Articles | Volume 29, issue 21
https://doi.org/10.5194/hess-29-6137-2025
© Author(s) 2025. This work is distributed under the Creative Commons Attribution 4.0 License.
Equilibrium-approximated solutions to the reactive Lauwerier problem: thermal fronts as controls on reactive fronts in Earth systems
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- Final revised paper (published on 11 Nov 2025)
- Supplement to the final revised paper
- Preprint (discussion started on 14 Mar 2025)
- Supplement to the preprint
Interactive discussion
Status: closed
Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor
| : Report abuse
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RC1: 'Comment on egusphere-2025-733', Atefeh Vafaie, 12 May 2025
- AC1: 'Reply on RC1', Roi Roded, 18 Jun 2025
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RC2: 'Comment on egusphere-2025-733', Thomas Driesner, 14 May 2025
- AC2: 'Reply on RC2', Roi Roded, 18 Jun 2025
Peer review completion
AR: Author's response | RR: Referee report | ED: Editor decision | EF: Editorial file upload
ED: Publish subject to revisions (further review by editor and referees) (23 Jun 2025) by Heng Dai
AR by Roi Roded on behalf of the Authors (15 Jul 2025)
Author's response
Author's tracked changes
Manuscript
ED: Referee Nomination & Report Request started (16 Jul 2025) by Heng Dai
RR by Anonymous Referee #3 (04 Aug 2025)
RR by Anonymous Referee #4 (05 Aug 2025)
ED: Publish as is (06 Aug 2025) by Heng Dai
AR by Roi Roded on behalf of the Authors (30 Aug 2025)
Manuscript
This is a well-written manuscript that presents simplified, equilibrium-based solutions to the Reactive Lauwerier Problem, which models how thermal changes drive mineral reactions in subsurface aquifers. By assuming reactions are fast compared to fluid transport (i.e., a high Damköhler number), the author derives clear analytical solutions for how porosity and reaction rates evolve. These are shown to agree well with more detailed kinetic models, except very close to the injection point. The paper offers a useful criterion for when the equilibrium assumption is valid and applies the findings to real-world processes like CO₂ injection, silica precipitation, and ore formation. The work builds on previous studies and contributes useful insights. I recommend publication after minor clarifications, particularly around what’s new compared to the earlier work (Roded et al., 2024b) and how to interpret the model’s limitations near injection wells.