Articles | Volume 27, issue 11
https://doi.org/10.5194/hess-27-2227-2023
https://doi.org/10.5194/hess-27-2227-2023
Research article
 | 
14 Jun 2023
Research article |  | 14 Jun 2023

Relationship of seasonal variations in drip water δ13CDIC, δ18O, and trace elements with surface and physical cave conditions of La Vallina cave, NW Spain

Oliver Kost, Saúl González-Lemos, Laura Rodríguez-Rodríguez, Jakub Sliwinski, Laura Endres, Negar Haghipour, and Heather Stoll

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Cited articles

AEMET: AEMET OpenData, State Meteorological Agency of Spain, https://opendata.aemet.es/centrodedescargas/inicio (last access: 13 September 2021), 2021. 
Álvarez, R., Ordóñez, A., Canteli, P., and De Miguel, E.: Unconventional gas resources in the Cantabrian Zone (NW Spain): A comprehensive preliminary assessment, Geol. J., 54, 2608–2620, https://doi.org/10.1002/gj.3314, 2019. 
Baker, A., Barnes, W. L., and Smart, P. L.: Variations in the discharge and organic matter content of stalagmite drip waters in Lower Cave, Bristol, Hydrol. Process., 11, 1541–1555, https://doi.org/10.1002/(SICI)1099-1085(199709)11:11<1541::AID-HYP484>3.0.CO;2-Z, 1997. 
Baker, A., Hartmann, A., Duan, W., Hankin, S., Comas-Bru, L., Cuthbert, M. O., Treble, P. C., Banner, J., Genty, D., Baldini, L. M., Bartolomé, M., Moreno, A., Pérez-Mejías, C., and Werner, M.: Global analysis reveals climatic controls on the oxygen isotope composition of cave drip water, Nat. Commun., 10, 2984, https://doi.org/10.1038/s41467-019-11027-w, 2019. 
Baker, A., Berthelin, R., Cuthbert, M. O., Treble, P. C., Hartmann, A., and Kss Cave Studies Team: Rainfall recharge thresholds in a subtropical climate determined using a regional cave drip water monitoring network, J. Hydrol., 587, 125001, https://doi.org/10.1016/j.jhydrol.2020.125001, 2020. 
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Short summary
Cave monitoring studies including cave drip water are unique opportunities to sample water which has percolated through the soil and rock. The change in drip water chemistry is resolved over the course of 16 months, inferring seasonal and hydrological variations in soil and karst processes at the water–air and water–rock interface. Such data sets improve the understanding of hydrological and hydrochemical processes and ultimately advance the interpretation of geochemical stalagmite records.