Articles | Volume 18, issue 11
https://doi.org/10.5194/hess-18-4687-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/hess-18-4687-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Iron oxidation kinetics and phosphate immobilization along the flow-path from groundwater into surface water
B. van der Grift
CORRESPONDING AUTHOR
Department of Innovation, Environmental and Energy Sciences – Faculty of Geosciences, Utrecht University, P.O. Box 80115, 3508 TA Utrecht, the Netherlands
Deltares, P.O. Box 85467, 3508 AL Utrecht, the Netherlands
J. C. Rozemeijer
Deltares, P.O. Box 85467, 3508 AL Utrecht, the Netherlands
J. Griffioen
Department of Innovation, Environmental and Energy Sciences – Faculty of Geosciences, Utrecht University, P.O. Box 80115, 3508 TA Utrecht, the Netherlands
Deltares, P.O. Box 85467, 3508 AL Utrecht, the Netherlands
Y. van der Velde
Soil Geography and Landscape, Wageningen University and Research Centre, Droevendaalsesteeg 4, 6708 PB Wageningen, the Netherlands
Related authors
Vince P. Kaandorp, Hans Peter Broers, Ype van der Velde, Joachim Rozemeijer, and Perry G. B. de Louw
Hydrol. Earth Syst. Sci., 25, 3691–3711, https://doi.org/10.5194/hess-25-3691-2021, https://doi.org/10.5194/hess-25-3691-2021, 2021
Short summary
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We reconstructed historical and present-day tritium, chloride, and nitrate concentrations in stream water of a catchment using
land-use-based input curves and calculated travel times of groundwater. Parameters such as the unsaturated zone thickness, mean travel time, and input patterns determine time lags between inputs and in-stream concentrations. The timescale of the breakthrough of pollutants in streams is dependent on the location of pollution in a catchment.
Liang Yu, Joachim C. Rozemeijer, Hans Peter Broers, Boris M. van Breukelen, Jack J. Middelburg, Maarten Ouboter, and Ype van der Velde
Hydrol. Earth Syst. Sci., 25, 69–87, https://doi.org/10.5194/hess-25-69-2021, https://doi.org/10.5194/hess-25-69-2021, 2021
Short summary
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The assessment of the collected water quality information is for the managers to find a way to improve the water environment to satisfy human uses and environmental needs. We found groundwater containing high concentrations of nutrient mixes with rain water in the ditches. The stable solutes are diluted during rain. The change in nutrients over time is determined by and uptaken by organisms and chemical processes. The water is more enriched with nutrients and looked
dirtierduring winter.
Liang Yu, Joachim Rozemeijer, Boris M. van Breukelen, Maarten Ouboter, Corné van der Vlugt, and Hans Peter Broers
Hydrol. Earth Syst. Sci., 22, 487–508, https://doi.org/10.5194/hess-22-487-2018, https://doi.org/10.5194/hess-22-487-2018, 2018
Short summary
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The study shows the importance of the connection between groundwater and surface water nutrient chemistry in a lowland delta area – the greater Amsterdam area. We expect that taking account of groundwater–surface water interaction is also important in other subsiding and urbanising deltas around the world, where water is managed intensively in order to enable agricultural productivity and achieve water-sustainable cities.
Frans C. van Geer, Brian Kronvang, and Hans Peter Broers
Hydrol. Earth Syst. Sci., 20, 3619–3629, https://doi.org/10.5194/hess-20-3619-2016, https://doi.org/10.5194/hess-20-3619-2016, 2016
Short summary
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The paper includes a review of the current state of high-frequency monitoring in groundwater and surface waters as an outcome of a special issue of HESS and four sessions at EGU on this topic. The focus of the paper is to look at how high-frequency monitoring can be used as a valuable support to assess the management efforts under various EU directives. We conclude that we in future will see a transition from research to implementation in operational monitoring use of high-frequency sensors.
Bas van der Grift, Hans Peter Broers, Wilbert Berendrecht, Joachim Rozemeijer, Leonard Osté, and Jasper Griffioen
Hydrol. Earth Syst. Sci., 20, 1851–1868, https://doi.org/10.5194/hess-20-1851-2016, https://doi.org/10.5194/hess-20-1851-2016, 2016
Short summary
Short summary
High-frequency water quality measurements at a pumping station where excess water is pumped out of a polder catchment have indicated that nitrate from agricultural areas is drained away relatively quickly in wet periods, but that phosphate is actually retained much more in polder systems than in free drainage areas. Phosphate emissions occur, therefore, not predominantly in winter, but due to the delayed release from the bed sediments and by feeding from the groundwater, rather in summer.
J. C. Rozemeijer, A. Visser, W. Borren, M. Winegram, Y. van der Velde, J. Klein, and H. P. Broers
Hydrol. Earth Syst. Sci., 20, 347–358, https://doi.org/10.5194/hess-20-347-2016, https://doi.org/10.5194/hess-20-347-2016, 2016
Short summary
Short summary
Controlled drainage has been recognized as an effective option to optimize soil moisture conditions for agriculture and to reduce unnecessary losses of fresh water and nutrients. For a grassland field in the Netherlands, we measured the changes in the field water and solute balance after introducing controlled drainage. We concluded that controlled drainage reduced the drain discharge and increased the groundwater storage in the field, but did not have clear positive effects for water quality.
S. R. Lutz, H. J. van Meerveld, M. J. Waterloo, H. P. Broers, and B. M. van Breukelen
Hydrol. Earth Syst. Sci., 17, 4505–4524, https://doi.org/10.5194/hess-17-4505-2013, https://doi.org/10.5194/hess-17-4505-2013, 2013
Ralf C. H. Aben, Daniël van de Craats, Jim Boonman, Stijn H. Peeters, Bart Vriend, Coline C. F. Boonman, Ype van der Velde, Gilles Erkens, and Merit van den Berg
Biogeosciences, 21, 4099–4118, https://doi.org/10.5194/bg-21-4099-2024, https://doi.org/10.5194/bg-21-4099-2024, 2024
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Drained peatlands cause high CO2 emissions. We assessed the effectiveness of subsurface water infiltration systems (WISs) in reducing CO2 emissions related to increases in water table depth (WTD) on 12 sites for up to 4 years. Results show WISs markedly reduced emissions by 2.1 t CO2-C ha-1 yr-1. The relationship between the amount of carbon above the WTD and CO2 emission was stronger than the relationship between WTD and emission. Long-term monitoring is crucial for accurate emission estimates.
Merit van den Berg, Thomas M. Gremmen, Renske J. E. Vroom, Jacobus van Huissteden, Jim Boonman, Corine J. A. van Huissteden, Ype van der Velde, Alfons J. P. Smolders, and Bas P. van de Riet
Biogeosciences, 21, 2669–2690, https://doi.org/10.5194/bg-21-2669-2024, https://doi.org/10.5194/bg-21-2669-2024, 2024
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Drained peatlands emit 3 % of the global greenhouse gas emissions. Paludiculture is a way to reduce CO2 emissions while at the same time generating an income for landowners. The side effect is the potentially high methane emissions. We found very high methane emissions for broadleaf cattail compared with narrowleaf cattail and water fern. The rewetting was, however, effective to stop CO2 emissions for all species. The highest potential to reduce greenhouse gas emissions had narrowleaf cattail.
Tanya J. R. Lippmann, Ype van der Velde, Monique M. P. D. Heijmans, Han Dolman, Dimmie M. D. Hendriks, and Ko van Huissteden
Geosci. Model Dev., 16, 6773–6804, https://doi.org/10.5194/gmd-16-6773-2023, https://doi.org/10.5194/gmd-16-6773-2023, 2023
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Vegetation is a critical component of carbon storage in peatlands but an often-overlooked concept in many peatland models. We developed a new model capable of simulating the response of vegetation to changing environments and management regimes. We evaluated the model against observed chamber data collected at two peatland sites. We found that daily air temperature, water level, harvest frequency and height, and vegetation composition drive methane and carbon dioxide emissions.
Alexa Marion Hinzman, Ylva Sjöberg, Steve W. Lyon, Wouter R. Berghuijs, and Ype van der Velde
EGUsphere, https://doi.org/10.5194/egusphere-2023-2391, https://doi.org/10.5194/egusphere-2023-2391, 2023
Preprint archived
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An Arctic catchment with permafrost responds in a linear fashion: water in=water out. As permafrost thaws, 9 of 10 nested catchments become more non-linear over time. We find upstream catchments have stronger streamflow seasonality and exhibit the most nonlinear storage-discharge relationships. Downstream catchments have the greatest increases in non-linearity over time. These long-term shifts in the storage-discharge relationship are not typically seen in current hydrological models.
Cindy Quik, Ype van der Velde, Jasper H. J. Candel, Luc Steinbuch, Roy van Beek, and Jakob Wallinga
Biogeosciences, 20, 695–718, https://doi.org/10.5194/bg-20-695-2023, https://doi.org/10.5194/bg-20-695-2023, 2023
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In NW Europe only parts of former peatlands remain. When these peatlands formed is not well known but relevant for questions on landscape, climate and archaeology. We investigated the age of Fochteloërveen, using radiocarbon dating and modelling. Results show that peat initiated at several sites 11 000–7000 years ago and expanded rapidly 5000 years ago. Our approach may ultimately be applied to model peat ages outside current remnants and provide a view of these lost landscapes.
Jim Boonman, Mariet M. Hefting, Corine J. A. van Huissteden, Merit van den Berg, Jacobus (Ko) van Huissteden, Gilles Erkens, Roel Melman, and Ype van der Velde
Biogeosciences, 19, 5707–5727, https://doi.org/10.5194/bg-19-5707-2022, https://doi.org/10.5194/bg-19-5707-2022, 2022
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Draining peat causes high CO2 emissions, and rewetting could potentially help solve this problem. In the dry year 2020 we measured that subsurface irrigation reduced CO2 emissions by 28 % and 83 % on two research sites. We modelled a peat parcel and found that the reduction depends on seepage and weather conditions and increases when using pressurized irrigation or maintaining high ditchwater levels. We found that soil temperature and moisture are suitable as indicators of peat CO2 emissions.
Tanya Juliette Rebecca Lippmann, Monique Heijmans, Han Dolman, Ype van der Velde, Dimmie Hendriks, and Ko van Huissteden
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2022-143, https://doi.org/10.5194/gmd-2022-143, 2022
Preprint withdrawn
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To assess the impact of vegetation on GHG fluxes in peatlands, we developed a new model, Peatland-VU-NUCOM (PVN). These results showed that plant communities impact GHG emissions, indicating that plant community re-establishment is a critical component of peatland restoration. This is the first time that a peatland emissions model investigated the role of re-introducing peat forming vegetation on GHG emissions.
Yousef Albuhaisi, Ype van der Velde, and Sander Houweling
Biogeosciences Discuss., https://doi.org/10.5194/bg-2022-55, https://doi.org/10.5194/bg-2022-55, 2022
Manuscript not accepted for further review
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An important uncertainty in the modelling of methane emissions from natural wetlands is the wetland area. It is important to get the spatiotemporal covariance between the variables that drive methane emissions right for accurate quantification. Using high-resolution wetland and soil carbon maps, in combination with a simplified methane emission model that is coarsened in six steps from 0.005° to 1°, we find a strong relation between wetland emissions and the model resolution.
Thomas Janssen, Ype van der Velde, Florian Hofhansl, Sebastiaan Luyssaert, Kim Naudts, Bart Driessen, Katrin Fleischer, and Han Dolman
Biogeosciences, 18, 4445–4472, https://doi.org/10.5194/bg-18-4445-2021, https://doi.org/10.5194/bg-18-4445-2021, 2021
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Satellite images show that the Amazon forest has greened up during past droughts. Measurements of tree stem growth and leaf litterfall upscaled using machine-learning algorithms show that leaf flushing at the onset of a drought results in canopy rejuvenation and green-up during drought while simultaneously trees excessively shed older leaves and tree stem growth declines. Canopy green-up during drought therefore does not necessarily point to enhanced tree growth and improved forest health.
Vince P. Kaandorp, Hans Peter Broers, Ype van der Velde, Joachim Rozemeijer, and Perry G. B. de Louw
Hydrol. Earth Syst. Sci., 25, 3691–3711, https://doi.org/10.5194/hess-25-3691-2021, https://doi.org/10.5194/hess-25-3691-2021, 2021
Short summary
Short summary
We reconstructed historical and present-day tritium, chloride, and nitrate concentrations in stream water of a catchment using
land-use-based input curves and calculated travel times of groundwater. Parameters such as the unsaturated zone thickness, mean travel time, and input patterns determine time lags between inputs and in-stream concentrations. The timescale of the breakthrough of pollutants in streams is dependent on the location of pollution in a catchment.
Liang Yu, Joachim C. Rozemeijer, Hans Peter Broers, Boris M. van Breukelen, Jack J. Middelburg, Maarten Ouboter, and Ype van der Velde
Hydrol. Earth Syst. Sci., 25, 69–87, https://doi.org/10.5194/hess-25-69-2021, https://doi.org/10.5194/hess-25-69-2021, 2021
Short summary
Short summary
The assessment of the collected water quality information is for the managers to find a way to improve the water environment to satisfy human uses and environmental needs. We found groundwater containing high concentrations of nutrient mixes with rain water in the ditches. The stable solutes are diluted during rain. The change in nutrients over time is determined by and uptaken by organisms and chemical processes. The water is more enriched with nutrients and looked
dirtierduring winter.
Rémon M. Saaltink, Maria Barciela-Rial, Thijs van Kessel, Stefan C. Dekker, Hugo J. de Boer, Claire Chassange, Jasper Griffioen, Martin J. Wassen, and Johan C. Winterwerp
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2019-194, https://doi.org/10.5194/hess-2019-194, 2019
Revised manuscript not accepted
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This paper focusses on exploring an alternative approach that uses natural processes, rather than a technological solution, to speed up drainage of soft sediment. In a controlled column experiment, we studied how Phragmites australis can act as an ecological engineer that enhances drainage. The presented results provide information needed for predictive modelling of plants as ecological engineers to speed up soil forming processes in the construction of wetlands with soft cohesive sediment.
Floris Loys Naus, Paul Schot, Koos Groen, Kazi Matin Ahmed, and Jasper Griffioen
Hydrol. Earth Syst. Sci., 23, 1431–1451, https://doi.org/10.5194/hess-23-1431-2019, https://doi.org/10.5194/hess-23-1431-2019, 2019
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In this paper, we postulate a possible evolution of the groundwater salinity around a village in southwestern Bangladesh, based on high-density fieldwork. We identified that the thickness of the surface clay layer, the surface elevation and the present-day land use determine whether fresh or saline groundwater has formed. The outcomes show how the large groundwater salinity variation in southwestern Bangladesh can be understood, which is valuable for the water management in the region.
Joachim Rozemeijer, Janneke Klein, Dimmie Hendriks, Wiebe Borren, Maarten Ouboter, and Winnie Rip
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hess-2017-636, https://doi.org/10.5194/hess-2017-636, 2018
Revised manuscript not accepted
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In lowland deltas surface water levels are often tightly controlled by inlet of diverted river water during dry periods and discharge via large-scale pumping stations during wet periods. The objective of this study was to assess the effects of changing the water level management from a fixed level to a flexible regime for 10 study catchments in The Netherlands. Water quality risks appeared and our methods could prevent such effects in the growing number of regulated catchments worldwide.
Fernando Jaramillo, Neil Cory, Berit Arheimer, Hjalmar Laudon, Ype van der Velde, Thomas B. Hasper, Claudia Teutschbein, and Johan Uddling
Hydrol. Earth Syst. Sci., 22, 567–580, https://doi.org/10.5194/hess-22-567-2018, https://doi.org/10.5194/hess-22-567-2018, 2018
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Which is the dominant effect on evapotranspiration in northern forests, an increase by recent forests expansion or a decrease by the water use response due to increasing CO2 concentrations? We determined the dominant effect during the period 1961–2012 in 65 Swedish basins. We used the Budyko framework to study the hydroclimatic movements in Budyko space. Our findings suggest that forest expansion is the dominant driver of long-term and large-scale evapotranspiration changes.
Liang Yu, Joachim Rozemeijer, Boris M. van Breukelen, Maarten Ouboter, Corné van der Vlugt, and Hans Peter Broers
Hydrol. Earth Syst. Sci., 22, 487–508, https://doi.org/10.5194/hess-22-487-2018, https://doi.org/10.5194/hess-22-487-2018, 2018
Short summary
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The study shows the importance of the connection between groundwater and surface water nutrient chemistry in a lowland delta area – the greater Amsterdam area. We expect that taking account of groundwater–surface water interaction is also important in other subsiding and urbanising deltas around the world, where water is managed intensively in order to enable agricultural productivity and achieve water-sustainable cities.
Stefanie R. Lutz, Ype van der Velde, Omniea F. Elsayed, Gwenaël Imfeld, Marie Lefrancq, Sylvain Payraudeau, and Boris M. van Breukelen
Hydrol. Earth Syst. Sci., 21, 5243–5261, https://doi.org/10.5194/hess-21-5243-2017, https://doi.org/10.5194/hess-21-5243-2017, 2017
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This study presents concentration and carbon isotope data of two herbicides from a small agricultural catchment. Herbicide concentrations at the catchment outlet were highest after intense rainfall events. The isotope data indicated herbicide degradation within 2 months after application. The system was modelled with a conceptual mathematical model using the transport formulation by travel-time distributions, which allowed testing of various assumptions of pesticide transport and degradation.
Rémon Saaltink, Stefan C. Dekker, Jasper Griffioen, and Martin J. Wassen
Biogeosciences, 13, 4945–4957, https://doi.org/10.5194/bg-13-4945-2016, https://doi.org/10.5194/bg-13-4945-2016, 2016
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We identified biogeochemical plant–soil feedback processes that occur when oxidation, drying and modification by plants alter sediment conditions. Wetland construction in Markermeer (a lake in the Netherlands) is used as a case study. Natural processes will be utilized during and after construction to accelerate ecosystem development. We conducted a 6-month greenhouse experiment to identify the key biogeochemical processes in the mud when Phragmites australis is used as an eco-engineer.
Frans C. van Geer, Brian Kronvang, and Hans Peter Broers
Hydrol. Earth Syst. Sci., 20, 3619–3629, https://doi.org/10.5194/hess-20-3619-2016, https://doi.org/10.5194/hess-20-3619-2016, 2016
Short summary
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The paper includes a review of the current state of high-frequency monitoring in groundwater and surface waters as an outcome of a special issue of HESS and four sessions at EGU on this topic. The focus of the paper is to look at how high-frequency monitoring can be used as a valuable support to assess the management efforts under various EU directives. We conclude that we in future will see a transition from research to implementation in operational monitoring use of high-frequency sensors.
Bas van der Grift, Hans Peter Broers, Wilbert Berendrecht, Joachim Rozemeijer, Leonard Osté, and Jasper Griffioen
Hydrol. Earth Syst. Sci., 20, 1851–1868, https://doi.org/10.5194/hess-20-1851-2016, https://doi.org/10.5194/hess-20-1851-2016, 2016
Short summary
Short summary
High-frequency water quality measurements at a pumping station where excess water is pumped out of a polder catchment have indicated that nitrate from agricultural areas is drained away relatively quickly in wet periods, but that phosphate is actually retained much more in polder systems than in free drainage areas. Phosphate emissions occur, therefore, not predominantly in winter, but due to the delayed release from the bed sediments and by feeding from the groundwater, rather in summer.
Patrick W. Bogaart, Ype van der Velde, Steve W. Lyon, and Stefan C. Dekker
Hydrol. Earth Syst. Sci., 20, 1413–1432, https://doi.org/10.5194/hess-20-1413-2016, https://doi.org/10.5194/hess-20-1413-2016, 2016
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We analyse how stream discharge declines after rain storms. This "recession" behaviour contains information about the capacity of the catchment to hold or release water. Looking at many rivers in Sweden, we were able to link distinct recession regimes to land use and catchment characteristics. Trends in recession behaviour are found to correspond to intensifying agriculture and extensive reforestation. We conclude that both humans and nature reorganizes the soil in order to enhance efficiency.
J. C. Rozemeijer, A. Visser, W. Borren, M. Winegram, Y. van der Velde, J. Klein, and H. P. Broers
Hydrol. Earth Syst. Sci., 20, 347–358, https://doi.org/10.5194/hess-20-347-2016, https://doi.org/10.5194/hess-20-347-2016, 2016
Short summary
Short summary
Controlled drainage has been recognized as an effective option to optimize soil moisture conditions for agriculture and to reduce unnecessary losses of fresh water and nutrients. For a grassland field in the Netherlands, we measured the changes in the field water and solute balance after introducing controlled drainage. We concluded that controlled drainage reduced the drain discharge and increased the groundwater storage in the field, but did not have clear positive effects for water quality.
B. J. Dermody, R. P. H. van Beek, E. Meeks, K. Klein Goldewijk, W. Scheidel, Y. van der Velde, M. F. P. Bierkens, M. J. Wassen, and S. C. Dekker
Hydrol. Earth Syst. Sci., 18, 5025–5040, https://doi.org/10.5194/hess-18-5025-2014, https://doi.org/10.5194/hess-18-5025-2014, 2014
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Our virtual water network of the Roman World shows that virtual water trade and irrigation provided the Romans with resilience to interannual climate variability. Virtual water trade enabled the Romans to meet food demands from regions with a surplus. Irrigation provided stable water supplies for agriculture, particularly in large river catchments. However, virtual water trade also stimulated urbanization and population growth, which eroded Roman resilience to climate variability over time.
S. R. Lutz, H. J. van Meerveld, M. J. Waterloo, H. P. Broers, and B. M. van Breukelen
Hydrol. Earth Syst. Sci., 17, 4505–4524, https://doi.org/10.5194/hess-17-4505-2013, https://doi.org/10.5194/hess-17-4505-2013, 2013
A. F. Bouwman, M. F. P. Bierkens, J. Griffioen, M. M. Hefting, J. J. Middelburg, H. Middelkoop, and C. P. Slomp
Biogeosciences, 10, 1–22, https://doi.org/10.5194/bg-10-1-2013, https://doi.org/10.5194/bg-10-1-2013, 2013
Related subject area
Subject: Biogeochemical processes | Techniques and Approaches: Theory development
Hydraulic shortcuts increase the connectivity of arable land areas to surface waters
Temperature controls production but hydrology regulates export of dissolved organic carbon at the catchment scale
Precipitation alters plastic film mulching impacts on soil respiration in an arid area of northwest China
A post-wildfire response in cave dripwater chemistry
Carbon and nitrogen dynamics and greenhouse gas emissions in constructed wetlands treating wastewater: a review
Landscape heterogeneity drives contrasting concentration–discharge relationships in shale headwater catchments
Phosphorus transport and retention in a channel draining an urban, tropical catchment with informal settlements
HESS Opinions "Biological catalysis of the hydrological cycle: life's thermodynamic function"
Urs Schönenberger and Christian Stamm
Hydrol. Earth Syst. Sci., 25, 1727–1746, https://doi.org/10.5194/hess-25-1727-2021, https://doi.org/10.5194/hess-25-1727-2021, 2021
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Pesticides are a major pollutant of surface waters. In this study, we assessed how so-called hydraulic shortcuts (e.g. inlet and maintenance shafts of road or field storm drainage systems) influence surface runoff and pesticide transport to Swiss surface waters. The study suggests that transport via hydraulic shortcuts is an important pesticide transport pathway and that current regulations may fall short in addressing this pathway.
Hang Wen, Julia Perdrial, Benjamin W. Abbott, Susana Bernal, Rémi Dupas, Sarah E. Godsey, Adrian Harpold, Donna Rizzo, Kristen Underwood, Thomas Adler, Gary Sterle, and Li Li
Hydrol. Earth Syst. Sci., 24, 945–966, https://doi.org/10.5194/hess-24-945-2020, https://doi.org/10.5194/hess-24-945-2020, 2020
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Lateral carbon fluxes from terrestrial to aquatic systems remain central uncertainties in determining ecosystem carbon balance. This work explores how temperature and hydrology control production and export of dissolved organic carbon (DOC) at the catchment scale. Results illustrate the asynchrony of DOC production, controlled by temperature, and export, governed by flow paths; concentration–discharge relationships are determined by the relative contribution of shallow versus groundwater flow.
Guanghui Ming, Hongchang Hu, Fuqiang Tian, Zhenyang Peng, Pengju Yang, and Yiqi Luo
Hydrol. Earth Syst. Sci., 22, 3075–3086, https://doi.org/10.5194/hess-22-3075-2018, https://doi.org/10.5194/hess-22-3075-2018, 2018
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The purpose of this research was to detect the effect of plastic film mulching (PFM), a widely applied cultivation method, on soil respiration. We found that soil respiration was not only affected by PFM, but it was also affected by irrigation and precipitation, and whether the PFM increases soil respiration compared to a non-mulched field largely depends on precipitation in the field. The result has an important meaning for agricultural carbon sequestration in the context of global warming.
Gurinder Nagra, Pauline C. Treble, Martin S. Andersen, Ian J. Fairchild, Katie Coleborn, and Andy Baker
Hydrol. Earth Syst. Sci., 20, 2745–2758, https://doi.org/10.5194/hess-20-2745-2016, https://doi.org/10.5194/hess-20-2745-2016, 2016
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Our current understanding of wildfires on Earth is filled with knowledge gaps. One reason for this is our poor record of fire in natural archives. We open the possibility for speleothems to be "a missing piece to the fire-puzzle". We find by effecting surface evaporation and transpiration rates, wildfires can have a multi-year impact on speleothem, forming dripwater hydrology and chemistry. We open a new avenue for speleothems as potential palaeo-fire archives.
M. M. R. Jahangir, K. G. Richards, M. G. Healy, L. Gill, C. Müller, P. Johnston, and O. Fenton
Hydrol. Earth Syst. Sci., 20, 109–123, https://doi.org/10.5194/hess-20-109-2016, https://doi.org/10.5194/hess-20-109-2016, 2016
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Removal efficiency of carbon and nitrogen in constructed wetlands is inconsistent and does not reveal whether the removal processes are from physical attenuation or transformation to other reactive forms. Previous research did not consider "pollution swapping" driven by transformational processes. Herein the biogeochemical dynamics and fate of carbon and nitrogen and their potential impact on the environment, as well as novel ways in which these knowledge gaps may be eliminated, are explored.
E. M. Herndon, A. L. Dere, P. L. Sullivan, D. Norris, B. Reynolds, and S. L. Brantley
Hydrol. Earth Syst. Sci., 19, 3333–3347, https://doi.org/10.5194/hess-19-3333-2015, https://doi.org/10.5194/hess-19-3333-2015, 2015
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Solute concentrations in headwater streams vary with discharge due to changing flow paths through the catchment during precipitation events. A comparison of stream chemistry across three headwater catchments reveals that solute heterogeneity across each landscape controls how different solutes respond to increasing discharge. Solute heterogeneity is at least partially controlled by landscape distributions of vegetation and soil organic matter.
P. M. Nyenje, L. M. G. Meijer, J. W. Foppen, R. Kulabako, and S. Uhlenbrook
Hydrol. Earth Syst. Sci., 18, 1009–1025, https://doi.org/10.5194/hess-18-1009-2014, https://doi.org/10.5194/hess-18-1009-2014, 2014
K. Michaelian
Hydrol. Earth Syst. Sci., 16, 2629–2645, https://doi.org/10.5194/hess-16-2629-2012, https://doi.org/10.5194/hess-16-2629-2012, 2012
Cited articles
Allard, T., Menguy, N., Salomon, J., Calligaro, T., Weber, T., Calas, G., and Benedetti, M. F.: Revealing forms of iron in river-borne material from major tropical rivers of the Amazon Basin (Brazil), Geochim. Cosmochim. Acta, 68, 3079–3094, https://doi.org/10.1016/j.gca.2004.01.014, 2004.
Baken, S., Sjöstedt, C., Gustafsson, J. P., Seuntjens, P., Desmet, N., De Schutter, J., and Smolders, E.: Characterisation of hydrous ferric oxides derived from iron-rich groundwaters and their contribution to the suspended sediment of streams, Appl. Geochem., 39, 59–68, https://doi.org/10.1016/j.apgeochem.2013.09.013, 2013.
Ball, J. W. and Nordstrom, D. K.: User's manual for WATEQ4F, with revised thermodynamic data base and text cases for calculating speciation of major, trace, and redox elements in natural waters, US Geological Survey Menlo Park, California, USA, 1991.
Ballantine, D. J., Walling, D. E., Collins, A. L., and Leeks, G. J. L.: The phosphorus content of fluvial suspended sediment in three lowland groundwater-dominated catchments, J. Hydrol., 357, 140–151, 2008.
Benedetti, M. F., Ranville, J. F., Allard, T., Bednar, A. J., and Menguy, N.: The iron status in colloidal matter from the Rio Negro, Brasil, Colloids Surf. A, 217, 1–9, https://doi.org/10.1016/S0927-7757(02)00553-8, 2003.
Bonte, M.: Impacts of shallow geothermal energy on groundwater quality A hydrochemical and geomicrobial study of the effects of ground source heat pumps and aquifer thermal energy storage, Ph.D., Ph.D. thesis, Vrije Universiteit Amsterdam, Amsterdam, the Netherlands, 2013.
Botter, G., Bertuzzo, E., and Rinaldo, A.: Catchment residence and travel time distributions: The master equation, Geophys. Res. Lett., 38, L11403, https://doi.org/10.1029/2011GL047666, 2011.
Carlyle, G. C. and Hill, A. R.: Groundwater phosphate dynamics in a river riparian zone: effects of hydrologic flowpaths, lithology and redox chemistry, J. Hydrol., 247, 151–168, 2001.
Chardon, W. J., Aalderink, G. H., and Van Der Salm, C.: Phosphorus leaching from cow manure patches on soil columns, J. Environ. Qual., 36, 17–22, 2007.
Châtellier, X., West, M. M., Rose, J., Fortin, D., Leppard, G. G., and Ferris, F. G.: Characterization of iron-oxides formed by oxidation of ferrous ions in the presence of various bacterial species and inorganic ligands, Geomicrobiol. J., 21, 99-112, 2004.
Dahlke, H. E., Easton, Z. M., Lyon, S. W., Todd Walter, M., Destouni, G., and Steenhuis, T. S.: Dissecting the variable source area concept –.Subsurface flow pathways and water mixing processes in a hillslope, J. Hydrol., 420–421, 125–141, 2012.
Dahm, C. N., Grimm, N. B., Marmonier, P., Valett, H. M., and Vervier, P.: Nutrient dynamics at the interface between surface waters and groundwaters, Freshwater Biol., 40, 427-451, https://doi.org/10.1046/j.1365-2427.1998.00367.x, 1998.
Deng, Y.: Formation of iron(III) hydroxides from homogeneous solutions, Water Res., 31, 1347–1354, 1997.
Deppe, T. and Benndorf, J.: Phosphorus reduction in a shallow hypereutrophic reservoir by in-lake dosage of ferrous iron, Water Res., 36, 4525–4534, https://doi.org/10.1016/S0043-1354(02)00193-8, 2002.
de Vet, W. W. J. M., Dinkla, I. J. T., Rietveld, L. C., and van Loosdrecht, M. C. M.: Biological iron oxidation by Gallionella spp. in drinking water production under fully aerated conditions, Water Res., 45, 5389–5398, 2011.
Dunne, E. J., Reddy, K. R., and Clark, M. W.: Phosphorus release and retention by soils of natural isolated wetlands, Int. J. Environ. Poll., 28, 496–516, 2006.
Dzombak, D. A. and Morel, F. M.: Surface complexation modeling: hydrous ferric oxide, Wiley, New York, 1990.
Elser, J. J., Bracken, M. E. S., Cleland, E. E., Gruner, D. S., Harpole, W. S., Hillebrand, H., Ngai, J. T., Seabloom, E. W., Shurin, J. B., and Smith, J. E.: Global analysis of nitrogen and phosphorus limitation of primary producers in freshwater, marine and terrestrial ecosystems, Ecol. Lett., 10, 1135–1142, https://doi.org/10.1111/j.1461-0248.2007.01113.x, 2007.
Fox, L. E.: A model for inorganic control of phosphate concentrations in river waters, Geochim. Cosmochim. Acta, 53, 417–428, 1989.
Frei, S., Knorr, K. H., Peiffer, S., and Fleckenstein, J. H.: Surface micro-topography causes hot spots of biogeochemical activity in wetland systems: A virtual modeling experiment, J. Geophys. Res.-Biogeo., 117, G00N12, https://doi.org/10.1029/2012JG002012, 2012.
Friedman, J. H.: A variable span scatterplot smoother, Laboratory for Computational Statistics, Stanford University, Stanford University Technical Report No. 5, Stanford, 1984.
Gerke, J.: Phosphate adsorption by humic/Fe-oxide mixtures aged at pH 4 and 7 and by poorly ordered Fe-oxide, Geoderma, 59, 279–288, 1993.
Griffioen, J.: Extent of immobilisation of phosphate during aeration of nutrient-rich, anoxic groundwater, J. Hydrol., 320, 359–369, https://doi.org/10.1016/j.jhydrol.2005.07.047, 2006.
Griffioen, J., Vermooten, S., and Janssen, G.: Geochemical and palaeohydrological controls on the composition of shallow groundwater in the Netherlands, Appl. Geochem., 39, 129–149, https://doi.org/10.1016/j.apgeochem.2013.10.005, 2013.
Gunnars, A., Blomqvist, S., Johansson, P., and Andersson, C.: Formation of Fe(III) oxyhydroxide colloids in freshwater and brackish seawater, with incorporation of phosphate and calcium, Geochim. Cosmochim. Acta, 66, 745–758, 2002.
Hayashi, M. and Yanagi, T.: Water and phosphorus budgets in the Yellow River estuary including the submarine fresh groundwater, in: From Headwaters to the Ocean: Hydrological Change and Water Management – Proceedings of the International Conference on Hydrological Changes and Management from Headwaters to the Ocean, Hydrochange 2008, 1–3 October 2009, Kyoto, Japan, 665–668, 2009.
Holman, I. P., Whelan, M. J., Howden, N. J. K., Bellamy, P. H., Willby, N. J., Rivas-Casado, M., and McConvey, P.: Phosphorus in groundwater – an overlooked contributor to eutrophication?, Hydrol. Process., 22, 5121–5127, https://doi.org/10.1002/hyp.7198, 2008.
Horowitz, A. J.: Determining annual suspended sediment and sediment-associated trace element and nutrient fluxes, Sci. Total Environ., 400, 315–343, https://doi.org/10.1016/j.scitotenv.2008.04.022, 2008.
Houot, S. and Berthelin, J.: Submicroscopic studies of iron deposits occurring in field drains: formation and evolution, Geoderma, 52, 209–222, 1992.
House, W. A. and Denison, F. H.: Nutrient dynamics in a lowland stream impacted by sewage effluent: Great Ouse, England, Sci. Total Environ., 205, 25–49, https://doi.org/10.1016/S0048-9697(97)00086-7, 1997.
Hug, S. J. and Leupin, O.: Iron-Catalyzed Oxidation of Arsenic(III) by Oxygen and by Hydrogen Peroxide:? pH-Dependent Formation of Oxidants in the Fenton Reaction, Environ. Sci. Technol., 37, 2734–2742, https://doi.org/10.1021/es026208x, 2003.
Jordan, P., Melland, A. R., Mellander, P. E., Shortle, G., and Wall, D.: The seasonality of phosphorus transfers from land to water: Implications for trophic impacts and policy evaluation, Sci. Total Environ., 434, 101–109, 2012.
Kaegi, R., Voegelin, A., Folini, D., and Hug, S. J.: Effect of phosphate, silicate, and Ca on the morphology, structure and elemental composition of Fe(III)-precipitates formed in aerated Fe(II) and As(III) containing water, Geochim. Cosmochim. Acta, 74, 5798–5816, https://doi.org/10.1016/j.gca.2010.07.017, 2010.
Kersting, K. and Kouwenhoven, P.: Annual and diel oxygen regime in two polder ditches, Hydrobiolog. Bull., 23, 111–123, https://doi.org/10.1007/BF02256728, 1989.
Krause, S., Heathwaite, L., Binley, A., and Keenan, P.: Nitrate concentration changes at the groundwater–surface water interface of a small Cumbrian river, Hydrol. Process., 23, 2195–2211, 2009.
Lienemann, C. P., Monnerat, M., Janusz, D., and Perret, D.: Identification of stoichiometric iron-phosphorus colloids produced in a eutrophic lake, Aquat. Sci., 61, 133–149, 1999.
Lofts, S., Tipping, E., and Hamilton-Taylor, J.: The Chemical Speciation of Fe(III) in Freshwaters, Aquat. Geochem., 14, 337-358, https://doi.org/10.1007/s10498-008-9040-5, 2008.
Lyvén, B., Hassellöv, M., Turner, D. R., Haraldsson, C., and Andersson, K.: Competition between iron- and carbon-based colloidal carriers for trace metals in a freshwater assessed using flow field-flow fractionation coupled to ICPMS, Geochim. Cosmochim. Acta, 67, 3791–3802, https://doi.org/10.1016/S0016-7037(03)00087-5, 2003.
Maassen, S. and Balla, D.: Impact of hydrodynamics (ex- and infiltration) on the microbially controlled phosphorus mobility in running water sediments of a cultivated northeast German wetland, Ecol. Eng., 36, 1146–1155, https://doi.org/10.1016/j.ecoleng.2010.01.009, 2010.
Macrae, M. L., Zhang, Z., Stone, M., Price, J. S., Bourbonniere, R. A., and Leach, M.: Subsurface mobilization of phosphorus in an agricultural riparian zone in response to flooding from an upstream reservoir, Can. Water Resour. J., 36, 293–311, https://doi.org/10.4296/cwrj3604810, 2011.
Mayer, T. D. and Jarrell, W. M.: Phosphorus sorption during iron(II) oxidation in the presence of dissolved silica, Water Res., 34, 3949–3956, https://doi.org/10.1016/S0043-1354(00)00158-5, 2000.
Meng, X., Korfiatis, G. P., Bang, S., and Bang, K. W.: Combined effects of anions on arsenic removal by iron hydroxides, Toxicol. Lett., 133, 103–111, https://doi.org/10.1016/S0378-4274(02)00080-2, 2002.
Neal, C., Jarvie, H. P., Williams, R. J., Neal, M., Wickham, H., and Hill, L.: Phosphorus – calcium carbonate saturation relationships in a lowland chalk river impacted by sewage inputs and phosphorus remediation: an assessment of phosphorus self-cleaning mechanisms in natural waters, Sci. Total Environ., 282–283, 295–310, https://doi.org/10.1016/S0048-9697(01)00920-2, 2002.
Neal, C., Lofts, S., Evans, C. D., Reynolds, B., Tipping, E., and Neal, M.: Increasing Iron Concentrations in UK Upland Waters, Aquat. Geochem., 14, 263–288, https://doi.org/10.1007/s10498-008-9036-1, 2008.
Parkhurst, D. L. and Appelo, C.: User's guide to PHREEQC (Version 2): A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations, US Geological Survey, Denver, Colorado, USA, 1999.
Pedersen, H. D., Postma, D., Jakobsen, R., and Larsen, O.: Fast transformation of iron oxyhydroxides by the catalytic action of aqueous Fe(II), Geochim. Cosmochim. Acta, 69, 3967–3977, https://doi.org/10.1016/j.gca.2005.03.016, 2005.
Perry, R. H., Green, D. W., and Maloney, J. O.: Perry's Chemical Engineers' Handbook, McGraw-Hill Education, New York, 1997.
Reddy, K. R., Kadlec, R. H., Flaig, E., and Gale, P. M.: Phosphorus Retention in Streams and Wetlands: A Review, Crit. Rev. Environ. Sci. Technol., 29, 83–146, 1999.
Roberts, L. C., Hug, S. J., Ruettimann, T., Billah, M., Khan, A. W., and Rahman, M. T.: Arsenic Removal with Iron(II) and Iron(III) in Waters with High Silicate and Phosphate Concentrations, Environ. Sci. Technol., 38, 307–315, 2004.
Rozemeijer, J., Van Der Velde, Y., De Jonge, H., Van Geer, F., Broers, H. P., and Bierkens, M.: Application and evaluation of a new passive sampler for measuring average solute concentrations in a catchment scale water quality monitoring study, Environ. Sci. Technol., 44, 1353–1359, 2010a.
Rozemeijer, J. C., Van Der Velde, Y., Van Geer, F. C., De Rooij, G. H., Torfs, P. J. J. F., and Broers, H. P.: Improving load estimates for NO3 and P in surface waters by characterizing the concentration response to rainfall events, Environ. Sci. Technol., 44, 6305–6312, 2010b.
Rozemeijer, J. C., Van Der Velde, Y., McLaren, R. G., Van Geer, F. C., Broers, H. P., and Bierkens, M. F. P.: Integrated modeling of groundwater-surface water interactions in a tile-drained agricultural field: The importance of directly measured flow route contributions, Water Resour. Res., 46, W11537, https://doi.org/10.1029/2010WR009155, 2010c.
Salminen, R.: FOREGS Geochemical Atlas of Europe, Part 1 – Background information, methodology and maps, Geological Survey of Finland, Espoo, Finland, 2005.
Scanlon, T. M., Kiely, G., and Amboldi, R.: Model determination of non-point source phosphorus transport pathways in a fertilized grassland catchment, Hydrol. Process., 19, 2801–2814, 2005.
Schaefer, M. V., Gorski, C. A., and Scherer, M. M.: Spectroscopic Evidence for Interfacial Fe(II)-Fe(III) Electron Transfer in a Clay Mineral, Environ. Sci. Technol., 45, 540–545, https://doi.org/10.1021/es102560m, 2010.
Sharpley, A. N., Kleinman, P. J. A., Heathwaite, A. L., Gburek, W. J., Folmar, G. J., and Schmidt, J. P.: Phosphorus loss from an agricultural watershed as a function of storm size, J. Environ. Qual., 37, 362–368, 2008.
Shenker, M., Seitelbach, S., Brand, S., Haim, A., and Litaor, M. I.: Redox reactions and phosphorus release in re-flooded soils of an altered wetland, Eur. J. Soil Sci., 56, 515–525, 2005.
Spiteri, C., Regnier, P., Slomp, C. P., and Charette, M. A.: pH-Dependent iron oxide precipitation in a subterranean estuary, J. Geochem. Explor., 88, 399–403, https://doi.org/10.1016/j.gexplo.2005.08.084, 2006.
Stumm, W. and Lee, G. F.: Oxygenation of Ferrous Iron, Indust. Eng. Chem., 53, 143–146, https://doi.org/10.1021/ie50614a030, 1961.
Sung, W. and Morgan, J. J.: Kinetics and product of ferrous iron oxygenation in aqueous systems, Environ. Sci. Technol., 14, 561–568, https://doi.org/10.1021/es60165a006, 1980.
Van Beek, C. G. E. M., Breedveld, R. J. M., Juhász-Holterman, M., Oosterhof, A., and Stuyfzand, P. J.: Cause and prevention of well bore clogging by particles, Hydrogeol. J., 17, 1877–1886, 2009.
Van den Eertwegh, G. A. P. H.: Water and Nutrient budgets at field and regional scale, travel times of drainage water and nutrient loads to surface water, Ph.D. thesis, Wageningen University, Wageningen, 2002.
Van der Velde, Y., Rozemeijer, J. C., de Rooij, G. H., van Geer, F. C., and Broers, H. P.: Field-Scale Measurements for Separation of Catchment Discharge into Flow Route Contributions, Vadose Zone J., 9, 25–35, https://doi.org/10.2136/vzj2008.0141, 2010.
Van Geen, A., Robertson, A. P., and Leckie, J. O.: Complexation of carbonate species at the goethite surface: implications for adsorption of metal ions in natural waters, Geochim. Cosmochim. Acta, 58, 2073–2086, 1994.
Vanlierde, E., De Schutter, J., Jacobs, P., and Mostaert, F.: Estimating and modeling the annual contribution of authigenic sediment to the total suspended sediment load in the Kleine Nete Basin, Belgium, Sediment. Geol., 202, 317-332, https://doi.org/10.1016/j.sedgeo.2007.05.003, 2007.
Verdonschot, R. M. and Verdonschot, P. M.: Shading effects of free-floating plants on drainage-ditch invertebrates, Limnology, 15, 225–235, https://doi.org/10.1007/s10201-013-0416-x, 2014.
Voegelin, A., Senn, A. C., Kaegi, R., Hug, S. J., and Mangold, S.: Dynamic Fe-precipitate formation induced by Fe(II) oxidation in aerated phosphate-containing water, Geochim. Cosmochim. Acta, 117, 216–231, 2013.
Vollrath, S., Behrends, T., and van Cappellen, P.: Oxygen Dependency of Neutrophilic Fe(II) Oxidation by Leptothrix Differs from Abiotic Reaction, Geomicrobiol. J., 29, 550–560, 2012.
von Gunten, U. and Schneider, W.: Primary products of the oxygenation of iron(II) at an oxic–anoxic boundary: Nucleation, aggregation, and aging, J. Coll. Interf. Sci., 145, 127–139, https://doi.org/10.1016/0021-9797(91)90106-I, 1991.
Walling, D. E., Collins, A. L., and Stroud, R. W.: Tracing suspended sediment and particulate phosphorus sources in catchments, J. Hydrol., 350, 274–289, 2008.
Wassen, M. J., Venterink, H. O., Lapshina, E. D., and Tanneberger, F.: Endangered plants persist under phosphorus limitation, Nature, 437, 547–550, 2005.
Withers, P. J. A. and Haygarth, P. M.: Agriculture, phosphorus and eutrophication: a European perspective, Soil Use Manage., 23, 1–4, https://doi.org/10.1111/j.1475-2743.2007.00116.x, 2007.
Wolthoorn, A., Temminghoff, E. J. M., Weng, L., and van Riemsdijk, W. H.: Colloid formation in groundwater: effect of phosphate, manganese, silicate and dissolved organic matter on the dynamic heterogeneous oxidation of ferrous iron, Appl. Geochem., 19, 611–622, https://doi.org/10.1016/j.apgeochem.2003.08.003, 2004.
Short summary
Exfiltration of anoxic groundwater containing Fe(II) to surface water is an important mechanism controlling P speciation in the lowland catchments. Due to changes in pH and temperature, the Fe(II) oxidation rates were much lower in winter than in summer. This study also shows a fast transformation of dissolved P to structural P during the initial stage of the Fe oxidation process resulting in low dissolved P concentrations in the surface water throughout the year.
Exfiltration of anoxic groundwater containing Fe(II) to surface water is an important mechanism...