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  <front>
    <journal-meta>
<journal-id journal-id-type="publisher">HESS</journal-id>
<journal-title-group>
<journal-title>Hydrology and Earth System Sciences</journal-title>
<abbrev-journal-title abbrev-type="publisher">HESS</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Hydrol. Earth Syst. Sci.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1607-7938</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>

    <article-meta>
      <article-id pub-id-type="doi">10.5194/hess-19-1599-2015</article-id><title-group><article-title>Groundwater surface mapping informs sources<?xmltex \hack{\newline}?> of catchment baseflow</article-title>
      </title-group><?xmltex \runningtitle{Groundwater surface mapping informs sources of catchment baseflow}?><?xmltex \runningauthor{J.~F.~Costelloe et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Costelloe</surname><given-names>J. F.</given-names></name>
          <email>jcost@unimelb.edu.au</email>
        <ext-link>https://orcid.org/0000-0002-0708-0088</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Peterson</surname><given-names>T. J.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Halbert</surname><given-names>K.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Western</surname><given-names>A. W.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-4982-146X</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3 aff4">
          <name><surname>McDonnell</surname><given-names>J. J.</given-names></name>
          
        </contrib>
        <aff id="aff1"><label>1</label><institution>Department of Infrastructure Engineering, University of Melbourne, Melbourne, Australia</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Ecole Centrale de Nantes, Nantes, France</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Global Institute For Water Security, University of Saskatchewan, Saskatoon, Canada</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>School of Geosciences, University of Aberdeen, Aberdeen, Scotland</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">J. F. Costelloe (jcost@unimelb.edu.au)</corresp></author-notes><pub-date><day>7</day><month>April</month><year>2015</year></pub-date>
      
      <volume>19</volume>
      <issue>4</issue>
      <fpage>1599</fpage><lpage>1613</lpage>
      <history>
        <date date-type="received"><day>13</day><month>October</month><year>2014</year></date>
           <date date-type="rev-request"><day>5</day><month>November</month><year>2014</year></date>
           <date date-type="rev-recd"><day>9</day><month>March</month><year>2015</year></date>
           <date date-type="accepted"><day>9</day><month>March</month><year>2015</year></date>
      </history>
      <permissions>
<license license-type="open-access">
<license-p>This work is licensed under a Creative Commons Attribution 3.0 Unported License. To view a copy of this license, visit <ext-link ext-link-type="uri" xlink:href="http://creativecommons.org/licenses/by/3.0/">http://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions><self-uri xlink:href="https://hess.copernicus.org/articles/.html">This article is available from https://hess.copernicus.org/articles/.html</self-uri>
<self-uri xlink:href="https://hess.copernicus.org/articles/.pdf">The full text article is available as a PDF file from https://hess.copernicus.org/articles/.pdf</self-uri>


      <abstract>
    <p>Groundwater discharge is a major contributor to stream baseflow. Quantifying
this flux is difficult, despite its considerable importance to water resource
management and evaluation of the effects of groundwater extraction on
streamflow. It is important to be able to differentiate between contributions
to streamflow from regional groundwater discharge (more susceptible to
groundwater extraction) compared to interflow processes (arguably less
susceptible to groundwater extraction). Here we explore the use of
groundwater surface mapping as an independent data set to constrain estimates
of groundwater discharge to streamflow using traditional digital filter and
tracer techniques. We developed groundwater surfaces from 88 monitoring bores
using Kriging with external drift and for a subset of 33 bores with shallow
screen depths. Baseflow estimates at the catchment outlet were made using the
Eckhardt digital filter approach and tracer data mixing analysis using major
ion signatures. Our groundwater mapping approach yielded two measures
(percentage area intersecting the land surface and monthly change in
saturated volume) that indicated that digital filter-derived baseflow
significantly exceeded probable groundwater discharge during most months.
Tracer analysis was not able to resolve contributions from ungauged tributary
flows (sourced from either shallow flow paths, i.e. interflow and perched
aquifer discharge, or regional groundwater discharge) and regional
groundwater. Groundwater mapping was able to identify ungauged sub-catchments
where regional groundwater discharge was too deep to contribute to tributary
flow and thus where shallow flow paths dominated the tributary flow. Our
results suggest that kriged groundwater surfaces provide a useful, empirical
and independent data set for investigating sources of fluxes contributing to
baseflow and identifying periods where baseflow analysis may overestimate
groundwater discharge to streamflow.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <title>Introduction</title>
      <p>Groundwater discharge is a major contributor to stream baseflow. Quantifying
this flux is of considerable importance to water resource management
(Woessner, 2000; Sophocleous, 2002; Cartwright et al., 2014). In recent
decades there have been dramatic increases in the extraction of groundwater
for agricultural use, driven by factors such as expansion of irrigated
agriculture in southern Asia (Llamas and Martínez-Santos, 2005; Perrin
et al., 2011) and long-term drought in southeastern Australia (Leblanc et
al., 2012; van Dijk et al., 2013). It has been long recognised that
over-extraction from aquifers may result in significant long-term declines in
groundwater levels, resulting in decreases in baseflow in rivers (Bredehoeft
et al., 1982). As a result, the switch to groundwater as a source of
irrigation supply has the potential to exacerbate decreases in baseflow in
rivers already experiencing reductions in flow from drought or instream water
use. Whilst these generalities of groundwater extraction and stream baseflow
reduction are clear, the particularities for any given catchment are complex
and difficult to quantify. The separation of baseflow contributions from
regional groundwater (i.e. where aquifers are unconfined in the vicinity of
streams) from other shallower sources, like interflow, bank storage return
and perched aquifer discharge, is technically difficult to quantify.
Nevertheless, this is fundamentally important for quantifying how regional
groundwater extraction may affect baseflow in rivers (Wittenberg, 1999).
Despite decades of work (e.g. Nathan and McMahon, 1990; Tallaksen, 1995;
Wittenberg, 1999; Eckhardt, 2005), methods to quantify and discriminate
between “slow flow” (itself a poorly defined term) contributions to the
stream using only streamflow data are approximate at best.</p>
      <p>From a physical perspective, the baseflow component of streamflow is the sum
of the slow flow pathways into the river (Ward and Robinson, 2000). Regional,
unconfined groundwater (often termed “deep groundwater”) can discharge into
the river via the valley floor or through more shallow, lateral flow paths,
such as discharge into tributaries draining the valley slopes. Rain event
driven interflow pathways can also contribute to tributary streamflow and
recent work has shown a continuum between groundwater and interflow processes
(sometimes referred to as “shallow groundwater” in hilly terrains) along
the stream reach (Jencso et al., 2009; Jencso and McGlynn, 2011). In terms of
water resource extraction (e.g. for urban supplies or irrigation on the
valley floor), groundwater pumping typically targets the deep groundwater,
and often in alluvial valley locations where the depth to groundwater is at a
minimum. Thus, it is important to be able to differentiate between
contributions to streamflow from deep groundwater discharge (more susceptible
to groundwater extraction) compared to shallower interflow processes
(arguably less susceptible to groundwater extraction).</p>
      <p>But how can the baseflow components be identified? Digital recursive filters
are the most common method of separating baseflow from streamflow but do not
discriminate between the different components of baseflow, and the estimate
is integrated over the entire catchment area upstream of the gauging station.
The technique rests on the assumption that baseflow is comprised of linear or
non-linear outflow from an aquifer (e.g. Nathan and McMahon, 1990;
Wittenberg, 1999; Eckhardt, 2005). All of the filter approaches require
calibration of 1–3 parameters based on subjective criteria (e.g. recession
curve analysis, typical values, etc.). Calibration of these parameters
against synthetic baseflow derived from a numerical model has shown that
optimal values vary considerably with catchment and climatic characteristics,
many of which are not known or not possible to know a priori for natural
catchments (Li et al., 2014).</p>
      <p>There is typically significant variability in recession curves from a given
catchment, suggesting a range of processes, stores and flow paths (e.g. deep
and shallow groundwater flow paths, interflow, bank storage) affecting
baseflow (Tallaksen, 1995; Jencso and McGlynn, 2011; Chen and Wang, 2013).
The regional unconfined groundwater may drive only some of this response
(Cartwright et al., 2014) and the baseflow derived from unconfined
groundwater is commonly defined by the slowest recession flows that form the
lower bound (e.g. the 95th percentile) of all recession curves used in the
analysis (Brutsaert, 2008; Eckhardt, 2008). The variable, often non-linear,
baseflow response has been attributed to additional processes affecting the
groundwater discharge, such as phreatic evapotranspiration (Wittenberg and
Sivapalan, 1999) and recharge from soils or perched aquifers (Fenicia et al.,
2006; Jencso and McGlynn, 2011). Baseflow analysis using digital recursive
filters typically does not use groundwater data to constrain or test the
estimates, even though baseflow should vary systematically with groundwater
levels (Gonzalez et al., 2009; Meshgi et al., 2014).</p>
      <p>Tracer data are also commonly used to estimate groundwater discharge to
streams (Cook et al., 2003; McGlynn and McDonnell, 2003; Cartwright et al.,
2011; Atkinson et al., 2015). The tracer approach relies on the assumption
that different contributors to streamflow have distinctive and invariant
chemical, isotopic or radiogenic end-member signatures that can be
apportioned in the streamflow mixture (McCallum et al., 2010). From a
geochemical perspective, mass balance estimates of baseflow using tracer data
can differ from estimates made by digital recursive filters, as some slow
flow components (e.g. bank storage) can be geochemically similar to quick
flow components (Cartwright et al., 2014). Insights have been gained into
heavily instrumented catchments that increase confidence in the
identification of sources and pathways of the fluxes to the stream – but
this is usually feasible only on small experimental catchments or hillslopes
(Kendall et al., 2001). In larger catchments utilised for water use, it can
be difficult to separate fluxes of interest due to similarities in the tracer
signatures, such as between surface flow and interflow (Kendall et al., 2001)
or bank storage discharge and streamflow (McCallum et al., 2010). This
problem has been addressed by using a multiple tracer approach, so that a mix
of isotopic and ionic data or conservative and radiogenic data can provide
independent information on sources and pathways within a catchment (Cook et
al., 2003; Cartwright et al., 2011; Atkinson et al., 2015). However, field
studies are rarely able to identify end-members for all flow paths of
interest, and deep and shallow groundwater fluxes are commonly lumped
together.</p>
      <p>Digital recursive filters and tracer-based analysis measure different
components of baseflow and provide different bounds to the estimation of
groundwater discharge. For instance, digital filter analysis provides an
upper bound to groundwater discharge, integrated over the upstream catchment
area. Tracer analysis can provide more spatially explicit estimates of
groundwater discharge, but can struggle with separating discharge from deep
groundwater flow paths compared to shallow, lateral groundwater flow paths.
Here we argue that additional data sets on groundwater dynamics are of
benefit in better constraining regional groundwater discharge estimates
determined by these traditional methods. One overlooked measure available in
many catchments is groundwater level data. Intuitively, such data are
directly relatable to the groundwater discharge component of baseflow
(Gonzalez et al., 2009; Meshgi et al., 2014). More importantly, we
hypothesise that groundwater observations provide complementary, independent
time series of data on the dynamics of the groundwater–surface water
interaction.</p>
      <p>The use of groundwater level data at the reach or catchment scale faces a
number of challenges, principally that these data are sporadically available
in time and space. To understand the spatial variability of groundwater
throughout a catchment, various geostatistical techniques have been developed
to interpolate sparse groundwater level observations (Desbarats et al., 2002;
Boezio et al., 2006; Lyon et al., 2006). However, to date, maps have been
derived for only the average groundwater level at each bore, rather than
distributed instantaneous levels across the catchment (Desbarats et al.,
2002), or at a specific time using either continuous water level observations
(Boezio et al., 2006; Lyon et al., 2006) or basic hydrograph interpolation
methods (Peterson et al., 2011) that ignore the variability between
observation times. Considering that groundwater observations are most often
collected manually and are rarely coincident across a catchment, using
groundwater maps to inform groundwater–surface water interaction requires
maps for specific time points and hence a hydrograph interpolation technique
that, ideally, accounts for the variability between observations. Recently,
Peterson and Western (2014) developed such an interpolation approach for
irregularly spaced observations that now allows for daily interpolated
observations to be generated for the estimation of groundwater surfaces for
any given date within the period of observation. This new method enables the
generation of high-frequency groundwater surfaces from operational monitoring
bore networks, which opens up a possible new way forward for estimating
groundwater contributions to baseflow.</p>
      <p>Here we combine groundwater head data, amalgamated as groundwater surface
maps using the new Peterson and Western (2014) temporal interpolation with
the Peterson et al. (2011) spatial interpolation approach. We then use this
as an independent and generally available approach to constrain estimates of
groundwater discharge to streamflow using traditional digital filter and
tracer techniques. Specifically we test three hypotheses:
<list list-type="order"><list-item>
      <p>variations in baseflow can be explained by variations in the areas of very shallow water tables (i.e. direct discharge areas),</p></list-item><list-item>
      <p>variations in baseflow can be explained by changes in saturated volume between monthly water
table surfaces, and</p></list-item><list-item>
      <p>water table mapping can identify whether ungauged tributary inflow is driven by regional groundwater discharge.</p></list-item></list>
We focus our work on a humid catchment in southeastern Australia where
substantial groundwater data have been collected arising from investigations
of groundwater extraction for urban water supply (SKM, 2012) and river
damming. We combine 44 years of streamflow and groundwater data observations
from 88 monitoring bores across the 311 km<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> catchment to investigate
the utility of the groundwater data for informing sources of catchment
baseflow.</p>
</sec>
<sec id="Ch1.S2">
  <title>Methods</title>
<sec id="Ch1.S2.SS1">
  <title>Study area</title>
      <p>The Gellibrand River catchment is located in southeastern Australia in the
Otway Ranges. It has a perennial, highly seasonal flow regime and a humid
climate (rainfall of 1000 mm a<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. The Gellibrand River is dominated
by a constrained valley with much of the study reach being forested by cool
temperate eucalypt rainforests, except for cleared grazing areas along the
valley floor. The catchment is well gauged, with gauging stations at Upper
Gellibrand and Bunker Hill on the Gellibrand River and gauging stations
measuring flow in two of the larger tributaries (Love Creek and Lardner
Creek, Fig. 1). The catchment has an area of 311 km<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> to a mid-catchment
gauging station at Bunker Hill. Comparison of potentiometric groundwater data
to river levels indicates mostly gaining conditions along the Gellibrand
River (SKM, 2012; Atkinson et al., 2015).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1"><caption><p>Location and geology of the Gellibrand River catchment in Victoria,
Australia, showing catchment and gauged subcatchment boundaries, monitoring
bores, gauging stations and the Sayers Bridge (ungauged) river sampling
location.</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://www.hydrol-earth-syst-sci.net/19/1599/2015/hess-19-1599-2015-f01.png"/>

        </fig>

      <p>The southern half of the catchment, which includes the upper reaches of the
Gellibrand River and coincides with steep, forested terrain, is underlain by
the volcanogenic sandstones, siltstones and mudstones of the Cretaceous
Otways Group (Fig. 1), which forms the basement to the catchment. Relatively
few bores occur within this unit in the Gellibrand catchment. The more open,
alluvial valley of the Gellibrand is underlain predominantly by fluvial sands
with interbedded silts and clays of the late Cretaceous Wangerrip Group and
overlying Quaternary alluvium. This area contains the most bores and is
considered the primary aquifer in the region (Atkinson et al., 2015). The
northern half of the catchment, particularly the Love Creek sub-catchment, is
underlain by the marine calcareous clays of the Miocene Heytesbury Group that
confine the underlying aquifers in the Wangerrip Group. A number of bores
occur in this area, but are mainly screened within the main aquifer (Eastern
View Formation) of the underlying Wangerrip Group.</p>
</sec>
<sec id="Ch1.S2.SS2">
  <title>Groundwater monitoring and mapping</title>
      <p>Eighty-eight groundwater monitoring bores in and around the boundary of the
Gellibrand catchment were identified and water level data were extracted from
the Victorian Groundwater Management System
(<uri>http://www.vvg.org.au/cb_pages/gms.php</uri>). The area contains a
relatively large number of monitoring bores due to earlier investigations for
a potential damming of the Gellibrand River and also extraction of
groundwater for urban water supply (SKM, 2012). Groundwater surfaces were
constructed from the total data set and also from a subset of 33 bores with
screened depths of <inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 40 m that only occur within the catchment boundary
(bore details in Supplement B). The total data set contains bores that are
screened at greater depths in the Wangerrip Group (main aquifer) and these
typically show higher heads relative to nearby bores screened at shallower
depths (typically in the Quaternary alluvium). Groundwater surfaces from the
total data set represent more of a potentiometric surface, while the smaller
data set of shallow bores represents a water table surface.</p>
      <p>In order to construct groundwater surface maps for specified dates, the
periodic (generally monthly) water level observations of the bore data were
first modelled using the nonlinear transfer–function–noise time series
modelling methodology of Peterson and Western (2014). Water level estimates
for the start of each month were then derived by adding the time series
simulation, interpolated to the required data, to a univariate ordinary
Kriging estimate of the time-series model error at the required date, which
ensured a zero error at dates with a water level observation. Groundwater
surface maps were then produced for the first of each month for the years
2007 to 2010 using the Kriging with external drift (KED) method (Peterson et
al., 2011). In applying the KED, the external drift term was the land surface
elevation (Shuttle Radar Terrain Model (SRTM) 30 m data set). A model
variogram was derived for the component of the groundwater elevation not
explained by the external drift. The KED approach requires the estimation of
three parameters for the residual model variogram and a parameter for the
maximum search radius during the mapping. Considerable effort was taken to
reliably calibrate the variogram parameters and set a search radius producing
cross-validation residuals that are approximately first-order stationary. The
Kriging variance (see example in Fig. 6) does provides an indicative estimate
of the map reliability for the given parameter set and the available water
level observations. However, the density and location of observations also
influences the variogram parameters and the maximum search radius parameter.
Accounting for this parameter uncertainty in the groundwater mapping is not
trivial and future work is required to explore methods that account for
variogram uncertainty (Ortiz and Deutsch, 2002) and localised estimation of the search radius (Abedini et al.,
2012). This groundwater level component was first
estimated using ordinary least squares regression and then minimised by
repeatedly fitting an isotropic exponential variogram, using multi-start
Levenberg–Marquardt optimisation and re-derivation of the water level
component, until a stable model variogram was achieved. The depth to
groundwater was calculated by difference from the SRTM representation of the
ground surface and used to measure changes in the percentage of the catchment
with very shallow groundwater surfaces (nominally “saturated” within the
uncertainty range of the groundwater surface position) over the period of
mapping. This was done for the parts of the catchment with an elevation of
<inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 100 m in order to analyse changes in the saturated area around the
valley floor and lower slopes of the catchment where most monitoring bores
were located and, hence, confidence in the groundwater surface mapping was
highest. Three threshold depths to the water table (0, 0.5, 1.0 m) were
used to determine changes between the seasonal maximum (spring) and minimum
(autumn) saturated areas. The threshold depths were not calibrated, but were
arbitrarily chosen to capture some of the uncertainty in the groundwater
position (i.e. see Fig. 5 for an indication of the standard deviation in the
groundwater surface positions) as mapped for each month. In addition, changes
in total volume below the mapped groundwater surface (i.e. volume containing
sediments and pore spaces) between months were calculated using the
groundwater surface maps, again using the catchment area below 100 m
elevation.</p>
</sec>
<sec id="Ch1.S2.SS3">
  <title>Digital recursive filter analysis of baseflow</title>
      <p>The Eckhardt (2005) two-parameter, digital recursive filter (<xref ref-type="disp-formula" rid="Ch1.E1"/>) was
used to produce baseflow time series for the Gellibrand streamflow record at
the Bunker Hill gauging station (station number 235227):
            <disp-formula id="Ch1.E1" content-type="numbered"><mml:math display="block"><mml:mrow><mml:msub><mml:mi>b</mml:mi><mml:mi>k</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mfenced open="(" close=")"><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="normal">BFI</mml:mi><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:mfenced><mml:mi>a</mml:mi><mml:msub><mml:mi>b</mml:mi><mml:mrow><mml:mi>k</mml:mi><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:mfenced close=")" open="("><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mi>a</mml:mi></mml:mfenced><mml:msub><mml:mi mathvariant="normal">BFI</mml:mi><mml:mi mathvariant="normal">max</mml:mi></mml:msub><mml:msub><mml:mi>Q</mml:mi><mml:mi>k</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mi>a</mml:mi><mml:msub><mml:mi mathvariant="normal">BFI</mml:mi><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math display="inline"><mml:mi>b</mml:mi></mml:math></inline-formula> (L<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> T<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) is the baseflow discharge, <inline-formula><mml:math display="inline"><mml:mi>Q</mml:mi></mml:math></inline-formula>
(L<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msup></mml:math></inline-formula> T<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) is the total streamflow discharge, <inline-formula><mml:math display="inline"><mml:mi>k</mml:mi></mml:math></inline-formula> (T) is the time
step, and <inline-formula><mml:math display="inline"><mml:mi>a</mml:mi></mml:math></inline-formula> (–) and BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula> (–) are parameters requiring
calibration. The Eckhardt filter separates the slow flow component of the
stream hydrograph based on the groundwater discharge being linearly
proportional to the unconfined aquifer storage. This filter was chosen as it
has a physical basis and produces results comparable with other digital
recursive filters (Eckhardt, 2008). The <inline-formula><mml:math display="inline"><mml:mi>a</mml:mi></mml:math></inline-formula> parameter (representing the
recession constant of streamflow) was determined by the 95th percentile upper
bound of the scatter plot of daily discharge (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi>k</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> against discharge from
the next day (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mrow><mml:mi>k</mml:mi><mml:mo>+</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. These data points were extracted for recession
flows of 5 days or longer (see Eckhardt, 2008) below a selection of
percentiles of total flows (i.e. 30th, 40th, 50th). The BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula>
parameter (representing the maximum value of the baseflow index, i.e.
baseflow/total streamflow, that can be modelled by the filter algorithm) was
chosen to minimise periods of baseflow greater than observed streamflow. The
filter is typically applied with the condition that <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>b</mml:mi><mml:mi>k</mml:mi></mml:msub><mml:mo>≤</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mi>k</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>
(Eckhardt, 2005), but this is an arbitrary constraint, and we explore the
resulting baseflow time series without this condition, except where stated.
Time series of baseflow were then defined using the selected pairs of
parameter values to represent a possible envelope of baseflow for the study
catchment.</p>
</sec>
<sec id="Ch1.S2.SS4">
  <title>Hydrochemical sampling and analysis</title>
      <p>Water samples from streamflow were collected by automatic samplers (ISCO) at
several locations in the catchment, including upstream (Upper Gellibrand
gauging station and Sayers Bridge, see Fig. 1) and downstream (Bunker Hill
gauging station) locations from the Gellibrand River and from major
tributaries in January and June 2013. Grab samples were also collected from
smaller, ungauged tributaries and from the Gellibrand River during the
sampling period and also in December 2013. Unconfined groundwater samples
were taken from bores in the alluvial area of the Gellibrand River (some data
supplied by Alex Atkinson, Monash University, see Atkinson et al., 2015)
after purging 2–3 well volumes of bores or until field water parameters
(e.g. electrical conductivity, pH, temperature) had stabilised. Samples were
filtered through a 0.45 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m membrane filter and the cation aliquots
were further acidified to pH <inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 2 using 1 M HNO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> and stored at
4 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C until analysis at the Research School of Earth Science
laboratory, Australian National University. Cation analyses were performed by
ICP mass spectrometry (Varian Vista AX CCD simultaneous ICP-OES) and anion
analysis performed by ion chromotography (Dionex Series 4500i). Colourimetric
alkalinity titrations were performed using a
Hach<sup>®</sup> field titration kit.</p>
      <p>Mass balance calculations were conducted on the streamflow samples using
selected ions (Cl, Na, Ca, Mg) in a multiple end-member model. The
hydrochemical samples included upstream and downstream (gauged) locations on
the Gellibrand River, major gauged tributaries and a range of smaller,
ungauged tributaries. The mass balance for a gaining reach is defined by the
load (2) and the discharge (3):

                <disp-formula specific-use="align" content-type="numbered"><mml:math display="block"><mml:mtable displaystyle="true"><mml:mlabeledtr id="Ch1.E2"><mml:mtd/><mml:mtd/><mml:mtd><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">ds</mml:mi></mml:msub><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="normal">ds</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">us</mml:mi></mml:msub><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="normal">us</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">gw</mml:mi></mml:msub><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="normal">gw</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">ut</mml:mi></mml:msub><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="normal">ut</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">gt</mml:mi></mml:msub><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="normal">gt</mml:mi></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E3"><mml:mtd/><mml:mtd/><mml:mtd><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">ds</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">us</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">gw</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">ut</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">gt</mml:mi></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

            where <inline-formula><mml:math display="inline"><mml:mi>Q</mml:mi></mml:math></inline-formula> is discharge and <inline-formula><mml:math display="inline"><mml:mi>C</mml:mi></mml:math></inline-formula> is concentration, and the subscripts refer to
ds – downstream Gellibrand (Bunker Hill gauging station), us – upstream
Gellibrand, gw – groundwater, ut – ungauged tributaries, and gt – gauged
tributaries. The unknowns in the above equations are <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">gw</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">ut</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, and to solve them requires two sets of concentrations, or a
single tracer with data over 2 or more days. This approach accounts for the
contribution from the alluvial groundwater in the reach between the Upper
Gellibrand and Bunker Hill gauging stations. To explore the uncertainty in
the mass balance estimates, the composition of the groundwater end-member was
varied by <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1 standard deviation, as this end-member had the largest
standard deviation for two of the ions (Cl and Na; see Supplement A) used in
the calculations.</p>
</sec>
</sec>
<sec id="Ch1.S3">
  <title>Results</title>
      <p>We first analyse the baseflow characteristics of the river using the
Eckhardt (2005) baseflow filter. Second, the streamflow chemical patterns are
presented and third, mass balance analysis is used to estimate groundwater
discharge and ungauged tributary discharge. Finally, using the results of
mapping the groundwater surfaces, we analyse relationships between the three
data sets (groundwater surfaces, baseflow filter estimates, mass balance
tracer estimates) and explore how the groundwater surfaces can be used to
constrain estimates of groundwater discharge derived from ionic mass balance
and baseflow filter analyses.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2"><caption><p>Hydrograph at Bunker Hill gauging station (235227) illustrating the
seasonality of flow. Three baseflow separation hydrographs generated using
different BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula> parameter values (0.20, 0.60, 0.80 and
<inline-formula><mml:math display="inline"><mml:mrow><mml:mi>a</mml:mi><mml:mo>=</mml:mo><mml:mn>0.988</mml:mn></mml:mrow></mml:math></inline-formula>) for the Eckhardt filter are displayed, along with the periods of
hydrochemical sampling of streamflow during 2013.</p></caption>
        <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://www.hydrol-earth-syst-sci.net/19/1599/2015/hess-19-1599-2015-f02.pdf"/>

      </fig>

<sec id="Ch1.S3.SS1">
  <title>Baseflow analysis</title>
      <p>The Eckhardt baseflow estimates produce patterns that follow the highly
seasonal pattern shown by the overall river discharge and indicated that
baseflow significantly contributed to overall streamflow (Fig. 2). The <inline-formula><mml:math display="inline"><mml:mi>a</mml:mi></mml:math></inline-formula>
parameter values declined moderately as the threshold flow percentile value
to define recession periods increased (30th – 0.990, 40th – 0.988, 50th –
0.985). The BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula> parameter values that minimised periods of
baseflow greater than streamflow clustered around 0.2 but showed slight
increases as <inline-formula><mml:math display="inline"><mml:mi>a</mml:mi></mml:math></inline-formula> decreased (30th – 0.20, 40th – 0.20, 50th – 0.22). The
resulting baseflow time series using these parameter values were similar and
the time series using <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>a</mml:mi><mml:mo>=</mml:mo><mml:mn>0.988</mml:mn></mml:mrow></mml:math></inline-formula> and BFI<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn>0.20</mml:mn></mml:mrow></mml:math></inline-formula> is shown in
Fig. 2. This method used for determining the BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula> parameter
produced values below the recommended range (<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.8 for perennial rivers
with porous aquifers, Eckhardt, 2005) and that lie closest to the recommended
BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula> value (0.25) for perennial rivers with hard rock aquifers.
In Fig. 2 we also show baseflow time series using <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>a</mml:mi><mml:mo>=</mml:mo><mml:mn>0.988</mml:mn></mml:mrow></mml:math></inline-formula> and the
recommended BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula> value for a river such as the Gellibrand
(0.80), and also using the maximum baseflow index value (0.60) found for the
Gellibrand River using tracer-based analysis by Atkinson et al. (2015). Using
the condition of <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>b</mml:mi><mml:mi>k</mml:mi></mml:msub><mml:mo>≤</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mi>k</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, the filtered baseflow time series produced
mean monthly BFI estimates of 0.48–0.55 (BFI<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn>0.20</mml:mn></mml:mrow></mml:math></inline-formula>–0.22) and
0.63–0.68 (BFI<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn>0.60</mml:mn></mml:mrow></mml:math></inline-formula>–0.80) during the summer–autumn period
(December–May), and 0.21–0.24 (BFI<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn>0.20</mml:mn></mml:mrow></mml:math></inline-formula>–0.22) and
0.47–0.58 (BFI<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn>0.60</mml:mn></mml:mrow></mml:math></inline-formula>–0.80) during the winter–spring period
(June–November).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3"><caption><p>Piper diagrams showing temporal and spatial patterns in the
chemistry of streamflow and groundwater. The top panel shows seasonal
variations in the composition of flow in the Gellibrand River at the upstream
(Upper Gellibrand) and downstream (Bunker Hill) sites over three sampling
trips. The data in the upper plot show compositional change from
upstream to downstream and also from summer to winter towards the general
groundwater composition. The lower panel shows compositional differences
across all sampling trips between the Gellibrand River, gauged tributaries,
ungauged tributaries and groundwater.</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://www.hydrol-earth-syst-sci.net/19/1599/2015/hess-19-1599-2015-f03.pdf"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS2">
  <title>Streamflow chemistry patterns</title>
      <p>Streamflow and groundwater samples of the Gellibrand catchment have similar
Na–Cl–HCO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> compositions (Supplement A) and are further examined using
a Piper diagram (Fig. 3). The upstream, downstream and major tributary flow
compositions plot closely together, with the downstream composition showing a
shift towards the alluvial groundwater composition, relative to the upstream
composition. However, seasonal changes in streamflow chemistry are also
apparent, with winter samples (June 2013) plotting closer to the groundwater
composition (higher Cl, lower HCO<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> in comparison to the summer low flow
samples (January and December 2013). The ungauged (minor) tributary samples
show a greater spread in compositions, with only the largest of the ungauged
tributaries (Charley's Creek, 47.4 km<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> plotting with the gauged
streamflow (Gellibrand, Love, Lardner), and others plotting in and around the
alluvial groundwater compositions. The Charley's Creek subcatchment drains
the southern half of the catchment underlain by the Otways group and has a
relatively similar area to the two gauged tributaries (Lardner Creek
51.8 km<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>, Love Creek 76.6 km<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. The ungauged tributaries show a
greater spread in composition than the alluvial groundwater, but this was
dominated by relatively high Mg and SO<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:math></inline-formula> concentrations in two
tributaries, whilst the other tributaries were slightly depleted in Ca and K
compared to the alluvial groundwater. The Love Creek samples have
significantly higher ionic concentrations than all other streamflow samples
in the catchment (Supplement A), but have similar ionic ratios, as shown by
them plotting closely to the gauged streamflow samples in Fig. 3.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4"><caption><p>Major ion changes during streamflow recession of January 2013
measured at Bunker Hill gauging station. Concentrations are divided by the
mean concentration of the sampling period for each tracer.</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://www.hydrol-earth-syst-sci.net/19/1599/2015/hess-19-1599-2015-f04.pdf"/>

        </fig>

      <p>The dominance of the contribution of groundwater discharge to streamflow
during summer low flow periods was also investigated by examining how tracer
values changed during the recession of flow events during the summer
(January 2013) sampling period (Fig. 4). In general, only the chloride data
showed an approximately linear increase in concentration that would be
expected if the groundwater discharge flux contributed proportionally more
to streamflow during the short-term recession. The other major ions (e.g.
Na, Ca, Mg) remained relatively consistent or showed a variable pattern over
time during the flow recession. In addition, the streamflow composition
remains distinct from the groundwater composition even during the summer low
flow periods (Figs. 3, 4). These patterns suggest that other end-member
fluxes need to be considered during the flow recession rather than a simple
two end-member system (i.e. upstream streamflow and groundwater discharge).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5"><caption><p>Depth to groundwater maps (<bold>a</bold> – “potentiometric surface”
(all bores), <bold>b</bold> – “water table” (shallow bores)) and Kriging
standard deviation (<bold>c</bold> – potentiometric surface, <bold>d</bold> – water
table) for 1 September 2009. Areas of shallow or intersecting (artesian)
groundwater are restricted to the Gellibrand River (centre) and Love Creek
(north) valley floors.</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://www.hydrol-earth-syst-sci.net/19/1599/2015/hess-19-1599-2015-f05.pdf"/>

        </fig>

      <p>The compositional similarities of the ungauged streamflow samples to the
alluvial groundwater samples, compared to the gauged streamflow samples,
raise the question of whether the minor ungauged tributaries represent
discharged groundwater. Alternatively, the ungauged streamflow may be driven
by perched aquifer or similar interflow-type processes. If the ungauged
tributary samples represent a source distinct from the regional groundwater,
then their chemical similarity to the groundwater samples could result in
chemical mass balance techniques that do not consider the contribution from
ungauged tributaries, overestimating the groundwater contribution to
streamflow (Sect. 3.3).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><caption><p>Estimates of groundwater discharge (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">gw</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and ungauged
tributary discharge (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">ut</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> using mass balance analysis and mean
measured compositions of groundwater and ungauged tributary flow. The values
within the brackets are the range of valid discharges generated by varying
the groundwater composition by 1 standard deviation for each ion used in the
analysis. <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">res</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the residual discharge after accounting for the
gauged discharges within the study catchment and the following value in
brackets is the ratio of <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">res</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> to the total streamflow measured at
Bunker Hill gauging station.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="6">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="left"/>
     <oasis:colspec colnum="6" colname="col6" align="left"/>
     <oasis:thead>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">Date</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">gw</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula><?xmltex \hack{\hfill\break}?>(MLd<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">ut</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula><?xmltex \hack{\hfill\break}?>(MLd<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mi mathvariant="normal">res</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula><?xmltex \hack{\hfill\break}?>(MLd<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>  
         <oasis:entry colname="col5">Tracer</oasis:entry>  
         <oasis:entry colname="col6">Method</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">21 Jan 2013</oasis:entry>  
         <oasis:entry colname="col2">14.0 (4.0–14.0)</oasis:entry>  
         <oasis:entry colname="col3">2.8 (2.8–12.8)</oasis:entry>  
         <oasis:entry colname="col4">16.8 (0.45)</oasis:entry>  
         <oasis:entry colname="col5">Cl–Ca</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">21 Jan 2013</oasis:entry>  
         <oasis:entry colname="col2">12.0 (7.0–12.0)</oasis:entry>  
         <oasis:entry colname="col3">4.8 (4.8–9.8)</oasis:entry>  
         <oasis:entry colname="col4">16.8 (0.45)</oasis:entry>  
         <oasis:entry colname="col5">Cl–Mg</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">21 Jan 2013</oasis:entry>  
         <oasis:entry colname="col2">14.8 (1.3–14.8)</oasis:entry>  
         <oasis:entry colname="col3">2.0 (2.0–15.5)</oasis:entry>  
         <oasis:entry colname="col4">16.8 (0.45)</oasis:entry>  
         <oasis:entry colname="col5">Ca–Mg</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">21 Jan 2013</oasis:entry>  
         <oasis:entry colname="col2">– (4.4–7.6)</oasis:entry>  
         <oasis:entry colname="col3">– (9.2–12.4)</oasis:entry>  
         <oasis:entry colname="col4">16.8 (0.45)</oasis:entry>  
         <oasis:entry colname="col5">Na–Mg</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">21 Jan 2013</oasis:entry>  
         <oasis:entry colname="col2">– (10.3)</oasis:entry>  
         <oasis:entry colname="col3">– (6.5)</oasis:entry>  
         <oasis:entry colname="col4">16.8 (0.45)</oasis:entry>  
         <oasis:entry colname="col5">Na–Ca</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">21–28 Jan 2013</oasis:entry>  
         <oasis:entry colname="col2">13.7 (5.3–13.7)</oasis:entry>  
         <oasis:entry colname="col3">1.8 (1.8–10.2)</oasis:entry>  
         <oasis:entry colname="col4">15.5 (0.45)</oasis:entry>  
         <oasis:entry colname="col5">Cl</oasis:entry>  
         <oasis:entry colname="col6">One end-member series</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">21–28 Jan 2013</oasis:entry>  
         <oasis:entry colname="col2">7.1 (3.8–12.6)</oasis:entry>  
         <oasis:entry colname="col3">8.4 (2.9–11.7)</oasis:entry>  
         <oasis:entry colname="col4">15.5 (0.45)</oasis:entry>  
         <oasis:entry colname="col5">Na</oasis:entry>  
         <oasis:entry colname="col6">One end-member series</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">21–28 Jan 2013</oasis:entry>  
         <oasis:entry colname="col2">13.7 (8.9–13.7)</oasis:entry>  
         <oasis:entry colname="col3">1.8 (1.8–6.6)</oasis:entry>  
         <oasis:entry colname="col4">15.5 (0.45)</oasis:entry>  
         <oasis:entry colname="col5">Ca</oasis:entry>  
         <oasis:entry colname="col6">One end-member series</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">21–28 Jan 2013</oasis:entry>  
         <oasis:entry colname="col2">13.7 (7.7–13.7)</oasis:entry>  
         <oasis:entry colname="col3">1.8 (1.8–7.9)</oasis:entry>  
         <oasis:entry colname="col4">15.5 (0.45)</oasis:entry>  
         <oasis:entry colname="col5">Mg</oasis:entry>  
         <oasis:entry colname="col6">One end-member series</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">21–28 Jan 2013</oasis:entry>  
         <oasis:entry colname="col2">4.7 (3.3–8.2)</oasis:entry>  
         <oasis:entry colname="col3">10.8 (7.3–12.2)</oasis:entry>  
         <oasis:entry colname="col4">15.5 (0.45)</oasis:entry>  
         <oasis:entry colname="col5"><inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn>18</mml:mn></mml:msup></mml:math></inline-formula>O</oasis:entry>  
         <oasis:entry colname="col6">One end-member series</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">21–28 Jan 2013</oasis:entry>  
         <oasis:entry colname="col2">8.1 (4.6–8.1)</oasis:entry>  
         <oasis:entry colname="col3">7.5 (7.5–10.9)</oasis:entry>  
         <oasis:entry colname="col4">15.5 (0.45)</oasis:entry>  
         <oasis:entry colname="col5"><inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>H</oasis:entry>  
         <oasis:entry colname="col6">One end-member series</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">7 Jun 2013</oasis:entry>  
         <oasis:entry colname="col2">25.2 (20.5–25.4)</oasis:entry>  
         <oasis:entry colname="col3">59.6 (59.4–64.3)</oasis:entry>  
         <oasis:entry colname="col4">84.8 (0.43)</oasis:entry>  
         <oasis:entry colname="col5">Cl–Na</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">7 Jun 2013</oasis:entry>  
         <oasis:entry colname="col2">48.8 (35.6–53.2)</oasis:entry>  
         <oasis:entry colname="col3">36.0 (31.6–49.2)</oasis:entry>  
         <oasis:entry colname="col4">84.8 (0.43)</oasis:entry>  
         <oasis:entry colname="col5">Na–Mg</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">7 Jun 2013</oasis:entry>  
         <oasis:entry colname="col2">38.2 (7.5–38.2)</oasis:entry>  
         <oasis:entry colname="col3">46.6 (46.6–77.3)</oasis:entry>  
         <oasis:entry colname="col4">84.8 (0.43)</oasis:entry>  
         <oasis:entry colname="col5">Cl–Ca</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">7 Jun 2013</oasis:entry>  
         <oasis:entry colname="col2">68.9 (36.6–68.9)</oasis:entry>  
         <oasis:entry colname="col3">15.9 (15.9–48.2)</oasis:entry>  
         <oasis:entry colname="col4">84.8 (0.43)</oasis:entry>  
         <oasis:entry colname="col5">Cl–Mg</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">7 Jun 2013</oasis:entry>  
         <oasis:entry colname="col2">9.8 (9.8–16.6)</oasis:entry>  
         <oasis:entry colname="col3">75.0 (68.2–75.0)</oasis:entry>  
         <oasis:entry colname="col4">84.8 (0.43)</oasis:entry>  
         <oasis:entry colname="col5">Na–Ca</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">7–11 Jun 2013</oasis:entry>  
         <oasis:entry colname="col2">– (18.8–29.9)</oasis:entry>  
         <oasis:entry colname="col3">– (17.1–28.2)</oasis:entry>  
         <oasis:entry colname="col4">47.0 (0.41)</oasis:entry>  
         <oasis:entry colname="col5">Cl</oasis:entry>  
         <oasis:entry colname="col6">One end-member series</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">7–11 Jun 2013</oasis:entry>  
         <oasis:entry colname="col2">2.2 (1.2–20.5)</oasis:entry>  
         <oasis:entry colname="col3">44.8 (26.5–45.8)</oasis:entry>  
         <oasis:entry colname="col4">47.0 (0.41)</oasis:entry>  
         <oasis:entry colname="col5">Na</oasis:entry>  
         <oasis:entry colname="col6">One end-member series</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">20 Jun 2013</oasis:entry>  
         <oasis:entry colname="col2">14.7 (10.0–14.9)</oasis:entry>  
         <oasis:entry colname="col3">31.0 (30.8–35.7)</oasis:entry>  
         <oasis:entry colname="col4">45.7 (0.38)</oasis:entry>  
         <oasis:entry colname="col5">Cl–Na</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">20 Jun 2013</oasis:entry>  
         <oasis:entry colname="col2">42.4 (3.8–42.4)</oasis:entry>  
         <oasis:entry colname="col3">3.3 (3.3–34.3)</oasis:entry>  
         <oasis:entry colname="col4">45.7 (0.38)</oasis:entry>  
         <oasis:entry colname="col5">Na–Mg</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">20 Jun 2013</oasis:entry>  
         <oasis:entry colname="col2">– (44.5)</oasis:entry>  
         <oasis:entry colname="col3">– (1.2)</oasis:entry>  
         <oasis:entry colname="col4">45.7 (0.38)</oasis:entry>  
         <oasis:entry colname="col5">Cl–Mg</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">20 Jun 2013</oasis:entry>  
         <oasis:entry colname="col2">– (0.2–1.0)</oasis:entry>  
         <oasis:entry colname="col3">– (34.8–35.6)</oasis:entry>  
         <oasis:entry colname="col4">45.7 (0.38)</oasis:entry>  
         <oasis:entry colname="col5">Cl–Ca</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">20 Jun 2013</oasis:entry>  
         <oasis:entry colname="col2">– (15.3–17.9)</oasis:entry>  
         <oasis:entry colname="col3">– (17.9–20.5)</oasis:entry>  
         <oasis:entry colname="col4">45.7 (0.38)</oasis:entry>  
         <oasis:entry colname="col5">Na–Ca</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">18–20 Jun 2013</oasis:entry>  
         <oasis:entry colname="col2">51.9 (31.3–51.9)</oasis:entry>  
         <oasis:entry colname="col3">0.3 (0.3–20.9)</oasis:entry>  
         <oasis:entry colname="col4">52.2 (0.42)</oasis:entry>  
         <oasis:entry colname="col5">Cl</oasis:entry>  
         <oasis:entry colname="col6">One end-member series</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">18–20 Jun 2013</oasis:entry>  
         <oasis:entry colname="col2">– (27.3–36.4)</oasis:entry>  
         <oasis:entry colname="col3">– (15.8–24.9)</oasis:entry>  
         <oasis:entry colname="col4">52.2 (0.42)</oasis:entry>  
         <oasis:entry colname="col5">Na</oasis:entry>  
         <oasis:entry colname="col6">One end-member series</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">18–20 Jun 2013</oasis:entry>  
         <oasis:entry colname="col2">– (36.9)</oasis:entry>  
         <oasis:entry colname="col3">– (15.3)</oasis:entry>  
         <oasis:entry colname="col4">52.2 (0.42)</oasis:entry>  
         <oasis:entry colname="col5">Cl–Na</oasis:entry>  
         <oasis:entry colname="col6">Two end-member series</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">18–20 Jun 2013</oasis:entry>  
         <oasis:entry colname="col2">– (17.3–45.2)</oasis:entry>  
         <oasis:entry colname="col3">– (7.0–34.9)</oasis:entry>  
         <oasis:entry colname="col4">52.2 (0.42)</oasis:entry>  
         <oasis:entry colname="col5">Ca–Mg</oasis:entry>  
         <oasis:entry colname="col6">Two end-member series</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">16 Dec 2013</oasis:entry>  
         <oasis:entry colname="col2">5.3 (5.3–26.6)</oasis:entry>  
         <oasis:entry colname="col3">30.6 (9.2–30.6)</oasis:entry>  
         <oasis:entry colname="col4">35.8 (0.30)</oasis:entry>  
         <oasis:entry colname="col5">Na–Ca</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">16 Dec 2013</oasis:entry>  
         <oasis:entry colname="col2">17.1 (0.2–17.1)</oasis:entry>  
         <oasis:entry colname="col3">18.7 (18.7–35.8)</oasis:entry>  
         <oasis:entry colname="col4">35.8 (0.30)</oasis:entry>  
         <oasis:entry colname="col5">Cl–Ca</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">16 Dec 2013</oasis:entry>  
         <oasis:entry colname="col2">– (16.2–16.6)</oasis:entry>  
         <oasis:entry colname="col3">– (19.2–19.6)</oasis:entry>  
         <oasis:entry colname="col4">35.8 (0.30)</oasis:entry>  
         <oasis:entry colname="col5">Na–Cl</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">16 Dec 2013</oasis:entry>  
         <oasis:entry colname="col2">– (3.8–12.6)</oasis:entry>  
         <oasis:entry colname="col3">– (23.2–32.1)</oasis:entry>  
         <oasis:entry colname="col4">35.8 (0.30)</oasis:entry>  
         <oasis:entry colname="col5">Na–Mg</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">16 Dec 2013</oasis:entry>  
         <oasis:entry colname="col2">– (18.0)</oasis:entry>  
         <oasis:entry colname="col3">– (17.8)</oasis:entry>  
         <oasis:entry colname="col4">35.8 (0.30)</oasis:entry>  
         <oasis:entry colname="col5">Ca–Mg</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">16 Dec 2013</oasis:entry>  
         <oasis:entry colname="col2">– (2.3–33.4)</oasis:entry>  
         <oasis:entry colname="col3">– (2.4–33.6)</oasis:entry>  
         <oasis:entry colname="col4">35.8 (0.30)</oasis:entry>  
         <oasis:entry colname="col5">Cl–Mg</oasis:entry>  
         <oasis:entry colname="col6">Two end-member</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

<?xmltex \hack{\newpage}?>
</sec>
<sec id="Ch1.S3.SS3">
  <title>Mass balance analysis</title>
      <p>Mass balances were calculated using Cl, Na, Ca and Mg results from samples
collected in January, June and December 2013 (Table 1). The January 2013
period covered a consistent recession period (see Fig. 4), while the
June 2013 period included a flow event midway through the sampling period.
The December 2013 sampling covered a 2 day “snapshot” during a recession
period. The valid range of groundwater and ungauged tributary discharges
generated by varying the groundwater end-member concentration by <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1
standard deviation is shown in brackets after the values generated by the
mean groundwater composition in Table 1.</p>
      <p>In January 2013, the selected ions showed similar downstream (i.e. Sayers
Bridge to Bunker Hill) percentage increases (62–82 %) during the
recession events and cross plots (not shown) indicated that Na, Ca and Mg
were showing conservative behaviour relative to Cl. The mass balance analysis
(Table 1) showed that a range of groundwater discharge and ungauged tributary
values was valid, even during summer low flow conditions. This was consistent
with field observations that a number of the larger ungauged tributaries were
flowing in January 2013, and this was also the case in the June and
December 2013 field trips. In June 2013, before and after a flow event, the
selected ions showed more variable downstream (i.e. Upper Gellibrand to
Bunker Hill) percentage increases (57–124 %). The resulting mass balance
analyses again showed a range of contributions from the groundwater discharge
and ungauged tributary flow terms (Table 1). A number of combinations of
end-members could not return physically realistic estimates (i.e. one
discharge term being negative).</p>
      <p>Allowing for variation within the groundwater end-member composition
demonstrated the uncertainty in the range of valid flux estimates. The mass
balance analyses indicated that the ungauged tributary flow term was often
significant (consistent with field observations) but difficult to separate
from the groundwater discharge term. This was likely due to the similarity
in signature between these two end-members. The possibility of the ungauged
tributary flow forming a distinctively different physical end-member to
regional groundwater discharge (i.e. representing a different store and flow
path) is further investigated in Sect. 3.5.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6"><caption><p>Percentage saturated area (intersection of groundwater surface with
land surface) variations over time for the potentiometric (all bores) data
set <bold>(a)</bold> and the water table (33 bores) data set <bold>(b)</bold> for the
catchment area with elevation <inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 100 m. The position of the water table is
shown for three depths (0, 0.5, 1.0 m) to allow for uncertainties in the
mapping of the depth to water table. The mean daily baseflow for each month
is shown for two sets of Eckhardt filter parameter values calculated from the
Bunker Hill gauging record. Baseflow 1 uses the low BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula> value
(<inline-formula><mml:math display="inline"><mml:mrow><mml:mi>a</mml:mi><mml:mo>=</mml:mo><mml:mn>0.988</mml:mn></mml:mrow></mml:math></inline-formula>, BFI<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn>0.20</mml:mn></mml:mrow></mml:math></inline-formula>), while Baseflow 2 uses a higher
BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula> value (<inline-formula><mml:math display="inline"><mml:mrow><mml:mi>a</mml:mi><mml:mo>=</mml:mo><mml:mn>0.988</mml:mn></mml:mrow></mml:math></inline-formula>, BFI<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn>0.60</mml:mn></mml:mrow></mml:math></inline-formula>).</p></caption>
          <?xmltex \igopts{width=213.395669pt}?><graphic xlink:href="https://www.hydrol-earth-syst-sci.net/19/1599/2015/hess-19-1599-2015-f06.pdf"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS4">
  <title>Baseflow–water table dynamics</title>
      <p>The monthly time series of groundwater surface mapping from both the
“potentiometric” data set (88 bores) and the “water table” data set (33
bores) allows analysis of the dynamics of the relationship between baseflow
and groundwater fluctuations and of the spatial distribution of shallow
groundwater relative to the sampling of ungauged tributaries. Both sets of
groundwater maps showed approximately similar patterns but with the water
table surfaces being slightly deeper and with higher standard deviations (see
the example in Fig. 5). The maps showed that areas with groundwater <inline-formula><mml:math display="inline"><mml:mo>≤</mml:mo></mml:math></inline-formula> 5 m from the ground surface were confined to the alluvial plains of the
Gellibrand River and one of its major gauged tributaries, Love Creek, and
these areas coincided with lower standard deviations in the water
table mapping (Fig. 5). The areas of very shallow groundwater (0 m,
<inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 0.5 m, <inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 1 m below the ground surface) were tabulated and plotted
for both the “potentiometric” data set and the “water table” data set
(Fig. 6) to identify areas where the groundwater could discharge to the
surface or into channels within the uncertainty range of the groundwater
mapping. The percentage changes in “saturated area” (i.e. water tables
within a specified depth to surface) showed different behaviour between the
potentiometric and water table data sets. The potentiometric data set showed
areas of artesian head along the valley floors and consistently small
seasonal variations with only minor differences between years. For example,
the difference between the spring (September–October) peak and autumn
(April–May) trough was low in absolute terms (<inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 0.15 % of area
<inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 100 m in elevation) and relative terms (9–19 % variation between
peaks and troughs). In contrast, the water table data set showed that
groundwater heads remained below the land surface, but did show much larger
variations in absolute area (e.g. <inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 1.2 % of area for groundwater
surfaces within 1 m of the land surface) and relative size of peaks (e.g.
80–100 %) between years compared to the potentiometric data set. In
comparison, the two baseflow time series (using BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula> parameter
values of 0.2 and 0.6, see Sect. 3.1) showed large relative variations of
72–95 % between peaks and troughs that were similar to the peak seasonal
variation shown by the water table surfaces, but not to the potentiometric
surfaces. The peak saturated areas typically coincided with peak estimated
baseflow, except for 2007. For both groundwater data sets, the results are
generally not consistent, with changes in the saturated area being the
dominant driver of peak variations in baseflow, as measured by the Eckhardt
filter. In particular, the potentiometric data set shows a far more
consistent range in seasonal peaks compared to the digital filter estimated
baseflow. While the water table data set does show a similar pattern in
seasonal peaks, the water table rarely reaches the land surface. The
saturated areas largely coincided (e.g. see Fig. 5) and were restricted to
the valley floor of the catchment and with little variation in the location
of these areas between dates. The restriction of the saturated areas to the
valley floors indicates little regional groundwater discharge into minor
tributaries, and this is analysed further in Sect. 3.5.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7"><caption><p>Monthly variations in saturated volumes for the catchment area with
elevation <inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 100 m for both the potentiometric and water table data sets
and for monthly baseflow derived from Eckhardt analysis (using a
BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula> value of 0.2).</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://www.hydrol-earth-syst-sci.net/19/1599/2015/hess-19-1599-2015-f07.pdf"/>

        </fig>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T2" specific-use="star"><caption><p>Minimum, median and 90th percentile values for the ratio of monthly
Eckhardt filter baseflow to “water table” volume changes using a range of
specific yields (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:mi>y</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> – Wangerrip Group, <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:mi>y</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> – alluvium, <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:mi>y</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>
– Heytesbury Group aquitards). Filtered baseflow time series were calculated
using an <inline-formula><mml:math display="inline"><mml:mi>a</mml:mi></mml:math></inline-formula> value of 0.988 and BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula> values of 0.2 or 0.6. Only
months with declining volume changes were used in the analysis.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="9">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="left"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="left"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:colspec colnum="9" colname="col9" align="right"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry rowsep="1" namest="col2" nameend="col3" align="center">Min ratio </oasis:entry>  
         <oasis:entry colname="col4"/>  
         <oasis:entry rowsep="1" namest="col5" nameend="col6" align="center">Median ratio </oasis:entry>  
         <oasis:entry colname="col7"/>  
         <oasis:entry rowsep="1" namest="col8" nameend="col9" align="center">90th perc. ratio </oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"><inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:mi mathvariant="normal">y</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:mi mathvariant="normal">y</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mrow><mml:mi mathvariant="normal">y</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col2">BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.2</oasis:entry>  
         <oasis:entry colname="col3">0.6</oasis:entry>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">0.2</oasis:entry>  
         <oasis:entry colname="col6">0.6</oasis:entry>  
         <oasis:entry colname="col7"/>  
         <oasis:entry colname="col8">0.2</oasis:entry>  
         <oasis:entry colname="col9">0.6</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">0.1, 0.3, 0.05</oasis:entry>  
         <oasis:entry colname="col2">0.41</oasis:entry>  
         <oasis:entry colname="col3">0.89</oasis:entry>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">3.23</oasis:entry>  
         <oasis:entry colname="col6">10.81</oasis:entry>  
         <oasis:entry colname="col7"/>  
         <oasis:entry colname="col8">27.3</oasis:entry>  
         <oasis:entry colname="col9">57.3</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">0.1, 0.2, 0.05</oasis:entry>  
         <oasis:entry colname="col2">0.41</oasis:entry>  
         <oasis:entry colname="col3">0.89</oasis:entry>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">3.88</oasis:entry>  
         <oasis:entry colname="col6">12.89</oasis:entry>  
         <oasis:entry colname="col7"/>  
         <oasis:entry colname="col8">28.4</oasis:entry>  
         <oasis:entry colname="col9">61.7</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">0.1, 0.1, 0.05</oasis:entry>  
         <oasis:entry colname="col2">0.41</oasis:entry>  
         <oasis:entry colname="col3">0.89</oasis:entry>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">6.77</oasis:entry>  
         <oasis:entry colname="col6">18.06</oasis:entry>  
         <oasis:entry colname="col7"/>  
         <oasis:entry colname="col8">38.0</oasis:entry>  
         <oasis:entry colname="col9">80.2</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">0.15, 0.3, 0.05</oasis:entry>  
         <oasis:entry colname="col2">0.27</oasis:entry>  
         <oasis:entry colname="col3">0.59</oasis:entry>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">2.52</oasis:entry>  
         <oasis:entry colname="col6">8.59</oasis:entry>  
         <oasis:entry colname="col7"/>  
         <oasis:entry colname="col8">15.9</oasis:entry>  
         <oasis:entry colname="col9">33.9</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">0.05, 0.05, 0.05</oasis:entry>  
         <oasis:entry colname="col2">0.82</oasis:entry>  
         <oasis:entry colname="col3">1.78</oasis:entry>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">11.9</oasis:entry>  
         <oasis:entry colname="col6">32.21</oasis:entry>  
         <oasis:entry colname="col7"/>  
         <oasis:entry colname="col8">49.8</oasis:entry>  
         <oasis:entry colname="col9">12.5</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">0.1, 0.1, 0.1</oasis:entry>  
         <oasis:entry colname="col2">0.41</oasis:entry>  
         <oasis:entry colname="col3">0.89</oasis:entry>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">5.96</oasis:entry>  
         <oasis:entry colname="col6">16.11</oasis:entry>  
         <oasis:entry colname="col7"/>  
         <oasis:entry colname="col8">24.9</oasis:entry>  
         <oasis:entry colname="col9">60.2</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">0.2, 0.2, 0.2</oasis:entry>  
         <oasis:entry colname="col2">0.21</oasis:entry>  
         <oasis:entry colname="col3">0.45</oasis:entry>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">2.98</oasis:entry>  
         <oasis:entry colname="col6">8.05</oasis:entry>  
         <oasis:entry colname="col7"/>  
         <oasis:entry colname="col8">12.4</oasis:entry>  
         <oasis:entry colname="col9">30.1</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">0.3, 0.3, 0.3</oasis:entry>  
         <oasis:entry colname="col2">0.14</oasis:entry>  
         <oasis:entry colname="col3">0.30</oasis:entry>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">1.99</oasis:entry>  
         <oasis:entry colname="col6">5.37</oasis:entry>  
         <oasis:entry colname="col7"/>  
         <oasis:entry colname="col8">8.3</oasis:entry>  
         <oasis:entry colname="col9">20.1</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p>The analysis of monthly changes in saturated volume and mean monthly Eckhardt
baseflow provides further evidence that the regional groundwater discharge is
not the major driver of the baseflow time series. The saturated volume
changes (at elevations <inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 100 m) for both the potentiometric and water
table data sets (Fig. 7) were similar, but with the water table data set
showing greater variability between months. The water table variation showed
an expected seasonal pattern of peak increases in winter and peak decreases
in summer. The baseflow time series showed a lagged response, with peak
baseflow occurring in spring. For months in the water table data set with
declining saturated volumes (i.e. periods where changes in saturated volume
are dominated by discharge), we used a range of specific yield values to
convert the total volume change to a volume of discharged water for areas
within the <inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 100 m mask (Table 2). There are no pump test data for the
catchment, but Atkinson et al. (2014) used a specific yield of 0.1 to
estimate recharge for the Eastern View Formation (Wangerrip Group),
consistent with the effective porosity of this unit (Love et al., 1993). A
hydrogeological modelling study in similar units of the Otway Basin used
specific yield values of 0.1 for both aquifers and aquitards in their
calibrated model (SKM, 2010). We use a range of realistic but relatively high
(Nwankwor et al., 1984) specific yield values from 0.05 to 0.3 for the
different geological units within the <inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 100 m elevation mask for the
groundwater surfaces (see Fig. 1). The estimates of the ratio of monthly
baseflow (from the Eckhardt filter) to monthly mapped volume change, shown in
Table 2, are generated using the same specific yield values across all
geological units and also by varying the values consistently with expected
hydrogeological properties (i.e. specific yield of alluvium <inline-formula><mml:math display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> Wangerrip
Group <inline-formula><mml:math display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> Heytesbury Group). We consider that this range of estimates based
on these specific yield values provides an upper bound to the groundwater
discharge, particularly since any phreatic evapotranspiration flux, which
would also account for some of the volume changes, is not considered. For the
study period of 2007–2010, only three months showed a ratio of <inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 1
between the monthly baseflow time series (generated using BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula>
values of 0.2 and 0.6) and the corresponding monthly change in mapped water
table volume (i.e. saturated volume change <inline-formula><mml:math display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> baseflow), using the range of
specific yield values. The median ratio for both baseflow time series ranged
from 2.0 to 32.2 (Table 2), with more realistic (i.e. smaller) specific yield
values generating the larger median ratios (i.e. saturated volume change
<inline-formula><mml:math display="inline"><mml:mo>≪</mml:mo></mml:math></inline-formula> baseflow) compared to specific yield values considered to represent an
upper bound. The late summer to early winter period (January to June, <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn>17</mml:mn></mml:mrow></mml:math></inline-formula>)
had median ratios 10–15 % less than the late winter to early summer
period (July to December, <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn>20</mml:mn></mml:mrow></mml:math></inline-formula>), but both periods had months with very
large (<inline-formula><mml:math display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 10) ratios. These results indicate that the monthly baseflow
fluxes are significantly larger than can be explained by groundwater
discharge from the valley regions during most months of the year and requires
a significant additional flux of “slow flow” into the river (see also
Fig. 9).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F8"><caption><p>Piper diagram (right) shows tributary samples grouped by the minimum
depth to groundwater table in the sub-catchment upstream of the sampling
point. Compositions of sampled groundwater bores are also shown. The spatial
location and sub-catchment extent are shown superimposed on the
potentiometric depth to groundwater map for September 2010.</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://www.hydrol-earth-syst-sci.net/19/1599/2015/hess-19-1599-2015-f08.pdf"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS5">
  <title>Relationship between groundwater and tributary chemistry</title>
      <p>The relationship between regional groundwater and ungauged tributary
chemistry was examined by grouping subcatchments using the depth to
potentiometric groundwater upstream of each sampling point on the ungauged
tributaries. The subcatchment areas ranged from 0.4 to 47.4 km<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> (mean
11.0 km<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and the seasonal peak groundwater level in September 2010 was
used in the analysis as it was a representative period of seasonal high
groundwater levels for the study period. The minimum monthly groundwater
depths within the subcatchments ranged from <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>6 (i.e. above ground surface)
to 84 m below ground surface. Given the uncertainty in the minimum mapped
position of the groundwater surface (i.e. see the mapped standard deviation
of the groundwater position in Fig. 5), the subcatchments were arbitrarily
divided between those with groundwater within 5 m of the land surface
anywhere within the sub-catchment (i.e. where groundwater discharge into
channels within the subcatchment was possible) and those with deeper
groundwater (Fig. 8). There were no significant differences in the tributary
compositions in subcatchments with shallow groundwater (i.e. minimum depths
<inline-formula><mml:math display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 5 m from the ground surface) or deep groundwater. These results suggest
that seasonal regional groundwater level rises are not likely to drive
seasonal increases in ungauged tributary inflow from the upper parts of the
catchment. This is consistent with the chemistry of the major tributaries
being similar to that of the Gellibrand River flow rather than that of the
alluvial groundwater (Fig. 3). Therefore, seasonal increases in ungauged
tributary inflow are more likely to be driven by interflow or perched aquifer
processes, rather than variations in the regional groundwater. The baseflow
filter estimates show large increases in the “slow flow” component of
streamflow during winter–spring periods that were not consistent with
probable groundwater discharge (Fig. 7). The mass balance calculations
indicate that small, ungauged tributaries are a significant contributorto
this increase and can be a contributor even during low flow periods.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F9"><caption><p>Scatter plots showing various estimates of baseflow and groundwater
discharge. <bold>(a)</bold> Mass balance tracer estimates (from Atkinson et
al. (2015) for 2011–2012 and the mid-point of the range shown in Table 1 for
2013) for groundwater discharge against the residual streamflow (Bunker Hill
streamflow less upstream gauged streamflow). <bold>(b)</bold> Mass balance tracer
estimates against the Eckhardt filter baseflow estimates (Qb1 uses <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>a</mml:mi><mml:mo>=</mml:mo><mml:mn>0.988</mml:mn></mml:mrow></mml:math></inline-formula>
and BFI<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn>0.2</mml:mn></mml:mrow></mml:math></inline-formula>; Qb2 uses <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>a</mml:mi><mml:mo>=</mml:mo><mml:mn>0.988</mml:mn></mml:mrow></mml:math></inline-formula> and BFI<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn>0.6</mml:mn></mml:mrow></mml:math></inline-formula>).
<bold>(c)</bold> Residual discharge against Eckhardt filter baseflow time series
for 2007–2013. <bold>(d)</bold> Saturated volume changes (using specific yield
set 0.15, 0.30, 0.05 from Table 2) against residual flow and Eckhardt filter
baseflow time series.</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://www.hydrol-earth-syst-sci.net/19/1599/2015/hess-19-1599-2015-f09.pdf"/>

        </fig>

</sec>
</sec>
<sec id="Ch1.S4">
  <title>Discussion</title>
<sec id="Ch1.S4.SS1">
  <title>Baseflow estimates</title>
      <p>Digital baseflow filters separate out the “slow flow” component of
streamflow. As such, they provide an effective upper bound on possible
groundwater discharge to streamflow (Cartwright et al., 2014). This was
tested by plotting scatter plots of baseflow estimates for the Gellibrand
River from Eckhardt digital filter analysis, residual streamflow (i.e. Bunker
Hill discharge less other gauged tributaries lagged by 1 day – Upper
Gellibrand, Lardner Creek, Love Creek) and tracer mass balance analyses
(Fig. 9a, b, c) for the 2011–2013 period. The tracer estimates include the
range of estimates from Atkinson et al. (2015) for sampling from known dates
conducted in 2011–2012 using <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mn>222</mml:mn></mml:msup></mml:math></inline-formula>Rn and Cl mass balance, plus the
results from this study for sampling in 2013 using major ions (shown as
mid-points of the range for each date shown in Table 1). None of these
estimates is directly comparable, as they measure different components of
baseflow, but their comparison is informative. The digital filter time-series
estimates baseflow from the entire catchment upstream of Bunker Hill gauging
station. The Atkinson et al. (2015) estimates are for the groundwater
discharge component of streamflow measured over the alluvial valley reach
(approximately two-thirds of the Bunker Hill to Upper Gellibrand reach, see
Fig. 1) and use a two end-member mass balance approach (tributary inflow was
not considered). The tracer mass balance results from our study are for the
groundwater discharge component of baseflow over the Bunker Hill to Upper
Gellibrand reach and account for ungauged tributary inflow. For additional
comparison, the residual monthly discharge, monthly baseflow and the monthly
saturated volume change for months with decreasing volumes were plotted
(Fig. 9d). The saturated volume change was calculated with a realistic
specific yield range (set 0.15, 0.3, 0.05 in Table 2) that produces a
relatively high estimate of groundwater discharge compared to estimates using
other specific yield values (see Table 2).</p>
      <p>The tracer estimates of groundwater discharge and the residual discharge
generally show a consistent relationship (Fig. 9a). The Atkinson et
al. (2015) estimates coincided with the residual discharge, except for two
outliers from one date sampled on a small rising limb, but neither method
separates out in-reach tributary flow from groundwater discharge. The tracer
estimates from this study used the residual discharge as an upper bound in
their estimation and so show a high correlation and a negative bias with the
residual discharge. When the tracer estimates are plotted against two
baseflow filter estimates (Fig. 9b, using <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>a</mml:mi><mml:mo>=</mml:mo><mml:mn>0.988</mml:mn></mml:mrow></mml:math></inline-formula>, BFI<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn>0.2</mml:mn></mml:mrow></mml:math></inline-formula>
and <inline-formula><mml:math display="inline"><mml:mrow><mml:mi>a</mml:mi><mml:mo>=</mml:mo><mml:mn>0.988</mml:mn></mml:mrow></mml:math></inline-formula>, BFI<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn>0.6</mml:mn></mml:mrow></mml:math></inline-formula>) the relationships are poorly
correlated and with the tracer estimates both under- and over-estimating
relative to the baseflow filter estimates. The use of the larger
BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula> value (0.6), more consistent with the recommendations of
Eckhardt (2005), results in the tracer estimates having a more negative bias
relative to the baseflow filter estimates. The daily residual discharge is
also compared to the baseflow filter estimates over the period 2007–2013
(Fig. 9c). The use of the larger BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula> value results in baseflow
generally higher than the residual flow (but with considerable scatter) while
the lower BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula> value results in baseflow generally lower than
the residual discharge, particularly at high discharges. Finally, the mapped
monthly changes in saturated groundwater volume (see Fig. 7) were plotted
against the monthly residual discharge and baseflow filter estimates (using
<inline-formula><mml:math display="inline"><mml:mrow><mml:mi>a</mml:mi><mml:mo>=</mml:mo><mml:mn>0.988</mml:mn></mml:mrow></mml:math></inline-formula>, BFI<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn>0.2</mml:mn></mml:mrow></mml:math></inline-formula> and 0.6) over the 2007–2010 period
(Fig. 9d). The saturated volume changes were typically lower than both the
residual discharge and the two baseflow discharges, consistent with the
residual and baseflow measures providing an upper bound to groundwater
discharge within the study reach. Even the groundwater volume change is more
likely to represent an upper bound estimate than an unbiased estimate due to
the use of a relatively high specific yield range and not accounting for
phreatic evapotranspiration.</p>
      <p>Tracer data can be used to calibrate the BFI<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:math></inline-formula> parameter in the
Eckhardt digital filter (Gonzalez et al., 2009) if a suitable end-member
signature can be identified. However, in catchments with low salinity
alluvial groundwater (i.e. catchments with low groundwater residence time),
end-member differentiation can be an issue (Kendall et al., 2001).</p>
      <p>The different estimates of baseflow and groundwater discharge emphasise the
difficulties in separating and defining these important fluxes, particularly
how they vary seasonally. In the context of the catchment used in this study,
these variations raise questions of whether the in-reach tributary inflow can
be lumped with groundwater discharge (i.e. whether regional groundwater
discharge also drives tributary flow) and whether the digital baseflow filter
analysis overestimates groundwater discharge during high flow periods. The
separation of groundwater discharge from other slow flow pathways
(e.g. interflow or perched aquifer discharge driving tributary flow) can be
an important distinction for water resource management.</p>
</sec>
<sec id="Ch1.S4.SS2">
  <title>Water table dynamics and uncertainties</title>
      <p>The first two hypotheses addressed by this paper involve the ability of
monthly groundwater surface dynamics to explain monthly variations in digital
filter estimated baseflow. Large increases in baseflow during the high flow
season (e.g. winter–spring) could also contain contributions from other slow
fluxes (e.g. interflow and perched aquifer discharge contributing to
tributary flow, bank storage return). In order to avoid overestimations of
groundwater discharge, it is important to independently test the assumption
of a single storage (i.e. regional groundwater) driving baseflow.</p>
      <p>In terms of the groundwater contribution, we postulated that the main driver
of large increases in baseflow would be non-linear increases in the discharge
area as groundwater levels rose and intersected more of the land surface.
Monthly groundwater surfaces were used to test whether such increases in
discharge area are a feasible mechanism. In the case of the Gellibrand
catchment, the groundwater data showed that only modest increases in possible
discharge area occurred during the seasonal peaks in groundwater levels. The
pattern in the magnitude of seasonal peaks of digital filter estimated
baseflow was similar to that shown by the water table surfaces but not by the
potentiometric surfaces. The limited seasonal variations in the
potentiometric surfaces probably reflect the upward gradients observed in
bores screened in the Eastern View Formation. The mapped water table surfaces
rarely reach the ground surface, but the large seasonal variations in the
water table within 1 m of the ground surface (Fig. 6b) are likely to
interact with the drainage system along the valley, particularly within the
uncertainty range of the groundwater mapping. Fluctuations in the water
table remain a relatively coarse measure and provide only a first-order
estimate of possible groundwater discharge patterns. For instance, the
mapping does not have the resolution to identify the fine detail of channels
and near-stream zones. Stage variations in channels will have local effects
on groundwater recharge and discharge that are not captured by the
groundwater mapping. Likewise, capillary fringing effects in near-stream
zones could lead to rapid increases in the water table with a small rise in
water content in the unsaturated zone (Gillham, 1984). Furthermore, the
spatial correlation (as defined by the model variogram) may vary with the
groundwater level (Lyon et al., 2006; Peterson et al., 2011) and alternative
external drift terms to land surface elevation, such as the topographic
wetness index, could possibly better represent near-stream spatial
heterogeneity.</p>
      <p>The groundwater mapping technique also assumes that the groundwater–river
interaction is dominated by unconfined groundwater. Atkinson et al. (2015)
found that much of the estimated groundwater discharge (50–90 %) in the
study catchment was occurring over a short 5–10 km reach where the river
intersected the outcropping Eastern View Formation, the main regional
semi-confined aquifer. It is quite possible that variations in discharge from
this regional aquifer may not be adequately represented by changes in the
potentiometric groundwater surfaces or the water table. However, temporal
changes in the saturated volume of the groundwater, as estimated by
groundwater surface mapping, should provide a first-order control on the
total amount of groundwater discharge. The digital filter estimates of
baseflow were generally significantly larger in most months than could be
explained by estimates of groundwater volume change in these periods using
specific yield values likely to represent the upper bound of the specific
yield range of the different geological units within the catchment. This
“excess” baseflow most likely represents interflow and hillslope perched
aquifer discharge contributing to streamflow as the catchment drains
following the winter–spring wet season.</p>
      <p>The generation of the potentiometric surface (using 88 bores) and the water
table (using 33 bores) gives an indication of the sensitivity of the use of
groundwater surface mapping to the number of data available. The maps
generated from the two data sets showed some differences, particularly in the
minimum depths to groundwater and the increase in the standard deviation of
the water table data set (e.g. see Fig. 5). The increase in the standard
deviation of each monthly groundwater surface from the use of fewer bores
demonstrates the expected result that confidence in the groundwater mapping
analysis will decrease with fewer data points. However, in the case of the
Gellibrand catchment, the similar estimates of monthly saturated volume
changes from both data sets (Fig. 8) indicated that the relative differences
between monthly groundwater surfaces generated by the two data sets were
small. This is probably because most monitoring bores in both data sets were
located on the valley floors, and so confidence in the interpolated water
table surfaces was highest in these areas. These areas are also of most
interest in investigating groundwater–river interactions. The effectiveness
of groundwater mapping as a water resource assessment tool will depend on the
number of monitoring bores within a catchment, but the question of how many
monitoring bores are required will be highly dependent on the catchment size
and spatial distribution of bores. In this study area, monitoring bores were
commonly located in clusters and transects of limited length and these
locations were likely determined by ease of access for drilling and the
specific aims of past investigations rather than to optimise the spatial
distribution of groundwater observations for catchment-wide water
table mapping. As a result, the uncertainty of groundwater surface maps would
be very catchment specific and difficult to generalise to other locations.</p>
</sec>
<sec id="Ch1.S4.SS3">
  <title>End-member–water table dynamics</title>
      <p>The geostatistical mapping of groundwater surfaces in conjunction with
terrain analysis allows the testing of end-member assumptions. For example,
streamflow from small tributaries during dry periods could be sourced
primarily from regional unconfined groundwater or perched
aquifer–interflow-type processes. Given the lack of availability of
piezometers targeting the latter pathways in most catchments, the capacity to
test the possible source of tributary flow provides important information on
the suitability of the tributary flow as a separate end-member to flow in the
main river. In this context, the results from this study clearly show that
much of the small tributary flow in the Gellibrand catchment has a similar
chemical signature to the regional groundwater. Nevertheless, most
tributaries were sampled from sub-catchments with regional groundwater
significantly deeper than the land surface. The chemical similarities between
the small tributary flow (probably representing interflow) and the regional
groundwater was not unexpected given that it is likely that this interflow
development is the major contributor to the deeper regional groundwater
recharge. The ionic similarities between these end-members illustrate that
mass balance techniques will struggle to separate these fluxes with any
confidence and that additional, independent data, such as water
table mapping, are required to confidently identify the groundwater discharge
flux.</p>
</sec>
</sec>
<sec id="Ch1.S5" sec-type="conclusions">
  <title>Conclusions</title>
      <p>Geostatistical mapping of unconfined groundwater surfaces provides a useful,
independent data set for investigating sources of fluxes contributing to
baseflow estimated by traditional digital filter and tracer end-member
approaches. In particular, the method can provide added confidence in the
lower bound of baseflow estimates that best correspond to regional
groundwater discharge in both low and high flow periods. Specifically, the
groundwater surface data set can be used to identify whether variations in
discharge area (i.e. groundwater intersecting the land surface) or saturated
volume can explain seasonal variations in baseflow, as estimated using
digital filters. This data set is particularly useful in humid, hilly
catchments where interflow or perched aquifer discharge is likely to be a
significant process and where the different “slow flow” fluxes have similar
low salinity chemistry that hinders end-member analysis. Sufficient
monitoring bore data to construct water table maps are not available in all
catchments and the method is likely to be restricted to catchments where
groundwater investigations have resulted in the existence of an adequate bore
network. The adequacy of the network will depend on catchment size, the
spatial distribution of bores (i.e. uniform versus non-uniform distribution,
location relative to the drainage network) and the spatial correlation of the
monitored water level. However, where adequate monitoring data are available,
this method adds significant value to water resource management by making
better use of an independent, but often under-utilised, data set that can
inform groundwater contributions to streamflow.</p>
</sec>

      
      </body>
    <back><app-group>
        <supplementary-material position="anchor"><p><bold>The Supplement related to this article is available online at <inline-supplementary-material xlink:href="http://dx.doi.org/10.5194/hess-19-1599-2015-supplement" xlink:title="pdf">doi:10.5194/hess-19-1599-2015-supplement</inline-supplementary-material>.</bold></p></supplementary-material>
        </app-group><notes notes-type="authorcontribution">

      <p>J. F. Costelloe, A. W. Western and J. J. McDonnell designed
the field experiments and analyses. K. Halbert and T. J. Peterson designed
and carried out the groundwater mapping, with T. J. Peterson developing the
model code for the temporal interpolation of groundwater observations and
mapping of groundwater surfaces. J. F. Costelloe carried out most of the data
analysis and prepared the manuscript with contributions from all co-authors.</p>
  </notes><ack><title>Acknowledgements</title><p>This work is funded by the Australian Research Council Discovery Project
scheme through project DP120100253. We greatly appreciate the provision of
groundwater chemistry data and introduction to the Gellibrand catchment by
Alex Atkinson and Ian Cartwright from Monash University. We thank two
anonymous reviewers and Ian Cartwright for their insightful and constructive
reviews that helped improve this paper.<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?> Edited
by: T. Bogaard</p></ack><ref-list>
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