Articles | Volume 21, issue 10
https://doi.org/10.5194/hess-21-5243-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/hess-21-5243-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
18 Oct 2017
Research article |
| 18 Oct 2017
Pesticide fate on catchment scale: conceptual modelling of stream CSIA data
UFZ Helmholtz Centre for Environmental Research, Department Catchment Hydrology, Theodor-Lieser-Str. 4, 06120 Halle (Saale), Germany
Ype van der Velde
Department of Earth Sciences, Faculty of Earth and Life Sciences, VU University Amsterdam, De Boelelaan 1085, 1081 HV Amsterdam, the Netherlands
Omniea F. Elsayed
Laboratoire d'hydrologie et de Géochimie de Strasbourg (LHyGeS), Université de Strasbourg/ENGEES, 1 rue Blessig, 67084 Strasbourg cedex, France
Gwenaël Imfeld
Laboratoire d'hydrologie et de Géochimie de Strasbourg (LHyGeS), Université de Strasbourg/ENGEES, 1 rue Blessig, 67084 Strasbourg cedex, France
Marie Lefrancq
Laboratoire d'hydrologie et de Géochimie de Strasbourg (LHyGeS), Université de Strasbourg/ENGEES, 1 rue Blessig, 67084 Strasbourg cedex, France
Sylvain Payraudeau
Laboratoire d'hydrologie et de Géochimie de Strasbourg (LHyGeS), Université de Strasbourg/ENGEES, 1 rue Blessig, 67084 Strasbourg cedex, France
Boris M. van Breukelen
Delft University of Technology, Faculty of Civil Engineering and Geosciences, Department of Water Management, Stevinweg 1, Delft, the Netherlands
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Cited
25 citations as recorded by crossref.
- Pulling the rabbit out of the hat: Unravelling hidden nitrogen legacies in catchment‐scale water quality models S. Lutz et al. 10.1002/hyp.14682
- A review of modeling pesticides in freshwaters: Current status, progress achieved and desirable improvements. M. Centanni et al. 10.1016/j.envpol.2022.120553
- On the shape of forward transit time distributions in low-order catchments I. Heidbüchel et al. 10.5194/hess-24-2895-2020
- Modelling the impacts of climate change on agrochemical fate and transport by water on a catchment scale P. Nagesh et al. 10.1016/j.heliyon.2024.e35669
- <i>tran</i>-SAS v1.0: a numerical model to compute catchment-scale hydrologic transport using StorAge Selection functions P. Benettin & E. Bertuzzo 10.5194/gmd-11-1627-2018
- Multi-elemental compound-specific isotope analysis of pesticides for source identification and monitoring of degradation in soil: a review P. Höhener et al. 10.1007/s10311-022-01489-8
- Modeling Nitrate Export From a Mesoscale Catchment Using StorAge Selection Functions T. Nguyen et al. 10.1029/2020WR028490
- The Role of Ponds in Pesticide Dissipation at the Agricultural Catchment Scale: A Critical Review G. Imfeld et al. 10.3390/w13091202
- Do CSIA data from aquifers inform on natural degradation of chlorinated ethenes in aquitards? H. Thouement et al. 10.1016/j.jconhyd.2019.103520
- Transit Time Estimation in Catchments: Recent Developments and Future Directions P. Benettin et al. 10.1029/2022WR033096
- Dimethomorph degradation in vineyards examined by isomeric and isotopic fractionation J. Masbou et al. 10.1016/j.chemosphere.2022.137341
- Can the young water fraction reduce predictive uncertainty in water transit time estimations? A. Borriero et al. 10.1016/j.jhydrol.2024.132238
- Compound-Specific Isotope Analysis Provides Direct Evidence for Identifying the Source of Residual Pesticides Diazinon and Procymidone in the Soil–Plant System H. Yun et al. 10.1021/acs.jafc.4c00640
- Carbon and nitrogen stable isotope fractionation during abiotic hydrolysis of pesticides J. Masbou et al. 10.1016/j.chemosphere.2018.09.056
- Pesticides in surface waters: from edge-of-field to global modelling A. Ippolito & G. Fait 10.1016/j.cosust.2018.10.023
- Fungicides: An Overlooked Pesticide Class? J. Zubrod et al. 10.1021/acs.est.8b04392
- Simple extraction methods for pesticide compound-specific isotope analysis from environmental samples T. Gilevska et al. 10.1016/j.mex.2022.101880
- Solid-phase extraction method for stable isotope analysis of pesticides from large volume environmental water samples C. Torrentó et al. 10.1039/C9AN00160C
- Chemical effect of pesticide application on soils: evidence from rare earth elements K. Semhi et al. 10.1007/s12517-018-3925-4
- Impact of atrazine concentration on bioavailability and apparent isotope fractionation in Gram-negative Rhizobium sp. CX-Z S. Chen et al. 10.1016/j.envpol.2019.113614
- Application of Compound-Specific Isotope Analysis in Environmental Forensic and Strategic Management Avenue for Pesticide Residues E. Won et al. 10.3390/molecules26154412
- Uncertainty in water transit time estimation with StorAge Selection functions and tracer data interpolation A. Borriero et al. 10.5194/hess-27-2989-2023
- Pesticide degradation and export losses at the catchment scale: Insights from compound-specific isotope analysis (CSIA) P. Alvarez-Zaldívar et al. 10.1016/j.watres.2018.03.061
- Optimal Transport for Assessing Nitrate Source‐Pathway Connectivity A. Husic et al. 10.1029/2020WR027446
- Perspectives of compound-specific isotope analysis of organic contaminants for assessing environmental fate and managing chemical pollution T. Hofstetter et al. 10.1038/s44221-023-00176-4
25 citations as recorded by crossref.
- Pulling the rabbit out of the hat: Unravelling hidden nitrogen legacies in catchment‐scale water quality models S. Lutz et al. 10.1002/hyp.14682
- A review of modeling pesticides in freshwaters: Current status, progress achieved and desirable improvements. M. Centanni et al. 10.1016/j.envpol.2022.120553
- On the shape of forward transit time distributions in low-order catchments I. Heidbüchel et al. 10.5194/hess-24-2895-2020
- Modelling the impacts of climate change on agrochemical fate and transport by water on a catchment scale P. Nagesh et al. 10.1016/j.heliyon.2024.e35669
- <i>tran</i>-SAS v1.0: a numerical model to compute catchment-scale hydrologic transport using StorAge Selection functions P. Benettin & E. Bertuzzo 10.5194/gmd-11-1627-2018
- Multi-elemental compound-specific isotope analysis of pesticides for source identification and monitoring of degradation in soil: a review P. Höhener et al. 10.1007/s10311-022-01489-8
- Modeling Nitrate Export From a Mesoscale Catchment Using StorAge Selection Functions T. Nguyen et al. 10.1029/2020WR028490
- The Role of Ponds in Pesticide Dissipation at the Agricultural Catchment Scale: A Critical Review G. Imfeld et al. 10.3390/w13091202
- Do CSIA data from aquifers inform on natural degradation of chlorinated ethenes in aquitards? H. Thouement et al. 10.1016/j.jconhyd.2019.103520
- Transit Time Estimation in Catchments: Recent Developments and Future Directions P. Benettin et al. 10.1029/2022WR033096
- Dimethomorph degradation in vineyards examined by isomeric and isotopic fractionation J. Masbou et al. 10.1016/j.chemosphere.2022.137341
- Can the young water fraction reduce predictive uncertainty in water transit time estimations? A. Borriero et al. 10.1016/j.jhydrol.2024.132238
- Compound-Specific Isotope Analysis Provides Direct Evidence for Identifying the Source of Residual Pesticides Diazinon and Procymidone in the Soil–Plant System H. Yun et al. 10.1021/acs.jafc.4c00640
- Carbon and nitrogen stable isotope fractionation during abiotic hydrolysis of pesticides J. Masbou et al. 10.1016/j.chemosphere.2018.09.056
- Pesticides in surface waters: from edge-of-field to global modelling A. Ippolito & G. Fait 10.1016/j.cosust.2018.10.023
- Fungicides: An Overlooked Pesticide Class? J. Zubrod et al. 10.1021/acs.est.8b04392
- Simple extraction methods for pesticide compound-specific isotope analysis from environmental samples T. Gilevska et al. 10.1016/j.mex.2022.101880
- Solid-phase extraction method for stable isotope analysis of pesticides from large volume environmental water samples C. Torrentó et al. 10.1039/C9AN00160C
- Chemical effect of pesticide application on soils: evidence from rare earth elements K. Semhi et al. 10.1007/s12517-018-3925-4
- Impact of atrazine concentration on bioavailability and apparent isotope fractionation in Gram-negative Rhizobium sp. CX-Z S. Chen et al. 10.1016/j.envpol.2019.113614
- Application of Compound-Specific Isotope Analysis in Environmental Forensic and Strategic Management Avenue for Pesticide Residues E. Won et al. 10.3390/molecules26154412
- Uncertainty in water transit time estimation with StorAge Selection functions and tracer data interpolation A. Borriero et al. 10.5194/hess-27-2989-2023
- Pesticide degradation and export losses at the catchment scale: Insights from compound-specific isotope analysis (CSIA) P. Alvarez-Zaldívar et al. 10.1016/j.watres.2018.03.061
- Optimal Transport for Assessing Nitrate Source‐Pathway Connectivity A. Husic et al. 10.1029/2020WR027446
- Perspectives of compound-specific isotope analysis of organic contaminants for assessing environmental fate and managing chemical pollution T. Hofstetter et al. 10.1038/s44221-023-00176-4
Latest update: 24 Dec 2024
Short summary
This study presents concentration and carbon isotope data of two herbicides from a small agricultural catchment. Herbicide concentrations at the catchment outlet were highest after intense rainfall events. The isotope data indicated herbicide degradation within 2 months after application. The system was modelled with a conceptual mathematical model using the transport formulation by travel-time distributions, which allowed testing of various assumptions of pesticide transport and degradation.
This study presents concentration and carbon isotope data of two herbicides from a small...
