., Sudicky, E., and Panday, S.: HydroGeoSphere: A three-dimensional numerical model describing fully-integrated subsurface and surface flow and solute transport, Groundwater Simulations Group, University of Waterloo, Waterloo, ON, 2010.
Vachon, D., Sponseller, R. A., and Karlsson, J.: Integrating carbon emission, accumulation and transport in inland waters to understand their role in the global carbon cycle, Glob. Change Biol., 27, 719–727, https://doi.org/10.1111/gcb.15448, 2021.
Wang, X., Zhang, H., Zhang, Y., Shi, Q., Wang, J., Yu, J., and Yang, M.: New Insights into Trihalomethane and Haloacetic Acid Formation Potentials: Correlation with the Molecular Composition of Natural Organic Matter in Source Water, Environ. Sci. Technol., 51, 2015–2021, https://doi.org/10.1021/acs.est.6b04817, 2017.
Wen, H., Perdrial, J., Abbott, B. W., Bernal, S., Dupas, R., Godsey, S. E., Harpold, A., Rizzo, D., Underwood, K., Adler, T., Sterle, G., and Li, L.: Temperature controls production but hydrology regulates export of dissolved organic carbon at the catchment scale, Hydrol. Earth Syst. Sci., 24, 945–966, https://doi.org/10.5194/hess-24-945-2020, 2020.
Werner, B. J.: High resolution spatial, chemical
(dissolved organic carbon) and hydrological dataset of the upper
Rappbode Catchment in the temperate Harz Mountains, Germany,
HydroShare [data set], https://doi.org/10.4211/hs.b32ba184414e475ba36a0bb193866ef1, 2021.
Werner, B. J., Musolff, A., Lechtenfeld, O. J., de Rooij, G. H., Oosterwoud, M. R., and Fleckenstein, J. H.: High-frequency measurements explain quantity and quality of dissolved organic carbon mobilization in a headwater catchment, Biogeosciences, 16, 4497–4516, https://doi.org/10.5194/bg-16-4497-2019, 2019.
Wilske, C., Herzsprung, P., Lechtenfeld, O. J., Kamjunke, N., and von Tumpling, W.: Photochemically Induced Changes of Dissolved Organic Matter in a Humic-Rich and Forested Stream, Water, 12, 331, https://doi.org/10.3390/w12020331, 2020.
Wilson, H. F. and Xenopoulos, M. A.: Effects of agricultural land use on the composition of fluvial dissolved organic matter, Nat. Geosci., 2, 37–41, https://doi.org/10.1038/ngeo391, 2008.
Wilson, H. F., Saiers, J. E., Raymond, P. A., and Sobczak, W. V.: Hydrologic Drivers and Seasonality of Dissolved Organic Carbon Concentration, Nitrogen Content, Bioavailability, and Export in a Forested New England Stream, Ecosystems, 16, 604–616, https://doi.org/10.1007/s10021-013-9635-6, 2013.
Wollschläger, U., Attinger, S., Borchardt, D., Brauns, M., Cuntz, M., Dietrich, P., Fleckenstein, J. H., Friese, K., Friesen, J., Harpke, A., Hildebrandt, A., Jäckel, G., Kamjunke, N., Knöller, K., Kögler, S., Kolditz, O., Krieg, R., Kumar, R., Lausch, A., Liess, M., Marx, A., Merz, R., Mueller, C., Musolff, A., Norf, H., Oswald, S. E., Rebmann, C., Reinstorf, F., Rode, M., Rink, K., Rinke, K., Samaniego, L., Vieweg, M., Vogel, H.-J., Weitere, M., Werban, U., Zink, M., and Zacharias, S.: The Bode hydrological observatory: a platform for integrated, interdisciplinary hydro-ecological research within the TERENO Harz/Central German Lowland Observatory, Environ. Earth Sci., 76, 1–25, https://doi.org/10.1007/s12665-016-6327-5, 2016.
Yang, J., Graf, T., and Ptak, T.: Impact of climate change on freshwater resources in a heterogeneous coastal aquifer of Bremerhaven, Germany: A three-dimensional modeling study, J. Contam. Hydrol., 177–178, 107–121, https://doi.org/10.1016/j.jconhyd.2015.03.014, 2015.
Yang, J., Heidbuchel, I., Musolff, A., Reinstorf, F., and Fleckenstein, J. H.: Exploring the Dynamics of Transit Times and Subsurface Mixing in a Small Agricultural Catchment, Water Resour. Res., 54, 2317–2335, https://doi.org/10.1002/2017wr021896, 2018.
Zarnetske, J. P., Bouda, M., Abbott, B. W., Saiers, J., and Raymond, P. A.: Generality of Hydrologic Transport Limitation of Watershed Organic Carbon Flux Across Ecoregions of the United States, Geophys. Res. Lett., 45, 11702–11711, https://doi.org/10.1029/2018gl080005, 2018.
Zhi, W., Li, L., Dong, W., Brown, W., Kaye, J., Steefel, C., and Williams, K. H.: Distinct Source Water Chemistry Shapes Contrasting Concentration-Discharge Patterns, Water Resour. Res., 55, 4233–4251, https://doi.org/10.1029/2018WR024257, 2019.
Short summary
Export of dissolved organic carbon (DOC) from riparian zones (RZs) is an important yet poorly understood component of the catchment carbon budget. This study chemically and spatially classifies DOC source zones within a RZ of a small catchment to assess DOC export patterns. Results highlight that DOC export from only a small fraction of the RZ with distinct DOC composition dominates overall DOC export. The application of a spatial, topographic proxy can be used to improve DOC export models.
Export of dissolved organic carbon (DOC) from riparian zones (RZs) is an important yet poorly...