Articles | Volume 24, issue 2
https://doi.org/10.5194/hess-24-945-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/hess-24-945-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| Highlight paper
| 
27 Feb 2020
Research article | Highlight paper |
| 27 Feb 2020
| 27 Feb 2020
Temperature controls production but hydrology regulates export of dissolved organic carbon at the catchment scale
Department of Civil and Environmental Engineering, The Pennsylvania
State University, University Park, PA 16802, USA
Julia Perdrial
Department of Geology, University of Vermont, Burlington, VT 05405, USA
Benjamin W. Abbott
Department of Plant and Wildlife Sciences, Brigham Young University, Provo, UT 84602, USA
Susana Bernal
Center of Advanced Studies of Blanes (CEAB-CSIC), Accés Cala St. Francesc 14, 17300, Blanes, Girona, Spain
Rémi Dupas
INRA, UMR 1069 SAS, Rennes, France
Sarah E. Godsey
Department of Geosciences, Idaho State University, Pocatello, ID
83201, USA
Adrian Harpold
Department of Natural Resources and Environmental Science, University of Nevada, Reno, NV 89557, USA
Donna Rizzo
Department of Civil and Environmental Engineering, University of
Vermont, Burlington, VT 05405, USA
Kristen Underwood
Department of Civil and Environmental Engineering, University of
Vermont, Burlington, VT 05405, USA
Thomas Adler
Department of Geology, University of Vermont, Burlington, VT 05405, USA
Gary Sterle
Department of Natural Resources and Environmental Science, University of Nevada, Reno, NV 89557, USA
Department of Civil and Environmental Engineering, The Pennsylvania
State University, University Park, PA 16802, USA
Related authors
Gary Sterle, Julia Perdrial, Dustin W. Kincaid, Kristen L. Underwood, Donna M. Rizzo, Ijaz Ul Haq, Li Li, Byung Suk Lee, Thomas Adler, Hang Wen, Helena Middleton, and Adrian A. Harpold
Hydrol. Earth Syst. Sci., 28, 611–630, https://doi.org/10.5194/hess-28-611-2024, https://doi.org/10.5194/hess-28-611-2024, 2024
Short summary
Short summary
We develop stream water chemistry to pair with the existing CAMELS (Catchment Attributes and Meteorology for Large-sample Studies) dataset. The newly developed dataset, termed CAMELS-Chem, includes common stream water chemistry constituents and wet deposition chemistry in 516 catchments. Examples show the value of CAMELS-Chem to trend and spatial analyses, as well as its limitations in sampling length and consistency.
Wei Zhi, Yuning Shi, Hang Wen, Leila Saberi, Gene-Hua Crystal Ng, Kayalvizhi Sadayappan, Devon Kerins, Bryn Stewart, and Li Li
Geosci. Model Dev., 15, 315–333, https://doi.org/10.5194/gmd-15-315-2022, https://doi.org/10.5194/gmd-15-315-2022, 2022
Short summary
Short summary
Watersheds are the fundamental Earth surface functioning unit that connects the land to aquatic systems. Here we present the recently developed BioRT-Flux-PIHM v1.0, a watershed-scale biogeochemical reactive transport model, to improve our ability to understand and predict solute export and water quality. The model has been verified against the benchmark code CrunchTope and has recently been applied to understand reactive transport processes in multiple watersheds of different conditions.
Hang Wen, Pamela L. Sullivan, Gwendolyn L. Macpherson, Sharon A. Billings, and Li Li
Biogeosciences, 18, 55–75, https://doi.org/10.5194/bg-18-55-2021, https://doi.org/10.5194/bg-18-55-2021, 2021
Short summary
Short summary
Carbonate weathering is essential in regulating carbon cycle at the century timescale. Plant roots accelerate weathering by elevating soil CO2 via respiration. It however remains poorly understood how and how much rooting characteristics modify flow paths and weathering. This work indicates that deepening roots in woodlands can enhance carbonate weathering by promoting recharge and CO2–carbonate contact in the deep, carbonate-abundant subsurface.
Roland Baatz, Pamela L. Sullivan, Li Li, Samantha R. Weintraub, Henry W. Loescher, Michael Mirtl, Peter M. Groffman, Diana H. Wall, Michael Young, Tim White, Hang Wen, Steffen Zacharias, Ingolf Kühn, Jianwu Tang, Jérôme Gaillardet, Isabelle Braud, Alejandro N. Flores, Praveen Kumar, Henry Lin, Teamrat Ghezzehei, Julia Jones, Henry L. Gholz, Harry Vereecken, and Kris Van Looy
Earth Syst. Dynam., 9, 593–609, https://doi.org/10.5194/esd-9-593-2018, https://doi.org/10.5194/esd-9-593-2018, 2018
Short summary
Short summary
Focusing on the usage of integrated models and in situ Earth observatory networks, three challenges are identified to advance understanding of ESD, in particular to strengthen links between biotic and abiotic, and above- and below-ground processes. We propose developing a model platform for interdisciplinary usage, to formalize current network infrastructure based on complementarities and operational synergies, and to extend the reanalysis concept to the ecosystem and critical zone.
Zewei Ma, Kaiyu Guan, Bin Peng, Wang Zhou, Robert Grant, Jinyun Tang, Murugesu Sivapalan, Ming Pan, Li Li, and Zhenong Jin
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2024-340, https://doi.org/10.5194/hess-2024-340, 2024
Preprint under review for HESS
Short summary
Short summary
We explore tile drainage’ impacts on the integrated hydrology-biogeochemistry-plant system, using ecosys with soil oxygen and microbe dynamics. We found that tile drainage lowers soil water content and improves soil oxygen levels, which helps crops grow better, especially during wet springs, and the developed root system also helps mitigate drought stress on dry summers. Overall, tile drainage increases crop resilience to climate change, making it a valuable future agricultural practice.
Thibault Lambert, Rémi Dupas, and Patrick Durand
Biogeosciences, 21, 4533–4547, https://doi.org/10.5194/bg-21-4533-2024, https://doi.org/10.5194/bg-21-4533-2024, 2024
Short summary
Short summary
This study investigates dissolved organic carbon (DOC) export in headwater catchments. Results show small links between DOC, nitrates, and the iron cycle throughout the year, calling into question our current conceptualization of DOC export at the catchment scale. Indeed, this study evidences that the winter period, referred as a non-productive period in our current conceptual model, acts as an active period for DOC production in riparian soils and DOC export toward stream waters.
Catherine M. Collins, Nicolas Perdrial, Pierre-Henri Blard, Nynke Keulen, William C. Mahaney, Halley Mastro, Juliana Souza, Donna M. Rizzo, Yves Marrocchi, Paul C. Knutz, and Paul R. Bierman
EGUsphere, https://doi.org/10.5194/egusphere-2024-2194, https://doi.org/10.5194/egusphere-2024-2194, 2024
Short summary
Short summary
The Camp Century sub-glacial core stores information about past climates, glacial and interglacial processes in northwest Greenland. In this study, we investigated the core archive making large scale observations using CT scans and micron scale observation observing physical and chemical characteristics of individual grains. We find evidence of past ice-free conditions, weathering processes during warmer periods, and past glaciations.
James Stegen, Amy Burgin, Michelle Busch, Joshua Fisher, Joshua Ladau, Jenna Abrahamson, Lauren Kinsman-Costello, Li Li, Xingyuan Chen, Thibault Datry, Nate McDowell, Corianne Tatariw, Anna Braswell, Jillian Deines, Julia Guimond, Peter Regier, Kenton Rod, Edward Bam, Etienne Fluet-Chouinard, Inke Forbrich, Kristin Jaeger, Teri O'Meara, Tim Scheibe, Erin Seybold, Jon Sweetman, Jianqiu Zheng, Daniel Allen, Elizabeth Herndon, Beth Middleton, Scott Painter, Kevin Roche, Julianne Scamardo, Ross Vander Vorste, Kristin Boye, Ellen Wohl, Margaret Zimmer, Kelly Hondula, Maggi Laan, Anna Marshall, and Kaizad Patel
EGUsphere, https://doi.org/10.5194/egusphere-2024-98, https://doi.org/10.5194/egusphere-2024-98, 2024
Short summary
Short summary
The loss and gain of surface water (variable inundation) is a common process across Earth. Global change shifts variable inundation dynamics, highlighting a need for unified understanding that transcends individual variably inundated ecosystems (VIEs). We review literature, highlight challenges, and emphasize opportunities to generate transferable knowledge by viewing VIEs through a common lens. We aim to inspire the emergence of a cross-VIE community based on a proposed continuum approach.
Gary Sterle, Julia Perdrial, Dustin W. Kincaid, Kristen L. Underwood, Donna M. Rizzo, Ijaz Ul Haq, Li Li, Byung Suk Lee, Thomas Adler, Hang Wen, Helena Middleton, and Adrian A. Harpold
Hydrol. Earth Syst. Sci., 28, 611–630, https://doi.org/10.5194/hess-28-611-2024, https://doi.org/10.5194/hess-28-611-2024, 2024
Short summary
Short summary
We develop stream water chemistry to pair with the existing CAMELS (Catchment Attributes and Meteorology for Large-sample Studies) dataset. The newly developed dataset, termed CAMELS-Chem, includes common stream water chemistry constituents and wet deposition chemistry in 516 catchments. Examples show the value of CAMELS-Chem to trend and spatial analyses, as well as its limitations in sampling length and consistency.
Chao Wang, Stephen Leisz, Li Li, Xiaoying Shi, Jiafu Mao, Yi Zheng, and Anping Chen
Earth Syst. Dynam., 15, 75–90, https://doi.org/10.5194/esd-15-75-2024, https://doi.org/10.5194/esd-15-75-2024, 2024
Short summary
Short summary
Climate change can significantly impact river runoff; however, predicting future runoff is challenging. Using historical runoff gauge data to evaluate model performances in runoff simulations for the Mekong River, we quantify future runoff changes in the Mekong River with the best simulation combination. Results suggest a significant increase in the annual runoff, along with varied seasonal distributions, thus heightening the need for adapted water resource management measures.
José L. J. Ledesma, Anna Lupon, Eugènia Martí, and Susana Bernal
Hydrol. Earth Syst. Sci., 26, 4209–4232, https://doi.org/10.5194/hess-26-4209-2022, https://doi.org/10.5194/hess-26-4209-2022, 2022
Short summary
Short summary
We studied a small stream located in a Mediterranean forest. Our goal was to understand how stream flow and the presence of riparian forests, which grow in flat banks near the stream, influence the availability of food for aquatic microorganisms. High flows were associated with higher amounts of food because rainfall episodes transfer it from the surrounding sources, particularly riparian forests, to the stream. Understanding how ecosystems work is essential to better manage natural resources.
Sebastian A. Krogh, Lucia Scaff, James W. Kirchner, Beatrice Gordon, Gary Sterle, and Adrian Harpold
Hydrol. Earth Syst. Sci., 26, 3393–3417, https://doi.org/10.5194/hess-26-3393-2022, https://doi.org/10.5194/hess-26-3393-2022, 2022
Short summary
Short summary
We present a new way to detect snowmelt using daily cycles in streamflow driven by solar radiation. Results show that warmer sites have earlier and more intermittent snowmelt than colder sites, and the timing of early snowmelt events is strongly correlated with the timing of streamflow volume. A space-for-time substitution shows greater sensitivity of streamflow timing to climate change in colder rather than in warmer places, which is then contrasted with land surface simulations.
Leonie Kiewiet, Ernesto Trujillo, Andrew Hedrick, Scott Havens, Katherine Hale, Mark Seyfried, Stephanie Kampf, and Sarah E. Godsey
Hydrol. Earth Syst. Sci., 26, 2779–2796, https://doi.org/10.5194/hess-26-2779-2022, https://doi.org/10.5194/hess-26-2779-2022, 2022
Short summary
Short summary
Climate change affects precipitation phase, which can propagate into changes in streamflow timing and magnitude. This study examines how variations in rainfall and snowmelt affect discharge. We found that annual discharge and stream cessation depended on the magnitude and timing of rainfall and snowmelt and on the snowpack melt-out date. This highlights the importance of precipitation timing and emphasizes the need for spatiotemporally distributed simulations of snowpack and rainfall dynamics.
Wei Zhi, Yuning Shi, Hang Wen, Leila Saberi, Gene-Hua Crystal Ng, Kayalvizhi Sadayappan, Devon Kerins, Bryn Stewart, and Li Li
Geosci. Model Dev., 15, 315–333, https://doi.org/10.5194/gmd-15-315-2022, https://doi.org/10.5194/gmd-15-315-2022, 2022
Short summary
Short summary
Watersheds are the fundamental Earth surface functioning unit that connects the land to aquatic systems. Here we present the recently developed BioRT-Flux-PIHM v1.0, a watershed-scale biogeochemical reactive transport model, to improve our ability to understand and predict solute export and water quality. The model has been verified against the benchmark code CrunchTope and has recently been applied to understand reactive transport processes in multiple watersheds of different conditions.
Arial J. Shogren, Jay P. Zarnetske, Benjamin W. Abbott, Samuel Bratsman, Brian Brown, Michael P. Carey, Randy Fulweber, Heather E. Greaves, Emma Haines, Frances Iannucci, Joshua C. Koch, Alexander Medvedeff, Jonathan A. O'Donnell, Leika Patch, Brett A. Poulin, Tanner J. Williamson, and William B. Bowden
Earth Syst. Sci. Data, 14, 95–116, https://doi.org/10.5194/essd-14-95-2022, https://doi.org/10.5194/essd-14-95-2022, 2022
Short summary
Short summary
Rapidly sampling multiple points in an entire river network provides a high-resolution snapshot in time that can reveal where nutrients and carbon are being taken up and released. Here, we describe two such datasets of river network chemistry in six Arctic watersheds in northern Alaska. We describe how these repeated snapshots can be used as an indicator of ecosystem response to climate change and to improve predictions of future release of carbon, nutrient, and other solutes.
Hang Wen, Pamela L. Sullivan, Gwendolyn L. Macpherson, Sharon A. Billings, and Li Li
Biogeosciences, 18, 55–75, https://doi.org/10.5194/bg-18-55-2021, https://doi.org/10.5194/bg-18-55-2021, 2021
Short summary
Short summary
Carbonate weathering is essential in regulating carbon cycle at the century timescale. Plant roots accelerate weathering by elevating soil CO2 via respiration. It however remains poorly understood how and how much rooting characteristics modify flow paths and weathering. This work indicates that deepening roots in woodlands can enhance carbonate weathering by promoting recharge and CO2–carbonate contact in the deep, carbonate-abundant subsurface.
James W. Kirchner, Sarah E. Godsey, Madeline Solomon, Randall Osterhuber, Joseph R. McConnell, and Daniele Penna
Hydrol. Earth Syst. Sci., 24, 5095–5123, https://doi.org/10.5194/hess-24-5095-2020, https://doi.org/10.5194/hess-24-5095-2020, 2020
Short summary
Short summary
Streams and groundwaters often show daily cycles in response to snowmelt and evapotranspiration. These typically have a roughly 6 h time lag, which is often interpreted as a travel-time lag. Here we show that it is instead primarily a phase lag that arises because aquifers integrate their inputs over time. We further show how these cycles shift seasonally, mirroring the springtime retreat of snow cover to higher elevations and the seasonal advance and retreat of photosynthetic activity.
Leila Saberi, Rachel T. McLaughlin, G.-H. Crystal Ng, Jeff La Frenierre, Andrew D. Wickert, Michel Baraer, Wei Zhi, Li Li, and Bryan G. Mark
Hydrol. Earth Syst. Sci., 23, 405–425, https://doi.org/10.5194/hess-23-405-2019, https://doi.org/10.5194/hess-23-405-2019, 2019
Short summary
Short summary
The relationship among glacier melt, groundwater, and streamflow remains highly uncertain, especially in tropical glacierized watersheds in response to climate. We implemented a multi-method approach and found that melt contribution varies considerably and may drive streamflow variability at hourly to multi-year timescales, rather than buffer it, as commonly thought. Some of the melt contribution occurs through groundwater pathways, resulting in longer timescale interactions with streamflow.
Rose Petersky and Adrian Harpold
Hydrol. Earth Syst. Sci., 22, 4891–4906, https://doi.org/10.5194/hess-22-4891-2018, https://doi.org/10.5194/hess-22-4891-2018, 2018
Short summary
Short summary
Ephemeral snowpacks are snowpacks that persist for less than 2 months. We show that ephemeral snowpacks melt earlier and provide less soil water input in the spring. Elevation is strongly correlated with whether snowpacks are ephemeral or seasonal. Snowpacks were also more likely to be ephemeral on south-facing slopes than north-facing slopes at high elevations. In warm years, the Great Basin shifts to ephemerally dominant as rain becomes more prevalent at increasing elevations.
Michael M. Loranty, Benjamin W. Abbott, Daan Blok, Thomas A. Douglas, Howard E. Epstein, Bruce C. Forbes, Benjamin M. Jones, Alexander L. Kholodov, Heather Kropp, Avni Malhotra, Steven D. Mamet, Isla H. Myers-Smith, Susan M. Natali, Jonathan A. O'Donnell, Gareth K. Phoenix, Adrian V. Rocha, Oliver Sonnentag, Ken D. Tape, and Donald A. Walker
Biogeosciences, 15, 5287–5313, https://doi.org/10.5194/bg-15-5287-2018, https://doi.org/10.5194/bg-15-5287-2018, 2018
Short summary
Short summary
Vegetation and soils strongly influence ground temperature in permafrost ecosystems across the Arctic and sub-Arctic. These effects will cause differences rates of permafrost thaw related to the distribution of tundra and boreal forests. As the distribution of forests and tundra change, the effects of climate change on permafrost will also change. We review the ecosystem processes that will influence permafrost thaw and outline how they will feed back to climate warming.
Anna Lupon, José L. J. Ledesma, and Susana Bernal
Hydrol. Earth Syst. Sci., 22, 4033–4045, https://doi.org/10.5194/hess-22-4033-2018, https://doi.org/10.5194/hess-22-4033-2018, 2018
Short summary
Short summary
We used the PERSiST model to explore the role of riparian evapotranspiration (ET) in regulating streamflow in Mediterranean regions. Riparian ET was essential for understanding streamflow dynamics, especially in summer. Moreover, climate change simulations showed that the contribution of riparian ET to annual water budgets will increase in the future. We must include riparian zones in hydrological models in order to establish proper management strategies in water-limited regions.
Sarah E. Godsey, Danny Marks, Patrick R. Kormos, Mark S. Seyfried, Clarissa L. Enslin, Adam H. Winstral, James P. McNamara, and Timothy E. Link
Earth Syst. Sci. Data, 10, 1207–1216, https://doi.org/10.5194/essd-10-1207-2018, https://doi.org/10.5194/essd-10-1207-2018, 2018
Short summary
Short summary
Weather data in mountainous rain-to-snow transition zones are limited, but are vital for water resources. We present a 10-year dataset for this zone that includes hourly temperatures, relative humidity, streamflow, snow depth, precipitation, wind speed/direction, solar energy, and soil moisture at 11 stations. Average air temperatures are near freezing 8 months each year, so that slight warming may determine whether rain falls instead of snow, affecting water supplies and fire risk.
Roland Baatz, Pamela L. Sullivan, Li Li, Samantha R. Weintraub, Henry W. Loescher, Michael Mirtl, Peter M. Groffman, Diana H. Wall, Michael Young, Tim White, Hang Wen, Steffen Zacharias, Ingolf Kühn, Jianwu Tang, Jérôme Gaillardet, Isabelle Braud, Alejandro N. Flores, Praveen Kumar, Henry Lin, Teamrat Ghezzehei, Julia Jones, Henry L. Gholz, Harry Vereecken, and Kris Van Looy
Earth Syst. Dynam., 9, 593–609, https://doi.org/10.5194/esd-9-593-2018, https://doi.org/10.5194/esd-9-593-2018, 2018
Short summary
Short summary
Focusing on the usage of integrated models and in situ Earth observatory networks, three challenges are identified to advance understanding of ESD, in particular to strengthen links between biotic and abiotic, and above- and below-ground processes. We propose developing a model platform for interdisciplinary usage, to formalize current network infrastructure based on complementarities and operational synergies, and to extend the reanalysis concept to the ecosystem and critical zone.
Susana Bernal, Anna Lupon, Núria Catalán, Sara Castelar, and Eugènia Martí
Hydrol. Earth Syst. Sci., 22, 1897–1910, https://doi.org/10.5194/hess-22-1897-2018, https://doi.org/10.5194/hess-22-1897-2018, 2018
Susan L. Brantley, David M. Eissenstat, Jill A. Marshall, Sarah E. Godsey, Zsuzsanna Balogh-Brunstad, Diana L. Karwan, Shirley A. Papuga, Joshua Roering, Todd E. Dawson, Jaivime Evaristo, Oliver Chadwick, Jeffrey J. McDonnell, and Kathleen C. Weathers
Biogeosciences, 14, 5115–5142, https://doi.org/10.5194/bg-14-5115-2017, https://doi.org/10.5194/bg-14-5115-2017, 2017
Short summary
Short summary
This review represents the outcome from an invigorating workshop discussion that involved tree physiologists, geomorphologists, ecologists, geochemists, and hydrologists and developed nine hypotheses that could be tested. We argue these hypotheses point to the essence of issues we must explore if we are to understand how the natural system of the earth surface evolves, and how humans will affect its evolution. This paper will create discussion and interest both before and after publication.
Rémi Dupas, Andreas Musolff, James W. Jawitz, P. Suresh C. Rao, Christoph G. Jäger, Jan H. Fleckenstein, Michael Rode, and Dietrich Borchardt
Biogeosciences, 14, 4391–4407, https://doi.org/10.5194/bg-14-4391-2017, https://doi.org/10.5194/bg-14-4391-2017, 2017
Short summary
Short summary
Carbon and nutrient export regimes were analyzed from archetypal headwater catchments to
downstream reaches. In headwater catchments, land use and lithology determine
land-to-stream C, N and P transfer processes. The crucial role of riparian
zones in C, N and P coupling was investigated. In downstream reaches,
point-source contributions and in-stream processes alter C, N and P export
regimes.
Adrian A. Harpold, Michael L. Kaplan, P. Zion Klos, Timothy Link, James P. McNamara, Seshadri Rajagopal, Rina Schumer, and Caitriana M. Steele
Hydrol. Earth Syst. Sci., 21, 1–22, https://doi.org/10.5194/hess-21-1-2017, https://doi.org/10.5194/hess-21-1-2017, 2017
Short summary
Short summary
The phase of precipitation as rain or snow is fundamental to hydrological processes and water resources. Despite its importance, the methods used to predict precipitation phase are inconsistent and often overly simplified. We review these methods and underlying mechanisms that control phase. We present a vision to meet important research gaps needed to improve prediction, including new field-based and remote measurements, validating new and existing methods, and expanding regional prediction.
Rémi Dupas, Jordy Salmon-Monviola, Keith J. Beven, Patrick Durand, Philip M. Haygarth, Michael J. Hollaway, and Chantal Gascuel-Odoux
Hydrol. Earth Syst. Sci., 20, 4819–4835, https://doi.org/10.5194/hess-20-4819-2016, https://doi.org/10.5194/hess-20-4819-2016, 2016
Short summary
Short summary
We developed a parsimonious topography-based hydrologic model coupled with a soil biogeochemistry sub-model in order to improve understanding and prediction of soluble reactive phosphorus (SRP) transfer in agricultural headwater catchments. The modelling approach includes an analysis of the information contained in the calibration data and propagation of uncertainty in model predictions using a GLUE "limits of acceptability" framework.
Anna Lupon, Susana Bernal, Sílvia Poblador, Eugènia Martí, and Francesc Sabater
Hydrol. Earth Syst. Sci., 20, 3831–3842, https://doi.org/10.5194/hess-20-3831-2016, https://doi.org/10.5194/hess-20-3831-2016, 2016
Short summary
Short summary
The influence of riparian evapotranspiration (ET) on stream hydrology and chemistry is poorly understood. We investigated temporal changes in riparian ET, stream discharge and nutrient chemistry along a Mediterranean catchment. Despite being a small component of annual water budgets (4.5 %), our results highlight that riparian ET drives stream and groundwater hydrology in Mediterranean catchments and, further, question the potential of the riparian zone as a natural filter of nitrogen loads.
Clarissa L. Enslin, Sarah E. Godsey, Danny Marks, Patrick R. Kormos, Mark S. Seyfried, James P. McNamara, and Timothy E. Link
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2016-44, https://doi.org/10.5194/essd-2016-44, 2016
Preprint withdrawn
Short summary
Short summary
Weather data in mountainous rain-to-snow transition zones are limited, but vital for water resources. We present a 10-year dataset for this zone that includes hourly temperatures, relative humidity, stream flow, snow depth, precipitation, wind speed/direction, solar energy, and soil moisture at 11 stations. Average air temperatures are near freezing eight months each year, so that slight warming may determine whether rain falls instead of snow, affecting water supplies, ecosystems and fire risk.
Zahra Thomas, Benjamin W. Abbott, Olivier Troccaz, Jacques Baudry, and Gilles Pinay
Biogeosciences, 13, 1863–1875, https://doi.org/10.5194/bg-13-1863-2016, https://doi.org/10.5194/bg-13-1863-2016, 2016
Short summary
Short summary
Direct human impact on a catchment (fertilizer input, soil disturbance, urbanization) is asymmetrically linked with inherent catchment properties (geology, soil, topography), which together determine catchment vulnerability to human activity. To quantify the influence of physical, hydrologic, and anthropogenic controls on surface water quality, we used a 5-year high-frequency water chemistry data set from three contrasting headwater catchments in western France.
J. E. Vonk, S. E. Tank, P. J. Mann, R. G. M. Spencer, C. C. Treat, R. G. Striegl, B. W. Abbott, and K. P. Wickland
Biogeosciences, 12, 6915–6930, https://doi.org/10.5194/bg-12-6915-2015, https://doi.org/10.5194/bg-12-6915-2015, 2015
Short summary
Short summary
We found that dissolved organic carbon (DOC) in arctic soils and aquatic systems is increasingly degradable with increasing permafrost extent. Also, DOC seems less degradable when moving down the fluvial network in continuous permafrost regions, i.e. from streams to large rivers, suggesting that highly bioavailable DOC is lost in headwater streams. We also recommend a standardized DOC incubation protocol to facilitate future comparison on processing and transport of DOC in a changing Arctic.
J. R. Larouche, B. W. Abbott, W. B. Bowden, and J. B. Jones
Biogeosciences, 12, 4221–4233, https://doi.org/10.5194/bg-12-4221-2015, https://doi.org/10.5194/bg-12-4221-2015, 2015
A. A. Harpold, J. A. Marshall, S. W. Lyon, T. B. Barnhart, B. A. Fisher, M. Donovan, K. M. Brubaker, C. J. Crosby, N. F. Glenn, C. L. Glennie, P. B. Kirchner, N. Lam, K. D. Mankoff, J. L. McCreight, N. P. Molotch, K. N. Musselman, J. Pelletier, T. Russo, H. Sangireddy, Y. Sjöberg, T. Swetnam, and N. West
Hydrol. Earth Syst. Sci., 19, 2881–2897, https://doi.org/10.5194/hess-19-2881-2015, https://doi.org/10.5194/hess-19-2881-2015, 2015
Short summary
Short summary
This review's objective is to demonstrate the transformative potential of lidar by critically assessing both challenges and opportunities for transdisciplinary lidar applications in geomorphology, hydrology, and ecology. We find that using lidar to its full potential will require numerous advances, including more powerful open-source processing tools, new lidar acquisition technologies, and improved integration with physically based models and complementary observations.
B. W. Abbott, J. B. Jones, S. E. Godsey, J. R. Larouche, and W. B. Bowden
Biogeosciences, 12, 3725–3740, https://doi.org/10.5194/bg-12-3725-2015, https://doi.org/10.5194/bg-12-3725-2015, 2015
Short summary
Short summary
As high latitudes warm, carbon and nitrogen stored in permafrost soil will be vulnerable to erosion and transport to Arctic streams and rivers. We sampled outflow from 83 permafrost collapse features in Alaska. Permafrost collapse caused substantial increases in dissolved organic carbon and inorganic nitrogen but decreased methane concentration by 90%. Upland thermokarst may be a dominant linkage transferring carbon and nutrients from terrestrial to aquatic ecosystems as the Arctic warms.
S. Bernal, A. Lupon, M. Ribot, F. Sabater, and E. Martí
Biogeosciences, 12, 1941–1954, https://doi.org/10.5194/bg-12-1941-2015, https://doi.org/10.5194/bg-12-1941-2015, 2015
Short summary
Short summary
Terrestrial inputs are considered the major driver of longitudinal patterns of nutrient concentration. Yet we show that longitudinal trends result from hydrological mixing with terrestrial inputs and in-stream processes. We challenge the idea that nutrient concentrations decrease downstream when in-stream net uptake is high. Conversely, in-stream processes can strongly affect stream nutrient chemistry and fluxes even in the absence of consistent longitudinal trends in nutrient concentration.
Related subject area
Subject: Biogeochemical processes | Techniques and Approaches: Theory development
Hydraulic shortcuts increase the connectivity of arable land areas to surface waters
Precipitation alters plastic film mulching impacts on soil respiration in an arid area of northwest China
A post-wildfire response in cave dripwater chemistry
Carbon and nitrogen dynamics and greenhouse gas emissions in constructed wetlands treating wastewater: a review
Landscape heterogeneity drives contrasting concentration–discharge relationships in shale headwater catchments
Iron oxidation kinetics and phosphate immobilization along the flow-path from groundwater into surface water
Phosphorus transport and retention in a channel draining an urban, tropical catchment with informal settlements
HESS Opinions "Biological catalysis of the hydrological cycle: life's thermodynamic function"
Urs Schönenberger and Christian Stamm
Hydrol. Earth Syst. Sci., 25, 1727–1746, https://doi.org/10.5194/hess-25-1727-2021, https://doi.org/10.5194/hess-25-1727-2021, 2021
Short summary
Short summary
Pesticides are a major pollutant of surface waters. In this study, we assessed how so-called hydraulic shortcuts (e.g. inlet and maintenance shafts of road or field storm drainage systems) influence surface runoff and pesticide transport to Swiss surface waters. The study suggests that transport via hydraulic shortcuts is an important pesticide transport pathway and that current regulations may fall short in addressing this pathway.
Guanghui Ming, Hongchang Hu, Fuqiang Tian, Zhenyang Peng, Pengju Yang, and Yiqi Luo
Hydrol. Earth Syst. Sci., 22, 3075–3086, https://doi.org/10.5194/hess-22-3075-2018, https://doi.org/10.5194/hess-22-3075-2018, 2018
Short summary
Short summary
The purpose of this research was to detect the effect of plastic film mulching (PFM), a widely applied cultivation method, on soil respiration. We found that soil respiration was not only affected by PFM, but it was also affected by irrigation and precipitation, and whether the PFM increases soil respiration compared to a non-mulched field largely depends on precipitation in the field. The result has an important meaning for agricultural carbon sequestration in the context of global warming.
Gurinder Nagra, Pauline C. Treble, Martin S. Andersen, Ian J. Fairchild, Katie Coleborn, and Andy Baker
Hydrol. Earth Syst. Sci., 20, 2745–2758, https://doi.org/10.5194/hess-20-2745-2016, https://doi.org/10.5194/hess-20-2745-2016, 2016
Short summary
Short summary
Our current understanding of wildfires on Earth is filled with knowledge gaps. One reason for this is our poor record of fire in natural archives. We open the possibility for speleothems to be "a missing piece to the fire-puzzle". We find by effecting surface evaporation and transpiration rates, wildfires can have a multi-year impact on speleothem, forming dripwater hydrology and chemistry. We open a new avenue for speleothems as potential palaeo-fire archives.
M. M. R. Jahangir, K. G. Richards, M. G. Healy, L. Gill, C. Müller, P. Johnston, and O. Fenton
Hydrol. Earth Syst. Sci., 20, 109–123, https://doi.org/10.5194/hess-20-109-2016, https://doi.org/10.5194/hess-20-109-2016, 2016
Short summary
Short summary
Removal efficiency of carbon and nitrogen in constructed wetlands is inconsistent and does not reveal whether the removal processes are from physical attenuation or transformation to other reactive forms. Previous research did not consider "pollution swapping" driven by transformational processes. Herein the biogeochemical dynamics and fate of carbon and nitrogen and their potential impact on the environment, as well as novel ways in which these knowledge gaps may be eliminated, are explored.
E. M. Herndon, A. L. Dere, P. L. Sullivan, D. Norris, B. Reynolds, and S. L. Brantley
Hydrol. Earth Syst. Sci., 19, 3333–3347, https://doi.org/10.5194/hess-19-3333-2015, https://doi.org/10.5194/hess-19-3333-2015, 2015
Short summary
Short summary
Solute concentrations in headwater streams vary with discharge due to changing flow paths through the catchment during precipitation events. A comparison of stream chemistry across three headwater catchments reveals that solute heterogeneity across each landscape controls how different solutes respond to increasing discharge. Solute heterogeneity is at least partially controlled by landscape distributions of vegetation and soil organic matter.
B. van der Grift, J. C. Rozemeijer, J. Griffioen, and Y. van der Velde
Hydrol. Earth Syst. Sci., 18, 4687–4702, https://doi.org/10.5194/hess-18-4687-2014, https://doi.org/10.5194/hess-18-4687-2014, 2014
Short summary
Short summary
Exfiltration of anoxic groundwater containing Fe(II) to surface water is an important mechanism controlling P speciation in the lowland catchments. Due to changes in pH and temperature, the Fe(II) oxidation rates were much lower in winter than in summer. This study also shows a fast transformation of dissolved P to structural P during the initial stage of the Fe oxidation process resulting in low dissolved P concentrations in the surface water throughout the year.
P. M. Nyenje, L. M. G. Meijer, J. W. Foppen, R. Kulabako, and S. Uhlenbrook
Hydrol. Earth Syst. Sci., 18, 1009–1025, https://doi.org/10.5194/hess-18-1009-2014, https://doi.org/10.5194/hess-18-1009-2014, 2014
K. Michaelian
Hydrol. Earth Syst. Sci., 16, 2629–2645, https://doi.org/10.5194/hess-16-2629-2012, https://doi.org/10.5194/hess-16-2629-2012, 2012
Cited articles
Abbott, B. W., Jones, J. B., Godsey, S. E., Larouche, J. R., and Bowden, W. B.: Patterns and persistence of hydrologic carbon and nutrient export from collapsing upland permafrost, Biogeosciences, 12, 3725–3740, https://doi.org/10.5194/bg-12-3725-2015, 2015.
Abbott, B. W., Baranov, V., Mendoza-Lera, C., Nikolakopoulou, M., Harjung,
A., Kolbe, T., Balasubramanian, M. N., Vaessen, T. N., Ciocca, F., Campeau,
A., Wallin, M. B., Romeijn, P., Antonelli, M., Goncalves, J., Datry, T.,
Laverman, A. M., de Dreuzy, J. R., Hannah, D. M., Krause, S., Oldham, C.,
and Pinay, G.: Using multi-tracer inference to move beyond single-catchment
ecohydrology, Earth-Sci. Rev., 160, 19–42, https://doi.org/10.1016/j.earscirev.2016.06.014,
2016.
Allard, D.: Simulating a geological lithofacies with respect to connectivity information using the truncated Gaussian model, in: Geostatistical Simulations, edited by: Armstrong M., and Dowd P.A., Springer, Dordrecht, the Netherlands, 197–211, https://doi.org/10.1007/978-94-015-8267-4_16, 1994.
Alvarez-Cobelas, M., Angeler, D. G., Sanchez-Carrillo, S., and Almendros,
G.: A worldwide view of organic carbon export from catchments,
Biogeochemistry, 107, 275–293, https://doi.org/10.1007/s10533-010-9553-z, 2012.
Andrews, D. M., Lin, H., Zhu, Q., Jin, L. X., and Brantley, S. L.: Hot Spots
and Hot Moments of Dissolved Organic Carbon Export and Soil Organic Carbon
Storage in the Shale Hills Catchment, Vadose Zone J., 10, 943–954, https://doi.org/10.2136/vzj2010.0149, 2011.
Aufdenkampe, A. K., Mayorga, E., Raymond, P. A., Melack, J. M., Doney, S.
C., Alin, S. R., Aalto, R. E., and Yoo, K.: Riverine coupling of
biogeochemical cycles between land, oceans, and atmosphere, Front. Ecol.
Environ., 9, 53–60, https://doi.org/10.1890/100014, 2011.
Bao, C., Li, L., Shi, Y. N., and Duffy, C.: Understanding watershed
hydrogeochemistry: 1. Development of RT-Flux-PIHM, Water Resour. Res., 53,
2328–2345, https://doi.org/10.1002/2016wr018934, 2017.
Battin, T. J., Luyssaert, S., Kaplan, L. A., Aufdenkampe, A. K., Richter,
A., and Tranvik, L. J.: The boundless carbon cycle, Nat. Geosci., 2,
598–600, https://doi.org/10.1038/ngeo618, 2009.
Bauer, J., Herbst, M., Huisman, J. A., Weihermuller, L., and Vereecken, H.:
Sensitivity of simulated soil heterotrophic respiration to temperature and
moisture reduction functions, Geoderma, 145, 17–27, https://doi.org/10.1016/j.geoderma.2008.01.026, 2008.
Bernal, S. and Sabater, F.: Changes in discharge and solute dynamics between hillslope and valley-bottom intermittent streams, Hydrol. Earth Syst. Sci., 16, 1595–1605, https://doi.org/10.5194/hess-16-1595-2012, 2012.
Bernal, S., Butturini, A., and Sabater, F.: Variability of DOC and nitrate responses to storms in a small Mediterranean forested catchment, Hydrol. Earth Syst. Sci., 6, 1031–1041, https://doi.org/10.5194/hess-6-1031-2002, 2002.
Bernal, S., Butturini, A., and Sabater, F.: Seasonal variations of dissolved
nitrogen and DOC : DON ratios in an intermittent Mediterranean stream,
Biogeochemistry, 75, 351–372, https://doi.org/10.1007/s10533-005-1246-7, 2005.
Bernhardt, E. S., Blaszczak, J. R., Ficken, C. D., Fork, M. L., Kaiser, K.
E., and Seybold, E. C.: Control Points in Ecosystems: Moving Beyond the Hot
Spot Hot Moment Concept, Ecosystems, 20, 665–682, https://doi.org/10.1007/s10021-016-0103-y,
2017.
Billings, S. A., Hirmas, D., Sullivan, P. L., Lehmeier, C. A., Bagchi, S.,
Min, K., Brecheisen, Z., Hauser, E., Stair, R., Flournoy, R., and Richter,
D. D.: Loss of deep roots limits biogenic agents of soil development that
are only partially restored by decades of forest regeneration,
Elem. Sci. Anth., 6, 34, https://doi.org/10.1525/elementa.287, 2018.
Bishop, K., Seibert, J., Köhler, S., and Laudon, H.: Resolving the
Double Paradox of rapidly mobilized old water with highly variable responses
in runoff chemistry, Hydrol. Process., 18, 185–189, https://doi.org/10.1002/hyp.5209,
2004.
Bolan, N. S., Adriano, D. C., Kunhikrishnan, A., James, T., McDowell, R.,
and Senesi, N.: Dissolved organic matter: biogeochemistry, dynamics, and
environmental significance in soils, in: Advances in Agronomy, vol. 110,
edited by: Sparks, D. L., Advances in Agronomy, Elsevier Academic Press Inc,
San Diego, USA, 1–75, 2011.
Brantley, S. L. and Duffy, C. J.: CZO Dataset: Shale Hills – Streamflow (2006–2012) and Stream Water Chemistry (2006–2010), available at: http://criticalzone.org/shale-hills/data/datasets/ (last access: 11 February 2020), 2012.
Brantley, S. L., White, T., West, N., Williams, J. Z., Forsythe, B.,
Shapich, D., Kaye, J., Lin, H., Shi, Y. N., Kaye, M., Herndon, E., Davis, K.
J., He, Y., Eissenstat, D., Weitzman, J., DiBiase, R., Li, L., Reed, W.,
Brubaker, K., and Gu, X.: Susquehanna Shale Hills Critical Zone Observatory:
Shale Hills in the Context of Shaver's Creek Watershed, Vadose Zone J., 17, 180092–180110, https://doi.org/10.2136/vzj2018.04.0092, 2018.
Campeau, A., Bishop, K., Amvrosiadi, N., Billett, M. F., Garnett, M. N.,
Laudon, H., Oquist, M. G., and Wallin, M. B.: Current forest carbon fixation
fuels stream CO2 emissions, Nat. Commun., 10, 1876, https://doi.org/10.1038/s41467-019-09922-3, 2019.
Chapin, F. S., Woodwell, G. M., Randerson, J. T., Rastetter, E. B., Lovett,
G. M., Baldocchi, D. D., Clark, D. A., Harmon, M. E., Schimel, D. S.,
Valentini, R., Wirth, C., Aber, J. D., Cole, J. J., Goulden, M. L., Harden,
J. W., Heimann, M., Howarth, R. W., Matson, P. A., McGuire, A. D., Melillo,
J. M., Mooney, H. A., Neff, J. C., Houghton, R. A., Pace, M. L., Ryan, M.
G., Running, S. W., Sala, O. E., Schlesinger, W. H., and Schulze, E. D.:
Reconciling carbon-cycle concepts, terminology, and methods, Ecosystems, 9,
1041–1050, https://doi.org/10.1007/s10021-005-0105-7, 2006.
Chiou, C. T., Lee, J. F., and Boyd, S. A.: THE SURFACE-AREA OF SOIL
ORGANIC-MATTER, Environ. Sci. Technol., 24, 1164–1166, https://doi.org/10.1021/es00078a002,
1990.
Cincotta, M., Perdrial, J. N., Shavitz, A., Shanley, J., Perdrial, N.,
Armfield, J., Liebenson, A., Landsman, M., and Adler, T.: Soil aggregates as
source of dissolved organic carbon to streams: an experimental study on the
effect of solution chemistry on water extractable carbon, Frontiers in Earth
Science, 7, 172, https://doi.org/10.3389/fenvs.2019.00172, 2019.
Clark, J. M., Bottrell, S. H., Evans, C. D., Monteith, D. T., Bartlett, R.,
Rose, R., Newton, R. J., and Chapman, P. J.: The importance of the
relationship between scale and process in understanding long-term DOC
dynamics, Sci. Total Environ., 408, 2768–2775, https://doi.org/10.1016/j.scitotenv.2010.02.046, 2010.
Conant, R. T., Ryan, M. G., Agren, G. I., Birge, H. E., Davidson, E. A.,
Eliasson, P. E., Evans, S. E., Frey, S. D., Giardina, C. P., Hopkins, F. M.,
Hyvonen, R., Kirschbaum, M. U. F., Lavallee, J. M., Leifeld, J., Parton, W.
J., Steinweg, J. M., Wallenstein, M. D., Wetterstedt, J. A. M., and
Bradford, M. A.: Temperature and soil organic matter decomposition rates -
synthesis of current knowledge and a way forward, Glob. Change Biol., 17,
3392–3404, https://doi.org/10.1111/j.1365-2486.2011.02496.x, 2011.
Correll, D. L., Jordan, T. E., and Weller, D. E.: Effects of precipitation,
air temperature, and land use on organic carbon discharges from rhode river
watersheds, Water Air Soil Poll., 128, 139–159, https://doi.org/10.1023/a:1010337623092, 2001.
Covino, T.: Hydrologic connectivity as a framework for understanding
biogeochemical flux through watersheds and along fluvial networks,
Geomorphology, 277, 133–144, https://doi.org/10.1016/j.geomorph.2016.09.030, 2017.
Crowther, T. W., Todd-Brown, K. E. O., Rowe, C. W., Wieder, W. R., Carey, J.
C., Machmuller, M. B., Snoek, B. L., Fang, S., Zhou, G., Allison, S. D.,
Blair, J. M., Bridgham, S. D., Burton, A. J., Carrillo, Y., Reich, P. B.,
Clark, J. S., Classen, A. T., Dijkstra, F. A., Elberling, B., Emmett, B. A.,
Estiarte, M., Frey, S. D., Guo, J., Harte, J., Jiang, L., Johnson, B. R.,
Kroel-Dulay, G., Larsen, K. S., Laudon, H., Lavallee, J. M., Luo, Y.,
Lupascu, M., Ma, L. N., Marhan, S., Michelsen, A., Mohan, J., Niu, S.,
Pendall, E., Penuelas, J., Pfeifer-Meister, L., Poll, C., Reinsch, S.,
Reynolds, L. L., Schmidt, I. K., Sistla, S., Sokol, N. W., Templer, P. H.,
Treseder, K. K., Welker, J. M., and Bradford, M. A.: Quantifying global soil
carbon losses in response to warming, Nature, 540, 104–108, https://doi.org/10.1038/nature20150, 2016.
Currie, W. S., Aber, J. D., McDowell, W. H., Boone, R. D., and Magill, A.
H.: Vertical transport of dissolved organic C and N under long-term N
amendments in pine and hardwood forests, Biogeochemistry, 35, 471–505, https://doi.org/10.1007/bf02183037, 1996.
D'Amore, D. V., Edwards, R. T., Herendeen, P. A., Hood, E., and Fellman, J.
B.: Dissolved Organic Carbon Fluxes from Hydropedologic Units in Alaskan
Coastal Temperate Rainforest Watersheds, Soil Sci. Soc. Am.
J., 79, 378–388, https://doi.org/10.2136/sssaj2014.09.0380, 2015.
Davidson, E. A. and Janssens, I. A.: Temperature sensitivity of soil carbon
decomposition and feedbacks to climate change, Nature, 440, 165–173, https://doi.org/10.1038/nature04514, 2006.
de Wit, H. A., Ledesma, J. L. J., and Futter, M. N.: Aquatic DOC export from
subarctic Atlantic blanket bog in Norway is controlled by seasalt
deposition, temperature and precipitation, Biogeochemistry, 127, 305–321, https://doi.org/10.1007/s10533-016-0182-z, 2016.
Dhillon, G. S. and Inamdar, S.: Storm event patterns of particulate organic
carbon (POC) for large storms and differences with dissolved organic carbon
(DOC), Biogeochemistry, 118, 61–81, https://doi.org/10.1007/s10533-013-9905-6, 2014.
Diem, S., von Rohr, M. R., Hering, J. G., Kohler, H. P. E., Schirmer, M.,
and von Gunten, U.: NOM degradation during river infiltration: Effects of
the climate variables temperature and discharge, Water Res., 47,
6585–6595, https://doi.org/10.1016/j.watres.2013.08.028, 2013.
Du, X. Z., Zhang, X. S., Mukundan, R., Hoang, L., and Owens, E. M.:
Integrating terrestrial and aquatic processes toward watershed scale
modeling of dissolved organic carbon fluxes, Environ. Pollut., 249, 125–135, https://doi.org/10.1016/j.envpol.2019.03.014, 2019.
Duffy, C., Shi, Y., Davis, K., Slingerland, R., Li, L., Sullivan, P. L.,
Goddéris, Y., Brantley, S. L. J. P. E., and Science, P.: Designing a
suite of models to explore critical zone function, Procedia Earth and Planetary Science, 10, 7–15, https://doi.org/10.1016/j.proeps.2014.08.003, 2014.
Duncan, J. M., Welty, C., Kemper, J. T., Groffman, P. M., and Band, L. E.:
Dynamics of nitrate concentration-discharge patterns in an urban watershed,
Water Resour. Res., 53, 7349–7365, https://doi.org/10.1002/2017WR020500, 2017.
Evans, C. D., Jones, T. G., Burden, A., Ostle, N., Zielinski, P., Cooper, M.
D. A., Peacock, M., Clark, J. M., Oulehle, F., Cooper, D., and Freeman, C.:
Acidity controls on dissolved organic carbon mobility in organic soils,
Glob. Change Biol., 18, 3317–3331, https://doi.org/10.1111/j.1365-2486.2012.02794.x, 2012.
Fissore, C., Giardina, C. P., Kolka, R. K., and Trettin, C. C.: Soil organic
carbon quality in forested mineral wetlands at different mean annual
temperature, Soil Biol. Biochem., 41, 458–466, https://doi.org/10.1016/j.soilbio.2008.11.004, 2009.
Futter, M. N., Butterfield, D., Cosby, B. J., Dillon, P. J., Wade, A. J.,
and Whitehead, P. G.: Modeling the mechanisms that control in-stream
dissolved organic carbon dynamics in upland and forested catchments, Water
Resour. Res., 43, W02424, https://doi.org/10.1029/2006wr004960, 2007.
Gillooly, J. F., Brown, J. H., West, G. B., Savage, V. M., and Charnov, E.
L.: Effects of size and temperature on metabolic rate, Science, 293,
2248–2251, https://doi.org/10.1126/science.1061967, 2001.
Godsey, S. E., Kirchner, J. W., and Clow, D. W.: Concentration-discharge
relationships reflect chemostatic characteristics of US catchments,
Hydrol. Process., 23, 1844–1864, https://doi.org/10.1002/hyp.7315, 2009.
Gomez, R., Arce, M. I., Sanchez, J. J., and Sanchez-Montoya, M. D.: The effects of drying on sediment nitrogen content in a Mediterranean intermittent stream: a microcosms study, Hydrobiologia, 679, 43–59, https://doi.org/10.1007/s10750-011-0854-6, 2012.
Hale, R. L., Turnbull, L., Earl, S. R., Childers, D. L., and Grimm, N. B.:
Stormwater Infrastructure Controls Runoff and Dissolved Material Export from
Arid Urban Watersheds, Ecosystems, 18, 62–75, https://doi.org/10.1007/s10021-014-9812-2,
2015.
Hamamoto, S., Moldrup, P., Kawamoto, K., and Komatsu, T.: Excluded-volume
expansion of Archie's law for gas and solute diffusivities and electrical
and thermal conductivities in variably saturated porous media, Water Resour.
Res., 46, W06514, https://doi.org/10.1029/2009wr008424, 2010.
Hasenmueller, E. A., Jin, L. X., Stinchcomb, G. E., Lin, H., Brantley, S.
L., and Kaye, J. P.: Topographic controls on the depth distribution of soil
CO2 in a small temperate watershed, Appl. Geochem., 63, 58–69, https://doi.org/10.1016/j.apgeochem.2015.07.005, 2015.
Herndon, E. M., Dere, A. L., Sullivan, P. L., Norris, D., Reynolds, B., and Brantley, S. L.: Landscape heterogeneity drives contrasting concentration–discharge relationships in shale headwater catchments, Hydrol. Earth Syst. Sci., 19, 3333–3347, https://doi.org/10.5194/hess-19-3333-2015, 2015.
Herndon, E. M., Steinhoefel, G., Dere, A. L. D., and Sullivan, P. L.:
Perennial flow through convergent hillslopes explains chemodynamic solute
behavior in a shale headwater catchment, Chem. Geol., 493, 413–425, https://doi.org/10.1016/j.chemgeo.2018.06.019, 2018.
Hoagland, B., Russo, T. A., Gu, X., Hill, L., Kaye, J., Forsythe, B., and
Brantley, S. L.: Hyporheic zone influences on concentration-discharge
relationships in a headwater sandstone stream, Water Resour. Res., 53,
4643–4667, https://doi.org/10.1002/2016wr019717, 2017.
Hugelius, G., Strauss, J., Zubrzycki, S., Harden, J. W., Schuur, E. A. G., Ping, C.-L., Schirrmeister, L., Grosse, G., Michaelson, G. J., Koven, C. D., O'Donnell, J. A., Elberling, B., Mishra, U., Camill, P., Yu, Z., Palmtag, J., and Kuhry, P.: Estimated stocks of circumpolar permafrost carbon with quantified uncertainty ranges and identified data gaps, Biogeosciences, 11, 6573–6593, https://doi.org/10.5194/bg-11-6573-2014, 2014.
Humbert, G., Jaffrezic, A., Fovet, O., Gruau, G., and Durand, P.: Dry-season
length and runoff control annual variability in stream DOC dynamics in a
small, shallow groundwater-dominated agricultural watershed, Water Resour.
Res., 51, 7860–7877, https://doi.org/10.1002/2015wr017336, 2015.
Iavorivska, L., Boyer, E. W., Miller, M. P., Brown, M. G., Vasilopoulos, T.,
Fuentes, J. D., and Duffy, C. J.: Atmospheric inputs of organic matter to a
forested watershed: Variations from storm to storm over the seasons,
Atmos. Environ., 147, 284–295, https://doi.org/10.1016/j.atmosenv.2016.10.002, 2016.
Jarvis, P. and Linder, S.: Botany – Constraints to growth of boreal
forests, Nature, 405, 904–905, https://doi.org/10.1038/35016154, 2000.
Jennings, E., Jarvinen, M., Allott, N., Arvola, L., Moore, K., Naden, P.,
Aonghusa, C. N., Noges, T., and Weyhenmeyer, G. A.: Impacts of Climate on
the Flux of Dissolved Organic Carbon from Catchments, in: Impact of Climate
Change on European Lakes, edited by: George, G., Aquatic Ecology Series,
Springer, Dordrecht, the Netherlands, 199–220, 2010.
Jin, L. and Brantley, S. L.: Soil chemistry and shale weathering on a
hillslope influenced by convergent hydrologic flow regime at the
Susquehanna/Shale Hills Critical Zone Observatory,
Supplement, Appl. Geochem., 26, S51–S56, https://doi.org/10.1016/j.apgeochem.2011.03.027, 2011.
Jin, L. X., Ravella, R., Ketchum, B., Bierman, P. R., Heaney, P., White, T.,
and Brantley, S. L.: Mineral weathering and elemental transport during
hillslope evolution at the Susquehanna/Shale Hills Critical Zone
Observatory, Geochim. Cosmochim. Ac., 74, 3669–3691, https://doi.org/10.1016/j.gca.2010.03.036,
2010.
Jin, L. X., Ogrinc, N., Yesavage, T., Hasenmueller, E. A., Ma, L., Sullivan,
P. L., Kaye, J., Duffy, C., and Brantley, S. L.: The CO2 consumption
potential during gray shale weathering: Insights from the evolution of
carbon isotopes in the Susquehanna Shale Hills critical zone observatory,
Geochim. Cosmochim. Ac., 142, 260–280, https://doi.org/10.1016/j.gca.2014.07.006, 2014.
Jobbagy, E. G. and Jackson, R. B.: The vertical distribution of soil
organic carbon and its relation to climate and vegetation, Ecol.
Appl., 10, 423–436, https://doi.org/10.1890/1051-0761(2000)010[0423:Tvdoso]2.0.Co;2,
2000.
Jordan, T. E., Correll, D. L., and Weller, D. E.: Relating nutrient
discharges from watersheds to land use and streamflow variability, Water
Resour. Res., 33, 2579–2590, https://doi.org/10.1029/97wr02005, 1997.
Kaiser, K. and Guggenberger, G.: Mineral surfaces and soil organic matter,
Eur. J. Soil Sci., 54, 219–236, https://doi.org/10.1046/j.1365-2389.2003.00544.x, 2003.
Kaiser, K., Kaupenjohann, M., and Zech, W.: Sorption of dissolved organic
carbon in soils: effects of soil sample storage, soil-to-solution ratio, and
temperature, Geoderma, 99, 317–328, https://doi.org/10.1016/s0016-7061(00)00077-x, 2001.
Kim, H., Gu, X., and Brantley, S. L.: Particle fluxes in groundwater change
subsurface shale rock chemistry over geologic time, Earth Planet. Sc. Lett.,
500, 180–191, https://doi.org/10.1016/j.epsl.2018.07.031, 2018.
Kolbe, T., de Dreuzy, J. R., Abbott, B. W., Aquilina, L., Babey, T., Green,
C. T., Fleckenstein, J. H., Labasque, T., Laverman, A. M., Marcais, J.,
Peiffer, S., Thomas, Z., and Pinay, G.: Stratification of reactivity
determines nitrate removal in groundwater, P. Natl.
Acad. Sci. USA, 116, 2494–2499, https://doi.org/10.1073/pnas.1816892116, 2019.
Korres, W., Reichenau, T. G., Fiener, P., Koyama, C. N., Bogena, H. R.,
Comelissen, T., Baatz, R., Herbst, M., Diekkruger, B., Vereecken, H., and
Schneider, K.: Spatio-temporal soil moisture patterns – A meta-analysis
using plot to catchment scale data, J. Hydrol., 520, 326–341, https://doi.org/10.1016/j.jhydrol.2014.11.042, 2015.
Lambert, T., Pierson-Wickmann, A. C., Gruau, G., Jaffrezic, A., Petitjean,
P., Thibault, J. N., and Jeanneau, L.: Hydrologically driven seasonal
changes in the sources and production mechanisms of dissolved organic carbon
in a small lowland catchment, Water Resour. Res., 49, 5792–5803, https://doi.org/10.1002/wrcr.20466, 2013.
Laudon, H., Buttle, J., Carey, S. K., McDonnell, J., McGuire, K., Seibert,
J., Shanley, J., Soulsby, C., and Tetzlaff, D.: Cross-regional prediction of
long-term trajectory of stream water DOC response to climate change, Geophys.
Res. Lett., 39, L18404, https://doi.org/10.1029/2012gl053033, 2012.
Lehmann, J., Kinyangi, J., and Solomon, D.: Organic matter stabilization in
soil microaggregates: implications from spatial heterogeneity of organic
carbon contents and carbon forms, Biogeochemistry, 85, 45–57, https://doi.org/10.1007/s10533-007-9105-3, 2007.
Lessels, J. S., Tetzlaff, D., Carey, S. K., Smith, P., and Soulsby, C.: A
coupled hydrology-biogeochemistry model to simulate dissolved organic carbon
exports from a permafrost-influenced catchment, Hydrol. Process., 29,
5383–5396, https://doi.org/10.1002/hyp.10566, 2015.
Li, L.: Watershed reactive transport, Rev. Mineral.
Geochem., 85, 381–418, 2019.
Li, L., Steefel, C. I., Williams, K. H., Wilkins, M. J., and Hubbard, S. S.:
Mineral Transformation and Biomass Accumulation Associated With Uranium
Bioremediation at Rifle, Colorado, Environ. Sci. Technol., 43, 5429–5435, https://doi.org/10.1021/es900016v, 2009.
Li, L., Bao, C., Sullivan, P. L., Brantley, S., Shi, Y., and Duffy, C.:
Understanding watershed hydrogeochemistry: 2. Synchronized hydrological and
geochemical processes drive stream chemostatic behavior, Water Resour. Res.,
53, 2346–2367, https://doi.org/10.1002/2016wr018935, 2017a.
Li, L., Maher, K., Navarre-Sitchler, A., Druhan, J., Meile, C., Lawrence, C., Moore, J., Perdrial, J., Sullivan, P., Thompson, A., Jin, L., Bolton, E. W., Brantley, S. L., Dietrich, W. E., Mayer, K. U., Steefel, C. I., Valocchi, A., Zachara, J., Kocar, B., McIntosh, J., Tutolo, B. M., Kumar, M., Sonnenthal, E., Bao, C., Beisman, J.: Expanding the role of reactive transport models in critical zone processes, Earth-Sci. Rev., 165, 280–301, 2017b.
Li, L., DiBiase, R. A., Del Vecchio, J., Marcon, V., Hoagland, B., Xiao, D.,
Wayman, C., Tang, Q., He, Y., Silverhart, P., Forsythe, B., Williams, J. Z.,
Shapich, D., Mount, G. J., Kaye, J., Guo, L., Lin, H., Eissenstat, D., Dere,
A., Brubaker, K., Kaye, M., Davis, K., Russo, T., and Brantley, S.:
Investigating the effect of lithology and agriculture at the Susquehanna
Shale Hills Critical Zone Observatory (SSHCZO): The Garner Run and Cole Farm
subcatchments, Vadose Zone J., 17, 180063–180077, https://doi.org/10.2136/vzj2018.03.0063, 2018.
Lim, K. J., Engel, B. A., Tang, Z. X., Choi, J., Kim, K. S., Muthukrishnan,
S., and Tripathy, D.: Automated Web Gis based hydrograph analysis tool,
what, J. Am. Water Resour. As., 41, 1407–1416, https://doi.org/10.1111/j.1752-1688.2005.tb03808.x, 2005.
Lin, H.: Temporal stability of soil moisture spatial pattern and subsurface
preferential flow pathways in the shale hills catchment, Vadose Zone J., 5,
317–340, https://doi.org/10.2136/vzj2005.0058, 2006.
Lin, H. and Zhou, X.: Evidence of subsurface preferential flow using soil
hydrologic monitoring in the Shale Hills catchment, Eur. J. Soil
Sci., 59, 34–49, https://doi.org/10.1111/j.1365-2389.2007.00988.x, 2008.
Ling, W. T., Xu, J. M., and Gao, Y. Z.: Dissolved organic matter enhances
the sorption of atrazine by soil, Biol. Fertil. Soils, 42, 418–425, https://doi.org/10.1007/s00374-006-0085-6, 2006.
Liu, Y., Wang, C. H., He, N. P., Wen, X. F., Gao, Y., Li, S. G., Niu, S. L.,
Butterbach-Bahl, K., Luo, Y. Q., and Yu, G. R.: A global synthesis of the
rate and temperature sensitivity of soil nitrogen mineralization:
latitudinal patterns and mechanisms, Glob. Change Biol., 23, 455–464, https://doi.org/10.1111/gcb.13372, 2017.
Ludwig, W., Probst, J. L., and Kempe, S.: Predicting the oceanic input of
organic carbon by continental erosion, Global Biogeochem. Cy., 10,
23–41, https://doi.org/10.1029/95gb02925, 1996.
Malone, E. T., Abbott, B. W., Klaar, M. J., Kidd, C., Sebilo, M., Milner, A.
M., and Pinay, G.: Decline in Ecosystem delta C-13 and Mid-Successional
Nitrogen Loss in a Two-Century Postglacial Chronosequence, Ecosystems, 21,
1659–1675, https://doi.org/10.1007/s10021-018-0245-1, 2018.
Mattsson, T., Kortelainen, P., and Raike, A.: Export of DOM from boreal
catchments: impacts of land use cover and climate, Biogeochemistry, 76,
373–394, https://doi.org/10.1007/s10533-005-6897-x, 2005.
Michalzik, B., Kalbitz, K., Park, J. H., Solinger, S., and Matzner, E.:
Fluxes and concentrations of dissolved organic carbon and nitrogen – a
synthesis for temperate forests, Biogeochemistry, 52, 173–205, https://doi.org/10.1023/a:1006441620810, 2001.
Moatar, F., Abbott, B. W., Minaudo, C., Curie, F., and Pinay, G.: Elemental
properties, hydrology, and biology interact to shape concentration-discharge
curves for carbon, nutrients, sediment, and major ions, Water Resour. Res.,
53, 1270–1287, https://doi.org/10.1002/2016WR019635, 2017.
Monteith, D. T., Stoddard, J. L., Evans, C. D., de Wit, H. A., Forsius, M.,
Hogasen, T., Wilander, A., Skjelkvale, B. L., Jeffries, D. S., Vuorenmaa,
J., Keller, B., Kopacek, J., and Vesely, J.: Dissolved organic carbon trends
resulting from changes in atmospheric deposition chemistry, Nature, 450,
537–539, https://doi.org/10.1038/nature06316, 2007.
Monteith, D. T., Henrys, P. A., Evans, C. D., Malcolm, I., Shilland, E. M.,
and Pereira, M. G.: Spatial controls on dissolved organic carbon in upland
waters inferred from a simple statistical model, Biogeochemistry, 123,
363–377, https://doi.org/10.1007/s10533-015-0071-x, 2015.
Moriasi, D. N., Arnold, J. G., Van Liew, M. W., Bingner, R. L., Harmel, R.
D., and Veith, T. L.: Model evaluation guidelines for systematic
quantification of accuracy in watershed simulations, T.
Asabe, 50, 885–900, 2007.
Moyano, F. E., Vasilyeva, N., Bouckaert, L., Cook, F., Craine, J., Curiel Yuste, J., Don, A., Epron, D., Formanek, P., Franzluebbers, A., Ilstedt, U., Kätterer, T., Orchard, V., Reichstein, M., Rey, A., Ruamps, L., Subke, J.-A., Thomsen, I. K., and Chenu, C.: The moisture response of soil heterotrophic respiration: interaction with soil properties, Biogeosciences, 9, 1173–1182, https://doi.org/10.5194/bg-9-1173-2012, 2012.
Musolff, A., Schmidt, C., Selle, B., and Fleckenstein, J. H.: Catchment
controls on solute export, Adv. Water Resour., 86, 133–146, https://doi.org/10.1016/j.advwatres.2015.09.026, 2015.
Musolff, A., Fleckenstein, J. H., Rao, P. S. C., and Jawitz, J. W.: Emergent
archetype patterns of coupled hydrologic and biogeochemical responses in
catchments, Geophys. Res. Lett., 44, 4143–4151, https://doi.org/10.1002/2017GL072630, 2017.
Musolff, A., Fleckenstein, J. H., Opitz, M., Büttner, O., Kumar, R., and
Tittel, J.: Spatio-temporal controls of dissolved organic carbon stream
water concentrations, J. Hydrol., 566, 205–215, https://doi.org/10.1016/j.jhydrol.2018.09.011, 2018.
Nash, J. E. and Sutcliffe, J. V.: River flow forecasting through conceptual
models part I – A discussion of principles, J. Hydrol., 10, 282–290, 1970.
Neff, J. C. and Asner, G. P.: Dissolved organic carbon in terrestrial
ecosystems: Synthesis and a model, Ecosystems, 4, 29–48, https://doi.org/10.1007/s100210000058, 2001.
Neff, J. C. and Hooper, D. U.: Vegetation and climate controls on potential
CO2, DOC and DON production in northern latitude soils, Glob. Change Biol.,
8, 872–884, https://doi.org/10.1046/j.1365-2486.2002.00517.x, 2002.
Oren, A. and Chefetz, B.: Sorptive and Desorptive Fractionation of
Dissolved Organic Matter by Mineral Soil Matrices, J. Environ.
Qual., 41, 526–533, https://doi.org/10.2134/jeq2011.0362, 2012.
Perdrial, J., McIntosh, J., Harpold, A., Brooks, P. D., Zapata-Rios, X.,
Ray, J., Meixner, T., Kanduc, T., Litvak, M., Troch, P. A., and Chorover,
J.: Stream water carbon controls in seasonally snow-covered mountain
catchments: impact of inter-annual variability of water fluxes, catchment
aspect and seasonal processes, Biogeochemistry, 118, 273–290, https://doi.org/10.1007/s10533-013-9929-y, 2014.
Perdrial, J., Brooks, P. D., Swetnam, T., Lohse, K. A., Rasmussen, C.,
Litvak, M., Harpold, A. A., Zapata-Rios, X., Broxton, P., Mitra, B.,
Meixner, T., Condon, K., Huckle, D., Stielstra, C., Vázquez-Ortega, A.,
Lybrand, R., Holleran, M., Orem, C., Pelletier, J., and Chorover, J.: A net
ecosystem carbon budget for snow dominated forested headwater catchments:
linking water and carbon fluxes to critical zone carbon storage,
Biogeochemistry, 138, 225–243, https://doi.org/10.1007/s10533-018-0440-3, 2018.
Piney, G., Bernal, S., Abbott, B. W., Lupon, A., Marti, E., Sabater, F., and
Krause, S.: Riparian corridors:
a new conceptual framework for assessing nitrogen buffering across biome, Front. Environ. Sci., 6, 47, https://doi.org/10.3389/fenvs.2018.00047, 2018.
Radke, A. G., Godsey, S. E., Lohse, K. A., McCorkle, E. P., Perdrial, J.,
Seyfried, M. S., and Holbrook, W. S.: Spatiotemporal heterogeneity of water flowpaths controls dissolved organic carbon sourcing in a snow-dominated, headwater catchment, Front. Ecol. Evol., 7, 46, https://doi.org/10.3389/fevo.2019.00046, 2019.
Rasmussen, C., Heckman, K., Wieder, W. R., Keiluweit, M., Lawrence, C. R.,
Berhe, A. A., Blankinship, J. C., Crow, S. E., Druhan, J. L., Hicks Pries,
C. E., Marin-Spiotta, E., Plante, A. F., Schädel, C., Schimel, J. P.,
Sierra, C. A., Thompson, A., and Wagai, R.: Beyond clay: towards an improved
set of variables for predicting soil organic matter content,
Biogeochemistry, 137, 297–306, https://doi.org/10.1007/s10533-018-0424-3, 2018.
Raymond, P. A., Saiers, J. E., and Sobczak, W. V.: Hydrological and
biogeochemical controls on watershed dissolved organic matter transport:
pulse-shunt concept, Ecology, 97, 5–16, https://doi.org/10.1890/14-1684.1, 2016.
Regnier, P., Friedlingstein, P., Ciais, P., Mackenzie, F. T., Gruber, N.,
Janssens, I. A., Laruelle, G. G., Lauerwald, R., Luyssaert, S., Andersson,
A. J., Arndt, S., Arnosti, C., Borges, A. V., Dale, A. W., Gallego-Sala, A.,
Godderis, Y., Goossens, N., Hartmann, J., Heinze, C., Ilyina, T., Joos, F.,
LaRowe, D. E., Leifeld, J., Meysman, F. J. R., Munhoven, G., Raymond, P. A.,
Spahni, R., Suntharalingam, P., and Thullner, M.: Anthropogenic perturbation
of the carbon fluxes from land to ocean, Nat. Geosci., 6, 597–607, https://doi.org/10.1038/ngeo1830, 2013.
Sadiq, R. and Rodriguez, M. J.: Disinfection by-products (DBPs) in drinking
water and predictive models for their occurrence: a review, Sci. Total Environ., 321, 21–46, https://doi.org/10.1016/j.scitotenv.2003.05.001, 2004.
Seibert, J., Grabs, T., Köhler, S., Laudon, H., Winterdahl, M., and Bishop, K.: Linking soil- and stream-water chemistry based on a Riparian Flow-Concentration Integration Model, Hydrol. Earth Syst. Sci., 13, 2287–2297, https://doi.org/10.5194/hess-13-2287-2009, 2009.
Shi, Y. N., Davis, K. J., Duffy, C. J., and Yu, X.: Development of a Coupled
Land Surface Hydrologic Model and Evaluation at a Critical Zone Observatory,
J. Hydrometeorol., 14, 1401–1420, https://doi.org/10.1175/jhm-d-12-0145.1, 2013.
Skjelkvale, B. L., Stoddard, J. L., Jeffries, D. S., Torseth, K., Hogasen,
T., Bowman, J., Mannio, J., Monteith, D. T., Mosello, R., Rogora, M.,
Rzychon, D., Vesely, J., Wieting, J., Wilander, A., and Worsztynowicz, A.:
Regional scale evidence for improvements in surface water chemistry
1990–2001, Environ. Pollut., 137, 165–176, https://doi.org/10.1016/j.envpol.2004.12.023,
2005.
Skopp, J., Jawson, M. D., and Doran, J. W.: Steady-State Aerobic Microbial
Activity As A Function Of Soil-Water Content, Soil Sci. Soc.
Am. J., 54, 1619–1625, https://doi.org/10.2136/sssaj1990.03615995005400060018x,
1990.
Smith, K. A., Ball, T., Conen, F., Dobbie, K. E., Massheder, J., and Rey,
A.: Exchange of greenhouse gases between soil and atmosphere: interactions
of soil physical factors and biological processes, Eur. J. Soil
Sci., 69, 10–20, https://doi.org/10.1111/ejss.12539, 2018.
Steefel, C. I., Appelo, C. A. J., Arora, B., Jacques, D., Kalbacher, T.,
Kolditz, O., Lagneau, V., Lichtner, P. C., Mayer, K. U., Meeussen, J. C. L.,
Molins, S., Moulton, D., Shao, H., Simunek, J., Spycher, N., Yabusaki, S.
B., and Yeh, G. T.: Reactive transport codes for subsurface environmental
simulation, Comput. Geosci., 19, 445–478, https://doi.org/10.1007/s10596-014-9443-x, 2015.
Stielstra, C., Brooks, P. D., Lohse, K. A., McIntosh, J. M., Chorover, J.,
Barron-Gafford, G., Perdrial, J. N., Barnard, H. R., and Litvak, M.:
Climatic and landscape influences on soil moisture are primary determinants
of soil carbon fluxes in seasonally snow-covered forest ecosystems,
Biogeochemistry, 123, 447–465, https://doi.org/10.1007/s10533-015-0078-3, 2015.
Stockmann, U., Adams, M. A., Crawford, J. W., Field, D. J., Henakaarchchi,
N., Jenkins, M., Minasny, B., McBratney, A. B., de Courcelles, V. D., Singh,
K., Wheeler, I., Abbott, L., Angers, D. A., Baldock, J., Bird, M., Brookes,
P. C., Chenu, C., Jastrow, J. D., Lal, R., Lehmann, J., O'Donnell, A. G.,
Parton, W. J., Whitehead, D., and Zimmermann, M.: The knowns, known unknowns
and unknowns of sequestration of soil organic carbon, Agr. Ecosyst.
Environ., 164, 80–99, https://doi.org/10.1016/j.agee.2012.10.001, 2013.
Sullivan, P. L., Ma, L., West, N., Jin, L., Karwan, D. L., Noireaux, J.,
Steinhoefel, G., Gaines, K. P., Eissenstat, D. M., Gaillardet, J., Derry, L.
A., Meek, K., Hynek, S., and Brantley, S. L.: CZ-tope at Susquehanna Shale
Hills CZO: Synthesizing multiple isotope proxies to elucidate Critical Zone
processes across timescales in a temperate forested landscape, Chem. Geol.,
445, 103–119, https://doi.org/10.1016/j.chemgeo.2016.05.012, 2016.
Tang, J., Yurova, A. Y., Schurgers, G., Miller, P. A., Olin, S., Smith, B.,
Siewert, M. B., Olefeldt, D., Pilesjo, P., and Poska, A.: Drivers of
dissolved organic carbon export in a subarctic catchment: Importance of
microbial decomposition, sorption-desorption, peatland and lateral flow,
Sci. Total Environ., 622, 260–274, https://doi.org/10.1016/j.scitotenv.2017.11.252, 2018.
Tank, S. E., Fellman, J. B., Hood, E., and Kritzberg, E. S.: Beyond
respiration: Controls on lateral carbon fluxes across the
terrestrial-aquatic interface, Limnol. Oceanogr. Lett., 3, 76–88, https://doi.org/10.1002/lol2.10065, 2018.
Temnerud, J., von Brömssen, C., Fölster, J., Buffam, I., Andersson, J.-O., Nyberg, L., and Bishop, K.: Map-based prediction of organic carbon in headwater streams improved by downstream observations from the river outlet, Biogeosciences, 13, 399–413, https://doi.org/10.5194/bg-13-399-2016, 2016.
Thomas, E. M., Lin, H., Duffy, C. J., Sullivan, P. L., Holmes, G. H.,
Brantley, S. L., and Jin, L. X.: Spatiotemporal patterns of water stable isotope compositions at the Shale Hills Critical Zone Observatory: Linkages to subsurface hydrologic processes, Vadose Zone J., 12, 1–16, https://doi.org/10.2136/vzj2013.01.0029, 2013.
Thomas, Z., Abbott, B. W., Troccaz, O., Baudry, J., and Pinay, G.: Proximate and ultimate controls on carbon and nutrient dynamics of small agricultural catchments, Biogeosciences, 13, 1863–1875, https://doi.org/10.5194/bg-13-1863-2016, 2016.
Underwood, K. L., Rizzo, D. M., Schroth, A. W., and Dewoolkar, M. M.:
Evaluating Spatial Variability in Sediment and Phosphorus
Concentration-Discharge Relationships Using Bayesian Inference and
Self-Organizing Maps, Water Resour. Res., 53, 10293–10316, https://doi.org/10.1002/2017wr021353, 2017.
Weigand, S., Bol, R., Reichert, B., Graf, A., Wiekenkamp, I., Stockinger,
M., Luecke, A., Tappe, W., Bogena, H., Puetz, T., Amelung, W., and
Vereecken, H.: Spatiotemporal analysis of dissolved organic carbon and nitrate in waters of a forested catchment using wavelet analysis, Vadose
Zone J., 16, 1–14, https://doi.org/10.2136/vzj2016.09.0077, 2017.
Weiler, M. and McDonnell, J. J.: Testing nutrient flushing hypotheses at
the hillslope scale: A virtual experiment approach, J. Hydrol.,
319, 339–356, https://doi.org/10.1016/j.jhydrol.2005.06.040, 2006.
Wen, H. and Li, L.: An upscaled rate law for mineral dissolution in
heterogeneous media: The role of time and length scales, Geochim. Cosmochim.
Ac., 235, 1–20, https://doi.org/10.1016/j.gca.2018.04.024, 2018.
Wen, H., Pan, Z. Z., Giammar, D., and Li, L.: Enhanced Uranium
Immobilization by Phosphate Amendment under Variable Geochemical and Flow
Conditions: Insights from Reactive Transport Modeling, Environ. Sci. Technol.,
52, 5841–5850, https://doi.org/10.1021/acs.est.7b05662, 2018.
Western, A. W., Bloschl, G., and Grayson, R. B.: Toward capturing
hydrologically significant connectivity in spatial patterns, Water Resour. Res., 37, 83–97, https://doi.org/10.1029/2000wr900241, 2001.
Wieder, W. R., Grandy, A. S., Kallenbach, C. M., and Bonan, G. B.: Integrating microbial physiology and physio-chemical principles in soils with the MIcrobial-MIneral Carbon Stabilization (MIMICS) model, Biogeosciences, 11, 3899–3917, https://doi.org/10.5194/bg-11-3899-2014, 2014.
Winterdahl, M., Erlandsson, M., Futter, M. N., Weyhenmeyer, G. A., and
Bishop, K.: Intra-annual variability of organic carbon concentrations in
running waters: Drivers along a climatic gradient, Global Biogeochem.
Cy., 28, 451–464, https://doi.org/10.1002/2013GB004770, 2014.
Winterdahl, M., Laudon, H., Lyon, S. W., Pers, C., and Bishop, K.:
Sensitivity of stream dissolved organic carbon to temperature and discharge:
Implications of future climates, J. Geophys. Res.-Biogeo., 121, 126–144, https://doi.org/10.1002/2015JG002922, 2016.
Worrall, F., Howden, N. J. K., Burt, T. P., and Bartlett, R.: Declines in
the dissolved organic carbon (DOC) concentration and flux from the UK, J.
Hydrol., 556, 775–789, https://doi.org/10.1016/j.jhydrol.2017.12.001, 2018.
Xiao, D., Shi, Y., Brantley, S., Forsythe, B., DiBiase, R., Davis, K., and
Li, L.: Streamflow generation from catchments of contrasting lithologies:
the role of soil properties, topography, and catchment size, Water Resour. Res.55, 9234–9257, https://doi.org/10.1029/2018WR023736, 2019.
Yan, Z. F., Liu, C. X., Todd-Brown, K. E., Liu, Y. Y., Bond-Lamberty, B.,
and Bailey, V. L.: Pore-scale investigation on the response of heterotrophic
respiration to moisture conditions in heterogeneous soils, Biogeochemistry,
131, 121–134, https://doi.org/10.1007/s10533-016-0270-0, 2016.
Yan, Z. F., Bond-Lamberty, B., Todd-Brown, K. E., Bailey, V. L., Li, S. L.,
Liu, C. Q., and Liu, C. X.: A moisture function of soil heterotrophic
respiration that incorporates microscale processes, Nat. Commun.,
9, 2562, https://doi.org/10.1038/s41467-018-04971-6, 2018.
Yuste, J. C., Baldocchi, D. D., Gershenson, A., Goldstein, A., Misson, L.,
and Wong, S.: Microbial soil respiration and its dependency on carbon
inputs, soil temperature and moisture, Glob. Change Biol., 13, 2018–2035, https://doi.org/10.1111/j.1365-2486.2007.01415.x, 2007.
Zarnetske, J. P., Bouda, M., Abbott, B. W., Saiers, J., and Raymond, P. A.:
Generality of Hydrologic Transport Limitation of Watershed Organic Carbon
Flux Across Ecoregions of the United States, Geophys. Res. Lett., 45,
11702–11711, https://doi.org/10.1029/2018gl080005, 2018.
Zhi, W., Li, L., Dong, W., Brown, W., Kaye, J., Steefel, C., and Williams,
K. H.: Distinct Source Water Chemistry Shapes Contrasting
Concentration-Discharge Patterns, Water Resour. Res., 55, 4233–4251, https://doi.org/10.1029/2018WR024257,
2019.
Short summary
Lateral carbon fluxes from terrestrial to aquatic systems remain central uncertainties in determining ecosystem carbon balance. This work explores how temperature and hydrology control production and export of dissolved organic carbon (DOC) at the catchment scale. Results illustrate the asynchrony of DOC production, controlled by temperature, and export, governed by flow paths; concentration–discharge relationships are determined by the relative contribution of shallow versus groundwater flow.
Lateral carbon fluxes from terrestrial to aquatic systems remain central uncertainties in...
