Articles | Volume 19, issue 11
https://doi.org/10.5194/hess-19-4427-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/hess-19-4427-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Determining the stable isotope composition of pore water from saturated and unsaturated zone core: improvements to the direct vapour equilibration laser spectrometry method
M. J. Hendry
CORRESPONDING AUTHOR
Department of Geological Sciences, University of Saskatchewan, 114 Science Place, Saskatoon, SK, S7N 5E2, Canada
E. Schmeling
Department of Geological Sciences, University of Saskatchewan, 114 Science Place, Saskatoon, SK, S7N 5E2, Canada
L. I. Wassenaar
Department of Geological Sciences, University of Saskatchewan, 114 Science Place, Saskatoon, SK, S7N 5E2, Canada
International Atomic Energy Agency, Vienna International Centre, 1400 Vienna, Austria
S. L. Barbour
Department of Civil and Geological Engineering, University of Saskatchewan, 57 Campus Drive, Saskatoon, SK, S7N 5A9, Canada
D. Pratt
Department of Civil and Geological Engineering, University of Saskatchewan, 57 Campus Drive, Saskatoon, SK, S7N 5A9, Canada
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56 citations as recorded by crossref.
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- Improved accuracy and precision of water stable isotope measurements using the direct vapour equilibration method A. Mattei et al. 10.1002/rcm.8494
- Sampling soil water along the pF curve for δ2H and δ18O analysis N. Orlowski & L. Breuer 10.1002/hyp.13916
- Estimating water fluxes in the critical zone using water stable isotope approaches in the Groundnut and Ferlo basins of Senegal D. Diongue et al. 10.1002/hyp.14787
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- Using vadose-zone water stable isotope profiles for assessing groundwater recharge under different climatic conditions L. Boumaiza et al. 10.1080/02626667.2021.1957479
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- Further experiments comparing direct vapor equilibration and cryogenic vacuum distillation for plant water stable isotope analysis C. Millar et al. 10.1002/rcm.8530
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- Plant and root‐zone water isotopes are difficult to measure, explain, and predict: Some practical recommendations for determining plant water sources J. von Freyberg et al. 10.1111/2041-210X.13461
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- Assessing the fate of explosives derived nitrate in mine waste rock dumps using the stable isotopes of oxygen and nitrogen M. Hendry et al. 10.1016/j.scitotenv.2018.05.275
- Faro Waste Rock Project: Characterizing Variably Saturated Flow Behavior Through Full‐Scale Waste‐Rock Dumps in the Continental Subarctic Region of Northern Canada Using Field Measurements and Stable Isotopes of Water Z. Bao et al. 10.1029/2019WR026374
- High-resolution profiling of the stable isotopes of water in unsaturated coal waste rock S. Barbour et al. 10.1016/j.jhydrol.2016.01.053
50 citations as recorded by crossref.
- Determining the stable isotope composition of porewater using low temperature multi-step extraction for low water content soils S. Jiang et al. 10.1016/j.jhydrol.2021.126079
- A comparison of extraction systems for plant water stable isotope analysis C. Millar et al. 10.1002/rcm.8136
- In situ unsaturated zone water stable isotope (<sup>2</sup>H and <sup>18</sup>O) measurements in semi-arid environments: a soil water balance M. Gaj et al. 10.5194/hess-20-715-2016
- No influence of CO2 on stable isotope analyses of soil waters with off‐axis integrated cavity output spectroscopy (OA‐ICOS) M. Sprenger et al. 10.1002/rcm.7815
- The Role of Matric Potential, Solid Interfacial Chemistry, and Wettability on Isotopic Equilibrium Fractionation M. Gaj et al. 10.2136/vzj2018.04.0083
- Thermal imagery of woodland tree canopies provides new insights into drought-induced tree mortality P. Drake et al. 10.1016/j.scitotenv.2022.155395
- Isotope diffusive exchange experiments for deriving porewater isotope composition in low-permeability rocks – Improvements in experimental procedure and data processing L. Aschwanden et al. 10.1016/j.apgeochem.2023.105844
- Hydrogen and oxygen stable isotope signatures of goethite hydration waters by thermogravimetry-enabled laser spectroscopy E. Oerter et al. 10.1016/j.chemgeo.2017.10.025
- Improved accuracy and precision of water stable isotope measurements using the direct vapour equilibration method A. Mattei et al. 10.1002/rcm.8494
- Sampling soil water along the pF curve for δ2H and δ18O analysis N. Orlowski & L. Breuer 10.1002/hyp.13916
- Estimating water fluxes in the critical zone using water stable isotope approaches in the Groundnut and Ferlo basins of Senegal D. Diongue et al. 10.1002/hyp.14787
- Correcting Laser-Based Water Stable Isotope Readings Biased by Carrier Gas Changes B. Gralher et al. 10.1021/acs.est.6b01124
- Using vadose-zone water stable isotope profiles for assessing groundwater recharge under different climatic conditions L. Boumaiza et al. 10.1080/02626667.2021.1957479
- Using soil water isotopes to infer the influence of contrasting urban green space on ecohydrological partitioning L. Kuhlemann et al. 10.5194/hess-25-927-2021
- Calibration method affects the measured δ2H and δ18O in soil water by direct H2Oliquid–H2Ovapour equilibration with laser spectroscopy H. Wang et al. 10.1002/hyp.13606
- Soil water vapour isotopes identify missing water source for streamside trees E. Oerter et al. 10.1002/eco.2083
- Further experiments comparing direct vapor equilibration and cryogenic vacuum distillation for plant water stable isotope analysis C. Millar et al. 10.1002/rcm.8530
- Membrane inlet laser spectroscopy to measure H and O stable isotope compositions of soil and sediment pore water with high sample throughput E. Oerter et al. 10.1002/rcm.7768
- Palaeohydrogeology and Transport Parameters Derived from 4He and Cl Profiles in Aquitard Pore Waters in a Large Multilayer Aquifer System, Central Australia S. Priestley et al. 10.1155/2017/9839861
- Storage, mixing, and fluxes of water in the critical zone across northern environments inferred by stable isotopes of soil water M. Sprenger et al. 10.1002/hyp.13135
- In situ measurements of soil and plant water isotopes: a review of approaches, practical considerations and a vision for the future M. Beyer et al. 10.5194/hess-24-4413-2020
- Technical note: Discrete in situ vapor sampling for subsequent lab-based water stable isotope analysis B. Herbstritt et al. 10.5194/hess-27-3701-2023
- Snow gauge undercatch and its effect on the hydrogen and oxygen stable isotopic composition of precipitation G. Koehler 10.1080/10256016.2019.1618853
- Organic contamination detection for isotopic analysis of water by laser spectroscopy C. Millar et al. 10.1002/rcm.9118
- Flushing or mixing? Stable water isotopes reveal differences in arctic forest and peatland soil water seasonality F. Muhic et al. 10.1002/hyp.14811
- Quantification of water fluxes and soil water balance in agricultural fields under different tillage and irrigation systems using water stable isotopes A. Canet-Martí et al. 10.1016/j.still.2023.105732
- Vadose zone water stable isotope profiles for assessing groundwater recharge: Sensitivity to seasonal soil sampling L. Boumaiza et al. 10.1016/j.jhydrol.2023.130291
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- Quantifying the contribution of matric suction on changes in stability and displacement rate of a translational landslide in glaciolacustrine clay K. Sattler et al. 10.1007/s10346-020-01611-3
- Unique stable isotope signatures of large cyclonic events as a tracer of soil moisture dynamics in the semiarid subtropics G. Skrzypek et al. 10.1016/j.jhydrol.2019.124124
- Intercomparison of soil pore water extraction methods for stable isotope analysis and interpretation of hillslope runoff sources N. Orlowski et al. 10.1002/hyp.13539
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- Evaluation of δ2H and δ18O of water in pores extracted by compression method-effects of closed pores and comparison to direct vapor equilibration and laser spectrometry method K. Nakata et al. 10.1016/j.jhydrol.2018.03.058
- 17O‐excess as a detector for co‐extracted organics in vapor analyses of plant isotope signatures M. Nehemy et al. 10.1002/rcm.8470
- Technical note: Unresolved aspects of the direct vapor equilibration method for stable isotope analysis (<i>δ</i><sup>18</sup>O, <i>δ</i><sup>2</sup>H) of matrix-bound water: unifying protocols through empirical and mathematical scrutiny B. Gralher et al. 10.5194/hess-25-5219-2021
- Possible soil tension controls on the isotopic equilibrium fractionation factor for evaporation from soil M. Gaj & J. McDonnell 10.1002/hyp.13418
- Influence of sample preparation procedures on water stable isotopes in plant organs using the water‐vapour equilibrium method S. Santos Pires et al. 10.1002/eco.2444
- Toward a common methodological framework for the sampling, extraction, and isotopic analysis of water in the Critical Zone to study vegetation water use N. Ceperley et al. 10.1002/wat2.1727
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- Soil water stable isotopes reveal evaporation dynamics at the soil–plant–atmosphere interface of the critical zone M. Sprenger et al. 10.5194/hess-21-3839-2017
- Ecohydrological travel times derived from in situ stable water isotope measurements in trees during a semi-controlled pot experiment D. Mennekes et al. 10.5194/hess-25-4513-2021
- Measuring techniques for concentration and stable isotopologues of CO2 in a terrestrial ecosystem: A review G. Voglar et al. 10.1016/j.earscirev.2019.102978
- An evaluation of materials and methods for vapour measurement of the isotopic composition of pore water in deep, unsaturated zones D. Pratt et al. 10.1080/10256016.2016.1151423
- Co-evolution of xylem water and soil water stable isotopic composition in a northern mixed forest biome J. Snelgrove et al. 10.5194/hess-25-2169-2021
- Intercomparison of soil pore water extraction methods for stable isotope analysis N. Orlowski et al. 10.1002/hyp.10870
- Spatio‐temporal heterogeneity in soil water stable isotopic composition and its ecohydrologic implications in semiarid ecosystems E. Oerter & G. Bowen 10.1002/hyp.13434
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- Application of the pore water stable isotope method and hydrogeological approaches to characterise a wetland system K. David et al. 10.5194/hess-22-6023-2018
- Using water stable isotopes to understand evaporation, moisture stress, and re-wetting in catchment forest and grassland soils of the summer drought of 2018 L. Kleine et al. 10.5194/hess-24-3737-2020
- Plant and root‐zone water isotopes are difficult to measure, explain, and predict: Some practical recommendations for determining plant water sources J. von Freyberg et al. 10.1111/2041-210X.13461
6 citations as recorded by crossref.
- Established methods and new opportunities for pore water stable isotope analysis M. Sprenger et al. 10.1002/hyp.10643
- The stable isotopes of site wide waters at an oil sands mine in northern Alberta, Canada T. Baer et al. 10.1016/j.jhydrol.2016.08.017
- Influence of equilibration time, soil texture, and saturation on the accuracy of porewater water isotope assays using the direct H2O(liquid)–H2O(vapor) equilibration method D. Vadibeler et al. 10.1016/j.jhydrol.2022.127560
- Assessing the fate of explosives derived nitrate in mine waste rock dumps using the stable isotopes of oxygen and nitrogen M. Hendry et al. 10.1016/j.scitotenv.2018.05.275
- Faro Waste Rock Project: Characterizing Variably Saturated Flow Behavior Through Full‐Scale Waste‐Rock Dumps in the Continental Subarctic Region of Northern Canada Using Field Measurements and Stable Isotopes of Water Z. Bao et al. 10.1029/2019WR026374
- High-resolution profiling of the stable isotopes of water in unsaturated coal waste rock S. Barbour et al. 10.1016/j.jhydrol.2016.01.053
Saved (final revised paper)
Latest update: 21 Nov 2024
Short summary
Improvements and limitations to the measurement δ2H and δ18O of pore waters in geologic core samples using laser spectrometry are presented. These included the use of a δ2H spike to assess the extent of drill fluid contamination and the effect of storage time and type of sample bag on pore water values.
Improvements and limitations to the measurement δ2H and δ18O of pore waters in geologic core...