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  <front>
    <journal-meta><journal-id journal-id-type="publisher">HESS</journal-id><journal-title-group>
    <journal-title>Hydrology and Earth System Sciences</journal-title>
    <abbrev-journal-title abbrev-type="publisher">HESS</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Hydrol. Earth Syst. Sci.</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1607-7938</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/hess-22-3807-2018</article-id><title-group><article-title>Dynamics of water fluxes and storages in an Alpine karst catchment under
current and potential future climate conditions</article-title><alt-title>Dynamics of water fluxes and storages in an Alpine karst catchment</alt-title>
      </title-group><?xmltex \runningtitle{Dynamics of water fluxes and storages in an Alpine karst catchment}?><?xmltex \runningauthor{Z. Chen et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Chen</surname><given-names>Zhao</given-names></name>
          <email>zhao.chen@kit.edu</email>
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2 aff3">
          <name><surname>Hartmann</surname><given-names>Andreas</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-0407-742X</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Wagener</surname><given-names>Thorsten</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-3881-5849</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Goldscheider</surname><given-names>Nico</given-names></name>
          
        </contrib>
        <aff id="aff1"><label>1</label><institution>Institute of Applied Geosciences, Karlsruhe Institute of Technology
(KIT), Karlsruhe, Germany</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Institute of Hydrology, Albert Ludwigs University of Freiburg,
Freiburg, Germany</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Department of Civil Engineering, University of Bristol, UK</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Zhao Chen (zhao.chen@kit.edu)</corresp></author-notes><pub-date><day>18</day><month>July</month><year>2018</year></pub-date>
      
      <volume>22</volume>
      <issue>7</issue>
      <fpage>3807</fpage><lpage>3823</lpage>
      <history>
        <date date-type="received"><day>11</day><month>April</month><year>2017</year></date>
           <date date-type="rev-request"><day>8</day><month>May</month><year>2017</year></date>
           <date date-type="rev-recd"><day>1</day><month>April</month><year>2018</year></date>
           <date date-type="accepted"><day>6</day><month>June</month><year>2018</year></date>
      </history>
      <permissions>
        
        
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 3.0 Unported License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/3.0/">https://creativecommons.org/licenses/by/3.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://hess.copernicus.org/articles/22/3807/2018/hess-22-3807-2018.html">This article is available from https://hess.copernicus.org/articles/22/3807/2018/hess-22-3807-2018.html</self-uri><self-uri xlink:href="https://hess.copernicus.org/articles/22/3807/2018/hess-22-3807-2018.pdf">The full text article is available as a PDF file from https://hess.copernicus.org/articles/22/3807/2018/hess-22-3807-2018.pdf</self-uri>
      <abstract>
    <p id="d1e121">Karst aquifers are difficult to manage due to their unique
hydrogeological characteristics. Future climate projections suggest a strong
change in temperature and precipitation regimes in European karst regions
over the next decades. Alpine karst systems can be especially vulnerable
under changing hydro-meteorological conditions since snowmelt in mountainous
environments is an important controlling process for aquifer recharge and is
highly sensitive to varying climatic conditions. Our paper presents the first
study to investigate potential impacts of climate change on mountainous karst
systems by using a combined lumped and distributed modeling approach with
consideration of subsurface karst drainage structures. The study site is
characterized by high-permeability (karstified) limestone formations and low-permeability
(non-karst) sedimentary Flysch. The model simulation under
current conditions demonstrates that a large proportion of precipitation
infiltrates into the karst aquifer as autogenic recharge. Moreover, the
result shows that surface snow storage is dominant from November to April,
while subsurface water storage in the karst aquifer dominates from May to
October. The climate scenario runs demonstrate that varied climate conditions
significantly affect the spatiotemporal distribution of water fluxes and
storages: (1) the total catchment discharge decreases under all
evaluated future climate conditions. (2) The spatiotemporal discharge
pattern is strongly controlled by temperature variations, which can shift the
seasonal snowmelt pattern, with snow storage in the cold season (December to
April) decreasing significantly under all change scenarios. (3) Increased
karst aquifer recharge in winter and spring, and decreased recharge in summer
and autumn, partly offset each other. (4) Impacts on the karst springs are
distinct; the lowest permanent spring presents a “robust” discharge
behavior, while the highest overflow outlet is highly sensitive to changing
climate. This analysis effectively demonstrates that the impacts on
subsurface flow dynamics are regulated by the characteristic dual flow and
spatially heterogeneous distributed drainage structure of the karst aquifer.
Overall, our study highlights the fast groundwater dynamics in mountainous
karst catchments, which make them highly vulnerable to future changing
climate conditions. Additionally, this work presents a novel holistic
modeling approach, which can be transferred to similar karst systems for
studying the impact of climate change on local karst water resources with
consideration of their individual hydrogeological complexity and hydraulic
heterogeneity.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <title>Introduction</title>
      <p id="d1e131">The Alps, called the “water tower of Europe”, form headwaters for
important regional river systems (Viviroli et al., 2007). Alpine catchments
are generally characterized by above-average precipitation due to orographic
effects, as well as by colder temperatures resulting in lower
evapotranspiration and temporary water storage in the form of snow and ice
(Zierl and Bugmann, 2005). Climate projections indicate that a shift in snow
and precipitation patterns is likely to alter catchment runoff regimes
(Gobiet et al., 2014). Additionally, extreme events, such as floods and
droughts, are expected to increase in frequency and intensity (Dobler et
al., 2013; Rössler et al., 2012). For sustainable management of<?pagebreak page3808?> water
resources in Alpine areas, it is imperative to understand the complex
mountainous hydrological processes (Kraller et al., 2012).</p>
      <p id="d1e134">In this context, numerical models are usually applied to describe the
hydrological processes in Alpine catchments (Abbaspour et al., 2007;
Achleitner et al., 2009; Benischke et al., 2010; Braun and Renner, 1992;
Junghans et al., 2011; Kraller et al., 2012). Lumped models are easy to use
in gauged catchments because their parameters can be effectively found via
calibration. For studying the spatial patterns of hydrological processes
across a catchment, distributed models are required, which discretize the
model domain into a grid of homogeneous subunits, for which surface
and/or
subsurface flow can be described by flow equations derived from basic
physical laws. Previously, most distributed models focused on surface
hydrological variables (e.g., vegetation, soil and snow cover) and/or
anthropogenic variables (e.g., land use and water use), with relatively poor
subsurface representations. Few studies (e.g., Kraller et al., 2012;
Kunstmann et al., 2006; Kunstmann and Stadler, 2005) explicitly considered
subsurface processes such as recharge, drainage and storage in their models
for Alpine regions. It is generally accepted that the geological and
lithological setting for mountainous catchments are often complex and could
have significant impact on the catchment flow regime (Goldscheider, 2011;
Rogger et al., 2013). The situation is even more complex when mountain
ranges within a catchment consist of highly permeable limestone formations
hydraulically characterized by fissures and/or conduit drainage networks,
as well as concentrated discharge via springs (Goldscheider, 2005; Gremaud et al.,
2009; Lauber and Goldscheider, 2014).</p>
      <p id="d1e137">In order to better understand complex hydrological processes in mountainous
karstic catchments as well as quantifying their dynamics, this study presents a
spatially distributed investigation of the water fluxes and storages in a
high-elevation Alpine catchment considering its complex subsurface
heterogeneous drainage structure. The study catchment constitutes an optimal
test case to explore complex hydrological processes since it includes many
typical characteristics of Alpine catchments, such as a seasonal snow cover,
a large range of elevations and a highly varied catchment flow regime.
Furthermore, the hydrogeology in the investigated catchment is complex. It
is characterized by high-permeability limestone formations (karst areas) and
low-permeability Flysch sedimentary rocks (non-karst areas) as described by
Goldscheider (2005). Here, we expanded an existing model (Chen and
Goldscheider, 2014) by adding a snow accumulation and melting routine with
high spatiotemporal resolution. We also developed a tailored calibration
strategy, building on a previous sensitivity analysis by Chen et al. (2017),
to calibrate the proposed catchment model reasonably and effectively.</p>
      <p id="d1e140">Several recent studies indicated the significant impact of climate change on
the catchment discharge behavior of Alpine areas, and demonstrated the
changing characteristics of flow regimes including amount, seasonality,
minima and maxima, as well as impacts on other hydrological variables, e.g.,
soil moisture and snow cover (Dobler et al., 2012; Jasper et al., 2004;
Kunstmann et al., 2004; Middelkoop et al., 2001; Rössler et al., 2012;
Zierl and Bugmann, 2005). Taylor et al. (2013) highlighted the impact of
changing climatic conditions on aquifer dynamics in mountainous areas. They
also pointed out that the effects of receding Alpine glaciers on groundwater
systems are poorly understood. Gremaud et al. (2009) and Gremaud and
Goldscheider (2010) studied a geologically complex, glacierized karst
catchment in the Alps by combining tracer tests and hydrological monitoring and
found that the changing hydro-meteorological conditions affect the water
storage in snow and ice significantly, which have high impact on the aquifer
recharge processes and discharge dynamics. Finger et al. (2013) investigated
glacier meltwater runoff in a high Alpine karst catchment under present and
future climate conditions using tracer experiments, karst structure modeling
and glacier melt modeling. The results indicated that parts of the glacier
meltwater are drained seasonally by the underlying karst system and the expected
climate change may jeopardize the water availability in the karst aquifer.
In order to better understand climate-change effects on complex hydrological
processes in Alpine karstic environments, we assessed the impacts of varied
climate conditions on the water fluxes and storages in the simulated model
domain, and we identified the hydrological processes most sensitive to
potential climate change. For this analysis, we used a pragmatic and widely
used delta approach to project the climate change in the model domain (e.g.,
Dobler et al., 2012; Lenderink et al., 2007; Singh et al., 2014).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><caption><p id="d1e146"><bold>(a)</bold> Location of the study area, <bold>(b)</bold> digital elevation model with grid
size 100 m <inline-formula><mml:math id="M1" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 100 m for the studied catchment and its surrounding
area with weather stations used for the interpolation of meteorological
parameters and <bold>(c)</bold> model configuration (modified from Chen and Goldscheider, 2014).</p></caption>
        <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://hess.copernicus.org/articles/22/3807/2018/hess-22-3807-2018-f01.png"/>

      </fig>

</sec>
<sec id="Ch1.S2">
  <title>Study area</title>
      <p id="d1e176">The study catchment is located in the northern Alps on the Germany/Austria
border (Fig. 1a). It has an area of about 35 km<inline-formula><mml:math id="M2" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>, and an altitude
varying between 1000 m a.s.l. (the lowest part of the Schwarzwasser valley) and
2230 m a.s.l. (the summit of Hochifen). The climate in the area is
cool-temperate and humid. The nearest permanent weather station lies to the
east in the Breitach valley at an altitude of 1140 m a.s.l. There, the mean
monthly temperature ranges from <inline-formula><mml:math id="M3" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>2.2 <inline-formula><mml:math id="M4" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C in January to 14.4 <inline-formula><mml:math id="M5" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C in July, with an annual average of 5.7 <inline-formula><mml:math id="M6" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (based on
data from 1961 to 1990, available from the Water Authority Vorarlberg). The mean
annual precipitation is 1836 mm with a maximum in June–August and a
secondary maximum in December–January. Snow accumulates commonly between
November and May.</p>
      <p id="d1e222">Hydrogeologically, the investigated catchment can be divided into karst and
non-karst areas, whose boundary is more or less marked by the Schwarzwasser
river. The karst area is characterized by the highly permeable Schrattenkalk
limestone formation (with about 100 m thickness), which is<?pagebreak page3809?> underlain by marl
formations. The underground flow paths in the karst system are controlled by
local folds and follow plunging synclines. The karst aquifer discharges at
three major system outlets: a permanent spring (QS), a large but
intermittent overflow spring (QA) and a cave that acts as overflow spring
during high-flow conditions, but transforms into a swallow hole during
low-flow conditions, a so-called estavelle (QE). The adjacent non-karst area
consists of low-permeability Flysch formations and drains via surface
streams. Several quantitative multi-tracer tests (Goldscheider, 2005;
Göppert and Goldscheider, 2008; Sinreich et al., 2002) revealed two
parallel drainage systems in this valley: a surface stream and a continuous
underground karst drainage system along the valley axis, which are
hydraulically connected via the estavelle and by diffuse seepage further
upstream.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2" specific-use="star"><caption><p id="d1e227"><bold>(a)</bold> Model concept for the subcatchments in the non-karst area and
<bold>(b)</bold> model concept for the subcatchments in the karst area.</p></caption>
        <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://hess.copernicus.org/articles/22/3807/2018/hess-22-3807-2018-f02.png"/>

      </fig>

</sec>
<sec id="Ch1.S3">
  <title>Methodology</title>
<sec id="Ch1.S3.SS1">
  <title>Setup of the catchment model</title>
      <p id="d1e252">The numerical model tested and evaluated in this manuscript is an improved
version of the model introduced in the study by Chen and Goldscheider (2014), which in turn has been derived from the distributed
hydrologic–hydraulic water quality simulation model – the Storm Water
Management Model (SWMM, version 5.0), described in Rossman (2010). The
hydrological conceptual model was developed mainly based on the geologic
study by Wagner (1950), the speleological investigation by the regional
caving club (Höhlenverein Sonthofen, 2006) and numerous tracer tests and
hydrogeological field observations by Goldscheider (2005). Additional tracer
experiments by Göppert and Goldscheider (2008) and Sinreich et al. (2002) improved this conceptual model. The current catchment model is
constructed by using a combined lumped and distributed modeling approach.
Basically, the lumped model represents water storage and drainage in the
soil and epikarst. The distributed model represents the underground karst
drainage network in the karst area, and the network of surface streams in
the non-karst area; these linear structures drain the flow generated from
the lumped model. Compared to the earlier catchment model by Chen and
Goldscheider (2014), new developments are (1) the updated model adopts the
HBV-snow routine and is able to simulate snow storage and snowmelt and their
influence on groundwater recharge processes (described in Sect. 3.3). (2)
The earlier model considers baseflow (slow flow) as a constant value, which
is<?pagebreak page3810?> insufficient for long-term climate-change impact predictions; in the
updated model, we applied the linear reservoir approach by Hartmann et al. (2011) to simulate transient slow-flow components, depending on groundwater
recharge and recession coefficient. (3) The laterally adjacent and
hydrogeologically connected non-karst area is included in the current model
domain; the updated model is able to simulate variable infiltration of
surface runoff from the non-karst area into the underground karst drainage
network. (4) In the updated model, the spatial discretization of the
catchment area is much finer by using the elevation bands approach, which
allows for a better representation of the spatial variability in
meteorological variables.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><caption><p id="d1e257">Strategy for the multi-step model calibration, where LF, MF and HF
are for low-, medium- and high-flow conditions, respectively.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://hess.copernicus.org/articles/22/3807/2018/hess-22-3807-2018-f03.png"/>

        </fig>

      <p id="d1e266">Due to the new developments, the current model is able to simultaneously simulate
all system outlets for a complete hydrological year,
including periods of snow accumulation, snowmelt and rainfall; additionally,
the current model is able to reproduce system discharge behavior during
drought periods, as the system baseflow was implemented as a function of
groundwater recharge and recession coefficient. In this study, the
simulation started in late autumn (November 2013), during very low-flow
condition. The discharge of QS during this time consists of slow-flow
components from the karst aquifer. This hydrologic state was used to define
the initial model condition. In total, 76 model parameters (Supplement) are
considered for the model setup: (1) model parameters <inline-formula><mml:math id="M7" display="inline"><mml:mrow><mml:mi>x</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula>–<inline-formula><mml:math id="M8" display="inline"><mml:mrow><mml:mi>x</mml:mi><mml:mn mathvariant="normal">20</mml:mn></mml:mrow></mml:math></inline-formula>
define the main hydrological processes of the unsaturated zone in the
individual karst subcatchments and the top layer of the low-permeability
Flysch rocks, (2) model parameters <inline-formula><mml:math id="M9" display="inline"><mml:mrow><mml:mi>x</mml:mi><mml:mn mathvariant="normal">21</mml:mn></mml:mrow></mml:math></inline-formula>–<inline-formula><mml:math id="M10" display="inline"><mml:mrow><mml:mi>x</mml:mi><mml:mn mathvariant="normal">76</mml:mn></mml:mrow></mml:math></inline-formula> describe the geometry and
hydraulic properties of the karst drainage conduit network as well as
surface stream channels in the non-karst area.</p>
</sec>
<sec id="Ch1.S3.SS2">
  <title>Monitoring network and data availability</title>
      <p id="d1e315">Four observation locations in the studied catchment were considered here:
(1) QS at 1035 m a.s.l. in the valley, (2) QA at 1080 m a.s.l., (3) QE at 1120 m a.s.l.
and (4) a gauging station (SR) at 1122 m a.s.l. quantifying the surface
runoff from the upper part of Schwarzwasser valley. Hourly-measured
discharges at the above-mentioned monitoring stations are used, whereas the
measurements for QS and QA are available from November 2013 to October 2014
and for QE and SR only from July to October 2014. For the same period, we
interpolated the meteorological data (hourly precipitation, air temperature
and relative humidity) from nine weather stations (Fig. 1b) across the study
catchment at a 100 m <inline-formula><mml:math id="M11" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 100 m grid resolution using combined inverse
distance weighting and linear regression gridding. Mean areal precipitation
and potential evapotranspiration for individual subunits are determined
based on the interpolated meteorological data, in which hourly potential
evapotranspiration is estimated using a modified Turc–Ivanov approach after
Wendling and Müller (1984), described in Conradt et al. (2013).</p>
</sec>
<sec id="Ch1.S3.SS3">
  <title>Modeling snow accumulation and melting</title>
      <?pagebreak page3811?><p id="d1e331">We applied the HBV-snow routine for simulating snow accumulation and melt.
The HBV model is described in various articles, e.g., Bergström (1975,
1995), Kollat et al. (2012) and Seibert (2000). We further modified the
calculation of snowmelt using the approach proposed by Hock (1999), to
simulate more realistic hourly-varying snowmelt in mountainous
catchments:
            <disp-formula id="Ch1.E1" content-type="numbered"><mml:math id="M12" display="block"><mml:mrow><mml:mi>M</mml:mi><mml:mo>=</mml:mo><mml:mfenced close="" open="{"><mml:mtable class="array" columnalign="left left"><mml:mtr><mml:mtd><mml:mrow><mml:mfenced close=")" open="("><mml:mrow><mml:mi mathvariant="normal">MF</mml:mi><mml:mo>+</mml:mo><mml:mi mathvariant="italic">α</mml:mi><mml:mo>×</mml:mo><mml:mi>I</mml:mi></mml:mrow></mml:mfenced><mml:mo>×</mml:mo><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>-</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>,</mml:mo></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mi>t</mml:mi><mml:mo>&gt;</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd><mml:mrow><mml:mn mathvariant="normal">0</mml:mn><mml:mo>,</mml:mo></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mi>t</mml:mi><mml:mo>≤</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:mfenced></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M13" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula> is snowmelt (mm h<inline-formula><mml:math id="M14" display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, MF is melt factor (mm h<inline-formula><mml:math id="M15" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M16" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C<inline-formula><mml:math id="M17" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>), <inline-formula><mml:math id="M18" display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula> is radiation coefficient, <inline-formula><mml:math id="M19" display="inline"><mml:mi>I</mml:mi></mml:math></inline-formula> is potential
clear-sky direct solar radiation at surface (W m<inline-formula><mml:math id="M20" display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M21" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> is measured
hourly air temperature (<inline-formula><mml:math id="M22" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) and <inline-formula><mml:math id="M23" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is threshold temperature
(<inline-formula><mml:math id="M24" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) for snow melting. The melt factor and the radiation
coefficient are empirical coefficients and can be estimated by model
calibration. The distributed potential clear-sky direct solar radiation is
dependent on surface topography and calculated with 100 m <inline-formula><mml:math id="M25" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 100 m grid resolution for the investigated area using the approach developed by
Kumar et al. (1997) and a digital elevation model for the study area.</p>
</sec>
<sec id="Ch1.S3.SS4">
  <title>Model calibration</title>
<sec id="Ch1.S3.SS4.SSS1">
  <title>Model optimization</title>
      <p id="d1e547">We used the DiffeRential Evolution Adaptive Metropolis (DREAM) by Vrugt (2016) to calibrate the model. The simultaneous minimization of the sum of
the squared errors (SSE) of multiple observed time series was applied to
constrain the model parameter space (described in Sect. 3.4.2), which was
defined based on our previous experience in the study region (Chen and
Goldscheider, 2014; Chen et al., 2017). The DREAM algorithm allows an
initial population of parameter sets to converge to a stationary sample.</p>
</sec>
<sec id="Ch1.S3.SS4.SSS2">
  <title>Calibration strategy</title>
      <p id="d1e556">In a previous comprehensive sensitivity analysis we demonstrated that the
controlling parameters exhibit varying sensitivity for different
hydrodynamic conditions and for different spatially distributed model
outlets (Chen et al., 2017). Based on this information, we outlined four
steps to calibrate the model using different hydrodynamic system conditions
and the observed time series for different outlets. Additionally, to
explicitly consider or completely remove the snow dynamic during
calibration, we divided the whole simulation period into a snow period
(November 2013–June 2014) and a rainfall period (June 2014–October
2014). There was no snow cover anywhere in the catchment during the rainfall
period.</p>
      <p id="d1e559">The multi-step calibration procedure applied here is illustrated in Fig. 3. In step 1, we used the rainfall period to constrain the model parameters
of the unsaturated zone and the drainage network during medium and high
flows. The different hydrodynamic conditions are defined using the
exceedance probability of the observed discharge at QS. In step 2, we used
the snow period to constrain the parameters of snow storage during medium
and high flows, whereas in the observation data the snow accumulation and
melting dynamics in the catchment are clearly reflected. The time series of
QS and QA are used for this calibration step. In step 3, we focused on the
low flows in the same simulation period as during step 2 to further
constrain the parameters of storage in snow, unsaturated zone and drainage
network using the observation data of QS and QA. In step 4, the ranges of
the previous parameters were constrained continuously using all flow
conditions and observation time series from all four outlets.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><caption><p id="d1e565"><bold>(a)</bold> The median (<inline-formula><mml:math id="M26" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula>) and the confidence intervals (<inline-formula><mml:math id="M27" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.025</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M28" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.975</mml:mn></mml:mrow></mml:math></inline-formula>)
of the probabilistic precipitation scenarios for years 2030, 2050 and 2070
are explicitly given as percentage change (compared to 1990) and applied for
the analysis described in Sect. 3.6. The scenarios are based on Frei (2004).
<bold>(b)</bold> The median (<inline-formula><mml:math id="M29" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula>) and the confidence intervals (<inline-formula><mml:math id="M30" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.025</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M31" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.975</mml:mn></mml:mrow></mml:math></inline-formula>)
of the probabilistic temperature scenarios for years 2030, 2050 and 2070 are
explicitly given as absolute change (compared to 1990) and applied for the
analysis described in Sect. 3.6. The scenarios are based on Frei (2004).</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="10">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right" colsep="1"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right" colsep="1"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:colspec colnum="9" colname="col9" align="right"/>
     <oasis:colspec colnum="10" colname="col10" align="right"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry namest="col2" nameend="col10" align="center"><bold>(a)</bold> Precipitation scenario (%) </oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Season</oasis:entry>
         <oasis:entry rowsep="1" namest="col2" nameend="col4" align="center" colsep="1">2030 </oasis:entry>
         <oasis:entry rowsep="1" namest="col5" nameend="col7" align="center" colsep="1">2050 </oasis:entry>
         <oasis:entry rowsep="1" namest="col8" nameend="col10" align="center">2070 </oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M32" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.025</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M33" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M34" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.975</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M35" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.025</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M36" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M37" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.975</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M38" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.025</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M39" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M40" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.975</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Dec/Jan/Feb</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M41" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M42" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M43" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">11</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M44" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M45" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">8</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M46" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">21</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M47" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M48" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">11</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M49" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">30</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Mar/Apr/May</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M50" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">0</oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M51" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M52" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">11</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M53" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M54" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">10</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M55" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">15</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M56" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M57" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">13</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Jun/Jul/Aug</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M58" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">18</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M59" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M60" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M61" display="inline"><mml:mn mathvariant="normal">31</mml:mn></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M62" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">17</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M63" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">7</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M64" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">41</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M65" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">23</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M66" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Sep/Oct/Nov</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M67" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">8</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M68" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">0</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M69" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">14</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M70" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M71" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M72" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">20</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M73" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M74" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry namest="col2" nameend="col10" align="center"><bold>(b)</bold> Temperature scenario (<inline-formula><mml:math id="M75" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) </oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Season</oasis:entry>
         <oasis:entry rowsep="1" namest="col2" nameend="col4" align="center" colsep="1">2030 </oasis:entry>
         <oasis:entry rowsep="1" namest="col5" nameend="col7" align="center" colsep="1">2050 </oasis:entry>
         <oasis:entry rowsep="1" namest="col8" nameend="col10" align="center">2070 </oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M76" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.025</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M77" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M78" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.975</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M79" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.025</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M80" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M81" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.975</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M82" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.025</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M83" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M84" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.975</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Dec/Jan/Feb</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M85" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.4</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M86" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M87" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.8</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M88" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.9</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M89" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.8</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M90" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">3.4</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M91" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.2</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M92" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.6</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M93" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">4.7</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Mar/Apr/May</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M94" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.4</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M95" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.9</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M96" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.8</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M97" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.8</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M98" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.8</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M99" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">3.3</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M100" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M101" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.5</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M102" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">4.8</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Jun/Jul/Aug</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M103" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.6</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M104" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.4</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M105" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.6</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M106" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.4</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M107" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.7</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M108" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">4.7</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M109" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.9</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M110" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">3.8</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M111" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">7</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Sep/Oct/Nov</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M112" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M113" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M114" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.8</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M115" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M116" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">2.1</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M117" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">3.5</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M118" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1.7</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M119" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M120" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">5.2</mml:mn></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4" specific-use="star"><caption><p id="d1e1770">Observed and simulated discharge of four spatially distributed
model outlets QS, QA, QE and SR using the best calibrated model parameter
set for the period November 2013–October 2014. Additionally, the mean
catchment precipitation and temperature for the same period are shown.</p></caption>
            <?xmltex \igopts{width=497.923228pt}?><graphic xlink:href="https://hess.copernicus.org/articles/22/3807/2018/hess-22-3807-2018-f04.png"/>

          </fig>

      <?pagebreak page3813?><p id="d1e1779">The error function used in DREAM is the SSE values defined in
individual calibration steps (Eq. 3 for step 1 and 4; Eq. 4 for step 2 and
3):
              <disp-formula id="Ch1.E2" content-type="numbered"><mml:math id="M121" display="block"><mml:mrow><mml:mi mathvariant="normal">SSE</mml:mi><mml:mo>=</mml:mo><mml:msubsup><mml:mo>∑</mml:mo><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow><mml:mi>N</mml:mi></mml:msubsup><mml:msup><mml:mfenced close=")" open="("><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">o</mml:mi></mml:mrow></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">s</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:mfenced><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
            where <inline-formula><mml:math id="M122" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">o</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is the observed discharge at time step <inline-formula><mml:math id="M123" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M124" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">s</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is the
simulated discharge at time step <inline-formula><mml:math id="M125" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M126" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> is the number of measurements in
the selected time series.

                  <disp-formula specific-use="align" content-type="numbered"><mml:math id="M127" display="block"><mml:mtable displaystyle="true"><mml:mlabeledtr id="Ch1.E3"><mml:mtd/><mml:mtd><mml:mstyle displaystyle="true" class="stylechange"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msub><mml:mi mathvariant="normal">SSE</mml:mi><mml:mrow><mml:mi mathvariant="normal">Objective</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="normal">SSE</mml:mi><mml:mi mathvariant="normal">QS</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="normal">SSE</mml:mi><mml:mi mathvariant="normal">QA</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="normal">SSE</mml:mi><mml:mi mathvariant="normal">QE</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="normal">SSE</mml:mi><mml:mi mathvariant="normal">SR</mml:mi></mml:msub></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E4"><mml:mtd/><mml:mtd><mml:mstyle displaystyle="true" class="stylechange"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msub><mml:mi mathvariant="normal">SSE</mml:mi><mml:mrow><mml:mi mathvariant="normal">Objective</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="normal">SSE</mml:mi><mml:mi mathvariant="normal">QS</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi mathvariant="normal">SSE</mml:mi><mml:mi mathvariant="normal">QA</mml:mi></mml:msub></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

              For each calibration step, 5000 parameter sets were generated using
Latin hypercube sampling within the defined prior parameter ranges. The last 1000
parameter sets of the converged sample in each calibration step are used to
represent the posterior distribution of “best” parameter sets. Posterior
parameter bounds are determined using the 95 % confidence interval for
these 1000 parameter sets. The parameter bounds of a previous step were
adopted as a-priori parameter bounds for the subsequent calibration step.</p>
</sec>
</sec>
<sec id="Ch1.S3.SS5">
  <title>Estimation of water storage</title>
      <p id="d1e1973">To understand water storage processes within the catchment, we estimated the
temporary water storage volumes for the entire catchment (Eq. 5), karst area
(Eq. 6) and non-karst area (Eq. 7):

                <disp-formula specific-use="align" content-type="numbered"><mml:math id="M128" display="block"><mml:mtable displaystyle="true"><mml:mtr><mml:mtd><mml:mstyle displaystyle="true" class="stylechange"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">catchment</mml:mi></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="normal">karstaquifer</mml:mi></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:munderover><mml:mo movablelimits="false">∑</mml:mo><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow><mml:mi>t</mml:mi></mml:munderover><mml:mo>(</mml:mo><mml:msub><mml:mi>P</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">catchment</mml:mi></mml:mrow></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="normal">ET</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">catchment</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:mtd></mml:mtr><mml:mlabeledtr id="Ch1.E5"><mml:mtd/><mml:mtd><mml:mstyle displaystyle="true" class="stylechange"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><?xmltex \hspace*{5mm}?><mml:mo>-</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">catchment</mml:mi></mml:mrow></mml:msub><mml:mo>)</mml:mo><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mtr><mml:mtd><mml:mstyle class="stylechange" displaystyle="true"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">karst</mml:mi></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="normal">karstaquifer</mml:mi></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:munderover><mml:mo movablelimits="false">∑</mml:mo><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow><mml:mi>t</mml:mi></mml:munderover><mml:mo>(</mml:mo><mml:msub><mml:mi>P</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">karst</mml:mi></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>R</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">allogenic</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:mtd></mml:mtr><mml:mlabeledtr id="Ch1.E6"><mml:mtd/><mml:mtd><mml:mstyle class="stylechange" displaystyle="true"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><?xmltex \hspace*{5mm}?><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="normal">ET</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">karst</mml:mi></mml:mrow></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">karst</mml:mi></mml:mrow></mml:msub><mml:mo>)</mml:mo><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mtr><mml:mtd><mml:mstyle class="stylechange" displaystyle="true"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">nonkarst</mml:mi></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:munderover><mml:mo movablelimits="false">∑</mml:mo><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow><mml:mi>t</mml:mi></mml:munderover><mml:mo>(</mml:mo><mml:msub><mml:mi>P</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">nonkarst</mml:mi></mml:mrow></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi>R</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">allogenic</mml:mi></mml:mrow></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="normal">ET</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">nonkarst</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:mtd></mml:mtr><mml:mlabeledtr id="Ch1.E7"><mml:mtd/><mml:mtd><mml:mstyle displaystyle="true" class="stylechange"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><?xmltex \hspace*{5mm}?><mml:mo>-</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">nonkarst</mml:mi></mml:mrow></mml:msub><mml:mo>)</mml:mo><mml:mo>.</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

            Surface runoff from the non-karst area can infiltrate into the underground
karst drainage network through the conduits C34–C38 constructed in the
upper part of the valley (Fig. 1c). This flow is considered as allogenic
recharge into the karst aquifer and was taken into account for the storage
calculation for the karst and non-karst areas. Additionally we simulated the
temporary subsurface water storage volume for the karst aquifer (Eq. 8):

                <disp-formula specific-use="align" content-type="numbered"><mml:math id="M129" display="block"><mml:mtable displaystyle="true"><mml:mtr><mml:mtd><mml:mstyle class="stylechange" displaystyle="true"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">karstaquifer</mml:mi></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="normal">karstaquifer</mml:mi></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:munderover><mml:mo movablelimits="false">∑</mml:mo><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow><mml:mi>t</mml:mi></mml:munderover><mml:mo>(</mml:mo><mml:msub><mml:mi>R</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">autogenic</mml:mi></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>R</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">allogenic</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:mtd></mml:mtr><mml:mlabeledtr id="Ch1.E8"><mml:mtd/><mml:mtd><mml:mstyle class="stylechange" displaystyle="true"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><?xmltex \hspace*{5mm}?><mml:mo>-</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">karst</mml:mi></mml:mrow></mml:msub><mml:mo>)</mml:mo><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

            where <inline-formula><mml:math id="M130" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mi>t</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M131" display="inline"><mml:mrow><mml:msub><mml:mi>P</mml:mi><mml:mi>t</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, ET<inline-formula><mml:math id="M132" display="inline"><mml:msub><mml:mi/><mml:mi>t</mml:mi></mml:msub></mml:math></inline-formula>, <inline-formula><mml:math id="M133" display="inline"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi>t</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M134" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi>t</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> are the storage,
precipitation, evapotranspiration, recharge and discharge in volume at time
step t (<inline-formula><mml:math id="M135" display="inline"><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is first simulation time step). The simulated temporary
storage volumes for the whole catchment (<inline-formula><mml:math id="M136" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">catchment</mml:mi></mml:mrow></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, karst area
(<inline-formula><mml:math id="M137" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">karst</mml:mi></mml:mrow></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, non-karst area (<inline-formula><mml:math id="M138" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">nonkarst</mml:mi></mml:mrow></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and karst aquifer
(<inline-formula><mml:math id="M139" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">karstaquifer</mml:mi></mml:mrow></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> are the absolute volumes, whereas the storage for the
karst aquifer (<inline-formula><mml:math id="M140" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>,</mml:mo><mml:mi mathvariant="normal">karstaquifer</mml:mi></mml:mrow></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> only describes the ground water storage
in the karst aquifer. The calculation of the initial water storage volume in
the karst aquifer is based on the approach introduced by Bonacci (1993):
            <disp-formula id="Ch1.E9" content-type="numbered"><mml:math id="M141" display="block"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="normal">karstaquifer</mml:mi></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:mi>k</mml:mi><mml:mo>×</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="normal">karstaquifer</mml:mi></mml:mrow></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M142" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mrow><mml:msub><mml:mi>t</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>,</mml:mo><mml:mi mathvariant="normal">karstaquifer</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is the discharge from the karst aquifer at
the first simulation time step and <inline-formula><mml:math id="M143" display="inline"><mml:mi>k</mml:mi></mml:math></inline-formula> is the recession coefficient, which can
be derived by analyzing the karst spring discharge hydrograph during low-flow conditions.</p>
</sec>
<sec id="Ch1.S3.SS6">
  <title>Climate-change projections</title>
      <p id="d1e2593">The focus of this analysis is to quantify the impact of varying climate
conditions on the water fluxes and storages throughout the model domain and
to identify the hydrological processes most sensitive to potential climate
change within the study catchment. We chose the probabilistic scenarios of
precipitation and temperature by Frei (2004) for the northern Alps as the
basis for our study. The median values (<inline-formula><mml:math id="M144" display="inline"><mml:mi>q</mml:mi></mml:math></inline-formula>0.5) and the confidence intervals
(<inline-formula><mml:math id="M145" display="inline"><mml:mi>q</mml:mi></mml:math></inline-formula>0.025 to <inline-formula><mml:math id="M146" display="inline"><mml:mi>q</mml:mi></mml:math></inline-formula>0.975) of the probabilistic scenarios for years 2030, 2050 and
2070 were derived in Frei (2004) and given in Table 1. We used a delta
approach to project the potential climate-change scenarios in the
investigated catchment by changing precipitation and temperature time series
for the pre-defined months (December–February, March–May, June–August and
September–November) by a given delta (percentage or value). For the
analysis, we first focused on the median climate scenarios of years 2030, 2050 and
2070 (described in Sect. 4.3.1) to better understand the general trend of
the climate-change projections. In the second part of the analysis, we
considered the uncertainty in the climate scenario for 2070 and estimated
its impact on the simulated water fluxes and storages across the model
domain (described in Sect. 4.3.2). To consider the climate-change scenario
uncertainty, 1000 uniformly distributed random samples within the defined
confidence intervals for the deltas of precipitation and temperature are
used.</p>
</sec>
</sec>
<sec id="Ch1.S4">
  <title>Results</title>
<sec id="Ch1.S4.SS1">
  <title>Model performance</title>
      <p id="d1e2629">Figure 4 shows the simulated karst spring discharges as well as the surface
runoff generated from the non-karst area of the final calibrated model. The
transient and highly variable discharge behavior at the four
spatially distributed model outlets is simultaneously simulated at an hourly
time step. The quality of the model simulation is demonstrated by two
different statistical criteria, the RMSE and the Nash–Sutcliffe coefficient (NSC):
RMSE values are 0.118 m<inline-formula><mml:math id="M147" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> s<inline-formula><mml:math id="M148" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for QS, 0.448 m<inline-formula><mml:math id="M149" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> s<inline-formula><mml:math id="M150" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for QA, 0.419 m<inline-formula><mml:math id="M151" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> s<inline-formula><mml:math id="M152" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for QE and
0.248 m<inline-formula><mml:math id="M153" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> s<inline-formula><mml:math id="M154" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for SR. NSC values are 0.71 for QS, 0.80 for QA, 0.74 for QE and
0.66 for SR. However, only one complete hydrological year of data can be
obtained in the test site and used for this study. To better evaluate the
model, we performed a split-sample test with the existing data
(Supplement) that showed that we can obtain stable model
parameterization and prediction with this relatively short observation
period.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5" specific-use="star"><caption><p id="d1e2719">Estimated cumulative volumes of precipitation, evapotranspiration,
recharge and discharge for the studied catchment for the period November
2013–October 2014 on an hourly time step in million cubic meters (MCM).</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://hess.copernicus.org/articles/22/3807/2018/hess-22-3807-2018-f05.png"/>

        </fig>

<?xmltex \hack{\newpage}?>
</sec>
<?pagebreak page3814?><sec id="Ch1.S4.SS2">
  <title>Estimated water fluxes and storages</title>
      <p id="d1e2736">For a simulation period of about 330 days, we estimated that about 5 % of
the total precipitation (52.79 MCM<fn id="Ch1.Footn1"><p id="d1e2739">MCM for million cubic meters</p></fn>)
left the catchment as evapotranspiration (2.39 MCM) (Fig. 5). Furthermore, we
calculated that about 84 % of the recharge (44.02 MCM) to the karst
aquifer is contributed by diffuse infiltration (36.78 MCM) over the karst
area. The remaining 16 % of the recharge is contributed by the allogenic
recharge (7.24 MCM); i.e., direct infiltration of the surface runoff from the
non-karst area into the underground karst drainage network in the upper part
of the valley. The catchment is mainly drained by the karst springs. About
20 % of the total catchment discharge (49.41 MCM) is provided by QS
(10.09 MCM), 44 % by QA (21.81 MCM), 23 % by QE (11.29 MCM) and
13 % by the surface runoff (6.23 MCM).</p>
      <p id="d1e2743">We compared the estimated water storages for the whole catchment, karst
area, non-karst area and karst aquifer to better understand different
storage processes (snow storage, soil water storage and subsurface water
storage) in the model domain (Fig. 6). It is considered that in the
simulated winter and early spring (November 2013–March 2014), the
catchment water storage dynamics are mainly characterized by snow storage
change in both the karst and non-karst areas. Afterwards, snowmelt (April–May 2014) led to rapidly decreasing catchment snow storage, but
increasing storage in the karst aquifer as subsurface water in both fast and
slow paths. During the rainfall season in the simulated summer and autumn
(June–October 2014), the catchment storage is mainly characterized by
subsurface water storage in the karst aquifer, while during medium and high
flows the water is also stored intermittently in the top layer of the
non-karst area.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T2" specific-use="star"><caption><p id="d1e2749"><bold>(a)</bold> Estimated total volume of precipitation (<inline-formula><mml:math id="M155" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula>), evapotranspiration
(ET), recharge (<inline-formula><mml:math id="M156" display="inline"><mml:mi>R</mml:mi></mml:math></inline-formula>) and discharge (<inline-formula><mml:math id="M157" display="inline"><mml:mi>Q</mml:mi></mml:math></inline-formula>) under varied climate conditions (median
climate scenarios of years 2030, 2050 and 2070 as well as the uncertainty in the
climate scenario of 2070) for the simulated time period of 330 days and
their units are MCM. <bold>(b)</bold> Estimated temporary water storage volumes (<inline-formula><mml:math id="M158" display="inline"><mml:mi>S</mml:mi></mml:math></inline-formula>) for the whole
catchment, karst area, non-karst area and karst aquifer at time step of 2665
(March) and 7896 (October) under varied climate conditions (median climate
scenarios of years 2030, 2050 and 2070 as well as the uncertainty in the climate
scenario of 2070) and their units are MCM.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="5">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1"><bold>(a)</bold> Climate condition</oasis:entry>
         <oasis:entry rowsep="1" colname="col2"><inline-formula><mml:math id="M159" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry rowsep="1" colname="col3">ET</oasis:entry>
         <oasis:entry rowsep="1" colname="col4"><inline-formula><mml:math id="M160" display="inline"><mml:mi>R</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry rowsep="1" colname="col5"><inline-formula><mml:math id="M161" display="inline"><mml:mi>Q</mml:mi></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Catchment</oasis:entry>
         <oasis:entry colname="col3">Catchment</oasis:entry>
         <oasis:entry colname="col4">Catchment</oasis:entry>
         <oasis:entry colname="col5">Catchment</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">current</oasis:entry>
         <oasis:entry colname="col2">52.79</oasis:entry>
         <oasis:entry colname="col3">2.39</oasis:entry>
         <oasis:entry colname="col4">44.02</oasis:entry>
         <oasis:entry colname="col5">49.41</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2030</oasis:entry>
         <oasis:entry colname="col2">50.58</oasis:entry>
         <oasis:entry colname="col3">2.52</oasis:entry>
         <oasis:entry colname="col4">42.08</oasis:entry>
         <oasis:entry colname="col5">47.32</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2050</oasis:entry>
         <oasis:entry colname="col2">48.48</oasis:entry>
         <oasis:entry colname="col3">2.66</oasis:entry>
         <oasis:entry colname="col4">40.15</oasis:entry>
         <oasis:entry colname="col5">45.33</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2070</oasis:entry>
         <oasis:entry colname="col2">46.97</oasis:entry>
         <oasis:entry colname="col3">2.77</oasis:entry>
         <oasis:entry colname="col4">38.76</oasis:entry>
         <oasis:entry colname="col5">43.91</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2070 max</oasis:entry>
         <oasis:entry colname="col2">53.15</oasis:entry>
         <oasis:entry colname="col3">3.34</oasis:entry>
         <oasis:entry colname="col4">43.74</oasis:entry>
         <oasis:entry colname="col5">49.33</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">2070 min</oasis:entry>
         <oasis:entry colname="col2">38.87</oasis:entry>
         <oasis:entry colname="col3">2.35</oasis:entry>
         <oasis:entry colname="col4">32.10</oasis:entry>
         <oasis:entry colname="col5">36.80</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry rowsep="1" namest="col2" nameend="col5" align="center"><inline-formula><mml:math id="M162" display="inline"><mml:mi>Q</mml:mi></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">QS</oasis:entry>
         <oasis:entry colname="col3">QA</oasis:entry>
         <oasis:entry colname="col4">QE</oasis:entry>
         <oasis:entry colname="col5">SR</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">current</oasis:entry>
         <oasis:entry colname="col2">10.09</oasis:entry>
         <oasis:entry colname="col3">21.81</oasis:entry>
         <oasis:entry colname="col4">11.29</oasis:entry>
         <oasis:entry colname="col5">6.23</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2030</oasis:entry>
         <oasis:entry colname="col2">9.88</oasis:entry>
         <oasis:entry colname="col3">21.35</oasis:entry>
         <oasis:entry colname="col4">10.26</oasis:entry>
         <oasis:entry colname="col5">5.83</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2050</oasis:entry>
         <oasis:entry colname="col2">9.69</oasis:entry>
         <oasis:entry colname="col3">20.99</oasis:entry>
         <oasis:entry colname="col4">9.14</oasis:entry>
         <oasis:entry colname="col5">5.51</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2070</oasis:entry>
         <oasis:entry colname="col2">9.56</oasis:entry>
         <oasis:entry colname="col3">20.89</oasis:entry>
         <oasis:entry colname="col4">8.17</oasis:entry>
         <oasis:entry colname="col5">5.28</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2070 max</oasis:entry>
         <oasis:entry colname="col2">10.15</oasis:entry>
         <oasis:entry colname="col3">23.96</oasis:entry>
         <oasis:entry colname="col4">10.09</oasis:entry>
         <oasis:entry colname="col5">6.04</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">2070 min</oasis:entry>
         <oasis:entry colname="col2">8.80</oasis:entry>
         <oasis:entry colname="col3">17.70</oasis:entry>
         <oasis:entry colname="col4">5.27</oasis:entry>
         <oasis:entry colname="col5">4.28</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><bold>(b)</bold> Climate condition</oasis:entry>
         <oasis:entry rowsep="1" namest="col2" nameend="col5" align="center"><inline-formula><mml:math id="M163" display="inline"><mml:mi>S</mml:mi></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry rowsep="1" namest="col2" nameend="col5" align="center">At time step of 2665 (March) </oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Whole catchment</oasis:entry>
         <oasis:entry colname="col3">Karst area</oasis:entry>
         <oasis:entry colname="col4">Non-karst area</oasis:entry>
         <oasis:entry colname="col5">Karst aquifer</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">current</oasis:entry>
         <oasis:entry colname="col2">10.87</oasis:entry>
         <oasis:entry colname="col3">8.66</oasis:entry>
         <oasis:entry colname="col4">2.21</oasis:entry>
         <oasis:entry colname="col5">2.89</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2030</oasis:entry>
         <oasis:entry colname="col2">10.63</oasis:entry>
         <oasis:entry colname="col3">8.49</oasis:entry>
         <oasis:entry colname="col4">2.15</oasis:entry>
         <oasis:entry colname="col5">2.97</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2050</oasis:entry>
         <oasis:entry colname="col2">10.03</oasis:entry>
         <oasis:entry colname="col3">8.07</oasis:entry>
         <oasis:entry colname="col4">1.96</oasis:entry>
         <oasis:entry colname="col5">3.09</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2070</oasis:entry>
         <oasis:entry colname="col2">8.89</oasis:entry>
         <oasis:entry colname="col3">7.20</oasis:entry>
         <oasis:entry colname="col4">1.69</oasis:entry>
         <oasis:entry colname="col5">3.29</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2070 max</oasis:entry>
         <oasis:entry colname="col2">9.95</oasis:entry>
         <oasis:entry colname="col3">7.99</oasis:entry>
         <oasis:entry colname="col4">1.97</oasis:entry>
         <oasis:entry colname="col5">4.25</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">2070 min</oasis:entry>
         <oasis:entry colname="col2">4.86</oasis:entry>
         <oasis:entry colname="col3">4.57</oasis:entry>
         <oasis:entry colname="col4">0.28</oasis:entry>
         <oasis:entry colname="col5">2.99</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry rowsep="1" namest="col2" nameend="col5" align="center"><inline-formula><mml:math id="M164" display="inline"><mml:mi>S</mml:mi></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry rowsep="1" namest="col2" nameend="col5" align="center">At time step of 7896 (October) </oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Whole catchment</oasis:entry>
         <oasis:entry colname="col3">Karst area</oasis:entry>
         <oasis:entry colname="col4">Non-karst area</oasis:entry>
         <oasis:entry colname="col5">Karst aquifer</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">current</oasis:entry>
         <oasis:entry colname="col2">5.66</oasis:entry>
         <oasis:entry colname="col3">5.50</oasis:entry>
         <oasis:entry colname="col4">0.16</oasis:entry>
         <oasis:entry colname="col5">5.50</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2030</oasis:entry>
         <oasis:entry colname="col2">5.40</oasis:entry>
         <oasis:entry colname="col3">5.25</oasis:entry>
         <oasis:entry colname="col4">0.15</oasis:entry>
         <oasis:entry colname="col5">5.25</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2050</oasis:entry>
         <oasis:entry colname="col2">5.15</oasis:entry>
         <oasis:entry colname="col3">5.00</oasis:entry>
         <oasis:entry colname="col4">0.15</oasis:entry>
         <oasis:entry colname="col5">5.00</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2070</oasis:entry>
         <oasis:entry colname="col2">4.96</oasis:entry>
         <oasis:entry colname="col3">4.81</oasis:entry>
         <oasis:entry colname="col4">0.15</oasis:entry>
         <oasis:entry colname="col5">4.81</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2070 max</oasis:entry>
         <oasis:entry colname="col2">5.34</oasis:entry>
         <oasis:entry colname="col3">5.19</oasis:entry>
         <oasis:entry colname="col4">0.15</oasis:entry>
         <oasis:entry colname="col5">5.19</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2070 min</oasis:entry>
         <oasis:entry colname="col2">4.38</oasis:entry>
         <oasis:entry colname="col3">4.24</oasis:entry>
         <oasis:entry colname="col4">0.14</oasis:entry>
         <oasis:entry colname="col5">4.24</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

</sec>
<sec id="Ch1.S4.SS3">
  <title>Assessing the impact of climate change</title>
      <p id="d1e3411">An overview of the change in water fluxes and storages under changing
climate conditions (median climate scenarios and uncertainty in the climate
scenario 2070) is given in Table 2.</p>
<sec id="Ch1.S4.SS3.SSS1">
  <title>Median climate scenarios</title>
      <p id="d1e3419">The simulations (Figs. 7–9) show that the water fluxes and storages are
sensitive to varying climate conditions. Compared to the current situation,
the precipitation over the catchment area is gradually decreasing (medians
of <inline-formula><mml:math id="M165" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>4.2, <inline-formula><mml:math id="M166" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>8.2 and <inline-formula><mml:math id="M167" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>11.0 %) for the climate scenarios of years 2030,
2050 and 2070, respectively, based on Frei (2004), whereas the evapotranspiration is
increasing (medians of <inline-formula><mml:math id="M168" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>5.5, <inline-formula><mml:math id="M169" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>11.4 and <inline-formula><mml:math id="M170" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>16.0 %). The
modeled precipitation, temperature and evapotranspiration for future
simulations contribute to the decreased recharge (medians of <inline-formula><mml:math id="M171" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>4.4, <inline-formula><mml:math id="M172" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>8.8 and
<inline-formula><mml:math id="M173" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>12.0 %) to the karst aquifer, whereas the recharge pattern is shifted,
i.e., the recharge is increasing in winter and spring and decreasing in
summer and autumn (Fig. 7).</p>
      <?pagebreak page3815?><p id="d1e3486">Furthermore, the catchment water storage pattern changes significantly,
especially during the normally “cold” period (from January to April).
Under the current conditions, 7.74 MCM of water is stored in snow at the end of
March, whereas at the same time, only 3.79 MCM as snow storage is estimated
there under the conditions of 2070 (Fig. 8). This indicates that the
simulated future climate conditions affect the snow storage massively.
Comparatively, the catchment water storage during the rainfall season is
much less influenced. For the karst aquifer, the shift of recharge pattern
towards increased recharge in winter and spring, and decreased recharge in
summer and autumn produces compensation, i.e., the annualized balance
between recharge and discharge for the karst aquifer is constant for the
simulations of years 2030, 2050 and 2070. Furthermore, the influence of the varied
climate conditions on the intermediate water storage in the karst aquifer
(epikarst and fast-flow path) and top layer of the non-karst area are
limited.</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F6" specific-use="star"><caption><p id="d1e3491">Estimated temporary water storage volumes for the whole catchment,
karst area, non-karst area and karst aquifer for the period November 2013–October 2014
on an hourly time step in million cubic meters (MCM).</p></caption>
            <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://hess.copernicus.org/articles/22/3807/2018/hess-22-3807-2018-f06.png"/>

          </fig>

      <?xmltex \floatpos{p}?><fig id="Ch1.F7" specific-use="star"><caption><p id="d1e3503">Impacts of the median climate scenarios (<inline-formula><mml:math id="M174" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula>) for years 2030, 2050 and
2070 as well as the uncertain climate scenarios (1000 random sampled
combinations) for 2070 on the simulated precipitation, evapotranspiration,
recharge and discharge for the studied catchment.</p></caption>
            <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://hess.copernicus.org/articles/22/3807/2018/hess-22-3807-2018-f07.png"/>

          </fig>

      <?pagebreak page3817?><p id="d1e3522">Our simulations (Fig. 9) show that the catchment discharge amount varies
under changing climate conditions. The total discharge of QE is decreasing
gradually (medians of 9.1, <inline-formula><mml:math id="M175" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>19.0 and <inline-formula><mml:math id="M176" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>27.6 %) for years 2030, 2050
and 2070, compared to the current situation. However, the deficit for QA
(medians of <inline-formula><mml:math id="M177" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>2.1, <inline-formula><mml:math id="M178" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>3.8 and <inline-formula><mml:math id="M179" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>4.2 %) and QS (medians of <inline-formula><mml:math id="M180" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>2.0, <inline-formula><mml:math id="M181" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>3.9 and <inline-formula><mml:math id="M182" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>5.2 %) is less significant. For the total surface
runoff generated from the non-karst area, climate-change effects are clearly
perceptible with the total runoff decreasing (medians of <inline-formula><mml:math id="M183" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>6.4, <inline-formula><mml:math id="M184" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>11.4
and <inline-formula><mml:math id="M185" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>15.1 %) for years 2030, 2050 and 2070. Also, the catchment discharge
pattern is influenced significantly. The simulated increasingly warming
winters and springs from 2030 to 2070 shift the discharge pattern of QA, QE
and surface runoff continuously, while the discharge pattern of QS is quite
stable until 2070.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F8"><caption><p id="d1e3605">Impacts of the median climate scenarios (<inline-formula><mml:math id="M186" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula>) for years 2030, 2050 and
2070 as well as the uncertain climate scenarios (1000 random sampled
combinations) for 2070 on <bold>(a)</bold> the simulated water storage of the whole
catchment, <bold>(b)</bold> the simulated snow storage of the whole catchment, <bold>(c)</bold> the
simulated water storage of the karst area, <bold>(d)</bold> the simulated snow storage of
the karst area, <bold>(e)</bold> the simulated water storage of the karst aquifer, <bold>(f)</bold> the
simulated water storage of the non-karst area and <bold>(g)</bold> the simulated snow
storage of the non-karst area.</p></caption>
            <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://hess.copernicus.org/articles/22/3807/2018/hess-22-3807-2018-f08.png"/>

          </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F9" specific-use="star"><caption><p id="d1e3648">Impacts of the median climate scenarios (<inline-formula><mml:math id="M187" display="inline"><mml:mrow><mml:mi>q</mml:mi><mml:mn mathvariant="normal">0.5</mml:mn></mml:mrow></mml:math></inline-formula>) for years 2030, 2050 and
2070 as well as the uncertain climate scenarios (1000 random sampled
combinations) for 2070 on the simulated discharge of QS, QA, QE and surface
runoff from the non-karst area.</p></caption>
            <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://hess.copernicus.org/articles/22/3807/2018/hess-22-3807-2018-f09.png"/>

          </fig>

</sec>
<sec id="Ch1.S4.SS3.SSS2">
  <title>Uncertainty in the climate scenario 2070</title>
      <p id="d1e3673">The results show (Fig. 7) that the impacts of the possible climate scenarios
for 2070 on the precipitation, evapotranspiration, recharge and catchment
discharge are uncertain. Compared to the current situation, a general trend
with the decrease in precipitation, recharge and catchment discharge or with
the increase in evapotranspiration can be expected. In the most extreme
cases, the change of precipitation varies between <inline-formula><mml:math id="M188" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>26.4 and 0.7 %,
evapotranspiration between <inline-formula><mml:math id="M189" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.8 and 39.6 %, recharge to the karst
aquifer between <inline-formula><mml:math id="M190" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>27.1 and <inline-formula><mml:math id="M191" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.6 % and catchment discharge between
<inline-formula><mml:math id="M192" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>25.5 and <inline-formula><mml:math id="M193" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.2 %, compared to the current situation. Furthermore,
the scenario runs indicate a shift of evapotranspiration, recharge and
catchment discharge pattern towards increased recharge as well as catchment
discharge in winter and spring and constantly increased evapotranspiration
throughout the year.</p>
      <p id="d1e3719">Moreover, the scenario runs indicate a clear trend with the decrease in
water storages for the simulated catchment (Fig. 8). Under the condition
“extremely warm” of 2070, the snow storage of the catchment changes so
dramatically that almost no water can be stored in snow during the normally
“cold” period (from December to April). Simultaneously, the water storage
pattern in the karst aquifer can be significantly shifted due to the
earlier-starting snowmelt. Also, the water storage in the karst aquifer in
summer and autumn are influenced strongly due to the significantly decreased
recharge. This contributes to a clearly negative “balance” at the last
time step of the simulation under the “extremely dry” conditions of 2070.
If this negative water storage could be transferred to the coming year, it
would cause more negative “balance” for the simulated karst aquifer based
on the simulated climate conditions. Accordingly, the stored water resource
in the karst aquifer would be decreased significantly.</p>
      <p id="d1e3722">Regarding the impacts of the uncertain scenarios on the karst spring
discharges and surface runoff, distinct trends are identified (Fig. 9): (1)
a clear trend with the decrease in QE and SR, (2) impacts on QA are highly
uncertain even an increase in its total discharge is projected and (3)
impacts on QS are clearly less uncertain and a general trend with decrease
in QS can be expected. In the most extreme cases, compared to the current
situation, the change of QS varies between <inline-formula><mml:math id="M194" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>25.5 and 0.7 %, QA
between <inline-formula><mml:math id="M195" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>18.8 and 9.9 %, QE between <inline-formula><mml:math id="M196" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>53.3 and <inline-formula><mml:math id="M197" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>10.6 % and
surface runoff between <inline-formula><mml:math id="M198" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>31.3 and <inline-formula><mml:math id="M199" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>2.9 %. QS discharge is
considered as the most “robust” in the face of strongly varied climate
conditions. Furthermore, a common shift of the discharge pattern of all
karst springs and the surface runoff pattern are identified, i.e., increased
QS, QA, QE and SR in winter and early spring.</p><?xmltex \hack{\newpage}?>
</sec>
</sec>
</sec>
<?pagebreak page3818?><sec id="Ch1.S5">
  <title>Discussion</title>
<sec id="Ch1.S5.SS1">
  <title>Realism of the model simulations</title>
      <p id="d1e3783">In this study, the karst catchment model simultaneously simulates the
transient and highly variable discharge behavior at the four model outlets.
The model evaluation using different approaches indicates that the results
are satisfying (described in Sect. 4.1). The previous studies have
demonstrated that the model adequately represents the hydraulic processes
observed in the karst aquifer and is able to transform them into realistic
catchment responses during rainfall periods (Chen and Goldscheider, 2014;
Chen et al., 2017). The current model represents the dominant flow process
for the investigated karst catchment during low-flow conditions. During the
snow accumulation period (November 2013–February 2014), the karst system was
undersaturated, and QS discharged the whole catchment, while other karst
springs (QA and QE) were dry and no significant surface runoff generated
from the non-karst area. The simulation is consistent with our measurements
and field observations. Furthermore, the current study shows that the snow
dynamic reflected in the major karst springs (QS and QA) is reproduced in
the model. It indicates that the model represents the recharge process
driven by the snow accumulation and melting in the studied karst catchment.
However, no snow observations to validate the accuracy of simulated snow
accumulation and melting are available. For this reason, we developed the
multi-step calibration procedure to achieve an efficient calibration of the
snow model (described in Sect. 3.4.2). To more realistically simulate snowmelt and its spatial pattern in complex mountainous topography, we applied
the extended snowmelt equation from Hock (1999) that considers the
distributed potential clear-sky direct solar radiation, which is calculated
based on a digital elevation model for the study area with 100 m resolution.
Warscher et al. (2013) pointed out that the HBV approach is too simple for
modeling distributed complex snow dynamics in mountainous environments, but
it is the best estimation that we can obtain due to the lack of data.
Therefore, the results concerning the simulated snow storage are associated
with uncertainty and should be interpreted carefully.</p>
      <p id="d1e3786">We find that the surface runoff generated from the non-karst area is much
less than the effective precipitation for the non-karst area. The reason is
that the allogenic recharge leads to significant loss. This model behavior
represents the conceptualization of our understanding about the hydraulic
connection between the karst and non-karst areas. However, the model
evaluation shows that the model underestimated the surface runoff generated
from the non-karst area in response to heavy rainfall events (Fig. 4). This
could be explained by an oversimplification of the complex hydrological
situation in the non-karst area under-representing its runoff dynamics.
Furthermore, the estimated low evapotranspiration (and very high recharge
rates) for the investigated catchment appears unusual. Very high recharge
rates in mountainous karst areas, ranging between 60 and 90 %, are
also<?pagebreak page3819?> reported in the literature (e.g., Malard et al., 2016). In Alpine
regions, low temperatures and high precipitation favor low
evapotranspiration. In the elevated parts of our test site, soil and
vegetation are almost entirely missing, and the limestone is extremely
karstified, so that water infiltrates directly into open fractures. Hence,
the high recharge rates are in accordance with our previous hydrogeological
conceptual model, which is based on detailed field investigations, including
18 tracer tests (Goldscheider, 2005; Göppert and Goldscheider, 2008;
Sinreich et al., 2002). The overall size of the karst system, the catchment
areas of the individual springs and the general configuration of the
underground drainage network are well-known. Yet, our quantification of
recharge is still associated with uncertainties. Possible reasons include the
following: (1) the interpolation of precipitation is uncertain. Most weather stations
used for interpolation are located outside the study area, at lower
elevations. Uncertainty depends on the density of observation points and the
interpolation method (e.g., Ohmer et al., 2017). Increase in precipitation
with elevation should also be taken into account. (2) Discharge quantities
during very high-flow conditions are also uncertain. Water stages were
continuously measured at all gauging stations, and numerous flow
measurements (salt-dilution method) were performed to establish rating
curves, which were used to obtain continuous hydrographs for all system
outlets. However, most flow measurements were done during low- to moderately
high-flow conditions, and the rating curves had to be extrapolated for very
high flows. Therefore, substantial uncertainties have to be expected for
very high-flow conditions (e.g., Baldassarre and Montanari, 2009; Coxon et
al., 2015). (3) Another source of uncertainty is that sublimation from snow
was not taken into account in the current model. However, some studies
suggest that snow evaporation can be significant in some high-elevation
catchments (e.g., Leydecker and Melack, 2000).</p>
</sec>
<sec id="Ch1.S5.SS2">
  <title>Hydrological process sensitivities</title>
      <p id="d1e3795">It is well known that long-term trends of karst aquifer dynamics (e.g.,
spring discharge, groundwater level) are affected mainly by regional
precipitation patterns (e.g., Ma et al., 2004; Hao et al., 2006; Jia et al.,
2017; Hartmann et al., 2012). In comparison to these earlier studies, our
current study shows significant short-term aquifer responses to changes in
hydro-meteorological conditions. The simulations demonstrate that the
seasonal discharge pattern is controlled by the temporal distribution of
precipitation on the one hand, and by the temperature pattern on the other
hand. The snow storage in the catchment is highly sensitive to temperature
variations, which can shift the seasonal patterns of snowmelt and aquifer
recharge. A similar recharge pattern that strongly depends on seasonal snow
accumulation and melting has been observed in other Alpine karst systems
(Finger et al., 2013; Gremaud, 2011). Previous studies suggest decreasing
spring discharge with increasing temperatures, as a result of increased
evapotranspiration (e.g., Loáiciga et al., 1999). Our findings suggest
that the extremely high recharge rates in our studied karst system will
reduce the impact of rising temperatures on aquifer dynamics.</p>
      <p id="d1e3798">For the studied karst aquifer, due to its characteristic duality of flow and
storage and additional spatially heterogeneous distributed drainage
structure, the impacts of the varied climate conditions on QS, QA and QE are
distinct. The simulations demonstrate well that QE is highly sensitive to
changing climate conditions. The explanation is that QE acts as the highest
overflow outlet of the studied karst aquifer, and its activation is strongly
controlled by the hydrodynamic conditions in the karst drainage network,
which are in turn highly sensitive to recharge and fast-flow processes. In
contrast, QS is the lowest outlet for the karst aquifer and its discharge is
“guaranteed” by the long-term water storage in matrix. Accordingly, QS is
the most “robust” in the face of changing climate conditions. Under the
simulated climate scenarios, QA shows a mixed character. On the one hand,
the QA discharge is significantly less influenced than QE; and on the other
hand, QA's discharge pattern can be more easily shifted than QS. It
demonstrates well that the high permeability flow in the conduit network
with less water-storage capacity is sensitive to changing hydrological
conditions, while the low-permeability flow in the matrix with greater water-storage capacity
is more resistant. In the non-karst area, the varied
climate conditions affect the snow accumulation and melting patterns. As the
non-karst and karst areas are hydraulically connected in the upper part of
the valley, the predicted earlier-starting snowmelt can generate more runoff in
the non-karst area which partly infiltrates into the underground drainage
network leading to greater loss for the surface runoff and increased
allogenic recharge to the karst aquifer.</p>
      <p id="d1e3801">For the current analysis, we used a pragmatic approach to analyze potential
climate-change scenarios. The uncertainties in the climate scenarios were
considered based on a random sampling approach. The final results
indicate the impacts of the seasonal changes in the pattern of precipitation and
temperature on the spatially varied hydrological processes within the
catchment. Additionally, we investigated the flow exceedance probability of
karst springs and surface runoff from the non-karst area (Supplement) and find that the simulated climate conditions affect the
frequency and amplitude of catchment flows. This suggests that the impacts
of the temporally stochastic distributions of meteorological parameters and
their variability on the catchment flow dynamics should be systematically
investigated.</p>
</sec>
</sec>
<sec id="Ch1.S6" sec-type="conclusions">
  <title>Conclusions</title>
      <p id="d1e3811">The current work presents an investigation of the water fluxes and storages
in a high-elevation Alpine catchment. We extended the existing karst
catchment model developed<?pagebreak page3820?> by Chen and Goldscheider (2014) to consider
spatially distributed snow dynamics and complex surface and subsurface
heterogeneous drainage structures. The new model is able to simultaneously
simulate the transient and highly variable discharge behavior of four
spatially distributed model outlets at an hourly time step. Furthermore, we
estimated the water fluxes and storages within the model domain. The results
demonstrate that the spatiotemporal distribution of water fluxes and
storages is controlled by the surface and subsurface hydrological setting.
We find a large portion of precipitation infiltrates in the karst aquifer as
autogenic recharge and contributes to surface runoff in the adjacent
non-karst area, which can partly infiltrate into the karst aquifer as
allogenic point recharge. In the simulation period, the catchment is mainly
drained by the karst springs, about 20 % of the total catchment discharge
is provided by the permanent spring QS, 44 % by the overflow spring QA,
23 % by the estavelle QE and 13 % by the surface runoff SR generated
from the non-karst area. In the simulated winter and early spring (November
2013–March 2014), the catchment water storage is mainly characterized by
the snow storage both in the karst and non-karst areas. During the rainfall
season in the simulated summer and autumn (June–October 2014), the
catchment storage is mainly characterized by the subsurface water storage in
the karst aquifer.</p>
      <p id="d1e3814">Additionally, we studied the impacts of potential climate-change patterns on
the spatially varied surface and subsurface hydrological processes in the
model using a delta approach combined with a random sampling technique. The
scenario runs demonstrate that the varied climate conditions affect the
spatiotemporal distribution of water fluxes and storages within the
catchment significantly: (1) the total catchment discharge decreases under
all evaluated future climate conditions. (2) The catchment snow storage
during the normally cold period from December to April decreases
significantly, while the autogenic and allogenic recharge to the karst
aquifer increase. (3) In the karst aquifer, due to its storage capacity, the
shift of the recharge pattern towards increased recharge in winter and spring,
and decreased recharge in summer and autumn offset each other under the
varied climate conditions. (4) The impacts of the potential future climate
conditions on the karst springs are distinct. The lowest permanent spring
presents a “robust” discharge behavior, while the highest overflow outlet
is highly sensitive to changing climatic conditions. This finding
demonstrates that climate change impacts on karst springs do not only depend
on the hydraulic characteristics of the aquifer system but also on the
topographic position of the individual springs.</p>
      <p id="d1e3817">As our climate scenario projections use a simple delta approach, the impact
of temporally stochastic distributions of meteorological parameters and
their variability could not be investigated in this study. Accordingly, the
results should only be applied to understand the relationship between the
hydrological processes within the studied catchment and potential climate
change patterns. It would be interesting to use more realistic data, i.e.,
the precipitation and temperature time series downscaled from regional
climate models, to investigate their impact on the spatially distributed
water fluxes and storages. But we warn that the measurements of
meteorological variables in high-elevation mountainous environment have a
quite large uncertainty. These uncertainties may have an impact on the model
simulations and the understanding of derived processes. Nevertheless, there
are several relevant general conclusions that can be drawn from this study.
Because of their specific hydraulic characteristics, Alpine karst aquifers
respond very fast and strong to hydrological events and seasonal variations,
including snow accumulation and melting. The seasonal patterns of
precipitation and snow regimes are projected to change in a changing
climate. Alpine karst systems are especially vulnerable to these changing
hydro-meteorological conditions. However, because of their hydrogeological
complexity and hydraulic heterogeneity, every karst system has its
individual characteristics, and different karst springs respond differently
to changing climatic conditions. Therefore, site-specific investigations are
required. The holistic modeling approach presented in our study can be
transferred and adapted to other Alpine karst systems and can be used for
studying impacts of climate change on Alpine karst water resources.</p>
</sec>

      
      </body>
    <back><notes notes-type="dataavailability">

      <p id="d1e3824">A part of the hydrological data used to support this
article were provided by the responsible state authority for water resource
management (Wasserwirtschaftsamt Vorarlberg) and are available upon request
(wasserwirtschaft@vorarlberg.at). Another part of the hydrological data was
collected by the Division of Hydrogeology at the Karlsruhe Institute of
Technology (KIT) and is available from the authors upon request
(zhao.chen@kit.edu). The simulation data necessary for reproducing the
paper's
results are also available from the authors upon request
(zhao.chen@kit.edu).</p>
  </notes><app-group>
        <supplementary-material position="anchor"><p id="d1e3827">The supplement related to this article is available online at: <inline-supplementary-material xlink:href="https://doi.org/10.5194/hess-22-3807-2018-supplement" xlink:title="zip">https://doi.org/10.5194/hess-22-3807-2018-supplement</inline-supplementary-material>.</p></supplementary-material>
        </app-group><notes notes-type="authorcontribution">

      <p id="d1e3836">ZC developed the method and obtained all results in consultation with AH, TW and NG. ZC wrote the manuscript. The final manuscript was reviewed by all authors.</p>
  </notes><notes notes-type="competinginterests">

      <p id="d1e3842">The authors declare that they have no conflict of
interest.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e3848">We acknowledge the support of the Open Access Publishing Fund of Karlsruhe
Institute of Technology (KIT). We thank Clemens Mathis and Ralf Grabher from
Water Authority Vorarlberg (Austria) for providing data, Laurence Gill
(Trinity College Dublin) for inspiring discussion concerning model setup,
Joël Arnault (KIT) for providing a Matlab routine for the<?pagebreak page3821?> interpolation
of meteorological parameters and Timothy Bechtel (Franklin &amp; Marshall
College) for proofreading the manuscript. We thank two anonymous colleagues
and Ronald Green for their constructive review comments.<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?> The article processing charges for this open-access
<?xmltex \hack{\newline}?> publication were covered by a Research <?xmltex \hack{\newline}?> Centre
of the Helmholtz Association.<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?> Edited by:
Jesús Carrera<?xmltex \hack{\newline}?> Reviewed by: two anonymous
referees</p></ack><ref-list>
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    <!--<article-title-html>Dynamics of water fluxes and storages in an Alpine karst catchment under current and potential future climate conditions</article-title-html>
<abstract-html><p>Karst aquifers are difficult to manage due to their unique
hydrogeological characteristics. Future climate projections suggest a strong
change in temperature and precipitation regimes in European karst regions
over the next decades. Alpine karst systems can be especially vulnerable
under changing hydro-meteorological conditions since snowmelt in mountainous
environments is an important controlling process for aquifer recharge and is
highly sensitive to varying climatic conditions. Our paper presents the first
study to investigate potential impacts of climate change on mountainous karst
systems by using a combined lumped and distributed modeling approach with
consideration of subsurface karst drainage structures. The study site is
characterized by high-permeability (karstified) limestone formations and low-permeability
(non-karst) sedimentary Flysch. The model simulation under
current conditions demonstrates that a large proportion of precipitation
infiltrates into the karst aquifer as autogenic recharge. Moreover, the
result shows that surface snow storage is dominant from November to April,
while subsurface water storage in the karst aquifer dominates from May to
October. The climate scenario runs demonstrate that varied climate conditions
significantly affect the spatiotemporal distribution of water fluxes and
storages: (1) the total catchment discharge decreases under all
evaluated future climate conditions. (2) The spatiotemporal discharge
pattern is strongly controlled by temperature variations, which can shift the
seasonal snowmelt pattern, with snow storage in the cold season (December to
April) decreasing significantly under all change scenarios. (3) Increased
karst aquifer recharge in winter and spring, and decreased recharge in summer
and autumn, partly offset each other. (4) Impacts on the karst springs are
distinct; the lowest permanent spring presents a <q>robust</q> discharge
behavior, while the highest overflow outlet is highly sensitive to changing
climate. This analysis effectively demonstrates that the impacts on
subsurface flow dynamics are regulated by the characteristic dual flow and
spatially heterogeneous distributed drainage structure of the karst aquifer.
Overall, our study highlights the fast groundwater dynamics in mountainous
karst catchments, which make them highly vulnerable to future changing
climate conditions. Additionally, this work presents a novel holistic
modeling approach, which can be transferred to similar karst systems for
studying the impact of climate change on local karst water resources with
consideration of their individual hydrogeological complexity and hydraulic
heterogeneity.</p></abstract-html>
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