Articles | Volume 29, issue 12
https://doi.org/10.5194/hess-29-2615-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/hess-29-2615-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Technical note: High-frequency, multi-elemental stream water monitoring – experiences, feedbacks and suggestions from 7 years of running three French field laboratories (Riverlabs)
Nicolai Brekenfeld
CORRESPONDING AUTHOR
INRAE, Institut Agro, UMR SAS, Rennes, 35042, France
Solenn Cotel
ITES Institut Terre et Environnement de Strasbourg, CNRS/Université de Strasbourg, Strasbourg, 67000, France
Mikael Faucheux
INRAE, Institut Agro, UMR SAS, Rennes, 35042, France
Colin Fourtet
ITES Institut Terre et Environnement de Strasbourg, CNRS/Université de Strasbourg, Strasbourg, 67000, France
Yannick Hamon
INRAE, Institut Agro, UMR SAS, Rennes, 35042, France
Patrice Petitjean
Géosciences Rennes UMR CNRS6118, University Rennes, Rennes, 35042, France
Arnaud Blanchouin
University of Paris-Saclay, INRAE Jouy-en-Josas – Antony, UR HYCAR, Antony, 92761, France
Celine Bouillis
INRAE, Institut Agro, UMR SAS, Rennes, 35042, France
Marie-Claire Pierret
ITES Institut Terre et Environnement de Strasbourg, CNRS/Université de Strasbourg, Strasbourg, 67000, France
Hocine Henine
University of Paris-Saclay, INRAE Jouy-en-Josas – Antony, UR HYCAR, Antony, 92761, France
Anne-Catherine Pierson-Wickmann
Géosciences Rennes UMR CNRS6118, University Rennes, Rennes, 35042, France
Sophie Guillon
Centre de Géosciences, MINES Paris, PSL University, Fontainebleau, 77300, France
Paul Floury
Extralab SAS, Paris, France
INRAE, Institut Agro, UMR SAS, Rennes, 35042, France
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Cited articles
Bieroza, M., Acharya, S., Benisch, J., ter Borg, R. N., Hallberg, L., Negri, C., Pruitt, A., Pucher, M., Saavedra, F., Staniszewska, K., van't Veen, S. G. M., Vincent, A., Winter, C., Basu, N. B., Jarvie, H. P., and Kirchner, J. W.: Advances in Catchment Science, Hydrochemistry, and Aquatic Ecology Enabled by High-Frequency Water Quality Measurements, Environ. Sci. Technol., 57, 4701–4719, https://doi.org/10.1021/acs.est.2c07798, 2023.
Brekenfeld, N., Cotel, S., Faucheux, M., Floury, P., Fourtet, C., Gaillardet, J., Guillon, S., Hamon, Y., Henine, H., Petitjean, P., Pierson-Wickmann, A. C., Pierret, M. C., and Fovet, O.: Using high-frequency solute synchronies to determine simple two-end-member mixing in catchments during storm events, Hydrol. Earth Syst. Sc., 28, 4309–4329, 2024.
Chappell, N. A., Jones, T. D., and Tych, W.: Sampling frequency for water quality variables in streams: Systems analysis to quantify minimum monitoring rates, Water Res., 123, 49–57, 2017.
Cotel, S., Viville, D., Benarioumlil, S., Ackerer, P., and Pierret, M. C.: Impact of the hydrological regime and forestry operations on the fluxes of suspended sediment and bedload of a small middle-mountain catchment, Sci. Total Environ., 743, 140228, https://doi.org/10.1016/j.scitotenv.2020.140228 2020.
El Gh'Mari, A.: Etude minéralogique, pétrophysique et géochimique de dynamique d'altération d'un granite soumis aux dépôts atmosphériques acides (bassin versant du Strengbach, Vosges, France). Mécanismes, bilans et modélisation, 1995, 1 volume, Universite Louis Pasteur, Strasbourg, 199 pp., https://hal.science/tel-04452531v1 (last access: 17 June 2025), 1995.
Floury, P., Gaillardet, J., Gayer, E., Bouchez, J., Tallec, G., Ansart, P., Koch, F., Gorge, C., Blanchouin, A., and Roubaty, J. L.: The potamochemical symphony: new progress in the high-frequency acquisition of stream chemical data, Hydrol. Earth Syst. Sc., 21, 6153–6165, 2017.
Floury, P., Bouchez, J., Druhan, J. L., Gaillardet, J., Blanchouin, A., Gayer, É., and Ansart, P.: Linking Dynamic Water Storage and Subsurface Geochemical Structure Using High-Frequency Concentration-Discharge Records, Water Resour. Res., 60, e2022WR033999, https://doi.org/10.1029/2022WR03399, 2024.
Fovet, O., Ruiz, L., Gruau, G., Akkal, N., Aquilina, L., Busnot, S., Dupas, R., Durand, P., Faucheux, M., Fauvel, Y., Fléchard, C., Gilliet, N., Grimaldi, C., Hamon, Y., Jaffrezic, A., Jeanneau, L., Labasque, T., Le Henaff, G., Mérot, P., Molénat, J., Petitjean, P., Pierson-Wickmann, A.-C., Squividant, H., Viaud, V., Walter, C., and Gascuel-Odoux, C.: AgrHyS: An Observatory of Response Times in Agro-Hydro Systems, Vadose Zone J., 17, 180066, https://doi.org/10.2136/vzj2018.04.0066, 2018.
Horowitz, A. J., Elrick, K. A., and Colberg, M. R.: The effect of membrane filtration artifacts on dissolved trace element concentrations, Water Res., 26, 753–763, 1992.
Jordan, P. and Cassidy, R.: Technical Note: Assessing a 24/7 solution for monitoring water quality loads in small river catchments, Hydrol. Earth Syst. Sc., 15, 3093–3100, 2011.
Jordan, P. and Cassidy, R.: Perspectives on Water Quality Monitoring Approaches for Behavioral Change Research, Frontiers in Water, 4, https://doi.org/10.3389/frwa.2022.917595, 2022.
Kirchner, J. W., Feng, X., Neal, C., and Robson, A. J.: The fine structure of water-quality dynamics: the (high-frequency) wave of the future, Hydrol. Process., 18, 1353–1359, 2004.
Kirchner, J. W., Benettin, P., and van Meerveld, I.: Instructive Surprises in the Hydrological Functioning of Landscapes, Annu. Rev. Earth Pl. Sc., 51, 277–299, 2023.
Lefrançois, J., Grimaldi, C., Gascuel-Odoux, C., and Gilliet, N.: Suspended sediment and discharge relationships to identify bank degradation as a main sediment source on small agricultural catchments, Hydrol. Process., 21, 2923–2933, 2007.
Pierret, M.-C., Cotel, S., Ackerer, P., Beaulieu, E., Benarioumlil, S., Boucher, M., Boutin, R., Chabaux, F., Delay, F., Fourtet, C., Friedmann, P., Fritz, B., Gangloff, S., Girard, J.-F., Legtchenko, A., Viville, D., Weill, S., and Probst, A.: The Strengbach Catchment: A Multidisciplinary Environmental Sentry for 30 Years, Vadose Zone J., 17, 180090, https://doi.org/10.2136/vzj2018.04.0090, 2018.
Pierret, M.-C., Viville, D., Dambrine, E., Cotel, S., and Probst, A.: Twenty-five year record of chemicals in open field precipitation and throughfall from a medium-altitude forest catchment (Strengbach – NE France): An obvious response to atmospheric pollution trends, Atmos. Environ., 202, 296–314, 2019.
Rode, M., Wade, A. J., Cohen, M. J., Hensley, R. T., Bowes, M. J., Kirchner, J. W., Arhonditsis, G. B., Jordan, P., Kronvang, B., Halliday, S. J., Skeffington, R. A., Rozemeijer, J. C., Aubert, A. H., Rinke, K., and Jomaa, S.: Sensors in the Stream: The High-Frequency Wave of the Present, Environ. Sci. Technol., 50, 10297–10307, 2016.
Skeffington, R. A., Halliday, S. J., Wade, A. J., Bowes, M. J., and Loewenthal, M.: Using high-frequency water quality data to assess sampling strategies for the EU Water Framework Directive, Hydrol. Earth Syst. Sc., 19, 2491–2504, 2015.
Tallec, G., Ansart, P., Guerin, A., Guerlet, N., Pourette, N., Guenne, A., Delaigue, O., Boudhraa, H., and Loumagne, C.: Introduction L'Orgeval, un observaoire long terme pour l'environnement: caractéristiques du bassin et variables mesurées. In: L'observation long terme en environnement, exemple du bassin versant de l'Orgeval, edited by: Loumagne, C. and Tallec, G., QUAE, Versaille, eBook ISBN 9782759220748, 2013.
Tunqui Neira, J. M., Andréassian, V., Tallec, G., and Mouchel, J. M.: Technical note: A two-sided affine power scaling relationship to represent the concentration–discharge relationship, Hydrol. Earth Syst. Sc., 24, 1823–1830, 2020a.
Tunqui Neira, J. M., Tallec, G., Andréassian, V., and Mouchel, J.-M.: A combined mixing model for high-frequency concentration–discharge relationships, J. Hydrol., 591, 125559, https://doi.org/10.1016/j.jhydrol.2020.125559, 2020b.
Tunqui Neira, J. M., Andréassian, V., Tallec, G., and Mouchel, J.-M.: Multi-objective fitting of concentration-discharge relationships, Hydrol. Process., 35, e14428, https://doi.org/10.1002/hyp.14428, 2021.
van Geer, F. C., Kronvang, B., and Broers, H. P.: High-resolution monitoring of nutrients in groundwater and surface waters: process understanding, quantification of loads and concentrations, and management applications, Hydrol. Earth Syst. Sc., 20, 3619–3629, 2016.
von Freyberg, J., Studer, B., and Kirchner, J. W.: A lab in the field: high-frequency analysis of water quality and stable isotopes in stream water and precipitation, Hydrol. Earth Syst. Sc., 21, 1721–1739, 2017.
Vongvixay, A., Grimaldi, C., Dupas, R., Fovet, O., Birgand, F., Gilliet, N., and Gascuel-Odoux, C.: Contrasting suspended sediment export in two small agricultural catchments: Cross-influence of hydrological behaviour and landscape degradation or stream bank management, Land Degrad. Dev., 29, 1385–1396, 2018.
Wade, A. J., Palmer-Felgate, E. J., Halliday, S. J., Skeffington, R. A., Loewenthal, M., Jarvie, H. P., Bowes, M. J., Greenway, G. M., Haswell, S. J., Bell, I. M., Joly, E., Fallatah, A., Neal, C., Williams, R. J., Gozzard, E., and Newman, J. R.: Hydrochemical processes in lowland rivers: insights from in situ, high-resolution monitoring, Hydrol. Earth Syst. Sc., 16, 4323–4342, 2012.
Wang, J., Bouchez, J., Dolant, A., Floury, P., Stumpf, A. J., Bauer, E., Keefer, L., Gaillardet, J., Kumar, P., and Druhan, J. L.: Sampling frequency, load estimation and the disproportionate effect of storms on solute mass flux in rivers, Sci. Total Environ., 906, 167379, https://doi.org/10.1016/j.scitotenv.2023.167379, 2024.
Short summary
In the last decade, the development of on-site field laboratories to measure water chemistry at sub-hourly measurement intervals has drastically advanced, while there is no literature that provides detailed technical, organisational and operational guidelines in running such equipment. Based on our experiences of running three French field laboratories over 7 years, we share the main stages in the deployment of this tool in the field, the difficulties encountered and the proposed solutions.
In the last decade, the development of on-site field laboratories to measure water chemistry at...