Articles | Volume 29, issue 22
https://doi.org/10.5194/hess-29-6577-2025
https://doi.org/10.5194/hess-29-6577-2025
Research article
 | 
21 Nov 2025
Research article |  | 21 Nov 2025

Transport behavior displayed by water isotopes and potential implications for assessment of catchment properties

Dan Elhanati, Erwin Zehe, Ishai Dror, and Brian Berkowitz

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This preprint is open for discussion and under review for Hydrology and Earth System Sciences (HESS).
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Cited articles

Aquilina, L., Ladouche, B., and Dörfliger, N.: Water storage and transfer in the epikarst of karstic systems during high flow periods, Journal of Hydrology, 327, 472–485, https://doi.org/10.1016/j.jhydrol.2005.11.054, 2006. 
Benettin, P., Rodriguez, N. B., Sprenger, M., Kim, M., Klaus, J., Harman, C. J., van der Velde, Y., Hrachowitz, M., Botter, G., McGuire, K. J., Kirchner, J. W., Rinaldo, A., and McDonnell, J. J.: Transit Time Estimation in Catchments: Recent Developments and Future Directions, Water Resources Research, 58, 1–36, https://doi.org/10.1029/2022WR033096, 2022. 
Berkowitz, B., Cortis, A., Dentz, M., and Scher, H.: Modeling non-Fickian transport in geological formations as a continuous time random walk, Reviews of Geophysics, 44, 1–49, https://doi.org/10.1029/2005RG000178, 2006a. 
Berkowitz, B., Cortis, A., Dentz, M., and Scher, H.: Modeling non-Fickian transport in geological formations as a continuous time random walk, Reviews of Geophysics, 44, 1–49, https://doi.org/10.1029/2005RG000178, 2006b. 
Berkowitz, B., Dror, I., Hansen, S. K., and Scher, H.: Measurements and models of reactive transport in geological media, Reviews of Geophysics, 54, 930–986, https://doi.org/10.1002/2016RG000524, 2016. 
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Short summary
Measurements of water isotopes are often used to estimate water transit time distributions and aquifer storage thickness in catchments. However, laboratory-scale measurements show that water isotopes exhibit transport behavior identical to that of inert chemical tracers rather than of pure water. The measured mean tracer and apparent mean water velocities are not necessarily equal; recognition of this inequality is critical when estimating catchment properties such as aquifer storage thickness.
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