Articles | Volume 18, issue 11
https://doi.org/10.5194/hess-18-4687-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/hess-18-4687-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Iron oxidation kinetics and phosphate immobilization along the flow-path from groundwater into surface water
B. van der Grift
CORRESPONDING AUTHOR
Department of Innovation, Environmental and Energy Sciences – Faculty of Geosciences, Utrecht University, P.O. Box 80115, 3508 TA Utrecht, the Netherlands
Deltares, P.O. Box 85467, 3508 AL Utrecht, the Netherlands
J. C. Rozemeijer
Deltares, P.O. Box 85467, 3508 AL Utrecht, the Netherlands
J. Griffioen
Department of Innovation, Environmental and Energy Sciences – Faculty of Geosciences, Utrecht University, P.O. Box 80115, 3508 TA Utrecht, the Netherlands
Deltares, P.O. Box 85467, 3508 AL Utrecht, the Netherlands
Y. van der Velde
Soil Geography and Landscape, Wageningen University and Research Centre, Droevendaalsesteeg 4, 6708 PB Wageningen, the Netherlands
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- Respective roles of Fe-oxyhydroxide dissolution, pH changes and sediment inputs in dissolved phosphorus release from wetland soils under anoxic conditions S. Gu et al. 10.1016/j.geoderma.2018.12.034
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- Groundwater control of biogeochemical processes causing phosphorus release from riparian wetlands R. Dupas et al. 10.1016/j.watres.2015.07.048
- Fe hydroxyphosphate precipitation and Fe(II) oxidation kinetics upon aeration of Fe(II) and phosphate-containing synthetic and natural solutions B. van der Grift et al. 10.1016/j.gca.2016.04.035
- Subarctic wintertime dissolved iron speciation driven by thermal constraints on Fe(II) oxidation, dissolved organic matter and stream reach Y. Morita et al. 10.1016/j.gca.2017.07.009
- Processes controlling the flux of legacy phosphorus to surface waters at the farm scale V. Barcala et al. 10.1088/1748-9326/abcdd4
- High-frequency monitoring of water fluxes and nutrient loads to assess the effects of controlled drainage on water storage and nutrient transport J. Rozemeijer et al. 10.5194/hess-20-347-2016
- Phosphorus Sources and Transport Pathways in the North Chaohu Lake Catchment of China L. Wang et al. 10.3390/w16020244
- Redox potential as an important characteristic of the chemical and biological state of surface waters (review) P. Linnik et al. 10.1080/02757540.2023.2225496
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Short summary
Exfiltration of anoxic groundwater containing Fe(II) to surface water is an important mechanism controlling P speciation in the lowland catchments. Due to changes in pH and temperature, the Fe(II) oxidation rates were much lower in winter than in summer. This study also shows a fast transformation of dissolved P to structural P during the initial stage of the Fe oxidation process resulting in low dissolved P concentrations in the surface water throughout the year.
Exfiltration of anoxic groundwater containing Fe(II) to surface water is an important mechanism...