We developed and validated a theoretical model for water vapor diffusion through sampling bags. This model accurately reconstructs the initial isotopic composition of the vapor samples. When applied to upper troposphere samples, the corrected data aligned closely with IASI satellite observations, enhancing the accuracy of drone-based measurements.

To better understand the spatial and temporal distribution of vapor isotopes, we present two vehicle-based spatially continuous snapshots of the near-surface vapor isotopes in China during the pre-monsoon and monsoon periods. These observations are explained well by different moisture sources and processes along the air mass trajectories. Our results suggest that proxy records need to be interpreted in the context of regional systems and sources of moisture.

Plant wax lipid ratios and their isotopes are used in vegetation and paleoclimate reconstructions. While studies often use either type of data, both can inform the mixing pattern of source plants. We developed a statistic model that evaluates ratios and isotopes together. Through case studies, we showed that the approach allows more detailed interpretations of vegetation and paleoclimate than traditional methods. This evolving framework can include more geochemical tracers in the future.