Articles | Volume 17, issue 12
https://doi.org/10.5194/hess-17-5213-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/hess-17-5213-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Model-based estimation of pesticides and transformation products and their export pathways in a headwater catchment
M. Gassmann
Chair of Sustainable Chemistry and Material Resources, Leuphana University of Lüneburg, Lüneburg, Germany
Chair of Hydrology, University of Freiburg, Freibung, Germany
Swiss Federal Institute of Aquatic Science and Technology (Eawag), Dübendorf, Switzerland
O. Olsson
Chair of Sustainable Chemistry and Material Resources, Leuphana University of Lüneburg, Lüneburg, Germany
Chair of Hydrology, University of Freiburg, Freibung, Germany
K. Kümmerer
Chair of Sustainable Chemistry and Material Resources, Leuphana University of Lüneburg, Lüneburg, Germany
M. Weiler
Chair of Hydrology, University of Freiburg, Freibung, Germany
Related authors
No articles found.
Robin Schwemmle, Hannes Leistert, Andreas Steinbrich, and Markus Weiler
Geosci. Model Dev., 17, 5249–5262, https://doi.org/10.5194/gmd-17-5249-2024, https://doi.org/10.5194/gmd-17-5249-2024, 2024
Short summary
Short summary
The new process-based hydrological toolbox model, RoGeR (https://roger.readthedocs.io/), can be used to estimate the components of the hydrological cycle and the related travel times of pollutants through parts of the hydrological cycle. These estimations may contribute to effective water resources management. This paper presents the toolbox concept and provides a simple example of providing estimations to water resources management.
Jonas Pyschik, Stefan Seeger, Barbara Herbstritt, and Markus Weiler
EGUsphere, https://doi.org/10.5194/egusphere-2024-528, https://doi.org/10.5194/egusphere-2024-528, 2024
Short summary
Short summary
We developed a device which automates the analysis process of stable water isotopes. Stable water isotopes are a natural tracer which many researchers use to investigate water (re-)distribution processes in environmental systems. The device helps to analyse such environmental samples by automating a formerly tidious manual labor process, alowwing for a higher sample throughput. This enables larger sampling campaigns, since more samples can be processed before reaching their limited storage time.
Barbara Herbstritt, Benjamin Gralher, Stefan Seeger, Michael Rinderer, and Markus Weiler
Hydrol. Earth Syst. Sci., 27, 3701–3718, https://doi.org/10.5194/hess-27-3701-2023, https://doi.org/10.5194/hess-27-3701-2023, 2023
Short summary
Short summary
We present a method to collect water vapor samples into bags in the field without an in-field analyser, followed by isotope analysis in the lab. This new method resolves even fine-scaled natural isotope variations. It combines low-cost and lightweight components for maximum spatial and temporal flexibility regarding environmental setups. Hence, it allows for sampling even in terrains that are rather difficult to access, enabling future extended isotope datasets in soil sciences and ecohydrology.
Stefan Seeger and Markus Weiler
Hydrol. Earth Syst. Sci., 27, 3393–3404, https://doi.org/10.5194/hess-27-3393-2023, https://doi.org/10.5194/hess-27-3393-2023, 2023
Short summary
Short summary
This study proposes a low-budget method to quantify the radial distribution of water transport velocities within trees at a high spatial resolution. We observed a wide spread of water transport velocities within a tree stem section, which were on average 3 times faster than the flux velocity. The distribution of transport velocities has implications for studies that use water isotopic signatures to study root water uptake and usually assume uniform or even implicitly infinite velocities.
Andreas Hänsler and Markus Weiler
Hydrol. Earth Syst. Sci., 26, 5069–5084, https://doi.org/10.5194/hess-26-5069-2022, https://doi.org/10.5194/hess-26-5069-2022, 2022
Short summary
Short summary
Spatially explicit quantification of design storms is essential for flood risk assessment and planning. However, available datasets are mainly based on spatially interpolated station-based design storms. Since the spatial interpolation of the data inherits a large potential for uncertainty, we develop an approach to be able to derive spatially explicit design storms on the basis of weather radar data. We find that our approach leads to an improved spatial representation of design storms.
Anne Hartmann, Markus Weiler, Konrad Greinwald, and Theresa Blume
Hydrol. Earth Syst. Sci., 26, 4953–4974, https://doi.org/10.5194/hess-26-4953-2022, https://doi.org/10.5194/hess-26-4953-2022, 2022
Short summary
Short summary
Analyzing the impact of soil age and rainfall intensity on vertical subsurface flow paths in calcareous soils, with a special focus on preferential flow occurrence, shows how water flow paths are linked to the organization of evolving landscapes. The observed increase in preferential flow occurrence with increasing moraine age provides important but rare data for a proper representation of hydrological processes within the feedback cycle of the hydro-pedo-geomorphological system.
Nils Hinrich Kaplan, Theresa Blume, and Markus Weiler
Hydrol. Earth Syst. Sci., 26, 2671–2696, https://doi.org/10.5194/hess-26-2671-2022, https://doi.org/10.5194/hess-26-2671-2022, 2022
Short summary
Short summary
This study is analyses how characteristics of precipitation events and soil moisture and temperature dynamics during these events can be used to model the associated streamflow responses in intermittent streams. The models are used to identify differences between the dominant controls of streamflow intermittency in three distinct geologies of the Attert catchment, Luxembourg. Overall, soil moisture was found to be the most important control of intermittent streamflow in all geologies.
Benjamin Gralher, Barbara Herbstritt, and Markus Weiler
Hydrol. Earth Syst. Sci., 25, 5219–5235, https://doi.org/10.5194/hess-25-5219-2021, https://doi.org/10.5194/hess-25-5219-2021, 2021
Short summary
Short summary
We scrutinized the quickest currently available method for stable isotope analysis of matrix-bound water. Simulating common procedures, we demonstrated the limits of certain materials currently used and identified a reliable and cost-efficient alternative. Further, we calculated the optimum proportions of important protocol aspects critical for precise and accurate analyses. Our unifying protocol suggestions increase data quality and comparability as well as the method's general applicability.
Felicia Linke, Oliver Olsson, Frank Preusser, Klaus Kümmerer, Lena Schnarr, Marcus Bork, and Jens Lange
Hydrol. Earth Syst. Sci., 25, 4495–4512, https://doi.org/10.5194/hess-25-4495-2021, https://doi.org/10.5194/hess-25-4495-2021, 2021
Short summary
Short summary
We used a two-step approach with limited sampling effort in existing storm water infrastructure to illustrate the risk of biocide emission in a 2 ha urban area 13 years after construction had ended. First samples at a swale confirmed the overall relevance of biocide pollution. Then we identified sources where biocides were used for film protection and pathways where transformation products were formed. Our results suggest that biocide pollution is a also continuous risk in aging urban areas.
Jan Greiwe, Markus Weiler, and Jens Lange
Biogeosciences, 18, 4705–4715, https://doi.org/10.5194/bg-18-4705-2021, https://doi.org/10.5194/bg-18-4705-2021, 2021
Short summary
Short summary
We analyzed variability in diel nitrate patterns at three locations in a lowland stream. Comparison of time lags between monitoring sites with water travel time indicated that diel patterns were created by in-stream processes rather than transported downstream from an upstream point of origin. Most of the patterns (70 %) could be explained by assimilatory nitrate uptake. The remaining patterns suggest seasonally varying dominance and synchronicity of different biochemical processes.
Stefan Seeger and Markus Weiler
Biogeosciences, 18, 4603–4627, https://doi.org/10.5194/bg-18-4603-2021, https://doi.org/10.5194/bg-18-4603-2021, 2021
Short summary
Short summary
We developed a setup for fully automated in situ measurements of stable water isotopes in soil and the stems of fully grown trees. We used this setup in a 12-week field campaign to monitor the propagation of a labelling pulse from the soil up to a stem height of 8 m.
We could observe trees shifting their main water uptake depths multiple times, depending on water availability.
The gained knowledge about the temporal dynamics can help to improve water uptake models and future study designs.
Andreas Hänsler and Markus Weiler
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2021-366, https://doi.org/10.5194/hess-2021-366, 2021
Manuscript not accepted for further review
Short summary
Short summary
Spatially explicit quantification on design storms are essential for flood risk assessment. However this information can be only achieved from substantially long records of rainfall measurements, usually only available for a few stations. Hence, design storms estimates from these few stations are then spatially interpolated leading to a major source of uncertainty. Therefore we defined a methodology to extend spatially explicit weather radar data to be used for the estimation of design storms.
Anne Hartmann, Markus Weiler, Konrad Greinwald, and Theresa Blume
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2021-242, https://doi.org/10.5194/hess-2021-242, 2021
Manuscript not accepted for further review
Short summary
Short summary
Our field observation-based examination of flow path evolution, soil formation and vegetation succession across ten millennia on calcareous parent material shows how water flow paths and subsurface water storage are linked to the organization of evolving landscapes. We provide important but rare data and observations for a proper handling of hydrologic processes and their role within the feedback cycle of the hydro-pedo-geomorphological system.
Axel Schaffitel, Tobias Schuetz, and Markus Weiler
Geosci. Model Dev., 14, 2127–2142, https://doi.org/10.5194/gmd-14-2127-2021, https://doi.org/10.5194/gmd-14-2127-2021, 2021
Short summary
Short summary
This paper presents FluSM, an algorithm to derive the water balance from soil moisture and metrological measurements. This data-driven water balance framework uses soil moisture as an input and therefore is applicable for cases with unclear processes and lacking parameters. In a case study, we apply FluSM to derive the water balance of 15 different permeable pavements under field conditions. These findings are of special interest for urban hydrology.
Robin Schwemmle, Dominic Demand, and Markus Weiler
Hydrol. Earth Syst. Sci., 25, 2187–2198, https://doi.org/10.5194/hess-25-2187-2021, https://doi.org/10.5194/hess-25-2187-2021, 2021
Short summary
Short summary
A better understanding of the reasons why model performance is unsatisfying represents a crucial part for meaningful model evaluation. We propose the novel diagnostic efficiency (DE) measure and diagnostic polar plots. The proposed evaluation approach provides a diagnostic tool for model developers and model users and facilitates interpretation of model performance.
Urs Schönenberger and Christian Stamm
Hydrol. Earth Syst. Sci., 25, 1727–1746, https://doi.org/10.5194/hess-25-1727-2021, https://doi.org/10.5194/hess-25-1727-2021, 2021
Short summary
Short summary
Pesticides are a major pollutant of surface waters. In this study, we assessed how so-called hydraulic shortcuts (e.g. inlet and maintenance shafts of road or field storm drainage systems) influence surface runoff and pesticide transport to Swiss surface waters. The study suggests that transport via hydraulic shortcuts is an important pesticide transport pathway and that current regulations may fall short in addressing this pathway.
Michael Rinderer, Jaane Krüger, Friederike Lang, Heike Puhlmann, and Markus Weiler
Biogeosciences, 18, 1009–1027, https://doi.org/10.5194/bg-18-1009-2021, https://doi.org/10.5194/bg-18-1009-2021, 2021
Short summary
Short summary
We quantified the lateral and vertical subsurface flow (SSF) and P concentrations of three beech forest plots with contrasting soil properties during sprinkling experiments. Vertical SSF was 2 orders of magnitude larger than lateral SSF, and both consisted mainly of pre-event water. P concentrations in SSF were high during the first 1 to 2 h (nutrient flushing) but nearly constant thereafter. This suggests that P in the soil solution was replenished fast by mineral or organic sources.
Merle Koelbing, Tobias Schuetz, and Markus Weiler
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2021-24, https://doi.org/10.5194/hess-2021-24, 2021
Revised manuscript not accepted
Short summary
Short summary
Based on a unique and comprehensive data set of urban micro-meteorological variables, which were observed with a mobile climate station, we developed a new method to transfer mesoscale reference potential evapotranspiration to the urban microscale in street canyons. Our findings can be transferred easily to existing urban hydrologic models to improve modelling results with a more precise estimate of potential evapotranspiration on street level.
Jan Greiwe, Oliver Olsson, Klaus Kümmerer, and Jens Lange
Hydrol. Earth Syst. Sci., 25, 497–509, https://doi.org/10.5194/hess-25-497-2021, https://doi.org/10.5194/hess-25-497-2021, 2021
Short summary
Short summary
We investigated the linkage between contaminant mobilization in catchments and their mitigation in vegetated treatment systems (VTSs). We identified different patterns in chemographs recorded at the inlet of a VTS, indicating distinct mobilization patterns that were associated with similar source areas, transport pathways, and discharge dynamics. Peak concentration reduction in the VTS was strongest for sharp-peaked chemographs, suggesting that dispersion was the principle mitigation process.
Anne Hartmann, Markus Weiler, and Theresa Blume
Earth Syst. Sci. Data, 12, 3189–3204, https://doi.org/10.5194/essd-12-3189-2020, https://doi.org/10.5194/essd-12-3189-2020, 2020
Short summary
Short summary
Our analysis of soil physical and hydraulic properties across two soil chronosequences of 10 millennia in the Swiss Alps provides important observation of the evolution of soil hydraulic behavior. A strong co-evolution of soil physical and hydraulic properties was revealed by the observed change of fast-draining coarse-textured soils to slow-draining soils with a high water-holding capacity in correlation with a distinct change in structural properties and organic matter content.
Daniel Beiter, Markus Weiler, and Theresa Blume
Hydrol. Earth Syst. Sci., 24, 5713–5744, https://doi.org/10.5194/hess-24-5713-2020, https://doi.org/10.5194/hess-24-5713-2020, 2020
Short summary
Short summary
We investigated the interactions between streams and their adjacent hillslopes in terms of water flow. It could be revealed that soil structure has a strong influence on how hillslopes connect to the streams, while the groundwater table tells us a lot about when the two connect. This observation could be used to improve models that try to predict whether or not hillslopes are in a state where a rain event will be likely to produce a flood in the stream.
Maria Staudinger, Stefan Seeger, Barbara Herbstritt, Michael Stoelzle, Jan Seibert, Kerstin Stahl, and Markus Weiler
Earth Syst. Sci. Data, 12, 3057–3066, https://doi.org/10.5194/essd-12-3057-2020, https://doi.org/10.5194/essd-12-3057-2020, 2020
Short summary
Short summary
The data set CH-IRP provides isotope composition in precipitation and streamflow from 23 Swiss catchments, being unique regarding its long-term multi-catchment coverage along an alpine–pre-alpine gradient. CH-IRP contains fortnightly time series of stable water isotopes from streamflow grab samples complemented by time series in precipitation. Sampling conditions, catchment and climate information, lab standards and errors are provided together with areal precipitation and catchment boundaries.
Nils Hinrich Kaplan, Theresa Blume, and Markus Weiler
Hydrol. Earth Syst. Sci., 24, 5453–5472, https://doi.org/10.5194/hess-24-5453-2020, https://doi.org/10.5194/hess-24-5453-2020, 2020
Short summary
Short summary
In recent decades the demand for detailed information of spatial and temporal dynamics of the stream network has grown in the fields of eco-hydrology and extreme flow prediction. We use temporal streamflow intermittency data obtained at various sites using innovative sensing technology as well as spatial predictors to predict and map probabilities of streamflow intermittency. This approach has the potential to provide intermittency maps for hydrological modelling and management practices.
Michael Stoelzle, Maria Staudinger, Kerstin Stahl, and Markus Weiler
Proc. IAHS, 383, 43–50, https://doi.org/10.5194/piahs-383-43-2020, https://doi.org/10.5194/piahs-383-43-2020, 2020
Short summary
Short summary
The role of recharge and catchment storage is crucial to understand streamflow drought sensitivity. Here we introduce a model experiment with recharge stress tests as complement to climate scenarios to quantify the streamflow drought sensitivities of catchments in Switzerland. We identified a pre-drought period of 12 months as maximum storage-memory for the study catchments. From stress testing, we found up to 200 days longer summer streamflow droughts and minimum flow reductions of 50 %–80 %.
Anne Hartmann, Ekaterina Semenova, Markus Weiler, and Theresa Blume
Hydrol. Earth Syst. Sci., 24, 3271–3288, https://doi.org/10.5194/hess-24-3271-2020, https://doi.org/10.5194/hess-24-3271-2020, 2020
Short summary
Short summary
Our field observation-based examination of flow path evolution, soil formation, and vegetation succession across 10 millennia shows how water flow paths and subsurface water storage are linked to the organization of evolving landscapes.
The increase found in water storage and preferential flow paths with increasing soil age shows the effect of the complex interaction of vegetation and soil development on flow paths, water balance, and runoff formation during landscape evolution.
Mirko Mälicke, Sibylle K. Hassler, Theresa Blume, Markus Weiler, and Erwin Zehe
Hydrol. Earth Syst. Sci., 24, 2633–2653, https://doi.org/10.5194/hess-24-2633-2020, https://doi.org/10.5194/hess-24-2633-2020, 2020
Short summary
Short summary
We could show that distributed soil moisture time series bear a considerable amount of information about dynamic changes in soil moisture. We developed a new method to describe spatial patterns and analyze their persistency. By combining uncertainty propagation with information theory, we were able to calculate the information content of spatial similarity with respect to measurement uncertainty. This does help to understand when and why the soil is drying in an organized manner.
Marcus Bork, Jens Lange, Markus Graf-Rosenfellner, and Friederike Lang
Hydrol. Earth Syst. Sci., 24, 977–989, https://doi.org/10.5194/hess-24-977-2020, https://doi.org/10.5194/hess-24-977-2020, 2020
Short summary
Short summary
Fluorescent tracers such as uranine and sulforhodamine B are useful tools to gain knowledge about water and solute fluxes in aquatic and terrestrial ecosystems. In this study we systematically investigated the influence of important soil properties (pH, organic carbon content and texture) on tracer adsorption in soils and sediments. These properties also determine whether the tracers in the respective soil behave conservatively or non-conservatively.
Axel Schaffitel, Tobias Schuetz, and Markus Weiler
Earth Syst. Sci. Data, 12, 501–517, https://doi.org/10.5194/essd-12-501-2020, https://doi.org/10.5194/essd-12-501-2020, 2020
Short summary
Short summary
This paper contains detailed information about the instrumentation of permeable pavements with soil moisture sensors and the performance of infiltration experiments on these surfaces. The collected data are beneficial for studying urban water and energy cycles. They contain valuable information about the hydrological behavior of permeable pavements and urban subsurface heat anomalies. Due to the lack of similar data, we are convinced that the dataset is of great scientific value.
Clemens Messerschmid, Martin Sauter, and Jens Lange
Hydrol. Earth Syst. Sci., 24, 887–917, https://doi.org/10.5194/hess-24-887-2020, https://doi.org/10.5194/hess-24-887-2020, 2020
Short summary
Short summary
Recharge assessment in the shared transboundary Western Aquifer Basin is highly relevant, scientifically as well as hydropolitically (in Israeli–Palestinian water negotiations). Our unique combination of field-measured soil characteristics and soil moisture time series with soil moisture saturation excess modelling provides a new basis for the spatial differentiation of formation-specific groundwater recharge (at any scale), applicable also in other previously ungauged basins around the world.
Michael Stoelzle, Tobias Schuetz, Markus Weiler, Kerstin Stahl, and Lena M. Tallaksen
Hydrol. Earth Syst. Sci., 24, 849–867, https://doi.org/10.5194/hess-24-849-2020, https://doi.org/10.5194/hess-24-849-2020, 2020
Short summary
Short summary
During dry weather, different delayed sources of runoff (e.g. from groundwater, wetlands or snowmelt) modulate the magnitude and variability of streamflow. Hydrograph separation methods often do not distinguish these delayed contributions and mostly pool them into only two components (i.e. quickflow and baseflow). We propose a method that uncovers multiple components and demonstrates how they better reflect streamflow generation processes of different flow regimes.
Fabian Ries, Lara Kirn, and Markus Weiler
Earth Syst. Sci. Data, 12, 245–255, https://doi.org/10.5194/essd-12-245-2020, https://doi.org/10.5194/essd-12-245-2020, 2020
Short summary
Short summary
Pluvial or flash floods generated by heavy precipitation events cause large economic damage and loss of life worldwide. As discharge observations from such extreme occurrences are rare, data from artificial sprinkling experiments offer valuable information on runoff generation processes, overland and subsurface flow rates, and response times. A extensive data set from 132 large-scale sprinkling experiments in Germany is described and presented in this paper.
Elena Fernández-Pascual, Marcus Bork, Birte Hensen, and Jens Lange
Hydrol. Earth Syst. Sci., 24, 41–60, https://doi.org/10.5194/hess-24-41-2020, https://doi.org/10.5194/hess-24-41-2020, 2020
Short summary
Short summary
In this study we explore the use of hydrological tracers coupled with high vertical resolution sampling and monitoring to evaluate temporal and spatial mechanisms that dominate transport and dissipation of pesticides in a laboratory-scale constructed wetland. Our results reveal different transport vectors and dissipation pathways of solutes over time and space that are influenced by the constructional design, the presence of plants and the alternation of different hydrological conditions.
Dominic Demand, Theresa Blume, and Markus Weiler
Hydrol. Earth Syst. Sci., 23, 4869–4889, https://doi.org/10.5194/hess-23-4869-2019, https://doi.org/10.5194/hess-23-4869-2019, 2019
Short summary
Short summary
This study presents an analysis of 135 soil moisture profiles for identification of the spatial and temporal preferential flow occurrence in a complex landscape. Especially dry conditions and high rainfall intensities were found to increase preferential flow occurrence in soils. This results in a seasonal pattern of preferential flow with a higher occurrence in summer. During this time grasslands showed increased flow velocities, whereas forest sites exhibited a higher amount of bypass flow.
Nils Hinrich Kaplan, Ernestine Sohrt, Theresa Blume, and Markus Weiler
Earth Syst. Sci. Data, 11, 1363–1374, https://doi.org/10.5194/essd-11-1363-2019, https://doi.org/10.5194/essd-11-1363-2019, 2019
Short summary
Short summary
Different sensing techniques including time-lapse imagery, electric conductivity and stage measurements were used to generate a combined dataset of the presence and absence of streamflow within a large number of nested sub-catchments in the Attert catchment, Luxembourg. The first sites of observation were established in 2013 and successively extended to a total number of 182 in 2016. The dataset can be used to improve understanding of the temporal and spatial dynamics of the stream network.
Barbara Herbstritt, Benjamin Gralher, and Markus Weiler
Hydrol. Earth Syst. Sci., 23, 3007–3019, https://doi.org/10.5194/hess-23-3007-2019, https://doi.org/10.5194/hess-23-3007-2019, 2019
Short summary
Short summary
We describe a novel technique for the precise, quasi real-time observation of water-stable isotopes in gross precipitation and throughfall from tree canopies in parallel. Various processes (e.g. rainfall intensity, evapotranspiration, exchange with ambient vapour) thereby control throughfall intensity and isotopic composition. The achieved temporal resolution now competes with common meteorological measurements, thus enabling new ways to employ water-stable isotopes in forested catchments.
Marlène Lavrieux, Axel Birkholz, Katrin Meusburger, Guido L. B. Wiesenberg, Adrian Gilli, Christian Stamm, and Christine Alewell
Biogeosciences, 16, 2131–2146, https://doi.org/10.5194/bg-16-2131-2019, https://doi.org/10.5194/bg-16-2131-2019, 2019
Short summary
Short summary
A fingerprinting approach using compound-specific stable isotopes was applied to a lake sediment core to reconstruct erosion processes over the past 150 years in a Swiss catchment. Even though the reconstruction of land use and eutrophication history was successful, the observation of comparatively low δ13C values of plant-derived fatty acids in the sediment suggests their alteration within the lake. Thus, their use as a tool for source attribution in sediment cores needs further investigation.
Jobin Joseph, Christoph Külls, Matthias Arend, Marcus Schaub, Frank Hagedorn, Arthur Gessler, and Markus Weiler
SOIL, 5, 49–62, https://doi.org/10.5194/soil-5-49-2019, https://doi.org/10.5194/soil-5-49-2019, 2019
Short summary
Short summary
By coupling an OA-ICOS with hydrophobic but gas-permeable membranes placed at different depths in acidic and calcareous soils, we investigated the contribution of abiotic and biotic components to total soil CO2 release. In calcareous Gleysol, CO2 originating from carbonate dissolution contributed to total soil CO2 concentration at detectable degrees, probably due to CO2 evasion from groundwater. Inward diffusion of atmospheric CO2 was found to be pronounced in the topsoil layers at both sites.
Marcus Bork, Jens Lange, Markus Graf-Rosenfellner, and Friederike Lang
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2018-549, https://doi.org/10.5194/hess-2018-549, 2018
Manuscript not accepted for further review
Short summary
Short summary
Fluorescent tracers such as uranine and sulforhodamine B are useful tools to gain knowledge about water and solute fluxes in aquatic and terrestrial ecosystems. In batch experiments, we investigated systematically the influence of pH, organic carbon and texture on tracer adsorption on soils and sediments and quantified their impact and possible interactions. Overall, the investigated controls determine if the respective tracer shows more conservative or more non-conservative transport behaviour.
Mirko Mälicke, Sibylle K. Hassler, Markus Weiler, Theresa Blume, and Erwin Zehe
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2018-396, https://doi.org/10.5194/hess-2018-396, 2018
Manuscript not accepted for further review
Short summary
Short summary
In this study we use time dependent variograms to identify periods of organized soil moisture during drying. We could identify emerging spatial patterns which imply periods of terrestrial control on soil moisture organization. The coupling of time dependent variograms with density based clustering is a new approach to detect similarity in spatial patterns. The presented method is useful to describe states of organization and improve kriging workflows by extending their prerequisites.
Andreas Moser, Devon Wemyss, Ruth Scheidegger, Fabrizio Fenicia, Mark Honti, and Christian Stamm
Hydrol. Earth Syst. Sci., 22, 4229–4249, https://doi.org/10.5194/hess-22-4229-2018, https://doi.org/10.5194/hess-22-4229-2018, 2018
Short summary
Short summary
Many chemicals such as pesticides, pharmaceuticals or household chemicals impair water quality in many areas worldwide. Measuring pollution everywhere is too costly. Models can be used instead to predict where high pollution levels are expected. We tested a model that can be used across large river basins. We find that for the selected chemicals predictions are generally within a factor of 2 to 4 from observed concentrations. Often, knowledge about the chemical use limits the predictions.
Jana von Freyberg, Scott T. Allen, Stefan Seeger, Markus Weiler, and James W. Kirchner
Hydrol. Earth Syst. Sci., 22, 3841–3861, https://doi.org/10.5194/hess-22-3841-2018, https://doi.org/10.5194/hess-22-3841-2018, 2018
Short summary
Short summary
We explored how the fraction of streamflow younger than ca. 3 months (Fyw) varies with landscape characteristics and climatic forcing, using an extensive isotope data set from 22 Swiss catchments. Overall, Fyw tends to be larger when catchments are wet and discharge is correspondingly higher, indicating an increase in the proportional contribution of faster flow paths at higher flows. We quantify this
discharge sensitivityof Fyw and relate it to the dominant streamflow-generating mechanisms.
Natalie Orlowski, Lutz Breuer, Nicolas Angeli, Pascal Boeckx, Christophe Brumbt, Craig S. Cook, Maren Dubbert, Jens Dyckmans, Barbora Gallagher, Benjamin Gralher, Barbara Herbstritt, Pedro Hervé-Fernández, Christophe Hissler, Paul Koeniger, Arnaud Legout, Chandelle Joan Macdonald, Carlos Oyarzún, Regine Redelstein, Christof Seidler, Rolf Siegwolf, Christine Stumpp, Simon Thomsen, Markus Weiler, Christiane Werner, and Jeffrey J. McDonnell
Hydrol. Earth Syst. Sci., 22, 3619–3637, https://doi.org/10.5194/hess-22-3619-2018, https://doi.org/10.5194/hess-22-3619-2018, 2018
Short summary
Short summary
To extract water from soils for isotopic analysis, cryogenic water extraction is the most widely used removal technique. This work presents results from a worldwide laboratory intercomparison test of cryogenic extraction systems. Our results showed large differences in retrieved isotopic signatures among participating laboratories linked to interactions between soil type and properties, system setup, extraction efficiency, extraction system leaks, and each lab’s internal accuracy.
Jakob Sohrt, Heike Puhlmann, and Markus Weiler
SOIL Discuss., https://doi.org/10.5194/soil-2018-13, https://doi.org/10.5194/soil-2018-13, 2018
Revised manuscript not accepted
Short summary
Short summary
We sampled concentrations of phosphorus (P) in laterally flowing water in the organic layer of three beech forest sites. Sampling frequency was in the range to minutes to ours with the intent of capturing short term variability of this parameter and the underlying mechanisms, which were analyzed with a modeling approach. While site affiliation was found to be a strong influence on P concentrations in lateral flow, some universal effects – like antecedent soil moisture – could also be determined.
Daphné Freudiger, David Mennekes, Jan Seibert, and Markus Weiler
Earth Syst. Sci. Data, 10, 805–814, https://doi.org/10.5194/essd-10-805-2018, https://doi.org/10.5194/essd-10-805-2018, 2018
Short summary
Short summary
To understand glacier changes in the Swiss Alps at the large scale, long-term datasets are needed. To fill the gap between the existing glacier inventories of the Swiss Alps between 1850 and 1973, we digitized glacier outlines from topographic historical maps of Switzerland for the time periods ca. 1900 and ca. 1935. We found that > 88 % of the digitized glacier area was plausible compared to four inventories. The presented dataset is therefore valuable information for long-term glacier studies.
Michael P. Schwab, Julian Klaus, Laurent Pfister, and Markus Weiler
Biogeosciences, 15, 2177–2188, https://doi.org/10.5194/bg-15-2177-2018, https://doi.org/10.5194/bg-15-2177-2018, 2018
Short summary
Short summary
We studied the diel fluctuations of dissolved organic carbon (DOC) concentrations in a small stream in Luxembourg. We identified an increased proportion of DOC from terrestrial sources as responsible for the peaks in DOC in the afternoon. Warmer water temperatures in the riparian zone in the afternoon increased the amount of water flowing towards the stream. Consequently, an increased amount of DOC-rich water from the riparian zone was entering the stream.
Jan Seibert, Marc J. P. Vis, Irene Kohn, Markus Weiler, and Kerstin Stahl
Hydrol. Earth Syst. Sci., 22, 2211–2224, https://doi.org/10.5194/hess-22-2211-2018, https://doi.org/10.5194/hess-22-2211-2018, 2018
Short summary
Short summary
In many glacio-hydrological models glacier areas are assumed to be constant over time, which is a crucial limitation. Here we describe a novel approach to translate mass balances as simulated by the (glacio)hydrological model into glacier area changes. We combined the Δh approach of Huss et al. (2010) with the bucket-type model HBV and introduced a lookup table approach, which also allows periods with advancing glaciers to be represented, which is not possible with the original Huss method.
Sibylle Kathrin Hassler, Markus Weiler, and Theresa Blume
Hydrol. Earth Syst. Sci., 22, 13–30, https://doi.org/10.5194/hess-22-13-2018, https://doi.org/10.5194/hess-22-13-2018, 2018
Short summary
Short summary
We use sap velocity measurements from 61 trees on 132 days to gain knowledge about the controls of landscape-scale transpiration, distinguishing tree-, stand- and site-specific controls on sap velocity and sap flow patterns and examining their dynamics during the vegetation period. Our results show that these patterns are not exclusively determined by tree characteristics. Thus, including site characteristics such as geology and aspect could be beneficial for modelling or management purposes.
Willem J. van Verseveld, Holly R. Barnard, Chris B. Graham, Jeffrey J. McDonnell, J. Renée Brooks, and Markus Weiler
Hydrol. Earth Syst. Sci., 21, 5891–5910, https://doi.org/10.5194/hess-21-5891-2017, https://doi.org/10.5194/hess-21-5891-2017, 2017
Short summary
Short summary
How stream water responds immediately to a rainfall or snow event, while the average time it takes water to travel through the hillslope can be years or decades and is poorly understood. We assessed this difference by combining a 24-day sprinkler experiment (a tracer was applied at the start) with a process-based hydrologic model. Immobile soil water, deep groundwater contribution and soil depth variability explained this difference at our hillslope site.
Michael P. Schwab, Julian Klaus, Laurent Pfister, and Markus Weiler
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2017-416, https://doi.org/10.5194/hess-2017-416, 2017
Revised manuscript not accepted
Lisa Angermann, Conrad Jackisch, Niklas Allroggen, Matthias Sprenger, Erwin Zehe, Jens Tronicke, Markus Weiler, and Theresa Blume
Hydrol. Earth Syst. Sci., 21, 3727–3748, https://doi.org/10.5194/hess-21-3727-2017, https://doi.org/10.5194/hess-21-3727-2017, 2017
Short summary
Short summary
This study investigates the temporal dynamics and response velocities of lateral preferential flow at the hillslope. The results are compared to catchment response behavior to infer the large-scale implications of the observed processes. A large portion of mobile water flows through preferential flow paths in the structured soils, causing an immediate discharge response. The study presents a methodological approach to cover the spatial and temporal domain of these highly heterogeneous processes.
Conrad Jackisch, Lisa Angermann, Niklas Allroggen, Matthias Sprenger, Theresa Blume, Jens Tronicke, and Erwin Zehe
Hydrol. Earth Syst. Sci., 21, 3749–3775, https://doi.org/10.5194/hess-21-3749-2017, https://doi.org/10.5194/hess-21-3749-2017, 2017
Short summary
Short summary
Rapid subsurface flow in structured soils facilitates fast vertical and lateral redistribution of event water. We present its in situ exploration through local measurements and irrigation experiments. Special emphasis is given to a coherent combination of hydrological and geophysical methods. The study highlights that form and function operate as conjugated pairs. Dynamic imaging through time-lapse GPR was key to observing both and to identifying hydrologically relevant structures.
Mark Honti, Nele Schuwirth, Jörg Rieckermann, and Christian Stamm
Hydrol. Earth Syst. Sci., 21, 1593–1609, https://doi.org/10.5194/hess-21-1593-2017, https://doi.org/10.5194/hess-21-1593-2017, 2017
Short summary
Short summary
We present a new catchment model that covers most major pollutants and is suitable for uncertainty analysis. The effects of climate change, population dynamics, socio-economic development, and management strategies on water quality are demonstrated in a small catchment in the Swiss Plateau. Models and data are still the largest sources of uncertainty for some water quality parameters. Uncertainty assessment helps to select robust management and focus research and monitoring efforts.
Jens Lange, Tineke Materne, and Jörg Grüner
Drink. Water Eng. Sci., 9, 47–55, https://doi.org/10.5194/dwes-9-47-2016, https://doi.org/10.5194/dwes-9-47-2016, 2016
Short summary
Short summary
Here we investigate the suitability of a specific low-cost water filter for drinking water treatment in households of rural South Africa. Distributed in the field, none of 51 individually tested water filters produced water without distinct contamination, and more than one-third even deteriorated hygienic water quality. We therefore recommend frequent monitoring of the filter performance at the point of use and identify dip slides as an efficient tool to assess critical contamination.
Maik Renner, Sibylle K. Hassler, Theresa Blume, Markus Weiler, Anke Hildebrandt, Marcus Guderle, Stanislaus J. Schymanski, and Axel Kleidon
Hydrol. Earth Syst. Sci., 20, 2063–2083, https://doi.org/10.5194/hess-20-2063-2016, https://doi.org/10.5194/hess-20-2063-2016, 2016
Short summary
Short summary
We estimated forest transpiration (European beech) along a steep valley cross section. Atmospheric demand, obtained by the thermodynamic limit of maximum power, is the dominant control of transpiration at all sites.
To our surprise we find that transpiration is rather similar across sites with different aspect (north vs. south) and different stand structure due to systematically varying sap velocities. Such a compensation effect is highly relevant for modeling and upscaling of transpiration.
Katharina F. Gimbel, Heike Puhlmann, and Markus Weiler
Hydrol. Earth Syst. Sci., 20, 1301–1317, https://doi.org/10.5194/hess-20-1301-2016, https://doi.org/10.5194/hess-20-1301-2016, 2016
Short summary
Short summary
It is usually assumed that soil properties are not affected by drought events. We used dye tracer experiments to test this assumption on six forest soils, which were forced into drought conditions. The results of this study show clear evidence for changes in infiltration pathways. In addition, most soils developed soil water repellency. Overall, the results suggest that the past climatic conditions are more important than the actual soil moisture status regarding hydrophobicity and infiltration.
Tobias Schuetz, Chantal Gascuel-Odoux, Patrick Durand, and Markus Weiler
Hydrol. Earth Syst. Sci., 20, 843–857, https://doi.org/10.5194/hess-20-843-2016, https://doi.org/10.5194/hess-20-843-2016, 2016
Short summary
Short summary
We quantify the spatio-temporal impact of distinct nitrate sinks and sources on stream network nitrate dynamics in an agricultural headwater. By applying a data-driven modelling approach, we are able to fully distinguish between mixing and dilution processes, and biogeochemical in-stream removal processes along the stream network. In-stream nitrate removal is estimated by applying a novel transfer coefficient based on energy availability.
A. Hartmann, J. Kobler, M. Kralik, T. Dirnböck, F. Humer, and M. Weiler
Biogeosciences, 13, 159–174, https://doi.org/10.5194/bg-13-159-2016, https://doi.org/10.5194/bg-13-159-2016, 2016
Short summary
Short summary
We consider the time period before and after a wind disturbance in an Austrian karst system. Using a process-based flow and solute transport simulation model we estimate impacts on DIN and DOC. We show that DIN increases for several years, while DOC remains within its pre-disturbance variability. Simulated transit times indicate that impact passes through the hydrological system within some months but with a small fraction exceeding transit times of even a year.
M. Sprenger, T. H. M. Volkmann, T. Blume, and M. Weiler
Hydrol. Earth Syst. Sci., 19, 2617–2635, https://doi.org/10.5194/hess-19-2617-2015, https://doi.org/10.5194/hess-19-2617-2015, 2015
Short summary
Short summary
We present a novel approach that includes information about the pore water stable isotopic composition in inverse model approaches to estimate soil hydraulic parameters. Different approaches are presented and their adequacy regarding the model efficiency, realism and parameter identifiability are discussed. The advantages of the new approach are shown by an application of the inverse estimated parameters to infer the water balance and the transit time for three different study sites.
F. Ries, J. Lange, S. Schmidt, H. Puhlmann, and M. Sauter
Hydrol. Earth Syst. Sci., 19, 1439–1456, https://doi.org/10.5194/hess-19-1439-2015, https://doi.org/10.5194/hess-19-1439-2015, 2015
Short summary
Short summary
Soil moisture was observed along a strong semi-arid climatic gradient in a Mediterranean karst area. Soil moisture data and soil hydraulic modelling with Hydrus-1D revealed a strong dependency of percolation fluxes with rainfall amounts and intensity during heavy rainfall events. Spatial and temporal extrapolation of the model illustrated the high variability of seasonal percolation amounts among single years and showed strong correlations between soil depth and potential groundwater recharge.
M. Staudinger, M. Weiler, and J. Seibert
Hydrol. Earth Syst. Sci., 19, 1371–1384, https://doi.org/10.5194/hess-19-1371-2015, https://doi.org/10.5194/hess-19-1371-2015, 2015
K. F. Gimbel, K. Felsmann, M. Baudis, H. Puhlmann, A. Gessler, H. Bruelheide, Z. Kayler, R. H. Ellerbrock, A. Ulrich, E. Welk, and M. Weiler
Biogeosciences, 12, 961–975, https://doi.org/10.5194/bg-12-961-2015, https://doi.org/10.5194/bg-12-961-2015, 2015
Short summary
Short summary
This paper introduces a novel rainfall reduction experiment to investigate drought effects on soil-forest-understory-ecosystems. An annual drought with a return period of 40 years was imposed, while other ecosystem variables (humidity, air & soil temperature) remained unaffected. The first year of drought showed considerable changes in soil moisture dynamics, which affected leaf stomatal conductance of understory species as well as evapotranspiration rates of the forest understory ecosystem.
S. Seeger and M. Weiler
Hydrol. Earth Syst. Sci., 18, 4751–4771, https://doi.org/10.5194/hess-18-4751-2014, https://doi.org/10.5194/hess-18-4751-2014, 2014
E. Zehe, U. Ehret, L. Pfister, T. Blume, B. Schröder, M. Westhoff, C. Jackisch, S. J. Schymanski, M. Weiler, K. Schulz, N. Allroggen, J. Tronicke, L. van Schaik, P. Dietrich, U. Scherer, J. Eccard, V. Wulfmeyer, and A. Kleidon
Hydrol. Earth Syst. Sci., 18, 4635–4655, https://doi.org/10.5194/hess-18-4635-2014, https://doi.org/10.5194/hess-18-4635-2014, 2014
J. Schwerdtfeger, M. S. Johnson, E. G. Couto, R. S. S. Amorim, L. Sanches, J. H. Campelo Jr., and M. Weiler
Hydrol. Earth Syst. Sci., 18, 4407–4422, https://doi.org/10.5194/hess-18-4407-2014, https://doi.org/10.5194/hess-18-4407-2014, 2014
T. Doppler, M. Honti, U. Zihlmann, P. Weisskopf, and C. Stamm
Hydrol. Earth Syst. Sci., 18, 3481–3498, https://doi.org/10.5194/hess-18-3481-2014, https://doi.org/10.5194/hess-18-3481-2014, 2014
M. Honti, A. Scheidegger, and C. Stamm
Hydrol. Earth Syst. Sci., 18, 3301–3317, https://doi.org/10.5194/hess-18-3301-2014, https://doi.org/10.5194/hess-18-3301-2014, 2014
C. Hahn, V. Prasuhn, C. Stamm, D. G. Milledge, and R. Schulin
Hydrol. Earth Syst. Sci., 18, 2975–2991, https://doi.org/10.5194/hess-18-2975-2014, https://doi.org/10.5194/hess-18-2975-2014, 2014
B. Merz, J. Aerts, K. Arnbjerg-Nielsen, M. Baldi, A. Becker, A. Bichet, G. Blöschl, L. M. Bouwer, A. Brauer, F. Cioffi, J. M. Delgado, M. Gocht, F. Guzzetti, S. Harrigan, K. Hirschboeck, C. Kilsby, W. Kron, H.-H. Kwon, U. Lall, R. Merz, K. Nissen, P. Salvatti, T. Swierczynski, U. Ulbrich, A. Viglione, P. J. Ward, M. Weiler, B. Wilhelm, and M. Nied
Nat. Hazards Earth Syst. Sci., 14, 1921–1942, https://doi.org/10.5194/nhess-14-1921-2014, https://doi.org/10.5194/nhess-14-1921-2014, 2014
D. Freudiger, I. Kohn, K. Stahl, and M. Weiler
Hydrol. Earth Syst. Sci., 18, 2695–2709, https://doi.org/10.5194/hess-18-2695-2014, https://doi.org/10.5194/hess-18-2695-2014, 2014
R. S. Smith, R. D. Moore, M. Weiler, and G. Jost
Hydrol. Earth Syst. Sci., 18, 1835–1856, https://doi.org/10.5194/hess-18-1835-2014, https://doi.org/10.5194/hess-18-1835-2014, 2014
T. H. M. Volkmann and M. Weiler
Hydrol. Earth Syst. Sci., 18, 1819–1833, https://doi.org/10.5194/hess-18-1819-2014, https://doi.org/10.5194/hess-18-1819-2014, 2014
C. Hahn, V. Prasuhn, C. Stamm, P. Lazzarotto, M. W. H. Evangelou, and R. Schulin
Hydrol. Earth Syst. Sci., 17, 3679–3693, https://doi.org/10.5194/hess-17-3679-2013, https://doi.org/10.5194/hess-17-3679-2013, 2013
A. Hartmann, M. Weiler, T. Wagener, J. Lange, M. Kralik, F. Humer, N. Mizyed, A. Rimmer, J. A. Barberá, B. Andreo, C. Butscher, and P. Huggenberger
Hydrol. Earth Syst. Sci., 17, 3305–3321, https://doi.org/10.5194/hess-17-3305-2013, https://doi.org/10.5194/hess-17-3305-2013, 2013
N. Dietermann and M. Weiler
Hydrol. Earth Syst. Sci., 17, 2657–2668, https://doi.org/10.5194/hess-17-2657-2013, https://doi.org/10.5194/hess-17-2657-2013, 2013
J. Garvelmann, S. Pohl, and M. Weiler
Hydrol. Earth Syst. Sci., 17, 1415–1429, https://doi.org/10.5194/hess-17-1415-2013, https://doi.org/10.5194/hess-17-1415-2013, 2013
M. Stoelzle, K. Stahl, and M. Weiler
Hydrol. Earth Syst. Sci., 17, 817–828, https://doi.org/10.5194/hess-17-817-2013, https://doi.org/10.5194/hess-17-817-2013, 2013
Related subject area
Subject: Catchment hydrology | Techniques and Approaches: Modelling approaches
On the use of streamflow transformations for hydrological model calibration
Simulation-based inference for parameter estimation of complex watershed simulators
Multi-scale soil moisture data and process-based modeling reveal the importance of lateral groundwater flow in a subarctic catchment
Catchment response to climatic variability: implications for root zone storage and streamflow predictions
Hybrid hydrological modeling for large alpine basins: a semi-distributed approach
Karst aquifer discharge response to rainfall interpreted as anomalous transport
HESS Opinions: Never train a Long Short-Term Memory (LSTM) network on a single basin
Large-sample hydrology – a few camels or a whole caravan?
Comment on “Are soils overrated in hydrology?” by Gao et al. (2023)
Multi-decadal fluctuations in root zone storage capacity through vegetation adaptation to hydro-climatic variability have minor effects on the hydrological response in the Neckar River basin, Germany
Projected future changes in the cryosphere and hydrology of a mountainous catchment in the upper Heihe River, China
On the importance of plant phenology in the evaporative process of a semi-arid woodland: could it be why satellite-based evaporation estimates in the miombo differ?
Regionalization of GR4J model parameters for river flow prediction in Paraná, Brazil
Evolution of river regimes in the Mekong River basin over 8 decades and the role of dams in recent hydrological extremes
Skill of seasonal flow forecasts at catchment scale: an assessment across South Korea
To what extent do flood-inducing storm events change future flood hazards?
When ancient numerical demons meet physics-informed machine learning: adjoint-based gradients for implicit differentiable modeling
Assessing the impact of climate change on high return levels of peak flows in Bavaria applying the CRCM5 large ensemble
Impacts of climate and land surface change on catchment evapotranspiration and runoff from 1951 to 2020 in Saxony, Germany
Quantifying and reducing flood forecast uncertainty by the CHUP-BMA method
Developing a tile drainage module for the Cold Regions Hydrological Model: lessons from a farm in southern Ontario, Canada
To bucket or not to bucket? Analyzing the performance and interpretability of hybrid hydrological models with dynamic parameterization
Widespread flooding dynamics under climate change: characterising floods using grid-based hydrological modelling and regional climate projections
HESS Opinions: The sword of Damocles of the impossible flood
Metamorphic testing of machine learning and conceptual hydrologic models
The influence of human activities on streamflow reductions during the megadrought in central Chile
Elevational control of isotopic composition and application in understanding hydrologic processes in the mid Merced River catchment, Sierra Nevada, California, USA
Lack of robustness of hydrological models: A large-sample diagnosis and an attempt to identify the hydrological and climatic drivers
The Significance of the Leaf-Area-Index on the Evapotranspiration Estimation in SWAT-T for Characteristic Land Cover Types of Western Africa
Enhancing long short-term memory (LSTM)-based streamflow prediction with a spatially distributed approach
Broadleaf afforestation impacts on terrestrial hydrology insignificant compared to climate change in Great Britain
Impacts of spatiotemporal resolutions of precipitation on flood event simulation based on multimodel structures – a case study over the Xiang River basin in China
A network approach for multiscale catchment classification using traits
Multi-model approach in a variable spatial framework for streamflow simulation
Advancing understanding of lake–watershed hydrology: a fully coupled numerical model illustrated by Qinghai Lake
Technical note: Testing the connection between hillslope-scale runoff fluctuations and streamflow hydrographs at the outlet of large river basins
Empirical stream thermal sensitivity cluster on the landscape according to geology and climate
Deep learning for monthly rainfall–runoff modelling: a large-sample comparison with conceptual models across Australia
A large-sample modelling approach towards integrating streamflow and evaporation data for the Spanish catchments
On optimization of calibrations of a distributed hydrological model with spatially distributed information on snow
Toward interpretable LSTM-based modeling of hydrological systems
Flow intermittence prediction using a hybrid hydrological modelling approach: influence of observed intermittence data on the training of a random forest model
What controls the tail behaviour of flood series: rainfall or runoff generation?
Learning Landscape Features from Streamflow with Autoencoders
Seasonal prediction of end-of-dry-season watershed behavior in a highly interconnected alluvial watershed in northern California
Glaciers determine the sensitivity of hydrological processes to perturbed climate in a large mountainous basin on the Tibetan Plateau
Leveraging gauge networks and strategic discharge measurements to aid the development of continuous streamflow records
On the need for physical constraints in deep learning rainfall–runoff projections under climate change: a sensitivity analysis to warming and shifts in potential evapotranspiration
Evaluation of hydrological models on small mountainous catchments: impact of the meteorological forcings
Projecting sediment export from two highly glacierized alpine catchments under climate change: exploring non-parametric regression as an analysis tool
Guillaume Thirel, Léonard Santos, Olivier Delaigue, and Charles Perrin
Hydrol. Earth Syst. Sci., 28, 4837–4860, https://doi.org/10.5194/hess-28-4837-2024, https://doi.org/10.5194/hess-28-4837-2024, 2024
Short summary
Short summary
We discuss how mathematical transformations impact calibrated hydrological model simulations. We assess how 11 transformations behave over the complete range of streamflows. Extreme transformations lead to models that are specialized for extreme streamflows but show poor performance outside the range of targeted streamflows and are less robust. We show that no a priori assumption about transformations can be taken as warranted.
Robert Hull, Elena Leonarduzzi, Luis De La Fuente, Hoang Viet Tran, Andrew Bennett, Peter Melchior, Reed M. Maxwell, and Laura E. Condon
Hydrol. Earth Syst. Sci., 28, 4685–4713, https://doi.org/10.5194/hess-28-4685-2024, https://doi.org/10.5194/hess-28-4685-2024, 2024
Short summary
Short summary
Large-scale hydrologic simulators are a needed tool to explore complex watershed processes and how they may evolve with a changing climate. However, calibrating them can be difficult because they are costly to run and have many unknown parameters. We implement a state-of-the-art approach to model calibration using neural networks with a set of experiments based on streamflow in the upper Colorado River basin.
Jari-Pekka Nousu, Kersti Leppä, Hannu Marttila, Pertti Ala-aho, Giulia Mazzotti, Terhikki Manninen, Mika Korkiakoski, Mika Aurela, Annalea Lohila, and Samuli Launiainen
Hydrol. Earth Syst. Sci., 28, 4643–4666, https://doi.org/10.5194/hess-28-4643-2024, https://doi.org/10.5194/hess-28-4643-2024, 2024
Short summary
Short summary
We used hydrological models, field measurements, and satellite-based data to study the soil moisture dynamics in a subarctic catchment. The role of groundwater was studied with different ways to model the groundwater dynamics and via comparisons to the observational data. The choice of groundwater model was shown to have a strong impact, and representation of lateral flow was important to capture wet soil conditions. Our results provide insights for ecohydrological studies in boreal regions.
Nienke Tempel, Laurène Bouaziz, Riccardo Taormina, Ellis van Noppen, Jasper Stam, Eric Sprokkereef, and Markus Hrachowitz
Hydrol. Earth Syst. Sci., 28, 4577–4597, https://doi.org/10.5194/hess-28-4577-2024, https://doi.org/10.5194/hess-28-4577-2024, 2024
Short summary
Short summary
This study explores the impact of climatic variability on root zone water storage capacities and, thus, on hydrological predictions. Analysing data from 286 areas in Europe and the US, we found that, despite some variations in root zone storage capacity due to changing climatic conditions over multiple decades, these changes are generally minor and have a limited effect on water storage and river flow predictions.
Bu Li, Ting Sun, Fuqiang Tian, Mahmut Tudaji, Li Qin, and Guangheng Ni
Hydrol. Earth Syst. Sci., 28, 4521–4538, https://doi.org/10.5194/hess-28-4521-2024, https://doi.org/10.5194/hess-28-4521-2024, 2024
Short summary
Short summary
This paper developed hybrid semi-distributed hydrological models by employing a process-based model as the backbone and utilizing deep learning to parameterize and replace internal modules. The main contribution is to provide a high-performance tool enriched with explicit hydrological knowledge for hydrological prediction and to improve understanding about the hydrological sensitivities to climate change in large alpine basins.
Dan Elhanati, Nadine Goeppert, and Brian Berkowitz
Hydrol. Earth Syst. Sci., 28, 4239–4249, https://doi.org/10.5194/hess-28-4239-2024, https://doi.org/10.5194/hess-28-4239-2024, 2024
Short summary
Short summary
A continuous time random walk framework was developed to allow modeling of a karst aquifer discharge response to measured rainfall. The application of the numerical model yielded robust fits between modeled and measured discharge values, especially for the distinctive long tails found during recession times. The findings shed light on the interplay of slow and fast flow in the karst system and establish the application of the model for simulating flow and transport in such systems.
Frederik Kratzert, Martin Gauch, Daniel Klotz, and Grey Nearing
Hydrol. Earth Syst. Sci., 28, 4187–4201, https://doi.org/10.5194/hess-28-4187-2024, https://doi.org/10.5194/hess-28-4187-2024, 2024
Short summary
Short summary
Recently, a special type of neural-network architecture became increasingly popular in hydrology literature. However, in most applications, this model was applied as a one-to-one replacement for hydrology models without adapting or rethinking the experimental setup. In this opinion paper, we show how this is almost always a bad decision and how using these kinds of models requires the use of large-sample hydrology data sets.
Franziska Clerc-Schwarzenbach, Giovanni Selleri, Mattia Neri, Elena Toth, Ilja van Meerveld, and Jan Seibert
Hydrol. Earth Syst. Sci., 28, 4219–4237, https://doi.org/10.5194/hess-28-4219-2024, https://doi.org/10.5194/hess-28-4219-2024, 2024
Short summary
Short summary
We show that the differences between the forcing data included in three CAMELS datasets (US, BR, GB) and the forcing data included for the same catchments in the Caravan dataset affect model calibration considerably. The model performance dropped when the data from the Caravan dataset were used instead of the original data. Most of the model performance drop could be attributed to the differences in precipitation data. However, differences were largest for the potential evapotranspiration data.
Ying Zhao, Mehdi Rahmati, Harry Vereecken, and Dani Or
Hydrol. Earth Syst. Sci., 28, 4059–4063, https://doi.org/10.5194/hess-28-4059-2024, https://doi.org/10.5194/hess-28-4059-2024, 2024
Short summary
Short summary
Gao et al. (2023) question the importance of soil in hydrology, sparking debate. We acknowledge some valid points but critique their broad, unsubstantiated views on soil's role. Our response highlights three key areas: (1) the false divide between ecosystem-centric and soil-centric approaches, (2) the vital yet varied impact of soil properties, and (3) the call for a scale-aware framework. We aim to unify these perspectives, enhancing hydrology's comprehensive understanding.
Siyuan Wang, Markus Hrachowitz, and Gerrit Schoups
Hydrol. Earth Syst. Sci., 28, 4011–4033, https://doi.org/10.5194/hess-28-4011-2024, https://doi.org/10.5194/hess-28-4011-2024, 2024
Short summary
Short summary
Root zone storage capacity (Sumax) changes significantly over multiple decades, reflecting vegetation adaptation to climatic variability. However, this temporal evolution of Sumax cannot explain long-term fluctuations in the partitioning of water fluxes as expressed by deviations ΔIE from the parametric Budyko curve over time with different climatic conditions, and it does not have any significant effects on shorter-term hydrological response characteristics of the upper Neckar catchment.
Zehua Chang, Hongkai Gao, Leilei Yong, Kang Wang, Rensheng Chen, Chuntan Han, Otgonbayar Demberel, Batsuren Dorjsuren, Shugui Hou, and Zheng Duan
Hydrol. Earth Syst. Sci., 28, 3897–3917, https://doi.org/10.5194/hess-28-3897-2024, https://doi.org/10.5194/hess-28-3897-2024, 2024
Short summary
Short summary
An integrated cryospheric–hydrologic model, FLEX-Cryo, was developed that considers glaciers, snow cover, and frozen soil and their dynamic impacts on hydrology. We utilized it to simulate future changes in cryosphere and hydrology in the Hulu catchment. Our projections showed the two glaciers will melt completely around 2050, snow cover will reduce, and permafrost will degrade. For hydrology, runoff will decrease after the glacier has melted, and permafrost degradation will increase baseflow.
Henry M. Zimba, Miriam Coenders-Gerrits, Kawawa E. Banda, Petra Hulsman, Nick van de Giesen, Imasiku A. Nyambe, and Hubert H. G. Savenije
Hydrol. Earth Syst. Sci., 28, 3633–3663, https://doi.org/10.5194/hess-28-3633-2024, https://doi.org/10.5194/hess-28-3633-2024, 2024
Short summary
Short summary
The fall and flushing of new leaves in the miombo woodlands co-occur in the dry season before the commencement of seasonal rainfall. The miombo species are also said to have access to soil moisture in deep soils, including groundwater in the dry season. Satellite-based evaporation estimates, temporal trends, and magnitudes differ the most in the dry season, most likely due to inadequate understanding and representation of the highlighted miombo species attributes in simulations.
Louise Akemi Kuana, Arlan Scortegagna Almeida, Emílio Graciliano Ferreira Mercuri, and Steffen Manfred Noe
Hydrol. Earth Syst. Sci., 28, 3367–3390, https://doi.org/10.5194/hess-28-3367-2024, https://doi.org/10.5194/hess-28-3367-2024, 2024
Short summary
Short summary
The authors compared regionalization methods for river flow prediction in 126 catchments from the south of Brazil, a region with humid subtropical and hot temperate climate. The regionalization method based on physiographic–climatic similarity had the best performance for predicting daily and Q95 reference flow. We showed that basins without flow monitoring can have a good approximation of streamflow using machine learning and physiographic–climatic information as inputs.
Huy Dang and Yadu Pokhrel
Hydrol. Earth Syst. Sci., 28, 3347–3365, https://doi.org/10.5194/hess-28-3347-2024, https://doi.org/10.5194/hess-28-3347-2024, 2024
Short summary
Short summary
By examining basin-wide simulations of a river regime over 83 years with and without dams, we present evidence that climate variation was a key driver of hydrologic variabilities in the Mekong River basin (MRB) over the long term; however, dams have largely altered the seasonality of the Mekong’s flow regime and annual flooding patterns in major downstream areas in recent years. These findings could help us rethink the planning of future dams and water resource management in the MRB.
Yongshin Lee, Francesca Pianosi, Andres Peñuela, and Miguel Angel Rico-Ramirez
Hydrol. Earth Syst. Sci., 28, 3261–3279, https://doi.org/10.5194/hess-28-3261-2024, https://doi.org/10.5194/hess-28-3261-2024, 2024
Short summary
Short summary
Following recent advancements in weather prediction technology, we explored how seasonal weather forecasts (1 or more months ahead) could benefit practical water management in South Korea. Our findings highlight that using seasonal weather forecasts for predicting flow patterns 1 to 3 months ahead is effective, especially during dry years. This suggest that seasonal weather forecasts can be helpful in improving the management of water resources.
Mariam Khanam, Giulia Sofia, and Emmanouil N. Anagnostou
Hydrol. Earth Syst. Sci., 28, 3161–3190, https://doi.org/10.5194/hess-28-3161-2024, https://doi.org/10.5194/hess-28-3161-2024, 2024
Short summary
Short summary
Flooding worsens due to climate change, with river dynamics being a key in local flood control. Predicting post-storm geomorphic changes is challenging. Using self-organizing maps and machine learning, this study forecasts post-storm alterations in stage–discharge relationships across 3101 US stream gages. The provided framework can aid in updating hazard assessments by identifying rivers prone to change, integrating channel adjustments into flood hazard assessment.
Yalan Song, Wouter J. M. Knoben, Martyn P. Clark, Dapeng Feng, Kathryn Lawson, Kamlesh Sawadekar, and Chaopeng Shen
Hydrol. Earth Syst. Sci., 28, 3051–3077, https://doi.org/10.5194/hess-28-3051-2024, https://doi.org/10.5194/hess-28-3051-2024, 2024
Short summary
Short summary
Differentiable models (DMs) integrate neural networks and physical equations for accuracy, interpretability, and knowledge discovery. We developed an adjoint-based DM for ordinary differential equations (ODEs) for hydrological modeling, reducing distorted fluxes and physical parameters from errors in models that use explicit and operation-splitting schemes. With a better numerical scheme and improved structure, the adjoint-based DM matches or surpasses long short-term memory (LSTM) performance.
Florian Willkofer, Raul R. Wood, and Ralf Ludwig
Hydrol. Earth Syst. Sci., 28, 2969–2989, https://doi.org/10.5194/hess-28-2969-2024, https://doi.org/10.5194/hess-28-2969-2024, 2024
Short summary
Short summary
Severe flood events pose a threat to riverine areas, yet robust estimates of the dynamics of these events in the future due to climate change are rarely available. Hence, this study uses data from a regional climate model, SMILE, to drive a high-resolution hydrological model for 98 catchments of hydrological Bavaria and exploits the large database to derive robust values for the 100-year flood events. Results indicate an increase in frequency and intensity for most catchments in the future.
Maik Renner and Corina Hauffe
Hydrol. Earth Syst. Sci., 28, 2849–2869, https://doi.org/10.5194/hess-28-2849-2024, https://doi.org/10.5194/hess-28-2849-2024, 2024
Short summary
Short summary
Climate and land surface changes influence the partitioning of water balance components decisively. Their impact is quantified for 71 catchments in Saxony. Germany. Distinct signatures in the joint water and energy budgets are found: (i) past forest dieback caused a decrease in and subsequent recovery of evapotranspiration in the affected regions, and (ii) the recent shift towards higher aridity imposed a large decline in runoff that has not been seen in the observation records before.
Zhen Cui, Shenglian Guo, Hua Chen, Dedi Liu, Yanlai Zhou, and Chong-Yu Xu
Hydrol. Earth Syst. Sci., 28, 2809–2829, https://doi.org/10.5194/hess-28-2809-2024, https://doi.org/10.5194/hess-28-2809-2024, 2024
Short summary
Short summary
Ensemble forecasting facilitates reliable flood forecasting and warning. This study couples the copula-based hydrologic uncertainty processor (CHUP) with Bayesian model averaging (BMA) and proposes the novel CHUP-BMA method of reducing inflow forecasting uncertainty of the Three Gorges Reservoir. The CHUP-BMA avoids the normal distribution assumption in the HUP-BMA and considers the constraint of initial conditions, which can improve the deterministic and probabilistic forecast performance.
Mazda Kompanizare, Diogo Costa, Merrin L. Macrae, John W. Pomeroy, and Richard M. Petrone
Hydrol. Earth Syst. Sci., 28, 2785–2807, https://doi.org/10.5194/hess-28-2785-2024, https://doi.org/10.5194/hess-28-2785-2024, 2024
Short summary
Short summary
A new agricultural tile drainage module was developed in the Cold Region Hydrological Model platform. Tile flow and water levels are simulated by considering the effect of capillary fringe thickness, drainable water and seasonal regional groundwater dynamics. The model was applied to a small well-instrumented farm in southern Ontario, Canada, where there are concerns about the impacts of agricultural drainage into Lake Erie.
Eduardo Acuña Espinoza, Ralf Loritz, Manuel Álvarez Chaves, Nicole Bäuerle, and Uwe Ehret
Hydrol. Earth Syst. Sci., 28, 2705–2719, https://doi.org/10.5194/hess-28-2705-2024, https://doi.org/10.5194/hess-28-2705-2024, 2024
Short summary
Short summary
Hydrological hybrid models promise to merge the performance of deep learning methods with the interpretability of process-based models. One hybrid approach is the dynamic parameterization of conceptual models using long short-term memory (LSTM) networks. We explored this method to evaluate the effect of the flexibility given by LSTMs on the process-based part.
Adam Griffin, Alison L. Kay, Paul Sayers, Victoria Bell, Elizabeth Stewart, and Sam Carr
Hydrol. Earth Syst. Sci., 28, 2635–2650, https://doi.org/10.5194/hess-28-2635-2024, https://doi.org/10.5194/hess-28-2635-2024, 2024
Short summary
Short summary
Widespread flooding is a major problem in the UK and is greatly affected by climate change and land-use change. To look at how widespread flooding changes in the future, climate model data (UKCP18) were used with a hydrological model (Grid-to-Grid) across the UK, and 14 400 events were identified between two time slices: 1980–2010 and 2050–2080. There was a strong increase in the number of winter events in the future time slice and in the peak return periods.
Alberto Montanari, Bruno Merz, and Günter Blöschl
Hydrol. Earth Syst. Sci., 28, 2603–2615, https://doi.org/10.5194/hess-28-2603-2024, https://doi.org/10.5194/hess-28-2603-2024, 2024
Short summary
Short summary
Floods often take communities by surprise, as they are often considered virtually
impossibleyet are an ever-present threat similar to the sword suspended over the head of Damocles in the classical Greek anecdote. We discuss four reasons why extremely large floods carry a risk that is often larger than expected. We provide suggestions for managing the risk of megafloods by calling for a creative exploration of hazard scenarios and communicating the unknown corners of the reality of floods.
Peter Reichert, Kai Ma, Marvin Höge, Fabrizio Fenicia, Marco Baity-Jesi, Dapeng Feng, and Chaopeng Shen
Hydrol. Earth Syst. Sci., 28, 2505–2529, https://doi.org/10.5194/hess-28-2505-2024, https://doi.org/10.5194/hess-28-2505-2024, 2024
Short summary
Short summary
We compared the predicted change in catchment outlet discharge to precipitation and temperature change for conceptual and machine learning hydrological models. We found that machine learning models, despite providing excellent fit and prediction capabilities, can be unreliable regarding the prediction of the effect of temperature change for low-elevation catchments. This indicates the need for caution when applying them for the prediction of the effect of climate change.
Nicolás Álamos, Camila Alvarez-Garreton, Ariel Muñoz, and Álvaro González-Reyes
Hydrol. Earth Syst. Sci., 28, 2483–2503, https://doi.org/10.5194/hess-28-2483-2024, https://doi.org/10.5194/hess-28-2483-2024, 2024
Short summary
Short summary
In this study, we assess the effects of climate and water use on streamflow reductions and drought intensification during the last 3 decades in central Chile. We address this by contrasting streamflow observations with near-natural streamflow simulations. We conclude that while the lack of precipitation dominates streamflow reductions in the megadrought, water uses have not diminished during this time, causing a worsening of the hydrological drought conditions and maladaptation conditions.
Fengjing Liu, Martha H. Conklin, and Glenn D. Shaw
Hydrol. Earth Syst. Sci., 28, 2239–2258, https://doi.org/10.5194/hess-28-2239-2024, https://doi.org/10.5194/hess-28-2239-2024, 2024
Short summary
Short summary
Mountain snowpack has been declining and more precipitation falls as rain than snow. Using stable isotopes, we found flows and flow duration in Yosemite Creek are most sensitive to climate warming due to strong evaporation of waterfalls, potentially lengthening the dry-up period of waterfalls in summer and negatively affecting tourism. Groundwater recharge in Yosemite Valley is primarily from the upper snow–rain transition (2000–2500 m) and very vulnerable to a reduction in the snow–rain ratio.
Léonard Santos, Vazken Andréassian, Torben O. Sonnenborg, Göran Lindström, Alban de Lavenne, Charles Perrin, Lila Collet, and Guillaume Thirel
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2024-80, https://doi.org/10.5194/hess-2024-80, 2024
Revised manuscript accepted for HESS
Short summary
Short summary
This work aims at investigating how hydrological models can be transferred to a period in which climatic conditions are different to the ones of the period in which it was set up. The RAT method, built to detect dependencies between model error and climatic drivers, was applied to 3 different hydrological models on 352 catchments in Denmark, France and Sweden. Potential issues are detected for a significant number of catchments for the 3 models even though these catchments differ for each model.
Fabian Merk, Timo Schaffhauser, Faizan Anwar, Ye Tuo, Jean-Martial Cohard, and Markus Disse
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2024-131, https://doi.org/10.5194/hess-2024-131, 2024
Revised manuscript accepted for HESS
Short summary
Short summary
ET is computed from vegetation (plant transpiration) and soil (soil evaporation). In Western Africa, plant transpiration correlates with vegetation growth. Vegetation is often represented with the leaf-area-index (LAI). In this study, we evaluate the importance of LAI for the ET calculation. We take a close look at the LAI-ET interaction and show the relevance to consider both, LAI and ET. Our work contributes to the understanding of the processes of the terrestrial water cycle.
Qiutong Yu, Bryan A. Tolson, Hongren Shen, Ming Han, Juliane Mai, and Jimmy Lin
Hydrol. Earth Syst. Sci., 28, 2107–2122, https://doi.org/10.5194/hess-28-2107-2024, https://doi.org/10.5194/hess-28-2107-2024, 2024
Short summary
Short summary
It is challenging to incorporate input variables' spatial distribution information when implementing long short-term memory (LSTM) models for streamflow prediction. This work presents a novel hybrid modelling approach to predict streamflow while accounting for spatial variability. We evaluated the performance against lumped LSTM predictions in 224 basins across the Great Lakes region in North America. This approach shows promise for predicting streamflow in large, ungauged basin.
Marcus Buechel, Louise Slater, and Simon Dadson
Hydrol. Earth Syst. Sci., 28, 2081–2105, https://doi.org/10.5194/hess-28-2081-2024, https://doi.org/10.5194/hess-28-2081-2024, 2024
Short summary
Short summary
Afforestation has been proposed internationally, but the hydrological implications of such large increases in the spatial extent of woodland are not fully understood. In this study, we use a land surface model to simulate hydrology across Great Britain with realistic afforestation scenarios and potential climate changes. Countrywide afforestation minimally influences hydrology, when compared to climate change, and reduces low streamflow whilst not lowering the highest flows.
Qian Zhu, Xiaodong Qin, Dongyang Zhou, Tiantian Yang, and Xinyi Song
Hydrol. Earth Syst. Sci., 28, 1665–1686, https://doi.org/10.5194/hess-28-1665-2024, https://doi.org/10.5194/hess-28-1665-2024, 2024
Short summary
Short summary
Input data, model and calibration strategy can affect the accuracy of flood event simulation and prediction. Satellite-based precipitation with different spatiotemporal resolutions is an important input source. Data-driven models are sometimes proven to be more accurate than hydrological models. Event-based calibration and conventional strategy are two options adopted for flood simulation. This study targets the three concerns for accurate flood event simulation and prediction.
Fabio Ciulla and Charuleka Varadharajan
Hydrol. Earth Syst. Sci., 28, 1617–1651, https://doi.org/10.5194/hess-28-1617-2024, https://doi.org/10.5194/hess-28-1617-2024, 2024
Short summary
Short summary
We present a new method based on network science for unsupervised classification of large datasets and apply it to classify 9067 US catchments and 274 biophysical traits at multiple scales. We find that our trait-based approach produces catchment classes with distinct streamflow behavior and that spatial patterns emerge amongst pristine and human-impacted catchments. This method can be widely used beyond hydrology to identify patterns, reduce trait redundancy, and select representative sites.
Cyril Thébault, Charles Perrin, Vazken Andréassian, Guillaume Thirel, Sébastien Legrand, and Olivier Delaigue
Hydrol. Earth Syst. Sci., 28, 1539–1566, https://doi.org/10.5194/hess-28-1539-2024, https://doi.org/10.5194/hess-28-1539-2024, 2024
Short summary
Short summary
Streamflow forecasting is useful for many applications, ranging from population safety (e.g. floods) to water resource management (e.g. agriculture or hydropower). To this end, hydrological models must be optimized. However, a model is inherently wrong. This study aims to analyse the contribution of a multi-model approach within a variable spatial framework to improve streamflow simulations. The underlying idea is to take advantage of the strength of each modelling framework tested.
Lele Shu, Xiaodong Li, Yan Chang, Xianhong Meng, Hao Chen, Yuan Qi, Hongwei Wang, Zhaoguo Li, and Shihua Lyu
Hydrol. Earth Syst. Sci., 28, 1477–1491, https://doi.org/10.5194/hess-28-1477-2024, https://doi.org/10.5194/hess-28-1477-2024, 2024
Short summary
Short summary
We developed a new model to better understand how water moves in a lake basin. Our model improves upon previous methods by accurately capturing the complexity of water movement, both on the surface and subsurface. Our model, tested using data from China's Qinghai Lake, accurately replicates complex water movements and identifies contributing factors of the lake's water balance. The findings provide a robust tool for predicting hydrological processes, aiding water resource planning.
Ricardo Mantilla, Morgan Fonley, and Nicolás Velásquez
Hydrol. Earth Syst. Sci., 28, 1373–1382, https://doi.org/10.5194/hess-28-1373-2024, https://doi.org/10.5194/hess-28-1373-2024, 2024
Short summary
Short summary
Hydrologists strive to “Be right for the right reasons” when modeling the hydrologic cycle; however, the datasets available to validate hydrological models are sparse, and in many cases, they comprise streamflow observations at the outlets of large catchments. In this work, we show that matching streamflow observations at the outlet of a large basin is not a reliable indicator of a correct description of the small-scale runoff processes.
Lillian M. McGill, E. Ashley Steel, and Aimee H. Fullerton
Hydrol. Earth Syst. Sci., 28, 1351–1371, https://doi.org/10.5194/hess-28-1351-2024, https://doi.org/10.5194/hess-28-1351-2024, 2024
Short summary
Short summary
This study examines the relationship between air and river temperatures in Washington's Snoqualmie and Wenatchee basins. We used classification and regression approaches to show that the sensitivity of river temperature to air temperature is variable across basins and controlled largely by geology and snowmelt. Findings can be used to inform strategies for river basin restoration and conservation, such as identifying climate-insensitive areas of the basin that should be preserved and protected.
Stephanie R. Clark, Julien Lerat, Jean-Michel Perraud, and Peter Fitch
Hydrol. Earth Syst. Sci., 28, 1191–1213, https://doi.org/10.5194/hess-28-1191-2024, https://doi.org/10.5194/hess-28-1191-2024, 2024
Short summary
Short summary
To determine if deep learning models are in general a viable alternative to traditional hydrologic modelling techniques in Australian catchments, a comparison of river–runoff predictions is made between traditional conceptual models and deep learning models in almost 500 catchments spread over the continent. It is found that the deep learning models match or outperform the traditional models in over two-thirds of the river catchments, indicating feasibility in a wide variety of conditions.
Patricio Yeste, Matilde García-Valdecasas Ojeda, Sonia R. Gámiz-Fortis, Yolanda Castro-Díez, Axel Bronstert, and María Jesús Esteban-Parra
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2024-57, https://doi.org/10.5194/hess-2024-57, 2024
Revised manuscript accepted for HESS
Short summary
Short summary
Integrating streamflow and evaporation data can help improve the physical realism of hydrologic models. In this work we investigate the capabilities of the Variable Infiltration Capacity (VIC) to reproduce both hydrologic variables for 189 headwater located in Spain. Results from sensitivity analysis indicate that adding two vegetation is enough to improve the representation of evaporation, and the performance of VIC exceeded that of the largest modelling effort currently available in Spain.
Dipti Tiwari, Mélanie Trudel, and Robert Leconte
Hydrol. Earth Syst. Sci., 28, 1127–1146, https://doi.org/10.5194/hess-28-1127-2024, https://doi.org/10.5194/hess-28-1127-2024, 2024
Short summary
Short summary
Calibrating hydrological models with multi-objective functions enhances model robustness. By using spatially distributed snow information in the calibration, the model performance can be enhanced without compromising the outputs. In this study the HYDROTEL model was calibrated in seven different experiments, incorporating the SPAEF (spatial efficiency) metric alongside Nash–Sutcliffe efficiency (NSE) and root-mean-square error (RMSE), with the aim of identifying the optimal calibration strategy.
Luis Andres De la Fuente, Mohammad Reza Ehsani, Hoshin Vijai Gupta, and Laura Elizabeth Condon
Hydrol. Earth Syst. Sci., 28, 945–971, https://doi.org/10.5194/hess-28-945-2024, https://doi.org/10.5194/hess-28-945-2024, 2024
Short summary
Short summary
Long short-term memory (LSTM) is a widely used machine-learning model in hydrology, but it is difficult to extract knowledge from it. We propose HydroLSTM, which represents processes like a hydrological reservoir. Models based on HydroLSTM perform similarly to LSTM while requiring fewer cell states. The learned parameters are informative about the dominant hydrology of a catchment. Our results show how parsimony and hydrological knowledge extraction can be achieved by using the new structure.
Louise Mimeau, Annika Künne, Flora Branger, Sven Kralisch, Alexandre Devers, and Jean-Philippe Vidal
Hydrol. Earth Syst. Sci., 28, 851–871, https://doi.org/10.5194/hess-28-851-2024, https://doi.org/10.5194/hess-28-851-2024, 2024
Short summary
Short summary
Modelling flow intermittence is essential for predicting the future evolution of drying in river networks and better understanding the ecological and socio-economic impacts. However, modelling flow intermittence is challenging, and observed data on temporary rivers are scarce. This study presents a new modelling approach for predicting flow intermittence in river networks and shows that combining different sources of observed data reduces the model uncertainty.
Elena Macdonald, Bruno Merz, Björn Guse, Viet Dung Nguyen, Xiaoxiang Guan, and Sergiy Vorogushyn
Hydrol. Earth Syst. Sci., 28, 833–850, https://doi.org/10.5194/hess-28-833-2024, https://doi.org/10.5194/hess-28-833-2024, 2024
Short summary
Short summary
In some rivers, the occurrence of extreme flood events is more likely than in other rivers – they have heavy-tailed distributions. We find that threshold processes in the runoff generation lead to such a relatively high occurrence probability of extremes. Further, we find that beyond a certain return period, i.e. for rare events, rainfall is often the dominant control compared to runoff generation. Our results can help to improve the estimation of the occurrence probability of extreme floods.
Alberto Bassi, Marvin Höge, Antonietta Mira, Fabrizio Fenicia, and Carlo Albert
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2024-47, https://doi.org/10.5194/hess-2024-47, 2024
Revised manuscript accepted for HESS
Short summary
Short summary
The goal is to remove the impact of meteorological drivers in order to uncover the unique landscape fingerprints of a catchment from streamflow data. Our results reveal an optimal two-feature summary for most catchments, with a third feature needed for challenging cases, associated with aridity and intermittent flow. Baseflow index, aridity, and soil/vegetation attributes strongly correlate with learned features, indicating their importance for streamflow prediction.
Claire Kouba and Thomas Harter
Hydrol. Earth Syst. Sci., 28, 691–718, https://doi.org/10.5194/hess-28-691-2024, https://doi.org/10.5194/hess-28-691-2024, 2024
Short summary
Short summary
In some watersheds, the severity of the dry season has a large impact on aquatic ecosystems. In this study, we design a way to predict, 5–6 months in advance, how severe the dry season will be in a rural watershed in northern California. This early warning can support seasonal adaptive management. To predict these two values, we assess data about snow, rain, groundwater, and river flows. We find that maximum snowpack and total wet season rainfall best predict dry season severity.
Yi Nan and Fuqiang Tian
Hydrol. Earth Syst. Sci., 28, 669–689, https://doi.org/10.5194/hess-28-669-2024, https://doi.org/10.5194/hess-28-669-2024, 2024
Short summary
Short summary
This paper utilized a tracer-aided model validated by multiple datasets in a large mountainous basin on the Tibetan Plateau to analyze hydrological sensitivity to climate change. The spatial pattern of the local hydrological sensitivities and the influence factors were analyzed in particular. The main finding of this paper is that the local hydrological sensitivity in mountainous basins is determined by the relationship between the glacier area ratio and the mean annual precipitation.
Michael J. Vlah, Matthew R. V. Ross, Spencer Rhea, and Emily S. Bernhardt
Hydrol. Earth Syst. Sci., 28, 545–573, https://doi.org/10.5194/hess-28-545-2024, https://doi.org/10.5194/hess-28-545-2024, 2024
Short summary
Short summary
Virtual stream gauging enables continuous streamflow estimation where a gauge might be difficult or impractical to install. We reconstructed flow at 27 gauges of the National Ecological Observatory Network (NEON), informing ~199 site-months of missing data in the official record and improving that accuracy of official estimates at 11 sites. This study shows that machine learning, but also routine regression methods, can be used to supplement existing gauge networks and reduce monitoring costs.
Sungwook Wi and Scott Steinschneider
Hydrol. Earth Syst. Sci., 28, 479–503, https://doi.org/10.5194/hess-28-479-2024, https://doi.org/10.5194/hess-28-479-2024, 2024
Short summary
Short summary
We investigate whether deep learning (DL) models can produce physically plausible streamflow projections under climate change. We address this question by focusing on modeled responses to increases in temperature and potential evapotranspiration and by employing three DL and three process-based hydrological models. The results suggest that physical constraints regarding model architecture and input are necessary to promote the physical realism of DL hydrological projections under climate change.
Guillaume Evin, Matthieu Le Lay, Catherine Fouchier, David Penot, Francois Colleoni, Alexandre Mas, Pierre-André Garambois, and Olivier Laurantin
Hydrol. Earth Syst. Sci., 28, 261–281, https://doi.org/10.5194/hess-28-261-2024, https://doi.org/10.5194/hess-28-261-2024, 2024
Short summary
Short summary
Hydrological modelling of mountainous catchments is challenging for many reasons, the main one being the temporal and spatial representation of precipitation forcings. This study presents an evaluation of the hydrological modelling of 55 small mountainous catchments of the northern French Alps, focusing on the influence of the type of precipitation reanalyses used as inputs. These evaluations emphasize the added value of radar measurements, in particular for the reproduction of flood events.
Lena Katharina Schmidt, Till Francke, Peter Martin Grosse, and Axel Bronstert
Hydrol. Earth Syst. Sci., 28, 139–161, https://doi.org/10.5194/hess-28-139-2024, https://doi.org/10.5194/hess-28-139-2024, 2024
Short summary
Short summary
How suspended sediment export from glacierized high-alpine areas responds to future climate change is hardly assessable as many interacting processes are involved, and appropriate physical models are lacking. We present the first study, to our knowledge, exploring machine learning to project sediment export until 2100 in two high-alpine catchments. We find that uncertainties due to methodological limitations are small until 2070. Negative trends imply that peak sediment may have already passed.
Cited articles
Ahuja, L. R., Sharpley, A. N., Yamamoto, M., and Menzel, R. G.: The depth of rainfall-runoff -soil interaction as determined by 32 P, Water Resour. Res., 17, 969–974, 1981.
Allen, R. G., Pereira, L. S., Raes, D., and Smith, M.: Crop Evapotranspiration – Guidelines for Computing Crop Water Requirements, FAO, Water Resources, Development and Management Service, Rome, Italy, 1998.
Arias-Estévez, M., López-Periago, E., Martínez-Carballo, E., Simal-Gándara, J., Mejuto, J.-C., and García-Río, L.: The mobility and degradation of pesticides in soils and the pollution of groundwater resources, Agr. Ecosyst. Environ., 123, 247–260, 2008.
Azizian, S.: Kinetic models of sorption: a theoretical analysis, J. Colloid Interf. Sci., 276, 47–52, 2004.
BASF: Draft Assessment Report (DAR) – Initial risk assessment provided by the rapporteur Member State Germany for the existing active substance DIMETHENAMID of the second stage of the review programme referred to in Article 8(Eq. (2)) of the Council Directive 91/414/EEC. Volume 3, Annex B, B.8, available at: http://dar.efsa.europa.eu/dar-web/provision/request/subid/35 (last access: 9 January 2013), European Food Safety Authority (EFSA), 2005.
Baskaran, S. and Kennedy, I. R.: Sorption and desorption kinetics of diuron, fluometuron, prometryn and pyrithiobac sodium in soils, J. Environ. Sci. Heal. B, 34, 943–963, 1999.
Beven, K. and Germann, P.: Macropores and water flow in soils, Water Resour. Res., 18, 1311–1325, 1982.
Bottoni, P., Keizer, J., and Funari, E.: Leaching indices of some major triazine metabolites, Chemosphere, 32, 1401–1411, 1996.
Boxall, A. B. A., Sinclair, C. J., Fenner, K., Kolpin, D., and Maund, S. J.: When synthetic chemicals degrade in the environment, Environ. Sci. Technol., 38, 368A–375A, 2004.
Breuer, L., Eckhardt, K., and Frede, H.-G.: Plant parameter values for models in temperate climates, Ecol. Modell., 169, 237–293, 2003.
Brown, C. D. and van Beinum, W.: Pesticide transport via sub-surface drains in Europe, Environ. Pollut., 157, 3314–3324, 2009.
Cold, A. and Forbes, V. E.: Consequences of a short pulse of pesticide exposure for survival and reproduction of Gammarus pulex, Aquat. Toxicol., 67, 287–299, 2004.
Craig, J. and Weiss, R.: Use of the gleams model to estimate pesticide overland and subsurface transport in USDA Forest Service nursery applications, Water Sci. Technol., 28, 425–429, 1993.
Cryer, S. A. and Havens, P. L.: Regional sensitivity analysis using a fractional factorial method for the USDA model GLEAMS, Environ. Modell. Softw., 14, 613–624, 1999.
De Wilde, T., Mertens, J., Spanoghe, P., Ryckeboer, J., Jaeken, P., and Springael, D.: Sorption kinetics and its effects on retention and leaching, Chemosphere, 72, 509–516, 2008.
Doppler, T., Camenzuli, L., Hirzel, G., Krauss, M., Lück, A., and Stamm, C.: Spatial variability of herbicide mobilisation and transport at catchment scale: insights from a field experiment, Hydrol. Earth Syst. Sci., 16, 1947–1967, https://doi.org/10.5194/hess-16-1947-2012, 2012.
Farlin, J., Gallé, T., Bayerle, M., Pittois, D., Braun, C., El Khabbaz, H., Lallement, C., Leopold, U., Vanderborght, J., and Weihermueller, L.: Using the long-term memory effect of pesticide and metabolite soil residues to estimate field degradation half-life and test leaching predictions, Geoderma, 207–208, 15–24, 2013.
Flanagan, D. C., Zuercher, B. W., and Huang, C.-H.: AnnAGNPS application and evaluation in NE Indiana, in: American Society of Agricultural and Biological Engineers Annual International Meeting 11, 085112, St. Joseph, Michigan, 2008.
Flury, M.: Experimental evidence of transport of pesticides through field soils – a review, J. Environ. Qual., 25, 25–45, 1996.
Fohrer, N., Dietrich, A., Kolychalow, O., and Ulrich, U.: Assessment of the environmental fate of the herbicides flufenacet and metazachlor with the SWAT model, J. Environ. Qual., 42, 1–11, 2013.
Fox, G. A., Sabbagh, G. J., Malone, R. W., and Rojas, K.: Modeling parent and metabolite fate and transport in subsurface drained fields with directly connected macropores, J. Am. Water Resour. As., 43, 1359–1372, 2007.
Freitas, L. G., Singer, H., Müller, S. R., Schwarzenbach, R. P., and Stamm, C.: Source area effects on pesticide losses to surface waters – a case study in the Swiss Plateau, Agr. Ecosyst. Environ., 128, 177–184, 2008.
Frey, M. P., Schneider, M. K., Dietzel, A., Reichert, P., and Stamm, C.: Predicting critical source areas for diffuse pesticide losses to surface waters: role of connectivity and boundary conditions, J. Hydrol., 365, 23–36, 2009.
Frey, M. P., Stamm, C., Schneider, M. K., and Reichert, P.: Using discharge data to reduce structural deficits in a hydrological model with a Bayesian inference approach and the implications for the prediction of critical source areas, Water Resour. Res., 47, W12529, https://doi.org/10.1029/2010WR009993, 2011.
Frolkovič , P. and Kačur, J.: Semi-analytical solutions of a contaminant transport equation with nonlinear sorption in 1 D, Comput. Geosci., 10, 279–290, 2006.
Gassmann, M., Lange, J., and Schuetz, T.: Erosion modelling designed for water quality simulation, Ecohydrology 5, 269–278, 2012.
Gassmann, M., Brito, D., and Olsson, O.: Estimation of phosphorus export from a Mediterranean agricultural catchment with scarce data, Hydrolog. Sci. J., https://doi.org/10.1080/02626667.2013.798661, in press, 2013.
Gassmann, M., Khodorkovsky, M., Friedler, E., Dubowski, Y., and Olsson, O.: Uncertainty in the river export modelling of pesticides and transformation products, Environ. Modell. Softw., 51, 35–44, 2014.
Gerke, H. H.: Preferential flow descriptions for structured soils, J. Plant Nutr. Soil Sci., 169, 382–400, 2006.
Gerke, H. H., Dusek, J., and Vogel, T.: Solute Mass Transfer Effects in Two-Dimensional Dual-Permeability Modeling of Bromide Leaching From a Tile-Drained Field, Vadose Zone J., 12, 1–1, https://doi.org/10.2136/vzj2012.0091, 2013.
Gouy, V., Dur, J.-C., Calvet, R., Belamie, R., and Chaplain, V.: Influence of adsorption– desorption phenomena on pesticide run-off from soil using simulated rainfall, Pestic. Sci., 55, 175–182, 1999.
Green, W. H. and Ampt, G. A.: Studies of soil physics. I. The flow of air and water through soils, J. Agr. Sci., 4, 1–24, 1911.
Hladik, M. L., Domagalski, J. L., and Kuivila, K. M.: Concentrations and loads of suspended sediment-associated pesticides in the San Joaquin River, California and tributaries during storm events, Sci. Total Environ., 408, 356–364, 2009.
Holvoet, K., van Griensven, A., Seuntjens, P., and Vanrolleghem, P. A.: Sensitivity analysis for hydrology and pesticide supply towards the river in SWAT, Phys. Chem. Earth, 30, 518–526, 2005.
Holvoet, K., van Griensven, A., Gevaert, V., Seuntjens, P., and Vanrolleghem, P. A.: Modifications to the SWAT code for modelling direct pesticide losses, Environ. Modell. Softw., 23, 72–81, 2008.
Huntscha, S., Singer, H., Canonica, S., Schwarzenbach, R. P., and Fenner, K.: Input dynamics and fate in surface water of the pesticide metolachlor and of its highly mobile transformation product metolachlor ESA, Environ. Sci. Technol., 42, 5507–5513, 2008.
Jarvis, N. J.: A review of non-equilibrium water flow and solute transport in soil macropores: principles, controlling factors and consequences for water quality, Eur. J. Soil Sci., 58, 523–546, 2007.
Johnson, A. C., Haria, A. H., Bhardwaj, C. L., Williams, R. J., and Walker, A.: Preferential flow pathways and their capacity to transport isoproturon in a structured clay soil, Pestic. Sci., 48, 225–237, 1996.
Johnson, B. E., Julien, P. Y., Molnar, D. K., and Watson, C. C.: The two-dimensional upland erosion model CASC2D-SED, J. Am. Water Resour. As., 36, 31–42, 2000.
Jury, W. A., Focht, D. D., and Farmer, W. J.: Evaluation of pesticide groundwater pollution potential from standard indices of soil-chemical adsorption and biodegradation, J. Environ. Qual., 16, 422–428, 1987.
Kalkhoff , S. J., Lee, K. E., Porter, S. D., Terrio, P. J., and Thurman, E. M.: Herbicides and pesticide degradation products in upper midwest agricultural streams during august base flow conditions, J. Environ. Qual., 32, 1025–1035, 2003.
Kannan, N., White, S. M., Worrall, F., and Whelan, M. J.: Pesticide modelling for a small catchment using SWAT-2000, J. Environ. Sci. Heal. B, 41, 1049–1070, 2006.
Kern, S., Singer, H., Hollender, J., Schwarzenbach, R. P., and Fenner, K.: Assessing exposure to transformation products of soil-applied organic contaminants in surface water: comparison of model predictions and field data, Environ. Sci. Technol., 45, 2833–2841, 2011.
Kladivko, E. J., van Scoyoc, G. E., Monke, E. J., Oates, K. M., and Pask, W.: Pesticide and nutrient movement into subsurface tile drains on a silt loam soil in Indiana, J. Environ. Qual., 20, 264–270, 1991.
Klaus, J. and Zehe, E.: A novel explicit approach to model bromide and pesticide transport in connected soil structures, Hydrol. Earth Syst. Sci., 15, 2127–2144, https://doi.org/10.5194/hess-15-2127-2011, 2011.
Kördel, W., Egli, H., and Klein, M.: Transport of pesticides via macropores (IUPAC technical report), Pure Appl. Chem., 80, 105–160, 2008.
Lange, J., Schuetz, T., Gregoire, C., Elsässer, D., Schulz, R., Passeport, E., and Tournebize, J.: Multi-tracer experiments to characterise contaminant mitigation capacities for different types of artificial wetlands, Int. J. Environ. Anal. Chem., 91, 768–785, 2011.
Larsbo, M., Roulier, S., Stenemo, F., Kasteel, R., and Jarvis, N.: An improved dual-permeability model of water flow and solute transport in the vadose zone, Vadose Zone J., 4, 398–406, 2005.
Larsson, M. H. and Jarvis, N. J.: Evaluation of a dual-porosity model to predict field-scale solute transport in a macroporous soil, J. Hydrol., 215, 153–171, 1999.
Larsson, M. H. and Jarvis, N. J.: Quantifying interactions between compound properties and macropore flow effects on pesticide leaching, Pest. Manag. Sci., 56, 133–141, 2000.
Leu, C., Singer, H., Stamm, C., Müller, S. R., and Schwarzenbach, R. P.: Simultaneous assessment of sources, processes, and factors influenicing pesticide losses to surface waters in a small agricultural catchment, Environ. Sci. Technol., 38, 3827–3834, 2004a.
Leu, C., Singer, H., Stamm, C., Müller, S. R., and Schwarzenbach, R. P.: Variability of pesticide losses from 13 fields to surface water within a small catchment after a controlled pesticide application, Environ. Sci. Technol., 38, 3835–3841, 2004b.
Lewan, E., Kreuger, J., and Jarvis, N.: Implications of precipitation patterns and antecedent soil water content for leaching of pesticides from arable land, Agr. Water Manage., 96, 1633–1640, 2009.
Limousin, G., Gaudet, J.-P., Charlet, L., Szenknect, S., Barthès, V., and Krimissa, M.: Sorption isotherms: a review on physical bases, modeling and measurement, Appl. Geochem., 22, 249–275, 2007.
Locke, M. A.: Sorption-desorption kinetics of alachlor in surface soil from two soybean tillage systems, J. Environ. Qual., 21, 558–566, 1992.
Ma, Q., Wauchope, R. D., Ma, L., Rojas, K. W., Malone, R. W., and Ahuja, L. R.: Test of the Root Zone Water Quality Model (RZWQM) for predicting runoff of atrazine, alachlor and fenamiphos species from conventional-tillage corn mesoplots, Pest Manag. Sci., 60, 267–276, 2004.
Maidment, D. R.: Handbook of Hydrology, McGraw-Hill, New York, 1993.
Menzel, L., Lang, H., and Rohmann, M.: Mittlere jährliche aktuelle Verdunstungshöhen 1973–1992, Hydrologischer Atlas der Schweiz (HADES), Bundesamt für Umwelt (BAFU), Switzerland, Bern, 1999.
Nash, J. and Sutcliffe, J.: River flow forecasting through conceptual models part I – a discussion of principles, J. Hydrol., 10, 282–290, 1970.
Neitsch, S., Arnold, J., Kiniry, J., Srinivasan, R., and Williams, J.: SWAT2009 Input/Output File Documentation, Texas Water Ressources Institute Technical Report No. 406, Temple, Texas, 2010.
Neitsch, S., Arnold, J., Kiniry, J., and Williams, J. R.: SWAT2009 Theoretical Documentation, Texas Water Ressources Institute Technical Report No. 406, Temple, Texas, 2011.
Olsson, O., Khodorkovsky, M., Gassmann, M., Friedler, E., Schneider, M., and Dubowski, Y.: Fate of pesticides and their transformation and products: first flush effects in a semi-arid catchment, Clean-Soil Air Water, 41, 134–142, 2013.
Patakioutas, G. I. and Albanis, T. A.: Runoff of pesticides from cropped and uncropped plots with different slopes, Int. J. Environ. Anal. Chem., 84, 103–121, 2004.
PPDB: The Pesticide Properties Database (PPDB), Agriculture and Environment Research Unit (AERU), University of Hertfordshire, funded by UK national sources and the EU-funded FOOTPRINT project (FP6-SSP-022704), University of Hertfordshire, 2009.
Rawls, W. J., Brakensiek, D. L., and Miller, N.: Green-ampt inflltration parameters from soils data, J. Hydraul. Eng., 109, 62–70, 1983.
Rosenbom, A. E., Kjær, J., Henriksen, T., Ullum, M., and Olsen, P.: Ability of the MACRO model to predict long-term leaching of metribuzin and diketometribuzin, Environ. Sci. Technol., 43, 3221–3226, 2009.
Schmocker-Fackel, P., Naef, F., and Scherrer, S.: Identifying runoff processes on the plot and catchment scale, Hydrol. Earth Syst. Sci., 11, 891–906, https://doi.org/10.5194/hess-11-891-2007, 2007.
Schulz, R.: Comparison of spray drift- and runoff -related input of azinphos-methyl and endosulfan from fruit orchards into the Lourens River, South Africa, Chemosphere, 45, 543–551, 2001.
Shariff, R. M.: Thermodynamic adsorption-desorption of metolachlor and 2,4-D on agricultural soils, Int. J. Chem., 3, 134–146, 2011.
Shipitalo, M. J. and Owens, L. B.: Atrazine, deethylatrazine, and deisopropylatrazine in surface runoff from conservation tilled watersheds, Environ. Sci. Technol., 37, 944–950, 2003.
Singh, N., Kloeppel, H., and Klein, W.: Movement of metolachlor and terbuthylazine in core and packed soil columns, Chemosphere, 47, 409–415, 2002.
Stamm, C., Waul, C., Leu, C., Freitas, L. G., Popow, G., Singer, H., and Muller, S.: Sorption effects on herbicide losses to surface waters in a small catchment of the Swiss Plateau, Z. Planzenk. Planzen., 19, 951–958, 2004.
Susyan, E. A., Rybyanets, D. S., and Ananyeva, N. D.: Microbial activity in the profiles of gray forest soil and chernozems, Eurasian Soil Sci. +, 39, 859–867, 2006.
Tang, X., Zhu, B., and Katou, H.: A review of rapid transport of pesticides from sloping farmland to surface waters: processes and mitigation strategies, J. Environ. Sci., 24, 351–361, 2012.
Tate III, R. L.: Microbial activity in organic soils as affected by soil depth and crop, Appl. Environ. Microbiol., 37, 1085–1090, 1979.
Traub-Eberhard, U., Kördel, W., Klein, W.: Pesticide movement into subsurface drains on a loamy silt soil, Chemosphere, 28 , 273–284, 1994.
van Genuchten, M. T.: A closed-form equation for predicting the hydraulic conductivity of unsaturated soils, Soil Sci. Soc. Am. J., 44, 892–898, 1980.
Vezzaro, L. and Mikkelsen, P. S.: Application of global sensitivity analysis and uncertainty quantification in dynamic modelling of micropollutants in stormwater runoff, Environ. Modell. Softw., 27–28, 40–51, 2012.
Villaverde, J., van Beinum, W., Beulke, S., and Brown, C. D.: The kinetics of sorption by retarded diffusion into soil aggregate pores, Environ. Sci. Technol., 43, 8227–8232, 2009.
Wang, D., Norman, J. M., Lowery, B., and McSweeney, K.: Nondestructive determination of hydrogeometrical characteristics of soil macropores, Soil Sci. Soc. Am. J., 58, 294–303, 1994.
Weiler, M.: An infiltration model based on flow variability in macropores: development, sensitivity analysis and applications, J. Hydrol., 310, 294–315, 2005.
Zehe, E. and Flühler, H.: Preferential transport of isoproturon at a plot scale and a field scale tile-drained site, J. Hydrol., 247, 100–115, 2001.