Water stable isotopes (δ²H and δ¹⁸O) in the Peninsula of Yucatan, Mexico

Abstract. The hydrogen and oxygen isotopic composition of water is a very important tool to estimate water balance, groundwater recharge, and evaporation. Water isotopes have been used to increase our understanding of the distribution and amounts of renewable and non-renewable groundwater. Isotopic data from precipitation and groundwater is available in much of Mexico but there is little information from the Peninsula of Yucatan, an area heavily relying in groundwater in which current estimates of groundwater availability are uncertain. In this paper, we compiled published and unpublished δ²H and δ¹⁸O data in meteoric (waters derived from precipitation), ground- and pore-waters, to obtain a regional meteoric water line (RMWL) expressed by the equation δ²H = 8.1846 δ¹⁸O + 10.289. The data suggest that precipitation originates in convective systems, low-pressure events, moisture from frontal events, and from re-condensed moisture. The evaporation lines from groundwater suggest mixing of water with different isotopic composition, but also provide clues to recent meteoric water rapid recharge, likely from rain events of great intensity. We present a groundwater isoscape of the Peninsula of Yucatan and finally address the lack of conciliation between hydrogeology and groundwater management.