Deforestation affects how catchments store and release water. Here we found that deforestation in the study catchment led to a 20 % increase in mean runoff, while reducing the vegetation-accessible water storage from about 258 to 101 mm. As a consequence, fractions of young water in the stream increased by up to 25 % during wet periods. This implies that water and solutes are more rapidly routed to the stream, which can, after contamination, lead to increased contaminant peak concentrations.