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  <front>
    <journal-meta><journal-id journal-id-type="publisher">HESS</journal-id><journal-title-group>
    <journal-title>Hydrology and Earth System Sciences</journal-title>
    <abbrev-journal-title abbrev-type="publisher">HESS</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Hydrol. Earth Syst. Sci.</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1607-7938</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/hess-23-1375-2019</article-id><title-group><article-title>Combining continuous spatial and temporal scales <?xmltex \hack{\break}?>for SGD investigations
using UAV-based thermal <?xmltex \hack{\break}?>infrared measurements</article-title><alt-title>Combining continuous spatial and temporal scales</alt-title>
      </title-group><?xmltex \runningtitle{Combining continuous spatial and temporal scales}?><?xmltex \runningauthor{U.~Mallast and C.~Siebert}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes">
          <name><surname>Mallast</surname><given-names>Ulf</given-names></name>
          <email>ulf.mallast@ufz.de</email>
        <ext-link>https://orcid.org/0000-0001-9238-3464</ext-link></contrib>
        <contrib contrib-type="author" corresp="no">
          <name><surname>Siebert</surname><given-names>Christian</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-7266-8112</ext-link></contrib>
        <aff id="aff1"><institution>Helmholtz Centre for Environmental Research – UFZ, T. Lieser Str. 4,
06120 Halle, Germany</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Ulf Mallast (ulf.mallast@ufz.de)</corresp></author-notes><pub-date><day>11</day><month>March</month><year>2019</year></pub-date>
      
      <volume>23</volume>
      <issue>3</issue>
      <fpage>1375</fpage><lpage>1392</lpage>
      <history>
        <date date-type="received"><day>29</day><month>June</month><year>2018</year></date>
           <date date-type="rev-request"><day>12</day><month>July</month><year>2018</year></date>
           <date date-type="rev-recd"><day>20</day><month>January</month><year>2019</year></date>
           <date date-type="accepted"><day>26</day><month>January</month><year>2019</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2019 Ulf Mallast</copyright-statement>
        <copyright-year>2019</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://hess.copernicus.org/articles/23/1375/2019/hess-23-1375-2019.html">This article is available from https://hess.copernicus.org/articles/23/1375/2019/hess-23-1375-2019.html</self-uri><self-uri xlink:href="https://hess.copernicus.org/articles/23/1375/2019/hess-23-1375-2019.pdf">The full text article is available as a PDF file from https://hess.copernicus.org/articles/23/1375/2019/hess-23-1375-2019.pdf</self-uri>
      <abstract><title>Abstract</title>
    <p id="d1e90">Submarine groundwater discharge (SGD) is highly variable in spatial and
temporal terms due to the interplay of several terrestrial and marine
processes. While discrete in situ measurements may provide a continuous
temporal scale to investigate underlying processes and thus account for
temporal heterogeneity, remotely sensed thermal infrared radiation sheds
light on the spatial heterogeneity as it provides a continuous spatial scale.</p>
    <p id="d1e93">Here we report results of the combination of both the continuous spatial and
temporal scales, using the ability of an unmanned aerial vehicle (UAV) to
hover above a predefined location, and the continuous recording of thermal
radiation of a coastal area at the Dead Sea (Israel). With a flight altitude
of 65 m above the water surface resulting in a spatial resolution of 13 cm
and a thermal camera (FLIR Tau2) that measures the upwelling long-wave
infrared radiation at 4 Hz resolution, we are able to generate a time series
of thermal radiation images that allows us to analyse spatio-temporal SGD
dynamics.</p>
    <p id="d1e96">In turn, focused SGD spots, otherwise camouflaged by strong lateral
flow dynamics, are revealed that may not be observed on single thermal
radiation images. The spatio-temporal behaviour of an SGD-induced thermal
radiation pattern varies in size and over time by up to 155 % for focused
SGDs and by up to 600 % for diffuse SGDs due to different underlying flow
dynamics. These flow dynamics even display a short-term periodicity of the
order of 20 to 78 s  for diffuse SGD, which we attribute to an interplay
between conduit maturity–geometry and wave set-up.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <title>Introduction</title>
      <p id="d1e106">Submarine groundwater discharge (SGD) is defined as “any and all flow of
water on continental margins from the seabed to the coastal ocean” (Burnett
et al., 2003). The definition already implies several proportions of water
with different origins contributing to SGD. Apart from recirculated
seawater, it is also fresh groundwater of meteoric origin. The relative
share of each water contribution depends on terrestrial and marine controls.
Recharge amounts, aquifer permeability and hydraulic gradients define the
terrestrial groundwater contribution, which may be the major SGD share in
areas with high permeability, such as karstic environments. In areas with
low hydraulic gradients and low aquifer permeability, recirculated seawater
as a share of SGD predominates. The recirculation is induced by the highly
variable hydraulic gradients caused by tidal or lunar cycles, storms, or
wave set-up. In situ  measurements such as seepage meters, multilevel
piezometers, tracers, etc. possess the ability to discriminate between the
SGD shares and allow a linkage to the underlying processes, since the
investigated temporal scale is continuous and ranges between daily and
seasonal cycles (Taniguchi et al., 2003a; Michael et al., 2011). Yet, all of
this cannot account for the spatial variability, as the entity and
interaction of terrestrial and marine controls lead to a highly variable SGD
appearance in terms of discharge type (diffuse vs. focused), temporal
discharge behaviour, flow rates, spatial abundance (even over small spatial
scales), and mixing (Michael et al., 2003; Taniguchi et al., 2003b; Burnett
et al., 2006).</p>
      <?pagebreak page1376?><p id="d1e109"><?xmltex \hack{\newpage}?>In contrast, remote sensing technology allows identification and
quantification of SGD over larger spatial scales without neglecting its
spatial and temporal variance, or the need to extrapolate from in situ
measurements. Depending on the intended spatial scale, utilized platforms
differ between satellite (spatial coverage <inline-formula><mml:math id="M1" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 10 000 km<inline-formula><mml:math id="M2" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>), airplane (spatial
coverage <inline-formula><mml:math id="M3" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 100 km<inline-formula><mml:math id="M4" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>), and unmanned aerial vehicle (hereafter UAV) systems
(spatial coverage <inline-formula><mml:math id="M5" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 100 km<inline-formula><mml:math id="M6" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>). From these systems
the majority of all approaches measure thermal infrared radiation (hereafter
thermal radiation/radiances) (i.e. Mejías et al., 2012; Kelly et al.,
2018; Mallast et al., 2013b; Lee et al., 2016).</p>
      <p id="d1e162">The principle of using thermal radiation for SGD detection is based on
temperature contrasts between SGD water and ambient water at the sea
surface. Since the surface temperatures are directly proportional to emitted
thermal radiation (see Stefan–Boltzman law) and assume a rather similar
emissivity for water, sea surface temperature contrasts evoke
distinguishable thermal radiation patterns or thermal radiation anomalies,
which are indicative of SGD. This qualitative approach has been expanded by
a few studies that use thermal anomalies to quantify SGD through a relation
of anomaly (plume) size to measured or modelled SGD rates (Kelly et al.,
2018; Tamborski et al., 2015; Lee et al., 2016). Given a positive buoyancy
of less saline groundwater in marine environments, the intriguing simplicity
of these approaches is based on the momentum of discharging groundwater
(Mallast et al., 2013a) and a potential deflection in the water body due to
currents and wave action (Lee et al., 2016), external forces (e.g. wind)
(Lewandowski et al., 2013), and Newton's law of cooling (Vollmer, 2009).
While the latter leads to a convective heat transfer between the discharging
and the ambient water with exponential adaption behaviour at the fringe of
the plume, the momentum and deflections are the forces defining the size and
shape of the plume. In turn, the momentum leads to a positive relationship
between plume size and discharge rate (Johnson et al., 2008; Mallast et al.,
2013a; Lee et al., 2016) for parts of the plume not being deflected and
demonstrates the practicability and numerous advantages in terms of spatial
continuity. The possible quantification approach, however, relies on thermal
radiation snapshots recorded at a certain instantaneous time (Kelly et al.,
2018; Tamborski et al., 2015).</p>
      <p id="d1e165">Thus, in terms of scale, the advantage of remote sensing for SGD
investigations is the continuous spatial scale, which allows the derivation
of a general picture in regard to SGD abundance and quantity independent of
its appearance and spatial variability. On the other hand, the advantage of
in situ measurements is explicitly the continuous temporal scale, which
permits a process understanding and elaboration on the drivers.</p>
      <p id="d1e169">However, with the advent and the ability of multicopters as a type of UAV
to hover over a predefined location, it becomes possible to combine the
continuous spatial and temporal scales in an unrivalled resolution and to
investigate the spatio-temporal behaviour of SGD in one context. Here we
report the results of such a study that uses a thermal camera system mounted
beneath a multicopter. The multicopter hovers above a predefined location
to (i) investigate the spatio-temporal variability of focused and diffuse SGD
and (ii) to outline additional values of the presented approach. The study is
conducted at a site on the hypersaline Dead Sea, at which previously
investigated submarine and terrestrial springs emerge. Existing hydraulic
gradients in the discharging aquifers and high density differences between
groundwater and lake water qualify the terminology SGD, which is usually bound
to marine environments only.</p>
</sec>
<sec id="Ch1.S2">
  <title>Study area</title>
      <p id="d1e178">The study was conducted at a known and pre-investigated SGD site (see
Sect. 2.2) at the eastern slope of the sedimentary fan of Wadi Darga,
located at the western coast of the Dead Sea (Fig. 1a, d, e).</p>
<sec id="Ch1.S2.SS1">
  <title>Hydrogeological setting</title>
      <p id="d1e186">Discharging groundwater at the study area is replenished in the Judean
Mountains either through precipitation or flash floods that infiltrate into
the Upper Cretaceous limestone and dolostone of the Judea Group Aquifer (JGA)
and flow east towards the Dead Sea Rift (DSR). After passing the transition
to the DSR, which is marked by normal faults and block tectonics, fresh
groundwater enters the Quaternary fluvio-lacustrine Dead Sea Group (DSG)
that is deposited in front of the Cretaceous rocks (Yechieli et al., 2010).
The DSG consists of stratified fine-grained lacustrine sediments (clay
minerals, aragonite, gypsum, halite), which are intercalated with coarser
clastic layers. At wadi outlets, the lacustrine strata are displaced with
fluviatile fine to coarse clastic sediments (Yechieli et al., 1995).</p>
      <p id="d1e189">Due to the alternations of coarse and fine strata, groundwater flow occurs
through separated subaquifers that possess different groundwater levels
(Yechieli et al., 2010). In addition, preferential flow paths in the form of
dissolution tubes and cavities develop due to dissolution of the evaporitic
minerals (Magal et al., 2010; Ionescu et al., 2012). The dissolution process
accelerates with the continuous and fast drop of the Dead Sea water level of
<inline-formula><mml:math id="M7" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1 m yr<inline-formula><mml:math id="M8" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>  (Yechieli et al., 2010), which forces the
formation of new groundwater flow paths. The resulting partially karstic
flow system in the DSG is highly transient, resulting in immensely variable
discharge rates, discharge locations and chemical composition of springs
along the lakeshore (Burg et al., 2016). Besides admixing of interstitial
brines to the groundwater, the degree of water–rock interaction in the DSG
controls the groundwater's composition. Hence, large observable differences
in the composition of discharging groundwater, which occur even within the
range of a few metres, are an expression of the<?pagebreak page1377?> heterogeneous maturity of
the karst system. The less mature the conduits, the larger the ratio
between wetted soluble surfaces and volume.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><label>Figure 1</label><caption><p id="d1e213">Location of the study area at the Dead Sea <bold>(a)</bold>, photo of the
UAV used during the study <bold>(b)</bold>, photo of both reflectors at the covered
coastline section <bold>(c)</bold>, distribution of focused SGD spots identified and
sampled by divers in the years 2011 and 2012, and onshore springs which have
been sampled frequently since 2009 <bold>(d)</bold>, and an aerial photograph from 10 February 2016 at 12:11 LT
of the covered area along with UAV
positions during hovering, location of reflectors, the footprint of the
processed frames after co-registration described in Sect. 2.3 and
locations of observed diffuse SGD <bold>(e)</bold>.</p></caption>
          <?xmltex \igopts{width=455.244094pt}?><graphic xlink:href="https://hess.copernicus.org/articles/23/1375/2019/hess-23-1375-2019-f01.jpg"/>

        </fig>

      <p id="d1e237">Consequently, diffuse SGD exhibits a high load of dissolved solids and thus
is saline (less mature karst system), while focused SGD is less loaded and
exhibits a lower salinity (mature karst system).</p>
</sec>
<sec id="Ch1.S2.SS2">
  <title>Submarine groundwater discharge and onshore spring
characteristics</title>
      <p id="d1e246">At the investigation site, focused SGD occurrences were mapped in 2011 and
2012 by scuba divers and hydrochemically investigated. Based on their
findings groundwater emerges from mature karst-like cavities down to depths
of 30 m below the sea surface (Ionescu et al., 2012; Mallast et al., 2014).</p>
      <p id="d1e249">From these cavities groundwater emerges as focused SGD. Subsequently,
density differences between SGD water (1.00–1.19 g cm<inline-formula><mml:math id="M9" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)
and Dead Sea brine (1.234 g cm<inline-formula><mml:math id="M10" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) trigger a continuous
positive buoyancy (buoyant jet) of the emerging groundwater towards the
lake's surface. Within the water column and alongside the buoyant jet,
considerable turbulences develop, entraining ambient Dead Sea brine. Thus,
the ascending water represents a mixture of fresh to brackish groundwater
and lake brine. Once the ascending mixture reaches the lake's surface, it
develops a radially orientated flow away from its jet centre, causing a
circular-like pattern. These patterns are partially visually observable as
shown in Mallast et al. (2014) at the Dead Sea and in various other cases
(Swarzenski et al., 2001).</p>
      <p id="d1e276">Apart from focused SGD, diffuse SGD occurs at the investigation site as
well, either in various depths below the water surface (Ionescu et al.,
2012) or at the shoreline. At the study area one diffuse SGD site exists
directly at the shoreline (Fig. 1e). The discharge seems to occur over a
length of approximately 20–25 m alongshore and was only detectable visually
through the occurrence of schlieren in the lake brine. However, low
discharge rates in combination with the immediate mixing with the lake brine
impede any attempt to sample that water.</p>
      <p id="d1e279">In order to still be able to compare groundwater characteristics, we sampled
five onshore springs (Fig. 1d). All are in close proximity to previously
mentioned SGD and to the shoreline, but emerge as focused flow in different
elevations of 0.5–10 m above the Dead Sea water level. The water
characteristics are shown in Table 2.</p>
</sec>
<sec id="Ch1.S2.SS3">
  <title>Hydrologic and atmospheric setting</title>
      <p id="d1e288">According to on-site measurements, SGD water temperatures at the orifices
are 21–31.5 <inline-formula><mml:math id="M11" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. During the time of investigation the Dead Sea had
a skin temperature of <inline-formula><mml:math id="M12" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 21 <inline-formula><mml:math id="M13" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C providing a
temperature maximum difference of 10.5 <inline-formula><mml:math id="M14" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C between groundwater and
ambient Dead Sea brine. Wind speeds amounted to 0.87 m s<inline-formula><mml:math id="M15" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>
(<inline-formula><mml:math id="M16" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.16</mml:mn></mml:mrow></mml:math></inline-formula>) approaching from SE to E (80–128<inline-formula><mml:math id="M17" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>).
Occurring waves, which may influence SGD size and shape, had a frequency of
3–7 s  with estimated wave heights <inline-formula><mml:math id="M18" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">15</mml:mn></mml:mrow></mml:math></inline-formula> cm. During the flight,
cloud-free conditions and thus homogeneous solar radiation existed, equally
reflected at the sea surface throughout the entire covered area.</p>
</sec>
</sec>
<sec id="Ch1.S3">
  <title>Materials and methods</title>
      <p id="d1e374">The general approach to investigate the spatio-temporal thermal radiation
variability induced by SGD consists of hovering with an UAV (multicopter –
model: geo-X8000) (Fig. 1b) above a pre-defined SGD spot (Fig. 1c) over a
time period of several minutes. The flight was conducted on 10 February 2016
between 12:43 and 12:50 LT (local time), with activated image recording between 12:45 to
12:48 LT. During that flight the UAV was equipped with a thermal system
comprising (i) a long-wave infrared camera core (FLIR Tau2), which is an
uncooled VOx Microbolometer with a 19 mm lens and a 640 <inline-formula><mml:math id="M19" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 512 focal plane
array (FLIR<sup>®</sup> Systems 2016) and (ii) a ThermalCapture
radiometry module and image grabber (TeAx Technology, 2016). The system
senses long-wavelength infrared radiation in the spectral range of
7.5–13.5 <inline-formula><mml:math id="M20" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m with a sensitivity of <inline-formula><mml:math id="M21" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">50</mml:mn></mml:mrow></mml:math></inline-formula> mK. Subsequently, sensed
radiation is captured as 14 bit images at a frame rate of 9 Hz, from which
only every fifth frame is exportable (approx. 4–5 Hz), deduced after
our own tests. The core was calibrated prior to the flight using an internal
flat-field corrector.</p>
      <p id="d1e405">The hovering position was at 31.576516<inline-formula><mml:math id="M22" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>, 35.415775<inline-formula><mml:math id="M23" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> with a flight altitude of
65 m above Dead Sea level. Due to the GPS-controlled nature of the UAV, the
hovering position displays a certain spatial variability which is according
to the flight log <inline-formula><mml:math id="M24" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1.5</mml:mn></mml:mrow></mml:math></inline-formula> m in the horizontal dimension and <inline-formula><mml:math id="M25" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1.75</mml:mn></mml:mrow></mml:math></inline-formula> m
in the vertical dimension. Position and altitude were chosen (i) according to
Israeli regulatory framework and (ii) to cover land and water in equal
shares. The latter was important for the image registration of each recorded
image to a selected reference image (see Sect. 3.1) in order to correct
the spatial variability of the UAV and the sensor during hovering, and to
determine the position accuracy of the image registration, which was based
on two aluminium reflectors (35 cm <inline-formula><mml:math id="M26" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 70 cm) placed directly on the shore
(Fig. 1b, c).</p>
<sec id="Ch1.S3.SS1">
  <title>Data processing</title>
      <p id="d1e458">Thermal radiance image recording with 4–5 Hz results in a total of 670
images recorded within a time span of 167 s. Each image displays thermal
radiances emitted by the surface. According to the Stefan–Boltzman law these
radiances are directly proportional to the existing surface temperatures and
thus are the basis for the present study. Yet, due to the UAV position
variability while hovering above the pre-defined flight position, the mapped
image footprint is not<?pagebreak page1378?> congruent for each image but varies spatially at the
same magnitude as the position variability, which is also described in
Holman et al. (2011).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2" specific-use="star"><label>Figure 2</label><caption><p id="d1e463">Graphic illustration of image recording and image preprocessing
applied during the presented approach.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://hess.copernicus.org/articles/23/1375/2019/hess-23-1375-2019-f02.png"/>

        </fig>

      <p id="d1e472">To overcome the varying footprint, we define the first image of the set as
the reference image and all remaining ones as input images (Fig. 2).
Subsequently all input images are automatically co-registered onto the
reference image using an intensity-based image registration within a MATLAB
2016 environment<fn id="Ch1.Footn1"><p id="d1e475">The MATLAB code used for the present study can be
distributed upon request.</p></fn>. The applied image registration uses a similarity
transformation that considers translation, rotation and scaling as possible
factors induced by the UAV position variability and thus the non-congruent
image footprints. This type of registration was chosen due to the fact that
the short-term differences between images would not cause (i) nonlinear geometric differences or (ii) a change
of intensities, which in the present case are radiances. Instead, the land
and placed reflectors especially represent those rigid parts with similar
intensities needed for intensity-based image registration (Kim and Fessler,
2004).</p>
      <p id="d1e479">The core of the intensity-based image registration consists of comparing an
input matrix (reference image) with a transformation matrix (each input
image). During an iterative regular step gradient descent optimization, the
transformation matrix is transformed, incorporating scaling, rotation and
translation. The intensities of both the input and transformation matrices
are compared using a similarity measure (e.g. a mean square metric as in the
presented study) with the aim to maximize the similarity between both
matrices (Viana et al., 2015). The iterative optimization process continues
until the maximum iteration criterion reaches 1000 iterations, or the
optimization criterion reaches a maximum step length of 0.01. This
image registration process is repeated for
all input images.</p>
      <p id="d1e483">To provide a further independent accuracy measure, we use the two previously
described aluminium reflectors. Similar to the automatic approach described
in Holman et al. (2017) to find GPS targets, we define search windows in<?pagebreak page1379?> the
registered input images, looking for the lowest radiance values
(<inline-formula><mml:math id="M27" display="inline"><mml:mo lspace="0mm">=</mml:mo></mml:math></inline-formula> reflector plates). Since the plates represent an area of several
connected pixels, we then extract the mass centre of both plates and each
image. Comparing the positions of the mass centres of both reflectors in the
reference image with each input image yields an independent spatial accuracy
measure. The so-obtained spatial accuracy of the image registration results
in an RMSE of 0.58 pixels (1 pixel <inline-formula><mml:math id="M28" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 13 cm), a mean of 0.5 pixels, and a
standard deviation of 0.3 pixels (see Fig. S1 in the Supplement).</p>
      <p id="d1e500">As a consequence of the image registration process and the transformation of
the input matrices, the footprint (covered area) varies. In order to be able
to analyse the same covered area, we reduce the image sizes to a common
footprint extent represented by all images. The so-obtained image size
amounts to 561 pixels <inline-formula><mml:math id="M29" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 376 pixels. Onto all co-registered images, we then apply a
manually derived land mask, masking out any radiances from land parts.
Subsequently, radiance values of the remaining water area are normalized
using a <inline-formula><mml:math id="M30" display="inline"><mml:mi>z</mml:mi></mml:math></inline-formula>-score normalization to account for potential global solar
radiation differences that may occur over the time of investigation and
would affect the result. The so-obtained processed image set consists of a
3-D data cube (<inline-formula><mml:math id="M31" display="inline"><mml:mrow><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mi>y</mml:mi><mml:mo>,</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula>) of 670 images (hereafter frames) resembling a total time
period of 167 s and showing normalized sea surface radiances in <inline-formula><mml:math id="M32" display="inline"><mml:mrow><mml:mi>x</mml:mi><mml:mo>,</mml:mo><mml:mi>y</mml:mi></mml:mrow></mml:math></inline-formula>
dimensions.</p>
</sec>
<sec id="Ch1.S3.SS2">
  <title>Delineation of diffuse and focused SGD spots</title>
      <p id="d1e551">Since SGD at the investigated site consists of focused SGD occurring
offshore and diffuse SGD occurring at the land–water interface, we use
different approaches to extract relevant discharge spots separately to
finally pursue the intended temporal investigations. Given the assumption of
a thermally stabilized area over time induced by focused SGD (Mallast et
al., 2013b; Siebert et al., 2014), we calculate the thermal variance per
pixel of the data cube's temporal dimension <inline-formula><mml:math id="M33" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> using MATLAB 2016. The
resulting low-variance areas represent focused SGD sites with constant and
intense discharge. To extract focused SGD sites, we apply a subjective
variance threshold of <inline-formula><mml:math id="M34" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">0.019</mml:mn></mml:mrow></mml:math></inline-formula><fn id="Ch1.Footn2"><p id="d1e570">Note that the subjective
variance threshold is optimal for the present case and will certainly change
in other environments. Thus, in order to investigate any spatio-temporal SGD
analysis, this threshold needs to be adapted otherwise it would create an
erroneous focused SGD outline and hence a wrong focus area.</p></fn> and eliminate
extraction artefacts, using a morphological closing and deletion of objects
smaller than 150 pixels to obtain the low-variance area representing focused
SGD sites only.</p>
      <p id="d1e574">In contrast, the observed diffuse SGD site along the shoreline discharges
less water with lower discharge rates and thus has a smaller momentum,
which inevitably leads to a smaller, thermally stabilized alongshore area
(<inline-formula><mml:math id="M35" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M36" display="inline"><mml:mrow><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mn mathvariant="normal">1</mml:mn></mml:msup><mml:mo>-</mml:mo><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> cm perpendicular to the coastline).
While thermally stabilized, several direct forces such as breaking waves and
currents influence the same area and thus the resulting thermal radiation
pattern on the sea surface. These factors lead to rather high variances
compared to focused SGD flow. Unfortunately, a similar variance can be
expected from ambient areas influenced by highly dynamic flow field induced
by waves, currents and discharge. As a consequence, we delineate diffuse SGD
from a single frame (frame 210 – not shown) in which thermal radiation
patterns and maximum spatial extents induced by high discharge rates are
unequivocally detectable (a comparable single image is shown in Fig. 3, upper left image). Analogous to the focused SGD sites, we apply a subjective
threshold of <inline-formula><mml:math id="M37" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">2.5</mml:mn></mml:mrow></mml:math></inline-formula> (normalized radiation) to extract discharge-induced thermal patterns and eliminate extraction artefacts using a
morphological closing to clean extracted pattern objects, followed by the
deletion of objects smaller than 150 pixels to focus on larger patterns only.</p>
</sec>
<sec id="Ch1.S3.SS3">
  <title>Spatio-temporal analyses</title>
      <?pagebreak page1380?><p id="d1e619">We conduct two forms of (spatio-)temporal analyses: (i) a spatio-temporal
analysis to identify the spatial variability of both thermal radiance patterns
induced by diffuse and focused SGD and (ii) a periodicity analysis to reveal
possible reoccurring temporal discharge patterns. To explore the
spatio-temporal behaviour, and within a MATLAB 2016 environment, we construct
transects across the maximum extent of each extracted SGD spot, as we expect
the most pristine patterns there. Along each transect, normalized thermal
radiances per frame are extracted, filtered using a 1-D ninth-order median
filter to reduce the white noise portion, and finally plotted, highlighting
the spatio-temporal behaviour for each spot.</p>
      <p id="d1e622">For the periodicity analysis we use an autocorrelation function, which
measures the self-similarity of a signal (Tzanetakis and Cook, 2002). If
discharge occurs regularly, it causes a periodic signal, which is expressed
as a significant peak (above or below 95 % confidence interval) in the
autocorrelation function. As we expect the most pristine discharge-induced
thermal pattern signals for both SGD types at the midpoint of each transect,
we pursue the periodicity analysis at the specific transect midpoint pixel
for each of the transects.</p>
</sec>
<sec id="Ch1.S3.SS4">
  <title>Water chemistry and inverse geochemical modelling</title>
      <p id="d1e631">To draw conclusions about the karst maturity of the flow net that feeds on-
and offshore springs, we investigate the type and intensity of
groundwater–rock interaction at each spring based on their on-site and
chemical parameters. Physicochemical on-site parameters (temperature,
density, pH, electrical conductivity) of all the above mentioned focused SGD
as well as onshore springs (see Fig. 1d, e) are measured in the field
using a WTW 350i and Mettler Toledo density meter. The sampling procedure for
groundwater samples to analyse the major element concentrations follows the
procedure described in detail in Ionescu et al. (2012). Generally, samples
for anion and cation analyses are filtered (0.22 <inline-formula><mml:math id="M38" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi></mml:mrow></mml:math></inline-formula>m CA filters),
separately filled in HDPE bottles and stored under cool conditions. Cation samples are
immediately acidified and later analysed by applying ICP-AES. Anions are
analysed using ion chromatography and bicarbonate by Gran titration (see
Table 2).</p>
      <p id="d1e642">The individual water–rock interactions, which lead to the chemical
composition of the respective groundwaters in the springs, are inversely
modelled applying PHREEQC and Pitzer thermodynamic database. We apply the
latter due to the high activities in the modelled environment, consisting of
a sedimentary saline aquifer body, soaked with interstitial brine, which
admixes to the fresh groundwater. On the basis of the abundant easily
soluble minerals (halite, aragonite and gypsum), we select reactive solid
phases in the sedimentary succession, enable ion exchange on clay minerals,
and evaluated modelling results based on the probability and lowest sum of
residuals.</p><?xmltex \hack{\newpage}?>
</sec>
</sec>
<sec id="Ch1.S4">
  <title>Results</title>
      <p id="d1e653">It is a proven fact that SGD influences the sea surface temperature and thus
the thermal radiances, and that it is thoroughly detectable given a
sufficient temperature contrast between groundwater and sea or lake water and a
certain minimum discharge volume and momentum (Johnson et al., 2008; Lee
et al., 2016; Tamborski et al., 2015). Our results confirm this fact as
diffuse SGD induces thermal radiance patterns with values <inline-formula><mml:math id="M39" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> (higher temperatures)
that are visible in Fig. 3a and
spatially coincide with our field observations. Yet, the single thermal
radiance image suggests the diffuse discharge occurs in two distinguishable
patterns.</p>
      <p id="d1e666">The first pattern is a coastal fringe of 35 m length and of 10 pixels (1.3 m)
width, showing elevated normalized thermal radiance (NTR) values
<inline-formula><mml:math id="M40" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula>. This alongshore distribution exceeds the visual results of
ca. 20 m by a factor of 1.5 and suggests a homogeneously distributed, low
velocity and low rate discharge of warmer groundwater that emerges partially
onshore and partially directly at the water–land interface (Fig. 3a).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><label>Figure 3</label><caption><p id="d1e681">Variance
of normalized thermal radiances over time starting with a
normalized thermal radiance image <bold>(a)</bold> showing ambiguous evidence
of focused SGD spots, but distinct evidence of diffuse SGD and counter
rotating vortex pairs (CVPs). The latter serves as an indication of a focused
flow within the diffuse SGD area <bold>(a)</bold>. The following panels
show the integration of 10 (<inline-formula><mml:math id="M41" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 2.5 s), 50 (<inline-formula><mml:math id="M42" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 12.5 s), 100 (<inline-formula><mml:math id="M43" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 25 s), 300 (<inline-formula><mml:math id="M44" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 75 s), and 670 frames (<inline-formula><mml:math id="M45" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 167.5 s)
as variance per pixel. The final image <bold>(f)</bold> shows three delineated focused
SGD spots (red boxes) indicated through variance values <inline-formula><mml:math id="M46" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">0.019</mml:mn></mml:mrow></mml:math></inline-formula>.</p></caption>
        <?xmltex \igopts{width=497.923228pt}?><graphic xlink:href="https://hess.copernicus.org/articles/23/1375/2019/hess-23-1375-2019-f03.png"/>

      </fig>

      <p id="d1e745">The second, seemingly dominant pattern is characterized by NTR values
<inline-formula><mml:math id="M47" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula>, but in contrast to the first, it consists of distinctive
counter-rotating vortex pair (CVP) flow structures (Cortelezzi and
Karagozian, 2001), discernible based on the mushroom shape, with length axes
between 20 and 46 pixels (2.6–6.0 m). The cause appears to be a focused and
lateral jet-like discharge at four locations (Fig. 3a).
Plumes, caused by both discharge forms, are subsequently deviated towards
NNE.</p>
      <p id="d1e759">Focused SGD with an expected circular to elliptical shape as observed by
Mallast et al. (2014) and Swarzenski et al. (2001), are not unequivocally
visible from the single frame (one thermal radiance image) only. At the
upper and left ends of the single frame (first frame in Fig. 3), three
half-circular patterns with NTR values between <inline-formula><mml:math id="M48" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.6</mml:mn></mml:mrow></mml:math></inline-formula> and 0 foreshadow focused
SGD spots, which coincide with in situ observed and sampled focused SGD
spots <inline-formula><mml:math id="M49" display="inline"><mml:mrow><mml:mn mathvariant="normal">11</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">120</mml:mn></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M50" display="inline"><mml:mrow><mml:mn mathvariant="normal">11</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">121</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M51" display="inline"><mml:mrow><mml:mn mathvariant="normal">12</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">382</mml:mn></mml:mrow></mml:math></inline-formula>. However, from the thermal radiation
perspective, spatial indications for more than these three SGD sites are
missing.</p>
      <p id="d1e808">Given the assumption of SGD to thermally stabilize thermal radiance
variation at the sea surface over time, as shown for satellite images
(Schubert et al., 2014; Oehler et al., 2017), we integrate several frames
(thermal radiance images) to enhance the above-mentioned focused SGD spots
and to reveal further ones.</p>
      <p id="d1e811">The thermal radiation variance of 10, 50 and 100 frames (integration of 2.5,
12.5 and 25 s  respectively) already indicates thermally stable (variance
values <inline-formula><mml:math id="M52" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">0.2</mml:mn></mml:mrow></mml:math></inline-formula>) and thermally labile areas (variance values <inline-formula><mml:math id="M53" display="inline"><mml:mrow><mml:mo>≥</mml:mo><mml:mn mathvariant="normal">0.2</mml:mn></mml:mrow></mml:math></inline-formula>). However, with larger integration times of 300 and 670 frames
(integration of 75 and 176 s  respectively), the three above-mentioned
focused SGD spots appear, as well as two additional SGD spots in the upper
part of the resulting variance image (Fig. 3f),<?pagebreak page1381?> which
spatially coincide with in situ observed focused SGD sites <inline-formula><mml:math id="M54" display="inline"><mml:mrow><mml:mn mathvariant="normal">11</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">101</mml:mn></mml:mrow></mml:math></inline-formula>, and
<inline-formula><mml:math id="M55" display="inline"><mml:mrow><mml:mn mathvariant="normal">11</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">102</mml:mn></mml:mrow></mml:math></inline-formula>. In the following sections, we focus on the three largely complete
focused SGD spots 1 to 3 (Fig. 3). These three focused SGD spots exhibit
variance values <inline-formula><mml:math id="M56" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">0.019</mml:mn></mml:mrow></mml:math></inline-formula> and elliptical (first spot) to circular
(second and third spot) shapes at the sea surface underlined by the
individual length <inline-formula><mml:math id="M57" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> width ratios (Fig. 4). The lowest variance values, and
therefore the thermally most stable areas are located at the southern end of
the first and second SGD spots and on the northern end of the third SGD spot.
Thermally indicated surface areas vary between 4.1 and
28.7 m<inline-formula><mml:math id="M58" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> despite similar spring depths of 13–20 m.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4" specific-use="star"><label>Figure 4</label><caption><p id="d1e887">Spatial characteristics of the presented focused SGD spots and
their spatial correspondence of sampled submarine springs during previous
campaigns.</p></caption>
        <?xmltex \igopts{width=497.923228pt}?><graphic xlink:href="https://hess.copernicus.org/articles/23/1375/2019/hess-23-1375-2019-f04.png"/>

      </fig>

<sec id="Ch1.S4.SS1">
  <title>Spatio-temporal behaviour of discharge-induced thermal radiance
patterns</title>
      <p id="d1e901">While the previous variance analysis highlights thermally stable and labile
areas useful for identifying SGD spots, time- specific information on
spatio-temporal discharge behaviour cannot be derived. We obtain this
information through the introduction of transects (see left column in Figs. 5 and 6)
along which we extract radiation values of each frame. The
transects are constructed across the maximum spatial extent of each
extracted, focused and diffuse SGD spot, as we expect the most pristine
temporal patterns representative for each spot to occur here.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><label>Table 1</label><caption><p id="d1e907">Summary of values characterizing the spatio-temporal
behaviour of each focused and diffuse SGD spot.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="7">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="center"/>
     <oasis:colspec colnum="3" colname="col3" align="center"/>
     <oasis:colspec colnum="4" colname="col4" align="center"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="center"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:thead>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2">SGD</oasis:entry>

         <oasis:entry colname="col3">Corresponds</oasis:entry>

         <oasis:entry colname="col4">Spatial</oasis:entry>

         <oasis:entry colname="col5">Peak values<inline-formula><mml:math id="M64" display="inline"><mml:msup><mml:mi/><mml:mtext>b</mml:mtext></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col6">Significant</oasis:entry>

         <oasis:entry colname="col7">Significant</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2">spot</oasis:entry>

         <oasis:entry colname="col3">to sampled</oasis:entry>

         <oasis:entry colname="col4">variation<inline-formula><mml:math id="M65" display="inline"><mml:msup><mml:mi/><mml:mtext>a</mml:mtext></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col5">(standard deviation)</oasis:entry>

         <oasis:entry colname="col6">periodicity</oasis:entry>

         <oasis:entry colname="col7">period</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col1"/>

         <oasis:entry colname="col2"/>

         <oasis:entry colname="col3">spring</oasis:entry>

         <oasis:entry colname="col4">(in %)</oasis:entry>

         <oasis:entry colname="col5"/>

         <oasis:entry colname="col6">(in s)</oasis:entry>

         <oasis:entry colname="col7"/>

       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>

         <?xmltex \rotentry?><oasis:entry rowsep="1" colname="col1" morerows="2">Focused</oasis:entry>

         <oasis:entry colname="col2">1st</oasis:entry>

         <oasis:entry colname="col3"><inline-formula><mml:math id="M66" display="inline"><mml:mrow><mml:mn mathvariant="normal">11</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">101</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col4">155</oasis:entry>

         <oasis:entry colname="col5">0.08–0.24 (0.11)<inline-formula><mml:math id="M67" display="inline"><mml:msup><mml:mi/><mml:mtext>c</mml:mtext></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col6">Yes</oasis:entry>

         <oasis:entry colname="col7">64–92</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col2">2nd</oasis:entry>

         <oasis:entry colname="col3"><inline-formula><mml:math id="M68" display="inline"><mml:mrow><mml:mn mathvariant="normal">12</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">382</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col4">139</oasis:entry>

         <oasis:entry colname="col5"><inline-formula><mml:math id="M69" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.17–0.26 (0.09)<inline-formula><mml:math id="M70" display="inline"><mml:msup><mml:mi/><mml:mtext>c</mml:mtext></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col6">Yes</oasis:entry>

         <oasis:entry colname="col7">20</oasis:entry>

       </oasis:row>
       <oasis:row rowsep="1">

         <oasis:entry colname="col2">3rd</oasis:entry>

         <oasis:entry colname="col3"><inline-formula><mml:math id="M71" display="inline"><mml:mrow><mml:mn mathvariant="normal">11</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">102</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col4">116</oasis:entry>

         <oasis:entry colname="col5"><inline-formula><mml:math id="M72" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.08–0.06 (0.07)<inline-formula><mml:math id="M73" display="inline"><mml:msup><mml:mi/><mml:mtext>c</mml:mtext></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col6">No</oasis:entry>

         <oasis:entry colname="col7">–</oasis:entry>

       </oasis:row>
       <oasis:row>

         <?xmltex \rotentry?><oasis:entry colname="col1" morerows="3">Diffuse</oasis:entry>

         <oasis:entry colname="col2">1st</oasis:entry>

         <oasis:entry colname="col3">–</oasis:entry>

         <oasis:entry colname="col4">150</oasis:entry>

         <oasis:entry colname="col5">2.99–4.52 (0.22)<inline-formula><mml:math id="M74" display="inline"><mml:msup><mml:mi/><mml:mtext>c</mml:mtext></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col6">Yes</oasis:entry>

         <oasis:entry colname="col7">20</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col2">2nd</oasis:entry>

         <oasis:entry colname="col3">–</oasis:entry>

         <oasis:entry colname="col4">266</oasis:entry>

         <oasis:entry colname="col5">3.54–4.71 (0.17)<inline-formula><mml:math id="M75" display="inline"><mml:msup><mml:mi/><mml:mtext>c</mml:mtext></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col6">Yes</oasis:entry>

         <oasis:entry colname="col7">20, 62</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col2">3rd</oasis:entry>

         <oasis:entry colname="col3">–</oasis:entry>

         <oasis:entry colname="col4">150</oasis:entry>

         <oasis:entry colname="col5">3.31–4.36 (0.17)<inline-formula><mml:math id="M76" display="inline"><mml:msup><mml:mi/><mml:mtext>c</mml:mtext></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col6">Yes</oasis:entry>

         <oasis:entry colname="col7">36</oasis:entry>

       </oasis:row>
       <oasis:row>

         <oasis:entry colname="col2">4th</oasis:entry>

         <oasis:entry colname="col3">–</oasis:entry>

         <oasis:entry colname="col4">600</oasis:entry>

         <oasis:entry colname="col5">1.37–3.17 (0.39)<inline-formula><mml:math id="M77" display="inline"><mml:msup><mml:mi/><mml:mtext>c</mml:mtext></mml:msup></mml:math></inline-formula></oasis:entry>

         <oasis:entry colname="col6">Yes</oasis:entry>

         <oasis:entry colname="col7">50, 78</oasis:entry>

       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table><table-wrap-foot><p id="d1e910"><inline-formula><mml:math id="M59" display="inline"><mml:msup><mml:mi/><mml:mtext>a</mml:mtext></mml:msup></mml:math></inline-formula> For 90 % of the data.
<inline-formula><mml:math id="M60" display="inline"><mml:msup><mml:mi/><mml:mtext>b</mml:mtext></mml:msup></mml:math></inline-formula> Mean of the maximum values per frame over time
<inline-formula><mml:math id="M61" display="inline"><mml:msup><mml:mi/><mml:mtext>c</mml:mtext></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M62" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula> value of <inline-formula><mml:math id="M63" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">0.001</mml:mn></mml:mrow></mml:math></inline-formula> according to a Wilcoxon rank sum test,
testing the significance of the peak values against non-peak values.</p></table-wrap-foot></table-wrap>

<?xmltex \hack{\newpage}?>
<sec id="Ch1.S4.SS1.SSS1">
  <title>Spatio-temporal behaviour of focused SGD spots</title>
      <p id="d1e1335">The middle column of Fig. 5  shows the time series of NTR values along each
SGD transect. Furthermore, SGD spot boundaries are indicated (white lines <inline-formula><mml:math id="M78" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> maximum
gradients of each transect profile), which provide an orientation
for the spatio-temporal behaviour of each spot. The focus is set on the area
in between the boundaries representing the area in which SGD governs the
thermal radiation distribution. In the case of the first focused SGD spot
that corresponds to sampled spring <inline-formula><mml:math id="M79" display="inline"><mml:mrow><mml:mn mathvariant="normal">11</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">101</mml:mn></mml:mrow></mml:math></inline-formula>, the location is rather stable with its centre between transect pixel 18 and 23 (spatial shift of <inline-formula><mml:math id="M80" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">0.65</mml:mn></mml:mrow></mml:math></inline-formula> m). In contrast, its boundaries
are highly dynamic resulting in a varying distance between 20 and 31 pixels
(2.6 to 4.0 m respectively; for 90 % of the data) and thus a change of
155 % (Table 1). This dynamic partially follows a certain trend during
which both boundaries (white lines) show a synchronous directional change
over a certain period (e.g. frame 150–400). Within the SGD spot, NTR values
peak around the transect centre and decrease towards both boundaries. This
peak is higher during the first 300 frames, with NTR values of 0.24, and
decreases slightly between frames 300 to 500 to values of 0.08 before it
increases to values around 0.18 for the remaining frames.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5" specific-use="star"><label>Figure 5</label><caption><p id="d1e1369">Analyses of spatio-temporal behaviour and potential periodicity of
SGD spots are presented. Panels <bold>(a), (d), (g)</bold> show transects across the maximum
extent and midpoint position of the SGD spot (subsets correspond to the red
boxes shown in Fig. 3; note that the spatial scale varies between each spot
indicated through the scale bar at the lower left of each subset). Panels <bold>(b), (e), (h)</bold> show the normalized thermal radiance (NTR) values along
transects over time. The white lines indicate the boundary of the focused
SGD spots. Panels <bold>(c), (f), (i)</bold> show the temporal autocorrelation of the NTR
values along the entire time series obtained at the midpoint of the transect as
described in Sect. 2 to detect possible periodicities.</p></caption>
            <?xmltex \igopts{width=497.923228pt}?><graphic xlink:href="https://hess.copernicus.org/articles/23/1375/2019/hess-23-1375-2019-f05.jpg"/>

          </fig>

      <p id="d1e1387">The centre of the second focused SGD spot, which corresponds to sampled
spring <inline-formula><mml:math id="M81" display="inline"><mml:mrow><mml:mn mathvariant="normal">12</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">382</mml:mn></mml:mrow></mml:math></inline-formula>, shifts between transect pixels 40 and 45 (<inline-formula><mml:math id="M82" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">0.65</mml:mn></mml:mrow></mml:math></inline-formula> m),
indicating similar stable conditions. The boundary behaviour differs
slightly from the first focused SGD spot. The lower boundary is rather
stable, fluctuating around transect pixel 70, whereas the upper<?pagebreak page1382?> boundary
describes on average a wave-like change between frames 1 and 300 before
displaying a stable fluctuation around transect pixel 20. The resulting
diameter of the second focused SGD spot is therefore between 43 and 60 pixels
(5.59 to 7.8 m; for 90 % of the data) and thus shows a change of
139 % (Table 1). Compared to the first focused SGD spot, the absolute peak
values of the second focused SGD spot of <inline-formula><mml:math id="M83" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.26</mml:mn></mml:mrow></mml:math></inline-formula> and their general trend over
time are lower. They display a rather random behaviour over all frames, with
the exception of frames 485 to 520, during which the peak values (around
<inline-formula><mml:math id="M84" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.17</mml:mn></mml:mrow></mml:math></inline-formula>) are higher.</p>
      <p id="d1e1432">The location of the third focused SGD spot, which corresponds to sampled
spring <inline-formula><mml:math id="M85" display="inline"><mml:mrow><mml:mn mathvariant="normal">11</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">102</mml:mn></mml:mrow></mml:math></inline-formula>, centres between transect pixels 15 to 20. The spot's
boundaries are stable during the first 200 frames, where they display a
synchronous directional change similar to the first focused SGD spot. For
the remaining frames, the lower boundary is highly dynamic and totally
random while the upper is rather stable with less fluctuation until frame
350. The resulting boundary distance within the first 200 frames is between
18 and 21 pixels (2.34 and 2.73 m respectively; for 90 % of the data) and
thus resembles a change of 116 % (Table 1). The peak values of <inline-formula><mml:math id="M86" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.08</mml:mn></mml:mrow></mml:math></inline-formula> to
0.06 resemble those of the first and to a lesser extent those of the second
focused SGD spot. Over time, they exhibit a similar random behaviour over
all frames, with the exception of frames 485 to 520, during which the peak
values are higher at 0.06.</p>
</sec>
<sec id="Ch1.S4.SS1.SSS2">
  <title>Spatio-temporal behaviour of diffuse SGD spots</title>
      <?pagebreak page1383?><p id="d1e1464">Analogous to the focused SGD spots, the middle column of Fig. 6 shows time
series of the NTR values along the transects of each diffuse SGD spot to
illuminate the spatio-temporal discharge behaviour. Apparent for the first,
second, and third diffuse SGD spots are higher NTR values <inline-formula><mml:math id="M87" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:math></inline-formula> for
a constant transect length of 5–8 pixels (0.65–1.02 m) starting at the
shoreline. Only the fourth diffuse SGD spot exhibits no constantly elevated
NTR values over the entire observation time close to the shoreline. All
spots show outburst-like events during which NTR values <inline-formula><mml:math id="M88" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:math></inline-formula>
occur. Among all spots, the onsets and influence lengths of these outburst events
vary. While for the first spot the average influence length reaches 20 pixels (<inline-formula><mml:math id="M89" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mn mathvariant="normal">2.60</mml:mn></mml:mrow></mml:math></inline-formula> m)
for NTR values <inline-formula><mml:math id="M90" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:math></inline-formula>, the average length of the
second is 33 pixels (<inline-formula><mml:math id="M91" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mn mathvariant="normal">4.29</mml:mn></mml:mrow></mml:math></inline-formula> m). The third has a length of 20 pixels
(2.60 m) and the fourth only 7 pixels (0.91 m). Consequently, the percentage
change of the influence length axis is between 150 % for the first and
third diffuse SGD spot, but amounts to 266 % for the second spot, and
reaches up to 600 % for the fourth spot.</p>
</sec>
</sec>
<sec id="Ch1.S4.SS2">
  <title>Periodicity analysis</title>
      <p id="d1e1525">The previous spatio-temporal behaviour already pointed at a certain
recurrence pattern of the observed thermal radiation but lacked a distinct
statement on whether or not it contains a significant periodicity and thus a
dominating force inducing it. In order to provide an unequivocally and
temporally pristine discharge signal, we analyse its temporal pattern based
on a single pixel of each transect (midpoint of the transect) using a
temporal autocorrelation analysis (right columns in Figs. 5 and 6
respectively).</p>
<sec id="Ch1.S4.SS2.SSS1">
  <title>Periodicity of focused SGD spots</title>
      <p id="d1e1533">Temporal autocorrelation of the first focused SGD spot distinctively differs
from the second and third focused SGD spots. The first spot shows a small
but significant negative autocorrelation of <inline-formula><mml:math id="M92" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.25</mml:mn></mml:mrow></mml:math></inline-formula> between lags (frames) 268
and 367<?pagebreak page1384?> (64–92 s), indicating a recurring pattern and hence a certain
periodicity (Fig. 5). This observation matches the aforementioned peak value
shift from 0.24 to 0.08 in the same frame region. The second focused SGD
spot shows a small positive autocorrelation of 0.21 at lag (frame) 80, while
remaining peaks vary in both directions, but below the confidence intervals.
Both facts are distinctively different from the autocorrelation of the first
focused SGD spot, but resemble the autocorrelation function of the third SGD
spot, whose peaks are exclusively insignificant and reflect no periodicity
indication.</p>
</sec>
<sec id="Ch1.S4.SS2.SSS2">
  <title>Periodicity of diffuse SGD spots</title>
      <p id="d1e1552">Time series plots (middle column in Fig. 6) indicate a regular recurrence of
thermal radiation values. This behaviour is underlined by the temporal
autocorrelation of all diffuse SGD spots, which show a significant temporal
autocorrelation that occurs at different lags and with mostly different
intensities. While the first diffuse SGD spot exhibits only one significant
period at lag 81 (20 s), the second spot shows two, one at lag 81 and a
second one at lag 247 (62 s). Despite the spatial proximity of ca. 5 m to
the first two diffuse SGD spots, the third diffuse SGD spot shows a
different temporal autocorrelation, with one significant peak at lag 143 (36 s). Also
different is the fourth spot, which exhibits two peaks at lag 198 (50 s)
and lag 314 (78 s). All plots in the right column contain a reference
autocorrelation function of a pixel close to the source point at the
shoreline (transect pixel three). This reference shows high-frequency
behaviour unlike the temporal, diffuse SGD, induced thermal radiation
behaviour described before (except for the last diffuse SGD spot).</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F6" specific-use="star"><label>Figure 6</label><caption><p id="d1e1557">Analyses of spatio-temporal behaviour and potential periodicity of
diffuse SGD spots are presented. Spot locations are outlined in Figs. 1 and
3, indicated by the location of the counter rotating vortex pairs (CVPs).
The first column shows transects across the maximum extent and midpoint
position of diffuse SGD spots (note that the spatial scale varies between
each spot indicated through the scale bar at the lower left of each subset).
The middle column shows the normalized thermal radiance (NTR) values along
transects over time. The third column shows the temporal autocorrelation of
NTR values along the entire time series obtained at the midpoint of the
transect. Those points reflect the most unaltered discharge signals (the
larger value). As reference, we show the third transect pixel (close to the
shoreline) as well in order to outline the wave influence on the
periodicity.</p></caption>
            <?xmltex \igopts{width=497.923228pt}?><graphic xlink:href="https://hess.copernicus.org/articles/23/1375/2019/hess-23-1375-2019-f06.jpg"/>

          </fig>

<?xmltex \floatpos{p}?><table-wrap id="Ch1.T2" specific-use="star" orientation="landscape"><label>Table 2</label><caption><p id="d1e1569">Water chemistry of all sampled focused SGD and onshore
springs (some springs are located next to the study area and not shown in
Fig. 1), along with the results from the inverse geochemical modelling and
the volumetric calculation. Note that the volumetric calculation is based on
the molar volume of halite (29.24 cm<inline-formula><mml:math id="M93" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> mol<inline-formula><mml:math id="M94" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>), aragonite
(34.17 cm<inline-formula><mml:math id="M95" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> mol<inline-formula><mml:math id="M96" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) and gypsum (74.29 cm<inline-formula><mml:math id="M97" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> mol<inline-formula><mml:math id="M98" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>). Also note that the information given here
represents a summary of the most important information. Full details are
given in Table S2 in the Supplement.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="13">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right" colsep="1"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:colspec colnum="9" colname="col9" align="right" colsep="1"/>
     <oasis:colspec colnum="10" colname="col10" align="right"/>
     <oasis:colspec colnum="11" colname="col11" align="right"/>
     <oasis:colspec colnum="12" colname="col12" align="right"/>
     <oasis:colspec colnum="13" colname="col13" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry rowsep="1" namest="col2" nameend="col5" align="center" colsep="1">Analytical results </oasis:entry>
         <oasis:entry rowsep="1" namest="col6" nameend="col9" align="center" colsep="1">Modelling results </oasis:entry>
         <oasis:entry rowsep="1" namest="col10" nameend="col13" align="center">Volumetric calculation </oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M99" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">pH</oasis:entry>
         <oasis:entry colname="col4">TDS</oasis:entry>
         <oasis:entry colname="col5">Density</oasis:entry>
         <oasis:entry colname="col6">Interstitial</oasis:entry>
         <oasis:entry colname="col7">Halite</oasis:entry>
         <oasis:entry colname="col8">Aragonite</oasis:entry>
         <oasis:entry colname="col9">Gypsum</oasis:entry>
         <oasis:entry colname="col10">Halite</oasis:entry>
         <oasis:entry colname="col11">Aragonite</oasis:entry>
         <oasis:entry colname="col12">Gypsum</oasis:entry>
         <oasis:entry colname="col13">Sum</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">(<inline-formula><mml:math id="M100" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)</oasis:entry>
         <oasis:entry colname="col3">(–)</oasis:entry>
         <oasis:entry colname="col4">(g L<inline-formula><mml:math id="M101" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col5">(g cm<inline-formula><mml:math id="M102" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col6">Brine</oasis:entry>
         <oasis:entry colname="col7">(mol kgw<inline-formula><mml:math id="M103" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col8">(mol kgw<inline-formula><mml:math id="M104" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col9">(mol kgw<inline-formula><mml:math id="M105" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col10">(cm<inline-formula><mml:math id="M106" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> m<inline-formula><mml:math id="M107" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col11">(cm<inline-formula><mml:math id="M108" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> m<inline-formula><mml:math id="M109" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col12">(cm<inline-formula><mml:math id="M110" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> m<inline-formula><mml:math id="M111" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col13"/>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3"/>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"/>
         <oasis:entry colname="col6">(kg)</oasis:entry>
         <oasis:entry colname="col7"/>
         <oasis:entry colname="col8"/>
         <oasis:entry colname="col9"/>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M112" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">H</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col11"><inline-formula><mml:math id="M113" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">H</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col12"><inline-formula><mml:math id="M114" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">H</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col13"/>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row rowsep="1">
         <oasis:entry namest="col1" nameend="col13">Interstitial brine </oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">35.6</oasis:entry>
         <oasis:entry colname="col3">5.38</oasis:entry>
         <oasis:entry colname="col4">345</oasis:entry>
         <oasis:entry colname="col5">1.23</oasis:entry>
         <oasis:entry colname="col6"/>
         <oasis:entry colname="col7"/>
         <oasis:entry colname="col8"/>
         <oasis:entry colname="col9"/>
         <oasis:entry colname="col10"/>
         <oasis:entry colname="col11"/>
         <oasis:entry colname="col12"/>
         <oasis:entry colname="col13"/>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry namest="col1" nameend="col13">Onshore springs </oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M115" display="inline"><mml:mrow><mml:mn mathvariant="normal">09</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">854</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">27.9</oasis:entry>
         <oasis:entry colname="col3">7.20</oasis:entry>
         <oasis:entry colname="col4">7.3</oasis:entry>
         <oasis:entry colname="col5">1.00</oasis:entry>
         <oasis:entry colname="col6">0.012</oasis:entry>
         <oasis:entry colname="col7">0.0123</oasis:entry>
         <oasis:entry colname="col8">0.0017</oasis:entry>
         <oasis:entry colname="col9">0.0017</oasis:entry>
         <oasis:entry colname="col10">359.5</oasis:entry>
         <oasis:entry colname="col11">59.5</oasis:entry>
         <oasis:entry colname="col12">125.7</oasis:entry>
         <oasis:entry colname="col13">544.7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M116" display="inline"><mml:mrow><mml:mn mathvariant="normal">09</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">855</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">28.5</oasis:entry>
         <oasis:entry colname="col3">7.12</oasis:entry>
         <oasis:entry colname="col4">26.0</oasis:entry>
         <oasis:entry colname="col5">1.00</oasis:entry>
         <oasis:entry colname="col6">0.049</oasis:entry>
         <oasis:entry colname="col7">0</oasis:entry>
         <oasis:entry colname="col8">0.0017</oasis:entry>
         <oasis:entry colname="col9">0.0201</oasis:entry>
         <oasis:entry colname="col10">0</oasis:entry>
         <oasis:entry colname="col11">59.4</oasis:entry>
         <oasis:entry colname="col12">1493.0</oasis:entry>
         <oasis:entry colname="col13">1552.4</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M117" display="inline"><mml:mrow><mml:mn mathvariant="normal">09</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">856</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">28.1</oasis:entry>
         <oasis:entry colname="col3">7.16</oasis:entry>
         <oasis:entry colname="col4">15.6</oasis:entry>
         <oasis:entry colname="col5">1.00</oasis:entry>
         <oasis:entry colname="col6">0.028</oasis:entry>
         <oasis:entry colname="col7">0</oasis:entry>
         <oasis:entry colname="col8">0.0019</oasis:entry>
         <oasis:entry colname="col9">0.0087</oasis:entry>
         <oasis:entry colname="col10">0</oasis:entry>
         <oasis:entry colname="col11">65.3</oasis:entry>
         <oasis:entry colname="col12">649.4</oasis:entry>
         <oasis:entry colname="col13">714.7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M118" display="inline"><mml:mrow><mml:mn mathvariant="normal">09</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">857</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">27.6</oasis:entry>
         <oasis:entry colname="col3">7.11</oasis:entry>
         <oasis:entry colname="col4">21.2</oasis:entry>
         <oasis:entry colname="col5">1.00</oasis:entry>
         <oasis:entry colname="col6">0.039</oasis:entry>
         <oasis:entry colname="col7">0</oasis:entry>
         <oasis:entry colname="col8">0.0017</oasis:entry>
         <oasis:entry colname="col9">0</oasis:entry>
         <oasis:entry colname="col10">0</oasis:entry>
         <oasis:entry colname="col11">59.0</oasis:entry>
         <oasis:entry colname="col12">0.0</oasis:entry>
         <oasis:entry colname="col13">59.0</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"><inline-formula><mml:math id="M119" display="inline"><mml:mrow><mml:mn mathvariant="normal">09</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">858</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">27.6</oasis:entry>
         <oasis:entry colname="col3">7.48</oasis:entry>
         <oasis:entry colname="col4">6.4</oasis:entry>
         <oasis:entry colname="col5">1.00</oasis:entry>
         <oasis:entry colname="col6">0.011</oasis:entry>
         <oasis:entry colname="col7">0.0071</oasis:entry>
         <oasis:entry colname="col8">0.0020</oasis:entry>
         <oasis:entry colname="col9">0.0016</oasis:entry>
         <oasis:entry colname="col10">208.3</oasis:entry>
         <oasis:entry colname="col11">69.5</oasis:entry>
         <oasis:entry colname="col12">119.8</oasis:entry>
         <oasis:entry colname="col13">397.6</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry namest="col1" nameend="col13">Focused SGD </oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M120" display="inline"><mml:mrow><mml:mn mathvariant="normal">11</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">120</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">29.6</oasis:entry>
         <oasis:entry colname="col3">7.25</oasis:entry>
         <oasis:entry colname="col4">15.8</oasis:entry>
         <oasis:entry colname="col5">1.00</oasis:entry>
         <oasis:entry colname="col6">0.030</oasis:entry>
         <oasis:entry colname="col7">0</oasis:entry>
         <oasis:entry colname="col8">0.0025</oasis:entry>
         <oasis:entry colname="col9">0.0071</oasis:entry>
         <oasis:entry colname="col10">0</oasis:entry>
         <oasis:entry colname="col11">85.5</oasis:entry>
         <oasis:entry colname="col12">527.1</oasis:entry>
         <oasis:entry colname="col13">612.6</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M121" display="inline"><mml:mrow><mml:mn mathvariant="normal">10</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">30</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">28.0</oasis:entry>
         <oasis:entry colname="col3">6.75</oasis:entry>
         <oasis:entry colname="col4">9.5</oasis:entry>
         <oasis:entry colname="col5">1.00</oasis:entry>
         <oasis:entry colname="col6">0.201</oasis:entry>
         <oasis:entry colname="col7">0</oasis:entry>
         <oasis:entry colname="col8">0</oasis:entry>
         <oasis:entry colname="col9">0.0011</oasis:entry>
         <oasis:entry colname="col10">0</oasis:entry>
         <oasis:entry colname="col11">0</oasis:entry>
         <oasis:entry colname="col12">79.8</oasis:entry>
         <oasis:entry colname="col13">79.8</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M122" display="inline"><mml:mrow><mml:mn mathvariant="normal">12</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">382</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">31.5</oasis:entry>
         <oasis:entry colname="col3">7.27</oasis:entry>
         <oasis:entry colname="col4">8.7</oasis:entry>
         <oasis:entry colname="col5">1.00</oasis:entry>
         <oasis:entry colname="col6">0.015</oasis:entry>
         <oasis:entry colname="col7">0.0056</oasis:entry>
         <oasis:entry colname="col8">0.0021</oasis:entry>
         <oasis:entry colname="col9">0.0024</oasis:entry>
         <oasis:entry colname="col10">163.4</oasis:entry>
         <oasis:entry colname="col11">73.3</oasis:entry>
         <oasis:entry colname="col12">177.3</oasis:entry>
         <oasis:entry colname="col13">414.0</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M123" display="inline"><mml:mrow><mml:mn mathvariant="normal">11</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">126</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">30.0</oasis:entry>
         <oasis:entry colname="col3">7.37</oasis:entry>
         <oasis:entry colname="col4">4.9</oasis:entry>
         <oasis:entry colname="col5">1.00</oasis:entry>
         <oasis:entry colname="col6">0.008</oasis:entry>
         <oasis:entry colname="col7">0.0051</oasis:entry>
         <oasis:entry colname="col8">0.0021</oasis:entry>
         <oasis:entry colname="col9">0.0012</oasis:entry>
         <oasis:entry colname="col10">150.0</oasis:entry>
         <oasis:entry colname="col11">71.6</oasis:entry>
         <oasis:entry colname="col12">88.0</oasis:entry>
         <oasis:entry colname="col13">309.6</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M124" display="inline"><mml:mrow><mml:mn mathvariant="normal">11</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">101</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">24.0</oasis:entry>
         <oasis:entry colname="col3">7.16</oasis:entry>
         <oasis:entry colname="col4">12.8</oasis:entry>
         <oasis:entry colname="col5">1.00</oasis:entry>
         <oasis:entry colname="col6">0.022</oasis:entry>
         <oasis:entry colname="col7">0.0109</oasis:entry>
         <oasis:entry colname="col8">0.0036</oasis:entry>
         <oasis:entry colname="col9">0.0034</oasis:entry>
         <oasis:entry colname="col10">319.3</oasis:entry>
         <oasis:entry colname="col11">122.3</oasis:entry>
         <oasis:entry colname="col12">254.8</oasis:entry>
         <oasis:entry colname="col13">696.5</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M125" display="inline"><mml:mrow><mml:mn mathvariant="normal">11</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">102</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">26.6</oasis:entry>
         <oasis:entry colname="col3">7.24</oasis:entry>
         <oasis:entry colname="col4">13.9</oasis:entry>
         <oasis:entry colname="col5">1.00</oasis:entry>
         <oasis:entry colname="col6">0.025</oasis:entry>
         <oasis:entry colname="col7">0.0125</oasis:entry>
         <oasis:entry colname="col8">0.0032</oasis:entry>
         <oasis:entry colname="col9">0.0037</oasis:entry>
         <oasis:entry colname="col10">365.6</oasis:entry>
         <oasis:entry colname="col11">110.3</oasis:entry>
         <oasis:entry colname="col12">273.8</oasis:entry>
         <oasis:entry colname="col13">749.7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M126" display="inline"><mml:mrow><mml:mn mathvariant="normal">11</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">121</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">21.0</oasis:entry>
         <oasis:entry colname="col3">7.08</oasis:entry>
         <oasis:entry colname="col4">24.8</oasis:entry>
         <oasis:entry colname="col5">1.00</oasis:entry>
         <oasis:entry colname="col6">0.048</oasis:entry>
         <oasis:entry colname="col7">0</oasis:entry>
         <oasis:entry colname="col8">0.0018</oasis:entry>
         <oasis:entry colname="col9">0</oasis:entry>
         <oasis:entry colname="col10">0</oasis:entry>
         <oasis:entry colname="col11">62.4</oasis:entry>
         <oasis:entry colname="col12">0</oasis:entry>
         <oasis:entry colname="col13">62.4</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

</sec>
</sec>
<sec id="Ch1.S4.SS3">
  <title>Water chemistry and inverse geochemical modelling</title>
      <p id="d1e2689">The samples focused on SGD and onshore springs discharge with a temperature
between 21 to 31.5 <inline-formula><mml:math id="M127" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. Though the groundwater of both focused SGD
and onshore springs originates from the freshwater JGA, the springs
discharge brackish water with salinities (TDS) ranging between 4.87 and
26.0 g L<inline-formula><mml:math id="M128" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> with the tendency to be on average less saline onshore (TDS <inline-formula><mml:math id="M129" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 12.8 g L<inline-formula><mml:math id="M130" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)
compared to the focused SGD (TDS <inline-formula><mml:math id="M131" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 20.1 g L<inline-formula><mml:math id="M132" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>). The inverse geochemical
modelling results indicate halite, aragonite and gypsum to be the most
important minerals in solution, though ion exchange on clay minerals plays a
significant role. Although discharge locations are very close, the amounts of
dissolved halite (0–0.01 mol kg<inline-formula><mml:math id="M133" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M134" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">H</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>), aragonite (0–0.004 mol kg<inline-formula><mml:math id="M135" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>
<inline-formula><mml:math id="M136" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">H</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>) and gypsum (0–0.02 mol kg<inline-formula><mml:math id="M137" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M138" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">H</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>) vary significantly between the
different springs (Table 2). Translated into cavitation rates, emerging
groundwater dissolves and relocates about 59.0–1.552.4 cm<inline-formula><mml:math id="M139" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> of halite,
aragonite and gypsum per cubic metre from the passed branches of the
groundwater flow net into the Dead Sea. Following the above-mentioned
approach, those springs with the lowest water–rock interactions, which
consequently emerge from the most mature karst pipes, are springs <inline-formula><mml:math id="M140" display="inline"><mml:mrow><mml:mn mathvariant="normal">09</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">857</mml:mn></mml:mrow></mml:math></inline-formula>,
<inline-formula><mml:math id="M141" display="inline"><mml:mrow><mml:mn mathvariant="normal">10</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">30</mml:mn></mml:mrow></mml:math></inline-formula>, and <inline-formula><mml:math id="M142" display="inline"><mml:mrow><mml:mn mathvariant="normal">11</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">121</mml:mn></mml:mrow></mml:math></inline-formula>, which all have values <inline-formula><mml:math id="M143" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">79.8</mml:mn></mml:mrow></mml:math></inline-formula> cm<inline-formula><mml:math id="M144" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> of halite,
aragonite and gypsum per cubic metre of water. In contrast, springs <inline-formula><mml:math id="M145" display="inline"><mml:mrow><mml:mn mathvariant="normal">09</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">855</mml:mn></mml:mrow></mml:math></inline-formula>,
<inline-formula><mml:math id="M146" display="inline"><mml:mrow><mml:mn mathvariant="normal">09</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">856</mml:mn></mml:mrow></mml:math></inline-formula> or <inline-formula><mml:math id="M147" display="inline"><mml:mrow><mml:mn mathvariant="normal">11</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">102</mml:mn></mml:mrow></mml:math></inline-formula> possess values <inline-formula><mml:math id="M148" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">714.7</mml:mn></mml:mrow></mml:math></inline-formula> cm<inline-formula><mml:math id="M149" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> of
halite, aragonite and gypsum per cubic metre water, which proves a higher
water–rock interaction and thus intense dissolution activity that can only
occur in less mature karst pipes (Table 2). Focused SGD spots reflect values
of 696.5 and 749.7 cm<inline-formula><mml:math id="M150" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> (first and third spot respectively)
and thus a less mature karst system, while the second focused SGD spot has
the lowest value of 414.0 cm<inline-formula><mml:math id="M151" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> of halite, aragonite and
gypsum per cubic metre of water and thus emerges from a more mature karst
system.</p>
</sec>
</sec>
<sec id="Ch1.S5">
  <title>Discussion</title>
      <p id="d1e2975">The high spatial and temporal resolutions of the thermal radiation data show
a highly dynamic setting with various discharge locations, patterns, and
forces. Analysing the spatio-temporal behaviour of each SGD spot independent
of its type reveals striking details: (i) it enhances focused SGD patterns
otherwise being camouflaged by strong lateral flow dynamics and sheds light
on crossflow influences, (ii) the spatio-temporal behaviour shows a thermal
SGD pattern size variation over time of up to 155 % for focused SGDs and
600 % for diffuse SGDs due to different flow dynamics, and (iii) it reveals
a periodicity for diffuse SGD. We discuss these aspects in the following
sections and outline possible driving forces or causes, and we conclude with
potentials for and limitations of the presented approach, including possible
transferability to other locations.</p>
<sec id="Ch1.S5.SS1">
  <title>Enhancing focused SGD</title>
      <p id="d1e2983">Deriving unequivocal SGD indications from single frames such as in Fig. 3 is
not trivial, especially in a highly dynamic system as the one presented. For
the present case, we suggest the following causes to be relevant:
<list list-type="custom"><list-item><label>i.</label>
      <p id="d1e2988">lateral flow dynamics induced by diffuse discharge with higher
temperatures (see point ii) govern the investigated area and superimpose
thermal radiance signals from vertical flow of focused SGD as mentioned in
Mallast et al. (2013a);</p></list-item><list-item><label>ii.</label>
      <p id="d1e2992">entrainment of ambient water during the turbulent ascent (buoyant jet)
of groundwater to the sea surface (Jirka, 2004) leads to a consequential
adaption of temperature and thus the emitted thermal radiance; and</p></list-item><list-item><label>iii.</label>
      <p id="d1e2996">potential groundwater discharge fluctuation with possibly very small
to stagnant discharge rates, as described in Ionescu et al. (2012) for the
presented site at the moment of recording, which lead to no traceable
thermal radiance signal from SGD at the sea surface.</p></list-item></list>
However, the above-mentioned possible relevant causes are all dynamic in
spatial and temporal terms. Thus, accounting for the fact of a thermal
stabilization at the sea surface as a consequence of a continuous discharge
of equally tempered groundwater (Siebert et al., 2014) reveals thermally
stable areas induced by SGD that might otherwise be undetectable. The
thermal stabilization is accompanied by the interplay of fluid movements
(lateral vs. vertical flow kinetics) and thus results in developing water
surface geometries (wave structures), e.g. at the interface of opposing
water flows. Surface geometries have an effect on the recorded thermal
radiances due to the directional dependence of the surface emissivity
(Norman and Becker, 1995; Cheng and Liang, 2014). Wave fronts, for example,
with surfaces being orthogonal to the sensor (0<inline-formula><mml:math id="M152" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>), would have the
highest thermal radiance values. As the angle to the sensor increases,
recorded thermal radiances decrease, although the sea surface temperature is
the same (Cheng and Liang, 2014). Thus, the temporal effects through thermal
stabilization and changing surface geometries as a consequence of flow
dynamics are the two governing drivers, which allow easy detection of
focused SGD through the integration of thermal radiation over longer time
periods. According to our findings, the thermal radiance variance over a
period of 25 s  (100 frames) already provides a sufficient basis to outline
SGD areas (Fig. 2). Integrating over longer time periods emphasizes SGD
areas, which consequently confirms the thermal radiance stabilization over
time at the sea surface of a SGD-affected area (Siebert et al., 2014).</p>
      <p id="d1e3009">Apart from enhancing focused SGD occurrences, the shape of the focused SGD
variance pattern at the sea surface along with the location of the lowest
variance values (area most thermally stable) gives an indication of SGD
emergence locations and the deflection of the resulting vertical plume until
it reaches the sea surface. None of the three are perfectly circular, which
would indicate an uninfluenced positive buoyancy of discharging water and a
SGD emergence directly beneath the centre of the variance pattern (Jirka,
2004). Instead, they are all more or less elliptical, with the lowest variance
values at the southern ends (first and second focused SGD spot) and at the
northern ends (third focused SGD spot). The remarkable elliptical shape of
the first focussed SGD spot implies a crossflow from the south causing a
northward deflection of the vertical SGD plume and an elliptic shape of the
horizontal plume pattern at the sea surface (Akar and Jirka, 1995). Less
pronounced elliptical shapes but with the same northward deflection trend
exhibit the second and third focused SGD spot. The northward deflection is
most likely induced by flow dynamics as a consequence of diffuse SGD. Since
the location of the diffuse SGD spots, especially those with distinctively
periodic events with higher discharge rates (Fig. 3), is directly SSW and
shows the same northward horizontal plume orientation, we suggest this
discharge is the driving force for the deflection.</p>
</sec>
<?pagebreak page1387?><sec id="Ch1.S5.SS2">
  <title>Spatio-temporal behaviour of SGD patterns</title>
      <p id="d1e3018">The variance image provides an average representation of all SGD spots,
which are especially useful for reliable size–discharge comparison purposes
between SGD spots and likewise allow SGD spots to be outlined. However, as the
previous section points out, all are subject to external forces such as
currents, waves, and the influence of internal discharge dynamics on
resulting pattern shape and size characteristics of the thermal radiance
pattern over time.</p>
      <p id="d1e3021">For focused SGD, the observed thermal radiance pattern sizes (distance
between boundaries) over time show a spatial variation between 116 %
(<inline-formula><mml:math id="M153" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mn mathvariant="normal">2.3</mml:mn></mml:mrow></mml:math></inline-formula> m for the first focused SGD spot) and 155 % (<inline-formula><mml:math id="M154" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mn mathvariant="normal">4.0</mml:mn></mml:mrow></mml:math></inline-formula> m for the
third focused SGD spot) as shown in Fig. 5. The variance is a result of
occurring lateral flow dynamics constantly influencing the pattern on the
sea surface. Yet, the influence is anisotropic in space and time as the
lateral flow dynamics are dominated by waves coming from the east and the
interaction of horizontal SGD plumes on the sea surface (e.g. second and
third focused SGD) as described in Teamah and Khairat (2015), but moreover
the strong lateral flow dynamics (crossflow) induced by the discharge
impulses of diffuse SGD that in the following is deflected to the NE. The
interplay and constant temporal changes lead to an asynchronous boundary
movement for most of the observed SGD-induced thermal radiance patterns. Only during the first 200 frames and for the
first and third focused SGD spot did the asynchronous behaviour change to synchronous behaviour. During this time only
one force seems to dominate the dynamic, causing the synchronous behaviour.</p>
      <p id="d1e3044">The SGD-induced thermal radiation pattern size variation is different for
the observed diffuse SGD spots. While three out of four spots constantly
influence a longshore area of 5–8 pixels (0.65–1.04 m), outburst-like events
change the cross-shore influence length between 150 % and 600 % and between 0.60 and 4.29 m
(Fig. 6). The constant influence reflects a continuous diffuse discharge
with lower discharge rates. The latter, however, shows a focused flow with
intermittent higher discharge rates. Higher discharge rates induce a higher
momentum and consequentially increase the influenced area off the discharge
spot. In turn it reveals that karst conduits exist close to the shoreline
and next to diffuse SGD. The intermittency with a seemingly recurring
temporal pattern, however, points to a steady interplay of different forces
that is the subject of the next section.</p>
</sec>
<sec id="Ch1.S5.SS3">
  <title>Periodicity of diffuse SGD</title>
      <p id="d1e3053">For focused SGD spots, we could not reveal a significant periodicity, either
because of the limited observation length or because no periodicity exists.
For diffuse SGD spots, the temporal autocorrelation analysis reveals
significant periodicities. The periodicity of discharge rate events varies
significantly among given spots between 20 and 78 s  (right<?pagebreak page1388?> column in Fig. 6).
It primarily provides a further example of the high temporal discharge
variability over small spatial scales which, normally, is due to tides or
wave set-up that change hydrostatic pressure conditions (Taniguchi et al.,
2003b; Burnett et al., 2006). For the present case, tidal influences are
irrelevant as the tidal cycles do not exist at the study site. Wave
influence on the other hand cannot be excluded, per se. However, most likely
it is not the main cause since observed wave frequency of 3 to 7 s  would
cause high-frequency discharge intermittency of the same magnitude.
Precisely this high frequency is observable in the autocorrelation graphs of
Fig. 6 close to the shoreline (transect pixel 3). Thus, the frequency proves
the minor wave influence on the main discharge events with an observed
frequency that is up to 10 magnitudes larger. Along with the focused
discharge nature, it rather points to an interplay between wave set-up and a
geometry effect within conduits of groundwater flow as the underlying
mechanism as described for karst areas in Smart and Ford (1986). Discharge
behaviour in this case depends on the maturity and geometric formation of
the conduit network. Following Surić et al. (2015) the discharge
behaviour is highly anisotropic and heterogeneous, and features a rapid
flow. The anisotropic and heterogeneous discharge behaviour is furthermore
underlined by the discharge onset and the periodicity that is unequal among
the individual spots, even though their spatial location is within 10 m
distance (Fig. 3).</p>
      <p id="d1e3056">According to the modelling results, groundwater passes the DSG through
several subaquifers as described in Yechieli et al. (2010), and most
probably via conduits, which develop through the fuzzy dissolution of easily
soluble minerals that make up large percentages of the sedimentary body. It
is further assumed, due to the impregnation of the sediment by Dead Sea
brine, that cavitation activity is lower closer and below the
freshwater–saltwater interface, although it exists and leads to abundant
submarine springs. However, groundwater may also reach the Dead Sea through
open faults, which may deeply fracture the sedimentary body as a result of
active rift tectonics. Further preferential groundwater pathways may also be
created through shallow cracks that develop through the relaxation of the
sediment due to the gravitational release of interstitial brine.</p>
      <p id="d1e3059">However, for whatever reason fresh groundwater is allowed to invade the DSG
due to the omnipresent abundance of easily soluble minerals, dissolution
activities will immediately start and will enlarge hydraulic apertures of
the initial pathways through the sedimentary body. Cavitation rates may be
dependent on boundary conditions (e.g. supply of freshwater, hydraulic
gradient and microbial activity), leading to different degrees of conduit
maturity and random conduit–network geometry.</p>
      <p id="d1e3062">Consequently, it is thoroughly possible that an initial anisotropic flow
system is about to develop close to the observed shoreline. In interaction
with the wave set-up, we suggest that such a randomly developed initial flow
system is the cause for the different onsets and influence areas for the
observed outburst-like events.</p>
</sec>
<sec id="Ch1.S5.SS4">
  <title>Potentials, limitations and potential errors</title>
      <p id="d1e3072">The hovering of the UAV over a predefined location and the sensing of
thermal radiation at a rate of 4–5 Hz allows a combination of the continuous
temporal with the continuous spatial scale for SGD research. In this context
it bears an enormous potential as it is possible to provide detailed and
high-resolution information on SGD dynamics but also on external forces
influencing it. The potential includes the high temporal resolution
(sampling intervals), which differs by 1 order of magnitude from
classical in situ measurement intervals of 10<inline-formula><mml:math id="M155" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">1</mml:mn></mml:msup></mml:math></inline-formula>–10<inline-formula><mml:math id="M156" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> min (Cable
et al., 1997; Mulligan and Charette, 2006; Michael et al., 2011), allowing
the illumination of short-term discharge dynamics that could not be
reflected with classical methods. The potential furthermore concerns the
spatio-temporal continuous characteristic of the presented approach. With the
unequivocal indication regarding where diffuse or focused SGD occurs, and
where exactly the transition between SGD and ambient fluids is, the
indication is that proper sampling sites for each of them could not have
been done with a subjective selection of sampling sites. Thus, applying the
presented approach before pursuing in situ sampling (which includes the
selection of proper sampling sites and sampling intervals) is undoubtedly
advantageous.</p>
      <p id="d1e3093">The third potential concerns SGD monitoring and especially SGD
quantification purposes. As mentioned in the Introduction, the basis for SGD
quantification is the size of thermal radiance patterns (plumes) in most
studies (Kelly et al., 2018; Mallast et al., 2013a; Tamborski et al., 2015;
Lee et al., 2016). The presented results show a spatial variation of
150 %–600 %, which indicates the possible uncertainty that underlies a
quantification based on single thermal infrared images. With the presented
approach these uncertainties could be specified, which, in turn, increases
the explanatory power of the quantification.</p>
      <p id="d1e3096">Apart from these potentials, the approach bears limitations and potential
errors that need to be accounted for, if the presented approach is to
be applicable to different locations. The first limitation concerns the need for
rigid image parts, such as land, to be able to pursue a proper image
registration. Equal share of land and water parts, as in the present case,
increases the accuracy and thus reduces the potential error due to an
erroneous intensity-based image registration, but reduces the investigable
area spatially and limits it to areas close to the shoreline. The
shoreline bond could be overcome by using rigidly fixed buoys and mounted
aluminium plates on top as ground control points anchored offshore. While
the investigable area is maximized, the image registration needs to be
changed to a procedure based on control points to determine the image
transformation and thus the registration as<?pagebreak page1389?> described, for example, in
Holman et al. (2017), since the intensity of an image cannot be taken as the
basis.</p>
      <p id="d1e3099">However, independent of the selected approach and the land–water share,
flight altitude and camera lens define the size of the footprint and thus
the spatial coverage. Due to regulatory framework, flight altitudes are
usually restricted, which consequently limits the maximum possible footprint.
Thus the restricted flight altitudes represent another spatial limitation of
the approach.</p>
      <p id="d1e3103">The aforementioned spatial limitations are furthermore accompanied by
temporal limitations and errors. These temporal limitations are given by the
flight times of present-day UAVs that reach up to tens of minutes (Floreano
and Wood, 2015). Continuous investigations for several hours, days, or
beyond have been, to date, impossible. This sort of long-term and continuous
investigation for monitoring purposes, for example, could be possible using
a thermal camera system fixed to a mast making flight times irrelevant.
Despite other factors coming into play with fixed cameras, such as the
viewing angle dependency on emissivity (Norman and Becker, 1995) and the
addition of a changing solar reflection component to thermal emission during
the day vs. solely thermal emission during the night, the potential lies in
the generation of a thermal radiation time series and trend analyses, for
example. Similar approaches using fixed video and camera systems, operating
in the visible spectrum (red–green–blue, RGB), are operational for near-shore monitoring and
management purposes (Holman et al., 2003; Taborda and Silva, 2012). Adapting
these operational approaches to fixed thermal camera systems would mean
overcoming temporal limitations on the presented UAV approach and generating
unforeseen potential in SGD research.</p>
      <p id="d1e3106">Further limitations concern sensors. A geometric error can be
introduced by lens characteristics which distort the thermal image.
In particular, a wide-angle lens produces geometric distortions (Meier et al.,
2011; Vidas et al., 2012) that can be corrected in order to achieve an image
projection that matches the true projection surface. A further sensor
limitation is a possible radiometric error. All uncooled microbolometers,
including the one applied, have the disadvantage that a thermal drift could occur
(Mesas-Carrascosa et al., 2018). Caused by effects of the ambient
temperature on the microbolometer detector housing and the consequential
energy dissipation from the housing onto the detector array, the thermal
drift leads to a non-uniform influence on the thermal image, which manifests
in a vignetting effect with radiance reduction towards the borders of a
recorded image relative to its projection centre (Meier et al., 2011). Since
it additionally changes with time (Wolf et al., 2016), this drift,
especially for long term investigations, needs to be accounted for,
otherwise Mesas-Carrascosa et al. (2018) estimate the temperature error to
increase by 0.7 <inline-formula><mml:math id="M157" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C min<inline-formula><mml:math id="M158" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>.</p>
      <p id="d1e3130">The aforementioned limitations are all of a technical nature. However, we need
to emphasize that natural limitations may also exist that may affect the
result. The most prominent factor is the temperature difference between
groundwater and ambient water. With a difference approaching 0 <inline-formula><mml:math id="M159" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C,
an unequivocal differentiation is almost impossible, especially if we
include entrainment of ambient water and thus the temperature adaption. The
higher the difference, the more likely the possibility of identifying
SGD-induced thermal anomalies in single images, but also of using a
time series of thermal radiance images – as in the presented approach. The
advantage of time series data is that the temporal dimension includes
dynamics which may enhance subtle temperature differences. These dynamics
may be due to waves in which the surface geometries provide the direct
indication rather than the surface temperature (recall the directional
dependence of the surface emissivity on recorded radiances – see Sect. 5.1). Hence, time series data, whether from an UAV platform or from a
mast, are thoroughly recommendable.</p>
      <p id="d1e3142">Further limitations may exist due to parallel existing strong lateral flow
dynamics, as in the present case. On single thermal radiation images, these
dynamics may camouflage further focused SGD sites, especially at sites with
low groundwater–ambient water temperature differences. Strong lateral
dynamics may also, as in the present case, camouflage any bathymetry effect
on thermal radiation images as it is described in Xie et al. (2002). If
bathymetry has affected the sea surface temperature, we could detect a
gradual decrease in temperature from the shoreline towards the sea centre.
The reason that we cannot detect any gradual decrease, apart from the
camouflaging lateral flow dynamics, may be the bathymetry itself. While the
bathymetry decreases gradually during the first 30 m until about 10 m, SGD
is found at the bottom of steep walls in depths of up to 30 m (Ionescu et
al., 2012) in distances of 50 m to the coastline, which is also visible in
Fig. 1a. This sudden morphological step may additionally cause the
disappearance of the gradual temperature decrease usually triggered by
bathymetry. However, we cannot exclude this effect occurring in other places
and different settings where, for example, the bathymetry consists of
uniform slopes <inline-formula><mml:math id="M160" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">5</mml:mn><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>. In these occasions, the bathymetry
would cause higher sea surface temperatures in summer and lower sea surface
temperatures in winter that may be accounted for in the case of SGD
detection.</p>
      <p id="d1e3159">As pointed out, for most technical limitations, solutions and corrections
exist to improve and adopt the presented approach independent of the study
sites' characteristics. Thus, we propose that the approach is applicable to
other areas with diffuse or focused SGD, since the general requirements
consist of an UAV with a mounted thermal camera system and rigid areas or
fixed points within the covered footprint to allow a proper co-registration
of all thermal images. The applicability of the presented approach
concerning natural limitations needs to be investigated in the future.
However, given a certain discharge rate and sufficient temperature
differences between groundwater and ambient water, the suggestion is that
time series data of thermal radiance images could prove to be a promising
tool for SGD investigations.</p>
</sec>
</sec>
<?pagebreak page1390?><sec id="Ch1.S6" sec-type="conclusions">
  <title>Conclusions</title>
      <p id="d1e3169">Hovering with an UAV over a predefined location recording thermal radiances
at a temporal resolution of 4–5 Hz is a novel application technique
combining continuous spatial and temporal scales. Based on the combination,
we enhance focused SGD patterns that are otherwise camouflaged by strong
lateral flow dynamics that may not be observed on single thermal radiation
images. We furthermore show the spatio-temporal behaviour of a SGD-induced
thermal radiation pattern to vary in size and over time by up to 155 % for
focused SGDs and by up to 600 % for diffuse SGDs due to different
underlying flow dynamics. We want to emphasize this aspect as it is
important for SGD monitoring and especially SGD quantification purposes,
which rely on single thermal radiation images and thus temporal snapshots
that may not provide the entire picture. And lastly, we are able to reveal a
short-term periodicity of the order of 20 to 78 s  for diffuse SGD, which
we attribute to an interplay between conduit maturity or geometry and wave
set-up. The observed periodicity differs by 1 order of magnitude from
classical in situ measurement intervals, which would not be able to detect
the temporal behaviour we observe.</p>
      <p id="d1e3172">Since SGD, independent of its type, is highly heterogeneous in space and
time, as we have also shown in our study, we suggest, where possible,
inclusion of the presented approach before any in situ sampling to identify
proper sampling locations and intervals. In this way, SGD investigations,
especially in systems with complex flow, will be able to optimize their
sampling strategies and possibly improve their results.</p>
</sec>

      
      </body>
    <back><notes notes-type="dataavailability"><title>Data availability</title>

      <p id="d1e3179">Raw thermal infrared radiation data are available
online at: <uri>https://doi.org/10.1594/PANGAEA.898377</uri>.</p>
  </notes><app-group>
        <supplementary-material position="anchor"><p id="d1e3185">The supplement related to this article is available online at: <inline-supplementary-material xlink:href="https://doi.org/10.5194/hess-23-1375-2019-supplement" xlink:title="pdf">https://doi.org/10.5194/hess-23-1375-2019-supplement</inline-supplementary-material>.</p></supplementary-material>
        </app-group><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d1e3194">UM and CS conducted the experiment, UM analysed the data and
drafted the paper. Both authors revised the paper and approved the final version.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d1e3200">The authors declare that they have no conflict of
interest.</p>
  </notes><notes notes-type="sistatement"><title>Special issue statement</title>

      <p id="d1e3206">This article is part of the special issue “Environmental
changes and hazards in the Dead Sea region (NHESS/ACP/HESS/SE inter-journal
SI)”. It is not associated with a conference.</p>
  </notes><?xmltex \hack{\newpage}?><ack><title>Acknowledgements</title><p id="d1e3213">This work was financed by the DESERVE Virtual Institute,
funded by the Helmholtz Association of German Research Centers (VH-VI-527)
and a scholarship from the German Federal Ministry of Education and Research
(YSEP97). Personal thanks are addressed to Yossi Yechieli and Gideon Baer
(both Geological Survey of Israel) for the kind support, warm welcome, and
unconditional assistance before and during the exchange of UM, including the
logistical help. Meteorological data were provided by KIT (Jutta Metzger).
This paper has benefited from the efforts, insightful comments and
additions of two anonymous reviewers to whom we are eternally grateful.</p><p id="d1e3215">The manuscript is dedicated to the memory of our deceased colleague and mentor Hans
Neumeister.
<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?>
The article processing charges for this open-access <?xmltex \hack{\newline}?>
publication  were covered by a Research <?xmltex \hack{\newline}?> Centre of the Helmholtz Association.
<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?>
Edited by: Efrat Morin<?xmltex \hack{\newline}?>
Reviewed by: two anonymous referees</p></ack><ref-list>
    <title>References</title>

      <ref id="bib1.bib1"><label>1</label><mixed-citation>
Akar, P. J. and Jirka, G. H.: Buoyant spreading processes in pollutant
transport and mixing Part 2, Upstream spreading in weak ambient current,
J. Hydraul. Res., 33, 87–100, 1995.</mixed-citation></ref>
      <ref id="bib1.bib2"><label>2</label><mixed-citation>Burg, A., Yechieli, Y., and Galili, U.: Response of a coastal
hydrogeological system to a rapid decline in sea level; the case of Zuqim
springs, The largest discharge area along the Dead Sea coast, J. Hydrol., 536, 222–235, <ext-link xlink:href="https://doi.org/10.1016/j.jhydrol.2016.02.039" ext-link-type="DOI">10.1016/j.jhydrol.2016.02.039</ext-link>,
2016.</mixed-citation></ref>
      <ref id="bib1.bib3"><label>3</label><mixed-citation>Burnett, W. C., Aggarwal, P. K., Aureli, A., Bokuniewicz, H., Cable, J. E.,
Charette, M. A., Kontar, E., Krupa, S., Kulkarni, K. M., Loveless, A.,
Moore, W. S., Oberdorfer, J. A., Oliveira, J., Ozyurt, N., Povinec, P.,
Privitera, A. M. G., Rajar, R., Ramessur, R. T., Scholten, J., Stieglitz,
T., Taniguchi, M., and Turner, J. V.: Quantifying submarine groundwater
discharge in the coastal zone via multiple methods, Sci. Total
Environ., 367, 498–543, <ext-link xlink:href="https://doi.org/10.1016/j.scitotenv.2006.05.009" ext-link-type="DOI">10.1016/j.scitotenv.2006.05.009</ext-link>, 2006.</mixed-citation></ref>
      <ref id="bib1.bib4"><label>4</label><mixed-citation>
Cable, J., Burnett, W., Chanton, J., Corbett, D., and Cable, P.: Field
evaluation of seepage meters in the coastal marine environment, Estuarine,
Coast. Shelf Sci., 45, 367–375, 1997.</mixed-citation></ref>
      <ref id="bib1.bib5"><label>5</label><mixed-citation>Cheng, J. and Liang, S.: Effects of Thermal-Infrared Emissivity
Directionality on Surface Broadband Emissivity and Longwave Net Radiation
Estimation, IEEE Geosci. Remote S., 11, 499–503,
<ext-link xlink:href="https://doi.org/10.1109/LGRS.2013.2270293" ext-link-type="DOI">10.1109/LGRS.2013.2270293</ext-link>, 2014.</mixed-citation></ref>
      <ref id="bib1.bib6"><label>6</label><mixed-citation>
Cortelezzi, L. and Karagozian, A. R.: On the formation of the
counter-rotating vortex pair in transverse jets, J. Fluid Mech.,
446, 347–373, 2001.</mixed-citation></ref>
      <ref id="bib1.bib7"><label>7</label><mixed-citation>Floreano, D. and Wood, R. J.: Science, technology and the future of small
autonomous drones, Nature, 521, 460, <ext-link xlink:href="https://doi.org/10.1038/nature14542" ext-link-type="DOI">10.1038/nature14542</ext-link>, 2015.</mixed-citation></ref>
      <ref id="bib1.bib8"><label>8</label><mixed-citation>FLIR<sup>®</sup> Systems: Tau<sup>®</sup> 2 Uncooled
Cores, available at: <uri>http://www.flir.com/cores/display/?id=54717</uri>, last access: 16 December 2016.</mixed-citation></ref>
      <ref id="bib1.bib9"><label>9</label><mixed-citation>
Holman, R., Stanley, J., and Ozkan-Haller, T.: Applying video sensor
networks to nearshore environment monitoring, IEEE Pervas. Comput., 2,
14–21, 2003.</mixed-citation></ref>
      <ref id="bib1.bib10"><label>10</label><mixed-citation>Holman, R. A., Holland, K. T., Lalejini, D. M., and Spansel, S. D.: Surf
zone characterization from Unmanned Aerial Vehicle imagery, Ocean Dynam.,
61, 1927–1935, <ext-link xlink:href="https://doi.org/10.1007/s10236-011-0447-y" ext-link-type="DOI">10.1007/s10236-011-0447-y</ext-link>, 2011.</mixed-citation></ref>
      <ref id="bib1.bib11"><label>11</label><mixed-citation>Holman, R. A., Brodie, K. L., and Spore, N. J.: Surf Zone Characterization
Using a Small Quadcopter: Technical Issues and Procedures, IEEE T. Geosci. Remote, 55, 2017–2027, <ext-link xlink:href="https://doi.org/10.1109/TGRS.2016.2635120" ext-link-type="DOI">10.1109/TGRS.2016.2635120</ext-link>,
2017.</mixed-citation></ref>
      <ref id="bib1.bib12"><label>12</label><mixed-citation>Ionescu, D., Siebert, C., Polerecky, L., Munwes, Y. Y., Lott, C.,
Häusler, S., Bižić-Ionescu, M., Quast, C., Peplies, J.,
Glöckner, F. O., Ramette, A., Rödiger, T., Dittmar, T., Oren, A.,
Geyer, S., Stärk, H.-J., Sauter, M., Licha, T., Laronne, J. B., and de
Beer, D.: Microbial and Chemical Characterization of Underwater Fresh Water
Springs in the Dead Sea, Plos One, 7, e38319, <ext-link xlink:href="https://doi.org/10.1371/journal.pone.0038319" ext-link-type="DOI">10.1371/journal.pone.0038319</ext-link>,
2012.</mixed-citation></ref>
      <ref id="bib1.bib13"><label>13</label><mixed-citation>
Jirka, G. H.: Integral model for turbulent buoyant jets in unbounded
stratified flows, Part I: Single round jet, Environ. Fluid Mech.,
4, 1–56, 2004.</mixed-citation></ref>
      <ref id="bib1.bib14"><label>14</label><mixed-citation>Johnson, A. G., Glenn, C. R., Burnett, W. C., Peterson, R. N., and Lucey, P.
G.: Aerial infrared imaging reveals large nutrient-rich groundwater inputs
to the ocean, Geophys. Res. Lett., 35, 15601–15606,
<ext-link xlink:href="https://doi.org/10.1029/2008gl034574" ext-link-type="DOI">10.1029/2008gl034574</ext-link>, 2008.</mixed-citation></ref>
      <ref id="bib1.bib15"><label>15</label><mixed-citation>
Kelly, J. L., Dulai, H., Glenn, C. R., and Lucey, P. G.: Integration of aerial
infrared thermography and in situ radon-222 to investigate submarine groundwater
discharge to Pearl Harbor, Hawaii, USA, Limnol. Oceanogr., 64, 238–257,
doi:10.1002/lno.11033, 2018.</mixed-citation></ref>
      <ref id="bib1.bib16"><label>16</label><mixed-citation>
Kim, J. and Fessler, J. A.: Intensity-based image registration using robust
correlation coefficients, IEEE T. Med. Imaging, 23, 1430–1444, 2004.</mixed-citation></ref>
      <ref id="bib1.bib17"><label>17</label><mixed-citation>Lee, E., Yoon, H., Hyun, S. P., Burnett, W. C., Koh, D. C., Ha, K., Kim, D.
J., Kim, Y., and Kang, K. M.: Unmanned aerial vehicles (UAVs)-based thermal
infrared (TIR) mapping, a novel approach to assess groundwater discharge
into the coastal zone, Limnol. Oceanogr.-Meth., 14, 725–735,
<ext-link xlink:href="https://doi.org/10.1002/lom3.10132" ext-link-type="DOI">10.1002/lom3.10132</ext-link>, 2016.</mixed-citation></ref>
      <ref id="bib1.bib18"><label>18</label><mixed-citation>
Lewandowski, J., Meinikmann, K., Ruhtz, T., Pöschke, F., and Kirillin,
G.: Localization of lacustrine groundwater discharge (LGD) by airborne
measurement of thermal infrared radiation, Remote Sens. Environ.,
138, 119–125, 2013.</mixed-citation></ref>
      <ref id="bib1.bib19"><label>19</label><mixed-citation>Magal, E., Weisbrod, N., Yakirevich, A., Kurtzman, D., and Yechieli, Y.:
Line-Source Multi-Tracer Test for Assessing High Groundwater Velocity,
Ground Water, 48, 892–897, <ext-link xlink:href="https://doi.org/10.1111/j.1745-6584.2010.00707.x" ext-link-type="DOI">10.1111/j.1745-6584.2010.00707.x</ext-link>, 2010.</mixed-citation></ref>
      <ref id="bib1.bib20"><label>20</label><mixed-citation>Mallast, U., Schwonke, F., Gloaguen, R., Geyer, S., Sauter, M., and Siebert, C.: Airborne Thermal Data
Identifies Groundwater Discharge at the North-Western Coast of the Dead Sea, Remote Sens., 5, 6361–6381, <ext-link xlink:href="https://doi.org/10.3390/rs5126361" ext-link-type="DOI">10.3390/rs5126361</ext-link>, 2013a.</mixed-citation></ref>
      <ref id="bib1.bib21"><label>21</label><mixed-citation>Mallast, U., Siebert, C., Wagner, B., Sauter, M., Gloaguen, R., Geyer, S., and Merz, R.:
Localisation and temporal variability of groundwater discharge into the Dead Sea using thermal
satellite data, Environ. Earth Sci., 69, 587–603, <ext-link xlink:href="https://doi.org/10.1007/s12665-013-2371-6" ext-link-type="DOI">10.1007/s12665-013-2371-6</ext-link>, 2013b.</mixed-citation></ref>
      <ref id="bib1.bib22"><label>22</label><mixed-citation>Mallast, U., Gloaguen, R., Friesen, J., Rödiger, T., Geyer, S., Merz, R.,
and Siebert, C.: How to identify groundwater-caused thermal anomalies in lakes
based on multi-temporal satellite data in semi-arid regions, Hydrol.
Earth Syst. Sci., 18, 2773–2787, <ext-link xlink:href="https://doi.org/10.5194/hess-18-2773-2014" ext-link-type="DOI">10.5194/hess-18-2773-2014</ext-link>, 2014.</mixed-citation></ref>
      <ref id="bib1.bib23"><label>23</label><mixed-citation>Meier, F., Scherer, D., Richters, J., and Christen, A.: Atmospheric correction of
thermal-infrared imagery of the 3-D urban environment acquired in oblique viewing
geometry, Atmos. Meas. Tech., 4, 909–922, <ext-link xlink:href="https://doi.org/10.5194/amt-4-909-2011" ext-link-type="DOI">10.5194/amt-4-909-2011</ext-link>, 2011.</mixed-citation></ref>
      <ref id="bib1.bib24"><label>24</label><mixed-citation>Mejías, M., Ballesteros, B. J., Antón-Pacheco, C., Domínguez,
J. A., Garcia-Orellana, J., Garcia-Solsona, E., and Masqué, P.:
Methodological study of submarine groundwater discharge from a karstic
aquifer in the Western Mediterranean Sea, J. Hydrol., 464, 27–40, <ext-link xlink:href="https://doi.org/10.1016/j.jhydrol.2012.06.020" ext-link-type="DOI">10.1016/j.jhydrol.2012.06.020</ext-link>, 2012.</mixed-citation></ref>
      <ref id="bib1.bib25"><label>25</label><mixed-citation>Mesas-Carrascosa, F.-J., Pérez-Porras, F., Meroño de Larriva, J.,
Mena Frau, C., Agüera-Vega, F., Carvajal-Ramírez, F.,
Martínez-Carricondo, P., and García-Ferrer, A.: Drift Correction
of Lightweight Microbolometer Thermal Sensors On-Board Unmanned Aerial
Vehicles, Remote Sens., 10, 615, <ext-link xlink:href="https://doi.org/10.3390/rs10040615" ext-link-type="DOI">10.3390/rs10040615</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bib26"><label>26</label><mixed-citation>Michael, H. A., Lubetsky, J. S., and Harvey, C. F.: Characterizing submarine
groundwater discharge: a seepage meter study in Waquoit Bay, Massachusetts,
Geophys. Res. Lett., 30, <ext-link xlink:href="https://doi.org/10.1029/2002GL016000" ext-link-type="DOI">10.1029/2002GL016000</ext-link>, 2003.</mixed-citation></ref>
      <ref id="bib1.bib27"><label>27</label><mixed-citation>Michael, H. A., Charette, M. A., and Harvey, C. F.: Patterns and variability
of groundwater flow and radium activity at the coast: A case study from
Waquoit Bay, Massachusetts, Mar. Chem., 127, 100–114,
<ext-link xlink:href="https://doi.org/10.1016/j.marchem.2011.08.001" ext-link-type="DOI">10.1016/j.marchem.2011.08.001</ext-link>, 2011.</mixed-citation></ref>
      <ref id="bib1.bib28"><label>28</label><mixed-citation>
Mulligan, A. E. and Charette, M. A.: Intercomparison of submarine
groundwater discharge estimates from a sandy unconfined aquifer, J. Hydrol., 327, 411–425, 2006.</mixed-citation></ref>
      <ref id="bib1.bib29"><label>29</label><mixed-citation>Norman, J. M. and Becker, F.: Terminology in thermal infrared remote
sensing of natural surfaces, Remote Sens. Rev., 12, 159–173,
<ext-link xlink:href="https://doi.org/10.1080/02757259509532284" ext-link-type="DOI">10.1080/02757259509532284</ext-link>, 1995.</mixed-citation></ref>
      <ref id="bib1.bib30"><label>30</label><mixed-citation>Oehler, T., Eiche, E., Putra, D., Adyasari, D., Hennig, H., Mallast, U.,
and Moosdorf, N.: Timing of land-ocean groundwater nutrient fluxes from a tropical
karstic region (southern Java, Indonesia), Hydrol. Earth Syst. Sci. Discuss.,
<ext-link xlink:href="https://doi.org/10.5194/hess-2017-621" ext-link-type="DOI">10.5194/hess-2017-621</ext-link>, 2017.</mixed-citation></ref>
      <ref id="bib1.bib31"><label>31</label><mixed-citation>
Schubert, M., Scholten, J., Schmidt, A., Comanducci, J. F., Pham, M. K.,
Mallast, U., and Knoeller, K.: Submarine Groundwater Discharge at a Single
Spot Location: Evaluation of Different Detection Approaches, Water, 6,
584–601, 2014.</mixed-citation></ref>
      <ref id="bib1.bib32"><label>32</label><mixed-citation>
Siebert, C., Rödiger, T., Mallast, U., Gräbe, A., Guttman, J.,
Laronne, J. B., Storz-Peretz, Y., Greenman, A., Salameh, E., and Al-Raggad,
M.: Challenges to estimate surface-and groundwater flow in arid regions: The
Dead Sea catchment, Sci. Total Environ., 485, 828–841, 2014.</mixed-citation></ref>
      <ref id="bib1.bib33"><label>33</label><mixed-citation>
Smart, C. and Ford, D.: Structure and function of a conduit aquifer,
Can. J. Earth Sci., 23, 919–929, 1986.</mixed-citation></ref>
      <ref id="bib1.bib34"><label>34</label><mixed-citation>Surić, M., Lončarić, R., Buzjak, N., Schultz, S. T.,
Šangulin, J., Maldini, K., and Tomas, D.: Influence of submarine
groundwater discharge on seawater properties in: Rovanjska-Modrič karst
region (Croatia), Environ. Earth Sci., 74, 5625–5638,
<ext-link xlink:href="https://doi.org/10.1007/s12665-015-4577-2" ext-link-type="DOI">10.1007/s12665-015-4577-2</ext-link>, 2015.</mixed-citation></ref>
      <ref id="bib1.bib35"><label>35</label><mixed-citation>Swarzenski, P. W., Reich, C. D., Spechler, R. M., Kindinger, J. L., and
Moore, W. S.: Using multiple geochemical tracers to characterize the
hydrogeology of the submarine spring off Crescent Beach, Florida, Chem. Geol., 179, 187–202, <ext-link xlink:href="https://doi.org/10.1016/S0009-2541(01)00322-9" ext-link-type="DOI">10.1016/S0009-2541(01)00322-9</ext-link>, 2001.</mixed-citation></ref>
      <ref id="bib1.bib36"><label>36</label><mixed-citation>
Taborda, R. and Silva, A.: COSMOS: A lightweight coastal video monitoring
system, Comput. Geosci., 49, 248–255, 2012.</mixed-citation></ref>
      <ref id="bib1.bib37"><label>37</label><mixed-citation>Tamborski, J. J., Rogers, A. D., Bokuniewicz, H. J., Cochran, J. K., and
Young, C. R.: Identification and quantification of diffuse fresh submarine
groundwater discharge via airborne thermal<?pagebreak page1392?> infrared remote sensing, Remote Sens. Environ., 171, 202–217,
<ext-link xlink:href="https://doi.org/10.1016/j.rse.2015.10.010" ext-link-type="DOI">10.1016/j.rse.2015.10.010</ext-link>, 2015.</mixed-citation></ref>
      <ref id="bib1.bib38"><label>38</label><mixed-citation>
Taniguchi, M., Burnett, W. C., Cable, J. E., and Turner, J. V.: Assessment
methodologies for submarine groundwater discharge, in: Land and Marine
Hydrogeology, edited by: Taniguchi, M., Wang, K., and Gamo, T., Elsevier,
Amsterdam, 1–23, 2003a.</mixed-citation></ref>
      <ref id="bib1.bib39"><label>39</label><mixed-citation>Taniguchi, M., Burnett, W. C., Smith, C. F., Paulsen, R. J., O'Rourke, D.,
Krupa, S. L., and Christoff, J. L.: Spatial and temporal distributions of
submarine groundwater discharge rates obtained from various types of seepage
meters at a site in the Northeastern Gulf of Mexico, Biogeochemistry, 66,
35–53, <ext-link xlink:href="https://doi.org/10.1023/B:BIOG.0000006090.25949.8d" ext-link-type="DOI">10.1023/B:BIOG.0000006090.25949.8d</ext-link>, 2003b.</mixed-citation></ref>
      <ref id="bib1.bib40"><label>40</label><mixed-citation>TeAx Technology: Thermal Capture, available at: <uri>http://thermalcapture.com/category/products/recordingsolutions/</uri>, last access:
16 December 2016.</mixed-citation></ref>
      <ref id="bib1.bib41"><label>41</label><mixed-citation>
Tzanetakis, G. and Cook, P.: Musical genre classification of audio signals,
IEEE T. Speech Audi. P., 10, 293–302, 2002.</mixed-citation></ref>
      <ref id="bib1.bib42"><label>42</label><mixed-citation>Viana, I., Orteu, J.-J., Cornille, N., and Bugarin, F.: Inspection of
aeronautical mechanical parts with a pan-tilt-zoom camera: an approach
guided by the computer-aided design model, J. Electron. Imaging,
24, 061118, <ext-link xlink:href="https://doi.org/10.1117/1.JEI.24.6.061118" ext-link-type="DOI">10.1117/1.JEI.24.6.061118</ext-link>, 2015.
</mixed-citation></ref><?xmltex \hack{\newpage}?>
      <ref id="bib1.bib43"><label>43</label><mixed-citation>
Vidas, S., Lakemond, R., Denman, S., Fookes, C., Sridharan, S., and Wark,
T.: A mask-based approach for the geometric calibration of thermal-infrared
cameras, IEEE T. Instrum. Meas., 61,
1625–1635, 2012.</mixed-citation></ref>
      <ref id="bib1.bib44"><label>44</label><mixed-citation>Vollmer, M.: Newton's law of cooling revisited, Eur. J. Phys.,
30, 1063, <ext-link xlink:href="https://doi.org/10.1088/0143-0807/30/5/014" ext-link-type="DOI">10.1088/0143-0807/30/5/014</ext-link>, 2009.</mixed-citation></ref>
      <ref id="bib1.bib45"><label>45</label><mixed-citation>Wolf, A., Pezoa, J. E., and Figueroa, M.: Modeling and Compensating
Temperature-Dependent Non-Uniformity Noise in IR Microbolometer Cameras,
Sensors, Basel, Switzerland, 16, 1121, <ext-link xlink:href="https://doi.org/10.3390/s16071121" ext-link-type="DOI">10.3390/s16071121</ext-link>, 2016.</mixed-citation></ref>
      <ref id="bib1.bib46"><label>46</label><mixed-citation>Xie, S.-P., Hafner, J., Tanimoto, Y., Liu, W. T., Tokinaga, H., and Xu, H.:
Bathymetric effect on the winter sea surface temperature and climate of the
Yellow and East China Seas, Geophys. Res. Lett., 29, 2228, <ext-link xlink:href="https://doi.org/10.1029/2002GL015884" ext-link-type="DOI">10.1029/2002GL015884</ext-link>, 2002.</mixed-citation></ref>
      <ref id="bib1.bib47"><label>47</label><mixed-citation>Yechieli, Y., Ronen, D., Berkowitz, B., Dershowitz, W. S., and Hadad, A.:
Aquifer Characteristics Derived From the Interaction Between Water Levels of
a Terminal Lake (Dead Sea) and an Adjacent Aquifer, Water Resour. Res., 31, 893–902, <ext-link xlink:href="https://doi.org/10.1029/94wr03154" ext-link-type="DOI">10.1029/94wr03154</ext-link>, 1995.</mixed-citation></ref>
      <ref id="bib1.bib48"><label>48</label><mixed-citation>Yechieli, Y., Shalev, E., Wollman, S., Kiro, Y., and Kafri, U.: Response of
the Mediterranean and Dead Sea coastal aquifers to sea level variations,
Water Resour. Res., 46, W12550, <ext-link xlink:href="https://doi.org/10.1029/2009wr008708" ext-link-type="DOI">10.1029/2009wr008708</ext-link>, 2010.</mixed-citation></ref>

  </ref-list></back>
    <!--<article-title-html>Combining continuous spatial and temporal scales for SGD investigations using UAV-based thermal infrared measurements</article-title-html>
<abstract-html><p>Submarine groundwater discharge (SGD) is highly variable in spatial and
temporal terms due to the interplay of several terrestrial and marine
processes. While discrete in situ measurements may provide a continuous
temporal scale to investigate underlying processes and thus account for
temporal heterogeneity, remotely sensed thermal infrared radiation sheds
light on the spatial heterogeneity as it provides a continuous spatial scale.</p><p>Here we report results of the combination of both the continuous spatial and
temporal scales, using the ability of an unmanned aerial vehicle (UAV) to
hover above a predefined location, and the continuous recording of thermal
radiation of a coastal area at the Dead Sea (Israel). With a flight altitude
of 65&thinsp;m above the water surface resulting in a spatial resolution of 13&thinsp;cm
and a thermal camera (FLIR Tau2) that measures the upwelling long-wave
infrared radiation at 4&thinsp;Hz resolution, we are able to generate a time series
of thermal radiation images that allows us to analyse spatio-temporal SGD
dynamics.</p><p>In turn, focused SGD spots, otherwise camouflaged by strong lateral
flow dynamics, are revealed that may not be observed on single thermal
radiation images. The spatio-temporal behaviour of an SGD-induced thermal
radiation pattern varies in size and over time by up to 155&thinsp;% for focused
SGDs and by up to 600&thinsp;% for diffuse SGDs due to different underlying flow
dynamics. These flow dynamics even display a short-term periodicity of the
order of 20 to 78&thinsp;s  for diffuse SGD, which we attribute to an interplay
between conduit maturity–geometry and wave set-up.</p></abstract-html>
<ref-html id="bib1.bib1"><label>1</label><mixed-citation>
Akar, P. J. and Jirka, G. H.: Buoyant spreading processes in pollutant
transport and mixing Part 2, Upstream spreading in weak ambient current,
J. Hydraul. Res., 33, 87–100, 1995.
</mixed-citation></ref-html>
<ref-html id="bib1.bib2"><label>2</label><mixed-citation>
Burg, A., Yechieli, Y., and Galili, U.: Response of a coastal
hydrogeological system to a rapid decline in sea level; the case of Zuqim
springs, The largest discharge area along the Dead Sea coast, J. Hydrol., 536, 222–235, <a href="https://doi.org/10.1016/j.jhydrol.2016.02.039" target="_blank">https://doi.org/10.1016/j.jhydrol.2016.02.039</a>,
2016.
</mixed-citation></ref-html>
<ref-html id="bib1.bib3"><label>3</label><mixed-citation>
Burnett, W. C., Aggarwal, P. K., Aureli, A., Bokuniewicz, H., Cable, J. E.,
Charette, M. A., Kontar, E., Krupa, S., Kulkarni, K. M., Loveless, A.,
Moore, W. S., Oberdorfer, J. A., Oliveira, J., Ozyurt, N., Povinec, P.,
Privitera, A. M. G., Rajar, R., Ramessur, R. T., Scholten, J., Stieglitz,
T., Taniguchi, M., and Turner, J. V.: Quantifying submarine groundwater
discharge in the coastal zone via multiple methods, Sci. Total
Environ., 367, 498–543, <a href="https://doi.org/10.1016/j.scitotenv.2006.05.009" target="_blank">https://doi.org/10.1016/j.scitotenv.2006.05.009</a>, 2006.
</mixed-citation></ref-html>
<ref-html id="bib1.bib4"><label>4</label><mixed-citation>
Cable, J., Burnett, W., Chanton, J., Corbett, D., and Cable, P.: Field
evaluation of seepage meters in the coastal marine environment, Estuarine,
Coast. Shelf Sci., 45, 367–375, 1997.
</mixed-citation></ref-html>
<ref-html id="bib1.bib5"><label>5</label><mixed-citation>
Cheng, J. and Liang, S.: Effects of Thermal-Infrared Emissivity
Directionality on Surface Broadband Emissivity and Longwave Net Radiation
Estimation, IEEE Geosci. Remote S., 11, 499–503,
<a href="https://doi.org/10.1109/LGRS.2013.2270293" target="_blank">https://doi.org/10.1109/LGRS.2013.2270293</a>, 2014.
</mixed-citation></ref-html>
<ref-html id="bib1.bib6"><label>6</label><mixed-citation>
Cortelezzi, L. and Karagozian, A. R.: On the formation of the
counter-rotating vortex pair in transverse jets, J. Fluid Mech.,
446, 347–373, 2001.
</mixed-citation></ref-html>
<ref-html id="bib1.bib7"><label>7</label><mixed-citation>
Floreano, D. and Wood, R. J.: Science, technology and the future of small
autonomous drones, Nature, 521, 460, <a href="https://doi.org/10.1038/nature14542" target="_blank">https://doi.org/10.1038/nature14542</a>, 2015.
</mixed-citation></ref-html>
<ref-html id="bib1.bib8"><label>8</label><mixed-citation>
FLIR<span style="position:relative; bottom:0.5em; " class="text">®</span> Systems: Tau<span style="position:relative; bottom:0.5em; " class="text">®</span> 2 Uncooled
Cores, available at: <a href="http://www.flir.com/cores/display/?id=54717" target="_blank">http://www.flir.com/cores/display/?id=54717</a>, last access: 16 December 2016.
</mixed-citation></ref-html>
<ref-html id="bib1.bib9"><label>9</label><mixed-citation>
Holman, R., Stanley, J., and Ozkan-Haller, T.: Applying video sensor
networks to nearshore environment monitoring, IEEE Pervas. Comput., 2,
14–21, 2003.
</mixed-citation></ref-html>
<ref-html id="bib1.bib10"><label>10</label><mixed-citation>
Holman, R. A., Holland, K. T., Lalejini, D. M., and Spansel, S. D.: Surf
zone characterization from Unmanned Aerial Vehicle imagery, Ocean Dynam.,
61, 1927–1935, <a href="https://doi.org/10.1007/s10236-011-0447-y" target="_blank">https://doi.org/10.1007/s10236-011-0447-y</a>, 2011.
</mixed-citation></ref-html>
<ref-html id="bib1.bib11"><label>11</label><mixed-citation>
Holman, R. A., Brodie, K. L., and Spore, N. J.: Surf Zone Characterization
Using a Small Quadcopter: Technical Issues and Procedures, IEEE T. Geosci. Remote, 55, 2017–2027, <a href="https://doi.org/10.1109/TGRS.2016.2635120" target="_blank">https://doi.org/10.1109/TGRS.2016.2635120</a>,
2017.
</mixed-citation></ref-html>
<ref-html id="bib1.bib12"><label>12</label><mixed-citation>
Ionescu, D., Siebert, C., Polerecky, L., Munwes, Y. Y., Lott, C.,
Häusler, S., Bižić-Ionescu, M., Quast, C., Peplies, J.,
Glöckner, F. O., Ramette, A., Rödiger, T., Dittmar, T., Oren, A.,
Geyer, S., Stärk, H.-J., Sauter, M., Licha, T., Laronne, J. B., and de
Beer, D.: Microbial and Chemical Characterization of Underwater Fresh Water
Springs in the Dead Sea, Plos One, 7, e38319, <a href="https://doi.org/10.1371/journal.pone.0038319" target="_blank">https://doi.org/10.1371/journal.pone.0038319</a>,
2012.
</mixed-citation></ref-html>
<ref-html id="bib1.bib13"><label>13</label><mixed-citation>
Jirka, G. H.: Integral model for turbulent buoyant jets in unbounded
stratified flows, Part I: Single round jet, Environ. Fluid Mech.,
4, 1–56, 2004.
</mixed-citation></ref-html>
<ref-html id="bib1.bib14"><label>14</label><mixed-citation>
Johnson, A. G., Glenn, C. R., Burnett, W. C., Peterson, R. N., and Lucey, P.
G.: Aerial infrared imaging reveals large nutrient-rich groundwater inputs
to the ocean, Geophys. Res. Lett., 35, 15601–15606,
<a href="https://doi.org/10.1029/2008gl034574" target="_blank">https://doi.org/10.1029/2008gl034574</a>, 2008.
</mixed-citation></ref-html>
<ref-html id="bib1.bib15"><label>15</label><mixed-citation>
Kelly, J. L., Dulai, H., Glenn, C. R., and Lucey, P. G.: Integration of aerial
infrared thermography and in situ radon-222 to investigate submarine groundwater
discharge to Pearl Harbor, Hawaii, USA, Limnol. Oceanogr., 64, 238–257,
doi:10.1002/lno.11033, 2018.
</mixed-citation></ref-html>
<ref-html id="bib1.bib16"><label>16</label><mixed-citation>
Kim, J. and Fessler, J. A.: Intensity-based image registration using robust
correlation coefficients, IEEE T. Med. Imaging, 23, 1430–1444, 2004.
</mixed-citation></ref-html>
<ref-html id="bib1.bib17"><label>17</label><mixed-citation>
Lee, E., Yoon, H., Hyun, S. P., Burnett, W. C., Koh, D. C., Ha, K., Kim, D.
J., Kim, Y., and Kang, K. M.: Unmanned aerial vehicles (UAVs)-based thermal
infrared (TIR) mapping, a novel approach to assess groundwater discharge
into the coastal zone, Limnol. Oceanogr.-Meth., 14, 725–735,
<a href="https://doi.org/10.1002/lom3.10132" target="_blank">https://doi.org/10.1002/lom3.10132</a>, 2016.
</mixed-citation></ref-html>
<ref-html id="bib1.bib18"><label>18</label><mixed-citation>
Lewandowski, J., Meinikmann, K., Ruhtz, T., Pöschke, F., and Kirillin,
G.: Localization of lacustrine groundwater discharge (LGD) by airborne
measurement of thermal infrared radiation, Remote Sens. Environ.,
138, 119–125, 2013.
</mixed-citation></ref-html>
<ref-html id="bib1.bib19"><label>19</label><mixed-citation>
Magal, E., Weisbrod, N., Yakirevich, A., Kurtzman, D., and Yechieli, Y.:
Line-Source Multi-Tracer Test for Assessing High Groundwater Velocity,
Ground Water, 48, 892–897, <a href="https://doi.org/10.1111/j.1745-6584.2010.00707.x" target="_blank">https://doi.org/10.1111/j.1745-6584.2010.00707.x</a>, 2010.
</mixed-citation></ref-html>
<ref-html id="bib1.bib20"><label>20</label><mixed-citation>
Mallast, U., Schwonke, F., Gloaguen, R., Geyer, S., Sauter, M., and Siebert, C.: Airborne Thermal Data
Identifies Groundwater Discharge at the North-Western Coast of the Dead Sea, Remote Sens., 5, 6361–6381, <a href="https://doi.org/10.3390/rs5126361" target="_blank">https://doi.org/10.3390/rs5126361</a>, 2013a.
</mixed-citation></ref-html>
<ref-html id="bib1.bib21"><label>21</label><mixed-citation>
Mallast, U., Siebert, C., Wagner, B., Sauter, M., Gloaguen, R., Geyer, S., and Merz, R.:
Localisation and temporal variability of groundwater discharge into the Dead Sea using thermal
satellite data, Environ. Earth Sci., 69, 587–603, <a href="https://doi.org/10.1007/s12665-013-2371-6" target="_blank">https://doi.org/10.1007/s12665-013-2371-6</a>, 2013b.
</mixed-citation></ref-html>
<ref-html id="bib1.bib22"><label>22</label><mixed-citation>
Mallast, U., Gloaguen, R., Friesen, J., Rödiger, T., Geyer, S., Merz, R.,
and Siebert, C.: How to identify groundwater-caused thermal anomalies in lakes
based on multi-temporal satellite data in semi-arid regions, Hydrol.
Earth Syst. Sci., 18, 2773–2787, <a href="https://doi.org/10.5194/hess-18-2773-2014" target="_blank">https://doi.org/10.5194/hess-18-2773-2014</a>, 2014.
</mixed-citation></ref-html>
<ref-html id="bib1.bib23"><label>23</label><mixed-citation>
Meier, F., Scherer, D., Richters, J., and Christen, A.: Atmospheric correction of
thermal-infrared imagery of the 3-D urban environment acquired in oblique viewing
geometry, Atmos. Meas. Tech., 4, 909–922, <a href="https://doi.org/10.5194/amt-4-909-2011" target="_blank">https://doi.org/10.5194/amt-4-909-2011</a>, 2011.
</mixed-citation></ref-html>
<ref-html id="bib1.bib24"><label>24</label><mixed-citation>
Mejías, M., Ballesteros, B. J., Antón-Pacheco, C., Domínguez,
J. A., Garcia-Orellana, J., Garcia-Solsona, E., and Masqué, P.:
Methodological study of submarine groundwater discharge from a karstic
aquifer in the Western Mediterranean Sea, J. Hydrol., 464, 27–40, <a href="https://doi.org/10.1016/j.jhydrol.2012.06.020" target="_blank">https://doi.org/10.1016/j.jhydrol.2012.06.020</a>, 2012.
</mixed-citation></ref-html>
<ref-html id="bib1.bib25"><label>25</label><mixed-citation>
Mesas-Carrascosa, F.-J., Pérez-Porras, F., Meroño de Larriva, J.,
Mena Frau, C., Agüera-Vega, F., Carvajal-Ramírez, F.,
Martínez-Carricondo, P., and García-Ferrer, A.: Drift Correction
of Lightweight Microbolometer Thermal Sensors On-Board Unmanned Aerial
Vehicles, Remote Sens., 10, 615, <a href="https://doi.org/10.3390/rs10040615" target="_blank">https://doi.org/10.3390/rs10040615</a>, 2018.
</mixed-citation></ref-html>
<ref-html id="bib1.bib26"><label>26</label><mixed-citation>
Michael, H. A., Lubetsky, J. S., and Harvey, C. F.: Characterizing submarine
groundwater discharge: a seepage meter study in Waquoit Bay, Massachusetts,
Geophys. Res. Lett., 30, <a href="https://doi.org/10.1029/2002GL016000" target="_blank">https://doi.org/10.1029/2002GL016000</a>, 2003.
</mixed-citation></ref-html>
<ref-html id="bib1.bib27"><label>27</label><mixed-citation>
Michael, H. A., Charette, M. A., and Harvey, C. F.: Patterns and variability
of groundwater flow and radium activity at the coast: A case study from
Waquoit Bay, Massachusetts, Mar. Chem., 127, 100–114,
<a href="https://doi.org/10.1016/j.marchem.2011.08.001" target="_blank">https://doi.org/10.1016/j.marchem.2011.08.001</a>, 2011.
</mixed-citation></ref-html>
<ref-html id="bib1.bib28"><label>28</label><mixed-citation>
Mulligan, A. E. and Charette, M. A.: Intercomparison of submarine
groundwater discharge estimates from a sandy unconfined aquifer, J. Hydrol., 327, 411–425, 2006.
</mixed-citation></ref-html>
<ref-html id="bib1.bib29"><label>29</label><mixed-citation>
Norman, J. M. and Becker, F.: Terminology in thermal infrared remote
sensing of natural surfaces, Remote Sens. Rev., 12, 159–173,
<a href="https://doi.org/10.1080/02757259509532284" target="_blank">https://doi.org/10.1080/02757259509532284</a>, 1995.
</mixed-citation></ref-html>
<ref-html id="bib1.bib30"><label>30</label><mixed-citation>
Oehler, T., Eiche, E., Putra, D., Adyasari, D., Hennig, H., Mallast, U.,
and Moosdorf, N.: Timing of land-ocean groundwater nutrient fluxes from a tropical
karstic region (southern Java, Indonesia), Hydrol. Earth Syst. Sci. Discuss.,
<a href="https://doi.org/10.5194/hess-2017-621" target="_blank">https://doi.org/10.5194/hess-2017-621</a>, 2017.
</mixed-citation></ref-html>
<ref-html id="bib1.bib31"><label>31</label><mixed-citation>
Schubert, M., Scholten, J., Schmidt, A., Comanducci, J. F., Pham, M. K.,
Mallast, U., and Knoeller, K.: Submarine Groundwater Discharge at a Single
Spot Location: Evaluation of Different Detection Approaches, Water, 6,
584–601, 2014.
</mixed-citation></ref-html>
<ref-html id="bib1.bib32"><label>32</label><mixed-citation>
Siebert, C., Rödiger, T., Mallast, U., Gräbe, A., Guttman, J.,
Laronne, J. B., Storz-Peretz, Y., Greenman, A., Salameh, E., and Al-Raggad,
M.: Challenges to estimate surface-and groundwater flow in arid regions: The
Dead Sea catchment, Sci. Total Environ., 485, 828–841, 2014.
</mixed-citation></ref-html>
<ref-html id="bib1.bib33"><label>33</label><mixed-citation>
Smart, C. and Ford, D.: Structure and function of a conduit aquifer,
Can. J. Earth Sci., 23, 919–929, 1986.
</mixed-citation></ref-html>
<ref-html id="bib1.bib34"><label>34</label><mixed-citation>
Surić, M., Lončarić, R., Buzjak, N., Schultz, S. T.,
Šangulin, J., Maldini, K., and Tomas, D.: Influence of submarine
groundwater discharge on seawater properties in: Rovanjska-Modrič karst
region (Croatia), Environ. Earth Sci., 74, 5625–5638,
<a href="https://doi.org/10.1007/s12665-015-4577-2" target="_blank">https://doi.org/10.1007/s12665-015-4577-2</a>, 2015.
</mixed-citation></ref-html>
<ref-html id="bib1.bib35"><label>35</label><mixed-citation>
Swarzenski, P. W., Reich, C. D., Spechler, R. M., Kindinger, J. L., and
Moore, W. S.: Using multiple geochemical tracers to characterize the
hydrogeology of the submarine spring off Crescent Beach, Florida, Chem. Geol., 179, 187–202, <a href="https://doi.org/10.1016/S0009-2541(01)00322-9" target="_blank">https://doi.org/10.1016/S0009-2541(01)00322-9</a>, 2001.
</mixed-citation></ref-html>
<ref-html id="bib1.bib36"><label>36</label><mixed-citation>
Taborda, R. and Silva, A.: COSMOS: A lightweight coastal video monitoring
system, Comput. Geosci., 49, 248–255, 2012.
</mixed-citation></ref-html>
<ref-html id="bib1.bib37"><label>37</label><mixed-citation>
Tamborski, J. J., Rogers, A. D., Bokuniewicz, H. J., Cochran, J. K., and
Young, C. R.: Identification and quantification of diffuse fresh submarine
groundwater discharge via airborne thermal infrared remote sensing, Remote Sens. Environ., 171, 202–217,
<a href="https://doi.org/10.1016/j.rse.2015.10.010" target="_blank">https://doi.org/10.1016/j.rse.2015.10.010</a>, 2015.
</mixed-citation></ref-html>
<ref-html id="bib1.bib38"><label>38</label><mixed-citation>
Taniguchi, M., Burnett, W. C., Cable, J. E., and Turner, J. V.: Assessment
methodologies for submarine groundwater discharge, in: Land and Marine
Hydrogeology, edited by: Taniguchi, M., Wang, K., and Gamo, T., Elsevier,
Amsterdam, 1–23, 2003a.
</mixed-citation></ref-html>
<ref-html id="bib1.bib39"><label>39</label><mixed-citation>
Taniguchi, M., Burnett, W. C., Smith, C. F., Paulsen, R. J., O'Rourke, D.,
Krupa, S. L., and Christoff, J. L.: Spatial and temporal distributions of
submarine groundwater discharge rates obtained from various types of seepage
meters at a site in the Northeastern Gulf of Mexico, Biogeochemistry, 66,
35–53, <a href="https://doi.org/10.1023/B:BIOG.0000006090.25949.8d" target="_blank">https://doi.org/10.1023/B:BIOG.0000006090.25949.8d</a>, 2003b.
</mixed-citation></ref-html>
<ref-html id="bib1.bib40"><label>40</label><mixed-citation>
TeAx Technology: Thermal Capture, available at: <a href="http://thermalcapture.com/category/products/recordingsolutions/" target="_blank">http://thermalcapture.com/category/products/recordingsolutions/</a>, last access:
16 December 2016.
</mixed-citation></ref-html>
<ref-html id="bib1.bib41"><label>41</label><mixed-citation>
Tzanetakis, G. and Cook, P.: Musical genre classification of audio signals,
IEEE T. Speech Audi. P., 10, 293–302, 2002.
</mixed-citation></ref-html>
<ref-html id="bib1.bib42"><label>42</label><mixed-citation>
Viana, I., Orteu, J.-J., Cornille, N., and Bugarin, F.: Inspection of
aeronautical mechanical parts with a pan-tilt-zoom camera: an approach
guided by the computer-aided design model, J. Electron. Imaging,
24, 061118, <a href="https://doi.org/10.1117/1.JEI.24.6.061118" target="_blank">https://doi.org/10.1117/1.JEI.24.6.061118</a>, 2015.

</mixed-citation></ref-html>
<ref-html id="bib1.bib43"><label>43</label><mixed-citation>
Vidas, S., Lakemond, R., Denman, S., Fookes, C., Sridharan, S., and Wark,
T.: A mask-based approach for the geometric calibration of thermal-infrared
cameras, IEEE T. Instrum. Meas., 61,
1625–1635, 2012.
</mixed-citation></ref-html>
<ref-html id="bib1.bib44"><label>44</label><mixed-citation>
Vollmer, M.: Newton's law of cooling revisited, Eur. J. Phys.,
30, 1063, <a href="https://doi.org/10.1088/0143-0807/30/5/014" target="_blank">https://doi.org/10.1088/0143-0807/30/5/014</a>, 2009.
</mixed-citation></ref-html>
<ref-html id="bib1.bib45"><label>45</label><mixed-citation>
Wolf, A., Pezoa, J. E., and Figueroa, M.: Modeling and Compensating
Temperature-Dependent Non-Uniformity Noise in IR Microbolometer Cameras,
Sensors, Basel, Switzerland, 16, 1121, <a href="https://doi.org/10.3390/s16071121" target="_blank">https://doi.org/10.3390/s16071121</a>, 2016.
</mixed-citation></ref-html>
<ref-html id="bib1.bib46"><label>46</label><mixed-citation>
Xie, S.-P., Hafner, J., Tanimoto, Y., Liu, W. T., Tokinaga, H., and Xu, H.:
Bathymetric effect on the winter sea surface temperature and climate of the
Yellow and East China Seas, Geophys. Res. Lett., 29, 2228, <a href="https://doi.org/10.1029/2002GL015884" target="_blank">https://doi.org/10.1029/2002GL015884</a>, 2002.
</mixed-citation></ref-html>
<ref-html id="bib1.bib47"><label>47</label><mixed-citation>
Yechieli, Y., Ronen, D., Berkowitz, B., Dershowitz, W. S., and Hadad, A.:
Aquifer Characteristics Derived From the Interaction Between Water Levels of
a Terminal Lake (Dead Sea) and an Adjacent Aquifer, Water Resour. Res., 31, 893–902, <a href="https://doi.org/10.1029/94wr03154" target="_blank">https://doi.org/10.1029/94wr03154</a>, 1995.
</mixed-citation></ref-html>
<ref-html id="bib1.bib48"><label>48</label><mixed-citation>
Yechieli, Y., Shalev, E., Wollman, S., Kiro, Y., and Kafri, U.: Response of
the Mediterranean and Dead Sea coastal aquifers to sea level variations,
Water Resour. Res., 46, W12550, <a href="https://doi.org/10.1029/2009wr008708" target="_blank">https://doi.org/10.1029/2009wr008708</a>, 2010.
</mixed-citation></ref-html>--></article>
