Articles | Volume 19, issue 11
https://doi.org/10.5194/hess-19-4427-2015
https://doi.org/10.5194/hess-19-4427-2015
Research article
 | 
04 Nov 2015
Research article |  | 04 Nov 2015

Determining the stable isotope composition of pore water from saturated and unsaturated zone core: improvements to the direct vapour equilibration laser spectrometry method

M. J. Hendry, E. Schmeling, L. I. Wassenaar, S. L. Barbour, and D. Pratt

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Cited articles

Allison, G. B. and Hughes, M. W.: The use of natural tracers as indicators of soil-water movement in a temperate semi-arid region, J. Hydrol., 60, 157–173, https://doi.org/10.1016/0022-1694(83)90019-7, 1983.
Altinier, M. V., Savoye, S., Michelot, J.-L., Beaucaire, C., Massault, M., Tessier, D., and Waber, H. N.: The isotopic composition of porewater from Tournemire argillite (France): An inter-comparison study, Phys. Chem. Earth Pt A/B/C, 32, 209–218, https://doi.org/10.1016/j.pce.2006.02.047, 2007.
Araguas-Araguas, L., Rozanski, K., Gonfiantini, R., and Louvat, D.: Isotope effects accompanying vacuum extraction of soil water for stable isotope analyses, J. Hydrol., 168, 159–171, https://doi.org/10.1016/0022-1694(94)02636-P, 1995.
Bensenouci, F., Michelot, J. L., Matray, J. M., Savoye, S., Tremosa, J., and Gaboreau, S.: Profiles of chloride and stable isotopes in pore-water obtained from a 2000-m deep borehole through the Mesozoic sedimentary series in the eastern Paris Basin, Phys. Chem. Earth, Pt A/B/C, 65, 1–10, https://doi.org/10.1016/j.pce.2011.10.024, 2013.
Bourke, S. A., Turchenek, J., Schmeling, E., Mahmood, F. N., Olson, B. M., and Hendry, M. J.: Comparison of continuous core profiles and monitoring wells for assessing groundwater contamination by agricultural nitrate, Ground Water Monit. R., 35, 110–117, https://doi.org/10.1111/gwmr.12104, 2015.
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Short summary
Improvements and limitations to the measurement δ2H and δ18O of pore waters in geologic core samples using laser spectrometry are presented. These included the use of a δ2H spike to assess the extent of drill fluid contamination and the effect of storage time and type of sample bag on pore water values.