Articles | Volume 27, issue 11
https://doi.org/10.5194/hess-27-2227-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/hess-27-2227-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Relationship of seasonal variations in drip water δ13CDIC, δ18O, and trace elements with surface and physical cave conditions of La Vallina cave, NW Spain
Oliver Kost
Geological Institute, ETH Zürich, Sonneggstrasse 5, 8092 Zurich, Switzerland
Saúl González-Lemos
ASCIEM Consulting SLP, C/Gutiérrez Herrero 52, 33402 Avilés, Spain
Laura Rodríguez-Rodríguez
Departamento Geología, Universidad de Oviedo, C/Jesús Arias de Velasco s/n, 33005 Oviedo, Spain
Jakub Sliwinski
Geological Institute, ETH Zürich, Sonneggstrasse 5, 8092 Zurich, Switzerland
School of Earth and Environmental Sciences, University of St Andrews, Queen's Terrace, KY16 9AJ St Andrews, Scotland
Laura Endres
Geological Institute, ETH Zürich, Sonneggstrasse 5, 8092 Zurich, Switzerland
Negar Haghipour
Geological Institute, ETH Zürich, Sonneggstrasse 5, 8092 Zurich, Switzerland
Ion Beam Physics, ETH Zürich, Otto-Stern-Weg 5, 8093 Zurich, Switzerland
Geological Institute, ETH Zürich, Sonneggstrasse 5, 8092 Zurich, Switzerland
Related authors
Heather M. Stoll, Chris Day, Franziska Lechleitner, Oliver Kost, Laura Endres, Jakub Sliwinski, Carlos Pérez-Mejías, Hai Cheng, and Denis Scholz
Clim. Past, 19, 2423–2444, https://doi.org/10.5194/cp-19-2423-2023, https://doi.org/10.5194/cp-19-2423-2023, 2023
Short summary
Short summary
Stalagmites formed in caves provide valuable information about past changes in climate and vegetation conditions. In this contribution, we present a new method to better estimate past changes in soil and vegetation productivity using carbon isotopes and trace elements measured in stalagmites. Applying this method to other stalagmites should provide a better indication of past vegetation feedbacks to climate change.
Franziska A. Lechleitner, Christopher C. Day, Oliver Kost, Micah Wilhelm, Negar Haghipour, Gideon M. Henderson, and Heather M. Stoll
Clim. Past, 17, 1903–1918, https://doi.org/10.5194/cp-17-1903-2021, https://doi.org/10.5194/cp-17-1903-2021, 2021
Short summary
Short summary
Soil respiration is a critical but poorly constrained component of the global carbon cycle. We analyse the effect of changing soil respiration rates on the stable carbon isotope ratio of speleothems from northern Spain covering the last deglaciation. Using geochemical analysis and forward modelling we quantify the processes affecting speleothem stable carbon isotope ratios and extract a signature of increasing soil respiration synchronous with deglacial warming.
Alexander J. Clark, Ismael Torres-Romero, Madalina Jaggi, Stefano M. Bernasconi, and Heather M. Stoll
Clim. Past, 20, 2081–2101, https://doi.org/10.5194/cp-20-2081-2024, https://doi.org/10.5194/cp-20-2081-2024, 2024
Short summary
Short summary
Coccoliths are abundant in sediments across the world’s oceans, yet it is difficult to apply traditional carbon or oxygen isotope methodologies for temperature reconstructions. We show that our coccolith clumped isotope temperature calibration with well-constrained temperatures systematically differs from inorganic carbonate calibrations. We suggest the use of our well-constrained calibration for future coccolith carbonate temperature reconstructions.
Giulia Zazzeri, Lukas Wacker, Negar Haghipour, Philip Gautchi, Thomas Laemmel, Sönke Szidat, and Heather Graven
Atmos. Meas. Tech. Discuss., https://doi.org/10.5194/amt-2024-123, https://doi.org/10.5194/amt-2024-123, 2024
Revised manuscript accepted for AMT
Short summary
Short summary
Radiocarbon (14C) is an optimal tracer of methane (CH4) emissions, as 14C measurements enable distinguishing fossil from biogenic methane. However, these measurements are particularly challenging, mainly due to technical difficulties in the sampling procedure. With this work we made the sample extraction much simpler and time efficient, providing a new technology that can be used by any research group, with the goal of expanding 14C measurements for an improved understanding of methane sources.
Judit Torner, Isabel Cacho, Heather Stoll, Ana Moreno, Joan O. Grimalt, Francisco J. Sierro, Hai Cheng, and R. Lawrence Edwards
Clim. Past Discuss., https://doi.org/10.5194/cp-2024-54, https://doi.org/10.5194/cp-2024-54, 2024
Revised manuscript accepted for CP
Short summary
Short summary
This study presents a new speleothem record of the western Mediterranean region that offers new insights into the timeline of glacial terminations TIV, TIII, and TIII.a. The comparison among the studied deglaciations reveals differences in terms of intensity and duration and opens the opportunity to evaluate marine sediment chronologies based on orbital tuning from the North Atlantic and the Western Mediterranean.
Szabina Karancz, Lennart J. de Nooijer, Bas van der Wagt, Marcel T. J. van der Meer, Sambuddha Misra, Rick Hennekam, Zeynep Erdem, Julie Lattaud, Negar Haghipour, Stefan Schouten, and Gert-Jan Reichart
EGUsphere, https://doi.org/10.5194/egusphere-2024-1915, https://doi.org/10.5194/egusphere-2024-1915, 2024
Short summary
Short summary
Changes in upwelling intensity of the Benguela upwelling region during the last glacial motivated us to investigate the local CO2-history during the last glacial to interglacial transition. Using various geochemical tracers on archives from both intermediate and surface waters reveal enhanced storage of carbon at depth during the last glacial maximum. An efficient biological pump likely prevented outgassing of CO2 from intermediate depth to the atmosphere.
Nikita Kaushal, Carlos Perez-Mejias, and Heather M. Stoll
Clim. Past Discuss., https://doi.org/10.5194/cp-2024-37, https://doi.org/10.5194/cp-2024-37, 2024
Revised manuscript under review for CP
Short summary
Short summary
Terminations are large magnitude rapid events triggered in the North Atlantic region that manifest across the global climate system. They provide key examples of climatic teleconnections and dynamics. In this study, we use the SISAL global speleothem database and find that there are sufficient climatic records from key locations to make speleothems a valuable archive for studying Terminations and provide instances for more targeted work on speleothem research.
Nikita Kaushal, Franziska A. Lechleitner, Micah Wilhelm, Khalil Azennoud, Janica C. Bühler, Kerstin Braun, Yassine Ait Brahim, Andy Baker, Yuval Burstyn, Laia Comas-Bru, Jens Fohlmeister, Yonaton Goldsmith, Sandy P. Harrison, István G. Hatvani, Kira Rehfeld, Magdalena Ritzau, Vanessa Skiba, Heather M. Stoll, József G. Szűcs, Péter Tanos, Pauline C. Treble, Vitor Azevedo, Jonathan L. Baker, Andrea Borsato, Sakonvan Chawchai, Andrea Columbu, Laura Endres, Jun Hu, Zoltán Kern, Alena Kimbrough, Koray Koç, Monika Markowska, Belen Martrat, Syed Masood Ahmad, Carole Nehme, Valdir Felipe Novello, Carlos Pérez-Mejías, Jiaoyang Ruan, Natasha Sekhon, Nitesh Sinha, Carol V. Tadros, Benjamin H. Tiger, Sophie Warken, Annabel Wolf, Haiwei Zhang, and SISAL Working Group members
Earth Syst. Sci. Data, 16, 1933–1963, https://doi.org/10.5194/essd-16-1933-2024, https://doi.org/10.5194/essd-16-1933-2024, 2024
Short summary
Short summary
Speleothems are a popular, multi-proxy climate archive that provide regional to global insights into past hydroclimate trends with precise chronologies. We present an update to the SISAL (Speleothem Isotopes
Synthesis and AnaLysis) database, SISALv3, which, for the first time, contains speleothem trace element records, in addition to an update to the stable isotope records available in previous versions of the database, cumulatively providing data from 365 globally distributed sites.
Synthesis and AnaLysis) database, SISALv3, which, for the first time, contains speleothem trace element records, in addition to an update to the stable isotope records available in previous versions of the database, cumulatively providing data from 365 globally distributed sites.
Miguel Bartolomé, Ana Moreno, Carlos Sancho, Isabel Cacho, Heather Stoll, Negar Haghipour, Ánchel Belmonte, Christoph Spötl, John Hellstrom, R. Lawrence Edwards, and Hai Cheng
Clim. Past, 20, 467–494, https://doi.org/10.5194/cp-20-467-2024, https://doi.org/10.5194/cp-20-467-2024, 2024
Short summary
Short summary
Reconstructing past temperatures at regional scales during the Common Era is necessary to place the current warming in the context of natural climate variability. We present a climate reconstruction based on eight stalagmites from four caves in the Pyrenees, NE Spain. These stalagmites were dated precisely and analysed for their oxygen isotopes, which appear dominated by temperature changes. Solar variability and major volcanic eruptions are the two main drivers of observed climate variability.
Kirsi H. Keskitalo, Lisa Bröder, Tommaso Tesi, Paul J. Mann, Dirk J. Jong, Sergio Bulte Garcia, Anna Davydova, Sergei Davydov, Nikita Zimov, Negar Haghipour, Timothy I. Eglinton, and Jorien E. Vonk
Biogeosciences, 21, 357–379, https://doi.org/10.5194/bg-21-357-2024, https://doi.org/10.5194/bg-21-357-2024, 2024
Short summary
Short summary
Permafrost thaw releases organic carbon into waterways. Decomposition of this carbon pool emits greenhouse gases into the atmosphere, enhancing climate warming. We show that Arctic river carbon and water chemistry are different between the spring ice breakup and summer and that primary production is initiated in small Arctic rivers right after ice breakup, in contrast to in large rivers. This may have implications for fluvial carbon dynamics and greenhouse gas uptake and emission balance.
Heather M. Stoll, Leopoldo D. Pena, Ivan Hernandez-Almeida, José Guitián, Thomas Tanner, and Heiko Pälike
Clim. Past, 20, 25–36, https://doi.org/10.5194/cp-20-25-2024, https://doi.org/10.5194/cp-20-25-2024, 2024
Short summary
Short summary
The Oligocene and early Miocene periods featured dynamic glacial cycles on Antarctica. In this paper, we use Sr isotopes in marine carbonate sediments to document a change in the location and intensity of continental weathering during short periods of very intense Antarctic glaciation. Potentially, the weathering intensity of old continental rocks on Antarctica was reduced during glaciation. We also show improved age models for correlation of Southern Ocean and North Atlantic sediments.
Heather M. Stoll, Chris Day, Franziska Lechleitner, Oliver Kost, Laura Endres, Jakub Sliwinski, Carlos Pérez-Mejías, Hai Cheng, and Denis Scholz
Clim. Past, 19, 2423–2444, https://doi.org/10.5194/cp-19-2423-2023, https://doi.org/10.5194/cp-19-2423-2023, 2023
Short summary
Short summary
Stalagmites formed in caves provide valuable information about past changes in climate and vegetation conditions. In this contribution, we present a new method to better estimate past changes in soil and vegetation productivity using carbon isotopes and trace elements measured in stalagmites. Applying this method to other stalagmites should provide a better indication of past vegetation feedbacks to climate change.
Amanda Gerotto, Hongrui Zhang, Renata Hanae Nagai, Heather M. Stoll, Rubens César Lopes Figueira, Chuanlian Liu, and Iván Hernández-Almeida
Biogeosciences, 20, 1725–1739, https://doi.org/10.5194/bg-20-1725-2023, https://doi.org/10.5194/bg-20-1725-2023, 2023
Short summary
Short summary
Based on the analysis of the response of coccolithophores’ morphological attributes in a laboratory dissolution experiment and surface sediment samples from the South China Sea, we proposed that the thickness shape (ks) factor of fossil coccoliths together with the normalized ks variation, which is the ratio of the standard deviation of ks (σ) over the mean ks (σ/ks), is a robust and novel proxy to reconstruct past changes in deep ocean carbon chemistry.
Thibauld M. Béjard, Andrés S. Rigual-Hernández, José A. Flores, Javier P. Tarruella, Xavier Durrieu de Madron, Isabel Cacho, Neghar Haghipour, Aidan Hunter, and Francisco J. Sierro
Biogeosciences, 20, 1505–1528, https://doi.org/10.5194/bg-20-1505-2023, https://doi.org/10.5194/bg-20-1505-2023, 2023
Short summary
Short summary
The Mediterranean Sea is undergoing a rapid and unprecedented environmental change. Planktic foraminifera calcification is affected on different timescales. On seasonal and interannual scales, calcification trends differ according to the species and are linked mainly to sea surface temperatures and carbonate system parameters, while comparison with pre/post-industrial assemblages shows that all three species have reduced their calcification between 10 % to 35 % according to the species.
Dirk Jong, Lisa Bröder, Tommaso Tesi, Kirsi H. Keskitalo, Nikita Zimov, Anna Davydova, Philip Pika, Negar Haghipour, Timothy I. Eglinton, and Jorien E. Vonk
Biogeosciences, 20, 271–294, https://doi.org/10.5194/bg-20-271-2023, https://doi.org/10.5194/bg-20-271-2023, 2023
Short summary
Short summary
With this study, we want to highlight the importance of studying both land and ocean together, and water and sediment together, as these systems function as a continuum, and determine how organic carbon derived from permafrost is broken down and its effect on global warming. Although on the one hand it appears that organic carbon is removed from sediments along the pathway of transport from river to ocean, it also appears to remain relatively ‘fresh’, despite this removal and its very old age.
Jessica G. M. Crumpton-Banks, Thomas Tanner, Ivan Hernández Almeida, James W. B. Rae, and Heather Stoll
Biogeosciences, 19, 5633–5644, https://doi.org/10.5194/bg-19-5633-2022, https://doi.org/10.5194/bg-19-5633-2022, 2022
Short summary
Short summary
Past ocean carbon is reconstructed using proxies, but it is unknown whether preparing ocean sediment for one proxy might damage the data given by another. We have tested whether the extraction of an organic proxy archive from sediment samples impacts the geochemistry of tiny shells also within the sediment. We find no difference in shell geochemistry between samples which come from treated and untreated sediment. This will help us to maximize scientific return from valuable sediment samples.
Melissa Sophia Schwab, Hannah Gies, Chantal Valérie Freymond, Maarten Lupker, Negar Haghipour, and Timothy Ian Eglinton
Biogeosciences, 19, 5591–5616, https://doi.org/10.5194/bg-19-5591-2022, https://doi.org/10.5194/bg-19-5591-2022, 2022
Short summary
Short summary
The majority of river studies focus on headwater or floodplain systems, while often neglecting intermediate river segments. Our study on the subalpine Sihl River bridges the gap between streams and lowlands and demonstrates that moderately steep river segments are areas of significant instream alterations, modulating the export of organic carbon over short distances.
José Guitián, Miguel Ángel Fuertes, José-Abel Flores, Iván Hernández-Almeida, and Heather Stoll
Biogeosciences, 19, 5007–5019, https://doi.org/10.5194/bg-19-5007-2022, https://doi.org/10.5194/bg-19-5007-2022, 2022
Short summary
Short summary
The effect of environmental conditions on the degree of calcification of marine phytoplankton remains unclear. This study implements a new microscopic approach to quantify the calcification of ancient coccolithophores, using North Atlantic sediments. Results show significant differences in the thickness and shape factor of coccoliths for samples with minimum dissolution, providing the first evaluation of phytoplankton physiology adaptation to million-year-scale variable environmental conditions.
Blanca Ausín, Negar Haghipour, Elena Bruni, and Timothy Eglinton
Biogeosciences, 19, 613–627, https://doi.org/10.5194/bg-19-613-2022, https://doi.org/10.5194/bg-19-613-2022, 2022
Short summary
Short summary
The preservation and distribution of alkenones – organic molecules produced by marine algae – in marine sediments allows us to reconstruct past variations in sea surface temperature, primary productivity and CO2. Here, we explore the impact of remobilization and lateral transport of sedimentary alkenones on their fate in marine sediments. We demonstrate the pervasive influence of these processes on alkenone-derived environmental signals, compromising the reliability of related paleorecords.
Franziska A. Lechleitner, Christopher C. Day, Oliver Kost, Micah Wilhelm, Negar Haghipour, Gideon M. Henderson, and Heather M. Stoll
Clim. Past, 17, 1903–1918, https://doi.org/10.5194/cp-17-1903-2021, https://doi.org/10.5194/cp-17-1903-2021, 2021
Short summary
Short summary
Soil respiration is a critical but poorly constrained component of the global carbon cycle. We analyse the effect of changing soil respiration rates on the stable carbon isotope ratio of speleothems from northern Spain covering the last deglaciation. Using geochemical analysis and forward modelling we quantify the processes affecting speleothem stable carbon isotope ratios and extract a signature of increasing soil respiration synchronous with deglacial warming.
Elena T. Bruni, Richard F. Ott, Vincenzo Picotti, Negar Haghipour, Karl W. Wegmann, and Sean F. Gallen
Earth Surf. Dynam., 9, 771–793, https://doi.org/10.5194/esurf-9-771-2021, https://doi.org/10.5194/esurf-9-771-2021, 2021
Short summary
Short summary
The Klados River catchment contains seemingly overlarge, well-preserved alluvial terraces and fans. Unlike previous studies, we argue that the deposits formed in the Holocene based on their position relative to a paleoshoreline uplifted in 365 CE and seven radiocarbon dates. We also find that constant sediment supply from high-lying landslide deposits disconnected the valley from regional tectonics and climate controls, which resulted in fan and terrace formation guided by stochastic events.
Ana Moreno, Miguel Iglesias, Cesar Azorin-Molina, Carlos Pérez-Mejías, Miguel Bartolomé, Carlos Sancho, Heather Stoll, Isabel Cacho, Jaime Frigola, Cinta Osácar, Arsenio Muñoz, Antonio Delgado-Huertas, Ileana Bladé, and Françoise Vimeux
Atmos. Chem. Phys., 21, 10159–10177, https://doi.org/10.5194/acp-21-10159-2021, https://doi.org/10.5194/acp-21-10159-2021, 2021
Short summary
Short summary
We present a large and unique dataset of the rainfall isotopic composition at seven sites from northern Iberia to characterize their variability at daily and monthly timescales and to assess the role of climate and geographic factors in the modulation of δ18O values. We found that the origin, moisture uptake along the trajectory and type of precipitation play a key role. These results will help to improve the interpretation of δ18O paleorecords from lacustrine carbonates or speleothems.
Jannik Martens, Evgeny Romankevich, Igor Semiletov, Birgit Wild, Bart van Dongen, Jorien Vonk, Tommaso Tesi, Natalia Shakhova, Oleg V. Dudarev, Denis Kosmach, Alexander Vetrov, Leopold Lobkovsky, Nikolay Belyaev, Robie W. Macdonald, Anna J. Pieńkowski, Timothy I. Eglinton, Negar Haghipour, Salve Dahle, Michael L. Carroll, Emmelie K. L. Åström, Jacqueline M. Grebmeier, Lee W. Cooper, Göran Possnert, and Örjan Gustafsson
Earth Syst. Sci. Data, 13, 2561–2572, https://doi.org/10.5194/essd-13-2561-2021, https://doi.org/10.5194/essd-13-2561-2021, 2021
Short summary
Short summary
The paper describes the establishment, structure and current status of the first Circum-Arctic Sediment CArbon DatabasE (CASCADE), which is a scientific effort to harmonize and curate all published and unpublished data of carbon, nitrogen, carbon isotopes, and terrigenous biomarkers in sediments of the Arctic Ocean in one database. CASCADE will enable a variety of studies of the Arctic carbon cycle and thus contribute to a better understanding of how climate change affects the Arctic.
Hongrui Zhang, Chuanlian Liu, Luz María Mejía, and Heather Stoll
Biogeosciences, 18, 1909–1916, https://doi.org/10.5194/bg-18-1909-2021, https://doi.org/10.5194/bg-18-1909-2021, 2021
Hannah Gies, Frank Hagedorn, Maarten Lupker, Daniel Montluçon, Negar Haghipour, Tessa Sophia van der Voort, and Timothy Ian Eglinton
Biogeosciences, 18, 189–205, https://doi.org/10.5194/bg-18-189-2021, https://doi.org/10.5194/bg-18-189-2021, 2021
Short summary
Short summary
Understanding controls on the persistence of organic matter in soils is essential to constrain its role in the carbon cycle. Emerging concepts suggest that the soil carbon pool is predominantly comprised of stabilized microbial residues. To test this hypothesis we isolated microbial membrane lipids from two Swiss soil profiles and measured their radiocarbon age. We find that the ages of these compounds are in the range of millenia and thus provide evidence for stabilized microbial mass in soils.
Catarina Cavaleiro, Antje H. L. Voelker, Heather Stoll, Karl-Heinz Baumann, and Michal Kucera
Clim. Past, 16, 2017–2037, https://doi.org/10.5194/cp-16-2017-2020, https://doi.org/10.5194/cp-16-2017-2020, 2020
Leticia G. Luz, Thiago P. Santos, Timothy I. Eglinton, Daniel Montluçon, Blanca Ausin, Negar Haghipour, Silvia M. Sousa, Renata H. Nagai, and Renato S. Carreira
Clim. Past, 16, 1245–1261, https://doi.org/10.5194/cp-16-1245-2020, https://doi.org/10.5194/cp-16-1245-2020, 2020
Short summary
Short summary
Two sediment cores retrieved from the SE Brazilian continental margin were studied using multiple organic (alkenones) and inorganic (oxygen isotopes in carbonate shells and water) proxies to reconstruct the sea surface temperature (SST) over the last 50 000 years. The findings indicate the formation of strong thermal gradients in the region during the last climate transition, a feature that may become more frequent in the future scenario of global water circulation changes.
Tessa Sophia van der Voort, Utsav Mannu, Frank Hagedorn, Cameron McIntyre, Lorenz Walthert, Patrick Schleppi, Negar Haghipour, and Timothy Ian Eglinton
Biogeosciences, 16, 3233–3246, https://doi.org/10.5194/bg-16-3233-2019, https://doi.org/10.5194/bg-16-3233-2019, 2019
Short summary
Short summary
The carbon stored in soils is the largest reservoir of organic carbon on land. In the context of greenhouse gas emissions and a changing climate, it is very important to understand how stable the carbon in the soil is and why. The deeper parts of the soil have often been overlooked even though they store a lot of carbon. In this paper, we discovered that although deep soil carbon is expected to be old and stable, there can be a significant young component that cycles much faster.
Hongrui Zhang, Heather Stoll, Clara Bolton, Xiaobo Jin, and Chuanlian Liu
Biogeosciences, 15, 4759–4775, https://doi.org/10.5194/bg-15-4759-2018, https://doi.org/10.5194/bg-15-4759-2018, 2018
Short summary
Short summary
The sinking speeds of coccoliths are relevant for laboratory methods to separate coccoliths for geochemical analysis. However, in the absence of estimates of coccolith settling velocity, previous implementations have depended mainly on time-consuming method development by trial and error. In this study, the sinking velocities of cocooliths were carefully measured for the first time. We also provide an estimation of coccolith sinking velocity by shape, which will make coccolith separation easier.
Muhammed Ojoshogu Usman, Frédérique Marie Sophie Anne Kirkels, Huub Michel Zwart, Sayak Basu, Camilo Ponton, Thomas Michael Blattmann, Michael Ploetze, Negar Haghipour, Cameron McIntyre, Francien Peterse, Maarten Lupker, Liviu Giosan, and Timothy Ian Eglinton
Biogeosciences, 15, 3357–3375, https://doi.org/10.5194/bg-15-3357-2018, https://doi.org/10.5194/bg-15-3357-2018, 2018
Saúl González-Lemos, José Guitián, Miguel-Ángel Fuertes, José-Abel Flores, and Heather M. Stoll
Biogeosciences, 15, 1079–1091, https://doi.org/10.5194/bg-15-1079-2018, https://doi.org/10.5194/bg-15-1079-2018, 2018
Short summary
Short summary
Changes in atmospheric carbon dioxide affect ocean chemistry and the ability of marine organisms to manufacture shells from calcium carbonate. We describe a technique to obtain more reproducible measurements of the thickness of calcium carbonate shells made by microscopic marine algae called coccolithophores, which will allow researchers to compare how the shell thickness responds to variations in ocean chemistry in the past and present.
Lorenz Wüthrich, Claudio Brändli, Régis Braucher, Heinz Veit, Negar Haghipour, Carla Terrizzano, Marcus Christl, Christian Gnägi, and Roland Zech
E&G Quaternary Sci. J., 66, 57–68, https://doi.org/10.5194/egqsj-66-57-2017, https://doi.org/10.5194/egqsj-66-57-2017, 2017
Liviu Giosan, Camilo Ponton, Muhammed Usman, Jerzy Blusztajn, Dorian Q. Fuller, Valier Galy, Negar Haghipour, Joel E. Johnson, Cameron McIntyre, Lukas Wacker, and Timothy I. Eglinton
Earth Surf. Dynam., 5, 781–789, https://doi.org/10.5194/esurf-5-781-2017, https://doi.org/10.5194/esurf-5-781-2017, 2017
Short summary
Short summary
A reconstruction of erosion in the core monsoon zone of India provides unintuitive but fundamental insights: in contrast to semiarid regions that experience enhanced erosion during erratic rain events, the monsoon is annual and acts as a veritable
erosional pumpaccelerating when the land cover is minimal. The existence of such a monsoon erosional pump promises to reconcile conflicting views on the land–sea sediment and carbon transfer as well as the monsoon evolution on longer timescales.
Robert B. Sparkes, Ayça Doğrul Selver, Örjan Gustafsson, Igor P. Semiletov, Negar Haghipour, Lukas Wacker, Timothy I. Eglinton, Helen M. Talbot, and Bart E. van Dongen
The Cryosphere, 10, 2485–2500, https://doi.org/10.5194/tc-10-2485-2016, https://doi.org/10.5194/tc-10-2485-2016, 2016
Short summary
Short summary
The permafrost in eastern Siberia contains large amounts of carbon frozen in soils and sediments. Continuing global warming is thawing the permafrost and releasing carbon to the Arctic Ocean. We used pyrolysis-GCMS, a chemical fingerprinting technique, to study the types of carbon being deposited on the continental shelf. We found large amounts of permafrost-sourced carbon being deposited up to 200 km offshore.
M. N. Müller, M. Lebrato, U. Riebesell, J. Barcelos e Ramos, K. G. Schulz, S. Blanco-Ameijeiras, S. Sett, A. Eisenhauer, and H. M. Stoll
Biogeosciences, 11, 1065–1075, https://doi.org/10.5194/bg-11-1065-2014, https://doi.org/10.5194/bg-11-1065-2014, 2014
Related subject area
Subject: Vadose Zone Hydrology | Techniques and Approaches: Instruments and observation techniques
High-resolution operational soil moisture monitoring for forests in central Germany
Technical Note: Revisiting the general calibration of cosmic-ray neutron sensors to estimate soil water content
Technical note: A fast and objective autosampler for direct vapor equilibration isotope measurements
Effects of changes in climatic conditions on soil water storage patterns
Coupled hydrogeophysical inversion of an artificial infiltration experiment monitored with ground-penetrating radar: synthetic demonstration
Technical note: Discrete in situ vapor sampling for subsequent lab-based water stable isotope analysis
A change in perspective: downhole cosmic-ray neutron sensing for the estimation of soil moisture
Impacts of soil management and climate on saturated and near-saturated hydraulic conductivity: analyses of the Open Tension-disk Infiltrometer Meta-database (OTIM)
Physics-informed machine learning for understanding rock moisture dynamics in a sandstone cave
In situ estimation of soil hydraulic and hydrodispersive properties by inversion of electromagnetic induction measurements and soil hydrological modeling
Towards disentangling heterogeneous soil moisture patterns in cosmic-ray neutron sensor footprints
The International Soil Moisture Network: serving Earth system science for over a decade
Technical note: Evaporating water is different from bulk soil water in δ2H and δ18O and has implications for evaporation calculation
Technical note: Unresolved aspects of the direct vapor equilibration method for stable isotope analysis (δ18O, δ2H) of matrix-bound water: unifying protocols through empirical and mathematical scrutiny
Spatio-temporal soil moisture retrieval at the catchment scale using a dense network of cosmic-ray neutron sensors
Deep desiccation of soils observed by long-term high-resolution measurements on a large inclined lysimeter
A novel analytical approach for the simultaneous measurement of nitrate and dissolved organic carbon in soil water
Exploring the regolith with electrical resistivity tomography in large-scale surveys: electrode spacing-related issues and possibility
Soil dielectric characterization during freeze–thaw transitions using L-band coaxial and soil moisture probes
Hydrological signals in tilt and gravity residuals at Conrad Observatory (Austria)
New measures of deep soil water recharge during the vegetation restoration process in semi-arid regions of northern China
Estimation of subsurface soil moisture from surface soil moisture in cold mountainous areas
Investigating unproductive water losses from irrigated agricultural crops in the humid tropics through analyses of stable isotopes of water
Pacific climate reflected in Waipuna Cave drip water hydrochemistry
Field observations of soil hydrological flow path evolution over 10 millennia
A proposed method for estimating interception from near-surface soil moisture response
Controls of fluorescent tracer retention by soils and sediments
Reflection tomography of time-lapse GPR data for studying dynamic unsaturated flow phenomena
Effects of preferential flow on snowmelt partitioning and groundwater recharge in frozen soils
Spatio-temporal relevance and controls of preferential flow at the landscape scale
Real-time monitoring of nitrate in soils as a key for optimization of agricultural productivity and prevention of groundwater pollution
A soil non-aqueous phase liquid (NAPL) flushing laboratory experiment based on measuring the dielectric properties of soil–organic mixtures via time domain reflectometry (TDR)
The value of satellite remote sensing soil moisture data and the DISPATCH algorithm in irrigation fields
Estimating epikarst water storage by time-lapse surface-to-depth gravity measurements
Inter-laboratory comparison of cryogenic water extraction systems for stable isotope analysis of soil water
Preferential flow systems amended with biogeochemical components: imaging of a two-dimensional study
Imaging groundwater infiltration dynamics in the karst vadose zone with long-term ERT monitoring
Calibrating electromagnetic induction conductivities with time-domain reflectometry measurements
Multiscale soil moisture estimates using static and roving cosmic-ray soil moisture sensors
Field-scale water balance closure in seasonally frozen conditions
Improving calibration and validation of cosmic-ray neutron sensors in the light of spatial sensitivity
Is annual recharge coefficient a valid concept in arid and semi-arid regions?
Transport and degradation of perchlorate in deep vadose zone: implications from direct observations during bioremediation treatment
Monitoring soil moisture from middle to high elevation in Switzerland: set-up and first results from the SOMOMOUNT network
Experimental study on retardation of a heavy NAPL vapor in partially saturated porous media
Repeated electromagnetic induction measurements for mapping soil moisture at the field scale: validation with data from a wireless soil moisture monitoring network
ENSO–cave drip water hydrochemical relationship: a 7-year dataset from south-eastern Australia
Incorporation of globally available datasets into the roving cosmic-ray neutron probe method for estimating field-scale soil water content
Real-time monitoring of nitrate transport in the deep vadose zone under a crop field – implications for groundwater protection
Technical note: Improving the AWAT filter with interpolation schemes for advanced processing of high resolution data
Ivan Vorobevskii, Thi Thanh Luong, Rico Kronenberg, and Rainer Petzold
Hydrol. Earth Syst. Sci., 28, 3567–3595, https://doi.org/10.5194/hess-28-3567-2024, https://doi.org/10.5194/hess-28-3567-2024, 2024
Short summary
Short summary
An introduced high-resolution soil moisture monitoring framework combines a 1D water balance model, real-time meteorological data, and a national soil database to present point-based operational data with a user-friendly web platform. Its significance lies in the improvement of forest management by making informed, local-scale decisions crucial for mitigating climate change impacts. In the paper, we present a technical description and validation of the framework and showcase its features.
Maik Heistermann, Till Francke, Martin Schrön, and Sascha E. Oswald
Hydrol. Earth Syst. Sci., 28, 989–1000, https://doi.org/10.5194/hess-28-989-2024, https://doi.org/10.5194/hess-28-989-2024, 2024
Short summary
Short summary
Cosmic-ray neutron sensing (CRNS) is a non-invasive technique used to obtain estimates of soil water content (SWC) at a horizontal footprint of around 150 m and a vertical penetration depth of up to 30 cm. However, typical CRNS applications require the local calibration of a function which converts neutron counts to SWC. As an alternative, we propose a generalized function as a way to avoid the use of local reference measurements of SWC and hence a major source of uncertainty.
Jonas Pyschik, Stefan Seeger, Barbara Herbstritt, and Markus Weiler
EGUsphere, https://doi.org/10.5194/egusphere-2024-528, https://doi.org/10.5194/egusphere-2024-528, 2024
Short summary
Short summary
We developed a device which automates the analysis process of stable water isotopes. Stable water isotopes are a natural tracer which many researchers use to investigate water (re-)distribution processes in environmental systems. The device helps to analyse such environmental samples by automating a formerly tidious manual labor process, alowwing for a higher sample throughput. This enables larger sampling campaigns, since more samples can be processed before reaching their limited storage time.
Annelie Ehrhardt, Jannis S. Groh, and Horst H. Gerke
EGUsphere, https://doi.org/10.5194/egusphere-2024-118, https://doi.org/10.5194/egusphere-2024-118, 2024
Short summary
Short summary
Soil water storage (SWS) describes the amount of water in the root zone of plants accessible for crop growth. SWS underlies annual cycles with maximum values in winter and minimum values in summer. For a soil that was transferred from a drier to a more humid climate we found that the maximum peak of SWS occurs earlier every year. This can be explained by an earlier start of the vegetation period. It is a first indication that the ability of soils to store water is affected by climate change.
Rohianuu Moua, Nolwenn Lesparre, Jean-François Girard, Benjamin Belfort, François Lehmann, and Anis Younes
Hydrol. Earth Syst. Sci., 27, 4317–4334, https://doi.org/10.5194/hess-27-4317-2023, https://doi.org/10.5194/hess-27-4317-2023, 2023
Short summary
Short summary
Hydraulic properties of soil include the ability of water to move through the soil and the amount of water that is held in the soil in dry or wet conditions. In this work, we further investigate a protocol used to evaluate such hydraulic properties. We propose a modified version of the protocol, with which we show (i) how the data obtained with this protocol are influenced by the soil hydraulic properties and (ii) how one can use it to estimate these properties.
Barbara Herbstritt, Benjamin Gralher, Stefan Seeger, Michael Rinderer, and Markus Weiler
Hydrol. Earth Syst. Sci., 27, 3701–3718, https://doi.org/10.5194/hess-27-3701-2023, https://doi.org/10.5194/hess-27-3701-2023, 2023
Short summary
Short summary
We present a method to collect water vapor samples into bags in the field without an in-field analyser, followed by isotope analysis in the lab. This new method resolves even fine-scaled natural isotope variations. It combines low-cost and lightweight components for maximum spatial and temporal flexibility regarding environmental setups. Hence, it allows for sampling even in terrains that are rather difficult to access, enabling future extended isotope datasets in soil sciences and ecohydrology.
Daniel Rasche, Jannis Weimar, Martin Schrön, Markus Köhli, Markus Morgner, Andreas Güntner, and Theresa Blume
Hydrol. Earth Syst. Sci., 27, 3059–3082, https://doi.org/10.5194/hess-27-3059-2023, https://doi.org/10.5194/hess-27-3059-2023, 2023
Short summary
Short summary
We introduce passive downhole cosmic-ray neutron sensing (d-CRNS) as an approach for the non-invasive estimation of soil moisture in deeper layers of the unsaturated zone which exceed the observational window of above-ground CRNS applications. Neutron transport simulations are used to derive mathematical descriptions and transfer functions, while experimental measurements in an existing groundwater observation well illustrate the feasibility and applicability of the approach.
Guillaume Blanchy, Lukas Albrecht, Gilberto Bragato, Sarah Garré, Nicholas Jarvis, and John Koestel
Hydrol. Earth Syst. Sci., 27, 2703–2724, https://doi.org/10.5194/hess-27-2703-2023, https://doi.org/10.5194/hess-27-2703-2023, 2023
Short summary
Short summary
We collated the Open Tension-disk Infiltrometer Meta-database (OTIM). We analysed topsoil hydraulic conductivities at supply tensions between 0 and 100 mm of 466 data entries. We found indications of different flow mechanisms at saturation and at tensions >20 mm. Climate factors were better correlated with near-saturated hydraulic conductivities than soil properties. Land use, tillage system, soil compaction and experimenter bias significantly influenced K to a similar degree to soil properties.
Kai-Gao Ouyang, Xiao-Wei Jiang, Gang Mei, Hong-Bin Yan, Ran Niu, Li Wan, and Yijian Zeng
Hydrol. Earth Syst. Sci., 27, 2579–2590, https://doi.org/10.5194/hess-27-2579-2023, https://doi.org/10.5194/hess-27-2579-2023, 2023
Short summary
Short summary
Our knowledge on sources and dynamics of rock moisture is limited. By using frequency domain reflectometry (FDR), we monitored rock moisture in a cave. The results of an explainable deep learning model reveal that the direct source of rock moisture responsible for weathering in the studied cave is vapour, not infiltrating precipitation. A physics-informed deep learning model, which uses variables controlling vapor condensation as model inputs, leads to accurate rock water content predictions.
Giovanna Dragonetti, Mohammad Farzamian, Angelo Basile, Fernando Monteiro Santos, and Antonio Coppola
Hydrol. Earth Syst. Sci., 26, 5119–5136, https://doi.org/10.5194/hess-26-5119-2022, https://doi.org/10.5194/hess-26-5119-2022, 2022
Short summary
Short summary
Soil hydraulic and hydrodispersive properties are necessary for modeling water and solute fluxes in agricultural and environmental systems. Despite the major efforts in developing methods (e.g., lab-based, pedotransfer functions), their characterization at applicative scales remains an imperative requirement. Thus, this paper proposes a noninvasive in situ method integrating electromagnetic induction and hydrological modeling to estimate soil hydraulic and transport properties at the plot scale.
Daniel Rasche, Markus Köhli, Martin Schrön, Theresa Blume, and Andreas Güntner
Hydrol. Earth Syst. Sci., 25, 6547–6566, https://doi.org/10.5194/hess-25-6547-2021, https://doi.org/10.5194/hess-25-6547-2021, 2021
Short summary
Short summary
Cosmic-ray neutron sensing provides areal average soil moisture measurements. We investigated how distinct differences in spatial soil moisture patterns influence the soil moisture estimates and present two approaches to improve the estimate of soil moisture close to the instrument by reducing the influence of soil moisture further afield. Additionally, we show that the heterogeneity of soil moisture can be assessed based on the relationship of different neutron energies.
Wouter Dorigo, Irene Himmelbauer, Daniel Aberer, Lukas Schremmer, Ivana Petrakovic, Luca Zappa, Wolfgang Preimesberger, Angelika Xaver, Frank Annor, Jonas Ardö, Dennis Baldocchi, Marco Bitelli, Günter Blöschl, Heye Bogena, Luca Brocca, Jean-Christophe Calvet, J. Julio Camarero, Giorgio Capello, Minha Choi, Michael C. Cosh, Nick van de Giesen, Istvan Hajdu, Jaakko Ikonen, Karsten H. Jensen, Kasturi Devi Kanniah, Ileen de Kat, Gottfried Kirchengast, Pankaj Kumar Rai, Jenni Kyrouac, Kristine Larson, Suxia Liu, Alexander Loew, Mahta Moghaddam, José Martínez Fernández, Cristian Mattar Bader, Renato Morbidelli, Jan P. Musial, Elise Osenga, Michael A. Palecki, Thierry Pellarin, George P. Petropoulos, Isabella Pfeil, Jarrett Powers, Alan Robock, Christoph Rüdiger, Udo Rummel, Michael Strobel, Zhongbo Su, Ryan Sullivan, Torbern Tagesson, Andrej Varlagin, Mariette Vreugdenhil, Jeffrey Walker, Jun Wen, Fred Wenger, Jean Pierre Wigneron, Mel Woods, Kun Yang, Yijian Zeng, Xiang Zhang, Marek Zreda, Stephan Dietrich, Alexander Gruber, Peter van Oevelen, Wolfgang Wagner, Klaus Scipal, Matthias Drusch, and Roberto Sabia
Hydrol. Earth Syst. Sci., 25, 5749–5804, https://doi.org/10.5194/hess-25-5749-2021, https://doi.org/10.5194/hess-25-5749-2021, 2021
Short summary
Short summary
The International Soil Moisture Network (ISMN) is a community-based open-access data portal for soil water measurements taken at the ground and is accessible at https://ismn.earth. Over 1000 scientific publications and thousands of users have made use of the ISMN. The scope of this paper is to inform readers about the data and functionality of the ISMN and to provide a review of the scientific progress facilitated through the ISMN with the scope to shape future research and operations.
Hongxiu Wang, Jingjing Jin, Buli Cui, Bingcheng Si, Xiaojun Ma, and Mingyi Wen
Hydrol. Earth Syst. Sci., 25, 5399–5413, https://doi.org/10.5194/hess-25-5399-2021, https://doi.org/10.5194/hess-25-5399-2021, 2021
Short summary
Short summary
Evaporation led to progressively more heavy-isotope-enriched bulk soil water (BW) following the precipitation/irrigation of heavy-isotope-depleted new water but causes progressively more heavy-isotope-depleted BW following irrigation of heavy-isotope-enriched new water. The results indicated that δ2H and δ18O in evaporating water (EW) were similar to new water and differed from BW. However, the evaporative water loss calculated from BW did not differ significantly from that of EW.
Benjamin Gralher, Barbara Herbstritt, and Markus Weiler
Hydrol. Earth Syst. Sci., 25, 5219–5235, https://doi.org/10.5194/hess-25-5219-2021, https://doi.org/10.5194/hess-25-5219-2021, 2021
Short summary
Short summary
We scrutinized the quickest currently available method for stable isotope analysis of matrix-bound water. Simulating common procedures, we demonstrated the limits of certain materials currently used and identified a reliable and cost-efficient alternative. Further, we calculated the optimum proportions of important protocol aspects critical for precise and accurate analyses. Our unifying protocol suggestions increase data quality and comparability as well as the method's general applicability.
Maik Heistermann, Till Francke, Martin Schrön, and Sascha E. Oswald
Hydrol. Earth Syst. Sci., 25, 4807–4824, https://doi.org/10.5194/hess-25-4807-2021, https://doi.org/10.5194/hess-25-4807-2021, 2021
Short summary
Short summary
Cosmic-ray neutron sensing (CRNS) is a powerful technique for retrieving representative estimates of soil moisture in footprints extending over hectometres in the horizontal and decimetres in the vertical. This study, however, demonstrates the potential of CRNS to obtain spatio-temporal patterns of soil moisture beyond isolated footprints. To that end, we analyse data from a unique observational campaign that featured a dense network of more than 20 neutron detectors in an area of just 1 km2.
Markus Merk, Nadine Goeppert, and Nico Goldscheider
Hydrol. Earth Syst. Sci., 25, 3519–3538, https://doi.org/10.5194/hess-25-3519-2021, https://doi.org/10.5194/hess-25-3519-2021, 2021
Short summary
Short summary
Soil moisture levels have decreased significantly over the past 2 decades. This decrease is not uniformly distributed over the observation period. The largest changes occur at tipping points during years of extreme drought, after which soil moisture levels reach significantly different alternate stable states. Not only the overall trend in soil moisture is affected, but also the seasonal dynamics.
Elad Yeshno, Ofer Dahan, Shoshana Bernstain, and Shlomi Arnon
Hydrol. Earth Syst. Sci., 25, 2159–2168, https://doi.org/10.5194/hess-25-2159-2021, https://doi.org/10.5194/hess-25-2159-2021, 2021
Short summary
Short summary
In this research, we present a novel approach, enabling the measurement of nitrate concentrations in natural soil porewater containing natural soil dissolved organic carbon. This method can be used as the basis onto which an affordable and miniaturized nitrate monitoring sensor for soils can be developed. This sensor can play a significant role in reducing nitrate pollution in water resources, optimizing fertilizers application during agricultural activity and decreasing food production costs.
Laurent Gourdol, Rémi Clément, Jérôme Juilleret, Laurent Pfister, and Christophe Hissler
Hydrol. Earth Syst. Sci., 25, 1785–1812, https://doi.org/10.5194/hess-25-1785-2021, https://doi.org/10.5194/hess-25-1785-2021, 2021
Short summary
Short summary
Electrical resistivity tomography (ERT) is a remarkable tool for characterizing the regolith, but its use over large areas remains cumbersome due to the requirement of small electrode spacing (ES). In this study we document the issues of using oversized ESs and propose a new approach to overcome this limitation. We demonstrate that our protocol significantly improves the accuracy of ERT profiles using large ES and offers a cost-effective means for carrying out large-scale surveys.
Alex Mavrovic, Renato Pardo Lara, Aaron Berg, François Demontoux, Alain Royer, and Alexandre Roy
Hydrol. Earth Syst. Sci., 25, 1117–1131, https://doi.org/10.5194/hess-25-1117-2021, https://doi.org/10.5194/hess-25-1117-2021, 2021
Short summary
Short summary
This paper presents a new probe that measures soil microwave permittivity in the frequency range of satellite L-band sensors. The probe capacities will allow for validation and calibration of the models used to estimate landscape physical properties from raw microwave satellite datasets. Our results show important discrepancies between model estimates and instrument measurements that will need to be addressed.
Bruno Meurers, Gábor Papp, Hannu Ruotsalainen, Judit Benedek, and Roman Leonhardt
Hydrol. Earth Syst. Sci., 25, 217–236, https://doi.org/10.5194/hess-25-217-2021, https://doi.org/10.5194/hess-25-217-2021, 2021
Short summary
Short summary
Gravity and tilt time series acquired at Conrad Observatory (Austria) reflect gravity and deformation associated with short- and long-term environmental processes, revealing a complex water transport process after heavy rain and rapid snowmelt. Gravity residuals are sensitive to the Newtonian effect of water mass transport. Tilt residual anomalies capture strain–tilt coupling effects due to surface or subsurface deformation from precipitation or pressure changes in the adjacent fracture system.
Yiben Cheng, Xinle Li, Yunqi Wang, Hongbin Zhan, Wenbin Yang, and Qunou Jiang
Hydrol. Earth Syst. Sci., 24, 5875–5890, https://doi.org/10.5194/hess-24-5875-2020, https://doi.org/10.5194/hess-24-5875-2020, 2020
Short summary
Short summary
The Three North Forest Program has produced a vast area of lined forest in semi-arid regions, which consumes a large amount of water resources. This study uses a newly designed lysimeter to measure water distribution without destroying the in situ vegetation soil structure. It addresses the shortcomings of a traditional lysimeter, in terms of changing the in situ soil structure and destroying the vegetation root system, and the shortcomings of high costs and inconvenient installation.
Jie Tian, Zhibo Han, Heye Reemt Bogena, Johan Alexander Huisman, Carsten Montzka, Baoqing Zhang, and Chansheng He
Hydrol. Earth Syst. Sci., 24, 4659–4674, https://doi.org/10.5194/hess-24-4659-2020, https://doi.org/10.5194/hess-24-4659-2020, 2020
Short summary
Short summary
Large-scale profile soil moisture (SM) is important for water resource management, but its estimation is a challenge. Thus, based on in situ SM observations in a cold mountain, a strong relationship between the surface SM and subsurface SM is found. Both the subsurface SM of 10–30 cm and the profile SM of 0–70 cm can be estimated from the surface SM of 0–10 cm accurately. By combing with the satellite product, we improve the large-scale profile SM estimation in the cold mountains finally.
Amani Mahindawansha, Christoph Külls, Philipp Kraft, and Lutz Breuer
Hydrol. Earth Syst. Sci., 24, 3627–3642, https://doi.org/10.5194/hess-24-3627-2020, https://doi.org/10.5194/hess-24-3627-2020, 2020
Short summary
Short summary
Stable isotopes of soil water are an effective tool to reveal soil hydrological processes in irrigated agricultural fields. Flow mechanisms and isotopic patterns of soil water in the soil matrix differ, depending on the crop and irrigation practices. Isotope data supported the fact that unproductive water losses via evaporation can be reduced by introducing dry seasonal crops to the crop rotation system.
Cinthya Nava-Fernandez, Adam Hartland, Fernando Gázquez, Ola Kwiecien, Norbert Marwan, Bethany Fox, John Hellstrom, Andrew Pearson, Brittany Ward, Amanda French, David A. Hodell, Adrian Immenhauser, and Sebastian F. M. Breitenbach
Hydrol. Earth Syst. Sci., 24, 3361–3380, https://doi.org/10.5194/hess-24-3361-2020, https://doi.org/10.5194/hess-24-3361-2020, 2020
Short summary
Short summary
Speleothems are powerful archives of past climate for understanding modern local hydrology and its relation to regional circulation patterns. We use a 3-year monitoring dataset to test the sensitivity of Waipuna Cave to seasonal changes and El Niño–Southern Oscillation (ENSO) dynamics. Drip water data suggest a fast response to rainfall events; its elemental composition reflects a seasonal cycle and ENSO variability. Waipuna Cave speleothems have a high potential for past ENSO reconstructions.
Anne Hartmann, Ekaterina Semenova, Markus Weiler, and Theresa Blume
Hydrol. Earth Syst. Sci., 24, 3271–3288, https://doi.org/10.5194/hess-24-3271-2020, https://doi.org/10.5194/hess-24-3271-2020, 2020
Short summary
Short summary
Our field observation-based examination of flow path evolution, soil formation, and vegetation succession across 10 millennia shows how water flow paths and subsurface water storage are linked to the organization of evolving landscapes.
The increase found in water storage and preferential flow paths with increasing soil age shows the effect of the complex interaction of vegetation and soil development on flow paths, water balance, and runoff formation during landscape evolution.
Subodh Acharya, Daniel McLaughlin, David Kaplan, and Matthew J. Cohen
Hydrol. Earth Syst. Sci., 24, 1859–1870, https://doi.org/10.5194/hess-24-1859-2020, https://doi.org/10.5194/hess-24-1859-2020, 2020
Short summary
Short summary
Interception is the storage and subsequent evaporation of rain by vegetation and surface litter. Quantifying interception is critical for understanding the water balance, but it can be difficult and costly to measure. We developed an approach to estimate interception using automated soil moisture measurements during rainfall events. Results suggest that interception can be estimated using soil moisture data, leading to potential cost savings and logistical advantages over conventional methods.
Marcus Bork, Jens Lange, Markus Graf-Rosenfellner, and Friederike Lang
Hydrol. Earth Syst. Sci., 24, 977–989, https://doi.org/10.5194/hess-24-977-2020, https://doi.org/10.5194/hess-24-977-2020, 2020
Short summary
Short summary
Fluorescent tracers such as uranine and sulforhodamine B are useful tools to gain knowledge about water and solute fluxes in aquatic and terrestrial ecosystems. In this study we systematically investigated the influence of important soil properties (pH, organic carbon content and texture) on tracer adsorption in soils and sediments. These properties also determine whether the tracers in the respective soil behave conservatively or non-conservatively.
Adam R. Mangel, Stephen M. J. Moysey, and John Bradford
Hydrol. Earth Syst. Sci., 24, 159–167, https://doi.org/10.5194/hess-24-159-2020, https://doi.org/10.5194/hess-24-159-2020, 2020
Short summary
Short summary
Water flows through soils in an incredibly complex network of pathways. Understanding these pathways is critical to sustainable use of water resources. Ground-penetrating radar (GPR) can image water in near-surface soils the same way an X-ray is used to image the human body. Utilizing innovative ways of collecting and processing the GPR data, we can image complex water flow in space and through time, which allows for the continued development of our ideas and models of subsurface water flow.
Aaron A. Mohammed, Igor Pavlovskii, Edwin E. Cey, and Masaki Hayashi
Hydrol. Earth Syst. Sci., 23, 5017–5031, https://doi.org/10.5194/hess-23-5017-2019, https://doi.org/10.5194/hess-23-5017-2019, 2019
Short summary
Short summary
In cold regions, the permeability of the frozen ground is an important factor influencing a watershed's response to snowmelt. This study highlights the effects of preferential flow in frozen soils on snowmelt redistribution and groundwater recharge in seasonally frozen landscapes.
Dominic Demand, Theresa Blume, and Markus Weiler
Hydrol. Earth Syst. Sci., 23, 4869–4889, https://doi.org/10.5194/hess-23-4869-2019, https://doi.org/10.5194/hess-23-4869-2019, 2019
Short summary
Short summary
This study presents an analysis of 135 soil moisture profiles for identification of the spatial and temporal preferential flow occurrence in a complex landscape. Especially dry conditions and high rainfall intensities were found to increase preferential flow occurrence in soils. This results in a seasonal pattern of preferential flow with a higher occurrence in summer. During this time grasslands showed increased flow velocities, whereas forest sites exhibited a higher amount of bypass flow.
Elad Yeshno, Shlomi Arnon, and Ofer Dahan
Hydrol. Earth Syst. Sci., 23, 3997–4010, https://doi.org/10.5194/hess-23-3997-2019, https://doi.org/10.5194/hess-23-3997-2019, 2019
Short summary
Short summary
Lack of adequate instrumentation for monitoring nutrient availability in agricultural soils leads in most cases to over-application of fertilizers, often resulting in groundwater pollution. This research presents a novel approach for real-time, in situ monitoring of nitrate in soils using absorption spectroscopy techniques while preventing interference from dissolved organic carbon. Column experiments with this system resulted in accurate nitrate measurements in three different soil types.
Alessandro Comegna, Antonio Coppola, Giovanna Dragonetti, and Angelo Sommella
Hydrol. Earth Syst. Sci., 23, 3593–3602, https://doi.org/10.5194/hess-23-3593-2019, https://doi.org/10.5194/hess-23-3593-2019, 2019
Short summary
Short summary
We carried out a series of laboratory-controlled experiments in order to simulate different scenarios of practical interest aiming to analyze, from a dielectric point of view, the influence of different washing solutions on non-aqueous phase liquid (NAPL) removal. Furthermore, on the basis of the results obtained, we validated a dielectric mixing model for predicting the volumetric amounts of NAPL (θNAPL) within the contaminated soil as the decontamination process progressed.
Mireia Fontanet, Daniel Fernàndez-Garcia, and Francesc Ferrer
Hydrol. Earth Syst. Sci., 22, 5889–5900, https://doi.org/10.5194/hess-22-5889-2018, https://doi.org/10.5194/hess-22-5889-2018, 2018
Short summary
Short summary
One of the main objectives of remote sensing methodology is to downscale soil moisture to improve irrigation management. The DISPATCH algorithm is able to measure soil moisture at 1 km resolution using SMOS and MODIS data. In this work DISPATCH has been evaluated with soil moisture sensors, under heterogeneous conditions where local irrigation is applied. Results show that DISPATCH is not sensitive when local irrigation is applied even at low resolution.
Cédric Champollion, Sabrina Deville, Jean Chéry, Erik Doerflinger, Nicolas Le Moigne, Roger Bayer, Philippe Vernant, and Naomi Mazzilli
Hydrol. Earth Syst. Sci., 22, 3825–3839, https://doi.org/10.5194/hess-22-3825-2018, https://doi.org/10.5194/hess-22-3825-2018, 2018
Short summary
Short summary
Gravity monitoring at the surface and in situ (in caves) has been conducted in a karst hydro-system in the south of France (Larzac plateau). Subsurface water storage is evidenced with a spatial variability probably associated with lithology differences and confirmed by MRS measurements. Gravity allows transient water storage to be estimated on the seasonal scale.
Natalie Orlowski, Lutz Breuer, Nicolas Angeli, Pascal Boeckx, Christophe Brumbt, Craig S. Cook, Maren Dubbert, Jens Dyckmans, Barbora Gallagher, Benjamin Gralher, Barbara Herbstritt, Pedro Hervé-Fernández, Christophe Hissler, Paul Koeniger, Arnaud Legout, Chandelle Joan Macdonald, Carlos Oyarzún, Regine Redelstein, Christof Seidler, Rolf Siegwolf, Christine Stumpp, Simon Thomsen, Markus Weiler, Christiane Werner, and Jeffrey J. McDonnell
Hydrol. Earth Syst. Sci., 22, 3619–3637, https://doi.org/10.5194/hess-22-3619-2018, https://doi.org/10.5194/hess-22-3619-2018, 2018
Short summary
Short summary
To extract water from soils for isotopic analysis, cryogenic water extraction is the most widely used removal technique. This work presents results from a worldwide laboratory intercomparison test of cryogenic extraction systems. Our results showed large differences in retrieved isotopic signatures among participating laboratories linked to interactions between soil type and properties, system setup, extraction efficiency, extraction system leaks, and each lab’s internal accuracy.
Ashley R. Pales, Biting Li, Heather M. Clifford, Shyla Kupis, Nimisha Edayilam, Dawn Montgomery, Wei-zhen Liang, Mine Dogan, Nishanth Tharayil, Nicole Martinez, Stephen Moysey, Brian Powell, and Christophe J. G. Darnault
Hydrol. Earth Syst. Sci., 22, 2487–2509, https://doi.org/10.5194/hess-22-2487-2018, https://doi.org/10.5194/hess-22-2487-2018, 2018
Arnaud Watlet, Olivier Kaufmann, Antoine Triantafyllou, Amaël Poulain, Jonathan E. Chambers, Philip I. Meldrum, Paul B. Wilkinson, Vincent Hallet, Yves Quinif, Michel Van Ruymbeke, and Michel Van Camp
Hydrol. Earth Syst. Sci., 22, 1563–1592, https://doi.org/10.5194/hess-22-1563-2018, https://doi.org/10.5194/hess-22-1563-2018, 2018
Short summary
Short summary
Understanding water infiltration in karst regions is crucial as the aquifers they host provide drinkable water for a quarter of the world's population. We present a non-invasive tool to image hydrological processes in karst systems. At our field site, the injection of electrical current in the ground, repeated daily over a 3-year period, allowed imaging changes in the groundwater content. We show that specific geological layers control seasonal to rainfall-triggered water infiltration dynamics.
Giovanna Dragonetti, Alessandro Comegna, Ali Ajeel, Gian Piero Deidda, Nicola Lamaddalena, Giuseppe Rodriguez, Giulio Vignoli, and Antonio Coppola
Hydrol. Earth Syst. Sci., 22, 1509–1523, https://doi.org/10.5194/hess-22-1509-2018, https://doi.org/10.5194/hess-22-1509-2018, 2018
Short summary
Short summary
The paper aims to infer the bulk electrical conductivity distribution in the root zone from EMI readings. TDR measurements were used as ground-truth data to evaluate the goodness of the estimations by EMI inversion. The approach is based on the mean and standard deviation of the EMI and TDR series. It looks for the physical reasons for the differences between EMI- and TDR-based electrical conductivity and provides a correction of the bias based on the statistical sources of the discrepancies.
David McJannet, Aaron Hawdon, Brett Baker, Luigi Renzullo, and Ross Searle
Hydrol. Earth Syst. Sci., 21, 6049–6067, https://doi.org/10.5194/hess-21-6049-2017, https://doi.org/10.5194/hess-21-6049-2017, 2017
Short summary
Short summary
Satellite and broad-scale model estimates of soil moisture have improved in resolution. However, validation and calibration of these products has been limited because of a lack of observations on corresponding scales. We use a mobile soil moisture monitoring platform, known as the
rover, to derive soil moisture at 9 km and 1 km resolution. We describe methods to calculate soil moisture and present results from multiple surveys. The products produced are well suited to validation studies.
Xicai Pan, Warren Helgason, Andrew Ireson, and Howard Wheater
Hydrol. Earth Syst. Sci., 21, 5401–5413, https://doi.org/10.5194/hess-21-5401-2017, https://doi.org/10.5194/hess-21-5401-2017, 2017
Short summary
Short summary
In this paper we present a case study from a heterogeneous pasture site in the Canadian prairies, where we have quantified the various components of the water balance on the field scale, and critically examine some of the simplifying assumptions which are often invoked when applying water budget approaches in applied hydrology. We highlight challenges caused by lateral fluxes of blowing snow and ambiguous partitioning of snow melt water into runoff and infiltration.
Martin Schrön, Markus Köhli, Lena Scheiffele, Joost Iwema, Heye R. Bogena, Ling Lv, Edoardo Martini, Gabriele Baroni, Rafael Rosolem, Jannis Weimar, Juliane Mai, Matthias Cuntz, Corinna Rebmann, Sascha E. Oswald, Peter Dietrich, Ulrich Schmidt, and Steffen Zacharias
Hydrol. Earth Syst. Sci., 21, 5009–5030, https://doi.org/10.5194/hess-21-5009-2017, https://doi.org/10.5194/hess-21-5009-2017, 2017
Short summary
Short summary
A field-scale average of near-surface water content can be sensed by cosmic-ray neutron detectors. To interpret, calibrate, and validate the integral signal, it is important to account for its sensitivity to heterogeneous patterns like dry or wet spots. We show how point samples contribute to the neutron signal based on their depth and distance from the detector. This approach robustly improves the sensor performance and data consistency, and even reveals otherwise hidden hydrological features.
Yiben Cheng, Hongbin Zhan, Wenbin Yang, Hongzhong Dang, and Wei Li
Hydrol. Earth Syst. Sci., 21, 5031–5042, https://doi.org/10.5194/hess-21-5031-2017, https://doi.org/10.5194/hess-21-5031-2017, 2017
Short summary
Short summary
This study uses a newly designed lysimeter to study three consecutive years (2013–2015) of deep soil recharge (DSR) underneath bare sand land on the eastern margin of Mu Us Sandy Land in the Ordos Basin of China. The objective is to identify the characteristics of the DSR distribution and the factors affecting the DSR distribution. Specifically, we would like to examine if the commonly used recharge coefficient concept can be applied for arid and semi-arid regions.
Ofer Dahan, Idan Katz, Lior Avishai, and Zeev Ronen
Hydrol. Earth Syst. Sci., 21, 4011–4020, https://doi.org/10.5194/hess-21-4011-2017, https://doi.org/10.5194/hess-21-4011-2017, 2017
Short summary
Short summary
In situ bioremediation of a perchlorate-contaminated vadose zone was conducted through infiltration of electron-donor-enriched water. A vadose zone monitoring system (VMS) provided real-time tracking of the hydraulic and chemical conditions across the unsaturated zone. Variations in concentration profiles of perchlorate, chloride, DOC and bromide in the vadose zone pore water showed limited migration capacity of biologically consumable carbon and significant mobilization of perchlorate.
Cécile Pellet and Christian Hauck
Hydrol. Earth Syst. Sci., 21, 3199–3220, https://doi.org/10.5194/hess-21-3199-2017, https://doi.org/10.5194/hess-21-3199-2017, 2017
Short summary
Short summary
This paper presents a detailed description of the new Swiss soil moisture monitoring network SOMOMOUNT, which comprises six stations distributed along an elevation gradient ranging from 1205 to 3410 m. The liquid soil moisture (LSM) data collected during the first 3 years are discussed with regard to their soil type and climate dependency as well as their altitudinal distribution. The elevation dependency of the LSM was found to be non-linear with distinct dynamics at high and low elevation.
Simon Matthias Kleinknecht, Holger Class, and Jürgen Braun
Hydrol. Earth Syst. Sci., 21, 1381–1396, https://doi.org/10.5194/hess-21-1381-2017, https://doi.org/10.5194/hess-21-1381-2017, 2017
Short summary
Short summary
Retardation of migrating contaminant vapors in the subsurface may mitigate groundwater contamination or vapor intrusion into buildings. An experimental investigation was conducted to quantify the retardation of carbon disulfide (CS2) vapor in moist porous media based on the analysis of concentration breakthrough curves. Findings linked retardation to types of porous media and water saturation. Moreover, the first evidence of biodegradation of the CS2 vapor was found in the column experiments.
Edoardo Martini, Ulrike Werban, Steffen Zacharias, Marco Pohle, Peter Dietrich, and Ute Wollschläger
Hydrol. Earth Syst. Sci., 21, 495–513, https://doi.org/10.5194/hess-21-495-2017, https://doi.org/10.5194/hess-21-495-2017, 2017
Short summary
Short summary
With a process-based interpretation of electromagnetic induction measurements, we discussed the potential and limitations of such a method for soil moisture mapping. Results will help clarify the complex and time-varying effect of stable soil properties and dynamic state variables on the physical parameters measured, with implications for future studies. We highlighted the importance of time-series data and the need for a multidisciplinary approach for proper interpretation.
Carol V. Tadros, Pauline C. Treble, Andy Baker, Ian Fairchild, Stuart Hankin, Regina Roach, Monika Markowska, and Janece McDonald
Hydrol. Earth Syst. Sci., 20, 4625–4640, https://doi.org/10.5194/hess-20-4625-2016, https://doi.org/10.5194/hess-20-4625-2016, 2016
Short summary
Short summary
We investigated the potential use of trace element and stable oxygen-isotope variations in cave drip water as palaeorainfall proxies in an Australian alpine karst site. Using 7 years of cave monitoring data, we constrained the hydrological processes impacting the drip-water composition and identified a robust ENSO–drip water hydrochemical relationship. These findings are fundamental for reconstructing past ENSO variability from speleothems (cave deposits) regionally and globally.
William Alexander Avery, Catherine Finkenbiner, Trenton E. Franz, Tiejun Wang, Anthony L. Nguy-Robertson, Andrew Suyker, Timothy Arkebauer, and Francisco Muñoz-Arriola
Hydrol. Earth Syst. Sci., 20, 3859–3872, https://doi.org/10.5194/hess-20-3859-2016, https://doi.org/10.5194/hess-20-3859-2016, 2016
Short summary
Short summary
Here we present a strategy to use globally available datasets in the calibration function used to convert observed moderated neutron counts into volumetric soil water content. While local sampling protocols are well documented for fixed probes, the use of roving probes presents new calibration challenges. With over 200 fixed probes and 10 roving probes in use globally, we anticipate this paper will serve as a keystone for the growing cosmic-ray neutron probe and hydrologic community.
Tuvia Turkeltaub, Daniel Kurtzman, and Ofer Dahan
Hydrol. Earth Syst. Sci., 20, 3099–3108, https://doi.org/10.5194/hess-20-3099-2016, https://doi.org/10.5194/hess-20-3099-2016, 2016
Short summary
Short summary
Efficient groundwater protection from pollution originating in agriculture requires effective monitoring means capable of tacking pollution processes in the vadose zone, long before groundwater pollution turns into an unavoidable fact. In this study, a vadose zone monitoring system that was installed under a crop field fertilized by dairy slurry enabled real-time tracking of nitrate plum migration down the vadose zone from the land surface to the water table at 18m depth.
Andre Peters, Thomas Nehls, and Gerd Wessolek
Hydrol. Earth Syst. Sci., 20, 2309–2315, https://doi.org/10.5194/hess-20-2309-2016, https://doi.org/10.5194/hess-20-2309-2016, 2016
Short summary
Short summary
The AWAT (Adaptive Window and Adaptive Threshold) filter routine for high-resolution lysimeter data is improved. The threshold scheme with original step interpolation yields unrealistic fluxes for high temporal resolution. Improvement applies linear and spline interpolation schemes so that fluxes in high temporal resolution are automatically calculated. The spline scheme allows continuous differentiability of filtered data so that any output resolution for the fluxes is sound.
Cited articles
AEMET: AEMET OpenData, State Meteorological Agency of Spain, https://opendata.aemet.es/centrodedescargas/inicio (last access: 13 September 2021), 2021.
Álvarez, R., Ordóñez, A., Canteli, P., and De Miguel, E.:
Unconventional gas resources in the Cantabrian Zone (NW Spain): A
comprehensive preliminary assessment, Geol. J., 54, 2608–2620,
https://doi.org/10.1002/gj.3314, 2019.
Baker, A., Barnes, W. L., and Smart, P. L.: Variations in the discharge and
organic matter content of stalagmite drip waters in Lower Cave, Bristol,
Hydrol. Process., 11, 1541–1555, https://doi.org/10.1002/(SICI)1099-1085(199709)11:11<1541::AID-HYP484>3.0.CO;2-Z, 1997.
Baker, A., Hartmann, A., Duan, W., Hankin, S., Comas-Bru, L., Cuthbert, M.
O., Treble, P. C., Banner, J., Genty, D., Baldini, L. M., Bartolomé, M.,
Moreno, A., Pérez-Mejías, C., and Werner, M.: Global analysis reveals climatic controls on the oxygen isotope composition of cave drip water, Nat. Commun., 10, 2984, https://doi.org/10.1038/s41467-019-11027-w, 2019.
Baker, A., Berthelin, R., Cuthbert, M. O., Treble, P. C., Hartmann, A., and
Kss Cave Studies Team: Rainfall recharge thresholds in a subtropical climate determined using a regional cave drip water monitoring network, J. Hydrol., 587, 125001, https://doi.org/10.1016/j.jhydrol.2020.125001, 2020.
Baker, A., Scheller, M., Oriani, F., Mariethoz, G., Hartmann, A., Wang, Z.,
and Cuthbert, M. O.: Quantifying temporal variability and spatial heterogeneity in rainfall recharge thresholds in a montane karst environment, J. Hydrol., 594, 125965, https://doi.org/10.1016/j.jhydrol.2021.125965, 2021.
Baldini, J. U. L., McDermott, F., Baldini, L. M., Ottley, C. J., Linge, K.
L., Clipson, N., and Jarvis, K. E.: Identifying short-term and seasonal trends in cave drip water trace element concentrations based on a daily-scale automatically collected drip water dataset, Chem. Geol., 330–331, 1–16, https://doi.org/10.1016/j.chemgeo.2012.08.009, 2012.
Benzaama, M. H., Menhoudj, S., Kontoleon, K. J., Mokhtari, A. M., and Lekhal, M. C.: Investigation of the thermal behavior of a combined geothermal system for cooling with regards to Algeria's climate, Sustain. Cities Soc., 43, 121–133, https://doi.org/10.1016/j.scs.2018.08.016, 2018.
Borsato, A., Frisia, S., Fairchild, I. J., Somogyi, A., and Susini, J.:
Trace element distribution in annual stalagmite laminae mapped by micrometer-resolution X-ray fluorescence: Implications for incorporation of
environmentally significant species, Geochim. Cosmochim. Ac., 71, 1494–1512, https://doi.org/10.1016/j.gca.2006.12.016, 2007.
Borsato, A., Frisia, S., and Miorandi, R.: Carbon dioxide concentration in
temperate climate caves and parent soils over an altitudinal gradient and
its influence on speleothem growth and fabrics, Earth Surf. Proc. Land., 40, 1158–1170, https://doi.org/10.1002/esp.3706, 2015.
Bradley, C., Baker, A., Jex, C. N., and Leng, M. J.: Hydrological uncertainties in the modelling of cave drip-water ä18O and the
implications for stalagmite palaeoclimate reconstructions, Quaternary Sci. Rev., 29, 2201–2214, https://doi.org/10.1016/j.quascirev.2010.05.017, 2010.
Breitenbach, S. F. M., Lechleitner, F. A., Meyer, H., Diengdoh, G., Mattey,
D., and Marwan, N.: Cave ventilation and rainfall signals in dripwater in a
monsoonal setting – a monitoring study from NE India, Chem. Geol., 402, 111–124, https://doi.org/10.1016/j.chemgeo.2015.03.011, 2015.
Brooksbank, K., Veneklaas, E. J., White, D. A., and Carter, J. L.: The fate
of hydraulically redistributed water in a semi-arid zone eucalyptus species,
Tree Physiol., 31, 649–658, https://doi.org/10.1093/treephys/tpr052, 2011.
Craig, H.: Isotopic Variations in Meteoric Waters, Science, 133, 1702–1703,
https://doi.org/10.1126/science.133.3465.1702, 1961.
Dasgupta, S., Mohanty, B. P., and Köhne, J. M.: Impacts of Juniper Vegetation and Karst Geology on Subsurface Flow Processes in the Edwards Plateau, Texas, Vadose Zone J., 5, 1076–1085, https://doi.org/10.2136/vzj2005.0073, 2006.
Deininger, M. and Scholz, D.: ISOLUTION 1.0: an ISOtope evoLUTION model
describing the stable oxygen (δ18O) and carbon (δ13C) isotope values of speleothems, Int. J. Speleol., 48, 21–32, 2019.
Deininger, M., Hansen, M., Fohlmeister, J., Schröder-Ritzrau, A., Burstyn, Y., and Scholz, D.: Are oxygen isotope fractionation factors
between calcite and water derived from speleothems systematically biased due
to prior calcite precipitation (PCP)?, Geochim. Cosmochim. Ac., 305, 212–227, https://doi.org/10.1016/j.gca.2021.03.026, 2021.
de Villiers, S., Greaves, M., and Elderfield, H.: An intensity ratio
calibration method for the accurate determination of and of marine carbonates by ICP-AES, Geochem. Geophy. Geosy., 3, 1–14, https://doi.org/10.1029/2001GC000169, 2002.
Domínguez-Villar, D., Krklec, K., Boomer, I., and Fairchild, I. J.:
ISODRIP, a model to transfer the δ18O signal of precipitation to drip water – Implementation of the model for Eagle Cave (central Spain), Sci. Total Environ., 797, 149188, https://doi.org/10.1016/j.scitotenv.2021.149188, 2021.
Dredge, J., Fairchild, I. J., Harrison, R. M., Fernandez-Cortes, A.,
Sanchez-Moral, S., Jurado, V., Gunn, J., Smith, A., Spötl, C., Mattey,
D., Wynn, P. M., and Grassineau, N.: Cave aerosols: distribution and contribution to speleothem geochemistry, Quaternary Sci. Rev., 63, 23–41, https://doi.org/10.1016/j.quascirev.2012.11.016, 2013.
Dreybrodt, W.: Chemical kinetics, speleothem growth and climate, Boreas, 28,
347–356, https://doi.org/10.1111/j.1502-3885.1999.tb00224.x, 1999.
Eylem, C., Erten, H. N., and Göktürk, H.: Sorption-desorption
behaviour of barium on clays, J. Environ. Radioactiv., 11, 183–200, https://doi.org/10.1016/0265-931X(90)90061-Y, 1990.
Fairchild, I. J. and Baker, A.: Speleothem Science: from process to past environments, in: Blackwell Quaternary Geoscience Series, Wiley-Blackwell, ISBN 978-1-4051-9620-8, 2012.
Fairchild, I. J. and Treble, P. C.: Trace elements in speleothems as
recorders of environmental change, Quaternary Sci. Rev. 28, 449–468,
https://doi.org/10.1016/j.quascirev.2008.11.007, 2009.
Fairchild, I. J., Borsato, A., Tooth, A. F., Frisia, S., Hawkesworth, C. J.,
Huang, Y., McDermott, F., and Spiro, B.: Controls on trace element (Sr–Mg)
compositions of carbonate cave waters: implications for speleothem climatic
records, Chem. Geol., 166, 255–269, https://doi.org/10.1016/S0009-2541(99)00216-8, 2000.
Fairchild, I. J., Spötl, C., Frisia, S., Borsato, A., Susini, J., Wynn,
P. M., Cauzid, J., EIMF, Pedley, H. M., and Rogerson, M.: Petrology and
geochemistry of annually laminated stalagmites from an Alpine cave (Obir,
Austria): seasonal cave physiology, in: Tufas and Speleothems: Unravelling
the Microbial and Physical Controls, Geological Society of London, https://doi.org/10.1144/sp336.16, 2010.
Faraji, M., Borsato, A., Frisia, S., Hellstrom, J. C., Lorrey, A., Hartland,
A., Greig, A., and Mattey, D. P.: Accurate dating of stalagmites from low
seasonal contrast tropical Pacific climate using Sr 2D maps, fabrics and
annual hydrological cycles, Sci. Rep., 11, 2178, https://doi.org/10.1038/s41598-021-81941-x, 2021.
Feng, W., Casteel, R. C., Banner, J. L., and Heinze-Fry, A.: Oxygen isotope
variations in rainfall, drip-water and speleothem calcite from a well-ventilated cave in Texas, USA: Assessing a new speleothem temperature
proxy, Geochim. Cosmochim. Ac., 127, 233–250, https://doi.org/10.1016/j.gca.2013.11.039, 2014.
Fohlmeister, J., Voarintsoa, N. R., Lechleitner, F., Boyd, M., Brandstätter, S., Jacobson, M., and Oster, J.: Main Controls on the
Stable Carbon Isotope Composition of Speleothems, Geochim. Cosmochim. Ac., 279, 67–87, https://doi.org/10.1016/j.gca.2020.03.042, 2020.
Frisia, S., Fairchild, I. J., Fohlmeister, J., Miorandi, R., Spötl, C.,
and Borsato, A.: Carbon mass-balance modelling and carbon isotope exchange
processes in dynamic caves, Geochim. Cosmochim. Ac., 75, 380–400, 2011.
Genty, D., Blamart, D., Ghaleb, B., Plagnes, V., Causse, C., Bakalowicz, M.,
Zouari, K., Chkir, N., Hellstrom, J., Wainer, K., and Bourges, F.: Timing
and dynamics of the last deglaciation from European and North African
ä13C stalagmite profiles – comparison with Chinese and South Hemisphere
stalagmites, Quaternary Sci. Rev., 25, 2118–2142, https://doi.org/10.1016/j.quascirev.2006.01.030, 2006.
Gibbons, W. and Moreno, T.: The geology of Spain, The Geological Society,
London, 649 pp., ISBN 1-86239-110-6, 2002.
Hamamoto, T. and Uchida, Y.: Sodium Contents in Dairy Cow Urine and Soil
Aggregate Sizes Influence the Amount of Nitrogen Lost from Soil, Appl. Environ. Soil Sci., 2015, 275985, https://doi.org/10.1155/2015/275985, 2015.
Hartland, A., Fairchild, I. J., Lead, J. R., Borsato, A., Baker, A., Frisia,
S., and Baalousha, M.: From soil to cave: Transport of trace metals by natural organic matter in karst dripwaters, Chem. Geol., 304–305, 68–82, https://doi.org/10.1016/j.chemgeo.2012.01.032, 2012.
Hartland, A., Fairchild, I. J., Müller, W., and Dominguez-Villar, D.:
Preservation of NOM-metal complexes in a modern hyperalkaline stalagmite:
Implications for speleothem trace element geochemistry, Geochim. Cosmochim. Ac., 128, 29–43, https://doi.org/10.1016/j.gca.2013.12.005, 2014.
Hasenmueller, E. A., Jin, L., Stinchcomb, G. E., Lin, H., Brantley, S. L.,
and Kaye, J. P.: Topographic controls on the depth distribution of soil CO2 in a small temperate watershed, Appl. Geochem., 63, 58–69, https://doi.org/10.1016/j.apgeochem.2015.07.005, 2015.
Hodges, C., Kim, H., Brantley, S. L., and Kaye, J.: Soil CO2 and O2
Concentrations Illuminate the Relative Importance of Weathering and Respiration to Seasonal Soil Gas Fluctuations, Soil Sci. Soc. Am. J., 83, 1167–1180, https://doi.org/10.2136/sssaj2019.02.0049, 2019.
IAEA/WMO: Global Network of Isotopes in Precipitation., The GNIP Database, https://www.gtn-h.info/gtnh_networks/gnip-gnir/ (last access: 10 January 2022), 2022.
Instituto Geográfico Nacional: Plan Nacional Ortofotografía Aérea – PNOA of Spanish IGN, https://centrodedescargas.cnig.es/CentroDescargas/index.jsp (last access: 24 November 2022), 2022.
James, E. W., Banner, J. L., and Hardt, B.: A global model for cave ventilation and seasonal bias in speleothem paleoclimate records, Geochem. Geophy. Geosy., 16, 1044–1051, https://doi.org/10.1002/2014GC005658, 2015.
Johnson, K. R., Hu, C., Belshaw, N. S., and Henderson, G. M.: Seasonal
trace-element and stable-isotope variations in a Chinese speleothem: The
potential for high-resolution paleomonsoon reconstruction, Earth Planet. Sc. Lett., 244, 394–407, https://doi.org/10.1016/j.epsl.2006.01.064, 2006.
Kabata-Pendias, A. and Pendias, H.: Trace elements in soils and plants, in: 3rd Edn., CRC Press LLC, Boca Raton, Florida, 331 pp., ISBN 0-8493-1575-1, 2000.
Krishna, M. P. and Mohan, M.: Litter decomposition in forest ecosystems: a
review, Energ. Ecol. Environ., 2, 236–249, https://doi.org/10.1007/s40974-017-0064-9, 2017.
Lechleitner, F. A., Day, C. C., Kost, O., Wilhelm, M., Haghipour, N., Henderson, G. M., and Stoll, H. M.: Stalagmite carbon isotopes suggest deglacial increase in soil respiration in western Europe driven by temperature change, Clim. Past, 17, 1903–1918, https://doi.org/10.5194/cp-17-1903-2021, 2021.
Lyu, Y., Luo, W., Wang, Y., Zeng, G., Wang, Y., Cheng, A., Zhang, L., Chen,
J., Cai, X., Zhang, R., and Wang, S.: Impacts of cave ventilation on drip
water δ13CDIC and its paleoclimate implication, Quatern. Int., 547, 7–21, https://doi.org/10.1016/j.quaint.2020.03.050, 2020.
Markowska, M., Baker, A., Andersen, M. S., Jex, C. N., Cuthbert, M. O., Rau,
G. C., Graham, P. W., Rutlidge, H., Mariethoz, G., Marjo, C. E., Treble, P.
C., and Edwards, N.: Semi-arid zone caves: Evaporation and hydrological
controls on δ18O drip water composition and implications for speleothem paleoclimate reconstructions, Quaternary Sci. Rev., 131, 285–301,
https://doi.org/10.1016/j.quascirev.2015.10.024, 2016.
Mattey, D. P., Fairchild, I. J., Atkinson, T. C., Latin, J.-P., Ainsworth, M., and Durell, R.: Seasonal microclimate control of calcite fabrics, stable
isotopes and trace elements in modern speleothem from St Michaels Cave,
Gibraltar, Geol. Soc. Lond. Spec. Publ., 336, 323–344, 2010.
Mattey, D. P., Atkinson, T. C., Barker, J. A., Fisher, R., Latin, J. P.,
Durrell, R., and Ainsworth, M.: Carbon dioxide, ground air and carbon cycling in Gibraltar karst, Geochim. Cosmochim. Ac., 184, 88–113, https://doi.org/10.1016/j.gca.2016.01.041, 2016.
Mishra, S. P. and Tiwary, D.: Ion exchangers in radioactive waste management. Part XI. Removal of barium and strontium ions from aqueous solutions by hydrous ferric oxide, Appl. Radiat. Isotop., 51, 359–366, https://doi.org/10.1016/S0969-8043(99)00065-2, 1999.
Moreno, A., Stoll, H., Jiménez-Sánchez, M., Cacho, I., Valero-Garcés, B., Ito, E., and Edwards, R. L.: A speleothem record of
glacial (25–11.6 kyr BP) rapid climatic changes from northern Iberian
Peninsula, Global Planet. Change, 71, 218–231, https://doi.org/10.1016/j.gloplacha.2009.10.002, 2010.
Moreno, A., Sancho, C., Bartolomé, M., Oliva-Urcia, B., Delgado-Huertas,
A., Estrela, M. J., Corell, D., López-Moreno, J. I., and Cacho, I.:
Climate controls on rainfall isotopes and their effects on cave drip water
and speleothem growth: the case of Molinos cave (Teruel, NE Spain), Clim.
Dynam., 43, 221–241, https://doi.org/10.1007/s00382-014-2140-6, 2014.
Moreno, A., Iglesias, M., Azorin-Molina, C., Pérez-Mejías, C.,
Bartolomé, M., Sancho, C., Stoll, H., Cacho, I., Frigola, J., Osácar, C., Muñoz, A., Delgado-Huertas, A., Bladé, I., and Vimeux, F.: Measurement report: Spatial variability of northern Iberian rainfall stable isotope values – investigating atmospheric controls on daily and monthly timescales, Atmos. Chem. Phys., 21, 10159–10177,
https://doi.org/10.5194/acp-21-10159-2021, 2021.
Noronha, A. L., Johnson, K. R., Hu, C., Ruan, J., Southon, J. R., and Ferguson, J. E.: Assessing influences on speleothem dead carbon variability
over the Holocene: Implications for speleothem-based radiocarbon calibration, Earth Planet. Sc. Lett., 394, 20–29, https://doi.org/10.1016/j.epsl.2014.03.015, 2014.
O'Leary, M. H.: Carbon Isotopes in Photosynthesis: Fractionation techniques
may reveal new aspects of carbon dynamics in plants, BioScience, 38, 328–336, https://doi.org/10.2307/1310735, 1988.
Owen, R., Day, C. C., and Henderson, G. M.: CaveCalc: A new model for speleothem chemistry & isotopes, Comput. Geosci., 119, 115–122, https://doi.org/10.1016/j.cageo.2018.06.011, 2018.
Parkhurst, D. L. and Appelo, C. A. J.: Description of input and examples for
PHREEQC version 3 – A computer program for speciation, batch-reaction,
one-dimensional transport, and inverse geochemical calculations, in: US Geological Survey Techniques and Methods, book 6, chap. A43, US Geological Survey, p. 497, https://pubs.usgs.gov/tm/06/a43/pdf/tm6-A43.pdf (last
access: 10 January 2022), 2013.
Pataki, D. E., Bowling, D. R., and Ehleringer, J. R.: Seasonal cycle of carbon dioxide and its isotopic composition in an urban atmosphere: Anthropogenic and biogenic effects, J. Geophys. Res.-Atmos., 108, 4735, https://doi.org/10.1029/2003JD003865, 2003.
Peel, M. C., Finlayson, B. L., and McMahon, T. A.: Updated world map of the
Köppen–Geiger climate classification, Hydrol. Earth Syst. Sci., 11,
1633–1644, https://doi.org/10.5194/hess-11-1633-2007, 2007.
Riechelmann, D. F. C., Schröder-Ritzrau, A., Scholz, D., Fohlmeister,
J., Spötl, C., Richter, D. K., and Mangini, A.: Monitoring Bunker Cave
(NW Germany): A prerequisite to interpret geochemical proxy data of
speleothems from this site, J. Hydrol., 409, 682–695, https://doi.org/10.1016/j.jhydrol.2011.08.068, 2011.
Ruff, M., Wacker, L., Gäggeler, H. W., Suter, M., Synal, H. A., and
Szidat, S.: A Gas Ion Source for Radiocarbon Measurements at 200 kV,
Radiocarbon, 49, 307–314, https://doi.org/10.1017/S0033822200042235, 2007.
Sinclair, D. J., Banner, J. L., Taylor, F. W., Partin, J., Jenson, J., Mylroie, J., Goddard, E., Quinn, T., Jocson, J., and Miklaviè, B.:
Magnesium and strontium systematics in tropical speleothems from the Western
Pacific, Chem. Geol., 294–295, 1–17, https://doi.org/10.1016/j.chemgeo.2011.10.008, 2012.
Sliwinski, J., Kost, O., Endres, L., Iglesias, M., Haghipour, N.,
González-Lemos, S., and Stoll, H.: Exploring soluble and colloidally
transported trace elements in stalagmites: The strontium-yttrium connection,
Geochim. Cosmochim. Ac., 343, 64–83, 2023.
Sliwinski, J. T. and Stoll, H. M.: Combined fluorescence imaging and LA-ICP-MS trace element mapping of stalagmites: Microfabric identification
and interpretation, Chem. Geol., 581, 120397, https://doi.org/10.1016/j.chemgeo.2021.120397, 2021.
Spötl, C., Fairchild, I. J., and Tooth, A. F.: Cave air control on
dripwater geochemistry, Obir Caves (Austria): Implications for speleothem
deposition in dynamically ventilated caves, Geochim. Cosmochim. Ac., 69, 2451–2468, https://doi.org/10.1016/j.gca.2004.12.009, 2005.
Stoll, H., Mendez-Vicente, A., Gonzalez-Lemos, S., Moreno, A., Cacho, I.,
Cheng, H., and Edwards, R. L.: Interpretation of orbital scale variability
in mid-latitude speleothem δ18O: Significance of growth rate controlled kinetic fractionation effects, Quaternary Sci. Rev., 127, 215–228, https://doi.org/10.1016/j.quascirev.2015.08.025, 2015.
Stoll, H. M., Müller, W., and Prieto, M.: I-STAL, a model for
interpretation of , and Ba/Ca variations in speleothems and its forward and inverse application on seasonal to millennial scales, Geochem. Geophy. Geosy., 13, Q09004, https://doi.org/10.1029/2012GC004183, 2012.
Stoll, H. M., Moreno, A., Mendez-Vicente, A., Gonzalez-Lemos, S., Jimenez-Sanchez, M., Dominguez-Cuesta, M. J., Edwards, R. L., Cheng, H., and
Wang, X.: Paleoclimate and growth rates of speleothems in the northwestern
Iberian Peninsula over the last two glacial cycles, Quatern. Res., 80,
284–290, https://doi.org/10.1016/j.yqres.2013.05.002, 2013.
Tadros, C. V., Treble, P. C., Baker, A., Fairchild, I., Hankin, S., Roach,
R., Markowska, M., and McDonald, J.: ENSO – cave drip water hydrochemical
relationship: a 7-year dataset from south-eastern Australia, Hydrol. Earth
Syst. Sci., 20, 4625–4640, https://doi.org/10.5194/hess-20-4625-2016, 2016.
Tadros, C. V., Treble, P. C., Baker, A., Hankin, S., and Roach, R.: Cave
drip water solutes in south-eastern Australia: Constraining sources, sinks
and processes, Sci. Total Environ., 651, 2175–2186, https://doi.org/10.1016/j.scitotenv.2018.10.035, 2019.
Treble, P. C., Fairchild, I. J., Baker, A., Meredith, K. T., Andersen, M.
S., Salmon, S. U., Bradley, C., Wynn, P. M., Hankin, S. I., Wood, A., and
McGuire, E.: Roles of forest bioproductivity, transpiration and fire in a
nine-year record of cave dripwater chemistry from southwest Australia, Geochim. Cosmochim. Ac., 184, 132-150, https://doi.org/10.1016/j.gca.2016.04.017, 2016.
Treble, P. C., Baker, A., Abram, N. J., Hellstrom, J. C., Crawford, J.,
Gagan, M. K., Borsato, A., Griffiths, A. D., Bajo, P., Markowska, M.,
Priestley, S. C., Hankin, S., and Paterson, D.: Ubiquitous karst hydrological control on speleothem oxygen isotope variability in a global study, Commun. Earth Environ., 3, 29, https://doi.org/10.1038/s43247-022-00347-3, 2022.
Tremaine, D. M. and Froelich, P. N.: Speleothem trace element signatures: A
hydrologic geochemical study of modern cave dripwaters and farmed calcite,
Geochim.t Cosmochim. Ac., 121, 522–545, https://doi.org/10.1016/j.gca.2013.07.026, 2013.
Tremaine, D. M., Sinclair, D. J., Stoll, H. M., Lagerström, M., Carvajal, C. P., and Sherrell, R. M.: A two-year automated dripwater chemistry study in a remote cave in the tropical south Pacific: Using [Cl−] as a conservative tracer for seasalt contribution of major cations, Geochim. Cosmochim. Ac., 184, 289–310, https://doi.org/10.1016/j.gca.2016.03.029, 2016.
UNEP: World atlas of desertification 2ED, https://wedocs.unep.org/handle/20.500.11822/30300;jsessionid=D481099AA75A2ACCAD3C4831B7C68FD6
(last access: 10 January 2022), 1997.
Waring, C. L., Hankin, S. I., Griffith, D. W. T., Kertesz, M. A., Kobylski,
V., Wilson, N. L., Coleman, N. V., Kettlewell, G., Zlot, R., Bosse, M., and
Bell, G.: Seasonal total methane depletion in limestone caves, Sci. Rep., 7, 8314, https://doi.org/10.1038/s41598-017-07769-6, 2017.
Wassenburg, J. A., Riechelmann, S., Schröder-Ritzrau, A., Riechelmann, D. F. C., Richter, D. K., Immenhauser, A., Terente, M., Constantin, S., Hachenberg, A., Hansen, M., and Scholz, D.: Calcite Mg and Sr partition
coefficients in cave environments: Implications for interpreting prior
calcite precipitation in speleothems, Geochim. Cosmochim. Ac., 269, 581–596, https://doi.org/10.1016/j.gca.2019.11.011, 2020.
Weremeichik, J. M., Gabitov, R. I., Thien, B. M. J., and Sadekov, A.: The
effect of growth rate on uranium partitioning between individual calcite
crystals and fluid, Chem. Geol., 450, 145–153, https://doi.org/10.1016/j.chemgeo.2016.12.026, 2017.
Short summary
Cave monitoring studies including cave drip water are unique opportunities to sample water which has percolated through the soil and rock. The change in drip water chemistry is resolved over the course of 16 months, inferring seasonal and hydrological variations in soil and karst processes at the water–air and water–rock interface. Such data sets improve the understanding of hydrological and hydrochemical processes and ultimately advance the interpretation of geochemical stalagmite records.
Cave monitoring studies including cave drip water are unique opportunities to sample water which...