Articles | Volume 25, issue 10
https://doi.org/10.5194/hess-25-5337-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/hess-25-5337-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
05 Oct 2021
Research article |
| 05 Oct 2021
| 05 Oct 2021
Preferential pathways for fluid and solutes in heterogeneous groundwater systems: self-organization, entropy, work
Karlsruhe Institute of Technology (KIT), Institute of Water and River Basin Management, Karlsruhe, Germany
Ralf Loritz
Karlsruhe Institute of Technology (KIT), Institute of Water and River Basin Management, Karlsruhe, Germany
Yaniv Edery
Technion – Israel Institute
of Technology, Haifa, Israel
Brian Berkowitz
Department of Earth and Planetary Sciences, Weizmann Institute of Science, Rehovot, Israel
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Hydrol. Earth Syst. Sci., 26, 3125–3150, https://doi.org/10.5194/hess-26-3125-2022, https://doi.org/10.5194/hess-26-3125-2022, 2022
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Hydrol. Earth Syst. Sci., 26, 1615–1629, https://doi.org/10.5194/hess-26-1615-2022, https://doi.org/10.5194/hess-26-1615-2022, 2022
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Hydrol. Earth Syst. Sci., 25, 1483–1508, https://doi.org/10.5194/hess-25-1483-2021, https://doi.org/10.5194/hess-25-1483-2021, 2021
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Hydrol. Earth Syst. Sci., 24, 1831–1858, https://doi.org/10.5194/hess-24-1831-2020, https://doi.org/10.5194/hess-24-1831-2020, 2020
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Hydrol. Earth Syst. Sci., 23, 4249–4267, https://doi.org/10.5194/hess-23-4249-2019, https://doi.org/10.5194/hess-23-4249-2019, 2019
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Axel Kleidon, Erwin Zehe, and Ralf Loritz
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Manuscript not accepted for further review
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Ralf Loritz, Axel Kleidon, Conrad Jackisch, Martijn Westhoff, Uwe Ehret, Hoshin Gupta, and Erwin Zehe
Hydrol. Earth Syst. Sci., 23, 3807–3821, https://doi.org/10.5194/hess-23-3807-2019, https://doi.org/10.5194/hess-23-3807-2019, 2019
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Hydrol. Earth Syst. Sci., 23, 971–987, https://doi.org/10.5194/hess-23-971-2019, https://doi.org/10.5194/hess-23-971-2019, 2019
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Publication in ESD not foreseen
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Nevil Quinn, Günter Blöschl, András Bárdossy, Attilio Castellarin, Martyn Clark, Christophe Cudennec, Demetris Koutsoyiannis, Upmanu Lall, Lubomir Lichner, Juraj Parajka, Christa D. Peters-Lidard, Graham Sander, Hubert Savenije, Keith Smettem, Harry Vereecken, Alberto Viglione, Patrick Willems, Andy Wood, Ross Woods, Chong-Yu Xu, and Erwin Zehe
Proc. IAHS, 380, 3–8, https://doi.org/10.5194/piahs-380-3-2018, https://doi.org/10.5194/piahs-380-3-2018, 2018
Nevil Quinn, Günter Blöschl, András Bárdossy, Attilio Castellarin, Martyn Clark, Christophe Cudennec, Demetris Koutsoyiannis, Upmanu Lall, Lubomir Lichner, Juraj Parajka, Christa D. Peters-Lidard, Graham Sander, Hubert Savenije, Keith Smettem, Harry Vereecken, Alberto Viglione, Patrick Willems, Andy Wood, Ross Woods, Chong-Yu Xu, and Erwin Zehe
Hydrol. Earth Syst. Sci., 22, 5735–5739, https://doi.org/10.5194/hess-22-5735-2018, https://doi.org/10.5194/hess-22-5735-2018, 2018
Mirko Mälicke, Sibylle K. Hassler, Markus Weiler, Theresa Blume, and Erwin Zehe
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2018-396, https://doi.org/10.5194/hess-2018-396, 2018
Manuscript not accepted for further review
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In this study we use time dependent variograms to identify periods of organized soil moisture during drying. We could identify emerging spatial patterns which imply periods of terrestrial control on soil moisture organization. The coupling of time dependent variograms with density based clustering is a new approach to detect similarity in spatial patterns. The presented method is useful to describe states of organization and improve kriging workflows by extending their prerequisites.
Ralf Loritz, Hoshin Gupta, Conrad Jackisch, Martijn Westhoff, Axel Kleidon, Uwe Ehret, and Erwin Zehe
Hydrol. Earth Syst. Sci., 22, 3663–3684, https://doi.org/10.5194/hess-22-3663-2018, https://doi.org/10.5194/hess-22-3663-2018, 2018
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In this study we explore the role of spatially distributed information on hydrological modeling. For that, we develop and test an approach which draws upon information theory and thermodynamic reasoning. We show that the proposed set of methods provide a powerful framework for understanding and diagnosing how and when process organization and functional similarity of hydrological systems emerge in time and, hence, when which landscape characteristic is important in a model application.
Conrad Jackisch and Erwin Zehe
Hydrol. Earth Syst. Sci., 22, 3639–3662, https://doi.org/10.5194/hess-22-3639-2018, https://doi.org/10.5194/hess-22-3639-2018, 2018
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We present a Lagrangian model for non-uniform soil water dynamics. It handles 2-D diffusion (based on a spatial random walk and implicit pore space redistribution) and 1-D advection in representative macropores (as film flow with dynamic interaction with the soil matrix). The interplay between the domains is calculated based on an energy-balance approach which does not require any additional parameterisation. Model tests give insight into the evolution of the non-uniform infiltration patterns.
Simon Höllering, Jan Wienhöfer, Jürgen Ihringer, Luis Samaniego, and Erwin Zehe
Hydrol. Earth Syst. Sci., 22, 203–220, https://doi.org/10.5194/hess-22-203-2018, https://doi.org/10.5194/hess-22-203-2018, 2018
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Hydrological fingerprints are introduced as response targets for sensitivity analysis and combined with a conventional approach using streamflow data for a temporally resolved sensitivity analysis. The joint benefit of both approaches is presented for several headwater catchments. The approach allows discerning a clarified pattern for parameter influences pinpointed to diverse response characteristics and detecting even slight regional differences.
Lisa Angermann, Conrad Jackisch, Niklas Allroggen, Matthias Sprenger, Erwin Zehe, Jens Tronicke, Markus Weiler, and Theresa Blume
Hydrol. Earth Syst. Sci., 21, 3727–3748, https://doi.org/10.5194/hess-21-3727-2017, https://doi.org/10.5194/hess-21-3727-2017, 2017
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This study investigates the temporal dynamics and response velocities of lateral preferential flow at the hillslope. The results are compared to catchment response behavior to infer the large-scale implications of the observed processes. A large portion of mobile water flows through preferential flow paths in the structured soils, causing an immediate discharge response. The study presents a methodological approach to cover the spatial and temporal domain of these highly heterogeneous processes.
Conrad Jackisch, Lisa Angermann, Niklas Allroggen, Matthias Sprenger, Theresa Blume, Jens Tronicke, and Erwin Zehe
Hydrol. Earth Syst. Sci., 21, 3749–3775, https://doi.org/10.5194/hess-21-3749-2017, https://doi.org/10.5194/hess-21-3749-2017, 2017
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Rapid subsurface flow in structured soils facilitates fast vertical and lateral redistribution of event water. We present its in situ exploration through local measurements and irrigation experiments. Special emphasis is given to a coherent combination of hydrological and geophysical methods. The study highlights that form and function operate as conjugated pairs. Dynamic imaging through time-lapse GPR was key to observing both and to identifying hydrologically relevant structures.
Simon Paul Seibert, Conrad Jackisch, Uwe Ehret, Laurent Pfister, and Erwin Zehe
Hydrol. Earth Syst. Sci., 21, 2817–2841, https://doi.org/10.5194/hess-21-2817-2017, https://doi.org/10.5194/hess-21-2817-2017, 2017
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Runoff production mechanisms and their corresponding physiographic controls continue to pose major research challenges in catchment hydrology. We propose innovative data-driven diagnostic signatures for overcoming the prevailing status quo in inter-comparison studies. Specifically, we present dimensionless double mass curves which allow us to infer information on runoff generation at the seasonal and annual timescales. The method is based on commonly available data.
Ralf Loritz, Sibylle K. Hassler, Conrad Jackisch, Niklas Allroggen, Loes van Schaik, Jan Wienhöfer, and Erwin Zehe
Hydrol. Earth Syst. Sci., 21, 1225–1249, https://doi.org/10.5194/hess-21-1225-2017, https://doi.org/10.5194/hess-21-1225-2017, 2017
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In this study we examine whether we can step beyond the qualitative character of perceptual models by using them as a blueprint for setting up representative hillslope models. Thereby we test the hypothesis of whether a single hillslope can represent the functioning of an entire lower mesoscale catchment in a spatially aggregated way.
Simon Paul Seibert, Uwe Ehret, and Erwin Zehe
Hydrol. Earth Syst. Sci., 20, 3745–3763, https://doi.org/10.5194/hess-20-3745-2016, https://doi.org/10.5194/hess-20-3745-2016, 2016
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While the assessment of "vertical" (magnitude) errors of streamflow simulations is standard practice, "horizontal" (timing) errors are rarely considered. To assess their role, we propose a method to quantify both errors simultaneously which closely resembles visual hydrograph comparison. Our results reveal differences in time–magnitude error statistics for different flow conditions. The proposed method thus offers novel perspectives for model diagnostics and evaluation.
Erwin Zehe and Conrad Jackisch
Hydrol. Earth Syst. Sci., 20, 3511–3526, https://doi.org/10.5194/hess-20-3511-2016, https://doi.org/10.5194/hess-20-3511-2016, 2016
Simon Höllering, Jürgen Ihringer, Luis Samaniego, and Erwin Zehe
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2016-249, https://doi.org/10.5194/hess-2016-249, 2016
Preprint withdrawn
M. Westhoff, E. Zehe, P. Archambeau, and B. Dewals
Hydrol. Earth Syst. Sci., 20, 479–486, https://doi.org/10.5194/hess-20-479-2016, https://doi.org/10.5194/hess-20-479-2016, 2016
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We derived mathematical formulations of relations between relative wetness and gradients driving run-off and evaporation for a one-box model such that, when conductances are optimized with the maximum power principle, the model leads exactly to a point on the Budyko curve.
With dry spells and dynamics in actual evaporation added, the model compared well with catchment observations without calibrating any parameter.
The maximum-power principle may thus be used to derive the Budyko curve.
U. Scherer and E. Zehe
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hessd-12-3527-2015, https://doi.org/10.5194/hessd-12-3527-2015, 2015
Revised manuscript not accepted
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This paper presents the development, parameterization and verification of a process-based soil erosion model for the catchment scale, which balances necessary complexity with greatest possible simplicity. We used the hydrologic model CATFLOW as a platform and further developed it to CATFLOW-SED by integrating approaches to simulate soil erosion. The model was validated on a hierarchy of scales which is characteristic for the governing processes.
E. Zehe, U. Ehret, L. Pfister, T. Blume, B. Schröder, M. Westhoff, C. Jackisch, S. J. Schymanski, M. Weiler, K. Schulz, N. Allroggen, J. Tronicke, L. van Schaik, P. Dietrich, U. Scherer, J. Eccard, V. Wulfmeyer, and A. Kleidon
Hydrol. Earth Syst. Sci., 18, 4635–4655, https://doi.org/10.5194/hess-18-4635-2014, https://doi.org/10.5194/hess-18-4635-2014, 2014
U. Ehret, H. V. Gupta, M. Sivapalan, S. V. Weijs, S. J. Schymanski, G. Blöschl, A. N. Gelfan, C. Harman, A. Kleidon, T. A. Bogaard, D. Wang, T. Wagener, U. Scherer, E. Zehe, M. F. P. Bierkens, G. Di Baldassarre, J. Parajka, L. P. H. van Beek, A. van Griensven, M. C. Westhoff, and H. C. Winsemius
Hydrol. Earth Syst. Sci., 18, 649–671, https://doi.org/10.5194/hess-18-649-2014, https://doi.org/10.5194/hess-18-649-2014, 2014
J. Wienhöfer and E. Zehe
Hydrol. Earth Syst. Sci., 18, 121–138, https://doi.org/10.5194/hess-18-121-2014, https://doi.org/10.5194/hess-18-121-2014, 2014
M. Liu, A. Bárdossy, and E. Zehe
Hydrol. Earth Syst. Sci., 17, 4685–4699, https://doi.org/10.5194/hess-17-4685-2013, https://doi.org/10.5194/hess-17-4685-2013, 2013
E. Zehe, U. Ehret, T. Blume, A. Kleidon, U. Scherer, and M. Westhoff
Hydrol. Earth Syst. Sci., 17, 4297–4322, https://doi.org/10.5194/hess-17-4297-2013, https://doi.org/10.5194/hess-17-4297-2013, 2013
M. C. Westhoff and E. Zehe
Hydrol. Earth Syst. Sci., 17, 3141–3157, https://doi.org/10.5194/hess-17-3141-2013, https://doi.org/10.5194/hess-17-3141-2013, 2013
A. Kleidon, E. Zehe, U. Ehret, and U. Scherer
Hydrol. Earth Syst. Sci., 17, 225–251, https://doi.org/10.5194/hess-17-225-2013, https://doi.org/10.5194/hess-17-225-2013, 2013
J. Wienhöfer, K. Germer, F. Lindenmaier, A. Färber, and E. Zehe
Hydrol. Earth Syst. Sci., 13, 1145–1161, https://doi.org/10.5194/hess-13-1145-2009, https://doi.org/10.5194/hess-13-1145-2009, 2009
Karl Nicolaus van Zweel, Laurent Gourdol, Jean François Iffly, Loïc Léonard, François Barnich, Laurent Pfister, Erwin Zehe, and Christophe Hissler
Earth Syst. Sci. Data, 17, 2217–2229, https://doi.org/10.5194/essd-17-2217-2025, https://doi.org/10.5194/essd-17-2217-2025, 2025
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Our study monitored groundwater in a Luxembourg forest over a year to understand water and chemical changes. We found seasonal variations in water chemistry, influenced by rainfall and soil interactions. These data help predict environmental responses and manage water resources better. By measuring key parameters like pH and dissolved oxygen, our research provides valuable insights into groundwater behaviour and serves as a resource for future environmental studies.
Judith Nijzink, Ralf Loritz, Laurent Gourdol, Davide Zoccatelli, Jean François Iffly, and Laurent Pfister
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2024-482, https://doi.org/10.5194/essd-2024-482, 2025
Preprint under review for ESSD
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The CAMELS-LUX dataset (Catchment Attributes and MEteorology for Large-sample Studies – LUXembourg) contains hydrologic, meteorologic and thunderstorm formation relevant atmospheric time series of 56 Luxembourgish catchments (2004–2021). These catchments are characterized by a large physiographic variety on a relatively small scale in a homogeneous climate. The dataset can be applied for (regional) hydrological analyses.
Svenja Hoffmeister, Sibylle Kathrin Hassler, Friederike Lang, Rebekka Maier, Betserai Isaac Nyoka, and Erwin Zehe
EGUsphere, https://doi.org/10.5194/egusphere-2025-1719, https://doi.org/10.5194/egusphere-2025-1719, 2025
This preprint is open for discussion and under review for Biogeosciences (BG).
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Combining trees and crops in agroforestry systems can potentially be a sustainable option for agriculture facing climate change impacts. We used methods from soil science and hydrology to assess the effect of adding gliricidia trees to maize fields, on carbon content, soil properties and water availability. Our results show a clear increase in carbon contents and effects on physical soil characteristics and water uptake and retention as a consequence of the agroforestry treatment.
Eduardo Acuña Espinoza, Frederik Kratzert, Daniel Klotz, Martin Gauch, Manuel Álvarez Chaves, Ralf Loritz, and Uwe Ehret
Hydrol. Earth Syst. Sci., 29, 1749–1758, https://doi.org/10.5194/hess-29-1749-2025, https://doi.org/10.5194/hess-29-1749-2025, 2025
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Long short-term memory (LSTM) networks have demonstrated state-of-the-art performance for rainfall-runoff hydrological modelling. However, most studies focus on predictions at a daily scale, limiting the benefits of sub-daily (e.g. hourly) predictions in applications like flood forecasting. In this study, we introduce a new architecture, multi-frequency LSTM (MF-LSTM), designed to use inputs of various temporal frequencies to produce sub-daily (e.g. hourly) predictions at a moderate computational cost.
Evgeny Shavelzon, Erwin Zehe, and Yaniv Edery
EGUsphere, https://doi.org/10.22541/essoar.173687429.91307309/v1, https://doi.org/10.22541/essoar.173687429.91307309/v1, 2025
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We analyze how chemical reactions and fluid movement interact in porous materials, focusing on how water paths form in underground environments. Using a thermodynamic approach, we track energy dissipation and entropy changes to understand this process. Over time, water channels become more defined, reducing chemical mixing and energy loss. Eventually, the system stabilizes, with flow concentrated in efficient pathways, minimizing further reactions and energy use.
Maria Staudinger, Anna Herzog, Ralf Loritz, Tobias Houska, Sandra Pool, Diana Spieler, Paul D. Wagner, Juliane Mai, Jens Kiesel, Stephan Thober, Björn Guse, and Uwe Ehret
EGUsphere, https://doi.org/10.5194/egusphere-2025-1076, https://doi.org/10.5194/egusphere-2025-1076, 2025
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Four process-based and four data-driven hydrological models are compared using different training data. We found process-based models to perform better with small data sets but stop learning soon, while data-driven models learn longer. The study highlights the importance of memory in data and the impact of different data sampling methods on model performance. The direct comparison of these models is novel and provides a clear understanding of their performance under various data conditions.
Eduardo Acuña Espinoza, Ralf Loritz, Frederik Kratzert, Daniel Klotz, Martin Gauch, Manuel Álvarez Chaves, and Uwe Ehret
Hydrol. Earth Syst. Sci., 29, 1277–1294, https://doi.org/10.5194/hess-29-1277-2025, https://doi.org/10.5194/hess-29-1277-2025, 2025
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Data-driven techniques have shown the potential to outperform process-based models in rainfall–runoff simulations. Hybrid models, combining both approaches, aim to enhance accuracy and maintain interpretability. Expanding the set of test cases to evaluate hybrid models under different conditions, we test their generalization capabilities for extreme hydrological events.
Sanika Baste, Daniel Klotz, Eduardo Acuña Espinoza, Andras Bardossy, and Ralf Loritz
EGUsphere, https://doi.org/10.5194/egusphere-2025-425, https://doi.org/10.5194/egusphere-2025-425, 2025
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This study evaluates the extrapolation performance of Long Short-Term Memory (LSTM) networks in rainfall-runoff modeling, specifically under extreme conditions. The findings reveal that the LSTM cannot predict discharge values beyond a theoretical limit, which is well below the extremity of its training data. This behavior results from the LSTM's gating structures rather than saturation of cell states alone.
Ashish Manoj J, Ralf Loritz, Hoshin Gupta, and Erwin Zehe
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2024-375, https://doi.org/10.5194/hess-2024-375, 2024
Preprint under review for HESS
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Traditional hydrological models typically operate in a forward mode, simulating streamflow and other catchment fluxes based on precipitation input. In this study, we explored the possibility of reversing this process—inferring precipitation from streamflow data—to improve flood event modelling. We then used the generated precipitation series to run hydrological models, resulting in more accurate estimates of streamflow and soil moisture.
Ralf Loritz, Alexander Dolich, Eduardo Acuña Espinoza, Pia Ebeling, Björn Guse, Jonas Götte, Sibylle K. Hassler, Corina Hauffe, Ingo Heidbüchel, Jens Kiesel, Mirko Mälicke, Hannes Müller-Thomy, Michael Stölzle, and Larisa Tarasova
Earth Syst. Sci. Data, 16, 5625–5642, https://doi.org/10.5194/essd-16-5625-2024, https://doi.org/10.5194/essd-16-5625-2024, 2024
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The CAMELS-DE dataset features data from 1582 streamflow gauges across Germany, with records spanning from 1951 to 2020. This comprehensive dataset, which includes time series of up to 70 years (median 46 years), enables advanced research on water flow and environmental trends and supports the development of hydrological models.
Adi Biran, Tomer Sapar, Ludmila Abezgauz, and Yaniv Edery
Hydrol. Earth Syst. Sci., 28, 4755–4770, https://doi.org/10.5194/hess-28-4755-2024, https://doi.org/10.5194/hess-28-4755-2024, 2024
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In Earth sciences, pH-driven reactions in porous environments impact natural processes like mineral dissolution and groundwater remediation. Traditional models struggle due to pore-scale complexities. This study explores how porous structure and flow rate affect mixing and chemical reactions. Surprisingly, pH-driven reactions occur faster than predicted, emphasizing water’s unique pH behavior in porous media.
Dan Elhanati, Nadine Goeppert, and Brian Berkowitz
Hydrol. Earth Syst. Sci., 28, 4239–4249, https://doi.org/10.5194/hess-28-4239-2024, https://doi.org/10.5194/hess-28-4239-2024, 2024
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A continuous time random walk framework was developed to allow modeling of a karst aquifer discharge response to measured rainfall. The application of the numerical model yielded robust fits between modeled and measured discharge values, especially for the distinctive long tails found during recession times. The findings shed light on the interplay of slow and fast flow in the karst system and establish the application of the model for simulating flow and transport in such systems.
Svenja Hoffmeister, Rafael Bohn Reckziegel, Ben du Toit, Sibylle K. Hassler, Florian Kestel, Rebekka Maier, Jonathan P. Sheppard, and Erwin Zehe
Hydrol. Earth Syst. Sci., 28, 3963–3982, https://doi.org/10.5194/hess-28-3963-2024, https://doi.org/10.5194/hess-28-3963-2024, 2024
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We studied a tree–crop ecosystem consisting of a blackberry field and an alder windbreak. In the water-scarce region, irrigation provides sufficient water for plant growth. The windbreak lowers the irrigation amount by reducing wind speed and therefore water transport into the atmosphere. These ecosystems could provide sustainable use of water-scarce landscapes, and we studied the complex interactions by observing several aspects (e.g. soil, nutrients, carbon assimilation, water).
Eduardo Acuña Espinoza, Ralf Loritz, Manuel Álvarez Chaves, Nicole Bäuerle, and Uwe Ehret
Hydrol. Earth Syst. Sci., 28, 2705–2719, https://doi.org/10.5194/hess-28-2705-2024, https://doi.org/10.5194/hess-28-2705-2024, 2024
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Hydrological hybrid models promise to merge the performance of deep learning methods with the interpretability of process-based models. One hybrid approach is the dynamic parameterization of conceptual models using long short-term memory (LSTM) networks. We explored this method to evaluate the effect of the flexibility given by LSTMs on the process-based part.
Evgeny Shavelzon and Yaniv Edery
Hydrol. Earth Syst. Sci., 28, 1803–1826, https://doi.org/10.5194/hess-28-1803-2024, https://doi.org/10.5194/hess-28-1803-2024, 2024
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We investigate the interaction of transport with dissolution–precipitation reactions in porous media using the concepts of entropy and work to quantify the emergence of preferential flow paths. We show that the preferential-flow-path phenomenon and the hydraulic power required to maintain the driving pressure drop intensify over time along with the heterogeneity due to the interaction between the transport and the reactive processes. This is more pronounced in diffusion-dominated flows.
Samuel Schroers, Ulrike Scherer, and Erwin Zehe
Hydrol. Earth Syst. Sci., 27, 2535–2557, https://doi.org/10.5194/hess-27-2535-2023, https://doi.org/10.5194/hess-27-2535-2023, 2023
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The hydrological cycle shapes our landscape. With an accelerating change of the world's climate and hydrological dynamics, concepts of evolution of natural systems become more important. In this study, we elaborated a thermodynamic framework for runoff and sediment transport and show from model results as well as from measurements during extreme events that the developed concept is useful for understanding the evolution of the system's mass, energy, and entropy fluxes.
Judith Meyer, Malte Neuper, Luca Mathias, Erwin Zehe, and Laurent Pfister
Hydrol. Earth Syst. Sci., 26, 6163–6183, https://doi.org/10.5194/hess-26-6163-2022, https://doi.org/10.5194/hess-26-6163-2022, 2022
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We identified and analysed the major atmospheric components of rain-intense thunderstorms that can eventually lead to flash floods: high atmospheric moisture, sufficient latent instability, and weak thunderstorm cell motion. Between 1981 and 2020, atmospheric conditions became likelier to support strong thunderstorms. However, the occurrence of extreme rainfall events as well as their rainfall intensity remained mostly unchanged.
Ralf Loritz, Maoya Bassiouni, Anke Hildebrandt, Sibylle K. Hassler, and Erwin Zehe
Hydrol. Earth Syst. Sci., 26, 4757–4771, https://doi.org/10.5194/hess-26-4757-2022, https://doi.org/10.5194/hess-26-4757-2022, 2022
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In this study, we combine a deep-learning approach that predicts sap flow with a hydrological model to improve soil moisture and transpiration estimates at the catchment scale. Our results highlight that hybrid-model approaches, combining machine learning with physically based models, are a promising way to improve our ability to make hydrological predictions.
Samuel Schroers, Olivier Eiff, Axel Kleidon, Ulrike Scherer, Jan Wienhöfer, and Erwin Zehe
Hydrol. Earth Syst. Sci., 26, 3125–3150, https://doi.org/10.5194/hess-26-3125-2022, https://doi.org/10.5194/hess-26-3125-2022, 2022
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In hydrology the formation of landform patterns is of special interest as changing forcings of the natural systems, such as climate or land use, will change these structures. In our study we developed a thermodynamic framework for surface runoff on hillslopes and highlight the differences of energy conversion patterns on two related spatial and temporal scales. The results indicate that surface runoff on hillslopes approaches a maximum power state.
Brian Berkowitz
Hydrol. Earth Syst. Sci., 26, 2161–2180, https://doi.org/10.5194/hess-26-2161-2022, https://doi.org/10.5194/hess-26-2161-2022, 2022
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Extensive efforts have focused on quantifying conservative chemical transport in geological formations. We assert that an explicit accounting of temporal information, under uncertainty, in addition to spatial information, is fundamental to an effective modeling formulation. We further assert that efforts to apply chemical transport equations at large length scales, based on measurements and model parameter values relevant to significantly smaller length scales, are an unattainable
holy grail.
Alexander Sternagel, Ralf Loritz, Brian Berkowitz, and Erwin Zehe
Hydrol. Earth Syst. Sci., 26, 1615–1629, https://doi.org/10.5194/hess-26-1615-2022, https://doi.org/10.5194/hess-26-1615-2022, 2022
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We present a (physically based) Lagrangian approach to simulate diffusive mixing processes on the pore scale beyond perfectly mixed conditions. Results show the feasibility of the approach for reproducing measured mixing times and concentrations of isotopes over pore sizes and that typical shapes of breakthrough curves (normally associated with non-uniform transport in heterogeneous soils) may also occur as a result of imperfect subscale mixing in a macroscopically homogeneous soil matrix.
Yaniv Edery, Martin Stolar, Giovanni Porta, and Alberto Guadagnini
Hydrol. Earth Syst. Sci., 25, 5905–5915, https://doi.org/10.5194/hess-25-5905-2021, https://doi.org/10.5194/hess-25-5905-2021, 2021
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The interplay between dissolution, precipitation and transport is widely encountered in porous media, from CO2 storage to cave formation in carbonate rocks. We show that dissolution occurs along preferential flow paths with high hydraulic conductivity, while precipitation occurs at locations close to yet separated from these flow paths, thus further funneling the flow and changing the probability density function of the transport, as measured on the altered conductivity field at various times.
Jan Bondy, Jan Wienhöfer, Laurent Pfister, and Erwin Zehe
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2021-174, https://doi.org/10.5194/hess-2021-174, 2021
Manuscript not accepted for further review
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The Budyko curve is a widely-used and simple framework to predict the mean water balance of river catchments. While many catchments are in close accordance with the Budyko curve, others show more or less significant deviations. Our study aims at better understanding the role of soil storage characteristics in the mean water balance and offsets from the Budyko curve. Soil storage proved to be a very sensitive property and potentially explains significant deviations from the curve.
Alexander Sternagel, Ralf Loritz, Julian Klaus, Brian Berkowitz, and Erwin Zehe
Hydrol. Earth Syst. Sci., 25, 1483–1508, https://doi.org/10.5194/hess-25-1483-2021, https://doi.org/10.5194/hess-25-1483-2021, 2021
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The key innovation of the study is a method to simulate reactive solute transport in the vadose zone within a Lagrangian framework. We extend the LAST-Model with a method to account for non-linear sorption and first-order degradation processes during unsaturated transport of reactive substances in the matrix and macropores. Model evaluations using bromide and pesticide data from irrigation experiments under different flow conditions on various timescales show the feasibility of the method.
Samuel Schroers, Olivier Eiff, Axel Kleidon, Jan Wienhöfer, and Erwin Zehe
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2021-79, https://doi.org/10.5194/hess-2021-79, 2021
Manuscript not accepted for further review
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In this study we ask the basic question why surface runoff forms drainage networks and confluences at all and how structural macro form and micro topography is a result of thermodynamic laws. We find that on a macro level hillslopes should tend from negative exponential towards exponential forms and that on a micro level the formation of rills goes hand in hand with drainage network formation of river basins. We hypothesize that we can learn more about erosion processes if we extend this theory.
Nicolas Björn Rodriguez, Laurent Pfister, Erwin Zehe, and Julian Klaus
Hydrol. Earth Syst. Sci., 25, 401–428, https://doi.org/10.5194/hess-25-401-2021, https://doi.org/10.5194/hess-25-401-2021, 2021
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Different parts of water have often been used as tracers to determine the age of water in streams. The stable tracers, such as deuterium, are thought to be unable to reveal old water compared to the radioactive tracer called tritium. We used both tracers, measured in precipitation and in a stream in Luxembourg, to show that this is not necessarily true. It is, in fact, advantageous to use the two tracers together, and we recommend systematically using tritium in future studies.
Ralf Loritz, Markus Hrachowitz, Malte Neuper, and Erwin Zehe
Hydrol. Earth Syst. Sci., 25, 147–167, https://doi.org/10.5194/hess-25-147-2021, https://doi.org/10.5194/hess-25-147-2021, 2021
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This study investigates the role and value of distributed rainfall in the runoff generation of a mesoscale catchment. We compare the performance of different hydrological models at different periods and show that a distributed model driven by distributed rainfall yields improved performances only during certain periods. We then step beyond this finding and develop a spatially adaptive model that is capable of dynamically adjusting its spatial model structure in time.
Conrad Jackisch, Samuel Knoblauch, Theresa Blume, Erwin Zehe, and Sibylle K. Hassler
Biogeosciences, 17, 5787–5808, https://doi.org/10.5194/bg-17-5787-2020, https://doi.org/10.5194/bg-17-5787-2020, 2020
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We developed software to calculate the root water uptake (RWU) of beech tree roots from soil moisture dynamics. We present our approach and compare RWU to measured sap flow in the tree stem. The study relates to two sites that are similar in topography and weather but with contrasting soils. While sap flow is very similar between the two sites, the RWU is different. This suggests that soil characteristics have substantial influence. Our easy-to-implement RWU estimate may help further studies.
Stephanie Thiesen, Diego M. Vieira, Mirko Mälicke, Ralf Loritz, J. Florian Wellmann, and Uwe Ehret
Hydrol. Earth Syst. Sci., 24, 4523–4540, https://doi.org/10.5194/hess-24-4523-2020, https://doi.org/10.5194/hess-24-4523-2020, 2020
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A spatial interpolator has been proposed for exploring the information content of the data in the light of geostatistics and information theory. It showed comparable results to traditional interpolators, with the advantage of presenting generalization properties. We discussed three different ways of combining distributions and their implications for the probabilistic results. By its construction, the method provides a suitable and flexible framework for uncertainty analysis and decision-making.
Uwe Ehret, Rik van Pruijssen, Marina Bortoli, Ralf Loritz, Elnaz Azmi, and Erwin Zehe
Hydrol. Earth Syst. Sci., 24, 4389–4411, https://doi.org/10.5194/hess-24-4389-2020, https://doi.org/10.5194/hess-24-4389-2020, 2020
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In this paper we propose adaptive clustering as a new method for reducing the computational efforts of distributed modelling. It consists of identifying similar-acting model elements during the runtime, clustering them, running the model for just a few representatives per cluster, and mapping their results to the remaining model elements in the cluster. With the example of a hydrological model, we show that this saves considerable computation time, while largely maintaining the output quality.
Mirko Mälicke, Sibylle K. Hassler, Theresa Blume, Markus Weiler, and Erwin Zehe
Hydrol. Earth Syst. Sci., 24, 2633–2653, https://doi.org/10.5194/hess-24-2633-2020, https://doi.org/10.5194/hess-24-2633-2020, 2020
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We could show that distributed soil moisture time series bear a considerable amount of information about dynamic changes in soil moisture. We developed a new method to describe spatial patterns and analyze their persistency. By combining uncertainty propagation with information theory, we were able to calculate the information content of spatial similarity with respect to measurement uncertainty. This does help to understand when and why the soil is drying in an organized manner.
Brian Berkowitz and Erwin Zehe
Hydrol. Earth Syst. Sci., 24, 1831–1858, https://doi.org/10.5194/hess-24-1831-2020, https://doi.org/10.5194/hess-24-1831-2020, 2020
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We present a
blueprintfor a unified modelling framework to quantify chemical transport in both surface water and groundwater systems. There has been extensive debate over recent decades, particularly in the surface water literature, about how to explain and account for long travel times of chemical species that are distinct from water flow (rainfall-runoff) travel times. We suggest a powerful modelling framework known to be robust and effective from the field of groundwater hydrology.
Alexander Sternagel, Ralf Loritz, Wolfgang Wilcke, and Erwin Zehe
Hydrol. Earth Syst. Sci., 23, 4249–4267, https://doi.org/10.5194/hess-23-4249-2019, https://doi.org/10.5194/hess-23-4249-2019, 2019
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We present our hydrological LAST-Model to simulate preferential soil water flow and tracer transport in macroporous soils. It relies on a Lagrangian perspective of the movement of discrete water particles carrying tracer masses through the subsoil and is hence an alternative approach to common models. Sensitivity analyses reveal the physical validity of the model concept and evaluation tests show that LAST can depict well observed tracer mass profiles with fingerprints of preferential flow.
Axel Kleidon, Erwin Zehe, and Ralf Loritz
Earth Syst. Dynam. Discuss., https://doi.org/10.5194/esd-2019-52, https://doi.org/10.5194/esd-2019-52, 2019
Manuscript not accepted for further review
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Many fluxes in Earth systems are not homogeneously distributed across space, but occur highly concentrated in structures, such as turbulent eddies, river networks, vascular networks of plants, or human-made infrastructures. Yet, the highly-organized nature of these fluxes is typically only described at a rudimentary level, if at all. We propose that it requires a novel approach to describe these structures that focuses on the work done to build and maintain these structures, and the feedbacks.
Ralf Loritz, Axel Kleidon, Conrad Jackisch, Martijn Westhoff, Uwe Ehret, Hoshin Gupta, and Erwin Zehe
Hydrol. Earth Syst. Sci., 23, 3807–3821, https://doi.org/10.5194/hess-23-3807-2019, https://doi.org/10.5194/hess-23-3807-2019, 2019
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In this study, we develop a topographic index explaining hydrological similarity within a energy-centered framework, with the observation that the majority of potential energy is dissipated when rainfall becomes runoff.
Erwin Zehe, Ralf Loritz, Conrad Jackisch, Martijn Westhoff, Axel Kleidon, Theresa Blume, Sibylle K. Hassler, and Hubert H. Savenije
Hydrol. Earth Syst. Sci., 23, 971–987, https://doi.org/10.5194/hess-23-971-2019, https://doi.org/10.5194/hess-23-971-2019, 2019
Martijn Westhoff, Axel Kleidon, Stan Schymanski, Benjamin Dewals, Femke Nijsse, Maik Renner, Henk Dijkstra, Hisashi Ozawa, Hubert Savenije, Han Dolman, Antoon Meesters, and Erwin Zehe
Earth Syst. Dynam. Discuss., https://doi.org/10.5194/esd-2019-6, https://doi.org/10.5194/esd-2019-6, 2019
Publication in ESD not foreseen
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Even models relying on physical laws have parameters that need to be measured or estimated. Thermodynamic optimality principles potentially offer a way to reduce the number of estimated parameters by stating that a system evolves to an optimum state. These principles have been applied successfully within the Earth system, but it is often unclear what to optimize and how. In this review paper we identify commonalities between different successful applications as well as some doubtful applications.
Nevil Quinn, Günter Blöschl, András Bárdossy, Attilio Castellarin, Martyn Clark, Christophe Cudennec, Demetris Koutsoyiannis, Upmanu Lall, Lubomir Lichner, Juraj Parajka, Christa D. Peters-Lidard, Graham Sander, Hubert Savenije, Keith Smettem, Harry Vereecken, Alberto Viglione, Patrick Willems, Andy Wood, Ross Woods, Chong-Yu Xu, and Erwin Zehe
Proc. IAHS, 380, 3–8, https://doi.org/10.5194/piahs-380-3-2018, https://doi.org/10.5194/piahs-380-3-2018, 2018
Nevil Quinn, Günter Blöschl, András Bárdossy, Attilio Castellarin, Martyn Clark, Christophe Cudennec, Demetris Koutsoyiannis, Upmanu Lall, Lubomir Lichner, Juraj Parajka, Christa D. Peters-Lidard, Graham Sander, Hubert Savenije, Keith Smettem, Harry Vereecken, Alberto Viglione, Patrick Willems, Andy Wood, Ross Woods, Chong-Yu Xu, and Erwin Zehe
Hydrol. Earth Syst. Sci., 22, 5735–5739, https://doi.org/10.5194/hess-22-5735-2018, https://doi.org/10.5194/hess-22-5735-2018, 2018
Mirko Mälicke, Sibylle K. Hassler, Markus Weiler, Theresa Blume, and Erwin Zehe
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2018-396, https://doi.org/10.5194/hess-2018-396, 2018
Manuscript not accepted for further review
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In this study we use time dependent variograms to identify periods of organized soil moisture during drying. We could identify emerging spatial patterns which imply periods of terrestrial control on soil moisture organization. The coupling of time dependent variograms with density based clustering is a new approach to detect similarity in spatial patterns. The presented method is useful to describe states of organization and improve kriging workflows by extending their prerequisites.
Ralf Loritz, Hoshin Gupta, Conrad Jackisch, Martijn Westhoff, Axel Kleidon, Uwe Ehret, and Erwin Zehe
Hydrol. Earth Syst. Sci., 22, 3663–3684, https://doi.org/10.5194/hess-22-3663-2018, https://doi.org/10.5194/hess-22-3663-2018, 2018
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In this study we explore the role of spatially distributed information on hydrological modeling. For that, we develop and test an approach which draws upon information theory and thermodynamic reasoning. We show that the proposed set of methods provide a powerful framework for understanding and diagnosing how and when process organization and functional similarity of hydrological systems emerge in time and, hence, when which landscape characteristic is important in a model application.
Conrad Jackisch and Erwin Zehe
Hydrol. Earth Syst. Sci., 22, 3639–3662, https://doi.org/10.5194/hess-22-3639-2018, https://doi.org/10.5194/hess-22-3639-2018, 2018
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We present a Lagrangian model for non-uniform soil water dynamics. It handles 2-D diffusion (based on a spatial random walk and implicit pore space redistribution) and 1-D advection in representative macropores (as film flow with dynamic interaction with the soil matrix). The interplay between the domains is calculated based on an energy-balance approach which does not require any additional parameterisation. Model tests give insight into the evolution of the non-uniform infiltration patterns.
Simon Höllering, Jan Wienhöfer, Jürgen Ihringer, Luis Samaniego, and Erwin Zehe
Hydrol. Earth Syst. Sci., 22, 203–220, https://doi.org/10.5194/hess-22-203-2018, https://doi.org/10.5194/hess-22-203-2018, 2018
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Hydrological fingerprints are introduced as response targets for sensitivity analysis and combined with a conventional approach using streamflow data for a temporally resolved sensitivity analysis. The joint benefit of both approaches is presented for several headwater catchments. The approach allows discerning a clarified pattern for parameter influences pinpointed to diverse response characteristics and detecting even slight regional differences.
Lisa Angermann, Conrad Jackisch, Niklas Allroggen, Matthias Sprenger, Erwin Zehe, Jens Tronicke, Markus Weiler, and Theresa Blume
Hydrol. Earth Syst. Sci., 21, 3727–3748, https://doi.org/10.5194/hess-21-3727-2017, https://doi.org/10.5194/hess-21-3727-2017, 2017
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This study investigates the temporal dynamics and response velocities of lateral preferential flow at the hillslope. The results are compared to catchment response behavior to infer the large-scale implications of the observed processes. A large portion of mobile water flows through preferential flow paths in the structured soils, causing an immediate discharge response. The study presents a methodological approach to cover the spatial and temporal domain of these highly heterogeneous processes.
Conrad Jackisch, Lisa Angermann, Niklas Allroggen, Matthias Sprenger, Theresa Blume, Jens Tronicke, and Erwin Zehe
Hydrol. Earth Syst. Sci., 21, 3749–3775, https://doi.org/10.5194/hess-21-3749-2017, https://doi.org/10.5194/hess-21-3749-2017, 2017
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Rapid subsurface flow in structured soils facilitates fast vertical and lateral redistribution of event water. We present its in situ exploration through local measurements and irrigation experiments. Special emphasis is given to a coherent combination of hydrological and geophysical methods. The study highlights that form and function operate as conjugated pairs. Dynamic imaging through time-lapse GPR was key to observing both and to identifying hydrologically relevant structures.
Simon Paul Seibert, Conrad Jackisch, Uwe Ehret, Laurent Pfister, and Erwin Zehe
Hydrol. Earth Syst. Sci., 21, 2817–2841, https://doi.org/10.5194/hess-21-2817-2017, https://doi.org/10.5194/hess-21-2817-2017, 2017
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Runoff production mechanisms and their corresponding physiographic controls continue to pose major research challenges in catchment hydrology. We propose innovative data-driven diagnostic signatures for overcoming the prevailing status quo in inter-comparison studies. Specifically, we present dimensionless double mass curves which allow us to infer information on runoff generation at the seasonal and annual timescales. The method is based on commonly available data.
Ralf Loritz, Sibylle K. Hassler, Conrad Jackisch, Niklas Allroggen, Loes van Schaik, Jan Wienhöfer, and Erwin Zehe
Hydrol. Earth Syst. Sci., 21, 1225–1249, https://doi.org/10.5194/hess-21-1225-2017, https://doi.org/10.5194/hess-21-1225-2017, 2017
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In this study we examine whether we can step beyond the qualitative character of perceptual models by using them as a blueprint for setting up representative hillslope models. Thereby we test the hypothesis of whether a single hillslope can represent the functioning of an entire lower mesoscale catchment in a spatially aggregated way.
Simon Paul Seibert, Uwe Ehret, and Erwin Zehe
Hydrol. Earth Syst. Sci., 20, 3745–3763, https://doi.org/10.5194/hess-20-3745-2016, https://doi.org/10.5194/hess-20-3745-2016, 2016
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While the assessment of "vertical" (magnitude) errors of streamflow simulations is standard practice, "horizontal" (timing) errors are rarely considered. To assess their role, we propose a method to quantify both errors simultaneously which closely resembles visual hydrograph comparison. Our results reveal differences in time–magnitude error statistics for different flow conditions. The proposed method thus offers novel perspectives for model diagnostics and evaluation.
Erwin Zehe and Conrad Jackisch
Hydrol. Earth Syst. Sci., 20, 3511–3526, https://doi.org/10.5194/hess-20-3511-2016, https://doi.org/10.5194/hess-20-3511-2016, 2016
Simon Höllering, Jürgen Ihringer, Luis Samaniego, and Erwin Zehe
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2016-249, https://doi.org/10.5194/hess-2016-249, 2016
Preprint withdrawn
M. Westhoff, E. Zehe, P. Archambeau, and B. Dewals
Hydrol. Earth Syst. Sci., 20, 479–486, https://doi.org/10.5194/hess-20-479-2016, https://doi.org/10.5194/hess-20-479-2016, 2016
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We derived mathematical formulations of relations between relative wetness and gradients driving run-off and evaporation for a one-box model such that, when conductances are optimized with the maximum power principle, the model leads exactly to a point on the Budyko curve.
With dry spells and dynamics in actual evaporation added, the model compared well with catchment observations without calibrating any parameter.
The maximum-power principle may thus be used to derive the Budyko curve.
U. Scherer and E. Zehe
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hessd-12-3527-2015, https://doi.org/10.5194/hessd-12-3527-2015, 2015
Revised manuscript not accepted
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This paper presents the development, parameterization and verification of a process-based soil erosion model for the catchment scale, which balances necessary complexity with greatest possible simplicity. We used the hydrologic model CATFLOW as a platform and further developed it to CATFLOW-SED by integrating approaches to simulate soil erosion. The model was validated on a hierarchy of scales which is characteristic for the governing processes.
E. Zehe, U. Ehret, L. Pfister, T. Blume, B. Schröder, M. Westhoff, C. Jackisch, S. J. Schymanski, M. Weiler, K. Schulz, N. Allroggen, J. Tronicke, L. van Schaik, P. Dietrich, U. Scherer, J. Eccard, V. Wulfmeyer, and A. Kleidon
Hydrol. Earth Syst. Sci., 18, 4635–4655, https://doi.org/10.5194/hess-18-4635-2014, https://doi.org/10.5194/hess-18-4635-2014, 2014
U. Ehret, H. V. Gupta, M. Sivapalan, S. V. Weijs, S. J. Schymanski, G. Blöschl, A. N. Gelfan, C. Harman, A. Kleidon, T. A. Bogaard, D. Wang, T. Wagener, U. Scherer, E. Zehe, M. F. P. Bierkens, G. Di Baldassarre, J. Parajka, L. P. H. van Beek, A. van Griensven, M. C. Westhoff, and H. C. Winsemius
Hydrol. Earth Syst. Sci., 18, 649–671, https://doi.org/10.5194/hess-18-649-2014, https://doi.org/10.5194/hess-18-649-2014, 2014
J. Wienhöfer and E. Zehe
Hydrol. Earth Syst. Sci., 18, 121–138, https://doi.org/10.5194/hess-18-121-2014, https://doi.org/10.5194/hess-18-121-2014, 2014
M. Liu, A. Bárdossy, and E. Zehe
Hydrol. Earth Syst. Sci., 17, 4685–4699, https://doi.org/10.5194/hess-17-4685-2013, https://doi.org/10.5194/hess-17-4685-2013, 2013
E. Zehe, U. Ehret, T. Blume, A. Kleidon, U. Scherer, and M. Westhoff
Hydrol. Earth Syst. Sci., 17, 4297–4322, https://doi.org/10.5194/hess-17-4297-2013, https://doi.org/10.5194/hess-17-4297-2013, 2013
M. C. Westhoff and E. Zehe
Hydrol. Earth Syst. Sci., 17, 3141–3157, https://doi.org/10.5194/hess-17-3141-2013, https://doi.org/10.5194/hess-17-3141-2013, 2013
A. Kleidon, E. Zehe, U. Ehret, and U. Scherer
Hydrol. Earth Syst. Sci., 17, 225–251, https://doi.org/10.5194/hess-17-225-2013, https://doi.org/10.5194/hess-17-225-2013, 2013
J. Wienhöfer, K. Germer, F. Lindenmaier, A. Färber, and E. Zehe
Hydrol. Earth Syst. Sci., 13, 1145–1161, https://doi.org/10.5194/hess-13-1145-2009, https://doi.org/10.5194/hess-13-1145-2009, 2009
Related subject area
Subject: Groundwater hydrology | Techniques and Approaches: Theory development
Identification, mapping, and eco-hydrological signal analysis for groundwater-dependent ecosystems (GDEs) in Langxi River basin, north China
Solutions and case studies for thermally driven reactive transport and porosity evolution in geothermal systems (reactive Lauwerier problem)
Technical note: Finite element formulations to map discrete fracture elements in three-dimensional groundwater models
Trends in long-term hydrological data from European karst areas: insights for groundwater recharge evaluation
Nitrate-nitrogen dynamics in response to forestry harvesting and climate variability: Four years of UV nitrate sensor data in a shallow, gravel aquifer
Technical note: Analytical solution for well water response to Earth tides in leaky aquifers with storage and compressibility in the aquitard
Flow recession behavior of preferential subsurface flow patterns with minimum energy dissipation
Towards a hydrogeomorphological understanding of proglacial catchments: an assessment of groundwater storage and release in an Alpine catchment
Effect of topographic slope on the export of nitrate in humid catchments: a 3D model study
Transit Time index (TTi) as an adaptation of the humification index to illustrate transit time differences in karst hydrosystems: application to the karst springs of the Fontaine de Vaucluse system (southeastern France)
In situ estimation of subsurface hydro-geomechanical properties using the groundwater response to semi-diurnal Earth and atmospheric tides
The Thiem team – Adolf and Günther Thiem, two forefathers of hydrogeology
Effects of aquifer geometry on seawater intrusion in annulus segment island aquifers
Depth to water table correction for initial carbon-14 activities in groundwater mean residence time estimation
Statistical characterization of environmental hot spots and hot moments and applications in groundwater hydrology
Technical note: Disentangling the groundwater response to Earth and atmospheric tides to improve subsurface characterisation
Flowing wells: terminology, history and role in the evolution of groundwater science
Asymmetric impact of groundwater use on groundwater droughts
New model of reactive transport in a single-well push–pull test with aquitard effect and wellbore storage
HESS Opinions: The myth of groundwater sustainability in Asia
Groundwater salinity variation in Upazila Assasuni (southwestern Bangladesh), as steered by surface clay layer thickness, relative elevation and present-day land use
Changes in groundwater drought associated with anthropogenic warming
Application of environmental tracers for investigation of groundwater mean residence time and aquifer recharge in fault-influenced hydraulic drop alluvium aquifers
HESS Opinions: Linking Darcy's equation to the linear reservoir
Effects of microarrangement of solid particles on PCE migration and its remediation in porous media
Hydrological connectivity from glaciers to rivers in the Qinghai–Tibet Plateau: roles of suprapermafrost and subpermafrost groundwater
Temporal variations of groundwater tables and implications for submarine groundwater discharge: a 3-decade case study in central Japan
Consequences and mitigation of saltwater intrusion induced by short-circuiting during aquifer storage and recovery in a coastal subsurface
Understanding groundwater – students' pre-conceptions and conceptual change by means of a theory-guided multimedia learning program
The referential grain size and effective porosity in the Kozeny–Carman model
Approximate analysis of three-dimensional groundwater flow toward a radial collector well in a finite-extent unconfined aquifer
Technical Note: The use of an interrupted-flow centrifugation method to characterise preferential flow in low permeability media
Shallow groundwater thermal sensitivity to climate change and land cover disturbances: derivation of analytical expressions and implications for stream temperature modeling
Confronting the vicinity of the surface water and sea shore in a shallow glaciogenic aquifer in southern Finland
Residence times and mixing of water in river banks: implications for recharge and groundwater–surface water exchange
Using 14C and 3H to understand groundwater flow and recharge in an aquifer window
Hydrogeology of an Alpine rockfall aquifer system and its role in flood attenuation and maintaining baseflow
Mobilisation or dilution? Nitrate response of karst springs to high rainfall events
Transferring the concept of minimum energy dissipation from river networks to subsurface flow patterns
Spectral induced polarization measurements for predicting the hydraulic conductivity in sandy aquifers
Transient analysis of fluctuations of electrical conductivity as tracer in the stream bed
Teaching hydrogeology: a review of current practice
Transient flow between aquifers and surface water: analytically derived field-scale hydraulic heads and fluxes
Influence of initial heterogeneities and recharge limitations on the evolution of aperture distributions in carbonate aquifers
Impact of climate change on groundwater point discharge: backflooding of karstic springs (Loiret, France)
Stream depletion rate with horizontal or slanted wells in confined aquifers near a stream
Tidal propagation in an oceanic island with sloping beaches
Mingyang Li, Fulin Li, Shidong Fu, Huawei Chen, Kairan Wang, Xuequn Chen, and Jiwen Huang
Hydrol. Earth Syst. Sci., 28, 4623–4642, https://doi.org/10.5194/hess-28-4623-2024, https://doi.org/10.5194/hess-28-4623-2024, 2024
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Research on groundwater-dependent ecosystems (GDEs) started earlier, but because there is no good identification and classification method, most of the related research is concentrated in Europe and Australia. In this study, the lower Yellow River basin in northern China, with well-developed karsts, was selected as the study area, and a four-diagnostic-criteria framework for identifying the GDEs based on remote sensing, GIS data dredging, and hydrogeological surveys was proposed.
Roi Roded, Einat Aharonov, Piotr Szymczak, Manolis Veveakis, Boaz Lazar, and Laura E. Dalton
Hydrol. Earth Syst. Sci., 28, 4559–4576, https://doi.org/10.5194/hess-28-4559-2024, https://doi.org/10.5194/hess-28-4559-2024, 2024
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Common practices in water resource management and geothermal applications involve the injection of hot or cold water into aquifers. The resulting thermal changes may lead to chemical disequilibrium and consequent mineral dissolution/precipitation in the rock void space. A mathematical model is developed to study the effects of such thermal fluid injection on the evolution of water composition, aquifer porosity, and permeability. The model is then applied to two important case studies.
Rob de Rooij
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2024-289, https://doi.org/10.5194/hess-2024-289, 2024
Revised manuscript accepted for HESS
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Coordinate transformations are often used in the finite element method. Here, three existing approaches are discussed that can be applied to the same mapping problem. From a mathematical viewpoint, the approaches are quite different. It is shown that all three approaches provide the same result. Interestingly, the more mathematically challenging approaches provide an expression that is the most practical to implement into a finite element code.
Markus Giese, Yvan Caballero, Andreas Hartmann, and Jean-Baptiste Charlier
EGUsphere, https://doi.org/10.5194/egusphere-2024-2078, https://doi.org/10.5194/egusphere-2024-2078, 2024
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Groundwater recharge and flow processes are difficult to quantify on a larger scale. Therefore, it is difficult to assess groundwater resources, substantially used for fresh water supply, and their changes over time. In karst areas, groundwater drainage networks over large areas are generated due to the soluble rocks. The observation of discharge from springs provides an alternative to estimate changes in groundwater resources over time, which can be connected to changing climatic conditions.
Ben Wilkins, Tom Johns, and Sarah Mager
EGUsphere, https://doi.org/10.5194/egusphere-2024-964, https://doi.org/10.5194/egusphere-2024-964, 2024
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We measured nitrate-nitrogen concentrations using a continuous UV nitrate sensor over four years in a shallow, gravel aquifer. We observed pulses of nitrate-nitrogen in response to forestry harvesting during subsequent rainfall recharge. Our novel hysteresis analysis helped elucidate event scale nitrate-nitrogen dynamics, while integrating continuous data improved nitrate-nitrogen load estimates. This work provides new insights into the variability of nitrate-nitrogen in permeable aquifers.
Rémi Valois, Agnès Rivière, Jean-Michel Vouillamoz, and Gabriel C. Rau
Hydrol. Earth Syst. Sci., 28, 1041–1054, https://doi.org/10.5194/hess-28-1041-2024, https://doi.org/10.5194/hess-28-1041-2024, 2024
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Characterizing aquifer systems is challenging because it is difficult to obtain in situ information. They can, however, be characterized using natural forces such as Earth tides. Models that account for more complex situations are still necessary to extend the use of Earth tides to assess hydromechanical properties of aquifer systems. Such a model is developed in this study and applied to a case study in Cambodia, where a combination of tides was used in order to better constrain the model.
Jannick Strüven and Stefan Hergarten
Hydrol. Earth Syst. Sci., 27, 3041–3058, https://doi.org/10.5194/hess-27-3041-2023, https://doi.org/10.5194/hess-27-3041-2023, 2023
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This study uses dendritic flow patterns to analyze the recession behavior of aquifer springs. The results show that the long-term recession becomes slower for large catchments. After a short recharge event, however, the short-term behavior differs strongly from the exponential recession that would be expected from a linear reservoir. The exponential component still accounts for more than 80 % of the total discharge, much more than typically assumed for karst aquifers.
Tom Müller, Stuart N. Lane, and Bettina Schaefli
Hydrol. Earth Syst. Sci., 26, 6029–6054, https://doi.org/10.5194/hess-26-6029-2022, https://doi.org/10.5194/hess-26-6029-2022, 2022
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This research provides a comprehensive analysis of groundwater storage in Alpine glacier forefields, a zone rapidly evolving with glacier retreat. Based on data analysis of a case study, it provides a simple perceptual model showing where and how groundwater is stored and released in a high Alpine environment. It especially points out the presence of groundwater storages in both fluvial and bedrock aquifers, which may become more important with future glacier retreat.
Jie Yang, Qiaoyu Wang, Ingo Heidbüchel, Chunhui Lu, Yueqing Xie, Andreas Musolff, and Jan H. Fleckenstein
Hydrol. Earth Syst. Sci., 26, 5051–5068, https://doi.org/10.5194/hess-26-5051-2022, https://doi.org/10.5194/hess-26-5051-2022, 2022
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We assessed the effect of catchment topographic slopes on the nitrate export dynamics in terms of the nitrogen mass fluxes and concentration level using a coupled surface–subsurface model. We found that flatter landscapes tend to retain more nitrogen mass in the soil and export less nitrogen mass to the stream, explained by the reduced leaching and increased potential of degradation in flat landscapes. We emphasized that stream water quality is potentially less vulnerable in flatter landscapes.
Leïla Serène, Christelle Batiot-Guilhe, Naomi Mazzilli, Christophe Emblanch, Milanka Babic, Julien Dupont, Roland Simler, Matthieu Blanc, and Gérard Massonnat
Hydrol. Earth Syst. Sci., 26, 5035–5049, https://doi.org/10.5194/hess-26-5035-2022, https://doi.org/10.5194/hess-26-5035-2022, 2022
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This work aims to develop the Transit Time index (TTi) as a natural tracer of karst groundwater transit time, usable in the 0–6-month range. Based on the fluorescence of organic matter, TTi shows its relevance to detect a small proportion of fast infiltration water within a mix, while other natural transit time tracers provide no or less sensitive information. Comparison of the average TTi of different karst springs also provides consistent results with the expected relative transit times.
Gabriel C. Rau, Timothy C. McMillan, Martin S. Andersen, and Wendy A. Timms
Hydrol. Earth Syst. Sci., 26, 4301–4321, https://doi.org/10.5194/hess-26-4301-2022, https://doi.org/10.5194/hess-26-4301-2022, 2022
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This work develops and applies a new method to estimate hydraulic and geomechanical subsurface properties in situ using standard groundwater and atmospheric pressure records. The estimated properties comply with expected values except for the Poisson ratio, which we attribute to the investigated scale and conditions. Our new approach can be used to cost-effectively investigate the subsurface using standard monitoring datasets.
Georg J. Houben and Okke Batelaan
Hydrol. Earth Syst. Sci., 26, 4055–4091, https://doi.org/10.5194/hess-26-4055-2022, https://doi.org/10.5194/hess-26-4055-2022, 2022
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Unbeknown to most hydrologists, many methods used in groundwater hydrology today go back to work by Adolf and Günther Thiem. Their work goes beyond the Dupuit–Thiem analytical model for pump tests mentioned in many textbooks. It includes, e.g., the development and improvement of isopotential maps, tracer tests, and vertical well constructions. Extensive literature and archive research has been conducted to identify how and where the Thiems developed their methods and how they spread.
Zhaoyang Luo, Jun Kong, Chengji Shen, Pei Xin, Chunhui Lu, Ling Li, and David Andrew Barry
Hydrol. Earth Syst. Sci., 25, 6591–6602, https://doi.org/10.5194/hess-25-6591-2021, https://doi.org/10.5194/hess-25-6591-2021, 2021
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Analytical solutions are derived for steady-state seawater intrusion in annulus segment aquifers. These analytical solutions are validated by comparing their predictions with experimental data. We find seawater intrusion is the most extensive in divergent aquifers, and the opposite is the case for convergent aquifers. The analytical solutions facilitate engineers and hydrologists in evaluating seawater intrusion more efficiently in annulus segment aquifers with a complex geometry.
Dylan J. Irvine, Cameron Wood, Ian Cartwright, and Tanya Oliver
Hydrol. Earth Syst. Sci., 25, 5415–5424, https://doi.org/10.5194/hess-25-5415-2021, https://doi.org/10.5194/hess-25-5415-2021, 2021
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It is widely assumed that 14C is in contact with the atmosphere until recharging water reaches the water table. Unsaturated zone (UZ) studies have shown that 14C decreases with depth below the land surface. We produce a relationship between UZ 14C and depth to the water table to estimate input 14C activities for groundwater age estimation. Application of the new relationship shows that it is important for UZ processes to be considered in groundwater mean residence time estimation.
Jiancong Chen, Bhavna Arora, Alberto Bellin, and Yoram Rubin
Hydrol. Earth Syst. Sci., 25, 4127–4146, https://doi.org/10.5194/hess-25-4127-2021, https://doi.org/10.5194/hess-25-4127-2021, 2021
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We developed a stochastic framework with indicator random variables to characterize the spatiotemporal distribution of environmental hot spots and hot moments (HSHMs) that represent rare locations and events exerting a disproportionate influence over the environment. HSHMs are characterized by static and dynamic indicators. This framework is advantageous as it allows us to calculate the uncertainty associated with HSHMs based on uncertainty associated with its contributors.
Gabriel C. Rau, Mark O. Cuthbert, R. Ian Acworth, and Philipp Blum
Hydrol. Earth Syst. Sci., 24, 6033–6046, https://doi.org/10.5194/hess-24-6033-2020, https://doi.org/10.5194/hess-24-6033-2020, 2020
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This work provides an important generalisation of a previously developed method that quantifies subsurface barometric efficiency using the groundwater level response to Earth and atmospheric tides. The new approach additionally allows the quantification of hydraulic conductivity and specific storage. This enables improved and rapid assessment of subsurface processes and properties using standard pressure measurements.
Xiao-Wei Jiang, John Cherry, and Li Wan
Hydrol. Earth Syst. Sci., 24, 6001–6019, https://doi.org/10.5194/hess-24-6001-2020, https://doi.org/10.5194/hess-24-6001-2020, 2020
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The gushing of water from flowing wells is a natural phenomenon of interest to the public. This review demonstrates that this spectacular phenomenon also instigated the science of groundwater and can be considered a root of groundwater hydrology. Observations of flowing wells not only led to the foundation of many principles of traditional groundwater hydrology but also played a vital role in the paradigm shift from aquitard-bound flow to cross-formational flow driven by topography.
Doris E. Wendt, Anne F. Van Loon, John P. Bloomfield, and David M. Hannah
Hydrol. Earth Syst. Sci., 24, 4853–4868, https://doi.org/10.5194/hess-24-4853-2020, https://doi.org/10.5194/hess-24-4853-2020, 2020
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Groundwater use changes the availability of groundwater, especially during droughts. This study investigates the impact of groundwater use on groundwater droughts. A methodological framework is presented that was developed and applied to the UK. We identified an asymmetric impact of groundwater use on droughts, which highlights the relation between short-term and long-term strategies for sustainable groundwater use.
Quanrong Wang, Junxia Wang, Hongbin Zhan, and Wenguang Shi
Hydrol. Earth Syst. Sci., 24, 3983–4000, https://doi.org/10.5194/hess-24-3983-2020, https://doi.org/10.5194/hess-24-3983-2020, 2020
Franklin W. Schwartz, Ganming Liu, and Zhongbo Yu
Hydrol. Earth Syst. Sci., 24, 489–500, https://doi.org/10.5194/hess-24-489-2020, https://doi.org/10.5194/hess-24-489-2020, 2020
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We are concerned about the sad state of affairs around groundwater in the developing countries of Asia and the obvious implications for sustainability. Groundwater production for irrigated agriculture has led to water-level declines that continue to worsen. Yet in the most populous countries, China, India, Pakistan, and Iran, there are only token efforts towards evidence-based sustainable management. It is unrealistic to expect evidence-based groundwater sustainability to develop any time soon.
Floris Loys Naus, Paul Schot, Koos Groen, Kazi Matin Ahmed, and Jasper Griffioen
Hydrol. Earth Syst. Sci., 23, 1431–1451, https://doi.org/10.5194/hess-23-1431-2019, https://doi.org/10.5194/hess-23-1431-2019, 2019
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In this paper, we postulate a possible evolution of the groundwater salinity around a village in southwestern Bangladesh, based on high-density fieldwork. We identified that the thickness of the surface clay layer, the surface elevation and the present-day land use determine whether fresh or saline groundwater has formed. The outcomes show how the large groundwater salinity variation in southwestern Bangladesh can be understood, which is valuable for the water management in the region.
John P. Bloomfield, Benjamin P. Marchant, and Andrew A. McKenzie
Hydrol. Earth Syst. Sci., 23, 1393–1408, https://doi.org/10.5194/hess-23-1393-2019, https://doi.org/10.5194/hess-23-1393-2019, 2019
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Groundwater is susceptible to drought due to natural variations in climate; however, to date there is no evidence of a relationship between climate change and groundwater drought. Using two long groundwater level records from the UK, we document increases in frequency, magnitude and intensity and changes in duration of groundwater drought associated with climate warming and infer that, given the extent of shallow groundwater globally, warming may widely effect changes to groundwater droughts.
Bin Ma, Menggui Jin, Xing Liang, and Jing Li
Hydrol. Earth Syst. Sci., 23, 427–446, https://doi.org/10.5194/hess-23-427-2019, https://doi.org/10.5194/hess-23-427-2019, 2019
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Groundwater supplies the most freshwater for industrial and agricultural production and domestic use in the arid northwest of China. This research uses environmental tracers to enhance one's understanding of groundwater, including aquifer recharge sources and groundwater mean residence times in the alluvium aquifers. The results provide valuable implications for groundwater resources regulation and sustainable development and have practical significance for other arid areas.
Hubert H. G. Savenije
Hydrol. Earth Syst. Sci., 22, 1911–1916, https://doi.org/10.5194/hess-22-1911-2018, https://doi.org/10.5194/hess-22-1911-2018, 2018
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This paper provides the connection between two simple equations describing groundwater flow at different scales: the Darcy equation describes groundwater flow at pore scale, the linear reservoir equation at catchment scale. The connection between the two appears to be very simple. The two parameters of the equations are proportional, depending on the porosity of the subsoil and the resistance for the groundwater to enter the surface drainage network.
Ming Wu, Jianfeng Wu, Jichun Wu, and Bill X. Hu
Hydrol. Earth Syst. Sci., 22, 1001–1015, https://doi.org/10.5194/hess-22-1001-2018, https://doi.org/10.5194/hess-22-1001-2018, 2018
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Fractal models of regular triangle arrangement (RTA) and square pitch arrangement (SPA) are developed in this study. Results suggest RTA can cause more groundwater contamination and make remediation more difficult. In contrast, the cleanup of contaminants in aquifers with SPA is easier. This study demonstrates how microscale arrangements control contaminant migration and remediation, which is helpful in designing successful remediation schemes for subsurface contamination.
Rui Ma, Ziyong Sun, Yalu Hu, Qixin Chang, Shuo Wang, Wenle Xing, and Mengyan Ge
Hydrol. Earth Syst. Sci., 21, 4803–4823, https://doi.org/10.5194/hess-21-4803-2017, https://doi.org/10.5194/hess-21-4803-2017, 2017
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The roles of groundwater flow in the hydrological cycle within the alpine area characterized by permafrost or seasonal frost are poorly known. We investigated the role of permafrost in controlling groundwater flow and hydrological connections between glaciers and river. The recharge, flow path and discharge of permafrost groundwater at the study site were explored. Two mechanisms were proposed to explain the significantly seasonal variation in interaction between groundwater and surface water.
Bing Zhang, Jing Zhang, and Takafumi Yoshida
Hydrol. Earth Syst. Sci., 21, 3417–3425, https://doi.org/10.5194/hess-21-3417-2017, https://doi.org/10.5194/hess-21-3417-2017, 2017
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Since groundwater is the linkage between climate changes and fresh submarine groundwater discharge, the variations of and relationships among monthly groundwater table, rainfall, snowfall, and climate change events from 1985 to 2015 were analyzed by wavelet coherence to discuss the implications for climate changes. The results show the increase in precipitation and the groundwater table, indicating that fresh submarine groundwater discharge flux may increase under climate change.
Koen Gerardus Zuurbier and Pieter Jan Stuyfzand
Hydrol. Earth Syst. Sci., 21, 1173–1188, https://doi.org/10.5194/hess-21-1173-2017, https://doi.org/10.5194/hess-21-1173-2017, 2017
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The subsurface is increasingly perforated for exploitation of water and energy. This has increased the risk of leakage between originally separated aquifers. It is shown how this leakage can have a very negative impact on the recovery of freshwater during aquifer storage and recovery (ASR) in brackish-saline aquifers. Deep interception of intruding brackish-saline water can mitigate the negative effects and buoyancy of freshwater to some extent, but not completely.
Ulrike Unterbruner, Sylke Hilberg, and Iris Schiffl
Hydrol. Earth Syst. Sci., 20, 2251–2266, https://doi.org/10.5194/hess-20-2251-2016, https://doi.org/10.5194/hess-20-2251-2016, 2016
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Studies show that young people have difficulties with correctly understanding groundwater. We designed a multimedia learning program about groundwater and tested its learning efficacy with pupils and teacher-training students. A novelty is the theory-guided designing of the program on the basis of hydrogeology and science education. The pupils and students greatly benefited from working through the multimedia learning program.
Kosta Urumović and Kosta Urumović Sr.
Hydrol. Earth Syst. Sci., 20, 1669–1680, https://doi.org/10.5194/hess-20-1669-2016, https://doi.org/10.5194/hess-20-1669-2016, 2016
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Calculation of hydraulic conductivity of porous materials is crucial for further use in hydrogeological modeling. The Kozeny–Carman model is theoretically impeccable but has not been properly used in recent scientific and expert literature. In this paper, proper use of the Kozeny-Carman formula is given through presentation of geometric mean grain size in the drilled-core sample as the referential mean grain size. Also, procedures for identification of real effective porosity of porous media are presented.
C.-S. Huang, J.-J. Chen, and H.-D. Yeh
Hydrol. Earth Syst. Sci., 20, 55–71, https://doi.org/10.5194/hess-20-55-2016, https://doi.org/10.5194/hess-20-55-2016, 2016
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Existing solutions for the problem of pumping at a radial collector well (RCW) in unconfined aquifers either require laborious calculation or predict divergent results at a middle period of pumping. This study relaxes the above two limitations to develop a new analytical solution for the problem. The application of the solution is convenient for those who are not familiar with numerical methods. New findings regarding the responses of flow to pumping at RCW are addressed.
R. A. Crane, M. O. Cuthbert, and W. Timms
Hydrol. Earth Syst. Sci., 19, 3991–4000, https://doi.org/10.5194/hess-19-3991-2015, https://doi.org/10.5194/hess-19-3991-2015, 2015
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We present an interrupted-flow centrifugation technique to characterise the vertical hydraulic properties of dual porosity, low permeability media. Use of large core samples (100mm diameter) enables hydraulic-conductivity-scale issues in dual porosity media to be overcome. Elevated centrifugal force also enables simulating in situ total stress conditions. The methodology is an important tool to assess the ability of dual porosity aquitards to protect underlying aquifer systems.
B. L. Kurylyk, K. T. B. MacQuarrie, D. Caissie, and J. M. McKenzie
Hydrol. Earth Syst. Sci., 19, 2469–2489, https://doi.org/10.5194/hess-19-2469-2015, https://doi.org/10.5194/hess-19-2469-2015, 2015
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Changes in climate and land cover are known to warm streams by altering surface heat fluxes. However, the influence of these disturbances on shallow groundwater temperature are not as well understood. In small streams, groundwater discharge may also exert a control on stream temperature, and thus groundwater warming may eventually produce additional stream warming not considered in most existing models. This study investigates these processes and suggests stream temperature model improvements.
S. Luoma, J. Okkonen, K. Korkka-Niemi, N. Hendriksson, and B. Backman
Hydrol. Earth Syst. Sci., 19, 1353–1370, https://doi.org/10.5194/hess-19-1353-2015, https://doi.org/10.5194/hess-19-1353-2015, 2015
N. P. Unland, I. Cartwright, D. I. Cendón, and R. Chisari
Hydrol. Earth Syst. Sci., 18, 5109–5124, https://doi.org/10.5194/hess-18-5109-2014, https://doi.org/10.5194/hess-18-5109-2014, 2014
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Periodic flooding of rivers should result in increased groundwater recharge near rivers and thus - younger and fresher groundwater near rivers. This study found the age and salinity of shallow groundwater to increase with proximity to the Tambo River in South East Australia. This appears to be due to the upwelling of older, regional groundwater closer the river. Other chemical parameters are consistent with this. This is a process that may be occurring in other similar river systems.
A. P. Atkinson, I. Cartwright, B. S. Gilfedder, D. I. Cendón, N. P. Unland, and H. Hofmann
Hydrol. Earth Syst. Sci., 18, 4951–4964, https://doi.org/10.5194/hess-18-4951-2014, https://doi.org/10.5194/hess-18-4951-2014, 2014
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This research article uses of radiogenic isotopes, stable isotopes and groundwater geochemistry to study groundwater age and recharge processes in the Gellibrand Valley, a relatively unstudied catchment and potential groundwater resource. The valley is found to contain both "old", regionally recharged groundwater (300-10,000 years) in the near-river environment, and modern groundwater (0-100 years old) further back on the floodplain. There is no recharge of the groundwater by high river flows.
U. Lauber, P. Kotyla, D. Morche, and N. Goldscheider
Hydrol. Earth Syst. Sci., 18, 4437–4452, https://doi.org/10.5194/hess-18-4437-2014, https://doi.org/10.5194/hess-18-4437-2014, 2014
M. Huebsch, O. Fenton, B. Horan, D. Hennessy, K. G. Richards, P. Jordan, N. Goldscheider, C. Butscher, and P. Blum
Hydrol. Earth Syst. Sci., 18, 4423–4435, https://doi.org/10.5194/hess-18-4423-2014, https://doi.org/10.5194/hess-18-4423-2014, 2014
S. Hergarten, G. Winkler, and S. Birk
Hydrol. Earth Syst. Sci., 18, 4277–4288, https://doi.org/10.5194/hess-18-4277-2014, https://doi.org/10.5194/hess-18-4277-2014, 2014
M. Attwa and T. Günther
Hydrol. Earth Syst. Sci., 17, 4079–4094, https://doi.org/10.5194/hess-17-4079-2013, https://doi.org/10.5194/hess-17-4079-2013, 2013
C. Schmidt, A. Musolff, N. Trauth, M. Vieweg, and J. H. Fleckenstein
Hydrol. Earth Syst. Sci., 16, 3689–3697, https://doi.org/10.5194/hess-16-3689-2012, https://doi.org/10.5194/hess-16-3689-2012, 2012
T. Gleeson, D. M. Allen, and G. Ferguson
Hydrol. Earth Syst. Sci., 16, 2159–2168, https://doi.org/10.5194/hess-16-2159-2012, https://doi.org/10.5194/hess-16-2159-2012, 2012
G. H. de Rooij
Hydrol. Earth Syst. Sci., 16, 649–669, https://doi.org/10.5194/hess-16-649-2012, https://doi.org/10.5194/hess-16-649-2012, 2012
B. Hubinger and S. Birk
Hydrol. Earth Syst. Sci., 15, 3715–3729, https://doi.org/10.5194/hess-15-3715-2011, https://doi.org/10.5194/hess-15-3715-2011, 2011
E. Joigneaux, P. Albéric, H. Pauwels, C. Pagé, L. Terray, and A. Bruand
Hydrol. Earth Syst. Sci., 15, 2459–2470, https://doi.org/10.5194/hess-15-2459-2011, https://doi.org/10.5194/hess-15-2459-2011, 2011
P.-R. Tsou, Z.-Y. Feng, H.-D. Yeh, and C.-S. Huang
Hydrol. Earth Syst. Sci., 14, 1477–1485, https://doi.org/10.5194/hess-14-1477-2010, https://doi.org/10.5194/hess-14-1477-2010, 2010
Y.-C. Chang, D.-S. Jeng, and H.-D. Yeh
Hydrol. Earth Syst. Sci., 14, 1341–1351, https://doi.org/10.5194/hess-14-1341-2010, https://doi.org/10.5194/hess-14-1341-2010, 2010
Cited articles
Ababou, R., McLaughlin, D., Gelhar, L. W., and Tompson, A. F. B.: Numerical
simulation of three-dimensional saturated flow in randomly heterogeneous
porous media, Transport Porous Med., 4, 549–565, 1989.
Applebaum, D.: Probability and Information, 1st edn., Cambridge University Press, Cambridge, 1996.
Becker, M. W. and Shapiro, A. M.: Tracer transport in fractured crystalline
rock: Evidence of nondiffusive breakthrough tailing, Water Resour.
Res., 36, 1677–1686, 2000.
Ben-Naim, A.: A Farewell to Entropy, World Scientific, chap. 1,
https://doi.org/10.1142/6469, 2008.
Berkowitz, B.: Characterizing flow and transport in fractured geological
media: A review, Adv. Water Resour., 25, 861–884, 2002.
Berkowitz, B. and Scher, H.: Anomalous transport in correlated velocity
fields, Phys. Rev. E., 81, 11128, https://doi.org/10.1103/PhysRevE.81.011128, 2010.
Berkowitz, B. and Zehe, E.: Surface water and groundwater: unifying conceptualization and quantification of the two “water worlds”, Hydrol. Earth Syst. Sci., 24, 1831–1858, https://doi.org/10.5194/hess-24-1831-2020, 2020.
Berkowitz, B., Cortis, A., Dentz, M., and Scher, H.: Modeling non-Fickian transport in geological formations as a continuous time random walk, Rev. Geophys., 44, RG2003, https://doi.org/10.1029/2005RG000178, 2006.
Beven, K. and Germann, P.: Water-Flow In Soil Macropores .2. A Combined
Flow Model, J. Soil Sci., 32, 15–29, 1981.
Beven, K. and Germann, P.: Macropores And Water-Flow In Soils, Water
Resour. Res., 18, 1311–1325, 1982.
Bianchi, M. and Pedretti, D.: Geological entropy and solute transport in
heterogeneous porous media, Water Resour. Res., 53, 4691–4708,
https://doi.org/10.1002/2016wr020195, 2017.
Bianchi, M. and Pedretti, D.: An entrogram-based approach to describe
spatial heterogeneity with applications to solute transport in porous media,
Water Resour. Res., 54, 4432–4448, https://doi.org/10.1029/2018wr022827, 2018.
Bianchi, M., Zheng, C., Wilson, C., Tick, G. R., Liu, G., and Gorelick, S. M.:
Spatial connectivity in a highly heterogeneous aquifer: From cores to
preferential flow paths, Water Resour. Res., 47, W05524,
https://doi.org/10.1029/2009WR008966, 2011.
Bolt, G. H. and Frissel, M. J.: Thermodynamics of soil moisture, Neth.
J. Agr. Sci., 8, 57–78, 1960.
Chiogna, G. and Rolle, M.: Entropy-based critical reaction time for
mixing-controlled reactive transport, Water Resour. Res., 53,
7488–7498, https://doi.org/10.1002/2017WR020522, 2017.
Cirpka, O. A. and Kitanidis, P. K.: Characterization of mixing and dilution in
heterogeneous aquifers by means of local temporal moments, Water Resour.
Res., 36, 1221–1236, 2000.
Clausius, R.: Über die Art der Bewegung, welche wir Wärme nennen,
Annalen der Physik und Chemie, 79, 353–380, 1857.
de Dreuzy, J.-R., Carrera, J., Dentz, M., and Le Borgne, T.: Time evolution of
mixing in heterogeneous porous media, Water Resour. Res., 48, W06511,
https://doi.org/10.1029/2011WR011360, 2012.
Dell'Oca, A., Guadagnini, A., and Riva, M.: Interpretation of multi-scale permeability data through an information theory perspective, Hydrol. Earth Syst. Sci., 24, 3097–3109, https://doi.org/10.5194/hess-24-3097-2020, 2020.
Domenico, P. A. and Schwartz, F. W.: Physical and Chemical Hydrogeology,
John Wiley, New York, 1990.
Edery, Y., Guadagnini, A., Scher, H., and Berkowitz, B.: Origins of
anomalous transport in disordered media: Structural and dynamic controls,
Water Resour. Res., 50, 1490–1505, https://doi.org/10.1002/2013WR015111, 2014.
Edery, Y., Stolar, M., Porta, G., and Guadagnini, A.: Feedback mechanisms between precipitation and dissolution reactions across randomly heterogeneous conductivity fields, Hydrol. Earth Syst. Sci. Discuss. [preprint], https://doi.org/10.5194/hess-2021-238, in review, 2021.
Fiori, A. and Jankovic, I.: On Preferential Flow, Channeling and
Connectivity in Heterogeneous Porous Formations, Math. Geosci., 44, 133–145,
https://doi.org/10.1007/s11004-011-9365-2, 2012.
Fahle, M., Hohenbrink, T. L., Dietrich, O., and Lischeid, G.: Temporal
variability of the optimal monitoring setup assessed using information
theory, Water Resour. Res., 51, 7723–7743, https://doi.org/10.1002/2015WR017137, 2015.
Flury, M., Flühler, H., Leuenberger, J., and Jury, W. A.: Susceptibility
of soils to preferential flow of water: a field study, Water Resour.
Res., 30, 1945–1954, 1994.
Groves, C. G. and Howard, A. D.: Early development of karst systems: 1.
Preferential flow path enlargement under laminar flow, Water Resour.
Res., 30, 2837–2846,
https://doi.org/10.1029/94WR01303, 1994.
Gómez-Hernánez, J. J., Sahuquillo, A., and Capilla, J.: Stochastic
simulation of transmissivity fields conditional to both transmissivity and
piezometric data – I. Theory, J. Hydrol., 203, 162–174,
https://doi.org/10.1016/S0022-1694(97)00098-X, 1997.
Haken, H.: Synergetics: An Introduction; Nonequilibrium Phase Transitions and Self-organization in Physics, Chemistry and Biology, 355 pp., Springer, Berlin, 1983.
Jackisch, C., Angermann, L., Allroggen, N., Sprenger, M., Blume, T., Tronicke, J., and Zehe, E.: Form and function in hillslope hydrology: in situ imaging and characterization of flow-relevant structures, Hydrol. Earth Syst. Sci., 21, 3749–3775, https://doi.org/10.5194/hess-21-3749-2017, 2017.
Jaynes, E. T.: Information theory and statistical mechanics, Phys. Rev. Lett., 106, 620–630, 1957.
Guadagnini, A. and Neuman, S. P.: Nonlocal and localized analyses of
conditional mean steady state flow in bounded, randomly nonuniform domains,
1, theory and computational approach, Water Resour. Res., 35, 2999–3018,
1999.
Hergarten, S., Winkler, G., and Birk, S.: Transferring the concept of minimum energy dissipation from river networks to subsurface flow patterns, Hydrol. Earth Syst. Sci., 18, 4277–4288, https://doi.org/10.5194/hess-18-4277-2014, 2014.
Howard, A. D.: Optimal angles of stream junctions: geometric stability to capture and minimum power criteria, Water Resour. Res., 7, 863–873, 1971.
Howard, A. D.: Theoretical model of optimal drainage networks, Water Resour.
Res., 26, 2107–2117, 1990.
Klaus, J. and Zehe, E.: A novel explicit approach to model bromide and pesticide transport in connected soil structures, Hydrol. Earth Syst. Sci., 15, 2127–2144, https://doi.org/10.5194/hess-15-2127-2011, 2011.
Kleidon, A.: Thermodynamic foundations of the Earth system, Cambridge University Press, New York
NY, 2016.
Kleidon, A., Zehe, E., Ehret, U., and Scherer, U.: Thermodynamics, maximum power, and the dynamics of preferential river flow structures at the continental scale, Hydrol. Earth Syst. Sci., 17, 225–251, https://doi.org/10.5194/hess-17-225-2013, 2013.
Kleidon, A., Renner, M., and Porada, P.: Estimates of the climatological land surface energy and water balance derived from maximum convective power, Hydrol. Earth Syst. Sci., 18, 2201–2218, https://doi.org/10.5194/hess-18-2201-2014, 2014.
Kitanidis, P. K.: The concept of the Dilution Index, Water Resour.
Res., 30, 2011–2026, https://doi.org/10.1029/94WR00762,
1994.
Kondepudi, D. and Prigogine, I.: Modern Thermodynamics: From Heat Engines
to Dissipative Structures, John Wiley Chichester, UK, 1998.
LaBolle, E. M. and Fogg, G. E.: Role of molecular diffusion in contaminant
migration and recovery in an alluvial aquifer system, Transport Porous
Med., 42, 155–179, 2001.
Levy, M. and Berkowitz, B.: Measurement and analysis of non-Fickian
dispersion in heterogeneous porous media, J. Contam. Hydrol., 64, 203–226,
2003.
Loritz, R., Gupta, H., Jackisch, C., Westhoff, M., Kleidon, A., Ehret, U., and Zehe, E.: On the dynamic nature of hydrological similarity, Hydrol. Earth Syst. Sci., 22, 3663–3684, https://doi.org/10.5194/hess-22-3663-2018, 2018.
Loritz, R., Kleidon, A., Jackisch, C., Westhoff, M., Ehret, U., Gupta, H., and Zehe, E.: A topographic index explaining hydrological similarity by accounting for the joint controls of runoff formation, Hydrol. Earth Syst. Sci., 23, 3807–3821, https://doi.org/10.5194/hess-23-3807-2019, 2019.
Loritz, R., Hrachowitz, M., Neuper, M., and Zehe, E.: The role and value of distributed precipitation data in hydrological models, Hydrol. Earth Syst. Sci., 25, 147–167, https://doi.org/10.5194/hess-25-147-2021, 2021.
Lotka, A. J.: Contribution to the energetics of evolution, P. Natl. Acad.
Sci. USA, 8, 147–151, 1922a.
Lotka, A. J.: Natural selection as a physical principle, P. Natl. Acad. Sci.
USA, 8, 151–154, 1922b.
Mälicke, M., Hassler, S. K., Blume, T., Weiler, M., and Zehe, E.: Soil moisture: variable in space but redundant in time, Hydrol. Earth Syst. Sci., 24, 2633–2653, https://doi.org/10.5194/hess-24-2633-2020, 2020.
Morvillo, M., Bonazzi, A., and Rizzo, C. B.: Improving the computational
efficiency of first arrival time uncertainty estimation using a
connectivity-based ranking Monte Carlo method, Stoch. Environ. Res. Risk
A., 35, 1039–1049, https://doi.org/10.1007/s00477-020-01943-5, 2021.
Nowak, W., Rubin, Y., and de Barros, F. P. J.: A hypothesis-driven approach to optimize field campaigns, Water Resour. Res., 48, https://doi.org/10.1029/2011WR011016, 2012.
Paltridge, G. W.: Climate and thermodynamic systems of maximum dissipation, Nature, 279, 630–631, https://doi.org/10.1038/279630a0, 1979.
Rinaldo, A., Maritan, A., Colaiori, F., Flammini, A., and Rigon, R.:
Thermodynamics of fractal networks, Phys. Rev. Lett., 76, 3364–3367,
1996.
Riva, M., Guadagnini, A., and Sanchez-Vila, X.: Effect of sorption
heterogeneity on moments of solute residence time in convergent flows, Math.
Geosci., 41, 835–853, https://doi.org/10.1007/s11004-009-9240-6, 2009.
Shannon, C. E.: A Mathematical Theory Of Communication, Bell Syst. Tech. J., 27, 623–656,
1948.
Sternagel, A., Loritz, R., Wilcke, W., and Zehe, E.: Simulating preferential soil water flow and tracer transport using the Lagrangian Soil Water and Solute Transport Model, Hydrol. Earth Syst. Sci., 23, 4249–4267, https://doi.org/10.5194/hess-23-4249-2019, 2019.
Sternagel, A., Loritz, R., Klaus, J., Berkowitz, B., and Zehe, E.: Simulation of reactive solute transport in the critical zone: a Lagrangian model for transient flow and preferential transport, Hydrol. Earth Syst. Sci., 25, 1483–1508, https://doi.org/10.5194/hess-25-1483-2021, 2021.
Schroers, S., Eiff, O., Kleidon, A., Wienhöfer, J., and Zehe, E.: Hortonian Overland Flow, Hillslope Morphology and Stream Power I: Spatial Energy Distributions and Steady-state Power Maxima, Hydrol. Earth Syst. Sci. Discuss. [preprint], https://doi.org/10.5194/hess-2021-79, 2021.
Šimůnek, J., Jarvis, N. J., van Genuchten, M. T., and
Gärdenäs, A.: Review and Comparison of models for describing
non-equilibrium and preferential flow and transport in the vadose zone,
J. Hydrol., 272, 14–35, 2003.
Tietjen, B., Zehe, E., and Jeltsch, F.: Simulating plant water availability in
dry lands under climate change: A generic model of two soil layers, Water
Resour. Res., 45, W01418,
https://doi.org/10.1029/2007WR006589, 2009.
van Schaik, L., Palm, J., Klaus, J., Zehe, E., and Schroeder, B.: Linking
spatial earthworm distribution to macropore numbers and hydrological
effectiveness, Ecohydrology, 7, 401–408, 2014.
Wienhöfer, J., Germer, K., Lindenmaier, F., Färber, A., and Zehe, E.: Applied tracers for the observation of subsurface stormflow at the hillslope scale, Hydrol. Earth Syst. Sci., 13, 1145–1161, https://doi.org/10.5194/hess-13-1145-2009, 2009.
Wienhöfer, J. and Zehe, E.: Predicting subsurface stormflow response of a forested hillslope – the role of connected flow paths, Hydrol. Earth Syst. Sci., 18, 121–138, https://doi.org/10.5194/hess-18-121-2014, 2014.
Willmann, M., Carrera, J., and Sánchez-Vila, X.: Transport upscaling in
heterogeneous aquifers: What physical parameters control memory functions?,
Water Resour. Res., 44, W12437, https://doi.org/10.1029/2007WR006531, 2008.
Woodbury, A. D. and Ulrych, T. J.: Minimum relative entropy: Forward
probabilistic modeling, Water Resour. Res., 29, 2847–2860,
https://doi.org/10.1029/93WR00923, 1993.
Zehe, E. and Flühler, H.: Preferential transport of isoproturon at a plot
scale and a field scale tile-drained site, J. Hydrol., 247,
100–115, 2001.
Zehe, E., Blume, T., and Bloschl, G.: The principle of `maximum energy dissipation': A novel thermodynamic perspective on rapid water flow in connected soil structures, Philos. T. Roy. Soc. B, 365, 1377–1386, https://doi.org/10.1098/rstb.2009.0308, 2010.
Zehe, E., Ehret, U., Blume, T., Kleidon, A., Scherer, U., and Westhoff, M.: A thermodynamic approach to link self-organization, preferential flow and rainfall–runoff behaviour, Hydrol. Earth Syst. Sci., 17, 4297–4322, https://doi.org/10.5194/hess-17-4297-2013, 2013.
Zehe, E., Loritz, R., Jackisch, C., Westhoff, M., Kleidon, A., Blume, T., Hassler, S. K., and Savenije, H. H.: Energy states of soil water – a thermodynamic perspective on soil water dynamics and storage-controlled streamflow generation in different landscapes, Hydrol. Earth Syst. Sci., 23, 971–987, https://doi.org/10.5194/hess-23-971-2019, 2019.
Short summary
This study uses the concepts of entropy and work to quantify and explain the emergence of preferential flow and transport in heterogeneous saturated porous media. We found that the downstream concentration of solutes in preferential pathways implies a downstream declining entropy in the transverse distribution of solute transport pathways. Preferential flow patterns with lower entropies emerged within media of higher heterogeneity – a stronger self-organization despite a higher randomness.
This study uses the concepts of entropy and work to quantify and explain the emergence of...
